PL416322A1 - Bis(trifluoromethylsulfonyl)imide of alkyl[2-(2-hydroexyethoxy)ethyl]dimethylammonium and method for obtaining them and application as electrolytes - Google Patents
Bis(trifluoromethylsulfonyl)imide of alkyl[2-(2-hydroexyethoxy)ethyl]dimethylammonium and method for obtaining them and application as electrolytesInfo
- Publication number
- PL416322A1 PL416322A1 PL416322A PL41632216A PL416322A1 PL 416322 A1 PL416322 A1 PL 416322A1 PL 416322 A PL416322 A PL 416322A PL 41632216 A PL41632216 A PL 41632216A PL 416322 A1 PL416322 A1 PL 416322A1
- Authority
- PL
- Poland
- Prior art keywords
- trifluoromethylsulfonyl
- ethyl
- alkyl
- bis
- imide
- Prior art date
Links
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 title abstract 4
- 125000000217 alkyl group Chemical group 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 title 2
- 239000003792 electrolyte Substances 0.000 title 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 title 1
- YSAANLSYLSUVHB-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]ethanol Chemical compound CN(C)CCOCCO YSAANLSYLSUVHB-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- -1 alkyl [2- (2-hydroxyethoxy) ethyl] dimethylammonium bromide Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 238000005349 anion exchange Methods 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000003990 capacitor Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000011255 nonaqueous electrolyte Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Secondary Cells (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Przedmiotem zgłoszenia jest bis(trifluorometylosulfonylo)imidek alkilo[2-(2-hydroksyetoksy)etylo]dimetyloamoniowy, o wzorze ogólnym 1 gdzie: R oznacza podstawnik alkilowy prostołańcuchowy zawierający od czterech do szesnastu atomów węgla. Zgłoszenie obejmuje też sposób otrzymywania bis(trifluorometylosulfonylo)imidku alkilo[2-(2- hydroksyetoksy)etylo]dimetylo-amoniowego, polega na tym, że czwartorzędowy bromek alkilo[2-(2-hydroksyetoksy)etylo]dimetyloamoniowy o wzorze ogólnym 2, w którym R oznacza podstawnik alkilowy prostołańcuchowy zawierający od czterech do szesnastu atomów węgla, poddaje się reakcji wymiany anionu z solą sodową lub potasową, lub litową, lub amonową kwasu bis(trifluorometylosulfonylo)imidkowego w stosunku molowym czwartorzędowej soli amoniowej do soli kwasu od 1:0,9 do 1:1,1, korzystnie 1:1, w temperaturze co najmniej 20°C, w środowisku wodnym lub w rozpuszczalniku organicznym z grupy: metanol, etanol, propanol, izopropanol, butanol, po czym z rozpuszczalnika organicznego odsącza się powstały nieorganiczny produkt uboczny, z przesączu odparowuje się rozpuszczalnik, a produkt reakcji suszy się. Przedmiotem zgłoszenia jest też zastosowanie bis(trifluorometylosulfonylo)imidku alkilo[2-(2-hydroksyetoksy)etylo]dimetylo-amoniowego w postaci czystej jako niewodny elektrolit kondensatora elektrochemicznego.The subject of the application is alkyl [2- (2-hydroxyethoxy) ethyl] dimethylammonium bis (trifluoromethylsulfonyl) imide, with the general formula 1 where: R is a straight chain alkyl substituent containing from four to sixteen carbon atoms. The application also includes a method for obtaining alkyl [2- (2-hydroxyethoxy) ethyl] dimethylammonium bis (trifluoromethylsulfonyl) imide, in which the quaternary alkyl [2- (2-hydroxyethoxy) ethyl] dimethylammonium bromide of general formula 2 in where R is a straight chain alkyl substituent containing from four to sixteen carbon atoms, is subjected to an anion exchange reaction with sodium, potassium, or lithium or ammonium salt of bis (trifluoromethylsulfonyl) imidic acid in a molar ratio of quaternary ammonium salt to acid salt from 1: 0, 9 to 1: 1.1, preferably 1: 1, at a temperature of at least 20 ° C, in an aqueous environment or in an organic solvent from the group: methanol, ethanol, propanol, isopropanol, butanol, after which the inorganic formed is filtered off by-product, the solvent is evaporated from the filtrate and the reaction product is dried. The subject of the application is also the use of alkyl [2- (2-hydroxyethoxy) ethyl] dimethylammonium bis (trifluoromethylsulfonyl) imide in pure form as a non-aqueous electrolyte of an electrochemical capacitor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL416322A PL230763B1 (en) | 2016-02-29 | 2016-02-29 | Bis(trifluoromethylsulfonyl)imide of alkyl[2-(2-hydroexyethoxy)ethyl]dimethylammonium and method for obtaining them and application as electrolytes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL416322A PL230763B1 (en) | 2016-02-29 | 2016-02-29 | Bis(trifluoromethylsulfonyl)imide of alkyl[2-(2-hydroexyethoxy)ethyl]dimethylammonium and method for obtaining them and application as electrolytes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL416322A1 true PL416322A1 (en) | 2017-09-11 |
| PL230763B1 PL230763B1 (en) | 2018-12-31 |
Family
ID=59771932
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL416322A PL230763B1 (en) | 2016-02-29 | 2016-02-29 | Bis(trifluoromethylsulfonyl)imide of alkyl[2-(2-hydroexyethoxy)ethyl]dimethylammonium and method for obtaining them and application as electrolytes |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL230763B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL443898A1 (en) * | 2023-02-27 | 2024-09-02 | Ppuh Autopart Jacek Bąk Spółka Z Ograniczoną Odpowiedzialnością | Lead-acid battery electrolyte modified with ionic liquid, its use and lead-acid battery with electrolyte modified with ionic liquid |
-
2016
- 2016-02-29 PL PL416322A patent/PL230763B1/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL443898A1 (en) * | 2023-02-27 | 2024-09-02 | Ppuh Autopart Jacek Bąk Spółka Z Ograniczoną Odpowiedzialnością | Lead-acid battery electrolyte modified with ionic liquid, its use and lead-acid battery with electrolyte modified with ionic liquid |
| PL246829B1 (en) * | 2023-02-27 | 2025-03-17 | Politechnika Poznanska | Lead-acid battery electrolyte modified with ionic liquid, its use and lead-acid battery with electrolyte modified with ionic liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| PL230763B1 (en) | 2018-12-31 |
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