RS59772B1 - Method for processing carbon dioxide contained in an exhaust gas flow - Google Patents
Method for processing carbon dioxide contained in an exhaust gas flowInfo
- Publication number
- RS59772B1 RS59772B1 RS20200030A RSP20200030A RS59772B1 RS 59772 B1 RS59772 B1 RS 59772B1 RS 20200030 A RS20200030 A RS 20200030A RS P20200030 A RSP20200030 A RS P20200030A RS 59772 B1 RS59772 B1 RS 59772B1
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- carbon
- aqueous medium
- alkaline earth
- ionized
- main chamber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Processing Of Solid Wastes (AREA)
- Carbon And Carbon Compounds (AREA)
Description
Opis Description
[0001] Predmetni pronalazak se odnosi na postupak za preradu ugljen-dioksida koji se nalazi u struji (toku) izduvnih gasova u proizvod pogodan za proizvodnju energije prema preambuli u zahtevu 1 i US2011/0256049. [0001] The present invention relates to a process for processing carbon dioxide found in the stream (flow) of exhaust gases into a product suitable for energy production according to the preamble in claim 1 and US2011/0256049.
[0002] Ovaj dokument otkriva postupak za proizvodnju nanosfera i drugih nanočestica ugljenika, pri čemu se ugljen dioksid i magnezijum prah koriste kao polazni materijali koji međusobno reaguju u reaktoru. Dostignuta visoka temperatura, od 2000 ° F do 5000 ° F, što odgovara oko 1100 ° C do 2760 ° C, oslobađa veliku količinu energije u obliku toplote i svetlosti. Različiti dodatni materijali se mogu koristiti, ali ključno je da ugljeni dioksid bude čist, a ne deo vazdušne smeše. [0002] This document discloses a process for the production of nanospheres and other carbon nanoparticles, wherein carbon dioxide and magnesium powder are used as starting materials that react with each other in a reactor. The high temperature reached, from 2000 ° F to 5000 ° F, which corresponds to about 1100 ° C to 2760 ° C, releases a large amount of energy in the form of heat and light. Various additional materials can be used, but the key is that the carbon dioxide is pure and not part of the air mixture.
[0003] Zbog toga postoji potreba za metodom kojom može da se preradi ugljendioksid koji se nalaziu struji izduvnih gasova. [0003] Therefore, there is a need for a method that can process the carbon dioxide found in the exhaust gas stream.
[0004] Prema pronalasku, ovaj cilj se postiže karakteristikama navedenim u karakterističnom delu zahteva 1. [0004] According to the invention, this goal is achieved by the features specified in the characteristic part of claim 1.
[0005] Ovaj tretman je postignut prema pronalasku pri čemu [0005] This treatment is achieved according to the invention whereby
a) struja izduvnih gasova koja ima temperaturu u opsegu od 150 do 170 ° C i pH od oko 4 struje izduvnih gasova u komori za sušenje i pH vrednost oko 4, u komori za sušenje i hlađenje sa sa poroznim, silikatnim materijalom vlažnosti od 15 - 60% na bazirano na suvoj ukupnoj masi silikatnog materijala i dodavanjem aluminijum hidroksid i/ili hidratisanog aluminijum oksida dovode se u kontakt da bhi se dobio bazni, vodeni medijuma sa pH vrednosti između 10 i 13 i hladi se na temperaturu od 30 do 50 ° C, količina aluminijum hidroksida i / ili aluminijum oksid hidrata koji se mešaju kontroliše se pomoću trenutnog merenja pH vrednosti, a vodeni medijum je ohlađen na temperaturu između 12 i 13 °C dok ne napusti komoru za sušenje i hlađenje, a) exhaust gas stream that has a temperature in the range of 150 to 170 ° C and a pH of about 4 exhaust gas stream in the drying chamber and a pH value of about 4, in the drying and cooling chamber with the porous, silicate material humidity of 15 - 60% based on the dry total weight of the silicate material and adding aluminum hydroxide and/or hydrated aluminum oxide are brought into contact to obtain a basic, aqueous medium with a pH value between 10 and 13 and cooled to a temperature of 30 to 50 °C, the amount of aluminum hydroxide and / or aluminum oxide hydrate to be mixed is controlled by means of an instantaneous measurement of the pH value, and the aqueous medium is cooled to a temperature between 12 and 13 °C until it leaves the drying and cooling chamber,
b) vodeni medijum se dovodi u sledeću predkomoru koja je napunjena oksidujućim zemnoalkalnim metalom i / ili teškim metalom, pri čemu dolazi do oksidacije zemnoalkalnog i / ili teškog metala, čiji odnos prema tečnosti vodenog medijuma je oko 1: 7 težinskih %, kiseonikom koji potiče iz jonizovanog i nestabilizovanog ugljen dioksida i zajedno sa tim, dolazi do neutralizaciju vodene, jonizovane sredine koja sadrži ugljenik i naknadno formiran oksid zemnoalkalnog i/ili teškog metala se zatim ispušta iz pretkomore, pri čemu se u zavisnosti od trenutnog merenja istovremeno vrši i isporuka materijal oksidujućeg zemnoalkalnog metala i/ili teškog metala i b) the aqueous medium is fed into the next antechamber, which is filled with oxidizing alkaline earth metal and/or heavy metal, whereby the oxidation of the alkaline earth and/or heavy metal occurs, the ratio of which to the liquid of the aqueous medium is about 1:7% by weight, with oxygen originating from ionized and destabilized carbon dioxide, and together with that, the neutralization of the aqueous, ionized medium containing carbon and subsequently formed alkaline earth oxide occurs and/or heavy metal is then discharged from the antechamber, whereby, depending on the current measurement, the material of oxidizing alkaline earth metal and/or heavy metal is delivered at the same time and
c) vodeni, jonizovani ugljeni (C) medijum se zatim dovodi u glavnu komoru opremljenu materijalom koji se sastoji od organskih jedinjenja ugljenika i / ili sadrži organska jedinjenja ugljenika, uz učešće jonizovanog ugljenika na temperaturama između 5 i 80 ° C i pritisku između 01, i 10 bara polireakcije sa organskim jedinjenjima ugljenika da bi se dobio krajnji proizvod obogaćen ugljenikom. c) the aqueous, ionized carbon (C) medium is then fed into the main chamber equipped with a material consisting of organic carbon compounds and / or containing organic carbon compounds, with the participation of ionized carbon at temperatures between 5 and 80 ° C and pressure between 01, and 10 bar of polyreaction with organic carbon compounds to obtain a final product enriched with carbon.
[0006] Pronalazak je detaljnije objašnjen u nastavku upućivanjem na crtež, gde Slika 1 prikazuje dijagram toka prema pronalasku postupka za preradu ugljen-dioksida CO2sadržanog u struji izduvnih gasova uz pomoć tro-komornog sistema u proizvod pogodan za proizvodnju energije, a slika 2a prikazuje prosečan početni sadržaj O2i CO2struje izduvnih gasova koji će biti obrađen, slika 2b prosečni sadržaja O2i CO2na izlazu iz pretkomore prikazanom u dijagramu protoka prema slici 1 i slici 2c daje prosečni sadržaj O2i CO2na izlazu glavne komore prikazan u dijagramu toka prema slici 1 , svaki tokom mernog perioda od tri dana. [0006] The invention is explained in more detail below with reference to the drawing, where Figure 1 shows a flow diagram according to the invention of a process for processing carbon dioxide CO2 contained in the exhaust gas stream with the help of a three-chamber system into a product suitable for energy production, and Figure 2a shows the average initial content of O2i CO2 of the exhaust gas stream to be processed, Figure 2b the average content of O2i CO2 at the outlet of the antechamber shown in the flow diagram according to Figure 1 and Figure 2c gives the average content of O2 and CO2 at the outlet of the main chamber shown in the flow diagram according to Figure 1, each during a measurement period of three days.
[0007] Treba unapred napomenuti da pojedinačne komponente upotrjebljenih materijala kao i sredina prisutna u odgovarajućim procesnim koracima podležu kontinualnom merenju 2 tokom celog niza procesa, pri čemu se punjenje materijala u odgovarajućim procesnim komorama reguliše prema potrebi ili u zavisnosti od rezultata merenja. Na primer, količina aluminijum hidroksida i / ili hidratisanog aluminijum oksida koja se meša kontroliše se pomoću kontinuiranog pH merenja 2. [0007] It should be noted in advance that the individual components of the materials used as well as the environment present in the respective process steps are subject to continuous measurement 2 during the entire series of processes, whereby the filling of materials in the respective process chambers is regulated as needed or depending on the measurement results. For example, the amount of aluminum hydroxide and/or hydrated aluminum oxide mixed is controlled by continuous pH measurement 2 .
[0008] U ovom slučaju, struja 1 izduvnih gasova, na primer sirov gas iz postrojenja za spaljivanje, najčešće sa pH od oko 4 i pri temperaturi u opsegu od 150 do 170 ° C, u savremenim postrojenjima za spaljivanje ispod 150 ° C, tokom prolaska kroz komoru 3 za sušenje i hlađenje, koja se po izboru sastoji od nekoliko jedinica komora, a koja je napunjena vlažnim, silikatnim, poroznim materijalom i pomešan sa aluminijum hidroksidom i / ili hidratom aluminijum oksida 4 i/ili drugim sredstvom za oksidaciju metala, ohlađen na temperaturu od 30 do 50 ° C, pri čemu se dobija bazna, vodena sredina i prisutan dobijeni ugljen dioksid CO2je stabilizovan. Vlažan, silikatni, porozni materijal 4 je, na primer, plovućac, vulkanska čađ i/ili perlit u granulisanom obliku i stabilizovan je sa CO2. Vlažan, silikatni, porozni materijal 4 je, na primer, plovućac, vulkanska čađ i/ili perlit u granulisanom obliku sa sadržajem vlage od 15 do 30%, bazirano na ukupnoj suvoj masi silikatnog materijala 4. Vlažan, silikatni, porozni materijal 4 je osušen ili njegova vlaga je apsorbovana strujom 1 izduvnih gasova, pri čemu se hladi. Podešeno je pH vodenog rastvora medijuma dobijenog u komori 3 za sušenje i hlađenje 3 na pH vrednost između 10 i 13 dodatkom aluminijum hidroksida i / ili hidrata aluminijum oksida. Vodeni medijum dobijen u komori 3 za sušenje i hlađenje , u kojoj se nalazi ugljen-dioksid CO2u nestabilizovanom ili jonizovanom obliku, dovodi se u narednu predkomoru 5 u koju je dodat materijal 6 koji sadrži oksidujući zemnoalkalni i/ ili teški metal, u kom slučaju oksidacija materijala 6 koji sadrži zemnoalkalni / ili teški metal i, uz istovremenu neutralizaciju vodenog medijuma koji sadrži jonizovani ugljenik C. Oksidujući zemnoalkalni metal, poželjno kalcijum, i / ili materijal koji nosi teške metale 6 je u finom sitnozrnatom obliku kao metal, npr. koriste se prašina, leteći pepeo, hidratisani kreč (kalcijum hidroksid) itd. Oksid 10 zemnoalkalnog i/ili teškog metala koji se formira tokom neutralizacije naknadno se odbacuje kao nusproizvod iz pretkomore 5, pri čemu se oksidujući materijal 6 koji sadržizemnoalkalne i/ili teške metale dovodi u funkciju kontinualnog meranja 2. Posle pretkomore 5, medijum obično ima pH vrednost 6. Vodeni medijum koji sadrži jonizovani ugljenik C se zatim dovodi u glavnu komoru 7 opremljenu materijalom 8 koji se sastoji od organskih jedinjenja ugljenika i / ili sadrži jedinjenja organskog ugljenika, a materijal 8 može da bude lignin, derivati lignina, reciklirani papir i/ili plastični materijali, pulpa ili otpadne supstance itd. Uz učešće jonizovanog ugljenika C, odvijaju se polireakcije (produženje lanca) organskim jedinjenjima ugljenika da bi dobio krajnji proizvod 9 obogaćen ugljenikom. Polireakcije koje se odvijaju u glavnoj komori 7 odvijaju se na temperaturama između 5 i 80 ° C, poželjno 30-60 ° C, a posebno poželjno na 40 do 45 ° C i pod pritiskom između 0,1 i 10 bara, poželjno između 0,1 i 0,7 bara ili 5 do 8 bara. [0008] In this case, the stream 1 of exhaust gases, for example raw gas from an incineration plant, most often with a pH of about 4 and at a temperature in the range of 150 to 170 ° C, in modern incineration plants below 150 ° C, during passage through a chamber 3 for drying and cooling, which consists of several chamber units, which is filled with moist, silicate, porous material and mixed with with aluminum hydroxide and/or aluminum oxide hydrate 4 and/or another metal oxidizing agent, cooled to a temperature of 30 to 50 °C, whereby a basic, aqueous environment is obtained and the resulting carbon dioxide CO2 is stabilized. The moist, silicate, porous material 4 is, for example, pumice, volcanic black and/or perlite in granular form and is stabilized with CO2. The moist, silicate, porous material 4 is, for example, pumice, volcanic soot and/or perlite in granular form with a moisture content of 15 to 30%, based on the total dry weight of the silicate material 4. The moist, silicate, porous material 4 is dried or its moisture is absorbed by the exhaust gas stream 1, whereby it is cooled. The pH of the aqueous solution of the medium obtained in chamber 3 for drying and cooling 3 was adjusted to a pH value between 10 and 13 by adding aluminum hydroxide and/or aluminum oxide hydrate. The aqueous medium obtained in the drying and cooling chamber 3, which contains carbon dioxide CO2 in an unstabilized or ionized form, is brought to the next pre-chamber 5, where material 6 containing oxidizing alkaline earth and/or heavy metal is added, in which case the oxidation of material 6 containing alkaline earth/or heavy metal and, with the simultaneous neutralization of the aqueous medium containing ionized carbon C. Oxidizing alkaline earth metal, preferably calcium, and/or material bearing heavy metals 6 is in fine fine-grained form as metal, e.g. dust, fly ash, hydrated lime (calcium hydroxide), etc. are used. The alkaline earth and/or heavy metal oxide 10 formed during neutralization is subsequently discarded as a by-product from the antechamber 5, whereby the oxidizing material 6 containing the alkaline earth and/or heavy metals is fed into the continuous measurement function 2. After the antechamber 5, the medium usually has a pH value of 6. The aqueous medium containing ionized carbon C is then fed into the main chamber 7 equipped with material 8 consisting of organic carbon compounds and/or contains organic carbon compounds, and the material 8 can be lignin, lignin derivatives, recycled paper and/or plastic materials, pulp or waste substances, etc. With the participation of ionized carbon C, polyreactions (chain extension) with organic carbon compounds take place to obtain the end product 9 enriched with carbon. The polyreactions that take place in the main chamber 7 take place at temperatures between 5 and 80 ° C, preferably 30-60 ° C, and especially preferably at 40 to 45 ° C and under a pressure between 0.1 and 10 bar, preferably between 0.1 and 0.7 bar or 5 to 8 bar.
[0009] Kontrola temperature postavljena u komori 3 za sušenje i hlađenje služi za odvajanje supstanci u odgovarajućem stanju specifičnom za susptancu (čvrsto, tečno, gasovito) da bi se dobila nova jedinjenja. [0009] The temperature control set in the chamber 3 for drying and cooling serves to separate the substances in the appropriate state specific to the substance (solid, liquid, gaseous) in order to obtain new compounds.
[0010] Generalno treba napomenuti da se pritisak vezivanja ugljenika C na vlažni, silikatni, porozni materijal 4 odvija brže ili se odvija znatno veće vezivanje. Pored toga, dodatne smeše supstanci mogu se dovoditi u glavnu komoru 7 kao akceleratori reakcije kako bi se konfigurisama reaktivnost supstanci i temperature u glavnoj komori 7 na takav način da se ugljen dioksid CO2koji se nalazi u struji 1 izduvnih gasova optimalno procesuira ili da se formira krajnji proizvod 9 obogaćen C-om. [0010] In general, it should be noted that the binding pressure of carbon C on the wet, silicate, porous material 4 occurs faster or significantly greater binding occurs. In addition, additional mixtures of substances can be fed into the main chamber 7 as reaction accelerators in order to configure the reactivity of the substances and the temperature in the main chamber 7 in such a way that the carbon dioxide CO2 contained in the stream 1 of the exhaust gases is optimally processed or the final product 9 enriched with C is formed.
[0011] Postupak pronalaska je objašnjen detaljnije koristeći poželjan primer realizacije. [0011] The method of the invention is explained in more detail using a preferred embodiment example.
[0012] Drvni otpaci se koriste se kao izvor sirovina za struju izduvnih gasova. Sirov gas koji nastaje sagorevanjem iseckanih drvnih otpadaka, koji ima prosečan sadržaj O2između 11,5 i 14 zapr. % i CO2između 7 i 9 zapr. %, na temperaturi od oko 150°C je dodat u komoru za sušenje i hlađenje, u kojoj se tok izduvnih gasova hladi na temperaturu ≤ 40 ° C, poželjno oko 30 ° C, i u koji je dodat plovućac kao porozni silikatni materijalsa sadržajem vlage do 60%, na bazi suve materije, sa dodatkom aluminijum hidroksida i / ili alumiju oksid hidrata, koji su jedinjenja aluminijuma dobijena u proizvodnji potaše. Struja izduvnih gasova skuplja vlagu iz plovućca, hladeći tok izduvnih gasova. Istovremeno, stvara se vodena sredina stvaranjem stabilne suspenzije aluminijumskih jedinjenja u vodi u komori za sušenje i hlađenje. U vodenoj sredini koja ima pH vrednost oko neutralne do bazne, pH 10 do 13, ugljen dioksid (CO2<) koji se u>njemu nalazi je jonizovan i nestabilan, a vodena sredina ostaje dok ne izađe iz komore za sušenje i hladi se komora za hlađenje na temperaturu između 12-13 ° C. [0012] Wood waste is used as a source of raw materials for the flow of exhaust gases. Raw gas produced by the combustion of chopped wood waste, which has an average O2 content between 11.5 and 14 ppm. % and CO2 between 7 and 9 %, at a temperature of about 150°C was added to the drying and cooling chamber, in which the flow of exhaust gases is cooled to a temperature ≤ 40°C, preferably about 30°C, and in which pumice was added as a porous silicate material with a moisture content of up to 60%, based on dry matter, with the addition of aluminum hydroxide and/or aluminum oxide hydrate, which are aluminum compounds obtained in the production of potash. The exhaust stream collects moisture from the pumice, cooling the exhaust stream. At the same time, an aqueous environment is created by creating a stable suspension of aluminum compounds in water in the drying and cooling chamber. In an aqueous environment that has a pH value around neutral to basic, pH 10 to 13, the carbon dioxide (CO2<) contained in it is ionized and unstable, and the aqueous environment remains until it leaves the drying chamber and cools the cooling chamber to a temperature between 12-13 ° C.
[0013] Vodena sredina je zatim poslata iz komore za sušenje i hlađenje u pretkomporu koja se nalazi nishodno, u koju su dodati opiljci gvožđa kao oksidujućim materijalom, gde odnos oksidujućeg materijala i tečnosti u vodenom medijumu iznosi oko 1: 7 tež. %. Opiljci gvožđa su oksidovani kiseonikom iz jonizovanog i nestabilizovanog ugljen dioksida tokom istovremen neutralizacije medijuma u pretkomori. Na izlazu iz pretkomore, vodeni medijum ima prosečan sadržaj O2od oko 16-17 zapr. % i CO2od oko 3,5-4 zapr. % pri pH od oko 6. [0013] The aqueous environment was then sent from the drying and cooling chamber to the antechamber located below, in which iron filings were added as oxidizing material, where the ratio of oxidizing material and liquid in the aqueous medium is about 1: 7 by weight. %. Iron filings are oxidized by oxygen from ionized and unstabilized carbon dioxide during the simultaneous neutralization of the medium in the antechamber. At the exit from the vestibule, the aqueous medium has an average O2 content of about 16-17 ppm. % and CO2 of about 3.5-4 per cent. % at a pH of about 6.
[0014] Za dalje tretiranje, vodeni medijum koji sadrži ugljenik se prenosi u glavnu komoru koja je opremljena materijalima koji sadrže jedinjenja organskog ugljenika. [0014] For further treatment, the aqueous medium containing carbon is transferred to the main chamber, which is equipped with materials containing organic carbon compounds.
Ovde se preferirano koriste materijali za recikliranje papira koji sadrže lignin, koji se mogu zameniti bilo kojim otpadnim materijalom koji sadrži bilo koji plastični materijal, pulpu i / ili alifatična i / ili aromatična jedinjenja uglenika. Uz učešće vodenog medijuma koji sadrži jonizovani ugljenik, u glavnoj komori se odvijaju polireakcije, zajedno sa polimerizacijom i pokondenzacijom, sa organskim jedinjenjima ugljenika iz papira za reciklizaciju, da bi se dobio krajnji proizvod obogaćen ugljenikom koji sadrži frakciju silikata od oko 20-25 zapr. % kao noseću strukturu. Polireakcija u glavnoj komori po mogućnosti se odvija na temperaturi između 40 i 45 ° C, pod pritiskom od 7-8 bara. Konačno, pod ovim pritiskom i temperaturnim uslovima, silikatna komponenta se takođe može odvojiti od krajnjeg proizvoda obogaćenog ugljenikom, koji predstavlja osnovnu sirovina koja se može koristiti na različite načine. Ovakav tretman struje izduvnih gasova na kraju dovodi do čistog gasa na izlazu iz glavne komore, koji ima prosečni sadržaj O2od 22 zapr. % i CO2od 0,2 zapr. %. Paper recycling materials containing lignin are preferably used here, which can be replaced by any waste material containing any plastic material, pulp and/or aliphatic and/or aromatic carbon compounds. With the participation of an aqueous medium containing ionized carbon, polyreactions take place in the main chamber, along with polymerization and post-condensation, with organic carbon compounds from the recycling paper, to obtain a carbon-enriched final product containing a silicate fraction of about 20-25 ppm. % as a supporting structure. The polyreaction in the main chamber preferably takes place at a temperature between 40 and 45 ° C, under a pressure of 7-8 bar. Finally, under these pressure and temperature conditions, the silicate component can also be separated from the carbon-enriched final product, which represents a basic raw material that can be used in a variety of ways. This treatment of the exhaust gas stream ultimately leads to clean gas at the exit of the main chamber, which has an average O2 content of 22 ppm. % and CO2 of 0.2 per cent. %.
[0015] Neprekidnim merenjem pojedinih procesnih parametara, kao što su pritisak, temperatura, količine materijala i sastavi u pojedinim delovima procesa, zagarantovana je optimizacija protoka procesa i rezultata. [0015] Continuous measurement of certain process parameters, such as pressure, temperature, material quantities and compositions in certain parts of the process, guarantees the optimization of process flow and results.
Claims (6)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ATA204/2012A AT511713B1 (en) | 2012-02-20 | 2012-02-20 | PROCESS FOR PREPARING CARBON DIOXIDE CONTAINED IN A GAS STREAM |
| PCT/AT2013/050037 WO2013123539A2 (en) | 2012-02-20 | 2013-02-13 | Method for processing carbon dioxide contained in an exhaust gas flow |
| EP13709295.3A EP2817081B1 (en) | 2012-02-20 | 2013-02-13 | Method for processing carbon dioxide contained in an exhaust gas flow |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RS59772B1 true RS59772B1 (en) | 2020-02-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| RS20200030A RS59772B1 (en) | 2012-02-20 | 2013-02-13 | Method for processing carbon dioxide contained in an exhaust gas flow |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US9382388B2 (en) |
| EP (1) | EP2817081B1 (en) |
| CN (1) | CN104114260B (en) |
| AT (1) | AT511713B1 (en) |
| BR (1) | BR112014020029A8 (en) |
| CY (1) | CY1122487T1 (en) |
| DE (1) | DE112013001040A5 (en) |
| DK (1) | DK2817081T3 (en) |
| ES (1) | ES2765178T3 (en) |
| HR (1) | HRP20192196T1 (en) |
| HU (1) | HUE046846T2 (en) |
| LT (1) | LT2817081T (en) |
| MX (1) | MX352830B (en) |
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| SI (1) | SI2817081T1 (en) |
| SM (1) | SMT201900689T1 (en) |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5981007B1 (en) * | 2015-09-24 | 2016-08-31 | 株式会社マグマスパジャパン | Atmosphere adjustment system and atmosphere adjustment method for exercise studio |
| CN115463494A (en) * | 2022-09-15 | 2022-12-13 | 无锡松煜科技有限公司 | A structure and method for preventing the clogging of the exhaust pipe at the tail of the process furnace |
| CZ310556B6 (en) * | 2023-04-12 | 2025-11-26 | Průmyslově právní strategie, spol. s r.o. | Method of neutralizing carbon dioxide |
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| US5776353A (en) * | 1996-02-16 | 1998-07-07 | Advanced Minerals Corporation | Advanced composite filtration media |
| DD116557A1 (en) * | 1974-04-23 | 1975-12-05 | ||
| SU677150A1 (en) * | 1977-08-02 | 1982-08-15 | Сектор Нефтехимии Института Физико-Органической Химии И Углехимии Ан Усср | Auxiliary filtering material |
| SU822847A1 (en) * | 1979-04-26 | 1981-04-23 | Восточно-Сибирский Технологическийинститут | Filtering material |
| JP2895325B2 (en) * | 1992-09-16 | 1999-05-24 | 関西電力株式会社 | Method for removing carbon dioxide in flue gas |
| DE4308250A1 (en) * | 1993-03-16 | 1994-09-22 | Solvay Umweltchemie Gmbh | Sorption of CO2 by CaCl2 from the Solvay soda process |
| DK1114219T3 (en) * | 1998-02-20 | 2004-02-16 | Air Liquide | Process for the synthesis of calcium carbonate and the product obtained |
| GB9926898D0 (en) * | 1999-11-12 | 2000-01-12 | School Of Earth & Environmenta | Calcium silicate sorbents |
| DE60120819T2 (en) * | 2000-04-04 | 2007-06-28 | Tosoh Corp., Shin-Nanyo | Process for the adsorptive separation of carbon dioxide |
| US6387337B1 (en) * | 2000-07-14 | 2002-05-14 | The United States Of America As Represented By The United States Department Of Energy | Carbon dioxide capture process with regenerable sorbents |
| GB0226590D0 (en) * | 2002-11-14 | 2002-12-24 | Univ Cambridge Tech | Method for producing carbon nanotubes and/or nanofibres |
| JP2004261658A (en) * | 2003-02-26 | 2004-09-24 | Tokyo Electric Power Co Inc:The | Method for immobilizing carbon dioxide in flue gas |
| US7132090B2 (en) * | 2003-05-02 | 2006-11-07 | General Motors Corporation | Sequestration of carbon dioxide |
| EP2438978B1 (en) * | 2006-03-10 | 2013-11-13 | C-Quest Technologies International LLC | Method for recycling industrial by-products |
| US7556673B2 (en) * | 2006-11-24 | 2009-07-07 | Basf Aktiengesellschaft | Method for the separation of carbon dioxide using a porous metal-organic framework material |
| DE102007006137A1 (en) * | 2007-02-07 | 2008-08-21 | First Vandalia Luxembourg Holding S.A. | Mixed product |
| US8398743B2 (en) * | 2007-05-08 | 2013-03-19 | General Electric Company | Methods and systems for reducing carbon dioxide in combustion flue gases |
| RU2010123008A (en) * | 2007-11-05 | 2011-12-20 | ГЛОБАЛ РИСЕРЧ ТЕКНОЛОДЖИЗ, ЭлЭлСи (US) | REMOVING CARBON GAS FROM AIR |
| WO2010068924A1 (en) * | 2008-12-11 | 2010-06-17 | Calera Corporation | Processing co2 utilizing a recirculating solution |
| EP2247366A4 (en) * | 2009-03-10 | 2011-04-20 | Calera Corp | Systems and methods for processing co2 |
| JP5630629B2 (en) * | 2009-09-29 | 2014-11-26 | アイシン精機株式会社 | Carbon dioxide treatment apparatus and carbon dioxide treatment method |
| EP2332632B1 (en) * | 2009-11-30 | 2014-06-04 | Lafarge | Process for removal of carbon dioxide from a gas stream |
| US8377408B2 (en) * | 2010-04-20 | 2013-02-19 | High Temperature Physics, Llc | Process for the production of carbon nanoparticles and sequestration of carbon |
| US20110277670A1 (en) * | 2010-05-14 | 2011-11-17 | Kyle Self | Systems and methods for processing co2 |
| US20120211421A1 (en) * | 2010-05-14 | 2012-08-23 | Kyle Self | Systems and methods for processing co2 |
| US8828338B2 (en) * | 2011-07-25 | 2014-09-09 | Silica de Panama S.A. | Conversion of gaseous carbon dioxide into aqueous alkaline and/or alkaline earth bicarbonate solutions |
| AT512330B1 (en) * | 2011-12-21 | 2013-09-15 | Commerzialbank Mattersburg Burgenland Ag | METHOD FOR GENERATING ENERGY FROM ORGANIC WASTE |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2013123539A2 (en) | 2013-08-29 |
| AT511713A4 (en) | 2013-02-15 |
| SMT201900689T1 (en) | 2020-01-14 |
| AT511713B1 (en) | 2013-02-15 |
| ES2765178T3 (en) | 2020-06-08 |
| EP2817081A2 (en) | 2014-12-31 |
| RU2014137920A (en) | 2016-04-10 |
| PL2817081T3 (en) | 2020-04-30 |
| DK2817081T3 (en) | 2020-02-03 |
| CY1122487T1 (en) | 2021-01-27 |
| WO2013123539A9 (en) | 2014-02-27 |
| HUE046846T2 (en) | 2020-03-30 |
| RU2595685C2 (en) | 2016-08-27 |
| BR112014020029A8 (en) | 2017-07-11 |
| BR112014020029A2 (en) | 2017-06-20 |
| DE112013001040A5 (en) | 2015-01-08 |
| HK1202477A1 (en) | 2015-10-02 |
| HRP20192196T1 (en) | 2020-03-06 |
| CN104114260B (en) | 2015-11-25 |
| US9382388B2 (en) | 2016-07-05 |
| SI2817081T1 (en) | 2020-02-28 |
| MX2014010034A (en) | 2014-12-05 |
| PT2817081T (en) | 2020-01-21 |
| MX352830B (en) | 2017-12-11 |
| US20150018536A1 (en) | 2015-01-15 |
| CN104114260A (en) | 2014-10-22 |
| LT2817081T (en) | 2019-12-10 |
| EP2817081B1 (en) | 2019-10-16 |
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