LU100762B1 - Clay activator - Google Patents
Clay activator Download PDFInfo
- Publication number
- LU100762B1 LU100762B1 LU100762A LU100762A LU100762B1 LU 100762 B1 LU100762 B1 LU 100762B1 LU 100762 A LU100762 A LU 100762A LU 100762 A LU100762 A LU 100762A LU 100762 B1 LU100762 B1 LU 100762B1
- Authority
- LU
- Luxembourg
- Prior art keywords
- nail polish
- cosmetic composition
- composition
- weight
- acid
- Prior art date
Links
- 239000004927 clay Substances 0.000 title description 3
- 239000012190 activator Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 74
- 239000002537 cosmetic Substances 0.000 claims abstract description 39
- 229910052615 phyllosilicate Inorganic materials 0.000 claims abstract description 30
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 14
- 150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 14
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims abstract description 14
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000138 intercalating agent Substances 0.000 claims abstract description 13
- 239000003960 organic solvent Substances 0.000 claims abstract description 12
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- 239000004310 lactic acid Substances 0.000 claims abstract description 8
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 8
- BTUDGPVTCYNYLK-UHFFFAOYSA-N 2,2-dimethylglutaric acid Chemical compound OC(=O)C(C)(C)CCC(O)=O BTUDGPVTCYNYLK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940074391 gallic acid Drugs 0.000 claims abstract description 7
- 235000004515 gallic acid Nutrition 0.000 claims abstract description 7
- 239000001384 succinic acid Substances 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 12
- 239000003086 colorant Substances 0.000 claims description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000000020 Nitrocellulose Substances 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 229920001220 nitrocellulos Polymers 0.000 claims description 6
- 239000006096 absorbing agent Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 4
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- OMVSWZDEEGIJJI-UHFFFAOYSA-N 2,2,4-Trimethyl-1,3-pentadienol diisobutyrate Chemical compound CC(C)C(=O)OC(C(C)C)C(C)(C)COC(=O)C(C)C OMVSWZDEEGIJJI-UHFFFAOYSA-N 0.000 claims description 2
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 claims description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical group CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 229940031769 diisobutyl adipate Drugs 0.000 claims description 2
- 229940031578 diisopropyl adipate Drugs 0.000 claims description 2
- 239000001087 glyceryl triacetate Substances 0.000 claims description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 2
- 238000009830 intercalation Methods 0.000 claims description 2
- 230000002687 intercalation Effects 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims description 2
- 229910021647 smectite Inorganic materials 0.000 claims description 2
- SYDJVRWZOWPNNO-UHFFFAOYSA-N sucrose-benzoate Natural products OCC1OC(OC2(COC(=O)c3ccccc3)OC(CO)C(O)C2O)C(O)C(O)C1O SYDJVRWZOWPNNO-UHFFFAOYSA-N 0.000 claims description 2
- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 claims description 2
- 229960002622 triacetin Drugs 0.000 claims description 2
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims description 2
- 239000001069 triethyl citrate Substances 0.000 claims description 2
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013769 triethyl citrate Nutrition 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- 235000019354 vermiculite Nutrition 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 claims 1
- 229940100539 dibutyl adipate Drugs 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- -1 K + Chemical class 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- VYGQUTWHTHXGQB-FFHKNEKCSA-N Retinol Palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C VYGQUTWHTHXGQB-FFHKNEKCSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 235000010980 cellulose Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004299 exfoliation Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 238000000518 rheometry Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 2
- YCMLQMDWSXFTIF-UHFFFAOYSA-N 2-methylbenzenesulfonimidic acid Chemical compound CC1=CC=CC=C1S(N)(=O)=O YCMLQMDWSXFTIF-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 2
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
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- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 2
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- 235000011187 glycerol Nutrition 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
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- 229910052700 potassium Inorganic materials 0.000 description 2
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- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
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- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 1
- 229960005193 avobenzone Drugs 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229960002685 biotin Drugs 0.000 description 1
- 235000020958 biotin Nutrition 0.000 description 1
- 239000011616 biotin Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 150000001669 calcium Chemical class 0.000 description 1
- FAPWYRCQGJNNSJ-UBKPKTQASA-L calcium D-pantothenic acid Chemical compound [Ca+2].OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O.OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O FAPWYRCQGJNNSJ-UBKPKTQASA-L 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229960002079 calcium pantothenate Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 229940075894 denatured ethanol Drugs 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- FOYKKGHVWRFIBD-UHFFFAOYSA-N gamma-tocopherol acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 FOYKKGHVWRFIBD-UHFFFAOYSA-N 0.000 description 1
- 229960003180 glutathione Drugs 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- DHRXPBUFQGUINE-UHFFFAOYSA-N n-(2-hydroxypropyl)benzenesulfonamide Chemical compound CC(O)CNS(=O)(=O)C1=CC=CC=C1 DHRXPBUFQGUINE-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- FGTVYMTUTYLLQR-UHFFFAOYSA-N n-ethyl-1-phenylmethanesulfonamide Chemical compound CCNS(=O)(=O)CC1=CC=CC=C1 FGTVYMTUTYLLQR-UHFFFAOYSA-N 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical class C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- FZBIESPTFIVNEJ-UHFFFAOYSA-N oxiran-2-ylmethyl decanoate Chemical compound CCCCCCCCCC(=O)OCC1CO1 FZBIESPTFIVNEJ-UHFFFAOYSA-N 0.000 description 1
- 229960001173 oxybenzone Drugs 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229940070720 stearalkonium Drugs 0.000 description 1
- 125000005502 stearalkonium group Chemical group 0.000 description 1
- 229940102548 stearalkonium hectorite Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000001797 sucrose acetate isobutyrate Substances 0.000 description 1
- 235000010983 sucrose acetate isobutyrate Nutrition 0.000 description 1
- UVGUPMLLGBCFEJ-SWTLDUCYSA-N sucrose acetate isobutyrate Chemical compound CC(C)C(=O)O[C@H]1[C@H](OC(=O)C(C)C)[C@@H](COC(=O)C(C)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(=O)C(C)C)[C@@H](OC(=O)C(C)C)[C@H](OC(=O)C(C)C)[C@@H](COC(C)=O)O1 UVGUPMLLGBCFEJ-SWTLDUCYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Composition cosmétique pour vernis à ongles comprenant au moins un solvant organique cosmétiquement acceptable et au moins un plastifiant, ladite composition étant structurée par au moins un phyllosilicate exfolié dérivant d'au moins un phyllosilicate intercalé par un agent intercalant, caractérisé en ce que l'agent intercalant est choisi parmi les acides carboxyliques ou dicarboxyliques en C3-Ci0, de préférence sélectionnés parmi les acides dicarboxyliques, par exemple l'acide succinique ou l'acide diméthylglutarique, ou parmi les acides carboxyliques hydroxylés, par exemple l'acide lactique ou l'acide gallique, dans une composition cosmétique pour vernis à ongles.Cosmetic composition for nail polish comprising at least one cosmetically acceptable organic solvent and at least one plasticizer, said composition being structured by at least one exfoliated phyllosilicate derived from at least one phyllosilicate intercalated by an intercalating agent, characterized in that the agent intercalant is chosen from C3-C10 carboxylic or dicarboxylic acids, preferably selected from dicarboxylic acids, for example succinic acid or dimethylglutaric acid, or from hydroxylated carboxylic acids, for example lactic acid or gallic acid, in a cosmetic composition for nail polish.
Description
ACTIVATEUR D’ARGILESACTIVATOR OF ARGILES
Domaine technique [0001] La présente invention concerne une composition cosmétique pour vernis à ongles.Technical Field [0001] The present invention relates to a cosmetic composition for nail polish.
Etat de la technique [0002] Les argiles ont de nombreuses propriétés intéressantes pour les applications cosmétiques telles que le gonflement (suspensions colloïdales et effet thixotropique), l'échange (capacité de complexation) ou encore leurs propriétés absorbantes.STATE OF THE ART [0002] Clays have numerous properties of interest for cosmetic applications such as swelling (colloidal suspensions and thixotropic effect), exchange (complexing capacity) or their absorbing properties.
[0003] Les argiles sont des minéraux de structure feuilletée (phyllosilicates) expliquant leur plasticité, ou fibreuse (sépiolite et palygorskite) expliquant leur qualité d'absorption.Clays are minerals of laminated structure (phyllosilicates) explaining their plasticity, or fibrous (sepiolite and palygorskite) explaining their quality of absorption.
[0004] La structure des argiles phyllosilicates se caractérise par la superposition de feuillets composés de couches tétraédriques ou octaédriques. Ces derniers sont classés en trois grandes familles selon l'épaisseur des feuillets (0,7, 1 ou 1,4 nm), qui correspondent à un nombre de couches d'oxydes tétraédriques (Si) et octaédriques (Al, Ni, Mg, Fe(ll), Fe(lll), Mn, Na, K, etc.).The structure of phyllosilicates clays is characterized by the superposition of layers composed of tetrahedral or octahedral layers. The latter are classified into three major families according to the thickness of the sheets (0.7, 1 or 1.4 nm), which correspond to a number of layers of tetrahedral (Si) and octahedral oxides (Al, Ni, Mg, Fe (II), Fe (III), Mn, Na, K, etc.).
[0005] L'interstice, ou espace interfoliaire (espace entre feuillets), peut contenir de l'eau ainsi que des cations comme K+, Na+, Ca++. Il en résulte des variations de la distance entre feuillets, et donc des variations dimensionnelles macroscopiques de l'argile quand elle s'hydrate (dilatation) ou s'assèche (contraction).The interstice, or interfoliar space (space between sheets), may contain water as well as cations such as K +, Na +, Ca ++. This results in variations in the distance between sheets, and therefore macroscopic dimensional variations of the clay when it is hydrated (dilation) or dries (contraction).
[0006] Pour que les phyllosilicates puissent jouer leur rôle structurant au sein d'une composition pour vernis à ongles, il faut donc intercaler voire exfolier les feuillets.For phyllosilicates can play their structuring role in a composition for nail polish, it is necessary to interpose or even exfoliate the sheets.
[0007] En cosmétique, un mécanisme de choix est l'intercalation par interaction acide, plus particulièrement par l'utilisation de l'acide ortho-phosphorique. En effet, il est traditionnellement admis que plus l'acide est fort, plus l'exfoliation est efficace. L'inconvénient de l'utilisation de l'acide ortho-phosphorique est que cet acide va nuire aux résines polyesters incluant un certain nombre de plastifiants comprenant une fonction ester, ainsi qu'éventuellement même à la nitrocellulose, présents dans la composition. En effet, les acides forts peuvent conduire à l'hydrolyse complète de la fonction ester conduisant à la destruction totale du polymère et/ou du plastifiant.In cosmetics, a mechanism of choice is intercalation by acid interaction, more particularly by the use of ortho-phosphoric acid. Indeed, it is traditionally accepted that the stronger the acid, the more effective the exfoliation. The disadvantage of the use of ortho-phosphoric acid is that this acid will harm the polyester resins including a number of plasticizers comprising an ester function, and possibly even nitrocellulose, present in the composition. Indeed, the strong acids can lead to the complete hydrolysis of the ester function leading to the total destruction of the polymer and / or the plasticizer.
[0008] En conséquence, il existe un besoin de développer des vernis à ongles pouvant remédier du moins partiellement à l'inconvénient mentionné ci-dessus.Accordingly, there is a need to develop nail polish that can at least partially remedy the disadvantage mentioned above.
Objet de l'invention [0009] Un objet de la présente invention est donc de proposer une alternative à l'utilisation de l'acide phosphorique tout en ne compromettant pas les propriétés attendues et nécessaires de la composition cosmétique.OBJECT OF THE INVENTION [0009] An object of the present invention is therefore to propose an alternative to the use of phosphoric acid while not compromising the expected and necessary properties of the cosmetic composition.
Description générale de l'invention [0010] Afin de résoudre le problème mentionné ci-dessus, la présente invention, propose, dans un premier aspect, une composition cosmétique pour vernis à ongles comprenant au moins un solvant organique cosmétiquement acceptable et au moins un plastifiant, ladite composition étant structurée par au moins un phyllosilicate exfolié dérivant d'au moins un phyllosilicate intercalé par un agent intercalant, caractérisée en ce que l'agent intercalant est choisi parmi les acides carboxyliques ou dicarboxyliques en C3-C10, de préférence sélectionnés parmi les acides dicarboxyliques, par exemple l'acide succinique ou l'acide diméthylglutarique, ou parmi les acides carboxyliques hydroxylés, par exemple l'acide lactique ou l'acide gallique.General description of the invention [0010] In order to solve the problem mentioned above, the present invention proposes, in a first aspect, a cosmetic composition for nail polish comprising at least one cosmetically acceptable organic solvent and at least one plasticizer. , said composition being structured by at least one exfoliated phyllosilicate derived from at least one phyllosilicate intercalated with an intercalating agent, characterized in that the intercalating agent is chosen from C3-C10 carboxylic or dicarboxylic acids, preferably selected from the group consisting of dicarboxylic acids, for example succinic acid or dimethylglutaric acid, or from hydroxylated carboxylic acids, for example lactic acid or gallic acid.
[0011] Dans un deuxième aspect, l'invention concerne un vernis à ongles comprenant une composition cosmétique pour vernis à ongles selon la présente invention.In a second aspect, the invention relates to a nail polish comprising a cosmetic composition for nail polish according to the present invention.
[0012] Dans un troisième aspect, l'invention propose également l'utilisation de l’agent intercalant défini ci-dessus pour exfolier les feuillets de phyllosilicates.In a third aspect, the invention also provides the use of the intercalating agent defined above for exfoliating the sheets of phyllosilicates.
[0013] De manière surprenante, les inventeurs ont découvert que la substitution (partielle ou totale) de l'acide ortho-phosphorique, utilisé traditionnellement comme agent intercalant pour exfolier les phyllosilicates, par un acide tel que les acides carboxyliques ou dicarboxyliques en C3-C10, de préférence sélectionnés parmi les acides dicarboxyliques, par exemple l'acide succinique ou l'acide diméthylglutarique, ou parmi les acides carboxyliques hydroxylés, par exemple l'acide lactique ou l'acide gallique, permettait une exfoliation tout en préservant les résines polyesters et certains plastifiants comprenant une fonction ester, voire la nitrocellulose, compris le cas échéant dans la composition cosmétique.Surprisingly, the inventors have discovered that the substitution (partial or total) of ortho-phosphoric acid, traditionally used as intercalating agent for exfoliating phyllosilicates, by an acid such as carboxylic or dicarboxylic acids in C3- C10, preferably selected from dicarboxylic acids, for example succinic acid or dimethylglutaric acid, or from hydroxylated carboxylic acids, for example lactic acid or gallic acid, allowed exfoliation while preserving the polyester resins and certain plasticizers comprising an ester function, or even nitrocellulose, optionally included in the cosmetic composition.
[0014] Une composition n'est pas juste une addition d'ingrédients facilement remplaçable par d'autres et il est probable que l’ajout ou la substitution d’un composant affecte négativement d’autres propriétés de la formulation.A composition is not just an addition of easily replaceable ingredients by others and it is likely that the addition or substitution of one component negatively affects other properties of the formulation.
[0015] Par conséquent, l'avantage de la présente invention consiste à proposer d'autres ingrédients compatibles avec les ingrédients normalement présent dans une composition et ayant une efficacité similaire. L'avantage additionnel étant un moindre degré de nuisance des résines et/ou de plastifiants et/ou nitrocellulose présents dans la composition. En outre, la composition reste stable dans le temps et ne montre ni synérèse, ni sédimentation.Therefore, the advantage of the present invention is to provide other ingredients compatible with the ingredients normally present in a composition and having a similar effectiveness. The additional advantage being a lesser degree of nuisance of the resins and / or plasticizers and / or nitrocellulose present in the composition. In addition, the composition remains stable over time and shows neither syneresis nor sedimentation.
[0016] Le terme «phyllosilicates intercalés», signifie que des phyllosilicates ont été traités avec des composés organiques ou inorganiques en vue d'introduire des molécules de ces composés dans les espaces interfoliaires desdits phyllosilicates, d'une part pour augmenter la distance entre les feuillets et, d'autre part leur apporter un caractère organophile.The term "interposed phyllosilicates" means that phyllosilicates have been treated with organic or inorganic compounds in order to introduce molecules of these compounds into the interplanar spaces of said phyllosilicates, on the one hand to increase the distance between them. leaflets and, on the other hand, bring them an organophilic character.
[0017] Dans l'expression «phyllosilicate exfolié dérivant d'au moins un phyllosilicate intercalé», on entend par le terme «dérivant», qualifié le fait que les phyllosilicates à l'état de feuillets sont obtenus à partir de phyllosilicates intercalés par application à ces derniers d'une force de cisaillement suffisante pour permettre au moins en partie, et notamment en totalité leur exfoliation.In the expression "exfoliated phyllosilicate derived from at least one interspersed phyllosilicate", the term "derivative" is used to describe the fact that phyllosilicates in the form of sheets are obtained from phyllosilicates intercalated by application. to these of a shearing force sufficient to allow at least partly, and in particular their entire exfoliation.
[0018] Les phyllosilicates utilisables selon l'invention, dérivent plus particulièrement de phyllosilicates de type smectite comme les montmorillonites notamment les montmorillonites de sodium, de potassium et/ou de calcium, les nontronites, beidellites, volkonskoïtes, hectorites, saponites, sauconites, sobockites, stevensites, svinfordites, vermiculites et leurs mélanges.The phyllosilicates that can be used according to the invention are derived more particularly from phyllosilicates of the smectite type, such as montmorillonites, in particular montmorillonites of sodium, potassium and / or calcium, nontronites, beidellites, volkonskoyes, hectorites, saponites, sauconites, and sobockites. , stevensites, svinfordites, vermiculites and mixtures thereof.
[0019] La composition selon l'invention possède une teneur en phyllosilicates exfoliés variant de 0.5 % à 10 % en poids, de préférence entre 1 % et 5 % en poids total de la composition pour vernis à ongles.The composition according to the invention has a content of exfoliated phyllosilicates ranging from 0.5% to 10% by weight, preferably between 1% and 5% by total weight of the composition for nail polish.
[0020] Les phyllosilicates exfoliés selon l'invention présentent avantageusement, adsorbés à la surface de leurs feuillets, au moins un «un agent intercalant», lequel agent étant intercalé entre les feuillets du phyllosilicate dit «intercalé» utilisé pour préparer la composition selon l'invention. La quantité de l'agent intercalant est généralement comprise entre 0,01 % et 1 % en poids et de préférence entre 0,05 % et 0,5 % en poids par rapport au poids de phyllosilicate sec (comprenant moins de 5 % d'eau).The exfoliated phyllosilicates according to the invention advantageously have, adsorbed on the surface of their layers, at least one "intercalating agent", which agent is interposed between the sheets of the phyllosilicate said "interposed" used to prepare the composition according to the invention. 'invention. The amount of the intercalating agent is generally between 0.01% and 1% by weight and preferably between 0.05% and 0.5% by weight relative to the weight of dry phyllosilicate (comprising less than 5% by weight). water).
[0021] La composition cosmétique selon la présente invention comprend au moins un plastifiant afin de moduler la dureté du film formé afin d'obtenir les caractéristiques physico-chimiques du film souhaitées et représentent en général de 3 % à 12 % en poids sec, de préférence 4 % à 8 % en poids sec par rapport au poids total de la composition. Le plastifiant est de préférence choisi parmi l'acétyl tributyl citrate, l'acétyl triéthyl citrate, le tributyl citrate, le triéthylcitrate, le dibutyl phtalate, le triphénylphosphate, la triacétine, le triméthyl pentanyl diisobutyrate, la triéthylhexanoïne, le sucrose benzoate, le dibutyl adipate, le diéthyl phtalate, le diisobutyl adipate, le diisopropyl adipate, le dipropylène glycol dibenzoate, le N-éthyl toluène sulfonamide, ses isomères ortho et para, le N-(2-hydroxypropyl) benzène sulfonamide et le N-(n-butyl) benzène sulfonamide, etc.The cosmetic composition according to the present invention comprises at least one plasticizer in order to modulate the hardness of the film formed in order to obtain the desired physico-chemical characteristics of the film and generally represent from 3% to 12% by dry weight, of preferably 4% to 8% by dry weight relative to the total weight of the composition. The plasticizer is preferably chosen from acetyl tributyl citrate, acetyl triethyl citrate, tributyl citrate, triethyl citrate, dibutyl phthalate, triphenyl phosphate, triacetin, trimethyl pentanyl diisobutyrate, triethyl hexanoine, sucrose benzoate and dibutyl. adipate, diethyl phthalate, diisobutyl adipate, diisopropyl adipate, dipropylene glycol dibenzoate, N-ethyl toluene sulfonamide, its ortho and para isomers, N- (2-hydroxypropyl) benzene sulfonamide and N- (n-butyl) ) benzene sulfonamide, etc.
[0022] La composition cosmétique pour vernis à ongles comprend un solvant organique. Ce solvant organique peut être choisi parmi le groupe constitué par le toluène, le xylène, l’acétate d’éthyle, l’acétate de butyle, comme l’acétate de n-butyle, l’acétate de sec-butyle, l’acétate de tert-butyle ou l’acétate d’isobutyle, l’acétate de propyle, l’acétate de méthyle, une cétone, un ester, l’isopropanol, le butanol, le diacétone alcool, l’éthanol dénaturé (avec la méthyléthylcétone ou le diéthyléther), les hydrocarbures linéaires ou cycliques, comme par exemple l’hexane, le cyclohexane, l’heptane et n’importe quelle combinaison de ceux-ci.The cosmetic composition for nail polish comprises an organic solvent. This organic solvent may be chosen from the group consisting of toluene, xylene, ethyl acetate and butyl acetate, such as n-butyl acetate, sec-butyl acetate and acetate. of tert-butyl or isobutyl acetate, propyl acetate, methyl acetate, a ketone, an ester, isopropanol, butanol, diacetone alcohol, denatured ethanol (with methyl ethyl ketone or diethyl ether), linear or cyclic hydrocarbons, such as, for example, hexane, cyclohexane, heptane and any combination thereof.
[0023] Le solvant organique pourra être choisi en fonction de ses propriétés physico-chimiques et en considération des autres composants présents dans la composition cosmétique pour vernis à ongles. De façon préférée, la quantité de solvant organique présente dans la composition cosmétique pour vernis à ongles est comprise entre 50 % et 80 % en poids par rapport au poids total de la composition.The organic solvent may be selected according to its physico-chemical properties and in consideration of the other components present in the cosmetic composition for nail polish. Preferably, the amount of organic solvent present in the cosmetic composition for nail polish is between 50% and 80% by weight relative to the total weight of the composition.
[0024] Avantageusement, le solvant organique est l’acétate de butyle et/ou l’acétate d’éthyle.[0024] Advantageously, the organic solvent is butyl acetate and / or ethyl acetate.
[0025] L'invention peut également comprendre un ou plusieurs agents filmogènes. Le ou les agent(s) filmogène(s) pouvant être compris dans la composition cosmétique pour vernis à ongles peu(ven)t être choisi(s) parmi le groupe constitué par la cellulose, un dérivé de cellulose, une résine vinylique, une résine acrylique et n’importe quelle combinaison de ceux-ci. Les dérivés de cellulose sont par exemple la nitrocellulose, l’acétate butyrate cellulose, l’éthylcellulose et l’hydroxypropyhcellulose. Préférentiellement, on choisira la nitrocellulose comme agent filmogène.The invention may also comprise one or more film-forming agents. The film-forming agent (s) that may be included in the cosmetic composition for nail polish may be chosen from the group consisting of cellulose, a cellulose derivative, a vinyl resin, a acrylic resin and any combination thereof. The cellulose derivatives are, for example, nitrocellulose, acetate butyrate cellulose, ethylcellulose and hydroxypropylcellulose. Preferably, nitrocellulose will be chosen as the film-forming agent.
[0026] Un agent filmogène seul ou une combinaison d’agents filmogènes peut être utilisé(e) dans la composition cosmétique pour vernis à ongles dans les proportions allant de 8 % à 20 % en poids sec et de façon préférée de 12 % à 16 % en poids sec par rapport au poids total de la composition.A film-forming agent alone or a combination of film-forming agents may be used in the cosmetic composition for nail polish in proportions ranging from 8% to 20% by dry weight and preferably from 12% to 16% by weight. % by dry weight relative to the total weight of the composition.
[0027] Si nécessaire ou souhaité, la composition cosmétique pour vernis à ongles peut également comprendre un agent filmogène de type biopolyester tel que l'acide polylactique et/ou le triéthylphosphate. Le pourcentage de cet agent filmogène dans la formule peut aller de 0,05 % à 15 % en poids sec par rapport au poids total de la composition.If necessary or desired, the cosmetic composition for nail polish may also comprise a film-forming agent of biopolyester type such as polylactic acid and / or triethylphosphate. The percentage of this film-forming agent in the formula can range from 0.05% to 15% by dry weight relative to the total weight of the composition.
[0028] Pour colorer ou fournir des effets particuliers à la composition cosmétique pour vernis à ongles, elle peut comprendre un ou plusieurs agents de coloration, de préférence choisis parmi les pigments, les nacres, les glitters (paillettes) et/ou les particules métalliques. Ces agents de coloration fournissent l’aspect esthétique recherché par les utilisateurs de vernis à ongles. Ces agents de coloration peuvent produire des effets très différents tels que « irisé », « métallisé », « nacré », « miroir », « crème », « pailleté », craquelé », « mat », « néon », « fluorescent », « holographique », etc.To color or provide particular effects to the cosmetic composition for nail polish, it may comprise one or more coloring agents, preferably chosen from pigments, nacres, glitters (glitter) and / or metal particles. . These coloring agents provide the aesthetic appearance sought by nail polish users. These coloring agents can produce very different effects such as "iridescent", "metallic", "pearlescent", "mirror", "cream", "glittery", crackle "," matte "," neon "," fluorescent " , "Holographic", etc.
[0029] En particulier, les pigments peuvent être sélectionnés parmi le groupe comprenant le dioxyde de titane (Cl 77891), l'oxyde de fer noir (Cl 77499), l'oxyde de fer rouge (Cl 77491 ), le DC Red 6 Ba Lake (Cl 15850), le DC Red 7 Ca Lake (Cl 15850:1), le DC Red 34 Ca Lake (Cl 15880), le FDC Yellow 5 Al Lake (Cl 19140), le FDC Blue 1 Al Lake (Cl 42090), le bleu ultramarine (Cl 77007), le DC Violet 2 (Cl 60725), le DC Black 2 (Cl 77266), etc.In particular, the pigments may be selected from the group consisting of titanium dioxide (Cl 77891), black iron oxide (Cl 77499), red iron oxide (Cl 77491), DC Red 6 Ba Lake (Cl 15850), DC Red 7 Ca Lake (Cl 15850: 1), DC Red 34 Ca Lake (Cl 15880), FDC Yellow 5 Al Lake (Cl 19140), FDC Blue 1 Al Lake (Cl 42090), ultramarine blue (Cl 77007), Violet DC 2 (Cl 60725), DC Black 2 (Cl 77266), etc.
[0030] Les nacres sont des particules minérales de différentes natures recouvertes d'une ou plusieurs couches d'oxydes (oxydes de titane ou oxydes de fer) ou encore de pigments. Les nacres peuvent se présenter sous la forme d'une poudre ou de plaques de tailles variées. Parmi les nacres utilisables dans l'invention, on peut citer : • les nacres préparées à partir de mica naturel et ayant subi des opérations de coating successives, • les nacres préparées à partir de mica synthétique appelé également « synthetic fluorphlogopite », • les nacres préparées à partir de calcium sodium borosilicate, • les nacres préparées à partir d'oxyde de silice.The nacres are mineral particles of different types covered with one or more layers of oxides (titanium oxides or iron oxides) or pigments. The nacres can be in the form of a powder or plates of various sizes. Among the nacres that may be used in the invention, mention may be made of: nacres prepared from natural mica and having undergone successive coating operations, nacres prepared from synthetic mica also called synthetic fluorphlogopite, nacres prepared from sodium borosilicate calcium, • nacres prepared from silica oxide.
[0031] Les glitters (paillettes) utilisables dans l'invention peuvent être préparés à partir de plusieurs types de matériaux comme les films polyesters comportant en surface une couche métallique, le polyéthylène téréphtalate, le polybutylène téréphtalate, les copolymères d'acrylates, les copolymères d'acrylates ou encore l'aluminium.The glitters (flakes) used in the invention can be prepared from several types of materials such as polyester films having on the surface a metal layer, polyethylene terephthalate, polybutylene terephthalate, copolymers of acrylates, copolymers acrylates or aluminum.
[0032] Selon un mode de réalisation de l’invention, la composition cosmétique pour vernis à ongles comprend une quantité d’agent de coloration comprise de 0,1 % à 20 % en poids sec et de préférence de 0,5 % à 15 % en poids sec par rapport au poids total de la composition.According to one embodiment of the invention, the cosmetic composition for nail polish comprises an amount of coloring agent of from 0.1% to 20% by dry weight and preferably from 0.5% to 15% by weight. % by dry weight relative to the total weight of the composition.
[0033] La composition cosmétique pour vernis à ongles selon l'invention peut également contenir des résines conventionnelles. Les résines conventionnelles utilisables sont les suivantes : • Résines polyester • Résines époxytosylamide • Résine acrylate et styrène-acrylate • Sucrose perbenzoate [0034] Des résines supplémentaires peuvent également être ajoutées dans la composition. En particulier, ces résines supplémentaires permettent d'augmenter le collant et l'adhérence du film sur l'ongle.The cosmetic composition for nail polish according to the invention may also contain conventional resins. The conventional resins that can be used are the following: • Polyester resins • Epoxytosylamide resins • Acrylate and styrene-acrylate resin • Sucrose perbenzoate [0034] Additional resins can also be added to the composition. In particular, these additional resins make it possible to increase the tackiness and the adhesion of the film to the nail.
[0035] Les résines supplémentaires pouvant être utilisées sont les suivantes : • Les résines tosylamide/formaldéhyde ou résines toluènesulfonamide/ formahdé_,hyde, • Les résines tosylamide/époxy ou résines toluènesulfonamide/époxy, • La résine de copolymères d’acide adipique, d’acide fumarique, de néopentylglycol et de cyclohexanediméthanol • Copolymères acide adipique/néopentyl glycol/anhydride triméllitique, • Copolymères d’anhydride phtalique/glycérine/glycidyl décanoate, • Copolymères d’anhydride phtalique/anhydride trimellitique/glycols, • Copolymères de glycérine/acide phtalique, • Copolymères styrène/acrylate/acrylonitrile, • Polymères et copolymères d'acrylates, • Copolymères d'acrylates et de styrène, • Sucrose acétate isobutyrate, • Résine polyvinylbutyral.The additional resins that may be used are the following: • tosylamide / formaldehyde resins or toluenesulfonamide / formahde, hyde resins, • tosylamide / epoxy resins or toluenesulfonamide / epoxy resins, • adipic acid copolymer resin, d fumaric acid, neopentyl glycol and cyclohexanedimethanol • Copolymers adipic acid / neopentyl glycol / trimellitic anhydride • Copolymers of phthalic anhydride / glycerin / glycidyl decanoate • Copolymers of phthalic anhydride / trimellitic anhydride / glycols • Copolymers of glycerin / acid phthalic, • Styrene / acrylate / acrylonitrile copolymers, • Polymers and copolymers of acrylates, • Copolymers of acrylates and styrene, • Sucrose acetate isobutyrate, • Polyvinylbutyral resin.
[0036] En plus de leur action collante, la plupart de ces résines ont également une action plastifiante. Les résines peuvent être utilisées dans la formule, seules ou sous la forme de mélanges, dans des quantités allant de 1 % à 25 % en poids sec, de préférence 5 % à 15 % en poids sec, en particulier de 7 % à 12 % en poids sec par rapport au poids total de la composition.In addition to their sticky action, most of these resins also have a plasticizing action. The resins can be used in the formula, alone or in the form of mixtures, in amounts ranging from 1% to 25% by dry weight, preferably 5% to 15% by dry weight, in particular from 7% to 12% by weight. in dry weight relative to the total weight of the composition.
[0037] La composition cosmétique pour vernis à ongles peut en outre comprendre divers additifs choisis parmi les additifs de rhéologie, les absorbeurs UV, les modificateurs de surface et les agents dits « traitants ».The cosmetic composition for nail polish may further comprise various additives selected from rheology additives, UV absorbers, surface modifiers and so-called "treating agents".
[0038] Les différents additifs utilisables dans l'invention sont :Parmi les additifs de rhéologie, on citera notamment les dérivés d'argile modifiés comme le stéaralkonium hectorite ou le stéaralkonium bentonite ou de type silice pyrogénée. Ces additifs de rhéologie seront de préférence utilisés de 0,1 à 4 % en poids sec par rapport au poids total de la composition. Ces additifs permettent notamment la suspension des particules insolubles dans le vernis tels que les pigments ou encore les nacres.The various additives that can be used in the invention are: Among the rheology additives, mention may be made in particular of modified clay derivatives such as stearalkonium hectorite or stearalkonium bentonite or of pyrogenic silica type. These rheology additives will preferably be used from 0.1 to 4% by dry weight relative to the total weight of the composition. These additives allow in particular the suspension of insoluble particles in the varnish such as pigments or nacres.
[0039] Parmi les absorbants UV, on citera les absorbants de lumière UV qui permettent de protéger la formulation ou les agents colorants utilisés l'invention des rayonnements UV. Parmi les protecteurs UV utilisables dans l'invention, on citera : la benzophénone-1 (CAS 131-56-6), la benzophénone-3 (CAS 131-57-7), le benzyl salicylate (CAS 118-58-1), l'étocrylène (CAS 5232-99-5), le drométrizole (CAS 2440-22-4), le butyl méthoxydibenzoylméthane (CAS 70356-09-1), etc.Among the UV absorbers, mention will be made of UV light absorbers which protect the formulation or the coloring agents used in the invention of UV radiation. Among the UV protectors that can be used in the invention, mention will be made of benzophenone-1 (CAS 131-56-6), benzophenone-3 (CAS 131-57-7) and benzyl salicylate (CAS 118-58-1). , etocrylene (CAS 5232-99-5), drometzole (CAS 2440-22-4), butyl methoxydibenzoylmethane (CAS 70356-09-1), etc.
[0040] Les absorbants UV seront utilisés seuls ou sous la forme de combinaison dont le pourcentage total dans la formule peut aller de 0,1 % à 1 % en poids sec par rapport au poids total de la composition.UV absorbers will be used alone or in the form of combination whose total percentage in the formula can range from 0.1% to 1% by dry weight relative to the total weight of the composition.
[0041] Parmi les additifs utilisables selon l'invention, on citera également les modificateurs de surface comme les cyclométhicones ou cyclopentasiloxane, les diméthicones et le triméthylsiloxysilicate.Among the additives that can be used according to the invention, mention may also be made of surface modifiers such as cyclomethicones or cyclopentasiloxane, dimethicones and trimethylsiloxysilicate.
[0042] Ces additifs de surface sont généralement utilisés dans des faibles quantités dans la formulation allant de 0,1 à 5 % en poids sec par rapport au poids total de la composition.These surface additives are generally used in small amounts in the formulation ranging from 0.1 to 5% by dry weight relative to the total weight of the composition.
[0043] On citera également les additifs dits « traitants » de l'ongle utilisables dans la composition selon l'invention. Les additifs traitants peuvent représenter de 0,01 % à 5 % en poids sec, de préférence de 0,05 % à 2 % en poids sec par rapport au poids total de la composition. Parmi ces additifs « traitants », on citera: • le formaldéhyde utilisé comme durcisseur de l'ongle, • la vitamine E acétate (tocophéryl acétate), • la vitamine A palmitate (rétinyl palmitate), • les dérivés organiques ou inorganiques de calcium tels que le chlorure de calcium, le pantothénate de calcium, • le diméthyloxobenzodioxasilane, • la myrrhe, • les acides aminés soufrés comme la cystéine, ses sels et leurs dérivés, la cystine, le glutathion. Les acides aminés soufrés sont en effet capables de créer des ponts de réticulation entre la kératine et les groupes SH libres de ces dérivés soufrés, • la kératine hydrolysée d'origine végétale, • les alpha-hydroxyacides comme l'acide citrique, l'acide ascorbique, • la biotine, • l'urée et la diméthylurée.Also include the so-called "treating" additives of the nail used in the composition according to the invention. The treating additives may represent from 0.01% to 5% by dry weight, preferably from 0.05% to 2% by dry weight relative to the total weight of the composition. These "treating" additives include: • formaldehyde used as a hardener for the nail, • vitamin E acetate (tocopheryl acetate), • vitamin A palmitate (retinyl palmitate), • organic or inorganic calcium derivatives such as calcium chloride, calcium pantothenate, • dimethyloxobenzodioxasilane, • myrrh, • sulfur-containing amino acids such as cysteine, its salts and derivatives, cystine, glutathione. The sulfur-containing amino acids are indeed capable of creating crosslinking bridges between keratin and the free SH groups of these sulfur-containing derivatives, • hydrolysed keratin of plant origin, • alpha-hydroxy acids such as citric acid, and acid. ascorbic acid, • biotin, • urea and dimethylurea.
[0044] Un autre objet de l’invention concerne un vernis à ongles comprenant une composition cosmétique telle que décrite précédemment.Another object of the invention relates to a nail polish comprising a cosmetic composition as described above.
[0045] Un aspect supplémentaire de l’invention concerne, l’utilisation d'un agent intercalant choisi parmi les acides carboxyliques ou dicarboxyliques en C3-C10, de préférence sélectionnés parmi les acides dicarboxyliques, par exemple l'acide succinique ou l'acide diméthylglutarique, ou parmi les acides carboxyliques hydroxylés, par exemple l'acide lactique ou l'acide gallique dans une composition cosmétique pour vernis à ongles pour exfolier les feuillets de phyllosilicates intercalés.A further aspect of the invention relates to the use of an intercalating agent selected from C3-C10 carboxylic or dicarboxylic acids, preferably selected from dicarboxylic acids, for example succinic acid or acid. dimethylglutaric acid, or from hydroxylated carboxylic acids, for example lactic acid or gallic acid in a cosmetic nail polish composition for exfoliating interposed phyllosilicate sheets.
Exemple L'exemple, ci-dessous, concerne une formulation de composition cosmétique pour vernis à ongles selon l’invention.EXAMPLE The example below relates to a cosmetic composition formulation for nail polishes according to the invention.
[0046] En conclusion, les Inventeurs ont démontré que la composition comprenant un agent intercalant choisi parmi les acides carboxyliques ou dicarboxyliques en C3-C10, de préférence sélectionnés parmi les acides dicarboxyliques, en particulier l'acide succinique ou l'acide diméthylglutarique ou parmi les acides carboxyliques hydroxylés, en particulier l'acide lactique ou l'acide gallique, reste stable dans le temps, i.e., après 3 mois que ce soit à 50°C ou à température ambiante et ne montre pas de synérèse ni de sédimentation.In conclusion, the inventors have demonstrated that the composition comprising an intercalating agent chosen from C3-C10 carboxylic or dicarboxylic acids, preferably selected from dicarboxylic acids, in particular succinic acid or dimethylglutaric acid or from the hydroxylated carboxylic acids, in particular lactic acid or gallic acid, remains stable over time, ie after 3 months, whether at 50 ° C. or at room temperature, and does not show syneresis or sedimentation.
Claims (16)
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| LU100762A LU100762B1 (en) | 2018-04-05 | 2018-04-05 | Clay activator |
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| LU100762A LU100762B1 (en) | 2018-04-05 | 2018-04-05 | Clay activator |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2427819A1 (en) * | 1978-06-08 | 1980-01-04 | Shiseido Co Ltd | COMPOSITION OF GEL AND NAIL VARNISH |
| EP0780340A1 (en) * | 1995-12-22 | 1997-06-25 | Amcol International Corporation | Intercalates and exfoliates formed with functional monomeric organic compounds; composite materials containing same and methods of modifying rheology therewith |
| JPH09175817A (en) * | 1995-12-27 | 1997-07-08 | Co-Op Chem Co Ltd | Sol-gel composition |
| EP1475082A1 (en) * | 2003-05-05 | 2004-11-10 | L'oreal | Cosmetic composition based on exfoliated phyllosilicates |
| US20080260665A1 (en) * | 2007-01-08 | 2008-10-23 | Laurence Guerchet | Nail varnish comprising at least one polycondensate and at least one polyoxyalkylene copolymer |
| FR2918268A1 (en) * | 2007-07-05 | 2009-01-09 | Oreal | COSMETIC OR PHARMACEUTICAL COMPOSITION COMPRISING A POLYCONDENSATE, COSMETIC PROCESSING METHOD EMPLOYING SAID COMPOSITION, POLYCONDENSATE AND PREPARATION METHOD |
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2018
- 2018-04-05 LU LU100762A patent/LU100762B1/en active IP Right Grant
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2427819A1 (en) * | 1978-06-08 | 1980-01-04 | Shiseido Co Ltd | COMPOSITION OF GEL AND NAIL VARNISH |
| EP0780340A1 (en) * | 1995-12-22 | 1997-06-25 | Amcol International Corporation | Intercalates and exfoliates formed with functional monomeric organic compounds; composite materials containing same and methods of modifying rheology therewith |
| JPH09175817A (en) * | 1995-12-27 | 1997-07-08 | Co-Op Chem Co Ltd | Sol-gel composition |
| EP1475082A1 (en) * | 2003-05-05 | 2004-11-10 | L'oreal | Cosmetic composition based on exfoliated phyllosilicates |
| US20080260665A1 (en) * | 2007-01-08 | 2008-10-23 | Laurence Guerchet | Nail varnish comprising at least one polycondensate and at least one polyoxyalkylene copolymer |
| FR2918268A1 (en) * | 2007-07-05 | 2009-01-09 | Oreal | COSMETIC OR PHARMACEUTICAL COMPOSITION COMPRISING A POLYCONDENSATE, COSMETIC PROCESSING METHOD EMPLOYING SAID COMPOSITION, POLYCONDENSATE AND PREPARATION METHOD |
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| Title |
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| DATABASE GNPD [online] MINTEL; January 2016 (2016-01-01), ANONYMOUS: "Nail Polish Base", XP002782016, Database accession no. 3740669 * |
| DATABASE GNPD [online] MINTEL; June 2011 (2011-06-01), ANONYMOUS: "Nail Polish", XP002782014, Database accession no. 1559880 * |
| DATABASE GNPD [online] MINTEL; May 2015 (2015-05-01), ANONYMOUS: "Lacque Brilliance Nail Polish", XP002782017, Database accession no. 3118823 * |
| DATABASE GNPD MINTEL; December 2012 (2012-12-01), PANVEL FARMACIAS: "Creamy Nail Polish", XP002782015, Database accession no. 1937741 * |
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| Date | Code | Title | Description |
|---|---|---|---|
| FG | Patent granted |
Effective date: 20191007 |