PE20000275A1 - Proceso mejorado de intercambio y regeneracion de iones para la separacion y el retiro de iones de hierro (iii) de soluciones acuosas de acido sulfurico que contienen iones metalicos - Google Patents
Proceso mejorado de intercambio y regeneracion de iones para la separacion y el retiro de iones de hierro (iii) de soluciones acuosas de acido sulfurico que contienen iones metalicosInfo
- Publication number
- PE20000275A1 PE20000275A1 PE1999000026A PE00002699A PE20000275A1 PE 20000275 A1 PE20000275 A1 PE 20000275A1 PE 1999000026 A PE1999000026 A PE 1999000026A PE 00002699 A PE00002699 A PE 00002699A PE 20000275 A1 PE20000275 A1 PE 20000275A1
- Authority
- PE
- Peru
- Prior art keywords
- ions
- iron
- iii
- sulfuric acid
- solid phase
- Prior art date
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title abstract 8
- -1 IRON (III) IONS Chemical class 0.000 title abstract 5
- 150000001455 metallic ions Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000007864 aqueous solution Substances 0.000 title 1
- 238000005342 ion exchange Methods 0.000 title 1
- 230000008929 regeneration Effects 0.000 title 1
- 238000011069 regeneration method Methods 0.000 title 1
- 238000000926 separation method Methods 0.000 title 1
- 239000007790 solid phase Substances 0.000 abstract 6
- 150000002500 ions Chemical class 0.000 abstract 4
- 239000007791 liquid phase Substances 0.000 abstract 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- LBFUKZWYPLNNJC-UHFFFAOYSA-N cobalt(ii,iii) oxide Chemical compound [Co]=O.O=[Co]O[Co]=O LBFUKZWYPLNNJC-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- XQRLCLUYWUNEEH-UHFFFAOYSA-L diphosphonate(2-) Chemical group [O-]P(=O)OP([O-])=O XQRLCLUYWUNEEH-UHFFFAOYSA-L 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/12—Compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/06—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing cationic exchangers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S204/00—Chemistry: electrical and wave energy
- Y10S204/13—Purification and treatment of electroplating baths and plating wastes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Removal Of Specific Substances (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
SE REFIERE A UN PROCESO QUE COMPRENDE : i) PONER EN CONTACTO UNA SOLUCION ACUOSA DE ACIDO SULFURICO QUE CONTIENE IONES METALICOS, DE PREFERENCIA IONES HIERRO (III) Y IONES DE VALENCIA MENOR DE +3 TALES COMO MANGANESO (II), COBRE (II) Y COBALTO (II), CON UN COPOLIMERO DEGRADADO INSOLUBLE CON MULTIPLES GRUPOS SUSPENDIDOS DIFOSFONATO GEMINAL DE FORMULA CH(PO3R2)2 o -C(PO3R2)2-, EN DONDE R ES UN CATION MONOVALENTE O DIVALENTE COMO HIDROGENO, AMONIO O UN CATION DE METAL ALCALINO; ii) MANTENER (i) EL TIEMPO SUFICIENTE PARA FORMAR IONES HIERRO (III) LIGADO DE FASE SOLIDA Y UNA FASE LIQUIDA ACUOSA QUE CONTIENE ACIDO SULFURICO Y LOS IONES DE VALENCIA MENOR DE +3; iii) SEPARAR LA FASE SOLIDA Y LA FASE LIQUIDA; iv) PONER EN CONTACTO LA FASE SOLIDA CON UNA SOLUCION REDUCTORA ACUOSA LIBRE DE SO2 LA CUAL CONTIENE DE 0,1 M A 6 M DE ACIDO SULFURICO Y IONES COBRE (I) SUFICIENTE PARA REDUCIR LOS IONES HIERRO (III) LIGADO DE FASE SOLIDA A IONES HIERRO (II) PARA FORMAR UNA SEGUNDA MEZCLA DE FASE SOLIDA/LIQUIDA; v) MANTENER LA MEZCLA OBTENIDA EN (iv) A UNA TEMPERATURA ENTRE 65°C Y 95°C EN TIEMPO SUFICIENTE PARA FORMAR UNA FASE LIQUIDA DE SOLUCION REDUCTORA ACUOSA QUE TIENE IONES HIERRO (II) Y UN MEDIO INTERCAMBIADOR DE IONES DE FASE SOLIDA REGENERADO; vi) SEPARAR LA FASE LIQUIDA DEL MEDIO INTERCAMBIADOR
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/019,677 US5948264A (en) | 1998-02-06 | 1998-02-06 | Ion exchange and regeneration process for separation and removal of iron (III) ions from aqueous sulfuric acid metal ion-containing solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PE20000275A1 true PE20000275A1 (es) | 2000-04-12 |
Family
ID=21794466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PE1999000026A PE20000275A1 (es) | 1998-02-06 | 1999-01-12 | Proceso mejorado de intercambio y regeneracion de iones para la separacion y el retiro de iones de hierro (iii) de soluciones acuosas de acido sulfurico que contienen iones metalicos |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5948264A (es) |
| AU (1) | AU1909699A (es) |
| PE (1) | PE20000275A1 (es) |
| WO (1) | WO1999040033A1 (es) |
| ZA (1) | ZA99144B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU758853B2 (en) | 1998-07-02 | 2003-04-03 | Arch Development Corporation | Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same |
| US6232353B1 (en) * | 1998-07-02 | 2001-05-15 | Arch Development Corporation | Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same |
| US6514414B1 (en) | 2000-09-08 | 2003-02-04 | Clariant Finance (Bvi) Limited | Process for separation and removal of iron ions from basic zinc solution |
| MXPA02003701A (es) | 2001-04-17 | 2005-11-28 | Sbr Ventures Llc | Proceso para remover impurezas de hierro ferrico desde una solucion acuosa acidico usada en la extraccion electrolitica de cobre. |
| US6599414B1 (en) * | 2001-08-07 | 2003-07-29 | Cognis Corporation | Solvent extraction processes for metal recovery |
| US20110180470A1 (en) * | 2010-01-27 | 2011-07-28 | James Jeffrey Harris | Aqueous iron removal process and apparatus |
| RU2453368C1 (ru) * | 2011-02-14 | 2012-06-20 | Открытое акционерное общество "Акрон" | Способ сорбционного извлечения железа из растворов нитратных солей |
| MX2016011624A (es) | 2014-03-07 | 2016-12-14 | Basf Se | Metodos y sistemas para controlar la concentracion de impurezas metalicas durante los procesos metalurgicos. |
| US10208389B2 (en) | 2015-08-26 | 2019-02-19 | Basf Se | Methods and systems for reducing impurity metal from a refinery electrolyte solution |
| CN109778227B (zh) * | 2019-03-20 | 2020-11-24 | 北京航天国环技术有限公司 | 一种含铁废盐的处理方法 |
| EP4313868A4 (en) * | 2021-03-24 | 2025-04-23 | Electrasteel, Inc. | Ore dissolution and iron conversion system |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3224873A (en) * | 1963-02-25 | 1965-12-21 | Gen Mills Inc | Liquid-liquid recovery of copper values using alpha-hydroxy oximes |
| US3440036A (en) * | 1966-05-16 | 1969-04-22 | Nassau Smelting & Refining Co | Recovery of copper from copper-bearing solutions |
| CA902931A (en) * | 1970-03-11 | 1972-06-20 | H. Lucas Bernard | Copper extraction from ammoniacal solutions |
| US4167481A (en) * | 1975-03-19 | 1979-09-11 | Leuven Research & Development Vzw | Process for the removal of metals from solution |
| US4100043A (en) * | 1976-09-17 | 1978-07-11 | Amax Inc. | Atmospheric leach ion-exchange process for treating iron-containing nickel-copper matte |
| US4083758A (en) * | 1976-09-27 | 1978-04-11 | Criterion | Process for regenerating and for recovering metallic copper from chloride-containing etching solutions |
| US4272492A (en) * | 1979-05-31 | 1981-06-09 | Jensen Wayne H | Selective extraction and recovery of copper |
| SE420737B (sv) * | 1980-03-18 | 1981-10-26 | Mx Processer Reinhardt | Forfarande for extraktion av koppar ur en ammoniakalisk kopparlosning samt medel for utforande av forfarandet |
| US4329210A (en) * | 1980-03-28 | 1982-05-11 | Robert W. Becker | Method of regenerating etchant and recovering etched metal |
| JPS59162108A (ja) * | 1983-03-03 | 1984-09-13 | Tadao Nagai | 硫酸溶液の浄液法 |
| US4900522A (en) * | 1986-07-22 | 1990-02-13 | Amax Inc. | Separation of nickel and cobalt from sulfate solutions by solvent extraction |
| US5108615A (en) * | 1989-11-28 | 1992-04-28 | Bio-Recovery Systems, Inc. | Method for recovery of a metal ion from electroless plating solutions |
| US5112392A (en) * | 1991-06-21 | 1992-05-12 | Martin Marietta Energy Systems, Inc. | Recovery process for electroless plating baths |
| US5192418A (en) * | 1991-07-08 | 1993-03-09 | Bethlehem Steel Corporation | Metal recovery method and system for electroplating wastes |
| US5281631A (en) * | 1991-12-20 | 1994-01-25 | Arch Development Corp. | Phosphonic acid based ion exchange resins |
| KR100240470B1 (ko) * | 1993-04-22 | 2000-01-15 | 에모또 간지 | 주석도금액의회수재생방법 |
| IT1261515B (it) * | 1993-08-13 | 1996-05-23 | In Tec Italia Int Env Tech Srl | Procedimento per il recupero delle soluzioni di incisione dei metalli spente. |
| US5500126A (en) * | 1994-10-20 | 1996-03-19 | Rohm And Haas Company | Process for removal of metal ions from aqueous solutions |
| US5618851A (en) * | 1995-02-06 | 1997-04-08 | Arch Development Corp. | Grafted methylenediphosphonate ion exchange resins |
| US5582737A (en) * | 1995-11-07 | 1996-12-10 | Eichrom Industries, Inc. | Ion exchange and regeneration process for separation and removal of iron (III) ions from aqueous sulfuric acid metal ion-containing solutions |
-
1998
- 1998-02-06 US US09/019,677 patent/US5948264A/en not_active Expired - Lifetime
- 1998-12-11 WO PCT/US1998/026324 patent/WO1999040033A1/en not_active Ceased
- 1998-12-11 AU AU19096/99A patent/AU1909699A/en not_active Abandoned
-
1999
- 1999-01-08 ZA ZA9900144A patent/ZA99144B/xx unknown
- 1999-01-12 PE PE1999000026A patent/PE20000275A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999040033A1 (en) | 1999-08-12 |
| AU1909699A (en) | 1999-08-23 |
| US5948264A (en) | 1999-09-07 |
| ZA99144B (en) | 1999-07-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration | ||
| FD | Application declared void or lapsed |