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LV10470B - Polyurethane foam and process for producing therof - Google Patents

Polyurethane foam and process for producing therof Download PDF

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Publication number
LV10470B
LV10470B LVP-93-33A LV930033A LV10470B LV 10470 B LV10470 B LV 10470B LV 930033 A LV930033 A LV 930033A LV 10470 B LV10470 B LV 10470B
Authority
LV
Latvia
Prior art keywords
polyurethane foam
foaming agent
mixture
flame retardant
starting component
Prior art date
Application number
LVP-93-33A
Other languages
English (en)
Other versions
LV10470A (lv
Inventor
Hetzen Hans Wilhelm
Original Assignee
Hetzen Hans Wilhelm
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27434579&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=LV10470(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from DE3933705A external-priority patent/DE3933705C1/de
Priority claimed from DE19893936227 external-priority patent/DE3936227A1/de
Priority claimed from DE19904003718 external-priority patent/DE4003718A1/de
Application filed by Hetzen Hans Wilhelm filed Critical Hetzen Hans Wilhelm
Publication of LV10470A publication Critical patent/LV10470A/lv
Publication of LV10470B publication Critical patent/LV10470B/lv

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/127—Mixtures of organic and inorganic blowing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Description

LV 10470 nOni/iyPETAHOBbll/! πεηοματερμαπ μ cnocoB ΕΓΟ nonyHEHn$ļ
HacTOfiLMee Μ3ο6ρθτθημθ othochtca κ nomiypeTaHOBOMy neHOMaiepnany (flanee ynoMHHaeMOMy KaK nyp-neHOMaTepnan)I MMeiomeMy ocoSeHHO OAHOpoflHyra aHenciyK) neHocipyKTypy, nopbi κοτοροιί cBoāoflHbi ot ranoreHnpoBaHHbix οοθαμηθημμ. TaKMe ranoreHMpoBaHHbie ymeBOflopoflHbie coeflMH0HMfl b HacTHOcrn, nonHOCTbfo ranoreHnpoBaHbie xnop$Topyrnepoflbi (ΧΦΫ) ncnonb3yioT no ypoBHto τθχημκμ b KanecTBe BcneHMBaioii4MX cpeflCTB. HacToaiAee M3o6peT8Hne flanee KacaeTcn cnocoāoB nonyneHMfl τθκμχ fiyP-MaiepnanoB, b KOTopbix oicyTCTByioT ranoreHMpoBaHHbie yrne80flopoflbi, ncnonb3yeMbie KaK BcneHMBaioLMee cpeflCTBO. nyP-neHOMaTepnanbi ncnonb3yiOTcn b 6onbiuMX κοπμηθοτβ3χ flnn caMbix pa3Hbix ueneii, HanpMMep, flnn noflyineK, xax npoMexyTOHHbie cnoM flna pa3MemeHnn nx nofl kobpom, β μηγκομ MečenM, flnn ynaKOBOHHbix ueneM, Kax M3onnpyiou4MM MaTepnan χμπμια μπμ Mopo3MnbHbix KaMep. flpOMbiujneHHO M3 Γ^Ρ np0M3B0flflT ΜΠΓΚΜΘ, ΟρβΑΗΘΧβΟΤΚΜβ Μ ΧβΟΤΚΜΘ ΠβΗω. ΜΠΓΚΜΘ ΠβΗΝ npoM3BOflnT o6biHHO c ncnonb30BaHMeM flMOKCMfla BOflopofla b KanecTBe BcneHMBaioiflero areHTa. Amokcma yrnepofla nonyHaiOT peaKflMeM flMM30MMaHaīa, c κοτοροΓο ηθημηβιοτ npopecc. m BOflbi, KOTOpyio fločaBnfiioT κ peaKLļMOHHOM CMeCM.
OflHaKO HeKOTopbie μπγκμθ neHbi nonynaiOT Taoce nocpe/ļCTBOM X<t>y, Mcnonb3yeMbix b KanecTBe BcneHMBaiomMx cpeflCTB. TBepfloneHHbie Maiepnanbi čonbīueM nacrbio npoM3BOflflT c ΧΦ^-πθηπιαμμμ cpeflCTBaMM. XΦy b 3tmx pennx ncnonb3yiOTcn b 6onbiuMX κοπΜΗβοτΒβχ. CymecrBeHHbie Koni/inecTBa BcneHMBatotflero areHTa τβρηιοτοη b npouecce npoM3BOflCTBa μπμ BbiCBo6oxflaioTcn, Korfla npM Mcnonb30BaHMM Maiepnana noMaioTcn οτθηκμ nop nyp MaiepMana. ΧΦΥ b KanecTBe BcneHMBaioiyero areHTa o6ecneHMBatoT xenaeMbie pe3ynbTaTbi bo μηογμχ οτηοιαθημαχ. Ohm npMflaiOT nonynaeMOMy nyP-MaTepMany cbomctbo HeBocnnaMeHeHMfl. flanee, nyP-MaTepManbi, ΠΟΠγΗΘΗΗΜΘ C 3MMM BCneHMBatOLLļMMM areHTaMM, MMeiOT M flpyrMe xenaTenbHbie Φμ3μηθοκμθ cBOMCTBa, TaKMe KaK, b nacTHOCTM, HM3Kan TennonpoBOflHOCTb, BbipaxaeMan b hm3kmx nnM6fla-ypoBHnx, nocKonbKy TaKMe MaTepManbi oneHb HyxHbi flnn npoM3BOflCTBa μπγκομ Me6enM, ομαθημμ (noflyiueK) m npM CTpOMTenbCTBe XMnbix μ προπΜΧ 3flaHMM. TaK, nyp-MaTepnanbi, nonyHaeMbie c stmmm βοπθημβ3τθππμμ, MoryT6biTb OTHeceHbi no KnaccMCļMKauMM κ rpynnaM c BecbMa bncokom TepMOM3onnuMeM, Heo6xoflMMbiM b pa3nMHHbix o6nacTbnx npMMeHeHMn neHOMaTepManoB. floāaBneHneM flononHMTenbHbix βθιαθοτβ nnaMeracMTeneM κ ομθομ μοχοαηνχ κομποηθητοβ μοχηο eifle 6onee ycMHMTb orHeynopHbie CBOMCTBa nonynaeMbix IT/P-neHOMaTepManoB ao orHeynopHbix KnaccoB B2 μ B1. nocKonbKy nyP-neHOMaTepManbi npoM3BOflnT M3 χμακμχ BcneHMBaeMbix MCXOflHblX ΚΟΜΠΟΗΘΗΤΟΒ, TO ΠρΜΜΘΗΘΗΜβ ΧΦΥ ΜΠΜ BOflbl npMBOflMT K OHeHb paBHOMepHoii πηθμοτομ CTpyKType c ManbīM očbeMHbiM βθοομ nonyHaeMoro MaTepnana. 3to oSecnenMBaeT npocToe ecneHMBaHMe MaTepMana β φορΜθ μπμ Ha nemre KOHBeMepa. 3Ta ποοπθαηππ npopeflypa πρΜΜβΗηβτοη, b MacTHOCTM, flnn nonyHeHMn M3onMpytoiflMx hmctob M3 TBepflbix nyP-neHOMaTepManoB, Mcnonb3yeMbix b 3flaHMnx m noflo6Hbix KOHCTpyKLļMnx. 3tot cnocoč, κροΜβ τογο, πο3βοππθτ npoM3BOflMTb neHO-liyP-MaTepMan c TBepflbiM -2- οποθμ Ha Kaxfloii οτοροΗΘ neHonncTa (H3 γμ6κογο μπμ χθοτκογο Maiepnana), nonyHan τθκμμ o6pa30M neHOCTpyKTypy Tuna ”c3Habmh”.
OflHaKO, c yweTOM acneKTOB 3aiqnTbi oKpyxaioiAeM cpeAbi Hančonee cymecTBeHHbiM b αθπθβομ MaTepnane m ero npon3BOflCTBe ηβππθτοπ to, hto Απη βοπθημβθημη τθκμχ MaTepnanoB, b HacmocTn χθοτκμχ ΠΥΡ-neHOMaiepnanoB, Mcnonb3yiOT nomu ncKmoHmenbHO ΧΦΥ b κθηθοτβθ βοπθημβθτθππ, a θτμ ΧΦΥ OKa3biBaioT KpaiiHe OTpMLļaTenbHoe αβηοτβμθ Ha 030H0Bbm οπομ, 6yflyHM pa3pywai0LAMMM 030H βθιαθοτβθμμ. ri03T0My πρμμθηθημθ τθκμχ βοπθημβθτθπθμ οοβοθμ ηθ xenaTenbHO m flaxe 3anpeineH0 βο μηογμχ cTpaHax. ri03T0My yxe HecKonbKO πθτ BeAyTcn cepte3Hbie μοοπθαοβθημπ c uenbīo ηβοτμηηο μπμ flaxe noriHOCTbio 3aMeHMTb ΧΦΥ b KanecTse βοπθημβθτθπθμ, BBMAy mx HexenaTenbHbix, pa3pyma}oiAMx 030H, CBOMCTB. ·
HanpuMep, McnbīTbieanoob npon3BOflCTBO μπγκμχ ΠΥΡ- neHOMaTepnanoB c οοηθτθημθμ μ3βθοτηογο floSaBneHna BOflbi κ ucnonb3yeMOMy neHOMaTepnany, coflepxameMy M30unaHaT Hapafly c flpyrnMM ΠρΜ3Η3Κ3ΜΜ, T3KMM 00pa30M, HTOČbl CO2 6bin OCHOBHbIM ΜΠΜ flOnOnHMTGJlbHblM ΒΟΠΘΗΜΒ3Κ)11|ΜΜ CpeflCTBOM, CHMXāfl ΜΠΜ flaxe npeflOTBpamap HexenaTenbHoe ββιοβοΘοχαθημθ BpeflOHOCHbix ΧΦΥ. Οαηθκο τθκμθ cnocočbi OKa3biBaiOT βρθαηοθ αθΛοτβμθ Ha Φμ3μηθοκμθ οβομοτβθ nonynaeMbix ΠΥΡ neHOMaiepnanoB. PaHHee o6pa30BaHne CO2 αππ βοπθημβθημπ npuBOflm κ TOMy, hto ΠΥΡ-neHOMaTepnanbi μμθιοτ 3HaHMTenbHoe κοπμηθοτβο OTKpbiTbix nop. JHanee, stot Maiepnan οοβοθμ ΜΠΓΟΚ, KOTfla OH ΗΘ nOilHOCTbK) Π0ΠΜΜΘρΜ30Β8Η, Μ ΤΟΗΚΜΘ ΟΤΘΗΚΜ ΠΟρ 3Τ0Γ0 Maiepnana πθγκο πομθιοτοπ. 3το ποβρθχαθημθ οτθηοκ nop μοχθτ 6biTb TepnuMbiM n flaxe xenaTenbHbiM y μπγκμχ ΠΥΡ-neHOMaTepiianoB, ho oho KpaiiHe HexenaTenbHO y τβθραηχ ΠΥΡ-neHOMaTepnanoB, y κοτορ^χ Tpe6yeTcn BbicoKan MexaHMHecKan npoHHOCTb.flanee, BOfla flnn npon3BOflCTBa CO2 b κθηθοτβθ βοπθημβθτθππ 0Ka3biBaeT βρθαηοθ αθμοτβμθ Ha M3onnTopHbie οβομοτβθ nonynaeMOro ΠΥΡ-neHOMaTepnana He3aBHCMM0 ot Toro, nonyHaiOT nu TBepflbiM μπμ μπγκμμ πθηομθτθρμθπ. HaKOHeiļ, ncnonb30BaHne BOflbi 3HaHMTenbH0 ynopoxaeT nonynaeMbiM ΠΥΡ-neHOMaTepiian, noTOMy hto oflHa nacTb BOflbi nnn npon3BOflCTBa BcneHMBaioiiļero CO2 Tpe6yeT jņnn yMacTnn b peaKUMM 16 nacTefi ΑΜΜ3011Μ3Η3Τ3, Τ.Θ. TaKOe ΚΟΠΜΗΘΟΤΒΟ βΜΜ3014Μ3Η3Τ3 ΠρΜΧΟΑΜΤΟΗ fl06aBnBTb Κ ΜΟΧΟβΗΟΜ ΟΜΘΟΜ ΚΟΜΠΟΗΘΗΤΟΒ. ΠρΜ MCn0Jlb30BaHMM ΧΦΥ Β Ka ΗΘΟΤΒΘ βοπθημβθτθππ Tpe6yeTcn 3HaHMTenbH0 MeHbiuee κοπμηθοτβο flMM30iļMaHaTa. flpyrne opraHMnecKMe MaTepnanbi, neTynMe no βρθμπ peaKUMM MCXOflHblX ΚΟΜΠΟΗΘΗΤΟΒ ΠΥΡ-neHOMaTepManOB, ΗΘ MOryT MCn0nb30BaTbCB ΜΠΜ ΗΘ OČnaAaiOT nOne3HblMM CBOMCTBaMM M3-3a Τ0Γ0, HTO ΟρΓΒΗΜΗΘΟΚΜΘ npoAyKTbi, CBo6oAHbie ot ranoreHa, oneHb ηθοτο πθγκο BOcnnaMeHMMbi μπμ Aaxe co3AaiOT c KMcnopOAOM B03Ayxa CMAbHbie B3pbiBHaTbie ομθομ. no3TOMy Τ3ΚΜΘ ΒΟΠΘΗ ΜΒΘΙΟΙΑΜΘ areHTbl HenpMrOAHbl Β ΟΤΗΟΙΑΘΗΜΜ ΤΘΧΗΜΚΜ 6e3onacHOCTM, m mx cneAyeT M36eraTb, Aa>xe θοπμ np0M3B0AMTenb TaKMx MaTepnanoB οΘθοπθημβθθτ ηθαθχηοθ yAaneHMe napoB opraHMHecKMx ΧΜΑΚΟΟΤΘΜ, BblCB06oxqaiOlMMXCn npM npeBpaiAeHMM. ΚρΟΜΘ ΤΟΓΟ, ΒΟ ΜΗΟΓΜΧ BbimeyKa3aHHbix o6nacTbax πρμμθηθημπ, 3aKpbiTbie nopbi ΠΥΡ-neHOMaTepMana MoryT pa3pbiBaTbcn npM ero Mcnonb30BaHMM, μ οργθημηθοκμθ napbl Μ ΧΜΑΚΟΟΤΜ M3 ΠΟρ ΜΟΓγΤ 33ΤΘΜ BblCB060XAaTbCB M C03AaTb OnaCHOCTb. -3- LV 10470 C Apyron CTopoHbi, ncnonb30BaHne BcneHMBaTeneii, CBo6oAHbix ot ranoreHa, 6bino onncaHO npn npon3BOACTBe ycToiiMHBbix κ ΥΦ οβηγπθΗΜίο OKpaiueHHbix nyP-neHOMaTepnanoB (cm. fln. 57-126 815). Χοτη θτη Maiepnanbi ηθ oOnaAaiOT Tpe6yeMbiM ManbīM oāteMHbiM βθοομ. flanbHeniune nonbīTKn 3aMeHHTb ΧΦΥ nnn CHH3mb ηχ κοπηηθοτβο Aenanncb πγτθΜ 3aMemnBaHnn B03flyxa b ncxoAHyfo cMecb flna nonnMepn3auMM nocpeflCTBOM MexaHHHecKnx npneMOB. TaK, μ3βθοτθη οποοοδ npuMeiuMBaHm B03flyxa μθχθηκηθοκμ b OH-coAepxaLL|nH κομποηθητ nnn b AHH30UnaHaTHbiii κομποηθητ nnn b o6a τθκηχ κομποηθητθ nocpeACTBOM nonacTen. Οαηθκο b τθκομ BbinonHeHnn A03npoBKa ΚΟΜΠΟΗΘΗΤΟΒ 3aTpyAHeHa H3-3a HepaBHOMepHOH nnOTHOCTH Β03ΑΥΧ0-CnHpTOBOM MJ1H B03AYX0-H30LļHaHaTH0n ηΟΧΟΑΗΟΗ ΟΜΘΟΜ. ΚρΟΜΘ ΤΟΓΟ, nopncTan cTpyKTypa nonyHaeMoro neHOMaTepnana οοβοθμ ηθ OAHopoAHa, KaK 3T0 τρβδγθτοη. A paBHOMepHan η TOHKan nopncTan οτργκτγρθ b κοηθηηομ neHOMaiepnane c HH3KHM oSteMHbiM βθοομ ηΒπηβτοη Heo6XOAMMblM ΥΟΠΟΒΜΘΜ fļnft ΧΟρΟΙΒΜΧ H30n«T0pHblX CBOHCTB ΠΟΠγΗΘΗΗΟΓΟ neHOMaTepnana. TonbKO ncnonb30BaHneM B03Ayxa b KanecTBe BcneHnBaioiAero areHTa tbkum cnoco6oM Henb3fl nonyHHTb xenaeMbin hh3kmh o6teMHbin Bec nopnAKa 30 γ/cm^ n Hnxe.
HaKOH eu, o6cyxAanacb 3aMeHa ΧΦΥ Ha ηθ nonHOCTbio ranoreHnpoBaHHbie ymeBOAopoAbi, Taxne KaK φτορηοτΗθ ymeBOAopoAbi (ΦΥ). Οαηθκο TaKan anbTepHaTnea ΧΦΥ ηεηηθτοη οηθηβ Aoporon n ee ΑβηοτΒηβ Ha pa3pymeHne 030Ha b TeneHne A^nTenbHoro nepnoAa βρθμθημ eme He nonHOCTbK) n3yneHO. Lļenbīo HacToniiļero n3o6peTeHnn ηΒπηβτοη nonyHeHne ΠΥΡ-neHOMaTepnana, nopbi κοτοροτο οβο6οαην ot ranoreHnpOBaHHbix γτπθΒΟΑοροΑΟΒ, b HacTHOCTn, TaKoro neHOMaTepnana, κοτορωη ηΜβθτ ΗΗ3κηη očbeMHbin βθο, HH3Kne 3HaneHnn nnMČAa (τ.β. Ηη3κγκ> τθπποβοαηοοτβ, BbicoKne Tennon3onnpyiomne CBoncTBa) n BbicoKne npoTnBonoxapHbie CBoncTBa (T.e. OTHOcnTcn κ Knaccy nnoxoBocnnaMeHneMbix προΑγκτοΒ), TaK xe KaK η οποοοδ ποπγΗβΗηη Taxnx ΠΥΡ neHOMaTepnanoB, b κοτορπχ He ncnonb3yeTcn BcneHnBaTenb, Knaccn$nunpyeMbin KaK ranoreHnpoBaHHbiii yrneBOAopoA. ΠΥΡ-neHOMaTepnanbi no HacTonmeMy η30δρβτβΗηκ), b HacTHOCTn, ΠΥΡ-χβοτκηβ neHbi, ηΒπηιοτοη MaTepnanaMn, KOTopbie coAepxaT HacTnHHO 3aKpbiTbie n npeAnoHTHTenbHO b 3HannTenbHon οτβπθΗη nonHOCTbio 3aKpbiTbie nopbi, CBOčoAHbie ot ranoreHnpoBaHHbix yrneBOAOpOAOB, 6yAb to ΧΦΥ nnn ΦΥ, a TaKxe Manoe KonnHecTBO BcneHnBaTenen, ncnonb3yeMbix b npouecce η3ΓΟτοβπθηηα TaKnx ΠΥΡ-neHOMaTepnanoB , npnneM yKa3aHHbiii BcneHnBaioiAnn areHT πρθαοτθβπβθτ οοδοή opraHnnecKnn χηΑκηη προΑγκτ, BbiSpaHHbin n3 rpynnbi, C0Aepxaunen HH3iunn anKaH, nMeraiuinn ot 3 no 6 aTOMOB yrnepoAa n CMecb H3 HecK0nbKnx TaKnx Hn3iunx anKaHOB, ημθιοιαηχ ot 3 ao 6 aTOMOB yrnepoAa, n nMeioiAnn TeMnepaTypy κηπθΗηη npn HopManbHOM AaBneHnn μθχαυ -10 n +70°C, n stot neHOMaTepnan ημθθτ paBHOMepHyio πορηοτγιο οτργκτγργ n o6beMHbin βθο nopnAKa 30 γ/cm^ η HHxe. ΠΥΡ-MaTepnanbi n3 yKa3aHHon πθην Aanee οοΑθρχητ o6biHHbie Ao6aBKn, τθκηθ KaK KaTann3aTopbi, BemecTBa ann CTa6nnn3npoBaHnn nop, areHTbi cmnBKn, nnaMnracnTenn n/nnn 3MynbrnpyioiAne areHTbi. nopbi γοτοβογο ΠΥΡ-neHOMaTepnana ΜΟΓγτ coAepxaTb nepemeAinnn b ηθτγπθβ -4- cocTOflHne BcneHMBaTenb b He6onbmMX κοπμηθοτββχ BnnoTb ao 30 % oSteMa πορ. B LļenoM, TaKne κοπμηθοτβ3 eme MeHbiue, b 3aBMCMM0CTM ot μοχοαηβιχ nyP-MaTepnanoB, απμτθπβηοοτμ xpaHeHMfl γοτοβμχ IT/P-neHOMaTepManoB, TeMnepaiypbi m AaBneHMn ripu xpaHeHMM, τ.θ. b 3aBMCMMOCTM ot ycnoBMM, βπμαιοιαμχ Ha ο6μθη BHeuiHero B03Ayxa c πβτγΗΜΜ BcneHMBaieneM πγτθΜ AH$$y3HH 3ΤΜΧ BeiiļeCTB Ηθρβ3 CTeHKM nop. B npeAnoHTUTenbHOM BapMaHTe βηποπηθημη HacToniAero Μ3θ6ρθΤΘΗΜη, nopbi neHbi κροΜΘ ocTaTKOB BcneHMBafoinero areHTa no H3o6peTeHnio n B03Ayxa, kotopbim βο βρθμη npoM3BOACTBa μ χρβΗβΗΜπ θτογο ΠΥΡ neHOMaiepnana An$$ynAnpyeT BHyTpb nop, 3aMeman McnapMBuiMMcn BcneHMBaTenb, C0Aep>KaT AononHMTenbHbifi ra3, BbičpaHHbiii M3 rpynnbi, cocToniiļeM M3 a30Ta b AononHeHMe m b 6onbiiiMX κοπμηθοτββχ, ηθμ ero oObiMHoe coAepxaHMe b B03Ayxe, čnaropoAHbiM ra3, CMecb a30Ta m OnaropoAHoro ra3a μπμ CMecb HecKonbKMX 6naropoAHbix ra30B. OcočeHHO npeAnoHTMTenbHbiM b stom BapMaHTe BbinonHeHMn AononHMTenbHbiM ra30M jļBnneTcn 6naropoAHbiM ra3 aproH.
[IpeAnoHTMTenbHO, nyP-neHOMaTepMan no HacTonmeMy μ3ο6ρθτθημιο ΒΚηΚ)Η3βΤ OAHy ΜΠΜ HeCKOHbKO M3BeCTHblX ΧΜΑΚΜΧ ΜΠΜ ΤΒβρΑ^Χ nnaMnracMTeneM,' npeAHOHTMTenbHO 0oc$opcoAepxamee coeAMHeHMe μπμ 6op-coAepxaujee οοθαμηθημθ, M38ecTHoe κάκ nnaMnracMTenb. 9τοτ nnaMnracMTenb npMcyTCTByeT, npeAnoHTMTenbHO, b KonMnecTBax οτ 5 ao 35 Mac. %, čonee npeAnoHTMTenbHO, ot 10 ao 20 Mac. % ot oāmero eeca ΠΥΡ-neHOMaTepMana cornacHO Μ3ο6ρθτθημιο. B HaMāonee npeAnoHTMTenbHOM BbinonHeHMM, nyP-neHOMaTepMan no HacToameMy Μ3θδρβτβΗΜΐο coAepXMT b KanecTBe TBepAoro nnaMnracMTenn aMMOHMeByio conb, Ta«yjo xax aMMOHMeBan conb φΟΟφΟρΗΟΜ KMCnOTbl, ΜΘΤΒφΟΟφΟρΗΟΜ KMCHOTbl, ΠΟΠΜφΟΟφσρΗΟΜ KMCHOTbl ΜΠΜ ČOpHOM KMCnOTbl. B APyroM npeAnoHTMTenbHOM BapMaHTe BbinonHeHMn, nyP-neHOMaTepMan TonbKO M3 neHbi μπμ BMecTe c TBepAbiM nnaMnracMTeneM BKmonaeT, b KanecTBe χμακογο φοοφορ-α>Αβρχ3ΐΑβΓθ nnaMnracMTenn, cnoxHbiM ΘφΜρ HM3mero anKMna μ φοοφθΗβτ3 HM3mero anxaHa φopMynbl
O
II RP—(CR')2 rpe R m R' πΒπηιοτοη hm3ujmmm anKMnaMM c 1-4 aTOMaMM yrnepoAa, npeAnoHTMTenbHO, μθτμπαμμ. HaMOonee npeAnoHTMTenbHO, ecnM stot ocoābiM χμακμμ nnaMnracMTenb Mcnonb3yiOT b coneTaHMM c μοηθβμηομ, b nacTHOCTM, b κοπΜΗβοτΒβ ot 10 ao 20 Mac. % ot Beca χμακογο φοοφορ-οοΑβρχΑΐΑβΓο nnaMnracMTenn. flanee HaMčonee npeAnoHTMTenbHO, ητο6ν θτοτ χμακμμ φοοφορ-οοΑθρχ3ΐΐ1ΜΜ nnaMnracMTenb coAepxan MoneBMHy, pacTBopeHHyio b χμακομ nnaMnracMTene ao HacbiiAeHMn o6pa3yioiAerocn pacTBopa. B KanecTBe Karan^aropa, ncnonb3ytor npeAnoHTMTenbHO ochobhom ΜΠΜ BbICOKOOCMOBHOM Κ3Τ3ΠΜ33Τ0ρ B 06blHHblX Κ0ΠΜΗβ0ΤΒ3Χ, HanpMMep,
TaKOM KaTanM3aTop, xax conb menoHHoro MeTanna cnaOoti kmchotu, npeAnoHTMTenbHO anKaH-KapSoHOBOM KMcnoTbi, t3kom xax yKcycHan KMcnOTa μπμ OKTaHOBan KMcnoTa. 3tot KaTanM3aT0p μπμ ero oct3tkm MoryT -5- LV 10470
Haxoflmbcjļ no 3T0My npe,iļnoHTMTenbHOMy BapnaHTy BbinonHeHnn b γοτοβομ nyP-Maiepnane M3 neHbi cornacHO HacTonmeMy Μ3θ6ρβτβΗηιο.
ComacHO ppyroMy Hančonee npeflnoHTmenbHOMy BapnaHTy BbinonHeHnn HacTonmero M3o6peTeHnn, liyP-neHOMaTepnan οοΑβρχητ Hečonbīune KonnnecTBa ocočoro BcneHMBaTenn no HacToaiLieMy Μ3θ6ρθΤΘΗΐ/ικ), τβκ xe KaK TBepflbiM nnaMnracnTenb β βμαθ conn θμμοημα BbiiueyKa3aHH0ii KncnoTbi, TaK xe KaK npeflnOHTmenbHbiM χμακμμ nnaMflracmenb n MOHeBMHy b yKa3aHHbix Bbiiue κοπμηθοτββχ, TaK xe KaK OCHOBHOe, BnnOTb flO CMJlbHOOCHOBHOrO, ΚΘΤβΠΜΤΜΗβΟΚΟΓΟ ΟΟΘβΜΗβΗΜΘ. Β 3aBMCMMOCTM οτ κοΗκρβΤΗοη mcxoahom ομθομ, ΙΤ/Ρ neHOMaTepnan no HacTonmeMy Μ3θ6ρβτβΗηιο μοχθτ copepxaTb ρο 10 Mac. % 3Manbmpyiou4ero areHTa. Hanāonee npeflnoHTurenbHO, ΠΥΡ neHOMaTepnan no HacTomAeMy M3o6peTeHnio b KanecTBe 3Mynbrnpyioiijero areHTa conepxnT HacbimeHHyio nnn HeHacbimeHHyK) xnpHyio KncnoTy, Unu ee cnoxHbin 3φηρ,· μπμ θθ npOM3BOflHOe.
Cnoco6 no μ3ο6ρθτθημιο ρηπ nonyMeHMfl nyp neHOMaTepnana no Μ3θ6ρθτβΗΜΐο xapaKTepM3yeTca τθμ, hto b KanecTBe BcneHMBaTenn ncnonb3yiOT opraHMHecKMM χμακμμ areHT, coflepxamnii b MoneKyne ranoreH m BbiSpaHHbiPi H3 rpynnbi, cocTOflmen M3 HH3iuero anKaHa, HMeiomero οτ 3 po 6 aTOMOB yrnepofla η CMecn HecKonbKHx τβκμχ HM3iunx anKaHOB c 3-6 aTOMaMi/i yrnepofla, npnneM yKa3aHHbin χμακμμ BcneHMBaTenb μμθθτ TeMnepaTypy κμπθημα Mexpy -10 h +70°C npn HopManbHOM flaeneHmi, n yKa3aHHbin BcneHMBaTenb πμ6ο npMMemaH κ CMecM M3 cnnpTHoro μοχοαηογο κομποηθητ8 m M30LļMaHaTHoro McxoflHoro KOMnoHeHTa flnn nyP-neHOMaTepMana b 06blHHblX προπορμπηχ Mexfly yKa3aHHblM CnMpTOBblM MCXOflHblM ΚΟΜΠΟΗβΗΤΟΜ M yKa3aHHblM M30AMaHaTHbiM MCXOflHblM ΚΟΜΠΟΗβΗΤΟΜ; yKa3aHHan CMecb copepxMT flpyrMe fločaBKM, TaKMe KaK KaTanM3aTOpbi, CTa6MnM3Mpytoii4Me nopbi areHTbi m nnaMaracnTenn β οΟηηηνχ κοπμηθοτββχ, μπμ, npeAnoHTMTenbHO, yKa3aHHbin BcneHMBaTenb tohko AUcneprnpoBaH b cnMpTOBOM mcxoahom κομποηθητθ απη nyP-neHOMaTepnana c Ao6aeneHneM ApyrMX BbiiueyKa3aHHbix AOāaBOK, a 3aTeM κ 3T0My tohko pacnpeAeneHHOMy npoAyKTy oObiHHbiMM npneMaMM npMMeiuMBaeTcn M3oqMaHaTHbm mcxoahom κομποηθητ; nonMMepM3aLļMio yKa3aHH0M CMecM μοχοαηνχ MaTepnanoB απη nonyHeHMn nyp neHOMaTepnanoB ocymecTBnnK)T b o6biHHbix ycnoBMnx, b nacTHOCTM, npM o6biHHbix TeMnepaTypHbix ycnoBnnx. Β ΟβΟΜΧ ΒΗΠΟΠΗβΗΜΑΧ BblUUeyKa3aHH0M npOLļeAypbl, BCneHMBaiOlAMM areHT ΑοββΒηηιοτ κ μοχοαηημ MaTepnanaM β TaKOM κοπμηθοτβθ, κοτοροβ ΗβοδχοΑΜΜΟ Ann nonyneHMn xenaeMon nnoTHOCTM fiyp neHbi, T.e. A^a xenaeMOM οτθπθημ BcneHMBaHnn nonyHaeMoro neHOMaTepnana. Ecnn Tpe6yeTcn āonbīuee BcneHMBaHMe, T.e. Tpe6yeTcn MeHbiuan nnoTHOCTb neHOMaTepnana, το 6onee BbicoKne KonnwecTBa χμακογο BcneHMBaTenn cnepyeT npMMemnBaTb κ cooTBeTCTByiomnM McxoAHbiM MaTepnanaM. CneuManMCT μοχθτ paccHMTaTb τοηηοθ κοπμηθοτβο, ΗβοδχοΑΜΜΟβ aπη npMMeUJMBaHMA K MCXOAHOM CMeCM, MCXOAH M3 Μ3ΒβΟΤΗΟΓΟ 06έ>ΘΜ3 McnapneMOro χμακογο BcneHMBaiomero areHTa n xenaeMoii πποτηοοτμ κοηθηηογο nyP-neHOMaTepnana. Tāme pacneTbi M3BecTHbi β οτηοιιιθημμ Apyrnx BCneHMBaTeneii, TaKMx KaK ΧΦΥ. Ecnn πρηχοΑΜΤοη ynMTbiBaTb TeMnepaTypy κμπθημη Mcnonb3yeMoro χμακογο BcneHMBaTenn, to nonMMepM3auMK) μοχηο ocyiAecTBn«Tb c πρΜποχβΗΜβΜ AasneHMn, -6-
ΠΟΗΜΧΘΗΗΟΓΟ ΜΠΜ ΠΟΒΝΐυΘΗΗΟΓΟ ΟΤ ΗΟρΜΒΠΒΗΟΓΟ 3ΗΒΗΘΗΜΛ Ha CTa flMM
BcneHUBaHMfl cnocoSa no Μ3θ6ρβτβΗΜΐο. Γοτοβημ ΠΥΡ-neHOMaTepMan npeflnoHTMTenbHO xpaHm b τθηθημθ nepnofla ot 2 αηθμ ao HecKonbKMX MecnueB, npeAnoHTMTenbHO ot 2 ao 7 αηθμ, npn κομηβτηομ TeMnepaType μπμ cna6o noBbimeHHoii TeMnepaType (οκοπο 45°C) npn aiMoc$epHOM α^βπθημμ μπμ npn necKonbKO ποημχθηηομ α^βπθημμ. B npeAnoMTUTenbHOM BapnaHTe βηποπηθημπ, k mcxoahom 3MynbCMM b KanecTBe nnaMnracMTenn Ao6aBnnK)T χμακμμ μ/μπμ TBepAbm nnaMAracuTenb, coAepxatAMii φοοφορ μπμ 6op-npon3BOAHoe, npeAnoHTMTenbHO, b κοπμηθοτβθ ot 5 ao 35 % Bec., npeAnoHTUTenbHee 10-20 Mac. % οτ očojero Beca κοηθηηογο neHOMaTepnana. Han6onee npeAnoHTMTenbHO, Mcnonb3yeMbiM nnaMnracuTeneM αβπλθτοα conb aMMOHHfl φοοφορΗΟΓΟ μ/μπμ 6opHoro coeAUHeHnn, HanSonee npeAnoHTMTenbHO β TBepAoti, KpucTannuMecKoPi φΟρΜΘ.
CornacHO APyroMy npeAnoHTMTenbHOMy BapnaHTy βηποπηθημα cnocoča no HacTonoļeMy M3o6peTeHMK>, ncnonb3yioT χμακμμ nnaMnracMTenb, yKa3aHHbiM χμακμμ nnaMAracuTenb npeAnoHTMTenbHO αβππθτοα npeAnoHTMTenbHO οποχηνμ 3φΜροΜ HH3Luero anKaHa - φοοφοΗΟΒΟΜ KucnoTbi cneAyioiAeM φopMyπbι 0
II R-P—(CR% c 1-4 aTOMaMM yrnepoAa b rpynne HM3iuero anKaHa b nacTHOCTM, 3φΜροΜ c HM3UJHM anKaHonoM c 1-4 aTOMaMM ymepOAa β ΘφΜρΗοίί rpynne Han6onee npeAnoHTMTenbHbiM ηπθηομ stom rpynnbi ηΒπηβτοη ακμθτμποββιμ 3φΜρ, ΜΘΤΜη-φοοφΟΗΟΒοίί KMcnoTbi, y κοτοροτο KaK TaK m o6a MeTMHbi. B APyroM npeAnoMTUTenbHOM BapMaHTe BbinonHeHMfl cnocoča no HacTonmeMy Μ3θ6ρβτΘΗΜ(θ, 3τοτ χμακμμ φοοφορ-οοΑβρχΗίΑΜίί nnaMnracMTenb BbimeyKa3aHH0ii φopMyπbι Mcnonb3yeTcn b CMecM c μοηθβμηομΒ npeAnoHTMTenbHO, β κοπμηθοτβθ (μοηθβμηβι) ot 10 ao 20 Mac. % οτ očmero Beca χμακογο φοοφορ-οοΑβρχοΐΑβτο nnaMaracMTenn. CornacHO HaMčonee npeAnoHTMTenbHOMy BapMamy BbinonHeHMH Μ3θ6ρβτβΗΜη, MoneBMHy Mcnonb3yfOT b CMecM c χμακμμ nnaMaracMTeneM β τ3κομ κοπμηθοτβθ , hto MoneBMHa npMcyTCTByeT β χμακομ φοοφορ-οοΑβρχ3ΐΑβΜ nnaMnracMTene b BMAe ee HacbtmeHHoro pacTBopa β υκά3Βηηομ χμακομ nnaMaracurene. C 3tmm nocneAHMM M3 ynoMHHyTbix BapnaHTOM 6bmM nonyneHbi χοροιηΜβ npOTMBonoxapHbie pe3ynbTaTbi b TeneHMe AJiMTenbHbix nepMOAOB epeMeHM, hto ηΒπηβτοη HaMāonee xenaTenbHbiM npM Mcnonb30BaHMM γοτοβνχ ΠΥΡ-neHOMaTepManOB. fIone3Hbie AHM30UMaHaTbi μπμ ΠΥΡ-npeAnonMMepbi c no MeHbujeti Mepe AByMJl CBOČOAHbIMM Μ30ΑΜ3Η3ΤΗΜΜΜ rpynnaMM Β ΜΟΠβ^Πβ M3BeCTHbl cnei4ManMCTy. ΚροΜβ τογο, cneLļManMCTy M3BecTHbi μ ποαχοαπιαμθ Α^οπΜρτω μπμ APyrne coeAMHeHMn, μμθιοιαμθ no MeHbiueM Mepe αβθ CBOāoAHbie TMApoKCM-rpynnbi b MoneKyne, TaKMe KaK ποπΜ3φΜρΗωβ nonMonbi μ/μπμ nonMonbi οποχηογο ποπΜ3φΜρ3. TaKxe M3BecTH0 cneuManMCTy m to, KaK 3tm ABe rpynnbi MCX0AHbix κομποηθητοβ μ b κβκμχ βθοοβνχ C00TH0ineHMnx Apyr κ -7- LV 10470
Apyry flucnupTOBbie w AMW30Ai/iaHaTHbie οοθαμηθημη pearnpyiOT Mexfly co6om Ann nonyneHn« μηγκμχ, nonyxecTKnx μπμ χθοτκμχ ΠΥΡ neHOMaiepnanoB.
B Θτοίί cbh3m μοχηο cocnaTbcn Ha μηοχθοτβο repMaHCKMX μ προΗΜΧ MHOCTpaHHblX Π3ΤΘΗΤ0Β M naTeHTHblX 3aaB0K CaMblX pa3HblX naieHTOo6naflaTeneM n 3anBmeneM, a Taxxe Ha μηογμθ o6\i\v\e ny6nnKai4i/iM, KOTopb/e Knaccn0nunpyiOTCfl no Knaccy MKM C 08 G, noflKnacc 18. npMMep oāiiieti ny6nnKai4mi - ”Χθμμπθκο/ιοη” Pēivina, 7-e M3fl. 1975, cc. 2774-2775 h AanbHetiujMe ccbinKi/i, KOTopbie τθμ flaHbi. nOflXOflaiMMMM OpraHMHeCKMMM ΟΟΘΑΜΗΘΗΜΗΜΜ, KOTOpbie cneAyeT ncnonb30BaTb b cnocoče no HacTonineMy μ3ο6ρθτθημκ> b KanecTBe BcneHMBaierm, ηΒπηκ)τοη τθκμθ οοθαμηθημη, KOTopbie ηθ pacTBOpmoTcn b ΟΠΜρΤΟΒΟΜ ΜΟΧΟΑΗΟΜ ΚΟΜΠΟΗΘΗΤΘ A^* nYP-neHOMaiepManOB ΠΟ 3T0My cnoco6y μπμ TaKMe οοθαμηθημη, KOTopbie b 3HaHmenbHOii οτθπθημ ηθ paCTBOpfltOTCfl B yK33aHH0M CHMpTOBOM ΜΟΧΟΑΗΟΜ ΚΟΜΠΟΗΘΗΤΘ M KOTopbie ΠΡ0Μ3Β0ΑΛΤ 3MyHbCMM C 3TMM CnMpTOBblM MCXOAHblM ΚΟΜΠΟΗΘΗΤΟΜ, ΘΟΠΜ ΗθοβχοΑΜΜΟ, b npMcyTCTBMM 3MynbraTopa πρθαποητμτθπβηο, b κοπμηθοτβθ ao 10 Mac. % ot KonunecTBa οπμρτοβογο ΠΥΡ-μοχοαηογο κομποηθητθ. npMMepaMM TaKnx ποαχοααιαμχ βοθημββτθπθμ aBnaKDTca ημθιιιμθ anKaHbi c 3-6 aTOMaMM yrnepoAa, τηκμθ κθκ H-6yiaH, M-neHTan, μ30πθητ3η, H-reKcaH, AMMeTnn6yTaH, μπμ ομθομ M3 HecKonbKMX Taxnx οοθαμηθημμ, ΠΒππιΟίΑΜΧοη no6oHHbiMM npoAyKTaMM, nonynaeMbiMM πρΜ αμοτμππηαμμ MMHepanbHoii ΗΘφτΜ μ HacTO c>KMraeMbix. flaioinne HannyHLUne pe3ynbTaTbi m no3TOMy Han6onee npeAnoHTmenbHbie τθκμθ βοπθημβητθπμ Bbi6npatOT m rpynnbi, cocToaiiļeH M3 H-neHTaHa m M3oneHTaHa. 3τμ βοπθημβ3τθπμ npoM3BOAm ΠΥΡ neHOMaiepnan, o6naAaiomnii oneHb paBHOMepHOfi αηθμοτομ cTpyKTypoM c He6onbiunM pa3MepOM nop, KOTopan coxpaHneTcn α^>κθ nocne χρβΗΘΗΜη nonyMeHHoro neHOMaTepnana. >Κμακμθ n TBepAbie neHoracmenn, ncnonb3yeMbie b cnocoče no HacTonmeMy μ3ο6ρθτθημιο, b 43οτηοοτμ, φοοφορ- Unu 6op-coAepxainne nnaMnracmenH, Tax xe xax h npeAnoHTmenbHbie conn aMMOHMn stmx οοθαμηθημμ, n3BecTHbi cneLļManMCTy b oānacTM ΠΥΡ-πθη. npMMepaMM Taxnx n0ne3HblX ΟΟΘΑΜΗΘΗΜΜ HBnfltOTCfl βορβΤΗ,φΟΟφΒΤΒΙ, ΜΘΤΘφΟΟφΒΤΗ, ποπΜφοοφΘΤΜ, h BbiineynoM5iHyTbie οποχηνθ 3φΜρ^ hm3ujmx θπκθηοποβ m hh3hihx aπκaH-φocφOHOBbιx KHcnoT. flnn τογο, HTočbi nonynmb npoAyKTbi no orHecTOMHHBOMy Knaccy B2, ππθμπγθομτθπμ ncnonb3yiOT b κοπμηθοτββχ, HanpiiMep, nopnAKa 6000 γ/μ^ m 6onee. Οοο6θηηο ποπθθηημ h nosTOMy npeAnoHTmenbHbiM M3 τβθρανχ ππθμαγθομτθπθμ πβπηιοτοπ θμμοημθβνθ οοπμ 3Τοίί rpynnbi. flpyrnMM ποαχοααιαμμμ neHoracmennMH M3 stom npeAnoHTMTenbHoii rpynnbi TBepAbix nnaMnracMTeneii ηΒηηιοτοη MeTa6opaT čapiin μπμ 6opaT αμηκθ. Τβθρα^θ nnaMnracmenM ηθ Ao6aBnniOT κ μοχοαηομ ομθομ nocpeACTBOM A03MpyioiAero Hacoca BbicoKoro AasneHiin, nocKonbKy TaKHe npoAyKTbi npeACTaBnnioT co6oti a6pa3HBHbie ποροαικιι. nosTOMy TaKMe TBepAbie nnaMnracMTenM Αοδ^Βηηιοτ κ μοχοαηομ ομθομ nocpeACTBOM cnnpanbHoPi MemanKM, βκπιοηθηηομ b np0H3B0ACTBeHHyio πιιημιο cpa3y 3a y3noM CMemuBaHHn xhakmx ncxoAHbix MaTepnanoB. (ΠΥΡ ncxoAHbie κομποηθητν nnioc BcneHMBaTenM). noAXOAniiļne 3MynbraTopbi μθβθοτηη cneunanncTy. Οοο6θηηο noAXOAnujnMn 3MynbraT0paMn, m no3TOMy Han6onee npeAnoHTHTenbHbiMH, -8- HBnaraTCfl npoflyKTbi HacbiiueHHbix m HeHacbimeHHbix XMpHbix κμοποτ, TaKne κβκ anKaHonaMMfl-STOKCunaT χμρηομ KMcnoTbi. riOAXOfl5ļU4MMM areHTaMM flJlfl C03flaHM51 nOnepeHHblX 0ΒΑ3βΜ ΠΥΡ ΠΘΗ jRBnatOTCH Taxxe M3BecTHbie 3KcnepTy Maiepnanbi, Taxne κάκ onpeneneHHbie nienoHHbie BemecTBa MaHHMxa (Mannich). flaxe Heāonbujue KonunecTBa BOflbi, TaKne Kax 0,5 - 2 % Bec. ot Beca μοχοαηομ ομθομ ΜΟΓγτ Mcnonb30BaTbcn b KanecTBe areHTa cujmbkm μ, ποβτοΜγ, μογυτ 6biTb flodaBneHbi κ μοχοαηομ ΟΜβΟΜ. ΚΟΠΜΗΘΟΤΒΟ M30LUiaHaT0B, MCX0A8 M3 3Τ0Γ0, ΑΟΠΧΗΟ ČbITb HeCKOnbKO ΥΒΘΠΜΜΘΗΟ, MTOČbl nOnyHMTb npaBMnbHOe COOTHOUJeHMe ΜΘΧΑΥ CnMpTOBbIM MCXOflHblM ΚΟΜΠΟΗΘΗΤΟΜ M M30LlMaHaTHblM MCXOflHblM ΚΟΜΠΟΗΘΗΤΟΜ. npeflnoHTMTenbHO Mcnonb3yioT o6a Tuna BbimeyKa3aHHbix areHTOB cujmbkm. llpeflnoHTMTenbHO Mcnonb30BaTb 3MynbraT0p npn 3MynbrMpoBaHMM ΧΜΑΚΟΓΟ BCneHMBaiOllļerO areHTa B ΟΠΜρΤΟΒΟΜ ΜΟΧΟΑΉΟΜ ΚΟΜΠΟΗβΗΤβ nyp-neHOMaTepiiana no Μ3θ6ρβτβΗΜΚ). ripu TaKOM βνποπηθημμ, o6pa30BaHne 3My/lbCMM M3 ΧΜΑΚΟΓΟ ΒΟΠΘHMBaTenfl Μ ΟΠΜρΤΗΟΓΟ ΜΟΧΟΑΗΟΓΟ Κ0ΜΠ0ΗΘΗΤ3 pe3K0 ynyHiuaeTCB. 3το o6pa30BaHMe 3MynbCMM χμακογο BcneHMBaTenn m ΟΠΜρΤΗΟΓΟ ΜΟΧΟΑΗΟΓΟ ΚΟΜΠΟΗΘΗΤΑ ΗΒΠΗβΤΟη ΗΘΟβΧΟΑΜΜΜΜ Β ΟΠΟΟΟδβ ΠΟ HacTOfnqeMy Μ3θ6ρβτβΗΜΐο. JļočaBneHMe 3MynbrMpyioiAero areHTa, οαη3κο, Aanee οποοοδοτΒγβτ οδΜβΗγ McnapMBiuerocfl χμακογο BcneHMBaTenn c ΒΟ3ΑΥΧ0Μ BO BpeMfl OKOHHaTenbHOTO nepMOAa ΧρβΗβΗΜΛ ΟΒβΧβΒΟΠβΗβΗΗΟΓΟ MaTepMana. JļnMTenbHOCTb nepMOAa OKOHHaTenbHoro xpaHeHMn απη očMeHa Mcnonb30BaHHoro BcneHMBaiomero χμακογο areHTa c B03AyxoM 33bmcmt ot KOHKpeTHblX MCn0nb30BaHHblX MCXOAHblX ΚΟΜΠΟΗβΗΤΟΒ, B HaCTHOCTM, OT Mcnonb30BaHHoro BcneHMBaTenH, TeMnepaTypbi OKpyxafomen cpeAbi, Β03Μ0ΧΗ0, MCnOnb30BaHHOrO ΠΟΗΜΧβΗΗΟΓΟ Α3ΒΠβΗΜΑ, a TaKXe OT BMAa M KonMMecTBa npeAnoHTMTenbHO Mcnonb30BaHHoro TBepAoro nnaMnracMTenn, TaK xe KaK οοηοβηογο KaTanM3aTopa μ/μπμ npMMeHeHHoro 3MynbraTopa. B ΗβκοτορΗΧ cnyHajļx, npMroTOBneHHbie nyP-neHOMaTepManbi nonynaioT yxe no npoTMBonoxapHOMy Knaccy B2 δβ3 xpaHeHMH, β 33βμομμοοτμ ot Bbl6paHHOM ΜΟΧΟΑΗΟΜ ΟΜβΟΜ M MCn0nb30BaHHblX ΠΠβΜηΓβΟΜΤβΠβΜ Μ ΜΧ KOJiMHecTBa, a Taxxe οτ Mcnonb30BaHHoro KaTanM3aTopa. BpeMH xpaHeHMn b ο6ιαθμ οοοτβΒπηβτ οτ 2 ao 7 Aneti, MHorAa 6onee AnMTenbHO, HanpMMep, ao 6 HeAenb μ β ρβΑΚΜΧ cnyHanx ao 4-6 μθοηαθβ. ΟδωπΗΟ nepMOA OKOHHaTenbHoro xpaHeHM8 3aKaHHMBaeTC^ nocne 3-4 αηθμ. 06μθη Mcnonb30BaHHoro BcneHMBaioiAero areHTa c 6e3BpeAHbiMM ra3aMM, tbkmmm KaK B03Ayx, μογυτ KOHTponMpoBaTbca nepe3 BOcnnaMeHneMOCTb ποπυηθηηογο neHOMaTepnana. KaK yi<a3biBanocb, BOcnnaMeHneMOCTb γπγπιηββτοη nepe3 onpeAeneHHbiti nepMOA OKOHHaTenbHoro χρβΗβΗΜη. flpyrMM κρΜτβρΜβΜ ηΒπηβτοη ΟΠρβΑΘΠβΗΗΟβ γΒΘΠΜΗβΗΜβ ΤβΠΠΟΠρΟΒΟΑΗΟΟΤΜ ΟΤ 0.021 KKan Μ/nāc °C, HenocpeACTBeHHO cpa3y nocne Hanana xpaHeHMn, ao 0.025 Kxan M/nac °C. 3Ta TennonpoBOAHOCTb b 0.025 Kxan M/nac °C 3aTeM ocTaeTcn ποητμ ΗβΜ3ΜβΗΗΟΜ Β ΤβΗβΗΜβ ΟΠρβΑβΠβΗΗΟΓΟ nepMOAa ΒρβΜβΗΜ, KOTOpbIM Π03Β0ΠηβΤ 3aKHK)4MTb, ΗΤΟ npoM30inen ΟδΜβΗ Mcnonb30BaHHoro opraHMHecKoro ΒοπβΗΜΒβτβπη c OKpyxaiomMM βο3αυχομ ao xenaeMoii οτβπβΗΜ, μ b ochobhom oh 3aBepiuMncn. KaK yKa3bmanocb Bbiiue, b 3aBMCMMOCTM OT Bbl6opa pa3nMHHblX ΚΟΜΠΟΗβΗΤΟΒ Μ/ΜΠΜ KonMMecTBa M BMAa Mcnonb30BaHHoro TBepAoro nnaMnracMTenn, μογυτ 6biTb nonyHeHbi fiyP-neHOMaTepManbi, yxe oānaAaioiAMe οβομοτββμμ no Knaccy B2 6e3 -9- LV 10470 OKOHMaienbHoro xpaHeHi/m. TennonpOBOAHOCTb 0.025 Kxan M/nac °C μοχθτ 6biTb CHnxeHa flo 3HaMeHiw nop^AKa 0.0205 Kxan Μ/nāc °C, τθπποπροβοαηοοτμ, KOTopan MHorAa ηθ nonyHanacb no npeAinecTByioiAHM cnocočaM. COBepUUeHHO HaoSopOT no CpaBHBHHK) C ΠΟΒΒΙΐυθΗΜΘΜ
TennonpoBOAHOCTM nyP-neHOMaiepnanoB no HacTonmeMy H30čpeTeHHKD bo Bpeivm xpaHeHnn, o6ctomt αθπο c BOcnnaMeHneMOCTbfo nonyMeHHoro Maiepnana. Ηθμθαπθηηο nocne ciaAnn BcneHHBaHMn, nyP-neHOMaTepnan nacTO πθγκο BocnnaMeHMM. B τθηθημθ xpaH0HMH, BocnnaMeHneMOCTb nyp neHOMaTepnana yMeHbwaeTcn n otot noKa3aienb ynyHUjaeTCn αθηβ oto aha. nyp neHOMaTepnan nocne 2-7, b nacTHOCTn, nocne 4 Aneti xpaHeHwn AOCTuraeT BOcnnaMeHneMOCTM cooTBeTCTByKDU4eti no ropeHmo xnaccy B2 nnn Aaxe B1 c noni/iM30iļnaHypaTHbiMM neHOMaTepnanaMM m npn AoāaBneHnn 6onbUJnx KommecTB nnaMnracuTeneti. KaK yxe ynoMMHanocb, ycTotiHHBOCTb CBOiiCTBa πποχοίί B03ropaeMOcm fiyp neHOMaTepnanoB no Μ3θ6ρβτβΗΜΚ> ynymuaeTcn πρι/ι ncnonb30BaHMM coneTaHun χμακογο c(30ccf}op-coAepxamero nnaMiiracmenn c ΜΟΗβΒΜΗοίί.
CneAyeT yKa3aTb, mto očteM ηβοτοπιαθγο Η3θβρβτΘΗΜη, KaK b OTHOiueHmi ΠΥΡ neHOMaiepnana, TaK m b OTHomeHMii cnocoSa ero nonyMeHMn, 0XBaTbiBaeicn eapnaHT, KorAa He6onbinoro KonunecTBa ranoreHi/ipoBaHHbix yrneBOAOpoAOB m Aa*e ΧΦΥ npUMemuBaioT κ BcneHMBa(omeMy aremy no HacToniAeMy W3o6peTeHi/uo m coneTaHiie o6onx ncnonb3yeTcn Ann nonyHeHnn npOAyKTa onpeAenneMoro CTaHAapTOM flUH 18164. CornacHO noAnyHKTy θτογο CTaHAapia flUH, oxBaTbiBaiOTcn TaKne nyP-neHOMaTepnanbi, KOTopbie 6binn nonyneHbi " c ncnonb30BaHneM ranoreHnpoBaHHbix yrneeofļopofļOB b KanecTBe BcneHMBa(ounnx βγθητοβ nyTeM χημμηθοκομ peaKLļnn c coeAnHeHunMn, coAepxamnMn KucnoTHbm boaopoa”. OpraHuneKuti xhakm BcnenuBaTenb, ncnonb3yeMbiti no HacTonu4eMy M306peTeHW0, μοχθτ dbiTb πθγκο cMeuuaH c HečonbLunMM KonMMecTBaMM ranoreHMpOBaHHbix yrneBOAopoAOB, TaK, hto Heo6xOAHMbie yrneBOAopoAbi 3aiviet4aiOTcn Ha BennHMHy ao 95 % μπμ Aaxe Ao 99 % χμακμμμ βοπθημβ3Κ3likumu areHTaMM no HacTonmeMy Μ3θ6ορβτβΗΜΚ>. KpoMe τογο, Ha ncnonb30BaHne 3MynbraT0p0B b HacTomueM cnoco6e He OKa3biBaeT bπμπημη πρμμθηθημθ He6onbWMX KonHHecTB Xcpy ηπμ MeTnneH-xnopnAa. ΠοοπβΑΗΜίί npoAyKT MMeeT TeMnepaiypy KMneHMfl b npeAenax, onpeAeneHHbix ηθοτοαιαμμ Μ3θ6ρθτβΗΜβΜ (ī.Kun. = 40°C).
Hnxe πρΜΒΟΑητ cn npmviepbi aka AanbHetiujeii HnntocTpapHM HacTonmero n3o5peieHnn. ΠΡΙ/1ΜΕΡ 1 nyp xecTKMti neHOMaTepnan nonynaK)T nyTeM 3MynbrnpOBaHnn npw 22°C cMecH, cocTonmeti - 50 Bec. nacTeti nonna$npHoro cnnpia, mvieioiiiero rnAPOKcnnbnoe HMcno οκοηο 550 (Bfl3KOCTb οκοηο 8000 cn npw 25°C) H3 rpynnbi npoAyKTOB CAPADOL cļJHpMbi Shell Chemie - 30 HacTeti (eecoBbix) HacbiineHHoro nonn30npa, MMeKDaļero TMApoKCHnbHoe HMcno οκοπο 500 (Bn3K0CTb npHMepHO ot 8000 ao 10000 cn npM 25°C) - 10- - 20 nacTeii (BecoBbix) apoMainnecKoro nonn30npHoro cnupia, MMetoiuero rMApOKCMnbHoe hmcho οκοπο 500 (BH3K0CTb npuMepHO 5000 cn npn 25°C) - 7 Bec.nacTeM χμακογο nnaMnracmenn fluμθτμπΜθΤΜπφοοφθΗ3Τ3 (ΑΜΜΦ), MMeiooiero coflep>KaHMe $oc0opa 26 %, - 5 Bec. nacTeti 3Mynbrnpyioinero areHTa EMULGIN φι/ipMbi XeHKenb ΑΓ - 2 sec. nacTM cunuKOHa b KanecTBe cTa6nnn3aTopa nop, - 28 Bec. nacTeti TBepfloro nnaMnracmenn, - nomicf)oc<ļ>aTa 3μμοημπ, - 3 Bec. nacTM Kaiann3aTopa, - apeiaia ιαθποηηογο MeTanna, -18 sec. nacTeii H-neHTaHa. K θτοίί 3MynbCMn npuMeiuMBatOT 172 Bec. nacTM flHM30unaHaTa MflM (flM0eHMnMeTaH-4,4'-fll1l13OLļtiaHaT ) CnOCOSOM, OČblHHblM npn np0M3B0flCTBe nyp-neHOMaiepnanoB. ΠοπγπθΗΗγιο CMecb BcneHMBatoT b ο6νμηομ BcneHMBaiomeii MainnHe npn HOpManbHOM α^βπθημμ μ κομηβτηομ TeMnepaType. nonyMeHHbiii ΠΥΡ neHOMaiepnan OKOHMaienbHO χρβΗπτ 4 αηπ npn κομηθτηομ TeMnepaType (20°C) n HOpManbHOM p,aBnenm. nonyHeHHbiii ΠΥΡ neHOMaiepnan MMeeT cneAyioiAMe CBoiicTBa: nnoTHOCTb HenocpeACTBeHHO nocne CTaAMM BcneHMBaHiin: 30-40 t/cm^, HanpnxceHne AasneHi/m ηθμθαπθηηο nocne BcneHMBaHun: οκοπο 1.3 κπ/ομ2, HanpnxeHne α^βπθημπ nocne xpaHeHMfl 4-6 HeAenb: 1.6 - 1.7 κπ/cm, BOcnnaMeHneMOCTb ΗβΜβΑπβΗΗΟ nocne BcneHMBaHun: κοροτκοβ B03ropaHne, κοτοροβ 3aieM caMonnKBMAnpyeTcn; nocne 4 αηθβηογο xpaHeHnn: Knacc B2. TennonpoBOAHOdb: cpa3y nocne BcneHMBaHun: οκοπο 0.021 4epe3 20 AHeii nocne BcneHUBaHMn: 0.024 - 0.025 nocne xpaHeHnn 14-16 HeAenb: 0.022 nocne xpaHeHHH 4-6 MecnAeB: 0.0205 ΠΡΜΜΕΡ2 >KecTKnii ΠΥΡ neHOMaiepiian nonyHaioT cneAytoiAHM očpa30M:
CneAyfoinyio CMecb 3MynbrnpyiOT npn κομη8τηοη TeMnepaType: - 50 Bec. nacTeti Π0ΠΜ3φΜρΗ0Γ0 cniipTa c γμαροκομπβηνμ mmchom οκοπο 550 (BH3K0CTb οκοπο 8000 cn npM 25°C), - 30 Bec. HacTePi HacbimeHHoro nonn3$npa, coAepx<amero ochobhom nonepeHHO cBn3biBaraiAHM areHT MaHHMxa m MMeioiuero o6mee γμαροκομπβηοθ HHcno οκοπο 500 (BH3K0CTb οκοπο 8000 - 10000 cn npn 25°C), - 20 Bec. Hacieii apoMamnecKoro ποπΜ3φΐ/ΐρΗθΓθ cntipTa, MMeioiuero THApoKCHnbHoe hhcho οκοπο 500 (Bfi3K0CTb οκοηο 5000 cn npw 25°C), - 7 Bec. nacTeM χμακογο nnaMnracmenn, - ΑΜΜβτΜΠΜβτΜπφοσφΟΗβτθ, - 5 Bec. nacTeti 3MynbrnpyK)mero areHTa EMULGIN φΐ/ipMbi XeHKenb ΑΓ, - 2 Bec. nacTH ciīnMKOHa b KanecTBe CTa6nnn3aTopa nop, - 48 Bec. sacTeii TBepAoro nnaMaracrnenn ΜθΗθ3ΜΜθΗΜΜφοοφ3Τ3, - 3 Bec. nacTM KanHM-apeiaiHoro KaTann3aiopa, - 26 Bec. nacTeM H-neHTaHa, coAepxamero ao 5 % p-nponaHa m h-6yTaHa. 172 eec. nacTM Ann30unaHaTa MflM nptiMeinMBaioT κ nonyHeHHoii 3MynbCMM 06blHHblM ΜβΤΟΑΟΜ npM np0M3B0ACTBe ΠΥΡ ΠβΗΟΜβΤβρΜβΠΟΒ. nonyHeHHyto CMecb noABepraioT BcneHHBaHWO b oābiHHOii MainuHe c OecKOHeMHoii KOHBeitepHOM πθητομ npw HOpManbHOM αββπθημμ. nonyHeHHbiii -11 - LV 10470 ΠΥΡ neHOMaTepnan OKOHnaTenbHO xpaHHT b τθηθημθ 4 αηθμ npn κομη3τηο£ι TeivmepaType (20°C) n HOpManbHOM α^βπθημμ. ΠΡΜΜΕΡ 3 >KecTKnfi ΠΥΡ neHOMaiepnan nonyHaiOT cneAytoiAwvi o6pa30M: CMecb,cocToymiyio H3: - 52 b©c. nacTeii ποπκοφι/ιρΗΟΓΟ cnupia c rnApOKCunbHbiM hhchom ΟΚΟΠΟ 550 (BH3K0CTb οκοπο 8000 cn npn 25°C), - 31 eec. nacTb HacbimeHHoro nonn30npa, coAepxaiA®ro nonepenHO-CB5i3biBaioiunii areHT m μμθιοιαι/ιμ rnflpoKCunbHoe nncno οκοπο 500 (BH3KOCTb npuMepHO 8000 - 10000 cn npn 25°C), - 20 Bec. nacTeii apOMaTunecKoro nonns0npHoro cnupia c rMflpOKCMnbHbIM MMCHOM ΟΚΟΠΟ 500 (Bfl3K0CTb ΟΚΟΠΟ 5000 ΟΠ ΠρΜ 25°C), - 7 βθο. nacTefi χμακογο nnaMaracrnenn ΑΜΜΦ, coflepxauļero 26 % cfioccļDopa, -1 Bec. nacTb BOflbi, - 5 Bec. nācies 3Mynbrnpyfomero areHTa EMULGIN C4, - 2 Bec. nāc™ cnnnKOHa b KanecTBe CTa6nnn3aTopa nop, - 50 Bec. nacTeM TBepfloro nnaivmracMTenfl,- flnaMMOHnii$oc$aTa) - 2 Bec. nāc™ KaTann3aTOpa,- Kanna OKToaia, n - 25 Bec. nacTefi H-neHTaHa, 3MynbrnpyioT npn 22°C. K θτοη 3MynbCMM npuMeuiMBatOT 172 Bec. nacTM AMM30iļnaHaTa Mfll/I n nonyHeHHyHD CMecb BcneHHBaroT npn HOpManbHOM flaBneHnn b oObiMHOH MauuMHe c 6ecKOHeHHOii KOHBeiiepHOH πθητομ. nonyHeHHbiti ΠΥΡ-neHOMaiepnan 3aieM xpaHAT b τθηθημθ 4 αηθμ ripu κομη3τηοη TeMnepaiype (20°C) M OČblHHOM flaBneHMM. nPk1M.EP.-4 >KecTKMti ΠΥΡ neHOMāTepnan nonyHaiOT cneAyiounMM o6pa30M: CMecb, cocTOflmyio m: - 50 Bec. Hacieii ποπΜθφηρΗΟΓΟ cni/ipTa c rnAPOKCunbHbiM μηοπομ οκοπο 550 (BB3K0CTb οκοπο 8000 cn npn 25°C), - 32 Bec . sacieti HacbiiAeHHoro nonnscļinpa c rMApOKCMnbHbiM mmchom οκοπο 500 (Bfl3K0CTb οκοπο 8000 - 10000 cn npn 25°C), - 20 Bec. nacTeii apoMainnecKoro ποπιιοφΜρΗΟΓΟ cnupia c rMAPOKCMnbHbIM MMCHOM ΟΚΟΠΟ 500 (BH3K0CTb ΟΚΟΠΟ 5000 CH Πρΐ/I 25°C), - 7 Bec. MacTen χηακογο nnaMnracmenn βΜΜΦ, coAepxaunero 26 % φθθφθρ3, - 5 Bec. nacTeii 3MynbrHpytouLiero areHTa EMULGIN 550 φηρΜΝ XeHKenb ΑΓ, - 2 Bec. MacTi/i cnnnKOHa b KanecTBe CTa6nnn3aTOpa nop, -1 Bec. nacTb BOAbi b KanecTBe nonepeHHO-CBfl3biBaiOLLļero areHTa, - 38 Bec. MacTen TBepAoro nnaMaracHTena, - ποπΜφοοφΒΤθ βμμοηηη, CMeiuaHHOro c 5 % 6opaTa LļHHKa, - 3 Bec. nacTH menoHHO-aueTaTHoro KaTann3aTopa, • 27 Bec. MacTen H-neHTaHa, 3MynbrnpyioT npn KOMHaTHOH TeMnepaType. 172 Bec.HacTM AH^30LļnaHaTa M/ļH npHMeujHBatoT κ BbiuueyKa3aH0H 3Mynbcnn n nonyneHHyK) CMecb noABepraioT BcneHHBaHHto npn HOpManbHOM AaBneHHH b oābiHHOM BcneHHBaioiAeii MaujHHe HenpepbiBHoro AeiicTBHn. - 12 - ΠοπγΗθΗΗΝΜ IT/P-neHOMaTepMan OKOHHaienbHO xpaHflT b τθηθημθ 4 αηθμ npn ΚΟΜΗΒΤΗΟΜ ΤΘΜΠθρθΤγρβ (20°C) M HOpMa/lbHOM ΑΘΒΠβΗΜΜ. ΠΡ1/1ΜΕΡ 5 >KecTKMii nyP-neHOMaTepnaji npuroTaBnuBaioT caeflyK)iAMM o6pa30M: CMecb, cocTOflmyio M3: - 50 Bec. HacTeii η0ΠΜ3φΜρΗ0Γ0 cnupTa c π/iApOKCnnbHbiM hmcjiom οκοπο 550 (Bii3K0CTb οκοπο 8000 cn npn 25°C), m rpynnbi npoAyicroB CAPADOL φΐ/ipMbi ”LUenn χθμμ”, - 30 eec. HacTeii HacbiiqeHHOro nonn3$npa, coflepxamero nonepenHO-CBH3blBaiOLI4l1M βΓΘΗΤ, C mflpOKCMnbHblM HMCflOM ΟΚΟΠΟ 500 (Bfl3K0CTb ΟΚΟΠΟ 8000-10000 cn npn 25°C), - 20 nacTeti apoMaTunecKoro ηοπΜβφΜρΗΟΓΟ cnupTa c rnflpoKCunbHbiM HncnOM οκοπο 500 (BH3KOCTb οκοπο 5000-cn npn 25°C), - 8 Bec. HacTeii HacbiiAeHHoro pacTBopa μομθβμηβι b χμακομ nnaMnracuTene, - βΜΜβτΜΠΜβΤΜπφοοφΟΗΒΤβ (ΑΜΜΦ), coAepxaiAeM 26 % φοοφορ3, npuneM yKa3aHHbiii pacTBOp coAepxm 1.05 Bec. nāciet MoweBMHbi Ha 7 HacTeii ΑΜΜΦ, - 5 Bec. sacieti 3Mynbrnpy(ouļero areHTa 3Mynbri/!H φιιρΜω ”XeHKenb ΑΓ’, - 2 eec. nacTM cunuKOHa b KanecTBe CTa6nmi3aTOpa nop, - 28 Bec. sacieti TBepAoro nnaMnracmenn, - ποπΜφοοφ3Τ3 aMMOHnn, - 3 Bec. nacTM Kaiann3aTopa, - aueiaia menosHoro Meianna, m 18 Bec. sacieti H-neHTaHa, 3MynbrwpyioT npn 22°C. 172 Bec. SaCTH A^eHMnMeTaHa-4,4'-AMH30aMaHaTa ΠρΜΜΘΙΑΜΒΘίΟΤ K BblliienpUBeAeHHOM 3Mynb cm 06blSHblM ΑΠΠ npOH3BOACTBa nyp neHOMaiepnana μθτοαομ, m nonyHeHHyio CMecb noABepraiOT nonnMepM3aAnn co BcneHMBaHueM npn KOMHaTHOti TeMnepaType m HopManbHOM AasneHnn b očbiHHoii BcneHMBaioiAeii MauuMHe HenpepbiBHoro αθκοτβμπ. rionyseHHbiti nyp neHOMaiepnan OKOHHaienbHO xpaHHT b Tesemie 4 αηθμ npn κομη3ϊηομ TeMnepaType (20°C) n HopManbHOM AaBneHMM.
OiļeHKa B03ropaeMOCTM no Knaccy B2 nocne stoto xpaHeHnn noAAepxnBanacb Aaxe nocne AanbHeiiiijero 6-HeAenbHoro xpaHeHnn, Aaxe npn HarpeBaHMM ao yMepeHHO noBbiujeHHbix TeMnepaiyp. LV 10470 ΦΟΡΜΥΠΑ M30EPETEHHfl 1. nonnypeTaHOBbiii neHOMaTepMan, coAepxaiAMPi KaTann3aTop, CTa6nnn3npytou4HM nopbi arem μ/μπμ nnaM«racmenb, οτπμηβκμαμμοη τθμ, hto, ero nopbi caoSoflHbi ot ranoreHnpoBaHHbix yrneBOflopoflOB m coflepxai He6onbiiine KonMnecTBa βοπθημβθιοιαθγο areHTa, ncnonb30BaHHoro npn npon3BOflCTBe 3Τ0Γ0 neHOMaiepnana n BbičpaHHoro M3 rpynnbi, cocToaiAePi m HM3iuero ariKaHa c 3-6 aTOMaMM ymepofla μ ομθομ yKa3aHHbix tskmx hm3ujmx a/iKaHOB, npnneM yKa3aHHbiM BcneHMBa»ou4MPi areHT μμθθτ TeMnepaiypy ΚΜΠΘΗΜΑ ΠρΜ HOpManbHOM Α^ΒΠΘΗΜΜ ΜΘΧJŅ -10°C M +70°C. 2. flonnypeTaHOBbiii neHOMaTepMan no n.1, OTnMnaiomnPicn τθμ, mto HM3UJMM anKaH, 3T0 Η-ΠΘΗΤ3Η. 3. nonnypeiaHOBbiPi neHOMaTepMan no n.1, OTnunaraiiļuPica τθμ, hto HM31UMM a/IKaH, 3T0 Μ30ΠΘΗΤ3Η. 4. nonnypeTaHOBbiPi neHOMaTepMan no nio6oMy M3 n.n. 1, 2, 3, OTnuHatoiiļuPica τθμ, ητο nopbi ero AononHMTenbHO coflepxaT ra3, BbičpaHHbiPi M3 rpynnbi, cocToamePi H3 a30Ta b κοπμηθοτβθ, OonbīueM, ηθμ o6bHHoe coflepxaHne a30Ta b B03flyxe, čnaropoflHoro ra3a n CMecePi jaKnx ra30B. 5. nonnypeTaHOBbiPi neHOMaTepMan no n. 4, οτπμηθιοιαμμοπ τθμ, hto nopbi 3Toro neHOMaTepnana coAepxaT 6naropoAHbiPi ra3 aproH. 6. nonnypeTaHOBbiPi neHOMaTepMan no nio6oMy H3 n.n. 1-5, OTDHnaioiAMPica τβΜ, hto stot MaTepMan coflepxnT nnaMnracMTenb, BbiāpaHHbiPi M3 rpynnw, cocToaiLļePi M3 χμακμχ nnaMnracnTeneM, TBepflbix nnaMaracuTenePi m ομθομ iaKMX χμακμχ n τβθραβιχ nnaMnracMTenePi. 7. nonnypeTaHOBbiPi neHOMaTepMan no n.6, OTnunatomuPica τθμ, hto 3tot nomiypeTaHOBbiM MaTepMan coAepxMT nnaMnracMTenb, Bbi6paHHbiPi m rpynnbi, $oc0op-coflepxamnx nnaMnracMTenePi, 6op-coflepxaiiinx nnaMaracuTenePi m cmθομ ηθοκοπβκμχ tskmx nnaMnracMTenePi. 8. nonnypeTaHOBbiPi neHOMaTepMan no n.n. 6 μπμ 7, OTnnnaioiLinPicn τθμ, hto 3tot nonMypeTaHOBbiti MaTepMan coAepxMT nnaMaracMTenb mm nnaMnracMTenn β κοπμηθοτβθ ot 5 ao 35 % (βθοοβνχ) ot oSujero Beca κοηθηηογο neHOMaTepMana. 9. nonMypeTaHosbiPi neHOMaTepMan no n.8, oTnunajoiAMPica τθμ, hto 3tot nonMypeTaHOBbiM MaTepMan οοαθρχμτ nnaMnracMTenb μπμ nnaMaracMTenM β κοπμηθοτβθ ot 10 ao 20 βθοοβηχ nacTePi ot o6mero Beca κοηθηηογο neHOMaTepnana. 10.11onMypeTaHOBbiPi neHOMaTepMan no OAHOMy M3 n.n. 6-9, OTnMHaraiAMPica τθμ, hto θτοτ nonMypeTaHOBbiPi neHOMaTepMan οοαθρχμτ conb aMMOHMa b KanecTBe τβθραογο nnaMaracMTena. 11. rionMypeTaHOBbiPi neHOMaTepMan no OAHOMy M3 n.n. 6-9, OTnMHatoiuMPica τθμ, hto stot nonMypeTaHOBbiPi MaTepMan οοαθρχμτ χμακμΡι nnaMaracMTenb, KOTopbin BbiāpaH m rpynnbi, cocToaiAePi M3 cnoxHbix 3φΜροΒ HM3LUMX anKaHOB C HM3UJMMM βη^Η-φΟΟφΟΗβΤΘΜΜ, ΓΑβ HM3UJMM anKSHOn M HM3iiiMPi anKaH KaxAbiPi οοαθρχμτ ot 1 ao 4 aTOMOB yrnepOAa, μ ομθομ HecKonbKMX tskmx nnaMnracMTenePi. 12. nonMypeTaHOBbiPi neHOMaTepMan no n. 11, OTnnnaioiAnPicn τθμ, hto HM3H1MM 3ΠΚ3Η-φθθφθΗ3Τ ΟΟΑβρΧΜΤ OT 10 AO 20 BeCOBblX ΗΘΟΤβΡί ΜΟΗΘΒΜΗω OT Beca ΗΜ3ΐυΘΓΟ 3ΠΚ3Η-φθθφθΗ3Τ3. -2- 13. nonnypeiaHOBbiM neHOMaiepnan no n.n. 11 μπμ 12, οτπμηθιοιαμμοπ ΤΘΜ, HTO HM3LLIHίΐ ΘΠΚΒΗ-φΟΟφΟΗΘΤ ΟΟββρΧΜΤ ΜΟΗβΒΜΗγ BnnOTb flO ΟΒΟΘΓΟ HacbiiiļeHUH. 14. Cnocoā nonyneHMn nonnypeiaHOBoro neHOMaiepnana no nio6oMy M3 n.n. 1-13, OTHMHaioiMMMCfl τθμ, ητο ncnonb3yraT b κθηθοτβθ BcneHMBatoiAero areHTa HeranoreHnpoBaHHbiii opraHunecKUM χμακμμ npoflyKT, Bbi6paHHbm m rpynnbi, οοοτοπιαθμ M3 hm3ujmx anKaHOB č 3-6 aTOMaMM ymepofla n ομθομ τβκμχ hm3uimx anKaHOB, πρμηθμ yKa3aHHbie ημθιπμθ anKaHbi μπμ cMecb τθκμχ hm3ujmx anKaHOB μμθιοτ TeMnepaTypy κμπθημπ MexAy -10 h +70°C npM HOpManbHOM αββπθημμ, npHMemuBaiOT βοπθημββιοιαμμ areHT m tohko ero pacnpeflennioT b ομθομ, cocTOBineCi H3: πμ6ο cnnpTOBoro μοχοαηογο κομποηθητθ h M30LtnaHaTHoro μοχοαηογο κομποηθητβ βππ αθπθβογο iiyP-neHOMaTepnana b oābiHHOM οοοτηοιιιθημμ cnnpTOBbix m n30i4naHaTHbix ncxoflHbix κομποηθητοβ, πρμηθμ yKa3aHHan CMecb TaiOKe βκπιοηθθτ flpyrne očbiHHbie floGaBKM, τθκμθ KaK nnaMnracMTenM, KaTann3aTOpbi h CTa6nnn3aiopbi nop b o6biHHbix κοπμηθοτββχ, μπμ cnnpTOBoro μοχοαηογο κομποηθητβ βππ αθπθβογο ΠΥΡ-neHOMaTepnana h flpyrnx BbiujeyKa3aHHbix ο6νηηηχ AoāaeoK, c αο63βπθημθμ b aiy tohko pacnpefleneHHyfo CMecb M3oanaHaTHoro μοχοαηογο κομποηθητβ, Πρί/ΙΗΘΜ ΟΟΟΤΗΟΙΙΙΘΗΜΘ Me>KAy ΗΜΜ Μ CnMpTOBblM MCXOAHblM ΚΟΜΠΟΗΘΗΤΟΜ ΗΒΠΗΘΤΟΠ OČblHHbIM βΠΠ ΠΥΡ ΒΟΠΘΗΜΒβθΜΜΧ MaTepManOB, Μ 38ΤΘΜ ocyiiļecTBnniOT nonMMepM3auMio μοχοαηνχ κομποηθητοβ ΠΥΡ neHOMaTepnana npM o6biHHbix ycnoBMnx, b ηβοτηοοτμ, οΘηηηβιχ TeMnepaTypHbix ycnoBnnx. 15. Cn0C06 ΠΟ Π. 14, ΟΤΠΜΗΒΙΟΙβΜΜΟΠ ΤΘΜ, HTO Π0ΠΜΜΘρΜ3ΒΑΜΚ) ocymecTBnflioT c ποααθρχθημθμ AaBneHMn ηθμηογο Bbime μπμ ηθμηογο ημχθ HopManbHoro αθβπθημπ, θοπμ Θτο ηθο6χοαμμο c yHeTOM TeMnepaTypbi ΚΜΠΘΗΜΠ MCnonb3yeMOrO ΧΜβΚΟΓΟ Β0ΠΘΗΜΒ3Κ)ΙβΘΓ0 ΒΓΘΗΤΘ. 16. Cnoco6 no močoMy Μ3 π.π. 14 μ 15, OTnMHaioiAMMcn τθμ, ητο nonyHeHHbiM T3KMM oāpa30M ΠΥΡ-neHOMaTepMaπ xpaHBT β τθηθημθ οτ 2 αηθμ ΑΟ ηθοκοπbKnx ΜΘΟΗβΘΒ, πρΜ TeMnepaType οτ κομηθτηομ TeMnepaTypbi βο οπθγκΒ noBbiujeHHoii TeMnepaTypbi, μ πρΜ αθβπθημμ οτ HopManbHoro βΒΒΠΘΗΜΗ, flO enerKa ΠΟΗΜΧΘΗΗΟΓΟ ββΒΠΘΗΜΠ. 17. Cnoco6 no nio6oMy m π.π. 14-16, οτπμηβιοιαμμοπ τθμ, ητο ΒΟΠΘΗΜΒΒΙΟΙβΜΜ areHT 3MynbrMpyiOT Β ΟΠΜΡΤΟΒΟΜ ΜΟΧΟβΗΟΜ ΚΟΜΠΟΗΘΗΤΘ C ΠρΜΜΘΙΠΜΒΒΗΜΘΜ flpyTMX 06blHHblX βθ6θΒΟΚ Μ nOCneflyKDUļMM ΠρΜΜΘΙΙΙΜΒΒΗΜΘΜ Κ 3Τ0Μ 3MynbCMM Μ30βΜ3Η3ΤΗ0Γ0 ΜΟΧΟβΗΟΓΟ ΚΟΜΠΟΗΘΗΤΒ. 18. Οποοοδ ΠΟ Π. 17, ΟΤΠΜΗΘΙΟΙΑΜΜΟΠ ΤΘΜ, ΗΤΟ 3MynbrMpOBaHMe ΧΜβκοΓΟ BcneHMBaioiJnero areHTa β οπμρτοβομ μοχοαηομ κομποηθητθ ο βΟδΒΒΠΘΗΜΘΜ flpyTMX 06blHHblX flOČaBOK OCyiHeCTBnfltOT HenpepbIBHO B ποβχοβηΐβΘΜ ycTpoiicTBe βπη ομθιημββημη, a M30LļMaHaTHbiM κομποηθητ ΠρΜΜΘΙ1ΙΜΒ3Κ)Τ K nOnyHeHHOM T3KMM 06pa30M 3MynbCMM ΒΠΟΟΠΘβΟΤΒΜΜ. 19. Cnocoā ΠΟ Π.Π. 17 ΜΠΜ 18, ΟΤΠΜΗ3Κ}ΙβΜΜΟΠ ΤΘΜ, HTO ΒΟΠΘΗΜΒΒΙΟΙβΜΜ areHT 3MynbrMpyioT β οπμρτοβομ μοχοαηομ κομποηθητθ ο αο68βπθημθμ ApyrMX o6biHHbix flOČaBOK μ c AanbHeMiiiMM πρμμθιπμββημθμ οαηογο μπμ ηθοκοπ bKMX 3MynbrMpyioiAMx areHTOB. -3- LV 10470 20. Cnoco6 no n. 19, OTnuMatoiiļi/iticfl τθμ, hto 3Mynbrwpyfoini4H areHT mjih 3Mynbrnpyiou4Me areHTbi fločaBnniOT b κοπκηθοτβθ ,ηο 18 Mac. % ot eeca cnuproBoro μοχοαηογο κομποηθητθ npoM3BojņnMoro ΠΥΡ-neHOMaTepnana. 21. Cnocoč no n. 19 nnn 20, omuHaioinniicjļ τθμ, hto 3Mynbrnpyfomt4ii areHT nnn 3MynbrnpyK)iiļne areHTbi πβππιοτοη npon3BOflHbiMH >KnpHOĪ4 KucnoTbi. 22. Cnocoč no mo6oMy H3 n.n. 14-16, οτπ unāro mufi es τθμ, mto
CnupTOBOĪi ΜΟΧΟβΗΟΜ ΚΟΜΠΟΗΘΗΤ, 143θρΜ3Η3ΤΗΝί4 UCXOflHOH ΚΟΜΠΟΗΘΗΤ, BcneHMBaiouniiii areHT m flpyrne oObiHHbie floāaBKM CMemuBaroT b cMecMTenbHOki γοποβκθ h nonyMeHHyio CMecb nojļBepraroT peaKLļuu nonHMepM3aUMM CO ΒΟΠΘΗΜΒ3ΗΙ4ΘΜ MSBeCTHblMM MeTOflaMM. 23. Cnoco6 no mo6oMy H3 n.n. 14-22, 0Tni4Haromni4Cfl τθμ, hto πμ6ο ncno/ib3yeMbiii BcneHMBaromuĪi areHT, mičo CMecb cnupTOBoro μοχοαηογο Κ0ΜΠ0ΗβΗΤ3 H ΧΜβΚΟΓΟ ΒΟΠΘΗΙ4Β3ΙΟΙΙ1ΘΓΟ 3ΓΘΗΤ3 HaCblUļeHbl Γ830Μ, BbičpaHHbiM i/i3 rpynnbi, cocTOJuneii 143 a30Ta, 6naropOflHbix ra30B, ομθοθμ a30Ta μ OnaropoflHoro ra3a m cMeon ηθοκοπbKMX 6naropoflHbix ra30B. 24. Cnocoč no πιοβοΜγ 143 n.n. 14-23, OTnunaromuMcn τθμ, mto Mcnonb3yeMbiii Kaiani43aTop peaKqi4i4 noni4Mepi43aui4i4 BbičpaH 143 rpynnbi, cocTosuuieM 143 ocHOBHbix KaTami3aTopoB, i43BecTHbix βππ ΠΥΡ noni4Mepi43ai4i4i4 u cnnbHbix ιιιθπομηηχ KaTani43aTopoB, H3BecTHbix flnn TaKoii peaKUMM. LV 10470 ΡΕΦΕΡΑΤ M3o6peTeHiie KacaeTca nonnypeTaHOBbix neHOMaTepnanoB, nopbi κοτορΝχ CBoOoflHbi ot rajioreHMpoBaHHbix ymeBOflopoflOB, b naGTHOCTM, cBoOojļHbi ot ΧΦΥ, m cnocoOa nonyHemiH τ3κμχ MaTepi/ianoB, He coflepxamnx ranoreHMpoBaHHbix ymeBOflopoAOB, b HacTHOCTM, 6e3 ncnonb30BaHMfi ΧΦΥ b KanecTBe BcneHMBaiou4MX areHTob. (lopbi ΠΥΡ neHOMaiepna/ia coflepxaT HeOonbuuoe KonunecTBO ncnapuBrneroca BcneHi/iBatoinero arei-rra, MCn0nb30BaHH0r0 B npOLJļeCCe Μ3Γ0Τ0ΒΠβΗ11Π ΠΟ Μ3θ6ρθΤΘΗΙ/ΠΟ, Τ.Θ. >ΚΜβΚΟΓΟ opraHunecKoro npoflyKTa, Bbi6paHHoro W3 rpynnbi, cocTOflUļeii m HH3iuero anKaHa c 3-6 aiOMaMM m ymepofla μ ομθομ Taxnx hh3ujmx anKaHOB, πρμηθμ yKa3aHHbifi xnflKnii BcneHMBatomnii areHT HMeeT TeMnepaTypy KuneHMP Mexny -10 u +70°C npn HopManbHOM α^βπθημμ. Πο cnoco6y HacToamero Μ3θδρΘΤθΗΜίΐ yKa3aHHbiM BcneHUBatomnM areHT πμ6ο tohko pacnpefleneH b
ΟΜΘΟΜ M3 CnUpTOBOrO H M30LļMaHaTHOrO MCXOflHblX ΚΟΜΠΟΗΘΗΤΟΒ, HJIM yKa3aHHbm BcneHMBaromMii areHT CHanana 3MynbrnpyeTca b οπκρτοβομ ncxoflHOM κοΜΠΟΗβΗΤβ, eonn Heo6xoflHMO, c noMOLiļbto 9MynbrupyiūLLļero areHTa, a 3aTeM κ stom 3Mynbcnn Ao6aBnflfOT M30LļnaHaTHbiH κομποηθητ, nocne Hero ocyiAecT8/iflioT 3K30TepMMHecKyio peaKbļHio nonnMepn3ai4HM ncxoflHbix ΚΟΜΠΟΗΘΗΤΟΒ. Bo3Moxho, TaKHM o6pa30M nonyHeHHbiti ΠΥΡ neHOMaTepnan xpaH$rr b TeneHMe HecKonbKnx nacoB wnn αηθμ.

Claims (24)

  1. LV 10470 IZGUDROJUMA FORMULA 1. Poliuretāna putuplasts, kurš satur katalizatoru, poras stabilizējošu aģentu un/vai liesmu slāpētāju, atšķiras ar to,ka tā porās nav halogenētu ogļūdeņražu un ir neliels daudzums putotājaģenta, kurš izmantots šī putuplasta ražošanā un izvēlēts no grupas, kura sastāv no zemākā alkāna ar 3-6 oglekļa atomiem un šādu norādīto zemāko alkānu maisījuma, pie tam norādītais putotājaģents ir ar vārīšanās temperatūru starp -10°C un +70°C pie normāla atmosfēras spiediena.
  2. 2. Poliuretāna putuplasts saskaņā ar 1. p., kas atšķi rasar to, ka zemākais alkāns, tas ir n-pentāns.
  3. 3. Poliuretāna putuplasts saskaņā ar 1. p., kas a t š ķ i r a s ar to, ka zemākais alkāns, tas ir izopentāns.
  4. 4. Poliuretāna putuplasts saskaņā ar jebkuru 1., 2., 3. p. p., kas atšķ iras arto, ka tā poras papildus satur gāzi, izvēlētu no grupas, kura sastāv no slāpekļa lielākā daudzumā, nekā parastais slāpekļa saturs gaisā, cēlgāzes un šādu gāzu maisījumiem.
  5. 5. Poliuretāna putuplasts saskaņā ar 4. p., kas atšķiras ar to, ka šī putuplasta poras satur cēlgāzi argonu.
  6. 6. Poliuretāna putuplasts saskaņā ar jebkuru no 1.-5. p .p., kas atšķir a s ar to, ka šis materiāls satur liesmu slāpētāju, izvēlētu no grupas, kura sastāv no šķidriem liesmu slāpētājiem, cietiem liesmu slāpētājiem un šādu šķidru un cietu liesmu slāpētāju maisījumiem..
  7. 7. Poliuretāna putuplasts saskaņā ar 6. p., kas atšķiras ar'to, ka šis poliuretāna materiāls satur liesmu slāpētāju, izvēlētu no fosforsaturošu liesmu slāpētāju, borsaturošu liesmu slāpētāju un vairāku tādu liesmu slāpētāju maisījumu grupas.
  8. 8. Poliuretāna putuplasts saskaņā ar 6. vai 7.p., kas atšķiras ar to, ka šis poliuretāna materiāls satur liesmu slāpētāju vai liesmu slāpētājus 5 līdz 35 masas % apmērā no putuplasta kopējās galīgās masas.
  9. 9. Poliuretāna putuplasts saskaņā ar 8.p., kas atšķiras ar to, ka šis poliuretāna materiāls satur liesmu slāpētāju vai liesmu slāpētājus 10 līdz 20 masas daļu apmērā no putuplasta kopējās galīgās masas. -2-
  10. 10. Poliuretāna putuplasts saskaņā ar vienu no 6.-9. p. p., kas atšķir a s ar to, ka šis poliuretāna materiāls kā cieto liesmu slāpētāju satur amonija sāli.
  11. 11. Poliuretāna putuplasts saskaņā ar vienu no 6.-9. p. p., kas atšķir a s ar to, ka šis poliuretāna materiāls satur šķidro liesmu slāpētāju, kurš izvēlēts no grupas, kura sastāv no zemāko alkānu esteriem ar zemākajiem alkān-fosfonātiem, kur zemākais alkanols un zemākais alkāns katrs satur no 1 līdz 4 oglekļa atomus, un vairāku tādu liesmu slāpētāju maisījumiem..
  12. 12. Poliuretāna putuplasts saskaņā ar 11. punktu, kas a t š ķ i r a s ar to, ka zemākais alkān-fosfonāts satur 10 līdz 20 masas daļas urīnvielas no zemākā alkānfosfonāta masas.
  13. 13. Poliuretāna putuplasts saskaņā ar 11. vai 12. p. p., kas atšķiras ar to, ka zemākais alkān-fosfonāts satur urīnvielu līdz savam piesātinājumam..
  14. 14. Poliuretāna putuplasta saskaņā ar jebkuru no 1.-13. p. p. iegūšanas paņēmiens, kas atšķiras ar to, ka kā putotājaģentu izmanto nehalogenētu organisku šķidru produktu, izvēlētu no grupas, kura sastāv no zemākajiem alkāniem ar 3-6 oglekļa atomiem un tādu zemāko, alkānu maisījuma, pie tam norādītie zemākie alkāni vai tādu zemāko alkānu maisījums ir ar vārīšanās temperatūru starp -10°C un +70°C pie normāla spiediena, izmanto putotājaģentu un smalki to sadala maisījumā, kurš sastāv no: vai nu spirta izejkomponenta un izocianāta izejkomponenta gala PUR-putuplastam parastajās spirta un izocionāta izejmateriālu attiecībās, pie tam šis maisījums tāpat satur citas parastās piedevas, tādas kā liesmu slāpētāji, katalizatori un poru stabilizatori parastajos daudzumos, vai spirta izejkomponenta gala PUR-putuplastam un citām augstākminētajām piedevām, pievienojot šim smalki sadalītajam maisījumam izocianāta izejkomponentu, pie tam attiecības starp to un spirta izejkomponentu ir parastās PUR uzputojamajiem materiāliem, un pēc tam izdara PUR putuplasta izejmateriālu polimerizāciju parastajos apstākļos, konkrēti, parastajos temperatūras apstākļos.
  15. 15. Paņēmiens saskaņā ar 14. p., kas a t š ķ i r a s ar to, ka polimerizāciju izdara, uzturot spiedienu nedaudz augstāku vai nedaudz zemāku par normālo spiedienu, ja tas nepieciešams, ņemot vērā izmantojamā putotājaģenta vārīšanās temperatūru.
  16. 16. Paņēmiens saskaņā ar jebkuru 14. vai 15. p. p., kas atšķiras ar to, ka tādā veidā iegūto PUR-putuplastu uzglabā laikā no 2 dienām līdz dažiem -3 - LV 10470 mēnešiem pie temperatūras no istabas temperatūras līdz nedaudz paaugstinātai temperatūrai un pie spiediena no normāla līdz nedaudz pazeminātam spiedienam.
  17. 17. Paņēmiens saskaņā ar jebkuru no 14.-16. p p., kas atšķiras ar to, ka putotājaģentu emulģē spirta izejkomponentā, piejaucot citas parastās piedevas un vēlāk piejaucot šai emulsijai izocianāta izejkomponentu.
  18. 18. Paņēmiens saskaņā ar 17. p., kas atšķiras ar to, ka šķidrā putotājaģenta emulģēšanu spirta izejkomponentā ar citu parasto piedevu pievienošanu izdara nepārtraukti piemērotā samaisīšanas ierīcē, bet izocianāta komponentu piejauc tādā veidā iegūtajai emulsijai vēlāk.
  19. 19. Paņēmiens saskaņā ar 17. vai 18. p. p., kas atšķiras ar to, ka putotājaģentu emulģē spirta izejkomponentā, pievienojot citas parastās piedevas un vēlāk piejaucot vienu vai vairākus emulģējošus aģentus.
  20. 20. Paņēmiens saskaņā ar 19. p., kas atšķiras ar to, ka emulģējošo aģentu vai emulģējošos aģentus pievieno daudzumā līdz 10 masas % no izgatavojamā PUR-putuplasta spirta izejkomponentā masas.
  21. 21. Paņēmiens saskaņā ar 19. vai 20. p:, kas atšķiras ar to, ka emulģējošais aģents vai emulģējošie aģenti ir taukskābes atvasinājumi.
  22. 22. Paņēmiens saskaņā ar jebkuru no 14.-16. p. p., kas atšķiras ar to, ka spirta izejkomponentu, izocianāta izejkomponentu, putotājaģentu un citas parastās piedevas samaisa maisītāja galviņā un iegūto maisījumu pakļauj polimerizācijas reakcijai ar putošanu ar parastajām metodēm.
  23. 23. Paņēmiens saskaņā ar jebkuru no 14.-22. p. p., kas atšķiras ar to, ka vai nu izmantojamo putotājaģentu, vai spirta izejkomponentā un šķidrā putotājaģenta maisījumu piesātina ar gāzi, izvēlētu no grupas, kura sastāv no slāpekļa, cēlgāzēm, slāpekļa un cēlgāzes maisījumiem un vairāku cēlgāzu maisījumiem.
  24. 24. Paņēmiens saskaņā ar jebkuru no 14.-23. p. p., kas atšķiras ar to, ka izmantojamais polimerizācijas reakcijas katalizators izvēlēts no grupas, kura sastāv no pamatkatalizatoriem, kuri pazīstami PUR polimerizācijai un no stipri sārmainiem katalizatoriem šādai reakcijai.
LVP-93-33A 1989-04-24 1993-01-15 Polyurethane foam and process for producing therof LV10470B (en)

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DE3913473 1989-04-24
DE3933705A DE3933705C1 (lv) 1989-04-24 1989-10-09
DE19893936227 DE3936227A1 (de) 1989-10-09 1989-10-31 Halogenkohlenwasserstofffreier polyurethanschaumstoff mit hohem waermeisolationsvermoegen und verfahren zu seiner herstellung
DE19904003718 DE4003718A1 (de) 1990-02-08 1990-02-08 Halogenkohlenwasserstofffreier polyurethanschaumstoff mit dauerhaftem brandschutz und verfahren zu seiner herstellung
PCT/EP1990/000581 WO1990012841A1 (en) 1989-04-24 1990-04-12 Polyurethane foam material free of halogenated hydrocarbons and process for producing the same

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LV10470A LV10470A (lv) 1995-02-20
LV10470B true LV10470B (en) 1995-10-20

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PT93851A (pt) 1990-11-20
RU2058336C1 (ru) 1996-04-20
PL164531B1 (en) 1994-08-31
US5182309A (en) 1993-01-26
CA2031218A1 (en) 1990-10-25
HUT59171A (en) 1992-04-28
LV10470A (lv) 1995-02-20
HU903726D0 (en) 1991-07-29
JPH0762090B2 (ja) 1995-07-05
CA2031218C (en) 1997-11-04
AU5406590A (en) 1990-11-16
EP0394769A1 (de) 1990-10-31
YU81690A (en) 1991-08-31
ATE161865T1 (de) 1998-01-15
JPH03505599A (ja) 1991-12-05
HU210404B (en) 1995-04-28
HRP920980A2 (hr) 1994-04-30
EP0394769B1 (de) 1998-01-07
PT93851B (pt) 1996-09-30
DE59010789D1 (de) 1998-02-12
WO1990012841A1 (en) 1990-11-01
AU638243B2 (en) 1993-06-24

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