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KR930703397A - 고내후성 1액가교형 에멀션 - Google Patents

고내후성 1액가교형 에멀션

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Publication number
KR930703397A
KR930703397A KR1019930702068A KR930702068A KR930703397A KR 930703397 A KR930703397 A KR 930703397A KR 1019930702068 A KR1019930702068 A KR 1019930702068A KR 930702068 A KR930702068 A KR 930702068A KR 930703397 A KR930703397 A KR 930703397A
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South Korea
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polymerizable
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polymerizable monomer
monomer
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KR960014561B1 (ko
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도시키 니카야
요시후미 후쿠시마
데르오 기쿠다
Original Assignee
다나카 쇼오소오
가부시키가이샤 닛폰 쇼쿠바이
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Publication of KR930703397A publication Critical patent/KR930703397A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

불포화카르복시산을 필수성분으로 함유하는 중합성 단량체 성분(A)을 탄소수가 6내지 18 알킬메르캅탄의 존재하에서 중합하여 얻은 산가가 200이상의 수용성 또는 수분산성의 말단알킬기를 가지는 중합성〔I〕및/ 또는 그 염을 유화제로서 사용하여, 중합성 자외선 안정성 단량체(a) 0.1 내지 10 중량%, 시클로알칼기함유 중합성 단량체(b) 5 내지 99.4 중량%, 카르복실기와의 반응성을 가지는 기를 함유하는 중합체 단량체(c) 0.5 내지 40중량%, 그밖이 중합성 단량체(d) 0내지 94.4중량%〔단 중합성 단량체 (a),(b),(c),(d)이 합계는 100중량%이다.〕로 이루어진 중합성 단량체 성분(Ⅱ)을, 수성매체 중에서 유화중합하여 얻은 유화중합체〔X〕를 사용한 고 내후성 1액가교형 에멀션이다.

Description

고내후성 1애가교형 에멀션
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 불포화카르복시산을 필수성분으로서 함유하는 중합성 다량체 성분(A)을 탄소수가 6내지 18의 알칼메르탄의 존재하에서 중합하여 얻은 산가가 200이상의 수용성 또는 수분산성의 말단알킬기를 가지는 중합성〔Ⅰ〕및/또는 그 염을 유화제로서 사용하여, 중합성 자외선 안전성 단량체(a) 0.1내지 10중량%, 시클로알킬기 함유 중합성 단량체(b), 5 내지 99.4중량%, 카르복실기와의 반응성을 가지는 기를 함유하는 중합성 단량체(c) 0.5 내지 40중량%, 그밖의 중합성 단량체(d) 0 내지 94.4중량% 〔단 중합성 단량체 (a),(b),(c),(d)이 합계는 100중량%이다.〕로 이루어진 중합성 단량체 성분(Ⅱ)을, 수성매체 중에서 유화중합하여 얻는 유화중합체[X〕를 사용하는 것을 특징으로 하는 고내후성 1액가교형 에멀션.
  2. 불포화카르복시산을 필수성분으로서 함유하는 중합성 단량체 성분(A)을 탄소수가 6내지 18의 알칼메르캅탄의 존재하에서 중합하여 얻은 산가가 200이상의 수용성 또는 수분산성의 말단알킬기를 가지는 중합성〔Ⅰ〕및/또는 그 염을 유화제로서 사용하여, 중합성 자외선 안전성 단량체(a) 0.1내지 10중량%, 시클로알킬기 함유 단량체(b), 5 내지 94.4중량%, 카르복실기와의 반응성을 가지는 기를 함유하는 중합성 단량체(c) 0.5 내지 40중량%, 탄소수 12내지 18의 포화알칼기를 가지는 중합성 단량체(e) 5내지 50중량%, 그밖의 중합성 단량체(d) 0 내지 89.4중량% 〔단 중합성 단량체 (a),(b),(c),(d),(e)의 합계는 100중량%이다.〕된 중합성 단량체 성분(Ⅲ)를, 수성매체 중에서 유화중합하여 얻어지는 유화중합체〔XX〕를 사용하는 것을 특징으로 하는 고내후성 1액가교형 에멀션.
  3. 불포화카르복시산 및 탄산수 12내지 18의 장쇄알킬(메타)아트릴레이트를 필수성분으로서 함유하는 중합성 다량체 성분(A′)을 탄소수가 6내지 18의 알칼메르캅탄의 존재하에서 중합하여 얻은 산가가 200이상의 수용성 또는 수분산성의 말단알킬기를 가지는 중합체〔Ⅰ′〕및/또는 그 염을 유화제로서 사용하여, 중합성 자외선 안전성 단량체(a) 0.1내지 10중량%, 시클로알킬기함유 중합성 단량체(b), 5 내지 94.4중량%, 카르복실기와의 반응성을 가지는 기를 함유하는 중합성 단량체(c) 0.5 내지 40중량%, 탄소수 12내지 18의 포화알칼기를 가지는 중합성 단량체(e) 5내지 50중량%, 그밖의 중합성 단량체(d) 0 내지 89.4중량%〔단 중합성 단량체 (a),(b),(c),(d),(e)의 합계는 100중량%이다.〕로 이루어진 중합성 단량체 성분(Ⅲ)을, 수성매체 중에서 유화중합하여 얻어지는 유화중합체〔XXX〕를 사용하는 것을 특징으로 하는 고내후성 1액가교형 에멀션.
  4. 제2항 또는 제3항 기제의 탄산수 2내지 18의 포화알칼기를 가지는 중합성 단량체(e)가 탄소수 12내지 18의 장쇄알킬(메타)아크릴레이트인 것을 특징으로 하는 고내후가형 에멀션.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930702068A 1991-11-18 1992-11-17 고내후성 l 액가교형 에멀션 Expired - Fee Related KR960014561B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP3329929A JP2546216B2 (ja) 1991-11-18 1991-11-18 高耐候性一液架橋型エマルション
JP91-329929 1991-11-18
PCT/JP1992/001499 WO1993010184A1 (en) 1991-11-18 1992-11-17 Highly weather-resistant one-pack cross-linking emulsion

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KR930703397A true KR930703397A (ko) 1993-11-30
KR960014561B1 KR960014561B1 (ko) 1996-10-16

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US (1) US5534579A (ko)
EP (1) EP0567654B1 (ko)
JP (1) JP2546216B2 (ko)
KR (1) KR960014561B1 (ko)
AU (1) AU661519B2 (ko)
CA (1) CA2100757A1 (ko)
DE (1) DE69220356T2 (ko)
TW (1) TW210348B (ko)
WO (1) WO1993010184A1 (ko)

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Publication number Publication date
DE69220356T2 (de) 1997-10-23
TW210348B (ko) 1993-08-01
DE69220356D1 (de) 1997-07-17
CA2100757A1 (en) 1993-05-19
EP0567654A1 (en) 1993-11-03
WO1993010184A1 (en) 1993-05-27
US5534579A (en) 1996-07-09
EP0567654B1 (en) 1997-06-11
AU2929392A (en) 1993-06-15
EP0567654A4 (en) 1994-03-16
AU661519B2 (en) 1995-07-27
KR960014561B1 (ko) 1996-10-16
JPH05140240A (ja) 1993-06-08
JP2546216B2 (ja) 1996-10-23

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