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PE20220205A1 - SYSTEMS AND METHODS TO RECOVER LITHIUM FROM BRINE - Google Patents

SYSTEMS AND METHODS TO RECOVER LITHIUM FROM BRINE

Info

Publication number
PE20220205A1
PE20220205A1 PE2021001898A PE2021001898A PE20220205A1 PE 20220205 A1 PE20220205 A1 PE 20220205A1 PE 2021001898 A PE2021001898 A PE 2021001898A PE 2021001898 A PE2021001898 A PE 2021001898A PE 20220205 A1 PE20220205 A1 PE 20220205A1
Authority
PE
Peru
Prior art keywords
lithium
evaporation
systems
methods
precipitation
Prior art date
Application number
PE2021001898A
Other languages
Spanish (es)
Inventor
Amit Patwardhan
Teague Egan
Original Assignee
Energy Exploration Tech Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Exploration Tech Inc filed Critical Energy Exploration Tech Inc
Publication of PE20220205A1 publication Critical patent/PE20220205A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/14—Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24—Binding; Briquetting ; Granulating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/06—Sulfates; Sulfites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00—Halides of sodium, potassium or alkali metals in general
    • C01D3/04—Chlorides
    • C01D3/06—Preparation by working up brines; seawater or spent lyes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/26—Magnesium halides
    • C01F5/30—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/38—Magnesium nitrates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/40—Magnesium sulfates
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

Sistemas y metodos que usan evaporacion solar para preconcentrar salmueras que contienen litio a o cerca de una saturacion de litio, seguida por procesos de separacion para separar el litio de las impurezas. Una corriente de impureza separada se recicla a un punto en la secuencia de evaporacion donde las condiciones son favorables para su precipitacion y remocion o se coloca en un estanque de evaporacion separado o se reinyecta bajo tierra, en tanto que una corriente de impureza inferior se transfiere a una o mas de la ubicacion de remocion, a un estanque posterior en la secuencia, o a una planta de litio o instalacion de concentracion. Entonces puede tener lugar una concentracion adicional de litio por evaporacion debido a que se remueven las impurezas, eliminando de este modo las perdidas de litio debido a la coprecipitacion y logrando concentraciones significativamente mayores de litio.Systems and methods that use solar evaporation to preconcentrate lithium-containing brines at or near lithium saturation, followed by separation processes to separate lithium from impurities. A separated impurity stream is either recycled to a point in the evaporation sequence where conditions are favorable for its precipitation and removal or placed in a separate evaporation pond or reinjected underground, while a lower impurity stream is transferred to one or more of the removal location, to a later pond in the sequence, or to a lithium plant or concentration facility. Further concentration of lithium by evaporation can then take place as impurities are removed, thereby eliminating lithium losses due to co-precipitation and achieving significantly higher concentrations of lithium.

PE2021001898A 2020-05-12 2021-05-12 SYSTEMS AND METHODS TO RECOVER LITHIUM FROM BRINE PE20220205A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US202063023528P 2020-05-12 2020-05-12
PCT/US2021/032027 WO2021231597A1 (en) 2020-05-12 2021-05-12 Systems and methods for recovering lithium from brines

Publications (1)

Publication Number Publication Date
PE20220205A1 true PE20220205A1 (en) 2022-02-01

Family

ID=78511805

Family Applications (1)

Application Number Title Priority Date Filing Date
PE2021001898A PE20220205A1 (en) 2020-05-12 2021-05-12 SYSTEMS AND METHODS TO RECOVER LITHIUM FROM BRINE

Country Status (9)

Country Link
EP (1) EP3947756A4 (en)
CN (1) CN113924375B (en)
AU (1) AU2021254665B2 (en)
CA (1) CA3136247C (en)
IL (1) IL287465B2 (en)
JO (1) JOP20210311A1 (en)
MX (1) MX2021013733A (en)
PE (1) PE20220205A1 (en)
WO (1) WO2021231597A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12391566B2 (en) 2020-08-21 2025-08-19 Schlumberger Technology Corporation Lithium extraction improvements
US20240226813A9 (en) * 2021-02-16 2024-07-11 Energy Exploration Technologies, Inc. Polymeric materials and methods for selective ion separation or transport
WO2023215353A1 (en) * 2022-05-03 2023-11-09 Schlumberger Technology Corporation Impurity control in lithium recovery
US20230373803A1 (en) * 2022-05-20 2023-11-23 Schlumberger Technology Corporation Lithium recovery from precipitated solids
CN115650476B (en) * 2022-09-30 2025-07-29 广东邦普循环科技有限公司 Filter device convenient for automatically replacing filter membrane for extracting lithium from salt lake brine by membrane method
US12421137B2 (en) 2022-12-07 2025-09-23 Schlumberger Technology Corporation Hydrocarbon and sulfide removal in direct aqueous extraction
WO2024249270A1 (en) * 2023-05-26 2024-12-05 Energy Exploration Technologies, Inc. Reagent compositions, apparatus and methods for extracting lithium from mixed salts
CN120230923A (en) * 2025-05-29 2025-07-01 河南中鑫新材料有限公司 A method for extracting lithium from pyroxenite

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IL118655A0 (en) * 1995-07-18 1996-10-16 Tarim Associates For Scient Mi Process for recovery of lithium and other metals and salts from brines
US6921522B2 (en) * 1998-07-16 2005-07-26 Chemetall Foote Corporation Production of lithium compounds directly from lithium containing brines
WO2010006366A1 (en) * 2008-07-18 2010-01-21 Rincon Lithium Limited A process for recovering lithium from a brine
JP5556450B2 (en) * 2010-07-02 2014-07-23 パナソニック株式会社 Rotary compressor
AU2011236094B2 (en) * 2011-01-20 2012-11-29 Rockwood Lithium Inc. Production of high purity lithium compounds directly from lithium containing brines
JP5791917B2 (en) * 2011-02-23 2015-10-07 Jx日鉱日石金属株式会社 Lithium recovery method
US9994930B2 (en) * 2011-09-15 2018-06-12 Orocobre Limited Process for producing lithium carbonate from concentrated lithium brine
AR083538A1 (en) * 2011-10-24 2013-03-06 Minera Exar S A HIGH PURITY LITHIUM CARBONATE PRODUCTION BATTERY DEGREE FROM NATURAL OR INDUSTRIAL SALMUERAS
WO2014098357A1 (en) * 2012-12-21 2014-06-26 재단법인 포항산업과학연구원 Method for extracting lithium from solution containing lithium
JP6681975B2 (en) * 2015-08-28 2020-04-15 アルベマール・コーポレーシヨン Process for recovering lithium valuables from lithium-containing brine
US11920211B2 (en) * 2017-06-26 2024-03-05 Daniel Ernesto Galli Method for obtaining concentrated brine of minimum impurity content from brine found in natural salt flats and salt marshes, said method having minimum environmental impact and maximum lithium recovery
CN111526936A (en) 2017-12-15 2020-08-11 莫纳什大学 Metal organic framework film
CN110606499A (en) * 2018-06-15 2019-12-24 上海东硕环保科技股份有限公司 Lithium-containing salt lake brine lithium extraction combined device
CN109748298A (en) 2019-02-23 2019-05-14 温州大学新材料与产业技术研究院 A method and device for spontaneous and selective separation of magnesium-enriched lithium from lithium-containing brine

Also Published As

Publication number Publication date
IL287465B2 (en) 2024-03-01
MX2021013733A (en) 2021-12-10
CA3136247C (en) 2022-12-20
AU2021254665A1 (en) 2021-12-02
IL287465B1 (en) 2023-11-01
WO2021231597A1 (en) 2021-11-18
EP3947756A4 (en) 2022-07-06
EP3947756A1 (en) 2022-02-09
JOP20210311A1 (en) 2023-01-30
CN113924375A (en) 2022-01-11
IL287465A (en) 2021-12-01
CN113924375B (en) 2023-04-04
CA3136247A1 (en) 2021-11-12
AU2021254665B2 (en) 2022-04-21
WO2021231597A9 (en) 2022-01-20

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