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PL101436B1 - METHOD OF MAKING MODIFIED ROAD ASPHALT - Google Patents

METHOD OF MAKING MODIFIED ROAD ASPHALT Download PDF

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Publication number
PL101436B1
PL101436B1 PL1975177416A PL17741675A PL101436B1 PL 101436 B1 PL101436 B1 PL 101436B1 PL 1975177416 A PL1975177416 A PL 1975177416A PL 17741675 A PL17741675 A PL 17741675A PL 101436 B1 PL101436 B1 PL 101436B1
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PL
Poland
Prior art keywords
asphalt
products
rubber waste
rubber
bitumens
Prior art date
Application number
PL1975177416A
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Polish (pl)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to PL1975177416A priority Critical patent/PL101436B1/en
Priority to FI753663A priority patent/FI66892C/en
Priority to NO760068A priority patent/NO150282C/en
Priority to SU762313353A priority patent/SU793407A3/en
Priority to DK11776*#A priority patent/DK11776A/en
Priority to DE2601132A priority patent/DE2601132C2/en
Priority to SE7600378A priority patent/SE429345B/en
Priority to CS76269A priority patent/CS209484B2/en
Priority to HU76II233A priority patent/HU177847B/en
Priority to BR7600271A priority patent/BR7600271A/en
Priority to LU74194A priority patent/LU74194A1/xx
Priority to AT0027576A priority patent/AT369418B/en
Priority to IT19337/76A priority patent/IT1054797B/en
Priority to DD190846A priority patent/DD123891A5/xx
Priority to RO84533A priority patent/RO80997B/en
Priority to JP51004843A priority patent/JPS5840586B2/en
Priority to GB406/76A priority patent/GB1539116A/en
Priority to BE163615A priority patent/BE837692A/en
Priority to NL7600509A priority patent/NL7600509A/en
Priority to FR7601248A priority patent/FR2297895A1/en
Priority to CA243,780A priority patent/CA1052057A/en
Publication of PL101436B1 publication Critical patent/PL101436B1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10CWORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C3/00Working-up pitch, asphalt, bitumen
    • C10C3/02Working-up pitch, asphalt, bitumen by chemical means reaction
    • C10C3/026Working-up pitch, asphalt, bitumen by chemical means reaction with organic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)
  • Road Paving Structures (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Working-Up Tar And Pitch (AREA)
  • Paints Or Removers (AREA)

Description

Przedmiotem wynalazku jest sposób wytwarzania asfaltów drogowych modyfikowanych produktami termicznej destrukcji gumy, przeznaczonych zwlaszcza do budowy asfaltowych nawierzchni drogowych. Znane sa sposoby modyfikowania asfaltów drogowych polegajace na wprowadzaniu do asfaltu kauczuków, zywic, polimerów trudno mieszalnych bezposrednio z asfaltem, w postaci emulsji wodnej lub roztworu w niskowrzacych rozpuszczalnikach. Po oddestylowaniu wody lub rozpuszczalnika uzyskuje sie homogeniczny i stabilny asfalt modyfikowany. Znany jest równiez sposób wprowadzania do asfaltów gumy polegajacy na ogrzewaniu mieszaniny rozdrobnionej gumy i aromatycznego rozpuszczalnika wrzacego w granicach 100 do 220°C w obecnosci katalizatora rozkladu gumy i w temperaturze 120 do 180°C. Otrzymany roztwór przetworzonej gumy miesza sie z asfaltem a nastepnie oddestylowuje rozpuszczalnik. W opisie patentowym PRL nr 97435 podano sposób otrzymywania homogenicznej mieszaniny asfaltu i produktów termicznej destrukcji gumy. Istota wynalazku. Istota wynalazku polega na wytworzeniu mieszaniny asfaltu i produktów termicznej destrukcji odpadów gumowych o korzystnych wlasnosciach uzytkowych w zastosowaniu do budowy asfalto¬ wych nawierzchni drogowych. Proces polega na oddestylowaniu z roztworu destruktu gumy w asfalcie lekkiego oleju powstalego w wyniku rozkladu gumy i czesciowo oleju zawartego w asfalcie. Jako odpady gumowe stosuje sie zuzyte opony, detki, tasmy transporterowe, odpady gumowe przemyslowe itp. Odpady gumowe oprócz gumy moga zawierac kord, i inneskladniki. < * ' W sposób wedlug wynalazku skladnik modyfikujacy otrzymuje sie przez ogrzewanie i mieszanie odpadów gumowych w temperaturze 240 do 380°C w srodowisku asfaltu ponaftowego, lub ekstraktów po rafinacji selektywnej olejów mineralnych, lub ciezkich produktów destrukcyjnej przeróbki produktów naftowych, lub ciezkich produktów smoly poweglowej w ilosci 1 do 80% wagowych liczac na wsad. Otrzymana mieszanine homogeniczna wprowadza sie do asfaltu naftowego lub naturalnego w takiej ilosci by zawartosc przetworzonych odpadów gumowych w gotowym asfalcie wynosila 1 do 50% wagowych. W inny sposób skladnik modyfikujacy wytwarza sie bezposrednio w asfalcie przez wprowadzenie 1 do 50% wagowych odpadów gumowych liczac na wsad do asfaltu podestylacyjnego, lub utlenionego, lub po rafinacji2 101436 propanem, lub naturalnego i ogrzewanie i mieszanie w temperaturze 240 do 380°C az do uzyskania homogenicznej mieszaniny. Zawartosc parafin w asfaltach i pólproduktach stosowanych do wytwarzania asfaltu powinna wynosic mniej niz 6% wagowych. Wytworzona w ten sposób homogeniczna mieszanine produktów termicznej destrukcji gumy, asfaltu, pólproduktów sluzacych do otrzymywania asfaltów drogowych poddaje sie destylacji pod obnizonym cisnieniem lub destylacji z para wodna oddestylowujac korzystnie oleje wrzace ponizej temperatury 550°C, aby uzyskac produkt o temperaturze zaplonu wedlug metody Marcusona korzystnie powyzej 200°C. W procesie destylacji wydziela sie z mieszaniny niskowrzace produkty termicznej destrukcji gumy oraz czesciowo oleje niskoczasteczkowe zawarte w asfaltach lub wprowadzone do procesu rozpuszczania gumy. Niskowrzace produkty termicznej destrukcji gumy posiadaja duza zawartosc nienasyconych weglowodorów i charakteryzuja sie niestabilnoscia chemiczna oraz przykrym zapachem. Ich oddestylowanie poprawia stabilnosc termooksydacyjna asfaltu, podwyzsza temperature zaplonu, podwyzsza temperature kropienia i obniza penetra- qe asfaltu, podwyzsza odpornosc asfaltu na dzialanie czynników atmosferycznych i przyczepnosc do kruszyw mineralnych. Destylujace lekkie produkty rozkladu gumy ulatwiaja oddestylowanie z asfaltu lekkich olejów poprzez obnizenie ich preznosci par i lepkosci co jest zjawiskiem korzystnie wplywajacym na jakosc asfaltu. Wzbogaca sie w ten sposób asfalt w zywice i asfalteny oraz oleje o duzym ciezarze czasteczkowym, oraz obniza zawartosc parafin grubokrystalicznych. Sposób wedlug wynalazku daje mozliwosc otrzymywania roztworów destruktu gumy w asfaltach i pólproduktach stosowanych do wytwarzania asfaltów w nizszych temperaturach i krótszym czasie mieszania dzieki mozliwosci zastosowania rozpuszczalników zawierajacych wieksza ilosc oleju tym samym o mniejszej lepkosci i wiekszej zdolnosci rozpuszczania. Otrzymane w opisany sposób asfalty drogowe modyfikowane moga byc uzyte do budowy nawierzchni asfaltowej bezposrednio lub po dodatkowym komponowaniu z asfaltami drogowymi i niemodyfikowanymi. Mieszanine asfaltu i produktów termicznej destrukcji gumy, mozna poddawac dodatkowej przeróbce i modyfikacji jak asfalty ponaftowe na przyklad utlenianiu sprezonym powietrzem. Przyklad I. 77 kg asfaltu podestylacyjnego o temperaturze mieknienia, metoda Pierscien i Kula 23 i zawartosci parafin 3,6% wagowych zmieszano z 23 kg rozdrobnionych opon samochodowych wraz z kordem poliamidowym po wczesniejszym oddzieleniu drutu i ogrzewano w temperaturze 330°C przez 3 godziny. Otrzymany jednorodny roztwór przedmuchiwano 1 godzine przegrzana do temperatury 380°C para wodna a nastepnie podgrzano do temperatury 340°C i pod cisnieniem 10 Torów oddestylowano 12% wagowych olejów niskowrzacych. Otrzymano asfalt drogowy o wlasnosciach: temperatura mieknienia metoda Pierscien, i Kula,°C 47 penetracja w temperaturze25°C 74 temperatura zaplonu,°C 236 temperatura lamliwosci metoda Frasha,°C —7 zawartosc parafiny,% 2,9 odparowalnosc,% 0,7 penetracja po odparowaniu w temperaturze 165°C, %51 Przyklad II. 70 kg granulatu zuzytych opon, i 30 kg ekstraktu pofurfurolowego o lepkosc 1,7°E w temperaturze 100°C ogrzewa sie i miesza w temperaturze 280°C przez 8 godzin. 20 kg otrzymanego roztworu destruktu gumy i 80 kg asfaltu drogowego utlenionego, o penetracji w 25°C 39 i zawartosci parafin 2,1% wagowych miesza sie a nastepnie w temperaturze 315°C przedmuchuje para wodna przegrzana do temperatury 400°C przez 2 godziny. Otrzymuje asfalt w wlasnosciach: penetracja w temperaturze 25°C 34 temperatura mieknienia,°C 56 temperatura zaplonu,°C 226 ciagliwosc w temperaturze 25°C 71 temperatura lamliwosci,°C —8 Przyklad III. 30 kg asfaltu podestylacyjnego, o temperaturze mieknienia 41 i 30 kg oleju antraceno¬ wego o granicach wrzenia 280 do 330°C zmieszano i ogrzewano w temperaturze 250°C z 40 kg odpadów gumowych przemyslowych zawierajacych 38% wagowych wulkanizowanego kauczuku butadienowo-styrenowego i 22% wagowych kauczuku niewulkanizowanego przez 8 godzin. Otrzymana homogeniczna mieszanina zmieszano w stosunku 1 do 2 z asfaltem podestylacyjnym i rozdestylowano pod cisnieniem 34 torów z dodatkiem przegrzanej pary wodnej. Uzyskano 38 kg destylatu olejowego i 62 kg asfaltu modyfikowanego o wlasnosciach:101 436 3 penetracja w temperaturze 25°C 93 temperatura mieknienia,°C 48 temperatura zaplonu,°C 221 ciagliwosc w 25°C, cm powyzej 100 ciagliwosc w 25°C, cm powyzej 100 zawartosc parafiny,% 1,8 PL PL PL PLThe invention concerns a method for producing road asphalts modified with thermal rubber degradation products, intended particularly for the construction of asphalt road surfaces. Known methods for modifying road asphalts involve introducing rubbers, resins, and polymers that are difficult to mix directly with the asphalt, either in the form of an aqueous emulsion or as a solution in low-boiling solvents. After distilling off the water or solvent, a homogeneous and stable modified asphalt is obtained. A method for incorporating rubber into asphalts is also known, involving heating a mixture of ground rubber and an aromatic solvent boiling between 100 and 220°C in the presence of a rubber degradation catalyst at a temperature of 120 to 180°C. The resulting solution of processed rubber is mixed with the asphalt, and then the solvent is distilled off. Polish Patent No. 97,435 describes a method for obtaining a homogeneous mixture of asphalt and thermally degraded rubber products. The essence of the invention: The essence of the invention consists in producing a mixture of asphalt and thermally degraded rubber waste products with advantageous performance properties for the construction of asphalt road surfaces. The process involves distilling the light oil resulting from the degraded rubber and partially the oil contained in the asphalt from a solution of degraded rubber in asphalt. Used rubber waste includes used tires, tubes, conveyor belts, industrial rubber waste, etc. In addition to rubber, the rubber waste may also contain cord and other components. < * ' In the method according to the invention, the modifying component is obtained by heating and mixing rubber waste at a temperature of 240 to 380°C in a petroleum asphalt environment, or extracts from selective refining of mineral oils, or heavy products of destructive processing of petroleum products, or heavy coal tar products in an amount of 1 to 80% by weight of the feed. The resulting homogeneous mixture is introduced into petroleum or natural asphalt in an amount such that the content of processed rubber waste in the finished asphalt is 1 to 50% by weight. Alternatively, the modifying component is produced directly in asphalt by incorporating 1 to 50% by weight of rubber waste, calculated on the feedstock, into distillation asphalt, oxidized asphalt, or propane-refined asphalt, or natural asphalt, and heating and mixing at 240 to 380°C until a homogeneous mixture is obtained. The paraffin content in asphalts and intermediate products used to produce asphalt should be less than 6% by weight. The homogeneous mixture of products of thermal destruction of rubber, asphalt, and intermediate products used to produce road asphalts thus obtained is subjected to distillation under reduced pressure or steam distillation, preferably distilling off oils boiling below 550°C, to obtain a product with a flash point, preferably above 200°C, according to the Marcuson method. The distillation process separates low-boiling rubber thermal degradation products from the mixture, as well as partially low-molecular-weight oils contained in asphalt or introduced into the rubber dissolution process. Low-boiling rubber thermal degradation products contain a high content of unsaturated hydrocarbons and are characterized by chemical instability and an unpleasant odor. Their distillation improves the thermo-oxidative stability of the asphalt, increases its flash point, raises its dripping point, and reduces its penetration, improving its resistance to weathering and improving its adhesion to mineral aggregates. Distilling light rubber degradation products facilitates the distillation of light oils from the asphalt by lowering their vapor pressure and viscosity, a phenomenon that positively impacts the quality of the asphalt. This enriches the asphalt with resins, asphaltenes, and high-molecular-weight oils, and reduces the content of coarse-crystalline paraffins. The method according to the invention enables the preparation of solutions of reclaimed rubber in asphalts and intermediates used in asphalt production at lower temperatures and in shorter mixing times thanks to the use of solvents containing higher amounts of oil, thus having lower viscosity and greater dissolving power. Modified road asphalts obtained in this manner can be used for the construction of asphalt surfaces directly or after additional blending with road and unmodified asphalts. The mixture of asphalt and thermally reclaimed rubber products can be subjected to additional processing and modification, similar to petroleum asphalts, for example, by oxidation with compressed air. Example I. 77 kg of distillation asphalt with a softening point of 23 using the Ring and Ball method and a paraffin content of 3.6% by weight was mixed with 23 kg of shredded car tires with polyamide cord after wire separation and heated at 330°C for 3 hours. The resulting homogeneous solution was blown with steam superheated to 380°C for 1 hour and then heated to 340°C, and 12% by weight of low-boiling oils was distilled off at a pressure of 10 Torr. A road asphalt was obtained with the following properties: softening point by the Ring and Ball method, °C 47 penetration at 25 °C 74 flash point, °C 236 brittle point by the Frash method, °C —7 paraffin content, % 2.9 evaporation, % 0.7 penetration after evaporation at 165 °C, % 51 Example II. 70 kg of granulate of worn tires and 30 kg of post-furfural extract with a viscosity of 1.7 °E at 100 °C are heated and stirred at 280 °C for 8 hours. 20 kg of the resulting reclaimed rubber solution and 80 kg of oxidized road asphalt, with a penetration at 25°C of 39 and a paraffin content of 2.1% by weight, are mixed and then blown with steam superheated to 400°C for 2 hours at 315°C. The resulting asphalt has the following properties: penetration at 25°C of 34, softening point,°C of 56, flash point,°C of 226, ductility at 25°C of 71, brittle point,°C of —8. Example III. Thirty kilograms of distillation asphalt with a softening point of 41°C and 30 kilograms of anthracene oil with a boiling range of 280 to 330°C were mixed and heated at 250°C with 40 kilograms of industrial rubber waste containing 38% by weight of vulcanized styrene-butadiene rubber and 22% by weight of unvulcanized rubber for 8 hours. The resulting homogeneous mixture was mixed in a 1 to 2 ratio with distillation asphalt and distilled at 34 torr with the addition of superheated steam. 38 kg of oil distillate and 62 kg of modified asphalt were obtained with the following properties: 101 436 3 penetration at 25°C 93 softening point,°C 48 flash point,°C 221 ductility at 25°C, cm above 100 ductility at 25°C, cm above 100 paraffin content,% 1.8 PL PL PL PL

Claims (2)

Zastrzezenia patentowePatent claims 1. Sposób otrzymywania asfaltów drogowych modyfikowanych, znamienny tym, ze asfalt lub pólprodukty stosowane do otrzymywania asfaltów o zawartosci parafin ponizej 6% wagowych, komponuje sie z produktami termicznej destrukcji odadów gumowych w takiej ilosci by zawartosc przetworzonych odpadów gumowych w gotowym asfalcie modyfikowanym wynosila 1 do 50% wagowych, przy czym produkt termicznej destrukcji odpadów gumowych otrzymuje sie przez ogrzewanie odpadów gumowych w temperaturze 240 do 380°C w srodowisku asfaltów ponaftowych, lub ekstraktów po selektywnej rafinacji olejów mineralnych, lub ciezkich produktów z destrukcyjnej przeróbki produktów naftowych, lub ciezkich produktów destylacji smoly poweglowej a otrzymana mieszanine homogeniczna produktu destrukcji odpadów gumowych i weglowodorów poddaje sie destylacji pod obnizonym cisnieniem lub z para wodna i wydziela niskoczasteczkowe niepozadane w asfaltach drogowych oleje.1. The method of obtaining modified road bitumens, characterized in that the bitumen or semi-products used for the preparation of bitumens with a paraffin content below 6% by weight, is mixed with the products of thermal destruction of rubber waste in such an amount that the content of processed rubber waste in the finished modified bitumen is 1 50% by weight, with the product of thermal destruction of rubber waste obtained by heating rubber waste at a temperature of 240 to 380 ° C in the environment of petroleum bitumens or extracts after selective refining of mineral oils or heavy products from destructive processing of petroleum products or heavy distillation products coal tar and the obtained homogeneous mixture of the product of destruction of rubber waste and hydrocarbons is distilled under reduced pressure or with steam and gives off low-molecular oils, not used in road bitumens. 2. Sposób wedlug zastrz. 1, znamienny tym, ze destrukcje odpadów gumowych prowadzi sie w trakcie oddestylowywania niskowrzacych skladników.2. The method according to claim The method of claim 1, characterized in that the destruction of the rubber waste is carried out while the low-boiling components are distilled off.
PL1975177416A 1975-01-19 1975-01-19 METHOD OF MAKING MODIFIED ROAD ASPHALT PL101436B1 (en)

Priority Applications (21)

Application Number Priority Date Filing Date Title
PL1975177416A PL101436B1 (en) 1975-01-19 1975-01-19 METHOD OF MAKING MODIFIED ROAD ASPHALT
FI753663A FI66892C (en) 1975-01-19 1975-12-29 FOERFARANDE FOER FRAMSTAELLNING AV ASFALTKOMPOSITION FOER VAEGYTOR
NO760068A NO150282C (en) 1975-01-19 1976-01-09 PROCEDURE FOR THE PREPARATION OF ASPHALT MIXTURES, SPECIAL FOR THE PREPARATION OF STREET TIRE
SU762313353A SU793407A3 (en) 1975-01-19 1976-01-12 Method of producing bituminous binder
DK11776*#A DK11776A (en) 1975-01-19 1976-01-13 ASPHALT MATERIAL, ICES FOR THE MANUFACTURE OF ASPHALT WALL COATINGS, AND METHOD FOR THE MANUFACTURE OF THE MATERIAL
DE2601132A DE2601132C2 (en) 1975-01-19 1976-01-14 Bitumen mixture made from a heat-treated mixture of bitumen and the decomposition products of worn rubber tires resulting from the heat treatment
SE7600378A SE429345B (en) 1975-01-19 1976-01-15 SET TO MAKE AN ASPHALT COMPOSITION BASED ON ASPHALT AND MINERAL FILLERS
CS76269A CS209484B2 (en) 1975-01-19 1976-01-15 Asphalt mixture on the base of asphalt part.for forming the surface of the asphalt roads and method of making the same mixture
HU76II233A HU177847B (en) 1975-01-19 1976-01-16 Process for producing bitumen composition for road building
BR7600271A BR7600271A (en) 1975-01-19 1976-01-16 ASPHALT COMPOSITION, PARTICULARLY FOR OBTAINING ASPHALT ROAD SURFACE, AND PROCESS FOR PRODUCING THESE COMPOSITION
LU74194A LU74194A1 (en) 1975-01-19 1976-01-16
AT0027576A AT369418B (en) 1975-01-19 1976-01-16 METHOD FOR PRODUCING BITUMEN MIXTURE, ESPECIALLY FOR PRODUCING BITUMEN ROAD CEILINGS
IT19337/76A IT1054797B (en) 1975-01-19 1976-01-16 ASPHALT COMPOSITION PARTICULARLY FOR OBTAINING ROOFS FOR ASPHALT ROADS AND PROCEDURE FOR PREPARING SUCH COMPOSITION
DD190846A DD123891A5 (en) 1975-01-19 1976-01-16
RO84533A RO80997B (en) 1975-01-19 1976-01-17 Asphaltum composition and process for making the same
JP51004843A JPS5840586B2 (en) 1975-01-19 1976-01-19 asphalt composition
GB406/76A GB1539116A (en) 1975-01-19 1976-01-19 Asphalt compositions
BE163615A BE837692A (en) 1975-01-19 1976-01-19 ASPHALTIC COMPOSITION AND PROCESS FOR PREPARING THIS COMPOSITION
NL7600509A NL7600509A (en) 1975-01-19 1976-01-19 METHOD FOR THE PREPARATION OF AN ASPHALT COMPOSITION PARTICULARLY INTENDED FOR COATING MATERIAL FOR ASPHALT ROADS.
FR7601248A FR2297895A1 (en) 1975-01-19 1976-01-19 COMPOSITION OF ASPHALT, DESIGNED BY
CA243,780A CA1052057A (en) 1975-01-19 1976-01-19 Asphalt composition, particularly for obtaining asphalt road surfaces, and method of producing this composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL1975177416A PL101436B1 (en) 1975-01-19 1975-01-19 METHOD OF MAKING MODIFIED ROAD ASPHALT

Publications (1)

Publication Number Publication Date
PL101436B1 true PL101436B1 (en) 1978-12-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
PL1975177416A PL101436B1 (en) 1975-01-19 1975-01-19 METHOD OF MAKING MODIFIED ROAD ASPHALT

Country Status (21)

Country Link
JP (1) JPS5840586B2 (en)
AT (1) AT369418B (en)
BE (1) BE837692A (en)
BR (1) BR7600271A (en)
CA (1) CA1052057A (en)
CS (1) CS209484B2 (en)
DD (1) DD123891A5 (en)
DE (1) DE2601132C2 (en)
DK (1) DK11776A (en)
FI (1) FI66892C (en)
FR (1) FR2297895A1 (en)
GB (1) GB1539116A (en)
HU (1) HU177847B (en)
IT (1) IT1054797B (en)
LU (1) LU74194A1 (en)
NL (1) NL7600509A (en)
NO (1) NO150282C (en)
PL (1) PL101436B1 (en)
RO (1) RO80997B (en)
SE (1) SE429345B (en)
SU (1) SU793407A3 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
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ZA77721B (en) * 1976-02-18 1978-09-27 Mobil Oil Corp Paving grade asphalt compositions
JPS58204205A (en) * 1982-04-26 1983-11-28 東亜道路工業株式会社 Regeneration and additive composition for pavement
JPS58204203A (en) * 1982-04-26 1983-11-28 東亜道路工業株式会社 Regeneration and additive composition for pavement
JPS58201847A (en) * 1982-04-26 1983-11-24 Toa Doro Kogyo Kk Regenerated additive composition for pavement
DE3630132C2 (en) * 1986-09-04 1999-12-16 Haas Johannes Process for the production of an elastic bituminous insulating and sealing compound
WO1989010383A1 (en) * 1988-04-28 1989-11-02 Nauchno-Proizvodstvennoe Obiedinenie "Dorstroitekh Bitumen-rubber composition and method of obtaining it
FI911739L (en) * 1991-04-11 1992-10-12 Neste Oy BINDER FOR ASPHALT
US5270361A (en) * 1992-02-25 1993-12-14 Bitumar R. & D. (2768836 Canada Inc.) Asphalt composition and process for obtaining same
DE9403628U1 (en) * 1994-03-04 1994-05-19 Bredemeyer, Jörg, 01159 Dresden Asphalt road surface with plastic admixtures
CN1218074A (en) * 1997-11-20 1999-06-02 波利法尔特有限公司 Bituminous compositions prepared with process treated vulcanized rubbers
CN102071613B (en) * 2011-01-26 2012-05-23 广东华盟路桥工程有限公司 Construction process of ATB asphalt macadam foundation
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FR2297895B1 (en) 1979-07-06
SU793407A3 (en) 1980-12-30
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DK11776A (en) 1976-07-20
DE2601132A1 (en) 1976-07-22
BR7600271A (en) 1976-08-31
BE837692A (en) 1976-05-14
RO80997A (en) 1984-06-21
NO760068L (en) 1976-07-20
NL7600509A (en) 1976-07-21
GB1539116A (en) 1979-01-24
SE429345B (en) 1983-08-29
DD123891A5 (en) 1977-01-19
FR2297895A1 (en) 1976-08-13
JPS51125412A (en) 1976-11-01
RO80997B (en) 1984-08-30
JPS5840586B2 (en) 1983-09-06
LU74194A1 (en) 1976-05-18
NO150282B (en) 1984-06-12
CA1052057A (en) 1979-04-10
IT1054797B (en) 1981-11-30
DE2601132C2 (en) 1982-03-25
FI66892C (en) 1984-12-10
FI753663A7 (en) 1976-07-20
CS209484B2 (en) 1981-12-31
FI66892B (en) 1984-08-31
SE7600378L (en) 1976-07-20
HU177847B (en) 1981-12-28
ATA27576A (en) 1982-05-15
AT369418B (en) 1982-12-27

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