[go: up one dir, main page]

PE20181185A1 - Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio - Google Patents

Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio

Info

Publication number
PE20181185A1
PE20181185A1 PE2018001079A PE2018001079A PE20181185A1 PE 20181185 A1 PE20181185 A1 PE 20181185A1 PE 2018001079 A PE2018001079 A PE 2018001079A PE 2018001079 A PE2018001079 A PE 2018001079A PE 20181185 A1 PE20181185 A1 PE 20181185A1
Authority
PE
Peru
Prior art keywords
potassium
thiosulfate
optionally
sulfur
bisulfite
Prior art date
Application number
PE2018001079A
Other languages
English (en)
Inventor
Michael Massoud Hojjatie
Constance Lynn Frank Lockhart
Alexandros Dimitriadis
Mark P Clarkson
Harry Charles Kominski
Nicholas S Shult
Adam T Goldsmith
Cauwenbergh Jeroen Van
Original Assignee
Tessenderlo Kerley Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tessenderlo Kerley Inc filed Critical Tessenderlo Kerley Inc
Publication of PE20181185A1 publication Critical patent/PE20181185A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/64Thiosulfates; Dithionites; Polythionates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1481Removing sulfur dioxide or sulfur trioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/62Methods of preparing sulfites in general
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/306Alkali metal compounds of potassium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/606Carbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/608Sulfates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10Inorganic absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/204Inorganic halogen compounds
    • B01D2257/2045Hydrochloric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/80Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Gas Separation By Absorption (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

La invencion se refiere a un proceso para la preparacion de tiosulfato de potasio, sulfito de potasio o bisulfito de potasio, que comprende las siguientes etapas: Etapa (1a): la provision de una solucion de carbonato de potasio o hidroxido de potasio para neutralizar componentes formadores de acido, tal como mediante la disolucion de SO2 o H2S; Etapa (1b): la provision de una solucion de contacto de SO2, que contiene por lo menos algo de sulfito de potasio o bisulfito de potasio o tiosulfato de potasio; Etapa (2): la provision de gas SO2; Etapa (3): la reaccion de estos para absorber el gas SO2 y formar una mezcla de reaccion intermedia que comprende sulfito de potasio, o bisulfito de potasio o una de sus mezclas, y en forma opcional, la recuperacion del sulfito de potasio, o bisulfito de potasio o una de sus mezclas, y/u opcionalmente, el uso de las etapas 4 y 5; Etapa (4): la adicion de compuesto que contiene azufre o sulfuro, que contiene azufre que tiene el estado de oxidacion de 0, -2 o de entre 0 y -2, a la mezcla de reaccion, y en forma opcional, hidroxido de potasio o carbonato de potasio, y la reaccion de la mezcla en condiciones adecuadas para formar tiosulfato de potasio; y Etapa (5): la recuperacion del tiosulfato de potasio, y en forma opcional, la concentracion del tiosulfato de potasio.
PE2018001079A 2015-12-30 2016-12-16 Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio PE20181185A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562273389P 2015-12-30 2015-12-30
US15/380,702 US10005667B2 (en) 2015-12-30 2016-12-15 Sulfur dioxide scrubbing system and process for producing potassium products

Publications (1)

Publication Number Publication Date
PE20181185A1 true PE20181185A1 (es) 2018-07-20

Family

ID=59225327

Family Applications (1)

Application Number Title Priority Date Filing Date
PE2018001079A PE20181185A1 (es) 2015-12-30 2016-12-16 Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio

Country Status (18)

Country Link
US (2) US10005667B2 (es)
EP (1) EP3397793B1 (es)
KR (1) KR102251321B1 (es)
CN (2) CN117228639A (es)
AU (1) AU2016382880B2 (es)
BR (2) BR122022000451B1 (es)
CA (1) CA3007484C (es)
CL (1) CL2018001718A1 (es)
CO (1) CO2018007613A2 (es)
EA (1) EA037223B1 (es)
ES (1) ES2981003T3 (es)
HU (1) HUE066700T2 (es)
MX (1) MX370761B (es)
PE (1) PE20181185A1 (es)
PL (1) PL3397793T3 (es)
UA (1) UA126145C2 (es)
WO (1) WO2017116773A1 (es)
ZA (1) ZA201803423B (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10005667B2 (en) * 2015-12-30 2018-06-26 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
EP3208237A1 (en) * 2016-02-18 2017-08-23 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
WO2021003479A1 (en) * 2019-07-03 2021-01-07 Tessenderlo Kerley, Inc. Products prepared from waste gas streams containing h 2s, so 2, and/or nh 3
CN110790235B (zh) * 2019-11-15 2021-05-25 浙江大洋生物科技集团股份有限公司 作为有机合成副产物的含氟氯化钾的综合利用方法
CN111003692B (zh) * 2019-12-13 2020-09-08 南京工业大学 一种二氧化硫资源化回用系统及方法
CN111039309A (zh) * 2019-12-31 2020-04-21 中船重工(邯郸)派瑞特种气体有限公司 一种分离硫酸氢钾和硫酸钾混合物的装置及方法
US11214489B1 (en) * 2020-11-28 2022-01-04 Ceres Technology, LLC Crossflow scrubbing method and apparatus to produce a product such as potassium thiosulfate or ammonium thiosulfate
WO2023057397A1 (en) 2021-10-04 2023-04-13 Tessenderlo Group Nv Methods for the production of thiosulfates via salt metathesis

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1570253A (en) * 1925-01-13 1926-01-19 Grasselli Chemical Co Process for the manufacture of sodium thiosulphate
US1760137A (en) * 1925-12-05 1930-05-27 Grasselli Chemical Co Process for the production of sodium thiosulphate
GB359989A (en) * 1930-05-24 1931-10-26 Ig Farbenindustrie Ag Improvements in the manufacture and production of sulphates from water-soluble sulphites or bisulphites
US2219258A (en) * 1939-12-05 1940-10-22 American Cyanamid Co Solid ammonium thiosulphate
DE1186451B (de) 1963-08-14 1965-02-04 Basf Ag Verfahren zur Herstellung von festem Kaliumdisulfit
CA988679A (en) * 1972-02-02 1976-05-11 Consolidation Coal Company Treatment of gases containing sulfur dioxide
DE2623057A1 (de) * 1975-05-27 1976-12-09 Continental Oil Co Regenerierverfahren und vorrichtung zum entfernen von so tief 2 aus einem so tief 2-haltigen gas
US4008310A (en) * 1975-05-27 1977-02-15 Continental Oil Company Regenerative sulfur dioxide scrubbing system
US4122148A (en) * 1976-04-20 1978-10-24 Davy Powergas Inc. Sulfur dioxide removal process
JPS5468775A (en) * 1977-11-11 1979-06-02 Kureha Chem Ind Co Ltd Treating method for exhaust gas containing nitrogen oxides and sulfur oxides
US4208395A (en) * 1978-12-05 1980-06-17 Continental Oil Company Removal of sulfur dioxide from flue gas
JPS58174223A (ja) * 1982-04-08 1983-10-13 Mitsubishi Heavy Ind Ltd 排ガス処理方法
FR2534571A1 (fr) 1982-10-19 1984-04-20 Magyar Tudomanyos Akademia Procede et equipement pour la production de sulfites de sodium et de potassium
UST103501I4 (en) * 1982-11-24 1983-10-04 Dewatering of flue gas desulfurization sulfite solids
US4976937A (en) * 1990-01-08 1990-12-11 Dravo Lime Company Sulfur dioxide removal from flue gases with sulfite oxidation inhibition
US5266285A (en) * 1992-04-13 1993-11-30 Southern Indiana Gas And Electric Company Sodium-enhanced lime scrubbing method for removing sulfur dioxide from gaseous streams
US5567406A (en) 1995-05-11 1996-10-22 Zeller, Iii; Robert L. Manufacturing clear potassium sulfite
TW358038B (en) * 1997-06-13 1999-05-11 Von Roll Umwelttechnik Ag Process for removing sulfur dioxide from flue gasses
US5944868A (en) 1998-01-28 1999-08-31 Tessenderlo Kerley, Inc. Production of liquid fertilizers by ion exchange
US8034318B1 (en) 2010-04-21 2011-10-11 Tessenderlo Kerley, Inc. Process for preparation of calcium thiosulfate liquid solution from lime, sulfur, and sulfur dioxide
PL2693868T3 (pl) 2011-04-05 2017-09-29 Tessenderlo Kerley, Inc. Ciekłe siarczyn potasu/wodorosiarczyn potasu (ks/kbs) jako nawozy
CN102423612B (zh) 2011-08-07 2014-05-07 宁波金远东工业科技有限公司 一种利用工业烟气生产硫代硫酸盐及回收二氧化碳的方法
CN202482062U (zh) * 2012-01-20 2012-10-10 鞍钢集团工程技术有限公司 一种由脱硫废液提取硫代硫酸铵、硫氰酸铵的装置
US10005667B2 (en) * 2015-12-30 2018-06-26 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
EP3208237A1 (en) * 2016-02-18 2017-08-23 Tessenderlo Kerley, Inc. Sulfur dioxide scrubbing system and process for producing potassium products
JP2019174223A (ja) * 2018-03-28 2019-10-10 三菱重工業株式会社 温度モニタ装置、温度モニタ方法、及び複合材の製造方法

Also Published As

Publication number Publication date
ES2981003T3 (es) 2024-10-04
HUE066700T2 (hu) 2024-08-28
KR102251321B1 (ko) 2021-05-12
CL2018001718A1 (es) 2018-09-21
US10472238B2 (en) 2019-11-12
CN117228639A (zh) 2023-12-15
CO2018007613A2 (es) 2018-07-31
BR112018013555B1 (pt) 2022-10-04
AU2016382880B2 (en) 2020-04-16
ZA201803423B (en) 2022-12-21
KR20180100056A (ko) 2018-09-06
MX2018008055A (es) 2018-11-29
US10005667B2 (en) 2018-06-26
EP3397793A4 (en) 2019-05-22
EP3397793B1 (en) 2024-03-13
CA3007484A1 (en) 2017-07-06
UA126145C2 (uk) 2022-08-25
MX370761B (es) 2019-12-13
US20180251375A1 (en) 2018-09-06
CN108495954A (zh) 2018-09-04
BR122022000451B1 (pt) 2022-12-20
EA037223B1 (ru) 2021-02-20
WO2017116773A1 (en) 2017-07-06
EA201891398A1 (ru) 2018-12-28
CA3007484C (en) 2022-04-19
EP3397793A1 (en) 2018-11-07
BR112018013555A2 (pt) 2018-12-04
US20170190575A1 (en) 2017-07-06
PL3397793T3 (pl) 2024-07-22
AU2016382880A1 (en) 2018-06-14

Similar Documents

Publication Publication Date Title
PE20181185A1 (es) Sistema de depuracion de dioxido de azufre y proceso para la produccion de productos de potasio
CL2019001213A1 (es) Procedimiento para la recuperación de litio.
PL420589A1 (pl) Sposób odzyskiwania ditlenku węgla do wzbogacania strumieni gazowych stosowanych w wytwarzaniu węglanu sodu i wodorowęglanu sodu metodą Solvaya
AR103239A1 (es) Proceso para producir carbonato / bicarbonato de sodio
CL2011000902A1 (es) Procedimiento para preparar tiosulfato de calcio que comprende hacer reaccionar una suspension que contiene un compuesto de calcio y azufre con dioxido de azufre para formar el tiosulfato de calcio y posteriormente recuperarlo.
CO2018003666A2 (es) Absorbente para la remoción selectiva de sulfuro de hidrógeno
CL2018000419A1 (es) Formación de complejos y remoción de mercurio de los sistemas de desulfuración de gases de combustión.
SA518391338B1 (ar) عملية لإزالة مركبات الكبريت من تيارات عملية
FI20165866L (fi) Menetelmä ja laitteisto kemikaalien talteenottamiseksi alkalisesta ligniinimateriaalista
BR112016018358A2 (pt) Composição reativa, e, processo
AR100063A1 (es) Depresión de cobre y sulfuros de hierro en circuitos de flotación de molibdenita
CL2012001382A1 (es) Proceso de lixiviacion de oro a partir de una mezcla que contiene azufre elemental y oro que comprende contactar dicha mezcla con solucion acuosa de hidroxido, reaccionar dicho hidroxido y azufre elemental y luego lixiviar oro mediante el tiosulfato producido.
ES2656223T3 (es) Eliminación de sulfuro de hidrógeno en amoniaco acuoso
IN2014KN02582A (es)
AR080415A1 (es) Metodo y composicion para recuperacion mejorada de petroleo
MX2016000390A (es) Proceso para fabricar haloacetamidas.
MX2018005879A (es) Proceso para reprocesar acido alcansulfonico.
MX2021006220A (es) Procesos para producir trifluoroyodometano de alta pureza.
AR094523A1 (es) Proceso, método y sistema para separar mercurio de fluidos
AR107204A1 (es) Sistema de depuración de dióxido de azufre y proceso para la producción de productos de potasio
BR112017023839A2 (pt) métodos para purificar 1,4-diaminobutano
ZA202104452B (en) Method for producing sodium sulfite by removing sulfur from sulfur-containing flue gas using industrial alkali residue containing arsenic
CL2018002800A1 (es) Eliminación de dióxido de azufre del gas residual
ES2442244B1 (es) Sistema microaerobio para controlar la concentración de sulfuro de hidrógeno en reactores de biometanización
FR3041658B1 (fr) Procede de production de l-methionine