[go: up one dir, main page]

PL2504366T3 - Catalysts of the ziegler-natta type for the (co)polymerization of -olefins with a high productivity - Google Patents

Catalysts of the ziegler-natta type for the (co)polymerization of -olefins with a high productivity

Info

Publication number
PL2504366T3
PL2504366T3 PL10784264T PL10784264T PL2504366T3 PL 2504366 T3 PL2504366 T3 PL 2504366T3 PL 10784264 T PL10784264 T PL 10784264T PL 10784264 T PL10784264 T PL 10784264T PL 2504366 T3 PL2504366 T3 PL 2504366T3
Authority
PL
Poland
Prior art keywords
ziegler
olefins
catalysts
polymerization
high productivity
Prior art date
Application number
PL10784264T
Other languages
Polish (pl)
Inventor
Francesco Masi
Mario Polesello
Roberto Fusco
Anna Sommazzi
Antonio Alfonso Proto
Laura Meda
Giuseppe Conti
Francesco Menconi
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of PL2504366T3 publication Critical patent/PL2504366T3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
PL10784264T 2009-11-23 2010-11-18 Catalysts of the ziegler-natta type for the (co)polymerization of -olefins with a high productivity PL2504366T3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2009A002057A IT1397080B1 (en) 2009-11-23 2009-11-23 ZIEGLER-NATTA TYPE CATALYST FOR LA (CO) POLYMERIZATION OF ALPHA-OLEPHINES WITH HIGH PRODUCTIVITY
PCT/EP2010/007067 WO2011060958A1 (en) 2009-11-23 2010-11-18 Catalysts of the ziegler-natta type for the (co)polymerization of olefins with a high productivity
EP10784264.3A EP2504366B1 (en) 2009-11-23 2010-11-18 Catalysts of the ziegler-natta type for the (co)polymerization of -olefins with a high productivity

Publications (1)

Publication Number Publication Date
PL2504366T3 true PL2504366T3 (en) 2015-02-27

Family

ID=42224498

Family Applications (1)

Application Number Title Priority Date Filing Date
PL10784264T PL2504366T3 (en) 2009-11-23 2010-11-18 Catalysts of the ziegler-natta type for the (co)polymerization of -olefins with a high productivity

Country Status (17)

Country Link
US (1) US9334341B2 (en)
EP (1) EP2504366B1 (en)
JP (1) JP5760002B2 (en)
KR (1) KR101721717B1 (en)
CN (1) CN102725317B (en)
AR (1) AR079119A1 (en)
BR (1) BR112012012275B1 (en)
CA (1) CA2781196C (en)
CL (1) CL2012001335A1 (en)
EA (1) EA021660B1 (en)
ES (1) ES2520993T3 (en)
IT (1) IT1397080B1 (en)
MX (1) MX2012005989A (en)
MY (1) MY161841A (en)
PL (1) PL2504366T3 (en)
TW (1) TWI519555B (en)
WO (1) WO2011060958A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0416482B1 (en) 2003-11-14 2020-12-01 Polimeri Europa S.P.A. solid catalyst component for the (co) polymerization of ethylene, process for the preparation of a solid component, and, catalyst and process for the (co) polymerization of ethylene
JP5695869B2 (en) * 2010-09-28 2015-04-08 日本ポリエチレン株式会社 Ziegler-Natta catalyst reforming method, modified Ziegler-Natta catalyst, olefin polymerization method using the same, and obtained olefin polymer
IT1403278B1 (en) * 2010-12-20 2013-10-17 Polimeri Europa Spa CATALYST AND CATALYST PRECURSOR FOR (CO) HIGH TEMPERATURE ALMA-OLEPHINE POLYMERIZATION
IT1403290B1 (en) * 2010-12-27 2013-10-17 Polimeri Europa Spa SOLID COMPONENT OF CATALYST, CATALYST INCLUDING THE SOLID COMPONENT, AND PROCEDURE OF (CO) POLYMERIZATION OF ALPHA-OLEFINES
BR112016008605B1 (en) 2013-10-18 2021-01-19 China Petroleum & Chemical Corporation METHOD FOR PREPARING A SPHERICAL CONVEYOR OF A POLYMERIZATION DEOLEFINS, SPHERICAL CONVEYOR, PROCESS FOR PREPARING A SOLID COMPOSITION, COMPOSITION OF SOLID, CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINES, METHODS OF PREPARATION OF OLEFINS AND METHOD FOR POLYMERIZING OLEFINS
EP3186290B8 (en) * 2014-07-31 2020-08-19 Versalis S.p.A. Solid catalyst for the (co)polymerisation of alpha-olefins and process for the preparation thereof
CN105817243B (en) * 2015-01-27 2019-03-22 中国石油化工股份有限公司 A kind of carbon-based material, preparation method and use
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
JP7539785B2 (en) 2020-03-31 2024-08-26 住友化学株式会社 Solid catalyst components for olefin polymerization

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA920299A (en) 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
BE791676A (en) 1971-12-08 1973-05-21 Solvay Process for the polymerization of olefins
LU64420A1 (en) 1971-12-08 1973-07-16
LU65587A1 (en) 1972-06-22 1973-12-27
IT1136627B (en) 1981-05-21 1986-09-03 Euteco Impianti Spa SUPPORTED CATALYST FOR THE POLYMERIZATION OF ETHYLENE
IT1212779B (en) 1983-10-14 1989-11-30 Enichimica Secondaria PROCEDURE FOR THE POLYMERIZATION OF ETHYLENE AND FOR THE COPOLYMERIZATION OF ETHYLENE WITH ALPHA-OLEPHINS AND RELATED CATALYST.
US4562170A (en) 1984-09-04 1985-12-31 Exxon Research & Engineering Co. Polymerization catalyst
IT1190319B (en) 1986-04-17 1988-02-16 Enichem Polimeri PROCEDURE FOR THE PREPARATION OF LOW OR MEDIUM DENSITY POLYETHYLENE AND CATALYSTS SUITABLE FOR THE PURPOSE
IT1203330B (en) 1987-02-06 1989-02-15 Enichem Base Spa Catalyst and catalyst component for the polymerization of ethylene or the co-polymerization of ethylene with alpha-Olefin
IT1251462B (en) 1991-07-12 1995-05-15 Enichem Polimeri SOLID COMPONENT OF CATALYST FOR THE (CO) POLYMERIZATION OF ETHYLENE AND ALPHA OLEFINS.
IT1311978B1 (en) 1999-03-25 2002-03-22 Polimeri Europa Srl BIMETALLIC CATALYST FOR THE (CO) POLYMERIZATION OF ALPHA-OLEFINS.
KR100579843B1 (en) * 2003-04-01 2006-05-12 주식회사 엘지화학 Hybrid supported metallocene catalyst and its preparation method and polyolefin production method using the same
BRPI0416482B1 (en) 2003-11-14 2020-12-01 Polimeri Europa S.P.A. solid catalyst component for the (co) polymerization of ethylene, process for the preparation of a solid component, and, catalyst and process for the (co) polymerization of ethylene

Also Published As

Publication number Publication date
CA2781196A1 (en) 2011-05-26
WO2011060958A1 (en) 2011-05-26
MY161841A (en) 2017-05-15
CN102725317B (en) 2014-12-10
BR112012012275A2 (en) 2018-03-27
CN102725317A (en) 2012-10-10
BR112012012275B1 (en) 2019-10-08
TW201129595A (en) 2011-09-01
AR079119A1 (en) 2011-12-28
MX2012005989A (en) 2012-11-23
JP5760002B2 (en) 2015-08-05
KR101721717B1 (en) 2017-03-30
EA201290283A1 (en) 2012-12-28
IT1397080B1 (en) 2012-12-28
EA021660B1 (en) 2015-08-31
US9334341B2 (en) 2016-05-10
KR20120091366A (en) 2012-08-17
EP2504366B1 (en) 2014-07-30
ES2520993T3 (en) 2014-11-12
ITMI20092057A1 (en) 2011-05-24
EP2504366A1 (en) 2012-10-03
HK1171037A1 (en) 2013-03-15
CA2781196C (en) 2018-01-02
TWI519555B (en) 2016-02-01
CL2012001335A1 (en) 2012-11-30
US20120322959A1 (en) 2012-12-20
JP2013511607A (en) 2013-04-04

Similar Documents

Publication Publication Date Title
PL2504366T3 (en) Catalysts of the ziegler-natta type for the (co)polymerization of -olefins with a high productivity
EP2413336A4 (en) Reactor
EP2495743A4 (en) Reactor
EP2428968A4 (en) Reactor
PL2185609T3 (en) Gas-phase polymerization process
EG25987A (en) Methods of preparing a polymerization catalyst
EP2450919A4 (en) Reactor
SG2014006266A (en) Process for polymerizing an olefin monomer and catalyst therefor
SG10201604444WA (en) Multi -Metallic Ziegler - Natta Procatalysts And Catalysts Prepared Therefrom For Olefin Polymerizations
EP2616513A4 (en) Catalysts and methods for polymer synthesis
ZA201204315B (en) A continuous process for the carbonylation of ethylene
AP3497A (en) Process for regenarating a cobalt comprising fischer-tropsch catalyst
EP2596859A4 (en) Gas-liquid reactor (variant embodiments)
GB201020204D0 (en) Process for the production of a sulfone monomer
EP2542338A4 (en) Catalysts for feedstock-flexible and process-flexible hydrogen production
EP2611538A4 (en) Catalyst composition for hydroformylation reaction and a hydroformylation process using the same
ZA201202378B (en) Reactor with channels
GB201013486D0 (en) A cask
EP2242580A4 (en) Ziegler-natta catalyst
EP2604634A4 (en) Catalyst component for olefin polymerization reaction and catalyst thereof
EP2520591B8 (en) Catalyst for polyolefin polymerisation and a production method for the same
EP2257576A4 (en) A process for the synthesis of alpha-olefin polymerization procatalysts
EP2358764A4 (en) Polyethylene polymerization processes
EP2520594A4 (en) Ziegler-natta catalyst for olefin polymerization
PL2382247T3 (en) Pe mib slurry polymerization