KR20190070534A - Face Cleansing Composition having Spicule - Google Patents

Abstract

The present invention relates to a face cleansing composition containing spicules, the composition comprising, based on 100 parts by weight of purified water, (A) 1 to 15 parts by weight of surfactant; (B) 0.1 to 20 parts by weight of spicule; (C) 1 to 5 parts by weight of betaine; (D) 3 to 10 Parts by weight of glycerin; and (E) 1 to 5 parts by weight allantoin.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a cleansing composition containing a speckle,

The present invention relates to a cleanser composition. More particularly, the present invention relates to a cleanser composition containing a speckle having a therapeutic effect of acne.

In general, spicule is one of the substances widely used in skin care. It is a fine structure that constitutes the skeleton of Spongilla Lacustris in freshwater. It is a fine structure of calcium and silicate taken from seaweed or coral. (Et al., "Effects of Spicule and Curcumin on Keratosis Pilaris ", Kor J. Aesthet. Cosmetol., Vol. 13 No .6, pp 883-890, December 2015). These spicules improve acne skin, reduce acne scars and shallow scars, and are applied to fine lines, broad pores, surface pigmentation, and dullness and stain.

Korean Patent No. 10-1678621 and No. 10-1728125 disclose a cosmetic composition for skin care comprising speckle. Thus, conventionally, spicule has been used as a cosmetic product such as cream, gel, and lotion. In order to effectively obtain the efficacy of the speckle, the speckle must be applied to the skin layer in a state of being applied to the skin.

Conventional cleansers are generally used to clean skin wastes such as sweat, sebum, and make-up residue. Therefore, cleansers used for acne skin have been developed focusing on the function of removing skin dead skin and waste products. However, although the acne is caused by the overgrowth of the pores and the growth of the anaerobic bacteria, the conventional acne remover mostly uses the principle of using the scrub or dissolving the skin horny with acid.

On the other hand, speckle has been proved to be effective for the improvement and treatment of acne when it infiltrates into the dermal layer with a fine needle-shaped structure and has an appropriate critical point. The specific mechanism is the principle that induces the death of bacteria due to the natural healing power due to the dermal layer stimulation and the oxygen supply in the pores through the porous material. Proper physical stimulation is required for these spicules to penetrate the dermis. Rubbing the surface of the skin with your hand can also be such a physical stimulus. Usually, when you wash your face, you will physically rub your skin to form a bubble. Therefore, it is important that a cleanser containing a speckle at the time of cleansing can remove skin wastes and facilitate speckle penetration, thereby inducing skin changes.

In addition, fine needle-shaped spicule generates minute pain and fever during penetration of the skin, which is the limit of products developed in the form of conventional cream or essence. However, the fine bubbles used at the time of cleansing reduce skin friction, resulting in minimal pain and fever.

Accordingly, the present inventor intends to propose a new cleanser composition that can sufficiently show the healing effect of spicule on acne.

It is an object of the present invention to provide a cleanser composition that is excellent in cleansing power and is useful for treating acne.

The above objects and other intrinsic objects of the present invention can be easily achieved by the present invention described below.

The cleanser composition containing a speckle according to the present invention contains 100 parts by weight of purified water,

(A) 1 to 15 parts by weight of a surfactant;

(B) 0.1 to 20 parts by weight of spicule;

(C) 1 to 5 parts by weight of betaine;

(D) 3 to 10 parts by weight of glycerin; And

(E) 1 to 5 parts by weight of allantoin;

And a control unit.

In the present invention, (F) may further comprise 1 to 3 parts by weight of a single or a mixture of two or more selected from the group consisting of monoolein, tributyrin, tricaproin, triolein and tripropionin.

In the present invention, the (A) surfactant is selected from the group consisting of sodium laureth sulfate, sodium lauroyl glutamate, sodium cocoyl clutamate, sodium cocoyl methyl aminopropionate, sodium lauroyl methyl aminopropionate, But are not limited to, stearyl methyl aminopropionate, potash cocoyl glycinate, potash myristoyl glutamate, potassium lauroyl glutamate, sodium cocoyl glycinate, thieccoyl glycinate, thieccoyl glutamate, Acetate, disodium cocoamphodopropionate or disodium coco-glucoside sulphosuccinate as a component.

In the present invention, the average particle size of the speckle is preferably 50 to 200 micrometers.

In the present invention, the glycerin may be at least one selected from the group consisting of ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, 1,3-butanediol, triethylene glycol, dipropylene glycol, Butanediol, 1,2-pentanediol, 1,4-pentanediol, 1,5-pentanediol, 2,4-pentanediol, 2-methyl- , 5-pentanediol, 1,2-hexanediol or 1,6-hexanediol.

INDUSTRIAL APPLICABILITY The present invention has the effect of providing a cleanser composition that is excellent in cleansing power but has no objection to use and which is useful in the treatment of acne.

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a pre-clinical photograph of a 17 year old male using the cleanser composition according to the present invention.
Fig. 2 is a photograph of a male clinic 1 week in Fig. 1;
FIG. 3 is a photograph of two weeks of the male of FIG. 1; FIG.
FIG. 4 is a photograph of a clinical three weeks of the male of FIG. 1;
Figure 5 is a pre-clinical picture of a 16 year old female using the cleanser composition according to the present invention.
FIG. 6 is a photograph of the female 2-week clinical chart of FIG.
Figure 7 is a pre-clinical photograph of a 24-year-old male.
FIG. 8 is a photograph of the male's clinical six weeks in FIG. 7; FIG.
Figure 9 is a pre-clinical picture of a 24 year old female.
FIG. 10 is a photograph of a female clinical examination of FIG. 9; FIG.
FIG. 11 is a photograph of the female 2 clinical weeks of FIG. 9; FIG.
FIG. 12 is a photograph of four weeks of the female of FIG. 9; FIG.

The cleanser composition containing a speckle according to the present invention comprises (A) 1 to 15 parts by weight of a surfactant, (B) 0.1 to 20 parts by weight of spicule; (C) 1 to 5 parts by weight of betaine; (D) 3 to 10 parts by weight of glycerin; (E) 1 to 5 parts by weight of allantoin; And optionally (F) 1 to 3 parts by weight of a mixture of one or more selected from the group consisting of monoolein, tributyrin, tricaproin, triolein and tripropionin.

The detergent composition according to the present invention determines the content of other ingredients based on 100 parts by weight of purified water.

(A) Surfactant

(A) a surfactant is used in the cleaning composition according to the present invention. The surfactant used in the present invention is preferably an amino acid surfactant that exhibits a strong detergency against the skin while exhibiting a strong protective action against the skin and maintains the skin condition moisturized even after cleaning. However, the surfactant is not always limited thereto, and cationic surfactants , An anionic surfactant, or a nonionic surfactant may be used.

Examples of the surfactant used in the present invention include sodium laureth sulfate, sodium lauroyl glutamate, sodium cocoyl clutamate, sodium cocoyl methyl aminopropionate, sodium lauroyl methyl aminopropionate, sodium myristyl Methyl aminopropionate, potash cocoyl glycinate, potash myristoyl glutamate, potassium lauroyl glutamate, sodium cocoyl glycinate, thieccoyl glycinate, thieccoyl glutamate, disodium cocoamphodiacetate , Disodium cocoamphodipropionate, disodium coco-glucoside sulfosuccinate, and the like may be used alone or in combination.

In the present invention, the content of (A) the surfactant is 1 to 15 parts by weight, more preferably 1 to 10 parts by weight, based on 100 parts by weight of purified water. If the content is less than 1 part by weight, the cleaning ability against fine pores is deteriorated. If the content is more than 15 parts by weight, the surfactant component may remain on the skin even after cleansing.

(B) Spicular

The main component of the composition according to the present invention, spicule, is a fragment of a sponge animal, which can be used by drying the sponge animal and then pulverizing it into a powder form. Preferably, the speckle used in the present invention is not limited to sponges collected from freshwater sponges. It is preferable that the particle size of the speckle prepared in powder form has an average value of 50 to 200 micrometers. When the average particle diameter is less than 50 micrometers, it is difficult to obtain a sufficient speck effect. When the average particle diameter is more than 200 micrometers, a feeling of foreign body may be felt when using the cleanser composition, which may be inconvenient.

The content of (B) spicule used in the present invention is 0.1 to 20 parts by weight based on 100 parts by weight of purified water. When it is used in an amount of less than 0.1 part by weight, sufficient acne treatment effect can not be obtained. When it is used in an amount exceeding 200 parts by weight, the speckle particles may have too much particles in the cleanser,

(C) Betaine

The betaine used in the present invention is a component which softens the skin while imparting detergency with (A) a surfactant.

Examples of the betaine used in the present invention include imidazoline betaine, babassuamidopropyl betaine, alkyldimethylaminoacetic acid betaine, fatty acid amide propylbetaine, sulphobetaine, lauryldimethylamino But are not limited to, betaine acetate, palm oil alkyl betaine, stearyldimethylaminoacetic acid betaine, palm oil fatty acid amide propyl betaine, palm oil fatty acid amide propyl carbobetaine, palm oil fatty acid amide propyl betaine, lauric acid amide propyl acetic acid betaine, Stearyl dihydroxyethyl betaine, etc. These may be used singly or in combination of two or more.

In the present invention, the content of (C) betaine is 1 to 5 parts by weight based on 100 parts by weight of purified water.

(D) glycerin

The glycerin used in the present invention acts as a fat component to prevent moisture from being supplied to the skin and drying of the skin. In the present invention, (D) glycerin may be used alone or in combination with one or more of the following ingredients. Examples of the miscible component include ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, 1,3-butanediol, triethylene glycol, dipropylene glycol, Butanediol, 1,2-pentanediol, 1,4-pentanediol, 1,5-pentanediol, 2,4-pentanediol, 2-methyl- - pentanediol, 1,2-hexanediol, 1,6-hexanediol, and the like. When used as a mixture, glycerin should be used in an amount of at least 50% by weight based on the total mixture weight.

In the present invention, the content of (D) glycerin is 3 to 10 parts by weight based on 100 parts by weight of purified water.

(E) Allantoin

Allantoin is a ureide compound of glyoxylic acid. Allantoin is a water-soluble, natural substance extracted from oats, comfrey root, sugar beet and wheat germs. It is known to help regenerate healthy skin cells, helping to heal small wounds and troubles in the skin.

The content of (E) allantoin used in the present invention is 1 to 5 parts by weight.

(F) a monoolefin, a tricaproin, a triolein and a tripropionin, or a mixture of two or more thereof

The monoolein used in the present invention is represented by the general formula C ₂₁ H ₄₀ O ₄ . Examples of the monoolefins of the present invention include glycerol monooleate; 1-oleoyl-sn-glycerol; 9-octadecenoic acid (Z) -, monoester of 1,2,3-propanetriol (9-Octadecenoic acid (Z) -, monoester with 1,2,3-propanetriol); Glyceryl oleate; Glyceyl oleate may be mentioned.

The tricaproin of the present invention is represented by the general formula C ₂₁ H ₃₈ O ₆ . Examples of the tricaproin of the present invention include tricaprioylglycerol; 1,2,3-Propanetriyl trihexanoate (1,2,3-Propanetriyl trihexanoate); Tricapriin; Tricaprioylglycerol; Tri-n-caproin. ≪ / RTI >

The triolein of the present invention is represented by the general formula C ₅₇ H ₁₀₄ O ₆ . Examples of the triolein used in the present invention include 9-octadecenoic acid (Z) -, 1,2,3-propanetriyl ester (9-Octadecenoic acid (Z) -, 1,2,3-propanetriyl ester ); 1,2,3-Propanetriyl tri- ((E) -9-octadecenoate) (1,2,3-Propanetriyl tri - ((E) -9-octadecenoate)); 9-octadecenoic acid (Z) -, 1,2,3-propanetriyl ester (9-Octadecenoic acid (Z) -, 1,2,3-propanetriyl ester); Glycerol trioleate; Glyceryl tri (oleate-1-13C)); Olein; Trioleoylglycerol can be mentioned.

The tripropionin of the present invention is represented by the general formula C ₁₂ H ₂₀ O ₆ . Examples of the tripropionine used in the present invention include 1,2,3-propanetriol, tripropanoate (1,2,3-Propanetriol, tripropanoate); 1,2,3-Propanetriyl tripropionate; Glyceryl tripropanoate; Tripropanoin; Tripropanoylglycerol; Tripropionylglycerol may be mentioned.

In the present invention, monoolein, tricaproin, triolein and tripropionine as described above are used singly or as a mixture of two or more thereof. The amount used is 1 to 3 parts by weight based on 100 parts by weight of purified water.

(C) beta-D, (D) glycerin, (E) allantoin, and (D) anionic surfactant. The aqueous solution is prepared by mixing the cleansing water with the surfactant (A) And / or (F) a single or a mixture of two or more selected from the group consisting of monoolein, tricaproin, triolein and tripropionin can be mixed in the reactor to obtain a cleanser composition. Specific examples of the preparation will be illustrated by the following examples.

Example

(A) TEA-Cocoyl Glutamate (trade name: MIAMI CT130 (S)) was used as a surfactant with respect to 100 parts by weight of purified water. (B) Spicule was prepared by washing the surface of fresh seawater with fresh purified water, placing it in a drier, hot-air drying at 150 ° C for 30 minutes, and then putting it into a pulverizer. The average particle size of the prepared spu- ces was 160 micrometers. (C) Palm oil fatty amide propyl carbobetaine (Nippon Kao Corporation, trade name: Ampitol 55AB) was used as betaine. (D) Glycerin used was MUSIM, a product of Dae Young Chemical Co. having a purity of 99.7% or more. (E) Allantoin was purchased from AKEMA, Italy, allantoin powder. As the component (F), monoolein and triolein were purchased from TCI (glycerol monooleate, glycerol tri-n-butyrate, and glycerol trioleate, respectively). Tricaproine and tripropionine were purchased from Aldrich (Product names: Glycerol tripropionate, Glycerol tri-n-hexanoate) were purchased and mixed with the four components.

The prepared components were prepared in the following order according to the ingredient contents shown in Table 1 below. First, purified water and thiearyl-cocoyl glutamate were placed in a stirrer and mixed at 25 캜 for 30 minutes while slowly injecting powdery spicule. To the mixed solution was added a mixture of palm oil fatty amide propyl carbobetaine, glycerin, allantoin, monoolein, triolein, tricaproin and tripropionin, stirred for 30 minutes or more, To prepare samples according to Examples 1 to 5. The samples according to Comparative Examples 1 to 3 were prepared by the same procedure except that some components were omitted as shown in Table 1. The efficacy and safety of the manufactured samples were evaluated by cleansing efficacy tests, and clinical trials were conducted to examine the effectiveness of acne treatment by selecting volunteers.

Cleaning efficacy test

To evaluate the detergency of the cleanser compositions prepared in the above Examples and Comparative Examples, a detergency test for a virtual contaminant was conducted. As a virtual contaminant, titanium dioxide and iron oxide were mixed in a ratio of 1: 1, dissolved in isopropyl alcohol solvent, and reacted at 40 ° C for 1 hour to obtain a viscous liquid type compound. This virtual contaminant was applied to the skin to make the residue visible on the skin.

The virtual contaminants were applied to the forearms of volunteers and dried at room temperature for 30 minutes. The standard color measured with a colormeter in the state where the virtual contaminants were completely dried and each of the cleaner samples prepared in the examples and the comparative examples were cleaned while applying a circle for 30 seconds on the area where the virtual contaminants were applied Then, it was washed with tap water and dried. After drying, the portion with the remaining contaminants was measured with a colorimeter to evaluate the detergency against the standard color. The washing power was obtained by dividing the measured value after cleaning by the standard color value, and then multiplying by 100 and expressed in%. Values below the decimal point are omitted.

Sensory test

Twenty volunteers were selected from the cleanser samples according to Examples 1 and 5 and Comparative Example 1, and sensory tests were conducted by using each of the three types of cleanser samples for 10 days each for 30 days. (5 points), good (4 points), normal (3 points), poor (2 points), and very poor (1 point) to the score table The grade of the step was checked, and the average score was calculated for each sample. The scores of all 20 persons were averaged, and are summarized in the following Table 3.

Clinical trial

Three voluntary participants with a lot of acne on their faces were selected and washed with morning and evening with the cleanser samples according to Example 1. The first participant was a 17-year-old male with a pre-clinical photograph, and FIG. 2 shows a photograph of a 1-week clinical photograph using the inventive cleaner sample for one week. Fig. 3 shows photographs of Clinical 2 weeks, and Fig. 4 shows photographs of Clinical 3 weeks. FIG. 5 is a pre-clinical photograph of a 16-year-old woman, and FIG. FIG. 7 is a pre-clinical image of a 24-year-old male, and FIG. FIG. 9 is a photograph of a 24-year-old female before the clinical examination, FIG. 10 is a photograph of a clinical sample, FIG. 11 is a photograph of two weeks, and FIG.

It should be noted that the description of the invention described above is for the understanding of the present invention and is not intended to define the scope of the present invention. It is intended that the scope of the invention be defined by the claims appended hereto, and that all such modifications and variations are intended to be included within the scope of the present invention.

Claims (5)

With respect to 100 parts by weight of purified water,
(A) 1 to 15 parts by weight of a surfactant;
(B) 0.1 to 20 parts by weight of spicule;
(C) 1 to 5 parts by weight of betaine;
(D) 3 to 10 parts by weight of glycerin; And
(E) 1 to 5 parts by weight of allantoin;
≪ / RTI > wherein the cleansing composition comprises a speckle. [3] The composition according to claim 1, further comprising 1 to 3 parts by weight of (F) a monoolein, tributyrin, tricaproin, triolein and tripropionin, Wherein the cleansing composition comprises a spicule. 3. The composition of claim 2, wherein the surfactant (A) is selected from the group consisting of sodium laureth sulfate, sodium lauroyl glutamate, sodium cocoyl clutamate, sodium cocoyl methyl aminopropionate, sodium lauroyl methylaminopropionate, But are not limited to, sodium myristyl methyl aminopropionate, potassium cocoyl glycinate, potash myristoyl glutamate, potassium lauroyl glutamate, sodium cocoyl glycinate, thieccoyl glycinate, thieccoyl glutamate, disodium coco Characterized in that it is used as at least one component of amphoteric acetic acid, disodium cocoamphodipropionate or disodium coco-glucoside sulfosuccinate. 3. The cleanser composition according to claim 1 or 2, wherein the average particle size of the speckle is 50 to 200 micrometers. [Claim 3] The method according to claim 2, wherein the glycerin is at least one selected from the group consisting of ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, 1,3-butanediol, triethylene glycol, Methyl-1,3-butanediol, 1,2-pentanediol, 1,4-pentanediol, 1,5-pentanediol, 2,4-pentanediol, -1,5-pentanediol, 1,2-hexanediol or 1,6-hexanediol, which is used in combination with at least one component.

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