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KR20180084678A - 3d printing material based on graphene-furan resin, preparation method and use thereof - Google Patents

3d printing material based on graphene-furan resin, preparation method and use thereof Download PDF

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Publication number
KR20180084678A
KR20180084678A KR1020180005948A KR20180005948A KR20180084678A KR 20180084678 A KR20180084678 A KR 20180084678A KR 1020180005948 A KR1020180005948 A KR 1020180005948A KR 20180005948 A KR20180005948 A KR 20180005948A KR 20180084678 A KR20180084678 A KR 20180084678A
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KR
South Korea
Prior art keywords
parts
printing material
graphene
furan resin
furan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR1020180005948A
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Korean (ko)
Inventor
왕 지준
신 리민
리앙 준리앙
왕 지아동
선 징리
왕 리후이
리우 샤
Original Assignee
스자좡 월드와이드 푸르푸랄 앤 푸르푸릴 알콜 컴퍼니 리미티드
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Publication of KR20180084678A publication Critical patent/KR20180084678A/en
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/34—Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C08L61/04, C08L61/18 and C08L61/20
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
    • C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
    • C08G16/04—Chemically modified polycondensates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
    • C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
    • C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
    • C08G16/025—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds
    • C08G16/0256—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds containing oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34922—Melamine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 그래핀-퓨란 수지에 기초한 3D(3차원) 프린팅 재료를 개시한다. 3D 프린팅 재료는 다음의 원료 성분의 중량부(Parts by weight)를 포함한다 : 퓨란메탄올 80 부분들, 퓨란 포름알데히드 20 부분들, 20mg/ml 내지 25mg/ml 농도의 그래핀 용액 30 내지 40 부분들, 멜라민 0.5 내지 1.0 부분들, 글리세롤 5 내지 7 부분들, 탄산나트륨 2 내지 4 부분들, 다가산(Polybasic acid) 4 내지 6 부분들 및 실란 커플링제(Silane coupling agent) 2 내지 3 부분들. 본 발명으로 제공된 3D 프린팅 재료를 채택하면, 얻어진 그래핀-퓨란 수지에 기초한 프린팅 재료는 그래핀과 퓨란 수지의 장점을 통합하여, 신규하고 환경 친화적이고 생분해 가능한 고분자량 재료이고, 매우 우수한 성능을 가진다. 더욱이, 본 발명으로 제공된 3D 프린팅 재료는 단순한 준비 공정, 낮은 단가 그리고 광범위한 적용의 장점을 가지고 있고, 다양한 배터리 전극 플레이트들의 제조에 사용되고, 광범위한 적용 가능성을 가지고 있으며, 3D 프린팅 기술의 발전에 긍정적인 효과를 가지고 있다.The present invention discloses a 3D (three-dimensional) printing material based on graphene-furan resin. The 3D printing material includes parts by weight of the following ingredients: furan methanol 80 parts, furan formaldehyde 20 parts, graphene solution 30 to 40 parts at a concentration of 20 mg / ml to 25 mg / ml 0.5 to 1.0 parts of melamine, 5 to 7 parts of glycerol, 2 to 4 parts of sodium carbonate, 4 to 6 parts of polybasic acid and 2 to 3 parts of silane coupling agent. Adopting the 3D printing material provided by the present invention, the resulting printing material based on graphene-furan resin incorporates the advantages of graphene and furan resin, and is a novel, environmentally friendly, biodegradable high molecular weight material and has very good performance . Furthermore, the 3D printing material provided by the present invention has advantages of simple preparation process, low unit price and wide application, is used for manufacturing various battery electrode plates, has wide applicability, has a positive effect on development of 3D printing technology Lt; / RTI >

KR1020180005948A 2017-01-17 2018-01-17 3d printing material based on graphene-furan resin, preparation method and use thereof Ceased KR20180084678A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710035089.9 2017-01-17
CN201710035089.9A CN106832168B (en) 2017-01-17 2017-01-17 3D printing material based on graphene furane resins and preparation method thereof, purposes

Publications (1)

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KR20180084678A true KR20180084678A (en) 2018-07-25

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ID=59124377

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CN (1) CN106832168B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110628169A (en) * 2019-07-04 2019-12-31 南通星球石墨设备有限公司 Furan resin graphite tube and preparation method thereof
FR3106523A1 (en) * 2020-01-28 2021-07-30 Institut Polytechnique De Grenoble Thermosetting composite material and associated printing process

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12337531B2 (en) 2018-08-22 2025-06-24 Peridot Print, LLC Three-dimensional printing
CN111081909B (en) * 2019-12-26 2022-04-08 郑州大学 3D printing compressible quasi-solid nickel-iron battery and preparation method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735550B (en) * 2009-12-23 2011-12-14 黄石市汇波防腐技术有限公司 Low-smell furan resin
CN104151515B (en) * 2014-08-13 2017-01-11 济南圣泉集团股份有限公司 Graphene modified furan resin and preparation method thereof
CN104448179B (en) * 2014-12-09 2016-08-17 济南圣泉集团股份有限公司 A kind of Graphene modified furan resin and preparation method thereof and furane resins fiberglass

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110628169A (en) * 2019-07-04 2019-12-31 南通星球石墨设备有限公司 Furan resin graphite tube and preparation method thereof
FR3106523A1 (en) * 2020-01-28 2021-07-30 Institut Polytechnique De Grenoble Thermosetting composite material and associated printing process
WO2021151893A1 (en) * 2020-01-28 2021-08-05 Institut Polytechnique De Grenoble Thermosetting composite material and associated printing process
US20230347584A1 (en) * 2020-01-28 2023-11-02 Institut Polytechnique De Grenoble Thermosetting composite material and associated printing method

Also Published As

Publication number Publication date
CN106832168A (en) 2017-06-13
CN106832168B (en) 2019-03-08

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