KR930703372A - 양호한 접착성을 지닌 이소시아네이트- 말단 폴리우레탄 예비중합체의 혼합물 - Google Patents
양호한 접착성을 지닌 이소시아네이트- 말단 폴리우레탄 예비중합체의 혼합물Info
- Publication number
- KR930703372A KR930703372A KR1019930702172A KR930702172A KR930703372A KR 930703372 A KR930703372 A KR 930703372A KR 1019930702172 A KR1019930702172 A KR 1019930702172A KR 930702172 A KR930702172 A KR 930702172A KR 930703372 A KR930703372 A KR 930703372A
- Authority
- KR
- South Korea
- Prior art keywords
- prepolymer
- mixture
- hydroxy
- reaction product
- isocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract 13
- 229920001730 Moisture cure polyurethane Polymers 0.000 title claims abstract 4
- 239000007795 chemical reaction product Substances 0.000 claims abstract 10
- 239000000463 material Substances 0.000 claims abstract 6
- 239000005056 polyisocyanate Substances 0.000 claims abstract 6
- 229920001228 polyisocyanate Polymers 0.000 claims abstract 6
- 239000000126 substance Substances 0.000 claims abstract 3
- 239000012948 isocyanate Substances 0.000 claims abstract 2
- 150000002513 isocyanates Chemical class 0.000 claims abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- 239000000556 agonist Substances 0.000 claims 3
- 150000002009 diols Chemical group 0.000 claims 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims 1
- 230000009477 glass transition Effects 0.000 claims 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims 1
- -1 polyhexamethylene adipate Polymers 0.000 claims 1
- 229920002959 polymer blend Polymers 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
- C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/20—Compositions for hot melt adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2250/00—Compositions for preparing crystalline polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
Claims (10)
- (a)적어도 거의 반정질의 히드록시-작용 물질과 이소시아네이트의 반응 생성물을 포함하는 제1예비중합체; (b)폴리(테트라메틸렌에테르)글리콜와 폴리이소시아네이트의 반응생성물을 포함하는 제2예비중합체;및 (c)거의 무정형의 히드록시-작용 물질과 폴리이소시아네이트의 반응 생성물을 포함하는 제3예비중합체를 포함하는 이소시아네이트-말단 폴리우레탄 예비중합체의 혼합물.
- 제1항에 있어서, 상기 적어도 거의 반정질의 히드록시-작용물질이 거의 선형의 포화된,지방족 구조를 지니는 예비중합체 혼합물.
- 제2항에 있어서, 상기 적어도 거의 반정질의 히드록시-작용물질의 결정 융점이 약5℃ 내지 120℃이고 유리 전이온도는 약 0℃이하인 예비중합체 혼합물.
- 제1항에 있어서, 상기 적어도 거의 반정질의 히드록시-작용물질이 약2내지 10개의 메틸렌기를 지닌 디올과 약2내지 10개의 메틸렌기를 지닌 디올과 약2내지 10개의 메틸렌기를 지닌 디카르복실산의 반응 생성물을 포함하는 예비중합체 혼합물.
- 제1항에 있어서, 상기 거의 무정형의 히드록시-작용물질이 방향족 관능성을 포함하는 예비중합체 혼합물.
- 제1항에 있어서, 상기 거의 무정형의 히드록시-작용물질이 에틸렌 글리콜, 프로필렌 글리콜, 부탄디올, 헥산디올, 네오펜틸 글리콜, 및 이들의 혼합물중에서 선택된 디올과 디카르복실산의 반응 생성물을 포함하는 예비중합체 혼합물.
- 제1항에 있어서, 야간 분지된 히드록시-작용물질과 폴리이소시아네이트의 반응생성물을 포함하는 제4이소시아네이트-말단 폴리우레탄 예비중합체를 부가로 포함하는 예비중합체 혼합물.
- 제1항에 있어서, 약10내지 약80중량부의 상기 제1예비중합체, 약10내지 약80중량부의 상기 제1예비중합체, 및 약10내지 약80중량부의 상기 제3예비중합체로 구성되는 예비중합체 혼합물.
- 제1항에 있어서, 상기 적어도 거의 반정질의 히드록시-작용물질이 폴리헥사메틸렌아디페이트인 예비중합체 혼합물.
- 기재위에 제1항의 예비중합체 혼합물층을 포함하는 제품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64606791A | 1991-01-25 | 1991-01-25 | |
| US646,067 | 1991-01-25 | ||
| PCT/US1992/000139 WO1992013017A1 (en) | 1991-01-25 | 1992-01-09 | Mixture of isocyanate-terminated polyurethane prepolymers having good adhesion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR930703372A true KR930703372A (ko) | 1993-11-29 |
Family
ID=24591609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930702172A Abandoned KR930703372A (ko) | 1991-01-25 | 1992-01-09 | 양호한 접착성을 지닌 이소시아네이트- 말단 폴리우레탄 예비중합체의 혼합물 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0568607B2 (ko) |
| JP (1) | JP3150970B2 (ko) |
| KR (1) | KR930703372A (ko) |
| CA (1) | CA2097796A1 (ko) |
| DE (1) | DE69221128T3 (ko) |
| WO (1) | WO1992013017A1 (ko) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2282144B (en) * | 1993-08-11 | 1997-10-15 | Minnesota Mining & Mfg | Element comprising abrasive particles embedded in hot-melt adhesive on a substrate |
| AU667448B2 (en) † | 1994-02-22 | 1996-03-21 | National Starch And Chemical Investment Holding Corporation | Catalyst for reactive hot melt adhesives |
| US5525663A (en) * | 1994-08-18 | 1996-06-11 | Minnesota Mining And Manufacturing Company | Reactive hot-melt adhesive and/or sealing composition and method of using same |
| US5595804A (en) * | 1994-08-22 | 1997-01-21 | Minnesota Mining And Manufacturing Company | Splice means, a method of splicing an abrasive article with same and the spliced abrasive article formed thereby |
| US5698656A (en) * | 1994-12-07 | 1997-12-16 | The Yokohama Rubber Co., Ltd. | Moisture-curing urethane adhesive composition |
| EP0764670A1 (en) | 1995-09-25 | 1997-03-26 | Minnesota Mining And Manufacturing Company | Reactive hot-melt adhesive and/or sealing composition |
| DE10028810A1 (de) | 2000-06-10 | 2001-12-20 | Henkel Kgaa | Polyurethan-Zusammensetzungen auf der Basis von Polyester-Block-Copolymeren |
| US6749943B1 (en) * | 2002-07-02 | 2004-06-15 | 3M Innovative Properties Company | Silane based moisture curing hot-melt adhesives |
| EP1801140A1 (en) | 2005-12-22 | 2007-06-27 | Mnemoscience GmbH | Macro-diacrylate |
| DE102007033651A1 (de) | 2007-07-17 | 2009-01-22 | Evonik Degussa Gmbh | Feuchtigkeitshärtender Schmelzklebstoff mit guter Haftung |
| DE102010001470A1 (de) | 2010-02-02 | 2011-08-04 | Henkel AG & Co. KGaA, 40589 | Polyetherblockcopolymere und daraus erhältliche Zusammensetzungen |
| EP2944662B1 (en) * | 2014-05-16 | 2018-07-18 | Henkel AG & Co. KGaA | Thermoplastic polyurethane hot melt adhesive |
| EP2944661B1 (en) * | 2014-05-16 | 2019-09-18 | Henkel AG & Co. KGaA | Thermoplastic polyurethane hot melt adhesive |
| JP7686270B2 (ja) * | 2020-06-30 | 2025-06-02 | 積水フーラー株式会社 | 湿気硬化型ホットメルト接着剤 |
| JP7706148B2 (ja) * | 2021-06-11 | 2025-07-11 | 積水フーラー株式会社 | 湿気硬化型ホットメルト接着剤 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4182898A (en) * | 1978-01-20 | 1980-01-08 | Anderson Development Company | Stable and storable polyester-polyether co-prepolymers |
| GB8810701D0 (en) * | 1988-05-06 | 1988-06-08 | Bostik Ltd | Hot-melt polyurethane adhesive compositions |
| NO891754L (no) * | 1988-06-02 | 1989-12-04 | Minnesota Mining & Mfg | Ikke-traaddannende fuktighets-herdende blandinger. |
| IT1227361B (it) * | 1988-11-18 | 1991-04-08 | Enichem Sintesi | Composizione di hot melt reattivo. |
| EP0392171B1 (en) * | 1989-04-10 | 1995-05-24 | Rheox International, Inc. | Foamable thermosetting polyurethane structural adhesive compositions and processes for producing the same |
| CA2039964A1 (en) * | 1990-04-27 | 1991-10-28 | Charles W. Stobbie, Iv | Mixture of isocyanate-terminated polyurethane prepolymers |
| US5166300A (en) * | 1990-07-20 | 1992-11-24 | Lord Corporation | Non-yellowing polyurethane adhesives |
-
1992
- 1992-01-09 JP JP50447792A patent/JP3150970B2/ja not_active Expired - Lifetime
- 1992-01-09 CA CA002097796A patent/CA2097796A1/en not_active Abandoned
- 1992-01-09 KR KR1019930702172A patent/KR930703372A/ko not_active Abandoned
- 1992-01-09 DE DE69221128T patent/DE69221128T3/de not_active Expired - Lifetime
- 1992-01-09 WO PCT/US1992/000139 patent/WO1992013017A1/en not_active Ceased
- 1992-01-09 EP EP92904419A patent/EP0568607B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69221128D1 (de) | 1997-09-04 |
| JP3150970B2 (ja) | 2001-03-26 |
| EP0568607B2 (en) | 2001-03-14 |
| EP0568607A1 (en) | 1993-11-10 |
| WO1992013017A1 (en) | 1992-08-06 |
| JPH06505279A (ja) | 1994-06-16 |
| DE69221128T3 (de) | 2001-10-25 |
| EP0568607B1 (en) | 1997-07-23 |
| CA2097796A1 (en) | 1992-07-26 |
| DE69221128T2 (de) | 1998-03-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19930722 |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 19970109 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19930722 Comment text: Patent Application |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19981230 |
|
| NORF | Unpaid initial registration fee | ||
| PC1904 | Unpaid initial registration fee |