RO78641B - Procedeu de cracare catalitica - Google Patents
Procedeu de cracare cataliticaInfo
- Publication number
- RO78641B RO78641B RO98322A RO9832279A RO78641B RO 78641 B RO78641 B RO 78641B RO 98322 A RO98322 A RO 98322A RO 9832279 A RO9832279 A RO 9832279A RO 78641 B RO78641 B RO 78641B
- Authority
- RO
- Romania
- Prior art keywords
- catalyst
- weight
- antimony
- carbon atoms
- cracking
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 206010011469 Crying Diseases 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000004523 catalytic cracking Methods 0.000 abstract 2
- 238000005336 cracking Methods 0.000 abstract 2
- 239000012530 fluid Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 206010027439 Metal poisoning Diseases 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 231100000572 poisoning Toxicity 0.000 abstract 1
- 230000000607 poisoning effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
Procedeu de cracare catalitica, folosit pentru cracarea catalitica a hidrocarburilor cu greutate moleculara mare, prin contactarea acestora, la temperaturi ridicate cu un catalizator de cracare, în prezenta unui agent de pasivizare a metalelor cu efect de otravuri pentru catalizator, constînd dintr-un compus de antimoniu cu formula generala: (vezi formula) în care R pot fi identici sau diferiti si reprezinta grupari alchil cu 2...10 atomi de carbon, ca atare substituite cu radicali cicloalchil cu 5...6 atomi de carbon, sau cu radical fenil, caracterizat prin aceea ca agentul de pasivizare se introduce în curentul fluid de hidrocarburi, de preferinta, amestecat cu aceasta într-o cantitate cuprinsa între 0,002 si 5% în greutate si de preferinta între 0,01 si 1,5% în greutate antimoniu, raportat la cantitatea de catalizator, agentul de pasivizare fiind tratat la o temperatura sub temperatura sa de descompunere si anume, sub 260 degree C, înainte de introducerea curentului fluid de hidrocarburi în zona de cracare.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/929,479 US4167471A (en) | 1978-07-31 | 1978-07-31 | Passivating metals on cracking catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO78641B true RO78641B (ro) | 1983-06-30 |
| RO78641A RO78641A (ro) | 1983-07-07 |
Family
ID=25457921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO7998322A RO78641A (ro) | 1978-07-31 | 1979-07-31 | Procedeu de cracare catalitica |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4167471A (ro) |
| EP (1) | EP0007426B1 (ro) |
| JP (1) | JPS5521477A (ro) |
| AT (1) | ATE1951T1 (ro) |
| AU (1) | AU516169B2 (ro) |
| BR (1) | BR7904163A (ro) |
| CA (1) | CA1125689A (ro) |
| DE (1) | DE2964202D1 (ro) |
| DK (1) | DK321179A (ro) |
| EG (1) | EG13905A (ro) |
| ES (1) | ES482882A1 (ro) |
| FI (1) | FI792341A7 (ro) |
| IN (1) | IN150665B (ro) |
| MA (1) | MA18489A1 (ro) |
| NO (1) | NO791986L (ro) |
| PH (1) | PH15607A (ro) |
| PL (1) | PL117531B1 (ro) |
| PT (1) | PT69868A (ro) |
| RO (1) | RO78641A (ro) |
| TR (1) | TR20404A (ro) |
| ZA (1) | ZA792626B (ro) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4324648A (en) * | 1980-03-24 | 1982-04-13 | Phillips Petroleum Company | Cracking catalyst poisons passivated with tin compounds plus both sulfur and phosphorus |
| US5358630A (en) * | 1980-11-17 | 1994-10-25 | Phillips Petroleum Company | Regenerating zeolitic cracking catalyst |
| US4394323A (en) * | 1981-04-01 | 1983-07-19 | Phillips Petroleum Company | Production of antimony organophosphorodithioates |
| US4394324A (en) * | 1981-05-18 | 1983-07-19 | Phillips Petroleum Company | Stable antimony organophosphorodithioates |
| US4430199A (en) | 1981-05-20 | 1984-02-07 | Engelhard Corporation | Passivation of contaminant metals on cracking catalysts by phosphorus addition |
| US4397767A (en) * | 1982-02-12 | 1983-08-09 | Phillips Petroleum Company | Catalyst poisons passivated with tin compounds plus both sulfur and phosphorus |
| US4427539A (en) | 1982-09-07 | 1984-01-24 | Ashland Oil, Inc. | Demetallizing and decarbonizing heavy residual oil feeds |
| US4488984A (en) * | 1983-07-05 | 1984-12-18 | Nalco Chemical Company | Self-dispersing antimony oxide sols |
| US4645589A (en) * | 1985-10-18 | 1987-02-24 | Mobil Oil Corporation | Process for removing metals from crude |
| US5064524A (en) * | 1988-06-17 | 1991-11-12 | Betz Laboratories, Inc. | Passivation of FCC catalysts |
| US4913801A (en) * | 1988-06-17 | 1990-04-03 | Betz Laboratories, Inc. | Passivation of FCC catalysts |
| US6537950B2 (en) * | 2001-07-13 | 2003-03-25 | Exxonmobil Research And Engineering Co. | Method for inhibiting corrosion using triphenylstibine |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3135683A (en) * | 1961-08-28 | 1964-06-02 | Phillips Petroleum Co | Double unit catalytic cracking |
| US3647677A (en) * | 1969-06-11 | 1972-03-07 | Standard Oil Co | Retardation of coke formation |
| US3711422A (en) * | 1970-09-08 | 1973-01-16 | Phillips Petroleum Co | Cracking catalyst restoration with antimony compounds |
| US3776835A (en) * | 1972-02-23 | 1973-12-04 | Union Oil Co | Fouling rate reduction in hydrocarbon streams |
| US3812029A (en) * | 1972-10-13 | 1974-05-21 | Mobil Oil Corp | Device for injecting easily coked fluids into a high temperature vessel |
| US4024049A (en) * | 1975-01-07 | 1977-05-17 | Nalco Chemical Company | Mono and di organophosphite esters as crude oil antifoulants |
| US4025458A (en) * | 1975-02-18 | 1977-05-24 | Phillips Petroleum Company | Passivating metals on cracking catalysts |
| US4031002A (en) * | 1975-02-18 | 1977-06-21 | Phillips Petroleum Company | Passivating metals on cracking catalysts with antimony compounds |
| JPS5832192B2 (ja) * | 1975-03-11 | 1983-07-11 | 三菱油化株式会社 | コ−キングノボウシホウホウ |
| US3977963A (en) * | 1975-04-17 | 1976-08-31 | Gulf Research & Development Company | Method of negating the effects of metals poisoning on cracking catalysts |
| JPS5326801A (en) * | 1976-08-23 | 1978-03-13 | Phillips Petroleum Co | Passivity method of metal on cracking catalyst |
-
1978
- 1978-07-31 US US05/929,479 patent/US4167471A/en not_active Expired - Lifetime
-
1979
- 1979-05-14 CA CA327,569A patent/CA1125689A/en not_active Expired
- 1979-05-28 ZA ZA792626A patent/ZA792626B/xx unknown
- 1979-05-29 IN IN553/CAL/79A patent/IN150665B/en unknown
- 1979-06-01 AU AU47688/79A patent/AU516169B2/en not_active Ceased
- 1979-06-04 PH PH22602A patent/PH15607A/en unknown
- 1979-06-14 NO NO791986A patent/NO791986L/no unknown
- 1979-06-15 DE DE7979101979T patent/DE2964202D1/de not_active Expired
- 1979-06-15 AT AT79101979T patent/ATE1951T1/de not_active IP Right Cessation
- 1979-06-15 EP EP79101979A patent/EP0007426B1/en not_active Expired
- 1979-06-22 MA MA18684A patent/MA18489A1/fr unknown
- 1979-07-02 JP JP8386479A patent/JPS5521477A/ja active Pending
- 1979-07-02 BR BR7904163A patent/BR7904163A/pt unknown
- 1979-07-02 EG EG397/79A patent/EG13905A/xx active
- 1979-07-03 PT PT69868A patent/PT69868A/pt unknown
- 1979-07-26 FI FI792341A patent/FI792341A7/fi not_active Application Discontinuation
- 1979-07-26 TR TR20404A patent/TR20404A/xx unknown
- 1979-07-27 ES ES482882A patent/ES482882A1/es not_active Expired
- 1979-07-28 PL PL1979217431A patent/PL117531B1/pl unknown
- 1979-07-30 DK DK321179A patent/DK321179A/da unknown
- 1979-07-31 RO RO7998322A patent/RO78641A/ro unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0007426B1 (en) | 1982-12-08 |
| IN150665B (ro) | 1982-11-20 |
| PT69868A (de) | 1979-08-01 |
| DE2964202D1 (en) | 1983-01-13 |
| AU516169B2 (en) | 1981-05-21 |
| NO791986L (no) | 1980-02-01 |
| JPS5521477A (en) | 1980-02-15 |
| PH15607A (en) | 1983-02-28 |
| EP0007426A1 (en) | 1980-02-06 |
| ES482882A1 (es) | 1980-09-01 |
| DK321179A (da) | 1980-02-01 |
| EG13905A (en) | 1983-03-31 |
| US4167471A (en) | 1979-09-11 |
| PL117531B1 (en) | 1981-08-31 |
| ATE1951T1 (de) | 1982-12-15 |
| BR7904163A (pt) | 1980-03-25 |
| CA1125689A (en) | 1982-06-15 |
| MA18489A1 (fr) | 1979-12-31 |
| TR20404A (tr) | 1981-06-10 |
| AU4768879A (en) | 1980-04-17 |
| ZA792626B (en) | 1980-06-25 |
| RO78641A (ro) | 1983-07-07 |
| PL217431A1 (ro) | 1980-06-02 |
| FI792341A7 (fi) | 1981-01-01 |
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