PH12018501689B1 - Sulfuration treatment method, sulfide production method, and hydrometallurgical process for nickel oxide ore - Google Patents
Sulfuration treatment method, sulfide production method, and hydrometallurgical process for nickel oxide oreInfo
- Publication number
- PH12018501689B1 PH12018501689B1 PH12018501689A PH12018501689A PH12018501689B1 PH 12018501689 B1 PH12018501689 B1 PH 12018501689B1 PH 12018501689 A PH12018501689 A PH 12018501689A PH 12018501689 A PH12018501689 A PH 12018501689A PH 12018501689 B1 PH12018501689 B1 PH 12018501689B1
- Authority
- PH
- Philippines
- Prior art keywords
- sulfuric acid
- acidic solution
- acid acidic
- added
- nickel
- Prior art date
Links
- 238000005987 sulfurization reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000009854 hydrometallurgy Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910000480 nickel oxide Inorganic materials 0.000 title 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 title 1
- 230000019086 sulfide ion homeostasis Effects 0.000 title 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 12
- 239000003929 acidic solution Substances 0.000 abstract 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 239000007789 gas Substances 0.000 abstract 4
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 abstract 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 101100243022 Mus musculus Pcnt gene Proteins 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/11—Sulfides; Oxysulfides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Provided is a method with which it is possible, when causing a sulfuration reaction to occur from a sulfuric acid acidic solution containing at least nickel through use of a sulfuration agent and generating a nickel sulfide, to suitably control the grain size of the generated sulfide while maintaining high reaction efficiency. The sulfuration treatment method according to the present invention comprises supplying a sulfuric acid acidic solution that contains nickel to a reactor, adding hydrogen sulfide gas to the sulfuric acid acidic solution, and generating nickel sulfide, wherein unreacted gas among the hydrogen sulfide gas added to the sulfuric acid acidic solution is recovered, sodium hydroxide is added to the recovered hydrogen sulfide gas, sodium hydrosulfide is generated, and the resulting solution of sodium hydrosulfide is added to sulfuric acid acidic solution. At this time, when the sodium hydrosulfide solution is added, the grain size of the generated nickel sulfide is set to 50 æm or higher by 50 pcnt particle size (D50) by controlling the amount of sodium hydrosulfide solution added to the reactor to which the sulfuric acid acidic solution is supplied.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016024712A JP6213586B2 (en) | 2016-02-12 | 2016-02-12 | Sulfidation treatment method, sulfide production method, and nickel oxide ore hydrometallurgy method |
| PCT/JP2017/003684 WO2017138421A1 (en) | 2016-02-12 | 2017-02-02 | Sulfuration treatment method, sulfide production method, and wet smelting method for nickel oxide ore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PH12018501689A1 PH12018501689A1 (en) | 2019-05-27 |
| PH12018501689B1 true PH12018501689B1 (en) | 2022-04-06 |
Family
ID=59563555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PH12018501689A PH12018501689B1 (en) | 2016-02-12 | 2018-08-08 | Sulfuration treatment method, sulfide production method, and hydrometallurgical process for nickel oxide ore |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6213586B2 (en) |
| AU (1) | AU2017218246B2 (en) |
| CU (1) | CU20180089A7 (en) |
| PH (1) | PH12018501689B1 (en) |
| WO (1) | WO2017138421A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019172392A1 (en) * | 2018-03-07 | 2019-09-12 | 住友金属鉱山株式会社 | METHOD FOR PRODUCING Ni/Co SULFIDE AND SYSTEM FOR STABILIZING IRON GRADE |
| JP7035735B2 (en) * | 2018-04-03 | 2022-03-15 | 住友金属鉱山株式会社 | Method for producing nickel-cobalt mixed sulfide from low nickel grade oxide ore |
| JP7196630B2 (en) * | 2019-01-22 | 2022-12-27 | 住友金属鉱山株式会社 | Method and equipment for recovering valuable metals from aqueous sulfuric acid solution |
| CN110127629B (en) * | 2019-04-25 | 2020-11-17 | 南京聚拓化工科技有限公司 | Device and process for preparing sulfuric acid from sulfide by wet process |
| JP7293873B2 (en) * | 2019-05-30 | 2023-06-20 | 住友金属鉱山株式会社 | Method for producing nickel sulfide, hydrometallurgical method for nickel oxide ore |
| JP7355186B1 (en) | 2022-08-29 | 2023-10-03 | 住友金属鉱山株式会社 | Particle size control method for nickel-cobalt mixed sulfide |
| JP7533807B1 (en) | 2023-02-13 | 2024-08-14 | 三菱マテリアル株式会社 | METHOD AND APPARATUS FOR RECOVERING METALS |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5506136B2 (en) * | 2006-12-25 | 2014-05-28 | 住友金属鉱山株式会社 | Method for chlorine leaching of mixed sulfides containing nickel and cobalt |
| JP5435058B2 (en) * | 2012-03-06 | 2014-03-05 | 住友金属鉱山株式会社 | Neutralization treatment method and neutralization treatment plant |
| JP5807689B2 (en) * | 2014-01-28 | 2015-11-10 | 住友金属鉱山株式会社 | Sulfide production equipment and method |
-
2016
- 2016-02-12 JP JP2016024712A patent/JP6213586B2/en active Active
-
2017
- 2017-02-02 CU CUP2018000089A patent/CU20180089A7/en unknown
- 2017-02-02 WO PCT/JP2017/003684 patent/WO2017138421A1/en not_active Ceased
- 2017-02-02 AU AU2017218246A patent/AU2017218246B2/en active Active
-
2018
- 2018-08-08 PH PH12018501689A patent/PH12018501689B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP6213586B2 (en) | 2017-10-18 |
| PH12018501689A1 (en) | 2019-05-27 |
| AU2017218246A1 (en) | 2018-08-23 |
| AU2017218246B2 (en) | 2019-01-31 |
| JP2017141499A (en) | 2017-08-17 |
| WO2017138421A1 (en) | 2017-08-17 |
| CU20180089A7 (en) | 2018-10-04 |
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