PH26835A - Method of preventing polymers scale formation - Google Patents

Method of preventing polymers scale formation Download PDF

Info

Publication number: PH26835A
Authority: PH; Philippines
Prior art keywords: black; acid; polymerization; solvent; coating
Prior art date: 1988-08-19

Application number

PH39066A

Other languages

English (en)

Inventor

Toshihide Shimizu

Ischiro Kaneko

Mikio Watanabe

Original Assignee

Shinetsu Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-08-19

Filing date

1990-10-08

Publication date

1992-11-05

1990-10-08 Application filed by Shinetsu Chemical Co filed Critical Shinetsu Chemical Co

1992-11-05 Publication of PH26835A publication Critical patent/PH26835A/en

Links

238000000034 method Methods 0.000 title claims description 56
229920000642 polymer Polymers 0.000 title description 29
230000015572 biosynthetic process Effects 0.000 title description 14
230000003405 preventing effect Effects 0.000 title description 12
238000006116 polymerization reaction Methods 0.000 claims description 93
238000000576 coating method Methods 0.000 claims description 88
239000011248 coating agent Substances 0.000 claims description 87
-1 C.I. Direct Black 32 Chemical compound 0.000 claims description 39
239000000178 monomer Substances 0.000 claims description 39
239000002904 solvent Substances 0.000 claims description 36
239000002253 acid Substances 0.000 claims description 25
238000006277 sulfonation reaction Methods 0.000 claims description 14
229920002554 vinyl polymer Polymers 0.000 claims description 8
AOMZHDJXSYHPKS-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(N=NC=3C=CC=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 AOMZHDJXSYHPKS-UHFFFAOYSA-L 0.000 claims description 7
150000003839 salts Chemical class 0.000 claims description 7
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 6
238000007720 emulsion polymerization reaction Methods 0.000 claims description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
229910052783 alkali metal Inorganic materials 0.000 claims description 5
150000003863 ammonium salts Chemical class 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
238000003756 stirring Methods 0.000 claims description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 claims description 4
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
YCUVUDODLRLVIC-UHFFFAOYSA-N Sudan black B Chemical compound C1=CC(=C23)NC(C)(C)NC2=CC=CC3=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC=C1 YCUVUDODLRLVIC-UHFFFAOYSA-N 0.000 claims description 4
238000010557 suspension polymerization reaction Methods 0.000 claims description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
GBPWTMZRCAESKB-UHFFFAOYSA-N 2-amino-n,n-dipropylacetamide;hydrochloride Chemical compound Cl.CCCN(CCC)C(=O)CN GBPWTMZRCAESKB-UHFFFAOYSA-N 0.000 claims description 3
238000012662 bulk polymerization Methods 0.000 claims description 3
125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 3
238000010528 free radical solution polymerization reaction Methods 0.000 claims description 3
OCQDPIXQTSYZJL-UHFFFAOYSA-N 1,4-bis(butylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCCC)=CC=C2NCCCC OCQDPIXQTSYZJL-UHFFFAOYSA-N 0.000 claims description 2
BLFZMXOCPASACY-UHFFFAOYSA-N 1,4-bis(propan-2-ylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC(C)C)=CC=C2NC(C)C BLFZMXOCPASACY-UHFFFAOYSA-N 0.000 claims description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
150000008064 anhydrides Chemical class 0.000 claims description 2
VJDDAARZIFHSQY-UHFFFAOYSA-N basic black 2 Chemical compound [Cl-].C=1C2=[N+](C=3C=CC=CC=3)C3=CC(N(CC)CC)=CC=C3N=C2C=CC=1NN=C1C=CC(=O)C=C1 VJDDAARZIFHSQY-UHFFFAOYSA-N 0.000 claims description 2
BPHHNXJPFPEJOF-UHFFFAOYSA-J chembl296966 Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC(S([O-])(=O)=O)=C(N)C2=C(O)C(N=NC3=CC=C(C=C3OC)C=3C=C(C(=CC=3)N=NC=3C(=C4C(N)=C(C=C(C4=CC=3)S([O-])(=O)=O)S([O-])(=O)=O)O)OC)=CC=C21 BPHHNXJPFPEJOF-UHFFFAOYSA-J 0.000 claims description 2
XRPLBRIHZGVJIC-UHFFFAOYSA-L chembl3182776 Chemical compound [Na+].[Na+].NC1=CC(N)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C(=CC3=CC(=C(N=NC=4C=CC=CC=4)C(O)=C3C=2N)S([O-])(=O)=O)S([O-])(=O)=O)C=C1 XRPLBRIHZGVJIC-UHFFFAOYSA-L 0.000 claims description 2
150000001993 dienes Chemical class 0.000 claims description 2
UZZFFIUHUDOYPS-UHFFFAOYSA-L disodium 4-amino-3,6-bis[[4-[(2,4-diaminophenyl)diazenyl]phenyl]diazenyl]-5-oxido-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2ccc(cc2)N=Nc2c(N)c3c(O)c(N=Nc4ccc(cc4)N=Nc4ccc(N)cc4N)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(N)c1 UZZFFIUHUDOYPS-UHFFFAOYSA-L 0.000 claims description 2
239000001530 fumaric acid Substances 0.000 claims description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
239000011976 maleic acid Substances 0.000 claims description 2
238000011084 recovery Methods 0.000 claims description 2
NTOOJLUHUFUGQI-UHFFFAOYSA-M sodium;4-(4-acetamidoanilino)-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(NC(=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O NTOOJLUHUFUGQI-UHFFFAOYSA-M 0.000 claims description 2
RBYJOOWYRXEJAM-UHFFFAOYSA-M sodium;5,9-dianilino-7-phenylbenzo[a]phenazin-7-ium-4,10-disulfonate Chemical compound [Na+].C=1C=CC=CC=1[N+]1=C2C=C(NC=3C=CC=CC=3)C(S(=O)(=O)[O-])=CC2=NC(C2=CC=CC(=C22)S([O-])(=O)=O)=C1C=C2NC1=CC=CC=C1 RBYJOOWYRXEJAM-UHFFFAOYSA-M 0.000 claims description 2
QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 claims description 2
MPCYPRXRVWZKGF-UHFFFAOYSA-J tetrasodium 5-amino-3-[[4-[4-[(8-amino-1-hydroxy-3,6-disulfonatonaphthalen-2-yl)diazenyl]phenyl]phenyl]diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(N=NC3=CC=C(C=C3)C3=CC=C(C=C3)N=NC3=C(C=C4C=C(C=C(C4=C3O)N)S([O-])(=O)=O)S([O-])(=O)=O)=C(O)C2=C1N MPCYPRXRVWZKGF-UHFFFAOYSA-J 0.000 claims description 2
SPDRRRCQUXHHLH-UHFFFAOYSA-N 1-amino-2-bromo-4-(4-methylanilino)anthracene-9,10-dione Chemical compound C1=CC(C)=CC=C1NC1=CC(Br)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O SPDRRRCQUXHHLH-UHFFFAOYSA-N 0.000 claims 1
125000005395 methacrylic acid group Chemical group 0.000 claims 1
239000000243 solution Substances 0.000 description 65
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 54
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
238000002474 experimental method Methods 0.000 description 20
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 18
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
239000000047 product Substances 0.000 description 12
239000000460 chlorine Substances 0.000 description 9
238000001035 drying Methods 0.000 description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
150000001875 compounds Chemical class 0.000 description 8
238000010438 heat treatment Methods 0.000 description 7
239000000203 mixture Substances 0.000 description 7
239000011734 sodium Substances 0.000 description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
238000009833 condensation Methods 0.000 description 6
230000005494 condensation Effects 0.000 description 6
239000002270 dispersing agent Substances 0.000 description 6
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
229910001220 stainless steel Inorganic materials 0.000 description 6
239000010935 stainless steel Substances 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
150000004985 diamines Chemical class 0.000 description 5
229940012017 ethylenediamine Drugs 0.000 description 5
229910052500 inorganic mineral Inorganic materials 0.000 description 5
239000011707 mineral Substances 0.000 description 5
235000010755 mineral Nutrition 0.000 description 5
238000005406 washing Methods 0.000 description 5
239000003643 water by type Substances 0.000 description 5
239000005977 Ethylene Substances 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
239000003960 organic solvent Substances 0.000 description 4
239000003505 polymerization initiator Substances 0.000 description 4
YCUVUDODLRLVIC-VPHDGDOJSA-N sudan black b Chemical compound C1=CC(=C23)NC(C)(C)NC2=CC=CC3=C1\N=N\C(C1=CC=CC=C11)=CC=C1\N=N\C1=CC=CC=C1 YCUVUDODLRLVIC-VPHDGDOJSA-N 0.000 description 4
UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 3
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 3
XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
239000000463 material Substances 0.000 description 3
230000000379 polymerizing effect Effects 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
239000004342 Benzoyl peroxide Substances 0.000 description 2
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000004372 Polyvinyl alcohol Substances 0.000 description 2
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
150000001339 alkali metal compounds Chemical class 0.000 description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
150000003868 ammonium compounds Chemical class 0.000 description 2
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
229910001870 ammonium persulfate Inorganic materials 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
235000019400 benzoyl peroxide Nutrition 0.000 description 2
VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
WZGWWPARMFQTAY-UHFFFAOYSA-N ethene;methanol Chemical group OC.C=C WZGWWPARMFQTAY-UHFFFAOYSA-N 0.000 description 2
229960002089 ferrous chloride Drugs 0.000 description 2
HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
229910052588 hydroxylapatite Inorganic materials 0.000 description 2
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 2
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PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
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230000001678 irradiating effect Effects 0.000 description 1
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239000000314 lubricant Substances 0.000 description 1
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UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical class [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
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QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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229930004008 p-menthane Natural products 0.000 description 1
239000003002 pH adjusting agent Substances 0.000 description 1
XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
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239000011591 potassium Substances 0.000 description 1
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JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 description 1
239000001230 potassium iodate Substances 0.000 description 1
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VLYFRFHWUBBLRR-UHFFFAOYSA-L potassium;sodium;carbonate Chemical compound [Na+].[K+].[O-]C([O-])=O VLYFRFHWUBBLRR-UHFFFAOYSA-L 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
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239000003381 stabilizer Substances 0.000 description 1
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239000000126 substance Substances 0.000 description 1
HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/004—Scale prevention in a polymerisation reactor or its auxiliary parts by a prior coating on the reactor walls

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)

PH39066A 1988-08-19 1990-10-08 Method of preventing polymers scale formation PH26835A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP20718588		1988-08-19

Publications (1)

Publication Number	Publication Date
PH26835A true PH26835A (en)	1992-11-05

Family

ID=16535655

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PH39066A PH26835A (en)	1988-08-19	1990-10-08	Method of preventing polymers scale formation

Country Status (30)

Country	Link
US (1)	US5034477A (fr)
EP (1)	EP0358364B1 (fr)
KR (1)	KR900003213A (fr)
CN (1)	CN1040596A (fr)
AU (1)	AU612883B2 (fr)
BG (1)	BG51355A3 (fr)
BR (1)	BR8904171A (fr)
CA (1)	CA1330683C (fr)
CZ (1)	CZ467089A3 (fr)
DD (1)	DD300292A7 (fr)
DE (1)	DE68924572T2 (fr)
DK (1)	DK406789A (fr)
EG (1)	EG18973A (fr)
ES (1)	ES2017406A6 (fr)
FI (1)	FI96213C (fr)
GR (1)	GR3018353T3 (fr)
GT (1)	GT198900046A (fr)
HU (1)	HU207105B (fr)
IL (1)	IL91313A0 (fr)
MX (1)	MX170464B (fr)
NO (1)	NO172988C (fr)
NZ (1)	NZ230341A (fr)
PH (1)	PH26835A (fr)
PL (1)	PL161850B1 (fr)
PT (1)	PT91484B (fr)
RO (1)	RO105288B1 (fr)
RU (1)	RU2019546C1 (fr)
TR (1)	TR25533A (fr)
YU (1)	YU47141B (fr)
ZA (1)	ZA896061B (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2053827A1 (fr) *	1990-10-23	1992-04-24	Toshihide Shimizu	Composition pour prevenir la formation de tartre
US5302639A (en) *	1990-10-23	1994-04-12	Shin-Etsu Chemical Co., Ltd.	Polymer scale preventive agent
JP3486718B2 (ja) *	1992-06-30	2004-01-13	株式会社ルネサステクノロジ	シングルチップマイクロコンピュータ
CA2138182C (fr) *	1993-12-27	1996-11-12	Seiichi Masuko	Procede pour la polymerisation du chlorure de vinyle
ES2144569T3 (es) *	1994-12-29	2000-06-16	Atochem Elf Sa	Procedimiento para la elaboracion de un revestimiento de poliolefina, substrato dotado con el citado revestimiento, y su utilizacion para entrar en contacto con polvos en movimiento.
JP3971974B2 (ja) *	2002-09-03	2007-09-05	三菱化学株式会社	（メタ）アクリル酸類の製造方法
JP3974882B2 (ja) *	2003-08-07	2007-09-12	信越化学工業株式会社	重合体スケール付着防止剤
PT1514878E (pt) *	2003-09-05	2012-05-21	Shinetsu Chemical Co	Agente preventivo de incrustação de polímero
CN103896864B (zh) *	2014-04-23	2015-12-09	青岛双桃精细化工（集团）有限公司	一种苯胺黑的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4068059A (en) *	1977-02-17	1978-01-10	The B. F. Goodrich Company	Internally coated reaction vessel for use in olefinic polymerization
JPS55155001A (en) *	1979-05-21	1980-12-03	Shin Etsu Chem Co Ltd	Polymerization of vinyl monomer
AU541568B2 (en) *	1979-09-14	1985-01-10	B.F. Goodrich Company, The	**
JPS58210902A (ja) *	1982-05-31	1983-12-08	Shin Etsu Chem Co Ltd	ビニル系単量体の重合方法
CA1289297C (fr) *	1987-12-08	1991-09-17	Toshihide Shimizu	Methode pour empecher les depots de polymere
IL91230A (en) *	1988-08-10	1994-01-25	Shinetsu Chemical Co	Method of preventing polymer scale formation

1989
- 1989-07-08 MX MX017122A patent/MX170464B/es unknown
- 1989-08-04 CZ CS894670A patent/CZ467089A3/cs unknown
- 1989-08-09 ZA ZA896061A patent/ZA896061B/xx unknown
- 1989-08-15 NO NO893267A patent/NO172988C/no unknown
- 1989-08-15 AU AU39949/89A patent/AU612883B2/en not_active Ceased
- 1989-08-15 IL IL91313A patent/IL91313A0/xx not_active IP Right Cessation
- 1989-08-16 RO RO141301A patent/RO105288B1/ro unknown
- 1989-08-17 BG BG089564A patent/BG51355A3/bg unknown
- 1989-08-17 NZ NZ230341A patent/NZ230341A/xx unknown
- 1989-08-17 YU YU161689A patent/YU47141B/sh unknown
- 1989-08-17 DD DD331876A patent/DD300292A7/de unknown
- 1989-08-17 EG EG40489A patent/EG18973A/xx active
- 1989-08-18 HU HU894244A patent/HU207105B/hu not_active IP Right Cessation
- 1989-08-18 DE DE68924572T patent/DE68924572T2/de not_active Expired - Fee Related
- 1989-08-18 PL PL89281088A patent/PL161850B1/pl unknown
- 1989-08-18 FI FI893909A patent/FI96213C/fi not_active IP Right Cessation
- 1989-08-18 KR KR1019890011746A patent/KR900003213A/ko not_active Ceased
- 1989-08-18 PT PT91484A patent/PT91484B/pt not_active IP Right Cessation
- 1989-08-18 DK DK406789A patent/DK406789A/da not_active Application Discontinuation
- 1989-08-18 CN CN89106490A patent/CN1040596A/zh active Pending
- 1989-08-18 BR BR898904171A patent/BR8904171A/pt not_active Application Discontinuation
- 1989-08-18 GT GT198900046A patent/GT198900046A/es unknown
- 1989-08-18 CA CA000608837A patent/CA1330683C/fr not_active Expired - Fee Related
- 1989-08-18 RU SU894614857A patent/RU2019546C1/ru active
- 1989-08-18 EP EP89308416A patent/EP0358364B1/fr not_active Expired - Lifetime
- 1989-08-18 ES ES898902897A patent/ES2017406A6/es not_active Expired - Lifetime
- 1989-08-18 TR TR89/0777A patent/TR25533A/xx unknown
1990
- 1990-04-24 US US07/512,595 patent/US5034477A/en not_active Expired - Fee Related
- 1990-10-08 PH PH39066A patent/PH26835A/en unknown
1995
- 1995-12-08 GR GR950403472T patent/GR3018353T3/el unknown

Also Published As

Publication number	Publication date
CN1040596A (zh)	1990-03-21
KR900003213A (ko)	1990-03-26
FI96213C (fi)	1996-05-27
PT91484B (pt)	1995-08-09
IL91313A0 (en)	1990-03-19
GT198900046A (es)	1991-02-09
EG18973A (en)	1994-03-30
NZ230341A (en)	1990-08-28
ZA896061B (en)	1990-05-30
DD300292A7 (de)	1992-06-04
CA1330683C (fr)	1994-07-12
EP0358364A3 (fr)	1991-06-05
BG51355A3 (bg)	1993-04-15
US5034477A (en)	1991-07-23
NO893267D0 (no)	1989-08-15
BR8904171A (pt)	1990-04-10
EP0358364A2 (fr)	1990-03-14
GR3018353T3 (en)	1996-03-31
DK406789D0 (da)	1989-08-18
DE68924572D1 (de)	1995-11-23
FI893909L (fi)	1990-02-20
FI893909A0 (fi)	1989-08-18
RO105288B1 (ro)	1995-08-03
FI96213B (fi)	1996-02-15
HU207105B (en)	1993-03-01
ES2017406A6 (es)	1991-02-01
CZ467089A3 (en)	1995-11-15
EP0358364B1 (fr)	1995-10-18
DK406789A (da)	1990-02-20
YU161689A (en)	1991-04-30
DE68924572T2 (de)	1996-05-30
PL161850B1 (pl)	1993-08-31
AU3994989A (en)	1990-02-22
HUT51302A (en)	1990-04-28
NO893267L (no)	1990-02-20
AU612883B2 (en)	1991-07-18
TR25533A (tr)	1993-03-18
NO172988B (no)	1993-06-28
RU2019546C1 (ru)	1994-09-15
NO172988C (no)	1993-10-06
YU47141B (sh)	1995-01-31
MX170464B (es)	1993-08-23
PT91484A (pt)	1990-03-08

Publication	Publication Date	Title
EP0372996B1 (fr)	1995-02-15	Procédé pour empêcher la formation de dépôts de polyméres dans un réacteur de polymérisation
PH26835A (en)	1992-11-05	Method of preventing polymers scale formation
US5053466A (en)	1991-10-01	Method of preventing polymer scale deposition
HU216429B (hu)	1999-06-28	Polimer lerakódását meggátló készítmény, valamint eljárás polimer előállítására
KR100318351B1 (ko)	2002-03-20	중합체스케일방지제
EP0372968B1 (fr)	1994-11-02	Procédé pour empêcher la formation de dépôts de polyméres
US5298220A (en)	1994-03-29	Method of preventing polymer scale formation
US5292834A (en)	1994-03-08	Method of preventing polymer scale deposition
EP0138660B1 (fr)	1988-03-02	Procédé de protection contre la formation de croûtes en polymérisation de monomères insaturés
CN104011149B (zh)	2017-05-24	添加剂、包含它的组合物及其用途
US5098968A (en)	1992-03-24	Method of preventing polymer scale deposition
EP0467311B1 (fr)	1996-03-06	Agent pour empêcher la formation d'encroûtement de polymères et un procédé pour empêcher la formation d'encroûtement utilisant cet agent
US5597878A (en)	1997-01-28	Process of producing vinyl chloride polymer
US5244986A (en)	1993-09-14	Method of preventing polymer scale deposition
JPH0617367B2 (ja)	1994-03-09	重合体スケールの付着防止方法
KR100336799B1 (ko)	2002-11-23	중합반응기의스케일부착방지용조성물및이의제조방법
EP0458267B1 (fr)	1994-10-26	Méthode pour empêcher la déposition d'incrustations de polymère
JPH02117901A (ja)	1990-05-02	重合体スケールの付着防止方法
JPH0617368B2 (ja)	1994-03-09	重合体スケールの付着防止方法
EP0473836A1 (fr)	1992-03-11	Procédé pour empêcher la formation de dépôts de polymères
JPH0655769B2 (ja)	1994-07-27	重合体スケールの付着防止方法
JPH0333180A (ja)	1991-02-13	重合体スケールの防止剤およびそれでコーティングされた重合用反応器
JPH08311109A (ja)	1996-11-26	重合体スケール付着防止剤及びそれを使用する重合体の製造方法
JPH0987304A (ja)	1997-03-31	重合体スケール付着防止剤及びそれを使用する重合体の製造方法
JPH0617366B2 (ja)	1994-03-09	重合体スケールの付着防止方法