LV11199B - Method for treating the fabric's materials and fabrics made from such materials - Google Patents

Abstract

Flame retardant cellulosic fabrics having reduced shrinkage are obtained by treatment of fabric with a tetrakis hydroxymethyl phosphonium compound or condensate and then curing with ammonia, followed by treatment involving reaction of the fabric with a non self-condensing methylolamide under aqueous acid conditions. The order of treatment can also be reversed.

Description

LV 11199

CnOCOB OEPAEOTKM TKAHM M TKAHb, OEPABOTAHHAfl 3TMM

CnOCOEOM

OnUCAHME

HacTOflLiele M3o6peTeHne othocmtch k cnoco6aM o6pa6oTKM τκθηθμ m, b ηθοτηοοτμ, κ cnocoSaM οδρββοτκΜ τκβΗβίί, o6pa6oTaHHbix θητμπμρθηομ.

XjionHaTo6yvia > KHbie τκθημ o6pa6aTWBaK > TCH aHTuriMpeHOM nocpeflCTBOM nponuTKM coeflMHeHMeM mm npeKOHfleHcaTOM TeTpa KMC (οκομμθτμγι) φοοφοΗΜΗ (THP) c nocneAyioii4eii TennoBOiS o6pa6oTKoiS oder aMMMaKOM. OflHaKO φΜ3ΜΗβΟ < Μβ CBOMCTBa Τ3ΚΜΧ ΤΚβΗβΜ Μ, B MaCTHOCTM, HecMMHaeMocTb m ycaflKa, 3aHacryK) yxyfliuaioTcn, mto orpaHMMUBaeT ncnonb30BaHne TaKMX TKaHeii b KaMecTBe He Tpe6yioinMX yxofla, Further preferably, noujMBa Offaly > Kflbi. BK)) Khom pernoHajībHOM nccjieflOBaTenbCKOM LļeHTpe 6bma npeAnpnH "Ta nonbīTKa cHsiTb yKa3aHHbie orpamineHHa nocpeflCTBOM o6pa6oTKM y > xe o6pa6oTaHHofi THP τκθημ cmojiom c nocneAy» omeM τβπ, ποΒΟΜ o6pa6oTKOM (PoynaHA μ M330H "TeKCTaiiJi pM3aM A * opH3Ji" 1977 οτρ. 365 - 71 n 721-8). ΠρβΑ-ΠΟΜβΗ Cnoeo6 Μ3ΓΟΤΟΒΛΘΗΜΛ 06pa60TaHH0M βΗΤΜΠΜρβΗΟΜ ΤΚΘΗΜ, o6 / iaAiLiLii τβιοκβ ynyHiueHHbiMM CBOMCTBaMM b sacTM npoMHocTn n yxoAa.

HacTOHinee Μ3θ6ρβτβΗΜβ HanpaeneHO Ha cnoco6 o6pa6oTKM the fabrics, npeAycMaTpMBaK) innPi o6pa6oTKy y > Ke npoiueAiiieii o6pa6oTKy b χοαθ nepBoro npoiļecca ΐ4β.ππκ) Π03Η0Μ the fabrics, npuneM nepebiM μπμ Βτοροίί npoijecc npeACTaBJipeT co6oū o6pa6oTKy TKaHU οοβΑΜΗβΗΜΘΜ μπμ κοηαθηοβτομ TeTpa KMC (OKCMMeTMJl) φθθφθΗΜΒ M nOCJieAyKJL4yK5 nOJlMMepM3ai4MIO, a Apyroii M3 yKa3aHHbix nepeoro μπμ BToporo npoLļeccoe npeACTaBnneT co6om nponMTKy tK3HM HecaMOKOHAeHCMpyK) LiļMMCfl OKCMMeTMJiaMMAOM c ΠΟ MeHbLUeM mepe AByMn OKCMMeTMJlbHblMM rpynnaMM, KOTOpbie MOryT 6blTb 3ΠΚΜΠΜρθΒ3ΗΗΝΜΜ c nocneAytoiAeM peaKLļneti tk3hm c yKa3aHHbiM οκομμθτμπβμμαομ b npncyTCTBMM BOflHoro solution of KucnoTbi, Further preferably, npn pH MeHbiue 3 1 b npeAnoMTMTejibHOM BapuaHTe cnoco6 o6pa6oTKM ίίοημ npeAycMaTpnBaeT nponnTKy coAepjKamen OTBep > KAeHHbiH ποηπΜβρ h npoiueAiiie o6pa6oTKy οοβΑΗΗβΗΗβΜ hah κοηαβηο3ΤΟΜ T EIPA KHC (οκοπΜβΤΜη) φοοφοΗΗΑ HecaMOKOHAeHCMpytOLAHMCii OKCHMeTMnaMHAOM c of MeHbLAeti mepe Abymes? i OKCUMeTMnbHbiMn rpynnaMH (KOTopbie Moryr 6biTb anKHAHpoBaHHbiMH) c nocneAyK) L4eii peaKiļneM τκβΗΗ c οκοημθτηαθμμαομ b npHcyTCTBHH βοαηογο solution of khcjiotn, nanpHMep, npn pH MeHbme 3B 3T0M npeAnoMTmenbHOM cnoco6e ncxoAHan cured Fabric coAep > KMT οτΒβρ > ΚΑβΗΗωίί nonuMep THP. Cured Fabric μοτκθτ 6brrb nponmaHa boahum paCTBOpOM COJ1H THP B CMeCH C COBMeCTHO K0HA6HCMpyeMblM ΟΟβΑΜΗβΗΜβΜ a30Ta, TaKMM CEC MenaMHH hah οκοΗ3ΤΗΑΜροΒ3ΗΗωίί MenaMHH hah MoneBHHa HAH paCTBOpOM ΠρβΚΟΗΑβΗΟΘΤΘ γΚ333ΗΗΟΗ ΟΟΠΜ Η ΟΟβΑΗΗβΗΗΑ Θ30ΤΘ HAH C pacTBopoM Coah THP hah of MeHbtneH mepe HACR / HHO HeiiTpanH30BaH0H Coah THP, Further preferably γηαροοκηοη THP c οοβΑΗΗβΗΗβΜ a30Ta hah 6e3 Hero c nocneAyKDiiiPi cywKOH nONHTaHHOH tk3hm h o6pa6oTKoii τθππομ η hah aMMMaKOM. B npeflnoMTUTenbHOM BapuaHTe TKaHb nponHTUBEtcA pacTBopo npeKOHAeHcaTa coah THP, HanpuMep, xnopnAa hah cynbφaτa, h MOMeBHHbi b MonnpHOM oTHOiueHMM MOMeBMHbi κ THP 0.05 - 0.8: 1, HanpuMep, 0.05 - 0.6: 1 HanpuMep KaK õncaHO b πθτθητθ CLIL N & 2 2983623 hah Ns 4078101, h o6pa6aTbiBaeTcn θμμηθκομ, Further preferably, Kak οπηοθηο b naTeHTax CLUA NfiNs 4,145,463, 4,468,026 hah 4494 951 Ποοηβ 3Toii o6pa6oTKM cured Fabric o6biHHO noABepraeTcn o6pa6oTKe οκοηαηροβθηηθμ nepeKHCbio BOAopoAa, npoMbiBaeTcn, HefiTpann3yeTca h CHoea npoMbiBaeTcn. Ποοηβ 3τογο TKaHb BbicyiunBaeTcn. 06pa6oTaHHaa τθκημ o6pa30M cured Fabric ο6μμηο οοΑβρκπτ 8-25% Further preferably 8-20% 14-20% cure and hah > KAeHHoro nonHMepa THP (ot EECA Heo6pa6oTaHHofi τκθηη) πρππβΜ 6oAee nencne τκβΗΗ οοΑβρχοτ 6onbuue nOAHMepa, ΗβΜ TfDKeAbie.

06pa6oTaHHaa THP TKaHb nponnTWBaeTcn boahhm pacTBopoM HecaMOKOHAeHcnpyKDLLlerocn OKCHMeTHAaMHAa c of MeHbLueu Mepe AByMa OKCHMeTHAbHbiMH rpynnaMH hah θΑΚΗηβφπροΜ 3Toro οοθαμηθημα. TaKHe oKCHMeTkinaMHAbi, κοτορωβ TaioKe H3BecTHbi KaK “pearHpy omHe cMOAbi”, o6biMHo HecaMOKOHAeHCnpytoTca b χοαθ hx headKLHH hah o6pa6oTKH c LlAAAtOA030H TK3HH. 3ΤΗ ΒβΙΑβΟΤΒβ KaK Πρ3ΒΗΑΟ Ηβ ΟΟΑβρΧΟΤ rpynn N -H, οαη3κο He6oAbLuoe κοαηηθοτβο t3khx rpynn Μθ > B npeAnoHTHTeAbHOM BapnaHTe sth οκοημθτηαβμηα αβααιοτοα OKCHMeTHAHpOBaHHblMH μΗΚΑΗΗβΟΚΗΜΗ ΜΟΗΘΒΗΗΘΜΗ HAH 0-aAKHAHpOBaHHblMH HX npOH3BOHb! MH. ΤθΚΗβ ΒβΙΑβΟΤΒΘ MOryT HMeTb φopMyAy Z - N (R1) - CO - N (R2) - Z, γαθ Ka > Kaan rpynna Z ηβααθτοα rpynnon CH2OH hah CH2OR, γαθ R - θακηα, 1 2

E.g. μθτηα c 1-6 aTOMaMH yrnepoAa a R h R - οοβμθοτηο o6pa3ytoT AByxBaneHTHyio 3ΑΗφ3ΤΗΜβο ^ ιο rpynny, KOTopan ΒΜβοτβ c Abymes θτομβμη 2 EN 11199 aaoTa m Kap6oHHAbHot4 rpynnofi o6paayeT Konbīļo 143 na ™, uiecTM mam CEMM aneMeHTOB. flByxBaneHTHafl an ^ aTHMecKaP rEncTo > κθτ μμθτβ 0opMyny -CR3R4 - (y) n -CR1R2 b κοτοροΜ 3ηβΜβΗπ »ι R3, R4. R114 R2 Moryr 6biTb OAMHaKOBbIMM 14AI4Pa3A4MHb Ml4 H nFACTaBAAK < t > T CO60? ATOM BOAOpOAa, rnAP0KcmibHyK > rpynny mjim βηκοκαι - rpynny, HanpuMep, c 1 - 6 aTOMaMu yrnepoAa, TaKyio KaK Μβτοκαι, n - 0,1 v m 2, b npeAnoMTmenbHOM , c 1 - 6 aTOMaMuPoAa, TaKa KaK Memn hah rpynna CR4R2, ΓΑβ Ka > KAbiPi H3 R4 n R5 μοτκθτ 6bm > oAUHaKOBbiM hah Pa3 / iMMHbiM 14 npeACTaBJiaeT co6oii atoms BOAopoAa hah anKHJibHyio rpynny, Further preferably, c 1-6 atoms yrnepoAa, TaKyK) κθκ μθτοκομ NPM ycnoBmi, ητο 2 mam 6οηββ γμαροκομ hah aAKOKCn - rpynnbi, npeACTaB / ieHHbie β BHA © R3 - R6, R4 Hah R5 Aon > KHbi 6biTb npncoeAHHeHbi κ3b4HHBM aTOMaM y / o / o 14 mto nn 2 n, 2 MeHbiueti Mepe OAHa rpynna y αβααθτοα rpynnofl CR4R5.

Takumi o6pa30M, AayxBaneHTHaA an ^ aTMHecKaa rpynna co οβο6οαηημμ BaAeHTHocTHMU Aayx οταθαβημχ 3Tomob μοϊκθτ coAep > KaTb 2-6 3tomob yrAepoAa, Further preferably, 1, 2 - 3Τΐ4ΑβΗ0Β3Α rpynna CH2 -CH2 mam - 1.2 -Anri4ApoKCM3Ti4AeHOBaA rpynna -CH (OH) -CH (OH) -. flByxBaneHTHaa 3Α14φ3Τ14ΗΘΟΚ3Α rpynna CO CB060AHblMl4 BaAeHTHOCTAMM τρβχ OTAeAbHblX aTOMOB Μ0 > κβτ coAepacaTb 3-10 aTOMOB yrAepoAa, Hanpi4Mep, 1,3.-Πρ0ΑΙ4Α6Η0Β3Α ΓργΠΠΘ B03M07KH0 C ΠΟ MeHbLUeft Μβρβ OAHOM rMAPOKCMAbHOM I4AI4 aAKMAbHOM (ΗΘΠρΜΜβρ, ΜβΤΜΑΒΗΟΜ) HAH ΜβΤ0ΚΟ4 3aMeLLļaiOU4ei4 rpynnOM,

HanpuMep, Ha 2 mam 3 aTOMe yrAepoAa, KaK b rpynnax CH2-CR4R5 CHR1 ΓΑβ R4

- BOAOPOA HAH ΜβΤΜΑ, R5 - ΒΟΑΟρΟΑ MA14 TMApOKCMA 14A14 ΜβΤ14Α, R2 - BOROpOR

HAI4 ΜΘΤ14Α I4AI4 ΜΘΤ0ΚΟ4. jOByXBaAeHTH3A 3ΑΜφ3Τ14ΗβΟΚ3Α rpynna CO CB060AHblMl4 Β3ΑβΗΤΗΟΟΤΑΜΙ4 ΤρβΧ 0TA6AbHblX aTOMOB ΜΟβΤ ΤΘΙΟΚΘ COAep > KaTb 3 5 3 7

2 - 6 aTOMOB yArMaMe MMeTb φopMyAy - CHR - CHR - mam CHR - HR 3 1 3 5 - CHR, ΓΑβ R m R - onpeAeneHbi Bbnue, ho β npeAAOHTMTenbHOM Bapi4aHTe ABAAiOTCA aTOMaMu BOAopoAa. flByxeaneHTHaA 3ΑΜφ3τΐ4Μβοκ3Α rpynna co CB060AHblMl4 Β3ΑβΗΤΗΟ (ΓΓΑΜΙ4 ΗβΤΝρβΧ 0TA6AbHblX aTOMOB ΜΟ > ΚΘΤ ΤΘΙΟΚβ coAep > KaTb 4-10 3tomob yrAepoAa, Further preferably 1.4 -6yTHAeHOBan rpynna 2 B03M0) KH0 C ΠΟ MeHbllieM Μβρβ OAHOii n4AP0KCHAbH0H HAH aAKMAbHOM (Further preferably, MeTMAbHoti) hah μθτοκομ saMeu ^ aiomM rpynnofi. 3 B APyrOM ΤΙ4ΠΘ ΟΚΟΜΜβΤΜΑΜρΟΒβΗΗΟΜ Lļl4KAI4HeCKOM MOMeBHHbl rpynnbl R1 H R2 cocraBAAioT HeTbipexBaneHTHyK) an ^ aTi4secKyK) rpynny, κοτορβη BMecTe c aTOMaMi4 a30Ta 14 Kap6oHHAbHbiMH rpynnaMi4 Aayx Z -N-CO-N- Z rpynn 4 o6pa3yioT Aaa KOHAeHcnpoBaHHbix KOAbLļa H3 5, 6 hah 7 3ΑβΜβΗτοβ. TaKne 3 5 3

MeTbipexBaneHTHbie rpynnbi o6nhho μμθιοτ φopMyny -CR - (y) n -CR -, ΓΑβ R, R1, y 14 η οπρβΑβηβΗΝ Bbiiue. Api πρβΑΠΟΜΤΜΤβΑΒΗΟΜ Bapi4aHTe n = 0, a rpynna ABAAeca 3ί1βτΐ4ΑβΗθΒθίί rpynnoii c ynoopMyno ¢ ί -CH -CH-. 5 npHMepaMH OKCI4MeTI4A14pOB3HHblX ψ4ΚΑ14ΜΘΟΚ14Χ ΜΟΜΘΒ14Η ABAAIOTCA Α140Κ014ΜβΤΙ4Α3ΤΜΑβΗ ΜΟΗβΒΙ4Η3 14 B MaCTHOCTM 1,3, N, N - AHOKCMMeTHA, 4,5-Α14ΓΗΑΡ0Κ0Ι43Τ14ΑβΗ ΜΟΗβΒΙ4Η3, HO TaiOKe ΑΜΟΚΟΜΠρΟΠΜΑβΗ ΜΟΗβΒΜΗΘ 14 ββ 4-ΜβτοκοΜ 5,5-ΑΜΜβΤΜη m 5-rnflpoKcn aHSJiom m 5-OKca m 5 -KMM-mmho aHanOR fluoKCMMeTMnnponuneH μοηθβμηι »ι m TeTpaoKCMMeTMnaLleTMneH AMMOHeBMHbl.

CoflepjKamaa 0TBepx < AeHHbiM ποηΜΜβρ THP cured Fabric nponmbiBaeTCfl BOAHbiM pacTBopoM oKCMMeTMnaMMAa, coAepMauļMM, Further preferably, 40-250 r / n from 80 to 180 r / η m OKCMMemnaMMAa wheel κμοποτηομ pH o6biHHO MeHbrne 3 Further preferably, 1-2 MnM, b MacrHocrn, μθηθθ first 3HaMeHMe pH pacrreopa OKCuMeTU / iaMuAa o6biHHO perynnpyeTca KMcnoTofi m, b MacTHocTn, npn HM3KOTeMnepaTypHofi οδρββοτκβ, HanpuMep, npn TeMnepaType MeHee 50 ° C. npeAnOMTMTeJlbHblMM BBJ1BIOTCB ΗβΟρΓΘΗΜΗβΟΟΙβ KMOlOTbl, ΤΘΚΜβ KaK COJIBHaB m oco6bhho cepHan. Mbm 6onbme κοπμμθοτβο Ao6aen «eMOM KMcnoTbi, τθμ Bbliue CKOpOCTb ΟΤΒβρΧφβΗΜΒ MnM CTeneHb ΟΤΒβρΤΚΑβΗΜΒ. KOHLLeHaMaMM npomiTOMHoro pacrBOP b KMcnoTe ο6μηηο cocraBnneT 0.1 - 10, HanpuMep, 0.5 - 10, abePeOneHTMTejibHOM eapnaHTe 1-6, HanpMMep, 1-4 mjim 4 - 6 N. PacTBop μο > κθτ coAep > HanpuMep, OAHO-AByx MnM TpexBaneHTHbix MeTannoe m θημοηη CMnbHbix kmcjiot, τθκμθ xax xnopnAbi HMTpaTbi m cynb < J > τββ. οκοηο 50 r / n. B KanecrBe coneii MoryT 6biTb ncnonb30BaHbJ cojui θμμοημβ, Further preferably, χηορΜΑ βμμοημβ, iiļenoHHbix MeTarmoB, menowH03eMenbHbix MeTannoB, τθκμχ CEC μθγήμμ m ljmhk m aniOMMHMM, npii 3T0M COJ1H ΜΟΠ / Τ nOBblCUTb CKOpOCTb ΟΤΒβρχςηβΗΜΒ. Co / lLLHHKa, HanpuMep, HHTpaT LHHKK Moryr coAeparaTbcn b κοπΜΜβστΒβ 2-20 r / n, a conn Mamnn, HanpuMep, χηορΜΑ μθγημα -10 - 50 r / n. PacTBop Μθ * βτ C0Aep & Ca. HanpuMep, 10-30 r / n pacTBopa. flnn BbicoKOT6MnepaTypHo (i o6pa6oTKH, Further preferably, πριι TeMnepaiype Bbime 50 ° C Moiyr 6biTb ncnonbsoBaHbi BOAHbie pacBopbi onncaHHbix Bbime coneii b OKCHMeTHnaMHAe, πρΜΗβΜ 3HaneHne pH nponMTbiBaioinero solution of perynnpyeTCii b npeAenax 2-6, Further preferably, 3 - 6 MoryT 6biTb Mcnonb30BaHbi paCTBOpHMbie B B0A6 Kap60HOBbie KMCnOTbl HanpMMep C 2 - 6 3T0M3MM yrnepoA h oSbiMHO 1-3 rMAPoKCMnbHbiMM rpynnaMn, HanpuMep, rnnKoneBooo, SoMOHHOU, ηδηοΗΗοϋ, ΜοηοπΗοϋ, βμηηομ h MMHAanbHOM khcjiot b «onHHecTBe 3-100 r / n, HanpuMep, 10-70 r / n, κοτορωβ Μοιγτ Mcnonb30BaTbcn b Otomo npoiļecce HapnAy Una βμθοτο yKa3aHHbix Bbime conefi. cured Fabric nponiiTbiBaeTcn pacreopoM, Nocni Mero ena > Khan cured Fabric ο6μηηο OOKHMaeTcn ao enax < HOCTH 50-120% Further preferably, 60-90% (ot cyxoro EECA οδρββοτβΗΗοϋ THP τκβημ). b ApyroM BapiiaHTe pacreop Μ0 > κβτ HaHOCMTCfl ΜβτοΑΟΜ, o6ecneHHBaK) iiHHMMbbHoe yeenMHeHMe eeca τκθημ, h Bna > KHO CTb Bcero nMUJb 10-50%. Cyxou npHBec oKCHMeTHnaMHAa o6biHHO cocraBnneT 3-20%, HanpuMep, 6-20% Unu 7 - 15% (Ha tom > κβ ocHoee). nocneAyK} LL (an o6pa6oTKa τκθημ μοκθτ 3θτθμ npoM3BOAMTbcn NPM BNA > KHOCTM 6-90% Further preferably, 30-90% κβκ Nocni οόκμμθ, MnM NPM BNA > KHOCTM 6-30% CEC Nocni προπμτκμ μθτοαομ μμημμβπβηογο npMBeca MnM Nocni cymKM MnM nocne HacTMHHoro Bt »icymMBaHMB οτχοτοϋ τκθημ.

HanajībHoe coflep > Kahn enarn nepefl o6pa6oTKOM mo > kho paccsuTaTb M3 EECA nponuTaHHoii τκθημ b by learning μομθητ, μ μοχοαηογο EECA m ena > KHOCTM τκθημ (paccMMTaHHoii of ποτβρβ EECA b npoLļecce cyuiKM) KOHiļempaLļMM τββρΑωχ BeilļeCTB M BOAbl B ΠρΟΠΜΤΟΗΗΟΜ solution of M npMBeca M3-3a Bfia > KHOCTH. nponuTaHHan boahbim pacTBopoM cured Fabric Ha6yxaeT m npn nocneAyK > MEM o6pa6oTKe pearnpyeT c OKCMMeTMnaMMAOM c o6pa30BaHMeM οτΒβρχςηβΗΗΟΜ of Fabric B KOTOpOM OKCMMeTMfiaMUA HaXOAMTCfl B ΟΤΒβρ > ΚΑβΗΗΟΜ COCTOflHMM n cB5i3aH c LļennK > no30M, HanpMMep, C03AaeT nonepem-ibie cbjtcm b L4ennK > no3e μ / μπμ CB «3aH c OTBep > KAeHHbiM ποπΜΜβροΜ THP. BoAHan cpeAa npMcyTCTByeT B TKaHM If BCeM ΠρΟΤΒΜβΗΜΜ ΟΤΒβρ > ΚΑβΗΜη Μ B KOHLEL npOljeCCa OTBepJKAeHHan TKaHb Acid OpaTaHa boahum pacTBopoM m HaxoAMTcn b pa36yxmeM COCTOJ1HMM. Tacoma npoiļecc ΟΤΒβρ > ΚΑβΗΜΗ ΜΟ) ΚΘΤ 6blTb Bbl3BaH BJia > KHblM ΟΤΒβρχςαβΗΜβΜ, B ΟΤΠΜΗΜβ OT CyXOIO ΟΤΒβρ) ΚΑβΗΜΗ, B ΧΟΑβ ΚΟΤΟρΟΓΟ Β / 137ΚΗ3Ρ nponMTaHHan cured Fabric Bbicyi ± iMBaeTcn αί * yAaneHM * BJiarM m BbipaSaTbiBaeTcn cnjiraiiļeHHaa (collapsed) nponMTaHHan cyxan cured Fabric, a nocneAytomee ΟΤΒβρ > ΚΑβΗΜβ npOM3BOAHTCfl Ha CyXOM TKaHM.

Ecjim B / ia > less than of the fabrics b Hanane npoLļecca οτΒβρχςαβΗΜη co < rraBnneT 6-30% TO oSblHHO pH ΒΟΑΗΟΓΟ solution of 0Κ0ΜΜβΤΜ3ΜΜΑ3, KOTOpbIM cured Fabric nponMTaHa, cocraBnneT 1 - 3 ab npeAnoHTMTenbHOM sapnaHTa 1 - 2 cured Fabric o6bMHO BbiAepx < Mbaka) T NPM TeMnepaType HM * e 50 ° C, HanpMMep, 10-40 ° C, ab NpeAnoHTMTenbHOM BapMaHTe npM TeMnepaType oKpywaioiie cpeflbi 15-40 ° C b τβΗβΗΜβ 5-50 nacoB, HanpMMep, 10 -30 nacoB, ab npeAnoHTMTenbHOM BapMaHTe 15-30 Hacoe. ΠρΜ 3τομ πρμημμθκϊτ Mepbi α-πη τογο, HTo6b BJia &Kt; iaCTMKOBblM nMCT. ΠρΜ ΗβΟβΧΟΑΜΜΟΟΤΜ TKaHb MO ≫ KHO OTBep > KAaTb npM TeMnepaType 50 - 180 ° C b τβΜβΗΜβ MHTepana ot 1 MMHyTbi Ao 6 Hacoe, HanpMMep, npM TeMnepaType 90 -140 ° C b τβπβΗΜβ 2 - 20 mmh / t, a mo > kho m npM TeMnepaType 140-180 ° C. Bo ecex stmx cnyHaax cneAyeT TmaTenbHo cneAMTb 3a οοχρβΗβΗΜβΜ ena > KHocTM of Fabric b yKa3aHHbix Bbiuue npeAenax, Ann Mero mo > kho npoeoAMTb οτθβρ > ΚΑβΗΜβ b napoeoM KaMepe, NPM ηθο6χοαμμοοτμ πόα AaBJieHMeM, a b npeAnoHTMTenbHOM BapMaHTe Mcnonb30BaTb HacbiiiļeHHbiM nap. ΠρΜ Tacoma BbicoKOTeMnepaTypHOM o6pa6oTKe pH solution of b τκ3Ηβ Μθ > κβτ cocraBnaTb 2-6, ab npeAnoHTMTenbHOM BapMaHTe 3-5 ρ, η * τκβΗβΡί, HarpeeaeMbix ao TeMnepaTypbi Bbime 90 ° C, m 2 - 3. Ann TKaHeii, HarpeBaeMbix ao TeMnepaTypbi b Anana30He 50 - 90 ° C. BpeMn, pH TeMnepaTypy m ο6ηηηο Bbi6MpatOT M3 ycnoBMn MaKCMMM3aLļMM CKOpOCTM cure and > KAeHMn M MMHMMM38I4MM CHM) KeHMn npOHHOCTM of Fabric B ycnoBM $ ix yK33aHH0M κμοποτηοοτμ m TeMnepaTypbt b τβπβΗΜβ yKa3aHHoro MHTepeana ΒρβΜβΗΜ.

Ecnn Bna > KHOCTb TKaHM b Hanane npoijecca 0ΤΒβρ > ΚΑβΗΜη cocTaBnneT 30-90%, HanpMMep, 30-60% μπμ 40-70% μπμ 45-65%, το 3HaneHMe pH pacTBopa, κοτορωΜ nponMTaHa TKaHb o6biHHO cocraBnneT MeHee 1, BpeMH m TeMnepaTypa Bt iAepx < KM TKaHM He AonatHa neacaTb b Anana30Hax, yKa3aHHbix 5 βπη Bbi, qep > KKn BbicyweHHon TKaHu. B npolylecce οτββρ > ΚΑβΗΗη B / i > KHOCTb nofl, aep > KMBaK) T b, qnana30He 6-90%, HanpnMep, 30-90%. Ecnn b ΠρΟΠΜΤΟΗΗΒΙίί paCTBOp flo6aBneHO 6onblUOe KOJMMeCTBO KHCnOTbl RO KpenOCTM b BaHHe 3 - 10 N HanpnMep, 4 - 6 N, to BpeM * οτΒβρχ < ΑβΗηη μο > Matches npn TeMnepaType OKpy > ΟΤΒβρ > ΚΑβΗΜβ TK3HM MO) KHO npOBOflMTb 6β3 ΠρΜΠΟΚβΗΜΗ ΒΗβΙϋΗβΓΟ ρβστίυκΒΗΜΛ ηηη οκθτηη. B npe, qnoHTMTe; ibHOM BapnaHTe nponnTaHHyI TKaHb cneflyeT 0TBep > KAaTb npn πρηηο > κβΗηΗ pacrrq > TaKoe ρβσιτυκβΗΗβ μο > κθτ 6biTb C03AaH0 3a CH6T πρηηοτκβΗη * ΒΗβιιίΗΜχ cnn n / nnn co3AaHnn BHyTpeHHnx cnn TKan. Tax, β ΗβπρβρωβΗΟΜ npoiļecce οδρβδοτκη, b κοτοροΜ nponnTaHHaa cured Fabric H3 nponuTOHHoii BaHHbi nponycKaeTca Me) Kay o6 > khmhwmh eanKaMn, a 3aTeM προχοΑΜτ Ha npneMHbin ea / ιηκ A-na οτΒβρ > κΑβΗΗ3, cured Fabric mo > kho HaMaTbieaTb Ha npneMHbin eannK c pacTq > KeHneM , no MeHbinen Mepe AocraTOMHbiM Α-π * npeAOTBpau4eHnq npoeeca TKaHn, ab npeAnoHTme / ibHOM BapnaHTe sto τβτηκβΗηβ coxpaH < o > npnneM 3to HaTFOKeHne > κθτ rsoκβ B03pacrn b npoLlecce OTBep > KAeHnq. riponnTaHHyK) cured Fabric Mokha HaMaTbieaTb Ha npneMHbin eannK πόα cn / ibHbiM HaTq > KeHneM, κοτοροβ coxpaH "eTcq bo BpeMn οτθβρ > κΑβΗηη, ho b npeAnoHTViTejibHOM BapnaHTe npnKnaAbiBaiOT MHHHManbHoe pacTJūKeHne απη npeAOTBpaaļeHna npoencaHna. Ecnn nponnTaHHan cured Fabric He BbicyujHBaeTcq, το πρη οτββρτκΑβΗηη wenaTenbHo npnHSTb Mepbi alkyl πρβΑοτΒρβιμβΗηη cnnea > κηΑΚθοτη, HanpnMep, BpaujaTb eannK μθα / ιθηηο c τθμ, HTo6bi n36ex < ATB cyu4ecTBeHHbix noTepb Biiam. Πρη ΗββχοΑΜΜοστη TKaHb motkho nepeMOTaTb c ΤΘΜ, HT06bl yMeHbllJnTb OCTaTOHHbie HanpflKeHHfl Β ΤΚ3Ηη. 06blHHO TKaHb OTBep > KAaioT b pacnpaBneHHOM cocToaHnn 6e3 cotAOK, ecnn He CTaBHTcn inenn nonyneHnq nnnccnpoeaHHon TKaHn. Πρη ckopocthom npoiļecce OTBepx < AeHnq, HanpnMep, b TeneHne 3 MHHyT, οτββρ > ΚΑβΗηβ mo > kho npoBOAnTb b napoBon KaMepe ποα pacrq > KeHneM, β πρβΑΠΟΗτητβηΒΗΟΜ BapnaHTe MnHnMa / ibHOM - TonbKo RNN npeAOTBpauļeHna npoBncaHnn. Ποοηβ οτΒβρΜΑβΗΗ * TKaHb npoMbieaioT, HenTpann3yK) T n cHoea npoMbiBaioT ao ΟΏκηΜβΗηη n cyujKn. Πρη o6pa6oTKe cMonon KonnnecTBo ΤΒβρΑΗΧ Indicates TB ο6νηηο no > KHT b npeAenax 1 - 6 η, b nacTHOcTn, 2-4%. noBTopHaa o6pa6oTKa OKcnMeTnnaMHAOM ο6ηηηο He Βηηηβτ Ha aHTnnnpeHOBbie CBoncTBa TKaHn, ho cymecrBeHHo ynyHUjaeT 3KcnnyaOldHHbie CBoncTBa TKaHn. Πο cpaBHeHnio c o6pa6oTaHHon THP TKaHbio, Ηβ πριηβΑίιιβη οδρβδοτκη OKcnMeTnnaMnAOM, o6pa6oTaHHan oKcnMeTnnaMnAOM cured Fabric o6biHHO o6naAaeT yMeHbiueHHon ycaAKon, ynyHi ± ieHHon HecMnHaeMocrbio yBennMeHHbiM yrnoM HecMnHaeMocrn bo bji3 > Khom cocTonHnn, 6-one BbicoKon paBHOBecHon B / iajKHocTbK) noHH > KeHHbiM ποΓηοίμβΗηβΜ Enam (ocraTOHHan BOAa Nocni 4eHTpn4 > yrnpoBaHna), ecnn οτββρ > κΑβΗηβ OKcnMeTnnaMnAa BbinonHaeTca ποα pacrq > KeHneM, το Μθ > CTeneHb coxpaHeHnn npoMHocm Ha pa3Anp η η3Ηθθοστοηκοοτη β 6 EN 11199 o6pa6oTaHHofi τκβΗΗ of cpaBHeHHto c THP - TKaHbio ao o6pa6oTKH o6biMHo 3HaMMTenbHO Bbiiue, ηθμ b o6pa6oTaHHbix τκβΗηχ, b κοτορωχ THP - cured Fabric o6pa6oTaHa OKCHMeTHnaMHAOM h noABepmyia TennoBOMy cure and > KfleHMK). B Apyrowi, ΜθΗββ npeAnoMTHTenbHOM eapnahthc HcxoAHaa TKaHb μο > κθτ 6biTb BHaHane noABepmyTeTeTeTeTeHKHLHH c OKCHMeTHnaMHAOM, a 33τθμ o6pa6oTaHa coeAHHeHneM min κοηα @ ηο3Τομ THP, nocne Measured 0TBep > KAeHa. It ecTb b τθκομ npoiļecce cured Fabric, npopearnpeaBLuaB c HecaMOKOHAeHCHpyK > LL | MMCB OKCHMeTHnaMHAOM, ΗΜβΚΗ11ΗΜ Π0 MeHbLUeH Μβρβ acid oKCMMeTHnbHbie rpynnbi (KOTopbie MoryT 6biTb anHKHnnpoBaHHbiMH) b npHcyTCTBnn βοαηογο solution of κηοποτη, e.g. npn pH MeHbiiie 3 o6pa6aTbiBaeTC? ≫ οοθαμηθημθμ πηπ κοηαθηοθτομ Cost khc (ΓΗΑροκοΗΜβτηη) φοοφθΗΗΒ, KOTopbiii 33ΤΘΜ OTBep > KAaeTCFi. CBoncTBa OKCHMeTHnaMHAa η προπητομηογο solution of h ero pH, a TaioKe μθτοαμκθ nponnTKM η οτΒβρχ < ΑβΗΜΒ τκθηη of cyiiļecTBy He OTnHMatoTCJi ot o6pa6oTKH OKCHMeTHnaMHAOM TKaHH, y > Ke coAep > Kau4eH 0TBep > KAeHHbiH ΠΟηΗΜβρ THP, 3a ΗΟΚΠΙΟΗβΗΗβΜ BNA > KHOCTH ΠρΟΠΗΤΘΗΗΟΗ OKCHMeTHnaMHAOM τκθΗΗ, κοτορβη o6bNHO cocTaBnneT 50-120%, HanpHMep, 60-110% (ot Beca cyxoH TKaHH), cyxoro Beca OKCHMeTHnaMHAa, o6whho cocraBnatomero 4-25%, HanpHMep, 6-18% nnn 8-14% (Ha τοη > κβ οοηοβθ) h ena > KHOCTH τκθηη b Hanane npoiļecca οτΒβρ > κΑβΗΗη, KOTopan Μο > κβτ cocTaBnnTb 6-30% ho b6onee npeAnoMTHTenbHOM BapnaHTe - 30-90% HanpHMep, 3-60% nnn 45-80% ho nymue - 60-90 %, b μβοτηοοτη, 70-90% (ot Beca hcxoahoh τκθηη), nocKonbKy TaKan BbicoKan HasanbHan Bna < tb > HOCTH 6-30%. ΓΊο cpaBH6HHK > co CBOHCTBaMH τκθηη, npoiueAiueH BNA > KHyio o6pa60TKy OKCHMeTHnaMHAOM, nocneAyK) iiļan o6pa6oTKa THP eecbMa cytiļecTBeHHO noBbiinaeT aHTHnnpeHOBbte cbohctb3 τκ3ηη, μο > κθτ yBenHHHTb yron HeCMHHaeMOCTH B CyXOM H BnaJKHOM COCTOBHHH, nOBblCHTb paBHOBeCHyK3 BNA > less than of h CHH3HTb BNA > less than of Nocni ^ eHτpHφyΓHpoBaHH5 ^ ( nornomeHHe BOAbi). Πο cpaBHeHHto c TKaHbio, cure and coAepjKaineii > KAeHHbiH nonnMep THP, cured Fabric, b Hanane o6pa6oTaHHaa OKCHMeTHnaMHAOM, a 3aTeM THP, o6naAaeT ΠΟΗΗΤΚβΗΗΟΗ ycaAKOH Nocni npOMblBKH H nOBbUiieHHblM yrnOM HeCMHHaeMOCTH b cyxoM h BNA > Khom coctobhhh. B οβιμβΜ TKaHb, o6pa6oTaHHan OKCHMeTHnaMHAOM ao o6pa6oTKH THP, oAnT yxyAiueHhbiMH οβοηοτβθμη ΠΟ CpaBHeHHtO C TKaHbtO, o6pa60TKa KOTOpOH OKCHMeTHnaMHAOM cymecTBnneTcn nocne οδρβδοτκπ THP. McKntoneHHe cocTaBnneT ycaAKa, KOTopan MeHbute y nepsoro BHAa TKaHH. flnn yMeHbiJueHHii noTepb npoMHOCTH Ha pa3AHp o6pa6oTaHHon τκθηη no cpaBHeHHto ΤΗΡ-TKaHbto nnn hcxoahoh TKaHbio ao οδρβδοτκπ κ τκθηη, coAep > KaiAeH OTBepx < ao nnn nocne oKOHHaTenbHOH onepaiHH cyiiKH Ao6aBnntoT πηβστΗφΗΚθτορ b KonMHecTBe 0.1-5% (ot Beca τκθηη). ΠρπΜβροΜ Takor nnacm ^ HKaTopa Μθ) κβτ CNY > KHTb npoAytcr KOHAeHcaiļHH) KHpHbix KHcnoT c 8-20 aTOMaMH yrnepoAa h nonnaMHHbi nnn npoAyKTbt hx i | b HxnH3ai4HH bhab conen ηθτβθρτηηηογο θμμοηηβ c AByMn 7 rpynnaMH χαιρΗοΚ anMtfcaTMMecKOM KucnoTbi, HanpMMep hammers c 8-20 aTOMaMM yrnepofla, b MacrnocrM, μθτμπ.

MBI y > Ke o6Hapy > KMnM, whereby to MexaHMHecKan ycaflKa, HanpMMep, MexaHMMecKafl ycaflKa οβχοτΜβΜ cymecrBeHHo CHM > Caete nporpeccnBHyto ycaflKy Nocni nOBTOpfllOUļMXCB npOMbIBOK TK3HM, o6pa6oTaHHOM THP M OKCMMeTvuiaMMflOM, He3aBMCMMO ot ^ nop hook o6pa6oTKM. npoijecc ycaflKM θ6χ «ΤΜβΜ o6blMHO ΒΚΠΙΟΜββΤ OnepaLMM yBnaXCH6HMB TK3HM BOAMM MnM napoM ao Ha6yxaHMii TKaHM, perynnpoBaHne newMpMHbi pa36yxLueM tk3hm ro KenaTe / ibHoro pa3Mepa, ycaAKM τκβημ οδχοτπβΜ m cyuiKM. ycaaxa οδχοτπβΜ Μθ > κβτ 6t > iTb npeeeAeHa nyreM bboa3 TKaHM b comata c pacraHyTbiM 3 / iacroMepHbiM MaTepManoM m coxpanemn dToro komcra b npoi ^ ecce yMeHbiueHMfl creneHM yAnMHeHMn Maepnana, HanpuMep, ao Hynn. CyiUKy MO > KHO npOBOAHTb B ycnOBMBX Οφ3ΗΜ4βΗΜΛ, Η3ΠρΜΜβρ, Π / ΓβΜ ΟδΧΟΤΜΒ yena > KHeHOH TKaHM Mex < Ποοηβ θτογο τκθηβ Μθ > κβτ 6biTb npoKaTaHa. ΠρΜΜβροΜ TaKoro npoiļecca ΑΒηηβτοη προμβοο (Sanforized) OriMcaHHbiM b International Taxtile BulletinDyeing (printig) Finishing 2/96, crp. 14-16, 20, 22 m 27 B pe3ynbTaTe οδρβδοτκΜ the fabrics oKCMMeTMnaMMAOM ao MnM Nocni o6pa6oTKM THP c nocneAy > oiiļeM μθχθημμθοκομ ycaAKOM pa3Hocrb paaMepoB, HanpMMep, b HanpaeneHMM ocHOBbi, Nocni onepeAHOM npoMbiBKM Μοτκβτ 6biTb CHM > KEHAI ao Manoft BenMHMHbi, HanpMMep, MeHee 2.5 MnM 2% MnM oseHb ManoM eenMMMHbi, HanpMMep, MeHee 1%. ΠρΜ 9tom creneHb nporpeccMBHOM ycaflKM nocne, HanpMMep, 50 προΜωβοκ Μο > κβτ 6bm > ManoM, HanpMMep, MeHee 5% MnM 04eHb ManoM, HanpMMep, MeHee 2 MnM 1%. EcnM creneHb MexaHMHecKOM ycaflKM the fabrics 6-one, 4βΜ AocTaTOMHa A / IFL KOMneHcai4MM ycaAKM b xofle oahom for Operations npoMbiBKM, to the fabrics, o6pa6oTaHHbie THP m OKCMMeTMnaMMAOM, Nocni MexaHMMecKOM ycaAKM 6yAyr pacrnrMBaTbcn Nocni oahom npoMbiBKM, HanpMMep Ha 5% μ m 3Ta creneHb pacTBMeHMfl Μ0 > κβτ ocraTbcn npaKTMHecKM ηθμ3μθηηομ b χοαθ nocneAytoiHMx 50 npoMbtBOK, b pesynbTaTe nero crreneHb nporpeccMBHOM ycaA «M 0Ka3UBaeTcn oneHb ManoM. EpaρΜ ΗβοδχοΑΜΜοοτΜ onepaLony nocne οτββρ > ΚΑβΗΜη ΜβΧ3ΗΜΜβ0Κ0Μ ycaAKM MOTKHO nPOBeCTM B XORe o6pa6oTKM OKCMMeTMnaMMAOM THP m aOlKLMMMM. B cnynae οδρβδοτκΜ OKCMMeTMnaMMAOM ao oTBepagLeHMn THP 3Ty onPLMoMoMoMo nOnBecTM βμθοτο MnM nocne peaKLMMM. EpaδωΜΗΟ onepaLMB MexaHMMecKOM ycaflKM BbinonHneTcn nocne nocneAHeM onPHLMM oTBepIcHeMMKKMMeTMnaMMfla MnM THP, ho g ββτ 6biTb BbinonHeHa m Me > Ecjim MexaHMMecKan ycaflKa He BbinonHneTcn, npeAnoHTMTenbHO npoeoAMTb o6pa6oTKy OKCMMeTMnaMMAOM nocne o6pa6oTKM THP. ΠρΜ TaKOM πορΒΑκβ οδρβδοτκΜ nonyMaioT TKaHb c MeHbineM ycaAKOM.

06biMHO 6onbuian Macrb ΒοηοκοΗ τκθημ nenmoTcn Lļenntono3HbiMM, a b npeAnoHTMTenbHOM BapMaHTe 100% ΒοηοκοΗ HBnnioTca iļenniono3HbiMM, XAX b ecrecTBeHHOM χηοπκβ, a TaioKe m b m PAMM nbHe, MnM pereHMpMpoeaHHbiMM BOnOKHaMM, HanpMMep, BMCK03HblMM MnM MeAHOaMMMaHHbIMM rMApaTLļennionosHbiMM BonoKHaMM. TxaHb Μθ > κβτ 6biTb noAaeprHyra MepCepM33LMMM BOAHBIM paCTBOpOM LLENENOHM MnM > KMAKMM 3MMMK0M, B03MO) KHO 8 LV 11199 c npuMecbto aMMHOB, KOTopaa b npeAnoHTMTenbHOM Bapname npoBOAMTca flo HaHeceHna οοθαμηθημη THP. L4ennrono3Hbie βοποκηθ Moryr 6biTb TKaHbiMM mam Bfl3aHbiMM. AHM ΜΟΓγΤ 6blTb CMeUiaHbl C MeHbLUMM KOAMHeCTBOM, HanpMMep, OT 1 13.0 50% COBMeCTMMblX ΒΟΑΟΚΟΗ, HanpMMep, Π0ΠΜ3φΜρΗωΧ C 06pa30BaHMeM CMecu H3, HanpMMep, 60-80%, χηορκβ c 20-40% ποηΜβφΜρβ. Οαηθκο OnUCaHHblf NPOOLC B B OCHOBHOM ΠρβΑΗ33Η3Η6Η AAA ΠρθΚΤΜΗβΟΚΜ nOAHOCTbKD LionsJiiono3Hbix τκθηθμ, β μθοτηοοτμ, χ / ioriKa. TKaHb ao o6pa6oTKH THP μοκθτ MMeTb Bec 0.05-1.00 κγ / μ2, HanpMMep, 0.1-1.00 κγ / μ2, o6biHHO 0.15-0.40 κγ / μ2, 0.37 κγ / μ2. flpMMepaMM τβκΜΧ τκθηθμ αβααιοτοα xnonHaTo6YMa > KHbiM tmk, npocTbiHHan TKaHb, py6aweHHaA TKaHb mam nopTbepHaa TKaHb. fl O 06pa60TKM THP cured Fabric MAM 0Κ0ΜΜ6ΤΜΑ3ΜΜΑ0Μ ΜΟ > ΚβΤ 6blTb OKpameHa, HanpMMep, Ky6oBbiM mam a30KpacMTeneM, xota Moryr 6biTb TaioKe McnoAb30BaHbi ocHOBHbie KpacMTeAM, peaKTMBHbie KpacMTeAM, npaMbie, KMCAOTHbie mam AMcneprMpoBaHHbie KpacMTeAM. Ecam TKaHb OKpaujMBaeTCfl nocne o6pa6oTKM THP, npeAnoHTMTeAbHbiM ABnaeTCA peaKTMBHbiM KpacMTeAb. Ecam > κβ TKaHb OKpauiHBActAo oOpActIoN, aNeTeTeMaTeAbHbiM ABAAeTCA Ky60BblM KpacMTeAb M aCoCMTeAb. TaKMM o6pa30M, npM McnoAb3aaaHMM Ky6oBoro mam a30KpacMTena TKaHb A ° n > KHa BHanane OKpanMBaTbCA, o6pa6aTbiBaTbca THP, 0TBep > B apvom eapnaHTe NPM MCnOAb30B3HMM ΗβΚΟΤΟρΒΙΧ ΟΤΤβΗΚΟΒ Ky60BOrO MAM 330KpaCMTeAA ΜΟ) ΚβΤ 0Ka3aTbCA 6oAee npeAnoHTMTeAbHbiM CHasana o6pa6aTbiBaTb cured Fabric oKCMMeTMAaMMAOM, 3aTeM KpacMTb, a 3aTeM o6pa6aTbieaTb THP cure and m > KAaTb. 06pa6oTaHHbie θητμπμρθηομ tk3Hm c yAyHLueHHbiMM 3KCnAyaTaLļM0HHblMM CB0MCTB3MM ΜΟΓγΤ 6blTb MCn0Ab30BaHbl AAA nOLUMBa φορΜω, HanpMMep, φορΜω aaa BÖMCKE 6e3onacHocTM m of > KapHbix, a TaioKe aaa pa6oneM 0Aex < Abi. Bonee nencMe τκθημ Moryr 6biTb McnoAb3oeaHbi aaaaMBa φορΜβΗΗ ^ χ py6ameK, aaa κοτορωχ οοο6θηηο cyu4ecrBeHHbi HecMMHaeMocrb m 3KcnnyaTa4MOHHue CBOMCTBa. Bonee Tfl > Kenbie τκθημ, HanpMMep, χαοπκοβομ tmk MoryT 6biTb McnoAb30BaHbi aaaMBaMeMaAe > kabi, HanpMMep, κομ6μηθ30ηοβ μ 6ριοκ, flnfl κοτορΜΧ oco6o cyiAecTBeHHa ycaAKa. Ημ > ΚΘ ΠρΜΒβΑβΗΟ OnMCaHMe ΠρΜΜβρΟΒ Μ3θ6ρβΤβΗΜΑ, B KOTOpblX McnoAbsoBaHbi nepeMMcneHHbie HMxce ΜβτοΑω McnbīTaHMM. B k3 > nynanaeKKKKKKKKKKbibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibibi sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac sac ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° °%%%%%%: 65% (othoc). 1. HecMMHaeMocTb. H3MepeHMe yrnoB HecMMHaeMOCTM b HanpasneHMM ocHOBbi o6pa6oTaHHOM m Heo6pa6oTaHHOM τκ3ημ, οαο > κθηηομ AMLļeeoM crropoHOM Hapyacy, β cyxoM μ βαθμηομ coctoahmm, c noMOUļbK) npM6opa MONSANTO wrinkle RECOVEY TESTER c Harpy3Koii 500 r.M 3-XMMHyTHbiMM MHTepBanaMM Harpy3KM - BOCCTaHOBneHMA. 9 2 OueHKa HecMMHaeMOCTM (1 P) B 1-15 npMepax cured Fabric oLieHMBanacb of MeTOAy ncnbīTaHuPi NFI 88 AATCC (ĀMepuKaHCKafl accoiļnaLļMfl cneLļnanncTOB of KpacHTennM απα τκβΗβίί) b cooTBeTCTBun co CTaHAapTOM Ha npoMUBxy n m3hoc a DP of rnaAKOCTM tk3hm Ha B3rn "A b cooTBeTCTBMM co craHAapTaMH 1-5 (1-HanxyAUJMii), ab npnMepax 16-26 - no MeTOAy 124 AATCC. 3. ycaflKa

YcaAKa from οοοοβθ m yTKy M3Mepnnacb οn μθτοακκθ BS 4923 (1973) nocne 40 npoMbiBOK (Α-π * npHMepoB 1-15) 4 npOHHOCTb ripoHHOCTb Ha paepbiB H3Mepflnn of CTaHflapTy BS 2756, a npoHHocrb Ha pa3Anp b HanpaBneHUH yTKa of ^ nMeHAopφy 5 AHTnnnpeHOBbie CBotfcTBa τκθημ onpeAermnn Nocni 12 npoMbiBOK πρκ T8MnepaType 93 ° C h Nocni 40 npoMbiBOK πρκ TeMnepaType 93 ° C (Α-π * npHMepoB 1-15) nocne 50 npoMbiBOK (α-πη npHMepoB 16-26) (μβγκομ ΒΟΑοίί from CTaHAapiy DIN 53920) from ΜβτοΑΜΚβ craHAapT B 3119 6. AHaJ1M3 TKaHM. nocne oKOHHaHM o6pa6oTKn ispeA © nnnn% P,% N, m coAepxcaHne φορΜβηΒΑβηίΑθ b MnnnnoHHbix Αοηηχ. % P,% N onpeAennnn TaioKe nocne 12 m 40 προΜΝΒοκ (A < n ^ npHMepoB 1-15) v 50 προΜΝΒοκ (a ^ npmviepoB 16-29) npH TeMnepaType 93 ° C. 3aT6M paccHMTbiBann aTOMHoe οτΗοιηβΗΜβ N: P. 7. H3HOCOCTOMKOCTb. ΥοκορβΗΜβ ncnb) TaHnn npoeoAnnn no MeTOAy A craHAapTa AATCC-99- 1984.

TKaHb o6pa6oTaHHaH THP TKaHbA

TxaHb αί * ncnonb30BaHnn b npnMepax 1-13, 15 m 27 nonyMann nocpeACTBOM προηκτιαι xnonHaTo6yMax < Horo TMKa 3111, MMetoiiļero Bec 0.285 10 E 11199 κγ / μ2 m OKpaiueHHoro npeABapMTenbHo npKHM opaH > Kebbi a30KpacnTeneM 6e3 C3H < t > opM3aLļnn, BOflHbiM pacTBopoM npeKOHAeHcaTa xnopnfla THP n MOMeBUHb B ΜΟΠίφΗΟΜ 0TH0LU6HMM 1: 0.5 H pH = 4.5. ΘΚΒΜΒ3ΠβΗΤ paCTBOpa ΠΟ ΟΤΗΟΐυβΗΜΚ) κ MOHy THP cocTaennn 25%. TKaHb nponuTbieanu ao ena KHOCTM οκοηο 80%, cyi ± iwin b TeMeHne 1 MHHyTbi npn. TeMnepaType 120 ° C, noc / n o o o n o B B A npMHyAMTenbHOM ποτοκβ ra30o6pa3Horo aMMnaKa β οοοτΒβτοτΒΜΜ c naTeHTOM CUJA 4 125 463. OTBep > KAeHHyio TKaHb oKCMAMpoeanM nepeKMCbto BOAopoAa. neiiTpann30Bann pacTBopoM yrneKHcnoro HaTpun, npoMbiBanu m cymnnn.

TKaHb B, C, D μ E

OnncaHHa «a ^« τκθημ A MeTOAHKa 6bina ncnonb3oeaHa h απη ocranbHbix Μβτωρβχ xnonMaTo6yMa > KHbix τκθηθμ co cneAyK) LLHHHH H3MeH6HMBMH. flpOMbieOHHafl BOAa ΟΟΑβρΧΟΠβ ΠΓΟΟΤΗφΗΚβΤΟρ TK3HM ( "AIKAMINE" FPS) b KonvmecTBe 2% ot Beca o6pa6oTaHHoii THP τκθημ, a KaxcAbiM o6pa3etļ o6pa6oTaHH0M THP τκθημ noABepranu MexaHMMecKoii ycaAKe οβχοτνιθΜ β οοοτβθτοτβμμ c npoiļeccoM 'Ό3ΗφορΜ33ψΐΜ \ B KaMecree o6pa3L (OB TKaHH Hcnonb30BaxiH MepcepM30BaHHyto caTHHOByfO cured Fabric Ann pa6oHeii OAE > Kabi eecoM 0.270 κγ / μ2, npeABaptiTejibHO OKpameHHyto Ky6oebiM chhmm KpacMTeneM (cured Fabric B) OKpauieHHbiH a30KpacMTeneM THK 3111 eecoM 0 346 κγ / μ2 (τκθηβ C) OKpaineHHbiM a30KpacnTeneM caTMHOBbiii THK eecoM 0.28 κγ / μ2 (cured Fabric D ), a TaioKe οπτμμθοκμ ocBeTneHHan capara eecoM 0,192 κγ / μ2 (TKaHb E). , N-OKcnMeTMn-4,5-AnrviApoKCH3TnneHMOHeBMHbi DMDHEU (ToproBan MapKa FIXAPRET CPN) h 5 0 μπ / π 98% cepHotf KMcnoTbi, pH pacreopa ΜβΗββ 1, a KOHLļeHTpamifl KMcnoTbi b BaHH6 - 1.88 N. BNA > KHyK) cured Fabric c o6lamm οοΑβρχοΗΜβΜ enarM οκοηο 68% (οτ EECA o6pa6oTaHHoii THP tk3hh) aKKypaTHo cnoaumu m noMecTnnn b nonn3TnneH0Bbiii πβκβτ, KOTopbitf repMeTH3npoBann, h BbiAep > KHBann b cbo6oahom coctobhmm (τ.β. 6β3 npnno > KeHHoro HaTn > KeHnn) β ΤβΜβΗΜΘ 22 MaCOB ΓφΜ Κ0ΜΗ3ΤΗ0Μ ΤβΜΠβρβΤγρβ Αηη ΟΤΒβρ > ΚΑβΗΜ51. 3aT8M cured Fabric BWHynn μ nocneAoeaTenbHO npoMbinn χοποαηοΑ βοαοΑ, βοαημμ pacTBopoM yrneKMcnoro HaTpun c KOHLļeHTpanMeH 10 r / n, βοαηβιμ pacTBopoM yrneKHcnoro HaTpun c KOHLļeHTpaLļkieCi 2 r / n μ ΑοδββκοΜ 2 r / n AeTepreHTa npvi TeMnepaType 50 ° C, ropnHeii boaom npn τβΜπβρβτγρβ 60 ° C h χοηοΑΗοίί boaom. riocne 3Toro TKaHb BbicyujMnn h ncnbiTann ΒΜβοτβ co cpaBHHTenbHbiMH o6pa3LMM τκθημ, o6pa6oTaHHofi THP (cpaBHMT. A). Pe3ynbTaTbi npHBeAeHbi ΗΜ > Κβ. 11 LV 11199 «= T sc, vo (0 I-

Pe3ynbTaTbi.

io l > > s C n z «o 2 Ι- ΙΟ J δ r > o CL § 1 5f O O § Q Q Tf IO CM o CN cm " z 05 co * CM N * CM * CL co r ** - CM * M1 h »CM * 1 Φ t c o o v ο n C Λ VO o Q_ Ž co and > cm " TT CM CM * z vO M · CO CO * 05 O co " a. nP 05 co CM l / > O co " S C _ 's' I ϊ K. £ Hit | | S. S. S s. s | (O tf) in m Ιο ^ = 3 Sz o ° -w o. 10 c * in M " u > _ φ 0. S g Q β τ h £ | ¤ Ο φ oz 2 yn CN io 3 £ e ~ RO (0 X o '' > o o o o o o s' s C 1! " ** s 2 o ® z X 10 ò ffl in x - IO O) > < > »o o 00 o σ > α ® 2 S α C - < r m nj CL o m j) Έ 0 01 c Φ o z Q Q Q Q κ κ CL CL n p: s x a > o.o φs X Φc; d Φ 2 roco EN 11199 ΠρΜΜθρ 2 llpoLļecc of npMMepy 1 noBTopunn co cneAyiOLLļMMH Μ3ΜβΗβΗΜΑΜΜ B nponMTOMHbiM solution was 6bin flo6aBJieH b KonMMecTBe 0.5 r / n CMaHMBaKJinMM areHT, npeflCTaBnnKJinviM οοβοίί mixture of n HenoHHoro 3ημοηηογο θγθητοβ c ToproBoii MapKOM WA 100 BbinycKaeMOM φπρΜΟΜ "brookston Chemicals Staffordshine ”, Αηγπμβ, a nocne 0ΤΒβρ > Bbipe3aHHbie M3 stom to Fabric "BaflpaTbi, a TaioKe M3 mcxoahom o6pa6oTaHHoii THP tkbhm npoMbieanncb b CTupa / ibHoii MaiuMHe b TeneHne 10 MMHyr npn TeMnepaType 60 ° C, 3aieM τρΜ pa3a npoMbiBanncb χοποαηομ boaom m LļeHTpki0yrkipoBanMCb b τθηθημθ 10 MMHyT npn CKopocrn 1000 o6 / mmh. Afοοπβ θτογο KBaflpaTbi τκθημ BbicymnBanncb Ha BepeBKe npn κομηβτηομ τβΜπβρβτγρβ μπμ b 6apa6aHe b τβΗβΗΜβ 15 MMHyr πρΜ κοηθμηομ MaKcuManbHoii TeMnepaType 70 ° C. 3th KBaApaTbi TKaHM BMecre co cpaBHMTenbHbiMM o6pa3Liw o6pa6oTaHHofi THP TKaHM (cpaBHMTenbHbiM πρΜΜβρ B) McnbiTbiBanMCb Ha oliHKy HecMMHaeMocTM. Pe3ynbTaTbi npMBeAeHbi b TaenMeel 2.

TaSfiMua 2 cured Fabric OijeHKa HecMHHaeMocTH CyujKa Ha Ββρββκβ CyuiKa b 6apa6aHe ΠρΜΜβρ 2 4-5 3-4 CpaBHMTenbHbiM πρΜΜβρ B 2 2 riPHMflP 3 flnn EXAMPLE 3 6bin ποβτορθη npoiļecc of npMMepy 1 co cjieAy > OII (MMM Μ3ΜβΗβΗΜ3ΜΜ: ΠροπΜΤΟΜΗΒΐίί solution was c pH MeHbine 1 C0Aepa & lt an 70 Mn / n KOHLeHpMpOBaHHOM (35%) COHflHOM KMCHOTbl (BMeCTO CepHOM) c KOHLeHTpai ^ MeM 0.82N, τβιοκβ 0.5 μπ / π CMaHMBatouol isHTa from npMMepy 2, ΟΤΒβρ) ΚΑβΗΜβ TKaHM nPOBOAMJIOCb B ΤβΗΘΗΜβ 16 HaCOB. Bna) KHOCTb TKaHM B Hanane npoiļecca οτΒβρχ ^ ίβΗΜΠ cocTaennna οκοηο 72% (οτ Beca o6pa6oTaHHoii THP τκβΗΜ).

Pe3ynbTaTbi McnbrraHMM stom of the fabrics, a TaioKe pe3ynbTaTbi McnbrraHMM cpaBHMTenbHoro o6pa3iļa o6pa6oTaHHoii THP of the fabrics (cpaBHMTenbHbiM πρΜΜβρ C) npMBefleHbi b Ta6nMiļax 3, 4, 5, 6, 13 m lažīmua 3- yrnbi HflCMMHaflMOCTM froanvcMl ΠρΜΜβρ BjiaMHasi OcHoea Υτοκ Cyxaa OcHoea Υτοκ CpaBHMT. C 95 85 91 89 3 139 131 92 88

TaSiiMU 4

VcanKa (πηοιιβΗΤΜΐ ΠρΜΜβρ OcHoea Υτοκ CpaBHMT. C 8 2.5 3 4 0.5

Ta6nmia 5 3aM6iLneHMe γορβημβ fno cTaHnap-rv B 3119¾ ΠρΜΜβρ CpeflHBB xapaKT. onMHa (mm) Ποοπβ o6pa6oTKH Ποοηβ 12 npoMbieoK Ποοπβ 40 npoMbieoK CpaBHMT. C 70 69 53 3 70 70 54

Ta6mma β

HeadshotsHamma ΠρΜΜβρ Ποοπβ o6pa6oTKM Ποοββ 12 npOMbIBOK Ποοπβ 40 npOMbIBOK% P% N HCHO ΜΠΗ. / 10Π% P% N% P% N CpaBHMT. C 3.07 3.22 300 2.87 2.80 2.74 2.72 3 2.91 3.50 320 2.75 3.15 2.70 3.13 Πρημβρμ 4-12 ripOLlCCC Π0 npMMepy 1 6blJl ΠΟΘΤΟρβΗ Cp3JlMHHblMM Κ0ΠΜΜΘ0ΤΒ3ΜΜ OTBepflmenfl m Ao6aBnaeMOM KOHIHOPPoBaHaCa cepHoPi kmcjiotn. Bo Bcex cnyMaax BJia) KH0CTb npn βνχολθ m eaHHbi c προπμτομηομ cMonoPi noAqep > KMBanacb okojio 80%, ena > KHOCTb b Hanane npoiļecca οτΒβρχφβΗΜη -οκοηο 63 - 72% (ot eeca opapaooTaHHofi THP thiohm). Pe3ynbTaTbi npuBefleHbi b Ta6nni4e 7. 14 LV 11199

lafiiumaJ

PflaynhraThi ΠριίΜβρ BaHHa οτββρ- JKfleHMH areHome / Cepnan KUcnoTa floSaeri. BB3HHy ΜΠ / Π flo6aBxa TBepfloro B-ea% ycaAxa% nocne 40 npOMblBOK yron HecMMH-eMOCTM BJiaJKH. OCHOBbl rpafl. ΠρΟΜΗ. Ha pa3flnp (κγ) H3HOCOCTOH KOCTb ycKop. % noTepb eeca 4 200 25 2.09 5.0 135 1.18 5 50 2.62 5.0 142 1.12 6 75 3.22 4.0 148 1.12 7 25 2.62 5.0 135 1 , 25 8 50 3.43 3.5 155 1.15 9.8 9 75 3.42 3.0 152 1.15 10 25 2.77 4.5 137 1.25 11 50 3.35 4.0 146 1.15 12 75 3.86 4.0 150 1.15 Heo6pa6oTaH-Haa TKaHb, You c OTBepjKfl. THP-10.0 95 1.54 9.2

BocnnaMeHJieMOCTb Bcex τκθηθμ cooTBeTCTByeT τρββοβθΗΜΠΜ CTaHflapTa B 3120. ΠρΜΜβρ 13 npoiļecc of EXAMPLE 7-9 6bin ποβτορβΗ c aaMeHOM cepHoii κμοποτν KOHlļeHTpMpOBaHHOM ΟΟΠΠΗΟΜ KMCJIOTOM B ΚΟΠΜΜβΟΤΒβ 100 ΜΠ (ΟΚΟΠΟ 30% Bec) solution of pH cocTaennn MeHee 1, a KOHiļeHTpaiļMfl KnenoTbi 1.17. Bna > KHocTb τκβημ b Hanane npoi ^ ecca 0TBep &Kt; KfleHMfl cocraBnana οκοπο 71% (οτ Beca o6pa6oTaHHoii ΤΗΡ τκβημ). 06pa6oTaHHyto τκθηβ noflBeprnu yo &op; opeHHbiM McnbīTaHunM If M3HOC, πρΜΜβΜ ποτβρπ Beca cocTaBuna 10.6%. flpyrne McnbīTaHMB Aanu cneAyioiAne pe3ynbTaTbi: ycaflKa Ha οοηοβθ 3.5% yron HeCMHHaeMOCTH ΒΟ BNA > Khom COCTOBHHM 150 ° C npOHHOCTb Ha pa3flnp (from 3nMeHAop4 > y, > αοκ) 1.10 κγ cpe / ļHnn xapaiaepMCTHMecKan, qnnHa ΓΡ Nocni npOMblBOK 68 MM. 15 IļPHMflP 14 ripoi4ecc of npmviepaM 7-9 6bin ποβτορθη co cneflyK) iiļMMM Μ3ΜβΗβΗΜ * ΜΜ: Mcnonb3oeanM o6pa6oTaHHy »o THP cured Fabric B, coflep > xaHMe sulfuric KMcnoTbi b προπμτοηηομ BaHHe 140 mn / n (KOHLļeHTpaLļnn KMcnoTbi 5.25 N) ΒρβΜΒ οτθβρ > κΑβΗΜη 3 naca. Bna > KHocTb tkbhm b Hanane npololecca OTBep > KfleHMfl okojio 57% (ot Beca o6pa6oTaHHOM THP tkbhm). Pe3ynbTaTW McnbīTaHMfi otom τκθημ m cpaBHMTenbHoro o6pa3iii o6pa6oTaHHofi THP TKaHM (cpaBHMT. B) npuBefleHbi b Ta6n. 9.

TaftuHua-8 ΠρΜΜβρ Yron HeCMMHaeMOCTM 0 Bna > KHOM OCHOBbl ripOHHOCTb Ha pa3flMp 3αμβηαορΦ FR xapaKT. AnMHa mm nocne 40 npOMblBOK 14 150 2,112 56 CpaBHMT. 90 2,976 52 riPHMen 15 npnolecc from npnMepy 14 noBTopnnM c o6pa6oTaHHiii THP TKaHbio A. Pe3ynbTaTbi McnbrraHMM 3tom tkbhm ΒΜβοτβ c pe3ynbTaTaMH cpaBHMTenbHoro o6pa3i A npuBeAeHbi b Ta6nmee 9.

Ta6niiua 9 ΠρΜΜβρ yron HOCMMHaeMOC TM BJiaKHOM 0 OCHOBbl npOMHOCTb Ha pasAMp 9ΑΜβΗΑ0ρφ FR xapaKT. AnMHa mm nocjie 40 fipOMblBOK M3HOCO-CTOMKOCTb% ycKop. 15 140 1.056 70 11.0 CpaBHMT. 95 1,540 55 9,2 ΠΡΜΜβρκι 16.19, Οτρβ3ΚΜ ΤΚβΗΘΜ A ΑΑΜΗΟΜ 20 Μβτροβ, TKaHM C AJIMHOM 30 ΜβΤρΟΒ, TKaHM E Α-ΠΜΗΟΜ 30 ΜβΤρΟΒ 6blJlM CLUMTbl ΒΜβΟΤΘ M nponyi Hbi ABa Mepe3 pacTBop, coAep > KamMM 350 r / n βοαηογο pacTBopa DMDHEU from npMMepy 1.9 r / n 98% cepHot KMcnoTbi m 2 r / n CMaHMBaiomero areHTa from npMMepy 2. CoalMaPlMc mActIcn b pacreope cocTaBMna 1.84 N, a 16 LV 11199 pH ΜβΗββ 1. M36brroK pacTBopa οτχο / ιμ M3 Ha6yxuieM τκθημ, κοτορνοο 3βτβΜ npn Biia > KHOCTM OKOTio 52-60% (ot Beca o6pa6oTaHHOM ΤΗΡ τκθημ) m MMHMMajlbHOM Η3ΤΗ? ΚβΗΜΜ, flOCTaTOHHOM TOJlbKO flJl ft npeflOTBpaUļeHM51 npoBucaHMfl, Hamota / iH Ha Ba / IOK, o6epHynn nnacTMKOBbiM jimctom m npoflon > KanM MefljieHHO BpauļaTb eanoK b TeneHMe 22 MacoB npn κομηθτηομ TeMnepaType (18 ° C) flo οτββρχςΑβΗΜΗ DMDHEU. 3axeaT pacTBopa TKaHbto cocraein Afia τκθημ A - 72%, C -59%, P - 72% μ E - 70%. Bce OTBepTABABHHbie TK3HM 6blJlM 3ΘΤΘΜ npOMbITbl BOflOM, Η6ΜΤρ3.ΠΜ30Β3ΗΝ M CH0B3 npoMbiTbi boaom b ΜθΐϋΜΗβ fl / ifl KpauieHMB Ha BanKax. 3aTeM 6bin npoBefleHa ontheMaNeTeTeMiCiTM, B χοαθ κοτοροϋ K2DCA3B M3 Μβτωρβχ ΤΚΘΗΘΜ 6blJia nponyuLLeHHa wepe3 BaHHy, coAepx < aiAyK > 10 r / n npoM3BOflHOM 3φΜρθ ηθμοηηομ JKMpHOM KMCJlOTbl B ΚΒΗβΟΤΒβ Π / ΙΘΟΤΜφΜΚΘΤΟρθ (Τ0ρΓ0Β3Β MapKa CPOSOFTXME, BbinycKaeMaB φΜρΜοίί " Crosfield Textile Chemicals). BnajKHan TKaHb 6bina BbicyiueHa oTcacbiBaHMeM, a 3βτβΜ HarpeeoM b paclipe TeMnepaType 150 ° C. nonyHeHHbie tbkmm o6a30M HeTbee τκθημ 6νπμ McnbīTaHbJ, a pe3ynbTaTbi μοπντθημμ Heo6pa6oTaHHbix m o6pa6oTaHHbix τκθηθμ πρΜΒβΑβΗω b Ta6 / iMixx 10-16.

Ta6nMU 10 1. Υοθακθ. (lpMMep TKaHb (%) OcHoea (%) Υτοκ A 13.2 6.0 16 06pa6.A 5.5 4.0 C 9.9 5.1 17 06pa6.C 4.0 4.3 D 8.0 6 , 3 18 06pa6 D 2.7 4.6 E 5.7 7.1 19 06 Pa 6. E 3.6 4.2 npoHHoeTb Ha pa3flMp b HanpaeneHMM yTKa no ^ / lMeH (^ opφy 17

Ta6fmua 11 ΠρΗΜβρ TKaHb ripOMHOCTb (ΚΓ) A 1.94 16 06pa6. A 1.87 C 4.64 17 06pa6.C 3.46 D 2.68 18 06pa6.D 1.91 E 1.63 19 06pa6. E 1.30 3rd RowHHocTb Ha pa3pbiB from CTaH / lsTy BS2756 o6pa6oTaHHoYo τίοημ m TonbKo flrm o6pa6oTaHHotf tk3hm C nocne 50 προωωθοκ npn τβΜΠβρβτγρβ 93 ° C (ΜΒΓΚοΐί BOfloū from CTaHflapTy DIN53920)

Ta6jiMua 12 ΠρΜΜβρ TKaHb nPOHHOCTb B HblOTOHaX OcHoea Υτοκ A 1252 690 16 06pa6oT. A 1030 619 C 1237 794 17 06 P 6 O C 1251 609 11.0 MbiTan C 1251 800 17 RhoMiTiO6 Pa6 C t 1183 683 D 1145 740 18 06pa6oT. D 913 597 E 760 529 19 06pa6oT. E 617 406 18 EN 11199

4. McnbeeThe Hue Ha 3aMeflneHMe ropeHna npoBOflmiocb, KaK HAPPY Bbime, HO nOCJie 50 npOMbIBOK lagmiua 13 ΠρΜΜβρ TKaHb CpeAHnfi xapaKT. AJiMHa (mm) A 52 16 06pa6.A 56 C 57 17 06pa6.C 56 D 58 18 06pa6. D 68 E 77 19 06pa6. E 79

5. ymbi HecMUHaeMocTM

TaSnui 14 ΠρΜΜβρ TKaHb BnaKHan O Cyxaa (?) A 100 90 16 06pa6.A 145 105 C 95 130 17 06pa6.C 145 135 D 95 95 18 06pa6. D 145 110 E 95 110 19 06pa6. E 145 130 6 OiļeHKa HecMMHaeMocm (DP) npoBOflu / iacb, Kak yKa3aH0 Bbiine Ha TK3Hfix Nocni oahom npoMbiBKM wheel TeMnepaType 95 ° C mc BbicyLUMBaHMeM of npnMepy 2 19 15 lagjnma ΠρΜΜβρ cured Fabric ΟμβΗΚβ DP CyuiKa Ha ββρββκβ CyuiKa b 6apa6aHHe A 2 2- 3 16 06pa6oT. 3-3.5 3-3.5 C 2 2 17 06pa6oT. C 3-3.5 3-3.5 D 2 2-3 18 06pa6oT. D 3-3.5 3.5-4.0 E 1-2 2 19 06pa6.0 E3 3-3.5 7. Pe3ynbTaTB aHanM3a o6pa6oTaHHViOn m nocne 50 npoMbiBOK npn τβΜπβρβτγρβ 93 ° C (μβγκομ boaom no CTaHflapTy 53920 )

IaS / iMua 16 ΠρΜΜβρ TKaHb flo npOMbIBKM nocne npoMbiBKM% P% N% P% N A 3.2 3.1 2.6 2.5 16 06pa6oT. A 3.0 3.5 2.7 3.1 C 2.9 2.9 2.3 2.2 17.06.6 C 2.7 3.3 2.6 3.0 D 2.3 2.1 2.0 1.8 18 06pa6oT. D 2.2 2.6 2.0 2.3 E 2.6 2.3 2.4 2.0 19 06pa6oT. E 2.4 2.7 2.3 2.5 8. CBgTOCTOMKOCTb OKDaCKH.

CTOMKOCTb K ΟΒΘΤγ ΚΟβΗΟΗΟΒΟίί flyrH Μ3ΜβρΗ / 1Μ B ΟΟΟΤΒβΤΟΤΒΜΜ CO CTaHAapTaMM BS02 B 106, 1978. 20 EN 11199 9. 3KcnnyaTai4MOHHbie ceoficTBa. 3aMeTHoii pa3HiBi Me > Kfly 3KcnjiyaTaLjM0HHbiMM CBoiicTBaMu Heo6pa6oTaHHbix m o6pa6oTaHHbix τκβΗβΜ A, C, D μE, οοοτΒβτοΒβΗΗΟ, o6Hapy > 10. BnajKHOcTb

Bnax < HOCTb o6pa6oTaHHbix v \ Heo6pa6oTaHHbix τκθηθμ A, C - E, ΟΟΤΒβΤΟΤΒΘΗΗΟ, OnpefleniUlM ΠΟΟ / Ιβ Bblflep > KMBaHMfl B T6H6HM6 24 M3C0B ΠρΜ OTHOCMTe / lbHOii ΒΠΘίΚΗΟΟΤΜ 65% nyTeM Β3Β6Ι ± ΙΜΒ3ΗΜΑ ΤΚβΗβΜ Flo H ΠΟΟίΙΘ CyUUKM B T8H6HMB 2 M3C0B ΠρΜ ΤβΜΠβρβΤγρθ 105 ° C. BnaJKHOCTb TKaHefi 6blJia npuMepHO Ha 0.5% MeHbuue, μθμ Bna > KHOCTb o6pa6oTaHHbJX τκθηθμ. MM ε6pa30M, δ6a6OcKe DHDMEU yBe / iHHMBEe BJiaronorjioifleHMe npn OTHOCUTe / lbHOii BJia > KHOCTM 65%. 11. ΠΟΓΠΟΙΙ ^ βΗΜβ BOflbl.

Heo6pa6oTaHHbie n o6pa6oīaHHbie TKaHU A, C - E 6binn προΜωτω HLCC b MaiUMHe "Servis Quartz" Nocni Mero 6bmo onpefleneHO κο / ιμηθοτθο OCTaTOMHOM BOflbl ΠΟΟΠβ LļeHTpn4) yrVipOBaHMfl BJia > KHblX TKaHeii B ΤβΗβΗΜβ 4 MMHyT npn ckopocth 1000 o6 / mmhk > 06pa6oTaHHbie TKaHki yflep KMBanM MeHbine BOflbl, ΜβΜ Heo6pa6oTaHHue m, cneflOBaTenbHo, o6pa6oTxa DHDMEU yMeHbiuaeT BOflonomoifleHMe. ΠρΜΜβρω 20 - 26

TicaHb flea Kycxa xnonMaTe6yMa) KHoro rma 3111 ajihhom 100 μm BecoM 0.295 kb / m2 6bmn noflBepmyrbi φβρΜβΗΤΗΟΜ ΟΜΜΟτκβ (enzymically desired), προΜωτω iibenoMbK BOflopofla b iflenoHHou cpefle. TxaHb 6bma B3 «Ta HenocpeflCTBeHHo c TKCKOR craHKa. OT6e / iHHaB TKaHb BecoM 0.27 κγ / μ2 6bina paspeaaHa Ha 4 Kycxa from 50 μ, κοτορωβ 6bmn noflBepmyrbi onPLMMBM o6pa6oTKH V, X, Υ μ Z, οοοτΒβτοτββΗΗο. 3tm onepaijMH npeflcraBnaiOT co6oii pa3JiMHHbie κομ6ι / ιη3Ι4ΙΜ cneflyK > LflHX bmaob οδρβδοτκιι: o6pa6oTKa DHDMEU c οτΒβρτκΑβΗΗβΜ, o6pa6oTxa οοθαμηθημθμ THP OTBepMfleHueM c h ycaflKa μθχθημμθοκμμ o6 > KaTneM. 3τμ κομ6μη8ι0TpaxceHbi b Ta6nmļe 17. 21

Ta6 / iMi4a 17

OnepauMsi V X Y Z Neean ΒτΒβρ > ΚΑβ HHe DHDMEU OTBep KAEHne THP ΟΤΒβρ > ΚΑβΗΜβ THP ΚΑτΚΑβρχςηβΗΜβ THP BTopan - - MexaHHH. ycaAKa Tperan ΟΤΒβρΧ ^ βΗΜβ THP - ΟΤΒβρΜΑβΗΜβ DHDMEU ΟτΒθρχςαβΗΜΘ DHDMEU MeTBepTan MexaHHH. ycaAxa MexaHHH. ycaAKa MexaHMH. ycaAKa MexaHMH. ycaAKa

06pa6oTxa THP c οτΒβρκΑβΗΜβΜ ear step of Operations V, X, Υ μ Z ripoLļeflypa o6pa6oTKH TKaHU οοοτβθτοτβοβ3πa onMcaHHofi fl / in tiohm A. BNA > less than of TK3HM ΠΟ BblXOAe M3 nponUTOMHOrO solution of NPM ΒΒΙΠΟΠΗβΗΜΜ onepaLļnn V cocraBuna okojio 80% (ot EECA 0ΤΒβρ > ΚΑβΗΗ0Μ τκθημ, o6pa6oTaHHofi DHDMEU τκ3ημ) m 100% ajih onepaMfi X, Y n Z (ot eeca ΟΤββΠβΗΗΟΐί TK3HM).

06pa6oTKa DHDMEU cοτβθρκαθημθμ a ^ si for Operations VYmZ npoiļeflypa o6pa6oTKM τκθημ cooTBeTCTBOBana onncaHHoii b npnMepax 16-19, 3aTeM νιοκηιοΗβΗΜβΜ, whereby to nponmoHHbiti solution was coAeparan 325 r / n BOflHoro solution of DHDMEU, 90g / l 98% cepHoii KucnoTbi 2 r / n CMaMHBatoiiļero AREMA, ncnonbsoBaHHoro b npuMepe 2, m 18 r / n 0nyopecLlMpyK) L4ero ocBeTnNomMa arArrIrrrriHhBoro κ κΜοηοτβ μ M3BecTHoro KaK JKMAKOCTb Leucophor BCP φκρΜω Sandoz. Bna > KHOCTb τκθημ from BbixoAe H3 pacTBopa cocraBuna 100% α-πη onepaLMM Y n Z (ot eeca tiohm, o6pa6oTaHHotf THP) m 79% AJifl npuMepoe 25 m 26 (ot eeca mcxoahom tk3hm).

MexaHMHecKan ycaAxa οβκβτιιβΜ llpoLlecc MexaHHH6CKoPi ycaAKM ο6χοτμθμ npoBOAnnn If KnaccMMecKOM MaujMHe 'Sanforizer' b οοοτβθτοτβμμ c onncaHueM, πρΜΒβΑβΗΗωΜ Textile Bulletin Dyeing / Printing / Finisching 2/86 crrp. 14, 16, 20, 22 m 27 Ilpoiļecc BKntOMan step of Operations o6pa6oTKH napoM, perynnpoBaHHR niupMHbi, πρμχοτμβ κ PACT? IHyToPi pe3MHOBOM neHTe, npn chbtmm ΗβπυκβΗΜη κοτοροίί npoMcxoAMT ycaAKa tiohm, cyujKM ο6χοτμθμ Me) Kay HarpeTbiM MeTannusecKUM LļMnMHApoM m nornoiiļaKoinuM cnoeM, n προιοτκΜ. Tip 3tom MaujMHa 6bina HacrpoeHa Ha ycaAKy 5% Ann onPLMM V, X, Y n Z. 22 LV 11199 ΟΠΤΗΜΘΟΚΟΘ ΟΟΒβΤΠβΗΙΙβ

OnTMHecKiiBiTTiMTejib bboamjim b npnonmoMHbitf pacreop DHDMEU, Anfl onPaint V, Υ μ Z h b npoMbiBOMHyfo BOAy noc / ie o6pa6oTKH THP α * ιη onepaLlnn X.

PeaYAbīaTbi CBoiicTBa o6pa6oTaHHbix TKaHefi npoeepjuiM Ha ΗβτΒβρτοΜ 3Tane onepaLļnii V, Y and Z, a HeKOTopbie M3 cboūctb Ha ποοπθαηθμ stane step of Operations X h paHHHx 3Tanax onepaLļHii X, Υ μ Z. B Ta6jiMLļe 18 npneeAeHa οβοακθ onepaiļuPi aji * npuMepoe 20-26 h cpaBHMTenbHbix npuMepoB D - C.

Tafrinua 18

flpMMep TKaHb CeoflKa onepauMM 3Tan onPaBM 21 3 Y THP, DHDMEU 22 3 Z THP, MexaHMH. ycaAKa, DHDMEU 23 4 Y THP, DHDMEU ΜβχβΗΜΜ. ycaAKa, 24 4 z THP, MexaHHM. ycaAKa, DHDMEU MexaHMH. ycaA «a 25 3 V DHDMEU, THP 26 4 V DHDMEU, THP μθχθημμ. ycaAKa CpaBHMT. D 4 X THP CpaBHMT. E 1 X McxoAHan o6eci4BeweHHafl TKaHb CpaBHHT. C 1 V Tonbock DHDMEU 1. YcajmL · B Ta6jimļe 19 πρΜΒβΑβΗω pe3y / ibTaTbi HcnbīTaHMii If ycaAKy from ΜβτοΑΜΚβ, oniicaHHOM b npnMepax 16-19, nocne 1 m 50 npoMbiBOK. 23

Ta6nMqa19 ΓΙρΚΜβρ% ycaAKH nocne yKa3aHHoro sncna mmkjiob προμβιβκμ 1 50 OCHOBa γτοκ OCHOBa γτοκ CpaBHHT. C 1.2 2.2 2.3 2.5 CpaBHMT. F - 12.8 5.6 CpaBHHT. E 3.9 3.5 12.4 8.8 CpaBHMT. D 1.0 2.8 7.3 5.9 21 1.4 2.1 4.4 3.5 22 1.8 2.2 4.7 3.3 23 +2.9 1.6 +2 3 2.1 24 - - +2.3 1.8 25 2.0 2.4 6.3 4.0 26 +3.1 2.1 +2.4 2.5 2ρΜΜβΠβΗΗβ: nono > KMTenbHb «M 3b3Κ , HanpuMep, + 2.3% 03HaMeT, mto nocne nPOMbIBKH ΜΜΘΘΤ M6CT0 Ηβ ycaflKa, 3 γΒβΠΜΜΘΗΜΘ ρθ3ΜβρθΒ. 2. npoMHoeTb Ha pasAup b HanpaBJieHHM yn < a no 9 / ΐΜβΗΑορφγ.

Ta6 / iHl 20 ΠρΜΜβρ npOMHOCTb (ΚΓ) OCHOBa Υτοκ CpaBHMT. 0 3,00 3,00 23 2,20 2,20 24 2,50 2,40 26 2,40 2,20 3. IlpOMHOCTb Ha pa3pblB B COOTBeTCTBMM CO CTaHflapTOM B 2756 24 EN 11199

Ta6jimia 21 ΠρΗΜβρ flpOMHOCTb (H) OCHOBa Υτοκ CpaBHMT. D 1262 751 23 1010 572 24 1012 575 26 1014 580 4. 3aMeAneHne ropeHMfl nocne 50 npoMbiBOK (MeTOflUKa Haha Bbime)

Taurmua 22 ΠρΜΜβρ CpeAHflfll ΑΠΜΗ3 (mm) CpaBHMT. D 60 23 62 24 67 26 53

5. yrnbi HecMMHaeMocTM

TaS / mua 23 ΠρΗΜβρ Bna) KHocb (0) Cyxaa (°) CpaBHMT. C 130 90 CpaBHMT. F 65 90 CpaBHMT. I 95 70 23 140 100 24 140 100 26 135 100 25 6. OijeHKa HecMMHaeMocTM (DP) nocne 1 npoMbiBKH npn TeMnepaType 95 ° C m cyujKe no npMMepy2 (μθτοαηκθ õncaHa Bbiiiie)

Ta6 / iMi 24 ΠρΜΜβρ OueHKa (DP) CyuiKa Ha Ββρββκβ CyuiKa b 6apa6aHe CpaBHHT. C 3-3.5 3-3.5 CpaBHHT. F 1-2 1-2 CpaBHHT. D 2 2 23 3-3.5 3-3.5 24 3-3.5 3-3.5 26 3 3 7. BnaMCHOCTb

OnpefleneHMe BnsoKHOCTM τκβημ npoBOAnnM b οοοτβθτοτβμη c luckHMeM npuMepoe 16-19. BnajKHoerb TKaHU b npnMepax 23, 24 m 26 0Ka3anacb Ha 0.5-1% Bbiiue, ηθμ drives cpaBHmenbHoro npMMepa D (npn cyuiKe b nenu). CneflOBaTe / ibHO, o6pa6oTo DHDMEU yBennMMBeT paBHOBecHy »o BJia &Kt; KHOCTb npn OTHOCMTBJlbHO BJ > KHOCTM 65%. 8. ΠοΓ / ιοιμθΗΗβ BOAbi ΠροΒβρκθ ocTaTOHHofi B / ia) KHOCTM nocne oilHPMc | 3yrvipoBaHnn npoBOflMnacb τθκ we, κβκ μ β npnviepax 16-19 flnn TKaHeii from npnwepaM 23, 24 m 26 m from cpaBHMTenbHOMy npnMepy D, TKam npuMepaM 23, 24 m 26 coxpaHflnu Ha 22% MeHbLue enar, ηθμ TKaHb from cpaBHMTenbHOMy npnMepy 0. CneaoBarenbHO, o6pa6oTKa DHDMEU yM6HbUJaeT nornomeHHe Boflbi. ΠρΜΜβρ 27 06pa6oTaHHan THP TKaHb A nponHTbiBanacb b pacTBope, coAepx < aBiMe 250 Mn / n 45% pacreopa DHDMEU, ncnonb3oeaHHoro b npMMepe 1, h20 r / n 98% cepHoue KHcnoTbi, pH patrreop cocraBnnn 1.7, κοΗμβΗτρβμΜη KHcnoTbi 0.2 N. nponnTaHHyio TKaHb 0OKMMann ao Bna > KHocrn 75%, nocne Measured HarpeeanM β τβπβΗΜβ 3 MHHyT b nn n nn n TeMnepaType 90 ° C flnn nonyneHnn BnajKHocTM 10%. nocne οτογο TKaHb cpa3y > κβ repMeTM3npoBann b nnacTHKOBOM naKeIe Ann CoxpaHe eNe Bna > KHocTM h BbiAep > nocne 3τογο TKaHb BbiHynn h npoMbinn, KaK no npnMepy 1, Bbicyajnnn h noABeprnu 50 26 LV 11199 npoMbiBKaM Paste TeMnepaType 93 ° C. YcaflKa o6pa6oTaHHoii τθκμμ o6pa30M TKaHM from οοηοβθ cocraBM / ia 5% of cpaBHeHMKJ c 10% fl / in npoMbrroii τθκμμ > 27 E 11199 ΦΟΡΜΥΓΙΑ Μ30ΒΡΕΤΕΗΜΛ 1 Cnoco6 o6pa6oTKM tkshh, omnunaioimjūcn MEM, hto c iļenbīo ynpoMHeHnn τκθημ μ οθηβΓΗβΗΜη yxofla 3a hepi BKniOHaeT BTopoū npoLļecc οβρββοτκΜ Lļermiono3HoPi τκθημ, YWE npouieAiuePi o6pa6oTKy b xoAe nepeoro npoiļecca, npuneM πβρβωΡί min BTopoPi npoiļecc πρβΑοτθΒ, πηβτ co6oPi o6pa6oTKy τκθημ coeAUHeHneM ham κοηα6ηο3τομ τβτρβ KMC (οκομμθτμπ) φοοφοΗΜη μ nocneAyioiiļyto nonMMepn3aiļmo, a APyroii m yKa3aHHbix nepBoro W1M ΒΤΟρΟΓΟ npOLļeCCOB ΠρβΑΟΤΒΒΠΑΘΤ C06oŪ ΠρΟΠΜΤΚγ TK3HM HecaMOKOHAeHcnpyiomnMcfl oKCHMemnaMMAOM c of MeHbLuePi mepe AByMfl oKcuMeTunbHbiMH rpynnaMM, κοτορωβ MoryT 6biTb a / iKnnnpoBaHHbiMn, c nocneAyioiiļePi peaKiļPiePi τκθημ c yKa3aHHbiM OKcuMeTunaMUAOM b npncyTCTBMM βοαηογο pacTBopa KucnoTbi. 2. Cnoco6 from nyHKTy 1, ommivaiomucmme, hto nepebiPi nololecc Βκηκ) Η3βτ o6pa6oTKy οοθακηθημθμ nnn κοηαθηοθτομ οοφοΗνιη h nocneAyioiiļee οτββρ > ΚΑβΗΜβ βμμμθκομ. 3. Cnoco6 no nyHioy 1, omnu ^ atovuuucp meM, hto ΒτοροΡί npoiļecc BKntoHaeT o6pa6oTKy coeAMHeHneM min κοηαθηοθτομ φοοφοΗΜη n nocneAy > OLILYK > o6pa6oTKy θμμμβκομ. 4. Cnoco6 from nio6My M3 npeAiuecTByioiJmMM nyHicroB 1-3, omnMMMMM, hto OKCMMeTMnaMMA b boahom pacrBope c pH MeHbLue 3 pearnpyeT c TKaHbio. 5. Cnoco6 no n o o ooMy M3 npeAwecTByiouMX nyHKTOB 1-4, omNaMeHHUuMMM, hOcMMeMaMaTeMaTe cKcHiHbio, ena KHOCTb κοτοροΡί cocTaBnneT 6 - 90%.

6. Cnoco6 no nyHioy 2, omnuvasomuūc m m, hto OKoMeTMnaMHA b boahom pacrBope goodwill TKaHbio, BJia &kt; KH0CTb κοτοροϋ cocraBnaeT 6 - 30%. 28 7. Cnoco6 from JiK) 6oMy M3 npeflichiTBytylMx nyHtcroB 1-5, omu 4aoLU, uucpMM, mto OKCMMeTM / iaMMA b boahom pacTBope c pH MeHbiue 1 pearnpyeT c TKaHbto, B / ia KHocTb κοτοροίί cocraBnneT 30-90%. 8. Cnoco6 from nyHKTy7, omnomodomic m m, mto OKCMMeTM / iaMMA pearnpyeT c TKaHbto, b boahom cpe ^ ec KOHLlempaLlMeM KHcnoTbi 1 - 6 N. mto οκομμθτμπθμμα npeflcrraBJifieT co6ofi OKCMMeTMnnpoBaHHyto 4MtcnMMecKyto MoneBMHy mjim ee 0-a / iKMpoBaHHyto npoM3BOAHyio. 10. Cnoco6 no nyHicry 9, omnunaiotMuucR MeM, mto OKCMMeTMJiaMMA ΠρβΑΟΤβΒΧΙΛΘΤ C060M 1.3, NN - AHOKCHMeTHfl - 4,5-ΑΜγμαροκομθτμπθη MOMeBnny. 11 Cnoco6 of nto6oMy M3 npeAwecTByiomMX nyHKTOB 1-10 omnu ^ anmuucp MEM, mto cured Fabric o6pa6aTbieaeTcn boahhm pacTBopoM KOHAeHcaTa οοθαμηθημα τβτρβ KMC (οκομμθτμπ) φοοφοΗΜ "μ ΜΟΜβΒΜΗΟΜ, a cure and 3aTeM > KAaeTCfl ra30o6pa3HbiM aMMMaKOM. 12. Cnoco6 nio6My M3 npeALuecrBolylMx nyHicTOB 1-11, OmnHaKHMuucftMM, mto TKaHb M3roToeneHaM3 xjionMaTo6YMa) KHbix BOJIOHOH MJIM HX CM6CM C A 50% OT Beca TK3HM nOHH3 < t HpHblX BOnOKH. 13. Cnoco6 no nO6My M3 npeALuecTBytouMX nyHKTOB 1-12, omnunaiOcfj meM, mto cyxoii eec coAepttamerocn b ήοημ OKCHMeTHnaMHAa cocTaBnaeT 6-20%, a wishMMep οοθαμηθημβ mjim κοηα © ηο3Τ3 TeTpa kmc (oKCMMeTMn) φοοφοΗΜΒ - 8-20%. 14. Cnoco6 from Jito6oMy M3 npeAuiecTBytomMX nyHKTOB 1-13, omnuHatomuucp meM, mto οκομμθτμ / ιθμμα pearMpyeT c TKaHbto, HaxoAHU4eMC? T coctobhmm pacTfl &Ke; 15. Cnoco6 from Jito6oMy M3 npeAiuecTBytOLiMX nyHKTOB 1-14, omnuvafolmMicRMM, mto noc / ie BToporo npoLlecca o6pa6oTKM TKaHb noABepraeTcn MexaHMMecKoii ycaAKe οδχοτΜβΜ.

16 Cnoco6 of Jito6oMy M3 npeAiuecTByK > MMX nyHtcroB 12-15, omnuvaiow, uucR MEM, mto xjionMaTo6yMa > KHbie eo / ioKHa o6pa6aTbtBatoTCB boahum pacTBopoM KOHfleHcaTa TeTpa KMC (οκομμθτμ / ι) φΟΰφΟΗΜΒ Μ ΜΟΜβΒΜΗΟΜ Μ cure and > KAaeTCfl ra3006pa3HblM aMMHaKOM, Nocni Mero cured Fabric nponMTbJBaeTcn boahum pacTBopoM 1,3-ΝΝ αμοκομμθτμπ-4,5-AMfMApOKCMSTMJieH ΜΟΜβΒΜΗΝ C pH MeHbUJe 1 M KOHLļeHTpaiļMeM KMCJlOTbl 1 -4N 29 E 11199 M wheel BJiajKHOCTM τκθημ 30-90% noc / ie Mero cured Fabric noflBepraeTCH MexaHMMecKofi ycaAKe o6 > KaTMeM . 17. Coco of / iK) 6oMy m npefliuecTByiomMX nyHKTOB 9-15, omma ^ fom m m m, mto b xofle BToporo npoiolecca oKCMMemnaMMA pearnpyeT c TKaHbK >, BJiajKHocrb κοτοροΜ cocraenneT 6-30%, b BOflHbix ycnoBMHX -140 ° C. 18. Cnoco6 no npeAiuecTByiomMM nyHicraM 1 nnn 2, omnuva tomuucn meM, mto oh cooTBeTCTByeTnio6oMy M3 npMMepoe 1-15. 19. Cnoco6 of npeAUjecTBytoinwM nHKMaM 1 v m 2, omnuvaomuc mM, mto oh cooTBeTCTByeT nio6oMy M3 πριίΜβροΒ 16-24. 20. Cnoco6 no nyHiory 3, the most powerful, mto oh cooTeeTCTByeT nto6oMy M3 npMMepoB 25 wine 26. 21. Cnoco6 no nyHioy 1, omnu'iaiouuuucn m, mto oh cooTBeTCTByeT npnMepy 27. 22. TKaHb, o6pa6oTaHHa ^ cnoco6oM no nio6oMy M3 npeALuecTByK > iiHHH NYHKTOB 1-21. 23. TKaHb, o6pa6oTaHHan cnoco6oM no nyHioy 2 μπμ no nto6oMy M3 nyHKTOB 4-13, ecnM οημ αοποπηηιοτ nyHKT 2. 24. TKaHb, o6pa6oTaHHaa cnoco6oM no nyHKTy 3 μπμ no nyHKT3M 16 μπμ 18, ecnM οημ ΑοποηΗΛιοτ nyHKT 2. 25. TKaHb, o6pa6oTaHHaa cnoco6oM no nyHicTy 3 Unu no nio6oMy M3 nyHKT0B 4, 5 -15 m 20, eon ohh AononHHtoT NYHKr 3. 30

Claims (25)

A method for treating a fabric, characterized in that, in order to increase the strength and simplify the care of the fabric, it comprises two successive processing processes, one of which involves treating the fabric with a tetrakisoxymethylphosphonium compound or a condensation product thereof, while the second process comprises: impregnation of the fabric with condensed oxymethylamide independently having at least two oxymethyl groups which may be alkylated, after which the fabric is treated with said oxymethylamide aqueous solution of the aqueous solution. Method according to claim 1, characterized in that the first process involves treating the fabric with a phosphonium compound or a condensation product thereof and further curing it with ammonia. 3. A method according to claim 1, wherein the second process involves treating the fabric with a phosphonium compound or a condensation product thereof and further curing it with ammonia. Method according to any one of the preceding claims, characterized in that the oxymethylamide reacts with the fabric in an aqueous solution having a pH of less than 3. Method according to any one of the preceding claims, characterized in that the oxymethylamide reacts with a fabric having a moisture content of 6 to 90%. Method according to claim 2, characterized in that the oxymethylamide in the aqueous solution reacts with a fabric having a moisture content of 6 to 30%. Method according to any one of claims 1 to 5, characterized in that the oxymethylamide reacts with a fabric having a moisture content of 30 to 90% in an aqueous solution having a pH of less than 1. 8. A method according to claim 7, wherein the oxymethylamide reacts with the fabric in an aqueous medium having an acid concentration of 1 to 6 N. 1 Method according to any one of the preceding claims, characterized in that the oxymethylamide is an oxymethylated cyclic urea or an O-alkylation thereof. 10. A process according to claim 9, wherein the oxymethylamide is 1,3, N, N-dioxymethyl-4,5-dihydroxyethylene urea. Method according to any one of the preceding claims, characterized in that the fabric is treated with an aqueous solution of urea tetrakisoxymethylphosphonium condensation product and urea and then cured with ammonia. Method according to any one of the preceding claims, characterized in that the fabric is made of cotton fibers or a mixture thereof with polyester fiber, which can account for up to 50% of the total fiber mass. Method according to any one of the preceding claims, characterized in that the content of oxymethylamide in the fabric is in the dry state from 6 to 20%, and the content of the polymer or condensation product of tetrakisoxymethylphosphonium is 8 to 20% of the total weight. Method according to any one of the preceding claims, characterized in that the oxymethylamide reacts with a fabric stretched in at least one of the warp or tissue directions. A method according to any one of the preceding claims, characterized in that, after the second processing, the fabric is suspended by mechanical pressing by pressing. Method according to any one of claims 12 to 15, characterized in that the cotton fibers are treated with a tetrakisoxymethylphosphonium condensed water solution and urea and cured with gaseous ammonia, then the fabric is impregnated with 1,3, N, N-dioxymethyl 4,5-Dihydroxyethylene urea water solution and reacts with it in water at a pH of less than 1, at an acid concentration of 1 to 4N, at a cloth humidity of 30 to 90%, and then subject the fabric to mechanical lubrication by pressing. Method according to any one of claims 9 to 15, characterized in that during the second process the oxymethylamide reacts with a fabric having a moisture content of 6 to 30% in an aqueous medium at a pH of 3 to 5 and a temperature of 90 to 140 ° C. 18. A method according to claim 1 or 2, characterized in that it corresponds to any one of claims 1 to 15. 19. A method according to claim 1 or 2, characterized in that it corresponds to any of claims 16 to 24. 20. A method according to claim 1 or 2, characterized in that it corresponds to example 25 or 26. 2 LV 11199 21. A method according to claim 1, characterized in that it corresponds to Example 27. 22. A fabric treated according to any of the preceding claims. 23. A fabric treated with a method according to claim 2 or any of claims 4 to 13, if it complements paragraph 2. 24. Fabrics treated by the method of paragraph 2 or by item 16 or 18, if it complements paragraph 2. 25. Fabrics treated by the method of paragraph 3 or by any one of claims 4 to 15, or by item 20 if it complements paragraph 3. 3