KR20180000906A - Hair dye composition - Google Patents
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9706—Algae
- A61K8/9711—Phaeophycota or Phaeophyta [brown algae], e.g. Fucus
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4322—Direct dyes in preparations for temporarily coloring the hair further containing an oxidizing agent
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- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/522—Antioxidants; Radical scavengers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/524—Preservatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
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Abstract
본 발명은 모발에 색을 더하는 염모제에 관한 것으로서, 상세하게는 천연 식물의 추출물을 이용한 염모제 조성물에 관한 것이다.
본 발명은 다시마류의 줄기, 잎, 뿌리 중 1종 이상으로부터 얻어진 추출물 85 내지 93 중량%, 0.5 내지 3중량%의 염료제 및 잔존량의 향료, 살균제, 소염제, 방부제, 산화방지제, 자외선 흡수제, 암모니아수, 글리콜산암모늄, 지방산알콜, 물 및 칼륨백반으로 이루어진 그룹에서 선택된 1종 이상을 포함하는 제1제; 및
상기 추출물 85 내지 90 중량% 및 잔존량의 상기 제1제를 산화하는 산화제 및 pH 조정제를 포함하는 제2제를 포함하여 구성되는 것으로, 모발에의 염착성을 향상시켜 염색성과 색상지속성을 향상시키고, 염색 후 염색시 발생하는 모발손상을 줄여주어 자연스러운 염색이 가능하게 하며, 천연성분을 함유하고 있어 기존의 염모제로 인한 피부 알레르기나 자극으로부터 두피를 보호해주고 피부 자극 완화로 두피 안정에도 상당한 효과가 있다. The present invention relates to a hair dye for adding color to hair, and more particularly, to a hair dye composition using an extract of a natural plant.
The present invention relates to a cosmetic composition comprising 85 to 93% by weight of an extract obtained from at least one of stems, leaves and roots of sea tangle, 0.5 to 3% by weight of a dye preparation and a perfume of a residual amount, a bactericide, an anti- inflammatory agent, an antiseptic, A first agent comprising at least one member selected from the group consisting of ammonia water, ammonium glycolate, fatty acid alcohol, water and potassium alum; And
And a second agent comprising 85 to 90% by weight of the extract and an oxidizing agent for oxidizing the first agent and a pH adjuster in the remaining amount, thereby improving dyeability and color sustainability by improving dyeability to hair, It reduces the hair damage caused by dyeing and allows natural dyeing. It contains natural ingredients, which protects the scalp from skin allergies and irritation caused by the existing hair dye, and has a considerable effect on scalp stability by alleviating skin irritation.
Description
본 발명은 모발에 색을 더하는 염모제에 관한 것으로서, 상세하게는 천연 식물의 추출물을 이용한 염모제 조성물에 관한 것이다. The present invention relates to a hair dye for adding color to hair, and more particularly, to a hair dye composition using an extract of a natural plant.
일반적으로 염모제는 모발을 다양하게 염색하는 조성물로 화학약품이 주종을 이루고 있으며, 최근에는 헤나 등을 이용한 천연물 염색제도 출시가 되어 이용되고 있다. 그런데 화학약품의 경우 피부에 대한 자극 등으로 유해성이 나타나고 있으며, 헤나의 경우 그 재료를 수입에 의존하고 있는 실정이다. In general, a hair dye is a composition for dyeing hair variously, and a chemical is a main species. Recently, a natural dye using a henna or the like has been introduced and used. However, in the case of chemicals, harmfulness is shown due to stimulation of the skin, and in the case of henna, the material is dependent on imports.
염모제는 염색 효과의 차이에 따라 영구 염모제, 반영구 염모제, 일시 염모제로 구분할 수 있다.The hair dye can be divided into permanent hair dye, permanent hair dye, and temporary hair dye depending on the difference of dyeing effect.
영구 염모제는 색소 형성 물질이 모발 내부에 모피질 또는 무수질 층까지 침투하여 화학변화를 일으켜 불용성 색소를 형성시킬 수 있는 것이다. 반영구 염모제는 색소 자체가 모피질이나 모발 표면의 큐티클 층에 침투하여 물리적으로 흡착되는 것이다. 또한, 일시 염모제는 색소를 모발의 표면인 큐티클 층에만 물리적으로 흡착시키는 것이다.Permanent hair dye can penetrate into the hair follicle or the water-free layer and cause chemical change to form insoluble pigment. The permanent dyeing agent is that the pigment itself is physically adsorbed on the follicle or the cuticle layer on the hair surface. In addition, the temporary hair dyeing agent physically adsorbs the pigment only to the cuticle layer which is the surface of the hair.
상기 영구 염모제는 다시 세 가지 즉, 식물성 염모제, 금속성 염모제 및 산화형 염모제로 나눌 수 있다. 식물성 염모제는 헤나 또는 카모마일을 포함하는 것으로 염색 효과가 낮고 밝게 염색하는 것이 어렵다. 금속성 염모제는 납이 산화될 때 검게 변하는 원리를 이용한 것으로 인체에 유해한 독성이 있어 현재는 거의 사용하지 않고 있다. 마지막으로 산화형 염모제는 염색효과가 우수하며, 밝은 색으로 염색이 가능하여 현재 가장 널리 사용되고 있다. The permanent hair dye can be further classified into three types, i.e., a vegetable hair dye, a metallic hair dye and an oxidative dye. The vegetable hair dye contains henna or chamomile and has low dyeing effect and is difficult to dye brightly. The metallic hair dye uses a principle that turns black when lead is oxidized. It is harmful toxic to the human body and is rarely used at present. Finally, oxidative dyeing agents are excellent in dyeing effect and can be dyed in bright colors, and they are most widely used nowadays.
산화형염모제는 일반적으로 1제와 2제를 혼합함으로써 1제에 들어있는 염료간에 산화중합반응을 일으킴으로써 색을 나타낸다. 또한 2제에 들어있는 과산화수소에 의해 모발에 있는 멜라닌 색소가 분해되어 모발을 탈색시킴으로써 모발의 바탕색을 밝게 하여 보다 선명한 색상이 표현될 수 있다.Oxidation type dyeing agents are generally colored by causing oxidation polymerization reaction between the dyes contained in one agent by mixing one agent and two agents. In addition, the hydrogen peroxide in the 2nd agent breaks down the melanin pigment in the hair to discolor the hair, so that the hue of the hair is brightened, and a brighter color can be expressed.
산화형염료는 크기가 작아서 모발의 코텍스층까지 들어갈 수 있으나, 산화반응에 의해 중합체가 형성되면 모발 속으로 들어가기가 어렵게 된다. 이렇게 산화형염료가 모발속으로 침투하기 전에 중합반응을 일으켜 분자의 크기가 커지게 되면 모발에서의 염색성도 저하되고, 염색 후 색상지속성도 떨어지게 된다. Oxidative dyes are small in size and can penetrate into the hair's cortex layer, but when the polymer is formed by the oxidation reaction, it is difficult to enter the hair. If the size of the molecule increases due to the polymerization reaction before the oxidative dye penetrates into the hair, the dyeability in the hair is lowered and the color persistence after dyeing is also lowered.
상기의 문제를 해결하기 위해, 염료의 반응성을 조절하고, 모발로의 침투가 잘 되도록 하는 등의 방법을 통해 염색성과 지속성을 향상시키기 위한 방법들이 제시되어 있다. 이와 관련된 기술로는 대한민국공개특허 제2006-0033932 "몰식자산 또는 그의 에스테르 유도체를 함유하는 케라틴 섬유의 산화염색용 염모제 조성물" 및 대한민국특허출원 제10-2007-0123256호 "오배자 또는 한련초를 함유하는 산화염색용 염모제" 등이 있다. In order to solve the above problems, there have been proposed methods for improving dyeability and durability by controlling the reactivity of the dye and allowing the dye to penetrate well. A related art is disclosed in Korean Patent Publication No. 2006-0033932, "a hair dye composition for dyeing keratin fibers containing gallic acid or an ester derivative thereof" and Korean Patent Application No. 10-2007-0123256 " "≪ / RTI >
이에 본 발명자는 산화형염모제의 염색성과 색상지속성을 향상시킬 수 있는 방법에 대해 연구한 결과 해조류의 일종인 다시마류 천연성분이 염색성 향상과 색상지속성 향상, 그리고 염색으로 인한 모발손상 완화에 효과가 있는 것을 발견하고 본 발명을 완성하게 되었다.Accordingly, the inventors of the present invention have studied about a method of improving the dyeability and color persistence of the oxidative type hair dye, and found that the natural component of seaweed, which is a type of seaweed, is effective in improving dyeability, improving color sustainability, And finally completed the present invention.
본 발명은 염색성과 색상지속성이 향상되고 모발 손상을 완화시킬 수 있는 천연성분을 함유하는 산화염색용 염모제 조성물을 제공함에 그 목적이 있다.It is an object of the present invention to provide a hair dye composition for dyeing with oxidation, which contains a natural component capable of improving dyeability and color sustainability and alleviating hair damage.
상기한 목적을 달성하기 위하여 본 발명에서는 다시마류인 참다시마, 애기다시마의 줄기, 잎, 뿌리 중에서 선택되는 하나 또는 둘 이상의 혼합물을 함유하는 것을 특징으로 하는 케라틴 섬유의 산화염색용 염모제 조성물 및 산화염색용 혼합첨가제를 제공한다.In order to achieve the above object, the present invention provides a hair dye composition for oxidation dyeing keratin fibers, which comprises a mixture of one or more selected from the group consisting of kelp, kelp, kelp, stem, Mixed additives are provided.
본 발명은 산화염료 전구체, 커플러 및 알칼리제, 항산화제, 환원제 등을 함유하는 제 1제 및 과산화수소 등의 산화제를 함유하는 제 2제로 구성되는 케라틴 섬유의 산화염색용 염모제 또는 제 1제만으로 구성되는 1제형 산화형염모제 조성물에 있어서, 상기 제 1제, 제 2제 또는 이들의 혼합물에 다시마류인 참다시마, 애기다시마의 줄기, 잎, 뿌리 중에서 선택되는 하나 또는 둘 이상의 혼합물을 사용하거나 산화형 염모제와 사용직전에 혼합하여 사용하는 혼합첨가제에 모발에의 염착성을 향상시켜 색상 표현력 및 지속성을 향상시키는 산화염색용 염모제 조성물을 제 The present invention relates to a dyeing agent for dyeing keratin fibers consisting of a first agent containing a dye precursor, a coupler and an alkali agent, an antioxidant, a reducing agent and the like and a second agent containing an oxidizing agent such as hydrogen peroxide, In the oxidizing type hair dye composition, one or a mixture of two or more selected from the group consisting of kelp kelp, stem, leaf and root of kelp are added to the first agent, the second agent or a mixture thereof, A dye additive composition for oxidation dyeing which improves colorability and persistence by enhancing dyeability to hair in a mixed additive used immediately before
공한다.I will.
또한 상기 산화형 염모제와 사용직전에 혼합하여 사용하는 혼합첨가제로 다시마류인 참다시마, 애기다시마의 줄기, 잎, 뿌리 중에서 선택되는 하나 또는 둘 이상의 혼합물을 사용함으로써 모발에의 염착성을 향상시켜 색상 표현력 및 지속성을 향상시키는 산화형 염모제 조성물을 제공한다. Also, by using one or two or more mixtures selected from the stem, leaf and root of kelp, kelp, kelp, kelp, kelp and kelp, as the mixed additive to be used immediately before use with the oxidative hair dyeing agent, To provide an oxidation type hair dye composition which improves durability.
본 발명은 산화염료 전구체, 커플러, 알칼리제, 수용성 항산화제 및 환원제를 함유하는 제 1제와 산화제를 함유하는 제 2제로 구성되는 케라틴 섬유의 산화염색용 염모제 조성물에 있어서, 상기 산화형염모제는 다시마류인 참다시마, 애기다시마의 줄기, 잎, 뿌리 중에서 선택되는 하나 또는 둘 이상의 혼합물을 함유하는 것을 특징으로 하는 케라틴 섬유의 산화염색용 염모제 조성물을 특징으로 한다. The present invention relates to a hair dye composition for dyeing keratin fibers comprising a first agent containing an oxidation dye precursor, a coupler, an alkali agent, a water-soluble antioxidant and a reducing agent and a second agent containing an oxidizing agent, Characterized in that the hair dye composition for skin dyeing of keratin fibers contains a mixture of one or more selected from the group consisting of kelp, kelp, stem, leaf and root of Arabidopsis kelp.
또한 본 발명의 케라틴 섬유의 산화염색용 염모제 조성물은 다시마류인 참다시마, 애기다시마의 줄기, 잎, 뿌리 중에서 선택되는 하나 또는 둘 이상의 혼합물을 제 1제, 제 2제 또는 이들의 혼합 조성물의 총 중량에 대하여 0.01 내 Also, the hair dye composition for dyeing keratin fibers of the present invention may be prepared by mixing one or more of a mixture selected from the stem, leaf and root of kelp kelp, kelp, kelp, and kelp, with the total weight of the first, second, 0.0 >
지 30 중량%로 함유되며, 제 3제의 혼합첨가제의 총 중량에 대하여 0.01 내지 100 중량% 함유하는 것을 특징으로 한다.30 wt% of the third additive, and 0.01 to 100 wt% of the total weight of the third additive.
이하, 본 발명을 보다 상세히 설명한다.Hereinafter, the present invention will be described in more detail.
상기 혼합물은 분쇄된 다시마분말을 용매 추출 공정으로 엽록소 및 저분자량 폴리페놀을 제거한 후, 열수 추출로 얻어진 다시마 추출액을 감압 농축하여 한외여과로 저분자량의 유리 단백질을 제거하고, 최종 한외 여과 농축액을 침전반응을 통해 침전된 다시마 농축액을 진공 건조하여 파우더 형태의 다시마 혼합물을 수득한다. The mixture is prepared by removing the chlorophyll and the low molecular weight polyphenol from the pulverized kelp powder by a solvent extraction process, concentrating the kelp extract obtained by hot water extraction under reduced pressure, removing the low molecular weight free protein by ultrafiltration, The kelp concentrate precipitated through the reaction is vacuum dried to obtain a powdery kelp mixture.
본 발명에 따른 산화염색용 염모제는 모발에의 염착성을 향상시켜 염색성과 색상지속성을 향상시키고 염색 후 염색시 발생하는 모발손상을 줄여주어 자연스러운 염색이 가능하게 하며, 천연성분을 함유하고 있어 기존의 염모제로 인한 피부 알레르기나 자극으로부터 두피를 보호해주고 피부 자극 완화로 두피 안정에도 상당한 효과가 있다.The dyeing agent for oxidation dyeing according to the present invention improves dyeability and color sustainability by improving dyeing property to hair, and it enables natural dyeing by reducing damage of hair caused by dyeing after dyeing, and since it contains natural ingredients, It protects the scalp from skin allergies and irritation caused by skin irritation.
본 발명은 하기 실시예 및 시험예에 의하여 더욱 구체적으로 설명한다. 그러나, 하기 실시예 및 시험예는 본 발명의 이해를 돕기 위한 것일 뿐, 어떤 의미로든 본 발명의 범위가 이러한 실시예 및 시험예에 의하여 한정되는 것은 아니다.The present invention will be described in more detail with reference to the following examples and test examples. However, the following examples and test examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited by these examples and test examples in any sense.
본 발명은 다시마류의 줄기, 잎, 뿌리 중 1종 이상으로부터 얻어진 추출물 85 내지 93 중량%, 0.5 내지 3중량%의 염료제 및 잔존량의 향료, 살균제, 소염제, 방부제, 산화방지제, 자외선 흡수제, 암모니아수, 글리콜산암모늄, 지방산알콜, 물 및 칼륨백반으로 이루어진 그룹에서 선택된 1종 이상을 포함하는 제1제; 및The present invention relates to a cosmetic composition comprising 85 to 93% by weight of an extract obtained from at least one of stems, leaves and roots of sea tangle, 0.5 to 3% by weight of a dye preparation and a perfume of a residual amount, a bactericide, an anti- inflammatory agent, an antiseptic, A first agent comprising at least one member selected from the group consisting of ammonia water, ammonium glycolate, fatty acid alcohol, water and potassium alum; And
상기 추출물 85 내지 90 중량% 및 잔존량의 상기 제1제를 산화하는 산화제 및 pH 조정제를 포함하는 제2제를 포함하는 것이다.And a second agent comprising 85 to 90% by weight of the extract and an oxidizing agent and a pH-adjusting agent for oxidizing the residual amount of the first agent.
-염색성 평가- - Dyeability evaluation -
염모제 조성물의 염착력을 평가하기 제 1제 조성물과 제 2제 산화제 조성물을 1:1 비율로 혼합한 후 모발무게의 2배 되는 양을 취해 길이 12cm의 실험용 사람 모발에 골고루 도포하였다. 모발은 흰머리가 약 30% 포함된 것을 이용하였다. 도포 후 통상적인 염모제 방치 시간인 30분간 방치한 후 샴푸액을 이용하여 흐르는 물에 1분간 세척한 후 헤어드라이어를 이용해 건조시켰다. 건조시킨 모발을 색차계(기종: Hunterlab Labscan XE)를 이용하여 색을 측정하였다. 결과는 염색성이 우수함을 알 수 있었다. Evaluation of Salt-Forming Ability of Hair-dyeing Composition The first composition and the second oxidizing agent composition were mixed at a ratio of 1: 1 and then applied to hair of a 12-cm-long experimental person evenly twice as much as the hair weight. The hair used was one containing about 30% of gray hair. After the application, the hair was allowed to stand for 30 minutes, which was the usual time for leaving the hair dye. Then, the hair was washed with running water for 1 minute using a shampoo solution, and then dried using a hair drier. The dried hair was measured for color using a color difference meter (model: Hunterlab Labscan XE). The results showed that the dyeability was excellent.
-색상 지속성 평가-- Color persistence evaluation -
염색한 모발을 샴푸액에 넣은 후 shaker를 이용하여 30분간 200rpm의 속도로The dyed hair was placed in a shampoo and shaken at a speed of 200 rpm for 30 minutes
흔들어 준 후 흐르는 물에 1분간 헹구어 헤어드라이어로 건조하였다. 건조 후 색차계를 이용하여 측정한 바 색상의 지속성이 우수함을 알 수 있었다.After shaking, it was rinsed in flowing water for 1 minute and dried with a hair dryer. It was found that color persistence was excellent when measured by using colorimeter after drying.
-모발 손상감 평가-- Assessment of hair damage -
조성물의 모발 손상감을 평가하기 위해, 상기 조성물을 이용하여 염색한 모발을 전문 패널 5명이 하기 기준에 따라 평가한 바, 본 발명에 따른 염모제 염색 후 모발의 손상이 감소되는 것을 확인 할 수 있어 모발 보호 효과가 역시 우수한 것을 확인 할 수 있었다. In order to evaluate the degree of hair damage of the composition, 5 dyes dyed with the above composition were evaluated according to the following criteria. It was confirmed that hair damage after dyeing according to the present invention was reduced, The effect was also excellent.
Claims (1)
상기 추출물 85 내지 90 중량% 및 잔존량의 상기 제1제를 산화하는 산화제 및 pH 조정제를 포함하는 제2제를 포함하는 것을 특징으로 하는 염모제용 조성물.An antiseptic, an antiseptic, an antioxidant, an ultraviolet absorber, an ammonia water, a glycol, an antioxidant, an antiseptic, an antiseptic, an antiseptic, an antiseptic, A first agent comprising at least one member selected from the group consisting of ammonium, fatty acid alcohols, water and potassium alum; And
A second agent comprising 85 to 90% by weight of the extract and an oxidizing agent for oxidizing the first agent in a remaining amount and a pH adjuster.
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