PT903354E - Polimero vinilaromatico de choque obtido a partir de uma borracha portadora de um agrupamento gerador de um radical livre estavel - Google Patents
Polimero vinilaromatico de choque obtido a partir de uma borracha portadora de um agrupamento gerador de um radical livre estavelInfo
- Publication number
- PT903354E PT903354E PT98116845T PT98116845T PT903354E PT 903354 E PT903354 E PT 903354E PT 98116845 T PT98116845 T PT 98116845T PT 98116845 T PT98116845 T PT 98116845T PT 903354 E PT903354 E PT 903354E
- Authority
- PT
- Portugal
- Prior art keywords
- rubber
- free
- free radical
- vinylaromatic polymer
- rubber carrier
- Prior art date
Links
- 229920001971 elastomer Polymers 0.000 title abstract 8
- 150000003254 radicals Chemical class 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 2
- 230000035939 shock Effects 0.000 title 1
- 239000003999 initiator Substances 0.000 abstract 3
- 239000000806 elastomer Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 239000011159 matrix material Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F253/00—Macromolecular compounds obtained by polymerising monomers on to natural rubbers or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/904—Activation of preformed polymer in absence or monomer, for subsequent polymerization thereon, e.g. trapped radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9711693A FR2768738A1 (fr) | 1997-09-19 | 1997-09-19 | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
| FR9806795A FR2768739B1 (fr) | 1997-09-19 | 1998-05-29 | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PT903354E true PT903354E (pt) | 2005-04-29 |
Family
ID=26233810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PT98116845T PT903354E (pt) | 1997-09-19 | 1998-09-07 | Polimero vinilaromatico de choque obtido a partir de uma borracha portadora de um agrupamento gerador de um radical livre estavel |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6255402B1 (pt) |
| EP (1) | EP0903354B1 (pt) |
| JP (1) | JP4863536B2 (pt) |
| KR (1) | KR100571319B1 (pt) |
| CN (1) | CN1195781C (pt) |
| AT (1) | ATE282639T1 (pt) |
| CA (1) | CA2245109C (pt) |
| DE (1) | DE69827570T2 (pt) |
| ES (1) | ES2232904T3 (pt) |
| FR (1) | FR2768739B1 (pt) |
| NO (1) | NO323322B1 (pt) |
| PT (1) | PT903354E (pt) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2779437B1 (fr) * | 1998-06-03 | 2004-10-15 | Atochem Elf Sa | Polymere vinylaromatique choc par polymerisation d'un monomere vinylaromatique en presence d'un radical libre stable et d'un amorceur de polymerisation |
| WO2000014134A1 (en) * | 1998-09-03 | 2000-03-16 | Ciba Specialty Chemicals Holding Inc. | Grafting of ethylenically unsaturated monomers onto polymers |
| BR9913416A (pt) * | 1998-09-03 | 2001-05-22 | Ciba Sc Holding Ag | Enxerto de monÈmeros etilenicamente insaturados em polìmeros |
| FR2791060A1 (fr) * | 1999-03-18 | 2000-09-22 | Atochem Elf Sa | Procede de preparation d'un caoutchouc porteur de radical libre stable et utilisation dudit caoutchouc porteur pour la preparation d'un polymere vinylaromatique choc |
| FR2792321B1 (fr) * | 1999-04-19 | 2003-12-12 | Atochem Elf Sa | Procede de fabrication d'une resine de polypropylene a rheologie controlee |
| FR2805268B1 (fr) * | 2000-02-23 | 2005-03-25 | Atofina | Polymeres thermoreversibles a fonctions mitroxyde |
| FR2819517B1 (fr) * | 2000-10-03 | 2003-03-21 | Atofina | Composition comprenant un nitroxyde, un promoteur et eventuellement un initiateur de radicaux libres |
| US6767940B2 (en) * | 2002-07-25 | 2004-07-27 | Acushnet Company | Golf ball compositions comprising stable free radicals |
| JP2004182926A (ja) * | 2002-12-05 | 2004-07-02 | Yokohama Rubber Co Ltd:The | ポリマーの変性方法 |
| CN101006112B (zh) * | 2003-02-05 | 2010-05-26 | 陶氏环球技术公司 | 由本体聚合方法生产的高光泽橡胶改性单亚乙烯基芳族聚合物 |
| US20060058465A1 (en) * | 2003-02-05 | 2006-03-16 | Gilbert Bouquet | Particle size and morphology control in rubber modified monovinylidene aromatic polymers |
| ATE455809T1 (de) | 2003-02-05 | 2010-02-15 | Dow Global Technologies Inc | Kautschukmodifizierte polymere von vinylaromatischen monomeren |
| US7226964B2 (en) | 2003-04-03 | 2007-06-05 | Arkema France | Composition comprising a nitroxide, a promoter and optionally a free-radical initiator |
| US20040220345A1 (en) * | 2003-05-01 | 2004-11-04 | Firestone Polymers, Llc | Stable free radical polymers |
| US6967228B2 (en) * | 2003-05-01 | 2005-11-22 | Firestone Polymers, Llc | Stable free radical polymers |
| CA2547063C (en) * | 2003-11-26 | 2013-12-31 | Arkema Inc. | Controlled radical acrylic copolymer thickeners |
| US20070149712A1 (en) * | 2003-12-24 | 2007-06-28 | Dow Global Technologies, Inc. | Free-radical initiation in the presence of a stable organic free radical and related compositions |
| WO2005066282A2 (en) * | 2003-12-24 | 2005-07-21 | Dow Global Technologies Inc. | Rheology modification of polymers |
| ITMI20040752A1 (it) | 2004-04-16 | 2004-07-16 | Polimeri Europa Spa | Procedimento per la preparazione di co polimeri vinilaromatici aggraffati su elastometro in modo controllato |
| FR2875502B1 (fr) * | 2004-09-22 | 2007-01-05 | Arkema Sa | Composition retardant le grillage |
| ITMI20042401A1 (it) * | 2004-12-16 | 2005-03-16 | Polimeri Europa Spa | Procedimento per la preparazione di co-polimeri vinilaromatici antiurto aggraffati su elastomero |
| US7906468B2 (en) | 2005-02-23 | 2011-03-15 | Arkema Inc. | Acrylic block copolymer low temperature flow modifiers in lubricating oils |
| US7279527B2 (en) * | 2005-04-22 | 2007-10-09 | Bridgestone Corporation | Method of converting anionic living end to protected free radical living end and applications thereof |
| US7834081B2 (en) * | 2005-08-02 | 2010-11-16 | Arkema Inc. | Methods of producing vinyl aromatic polymers using (meth)acrylic macroinitiators |
| US7560509B2 (en) * | 2006-12-29 | 2009-07-14 | Bridgestone Corporation | Method of directing grafting by controlling the location of high vinyl segments in a polymer |
| US8030410B2 (en) * | 2006-12-29 | 2011-10-04 | Bridgestone Corporation | Method for generating free radical capable polymers using carbonyl-containing compounds |
| US7737218B2 (en) | 2006-12-29 | 2010-06-15 | Bridgestone Corporation | Method for generating free radical capable polymers using tin or silicon halide compounds |
| US7396887B1 (en) * | 2006-12-29 | 2008-07-08 | Bridgestone Corporation | Insitu removal of chelator from anionic polymerization reactions |
| CN101663329A (zh) * | 2007-04-25 | 2010-03-03 | 陶氏环球技术公司 | 通过介导的自由基链生长聚合制备(共聚)聚合物组合物的方法 |
| EP2155842A4 (en) * | 2007-06-11 | 2011-08-03 | Arkema Inc | ACRYLIC POLYMER LOW TEMPERATURE FLOW MODIFIERS IN BIOFUELS |
| JP2009001776A (ja) | 2007-06-11 | 2009-01-08 | Rohm & Haas Co | 水性エマルジョンポリマー会合性増粘剤 |
| EP2093238A1 (en) | 2008-02-21 | 2009-08-26 | Total Petrochemicals France | Process for preparing hydroperoxidized elastomers and their use in high impact monovinylaromatic polymers |
| IT1391109B1 (it) * | 2008-08-20 | 2011-11-18 | Polimeri Europa Spa | Procedimento per la sintesi di poli(1,3-alcadieni) funzionalizzati e loro impiego nella preparazione di polimeri vinilaromatici ad alta resistenza all'urto |
| US20100109245A1 (en) * | 2008-10-30 | 2010-05-06 | Double-Back Jack, Llc | Method of playing a variation of blackjack (21) |
| FR3096369B1 (fr) * | 2019-05-24 | 2022-01-14 | Arkema France | Procédé de polymérisation d’une composition en présence de copolymère à blocs |
| TW202330677A (zh) | 2021-12-10 | 2023-08-01 | 義大利商佛沙里斯股份有限公司 | 橡膠強化的乙烯芳香族(共)聚合物及其製備方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3035570A1 (de) | 1980-09-20 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Schlagfeste thermoplastische formmasse |
| KR930000892B1 (ko) | 1983-07-11 | 1993-02-11 | 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 | 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법 |
| AU571240B2 (en) * | 1983-07-11 | 1988-04-14 | Commonwealth Scientific And Industrial Research Organisation | Alkoxy-amines, useful as initiators |
| DD294493A5 (de) * | 1990-05-21 | 1991-10-02 | Buna Ag,De | Verfahren zur herstellung von thermoelastoplastischen materialien |
| DE4018230A1 (de) | 1990-06-07 | 1991-12-12 | Basf Ag | Thermoplastische formmassen |
| US5322912A (en) | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
| US5428106A (en) | 1993-09-02 | 1995-06-27 | The Dow Chemical Company | Rubber modified polystyrene |
| DE4440675A1 (de) * | 1994-11-14 | 1996-05-15 | Basf Ag | Verfahren zur Herstellung von kautschukmodifizierten Formmassen mittels in den Kautschuk eingebauten, bei thermischer Zersetzung Radikale bildenden Gruppen |
| FR2730240A1 (fr) | 1995-02-07 | 1996-08-09 | Atochem Elf Sa | Stabilisation d'un polymere par un radical libre stable |
| FR2730241B1 (fr) * | 1995-02-07 | 1997-02-28 | Atofina | Procede de fabrication d'une composition comprenant un polymere vinylaromatique et un caoutchouc par polymerisation en presence d'un radical libre stable |
| IT1275913B1 (it) | 1995-03-16 | 1997-10-24 | Enichem Spa | Polistirene antiurto ad elevata lucentezza e processo per la sua preparazione |
| US5498679A (en) | 1995-03-30 | 1996-03-12 | Xerox Corporation | Process for producing telechelic, branched and star thermoplastic resin polymers |
| US5627248A (en) | 1995-09-26 | 1997-05-06 | The Dow Chemical Company | Difunctional living free radical polymerization initiators |
| EP0889918B1 (en) * | 1996-03-29 | 2000-03-22 | The Dow Chemical Company | In situ block copolymer formation during polymerization of a vinyl aromatic monomer |
| KR19990036179A (ko) * | 1996-06-04 | 1999-05-25 | 베아트리체 델로스탈 | 안정한 자유 라디칼의 존재하에 1,3-디엔의 제어된 자유 라디칼 중합에 의한 텔레켈릭 1,3-디엔 올리고머의 제조 방법 |
-
1998
- 1998-05-29 FR FR9806795A patent/FR2768739B1/fr not_active Expired - Fee Related
- 1998-09-07 AT AT98116845T patent/ATE282639T1/de active
- 1998-09-07 EP EP98116845A patent/EP0903354B1/fr not_active Expired - Lifetime
- 1998-09-07 DE DE69827570T patent/DE69827570T2/de not_active Expired - Lifetime
- 1998-09-07 ES ES98116845T patent/ES2232904T3/es not_active Expired - Lifetime
- 1998-09-07 PT PT98116845T patent/PT903354E/pt unknown
- 1998-09-15 NO NO19984271A patent/NO323322B1/no not_active IP Right Cessation
- 1998-09-17 CA CA002245109A patent/CA2245109C/fr not_active Expired - Fee Related
- 1998-09-17 KR KR1019980038454A patent/KR100571319B1/ko not_active Expired - Fee Related
- 1998-09-18 US US09/157,309 patent/US6255402B1/en not_active Expired - Fee Related
- 1998-09-19 CN CNB981205550A patent/CN1195781C/zh not_active Expired - Fee Related
- 1998-09-21 JP JP26680498A patent/JP4863536B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69827570T2 (de) | 2005-12-22 |
| FR2768739A1 (fr) | 1999-03-26 |
| KR19990029899A (ko) | 1999-04-26 |
| US6255402B1 (en) | 2001-07-03 |
| JPH11147912A (ja) | 1999-06-02 |
| CA2245109A1 (fr) | 1999-03-19 |
| KR100571319B1 (ko) | 2006-07-25 |
| FR2768739B1 (fr) | 2004-08-06 |
| CA2245109C (fr) | 2007-02-20 |
| EP0903354A1 (fr) | 1999-03-24 |
| DE69827570D1 (de) | 2004-12-23 |
| ATE282639T1 (de) | 2004-12-15 |
| CN1195781C (zh) | 2005-04-06 |
| CN1214351A (zh) | 1999-04-21 |
| NO323322B1 (no) | 2007-03-19 |
| NO984271D0 (no) | 1998-09-15 |
| ES2232904T3 (es) | 2005-06-01 |
| JP4863536B2 (ja) | 2012-01-25 |
| EP0903354B1 (fr) | 2004-11-17 |
| NO984271L (no) | 1999-03-22 |
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