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KR20160037631A - Electrolysis apparatus with assistant electrode - Google Patents

Electrolysis apparatus with assistant electrode Download PDF

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KR20160037631A
KR20160037631A KR1020140130474A KR20140130474A KR20160037631A KR 20160037631 A KR20160037631 A KR 20160037631A KR 1020140130474 A KR1020140130474 A KR 1020140130474A KR 20140130474 A KR20140130474 A KR 20140130474A KR 20160037631 A KR20160037631 A KR 20160037631A
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electrolytic
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박시춘
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(주)미라클인
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C25B1/26—Chlorine; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/63—Holders for electrodes; Positioning of the electrodes

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  • Organic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

본 발명은 피처리수의 살균효과와 피처리수가 이송되는 배관의 세정효과도 우수한 새로운 구성의 보조전극이 구비된 전해장치에 대한 것이다.
본 발명에 따르면, 묽은 염산이 주입되는 전해공간(102)과, 피처리수가 유입 및 배출되는 희석공간(104)이 내부에 구획형성되며, 상기 전해공간(102)과 희석공간(104) 사이에는 전해공간(102)에서 생성되는 전해물질이 희석공간(104)으로 배출되는 전해물질배출공(105)이 형성된 하우징(100); 상기 전해공간(102)에 구비되어, 전해공간(102)으로 유입되는 염산을 전기분해하는 메인전극(200); 및 상기 희석공간(104)에 구비되어 상기 희석공간(104)에서 생성되는 염산을 전기분해하는 보조전극(300);을 포함하여 이루어진 것을 특징으로 하는 보조전극이 구비된 전해장치가 제공된다.The present invention relates to an electrolytic apparatus provided with a auxiliary electrode of a novel structure which is excellent in a sterilizing effect of the water to be treated and a cleaning effect of a pipe to which the water to be treated is fed.
According to the present invention, an electrolytic space 102 into which diluted hydrochloric acid is injected and a dilution space 104 into which the for-treatment water is introduced and into which are partitioned, and between the electrolysis space 102 and the dilution space 104 A housing 100 having an electrolyte discharge hole 105 through which the electrolytic material generated in the electrolytic space 102 is discharged into the dilution space 104; A main electrode 200 provided in the electrolysis space 102 to electrolyze hydrochloric acid flowing into the electrolysis space 102; And an auxiliary electrode (300) provided in the dilution space (104) to electrolyze hydrochloric acid generated in the dilution space (104).

Description

보조전극이 구비된 전해장치{Electrolysis apparatus with assistant electrode }[0001] Electrolysis apparatus with assistant electrode [0002]

본 발명은 보조전극이 구비된 전해장치에 관한 것으로서, 보다 상세하게는 피처리수의 살균효과와 피처리수가 이송되는 배관의 세정효과도 우수한 새로운 구성의 보조전극이 구비된 전해장치에 관한 것이다.
The present invention relates to an electrolytic apparatus having an auxiliary electrode, and more particularly, to an electrolytic apparatus provided with an auxiliary electrode of a novel structure, which is excellent in a sterilizing effect of the water to be treated and a cleaning effect of a pipe to be treated.

수영장 등의 물놀이 시설에서는 물을 살균하고 주기적으로 배관을 청소하는 등 위생적인 관리가 요구된다. 뿐만 아니라 각종 공장이나, 가축 농장 등을 비롯하여 다양한 분야에서 사용되는 용수도 위생적인 관리가 요구된다.In a watering facility such as a swimming pool, hygienic management is required such as sterilizing water and periodically cleaning the pipe. In addition, hygienic management of water used in various fields such as various factories, livestock farms, etc. is required.

일반적으로 물을 살균하거나 배관을 세척하기 위한 방법으로 물을 전기분해하는 방법이 사용되고 있다. 배관에 전해장치를 연결하여 배관에 이송되는 물을 전기분해시키는데, 물이 전기분해되어 발생되는 전해물질의 산화 및 환원성에 의해 배관에 부착된 슬러리가 이온화되어 용해, 제거됨에 따라 배관이 세척되며, 아울러 물도 살균된다. Generally, a method for electrolyzing water is used as a method for sterilizing water or washing pipes. The electrolytic apparatus is connected to the piping to electrolyze water transferred to the piping. The piping is cleaned as the slurry attached to the piping is ionized and dissolved and removed by the oxidation and reduction of the electrolytic substance generated by electrolysis of water, In addition, water is sterilized.

그러나 이와 같이 전기분해를 이용한 처리방법은 살균효과가 미미하기 때문에, 추가로 별도의 살균처리를 하여야 하는 번거로움이 발생되고, 그에 따른 추가 비용도 발생된다. However, since the disinfecting effect of the electrolytic treatment is insignificant, additional disinfection treatment is required and additional costs are incurred.

한편, 차아염소산수는 인체에 무해하면서도 뛰어난 살균력을 가지는데, pH5~6.5 정도의 미산성 영역에서 살균력이 가장 우수한 것으로 알려져 있다. 이러한 차아염소산수는 흔히, 2~6% 정도의 묽은 염산을 무격막 전기분해장치로 전기분해하여 제조된다. 염산의 전기분해에 의해 차아염소산이 생성되는 메카니즘을 살펴보면, 염산이 전기분해되어 염소가스가 발생되고, 이 염소가스가 물에 용해되어 차아염소산수가 생성된다. On the other hand, hypochlorous acid water is harmless to the human body but has excellent sterilizing power. It is known that the sterilizing power is the most excellent in the acidic range of pH 5 ~ 6.5. Such hypochlorous acid water is often prepared by electrolyzing 2-6% of diluted hydrochloric acid with a non-diaphragm electrolysis apparatus. The mechanism by which hypochlorous acid is produced by electrolysis of hydrochloric acid is as follows. Hydrochloric acid is electrolyzed to generate chlorine gas, which is dissolved in water to generate hypochlorous acid water.

한편, 염소가스가 희석수에 용해되어 차아염소산수가 생성되는 과정에서, 아래의 화학식과 같이, 염소가스의 일부는 염산으로 재생성되는데, 이에 따라 생성되는 차염소산수의 pH가 낮아진다. On the other hand, in the process in which chlorine gas is dissolved in diluted water to generate hypochlorous acid water, a part of the chlorine gas is regenerated as hydrochloric acid, thereby lowering the pH of the produced hypochlorous acid water.

H2O + Cl2 → HOCl + HClH 2 O + Cl 2 - > HOCl + HCl

그런데 전술한 바와 같이, 차아염소산수는 pH5~6.5의 미산성 수준에서 가장 우수한 살균력을 갖기 때문에, 차아염소산수의 살균력을 향상시키기 위해서는 차아염소산수의 pH를 미산성 수준으로 조절할 필요가 있다.However, as described above, hypochlorous acid water has the best sterilizing power at the microacid level of pH 5 ~ 6.5. Therefore, in order to improve the sterilizing power of hypochlorous acid water, it is necessary to adjust the pH of the hypochlorous acid water to a microacid level.

대한민국 등록특허 제10-0223694호(1999. 07. 12.)Korean Patent No. 10-0223694 (1999. 07. 12.)

본 발명은 상기의 문제점을 해결하기 위한 것으로서, 본 발명의 목적은 미산성 수준의 차아염소산이 제조되기 때문에, 피처리수의 살균효과가 우수함은 물론이며, 피처리수가 이송되는 배관 내부의 세정효과도 우수한 새로운 구성의 보조전극이 구비된 전해장치를 제공하는 것이다.
The object of the present invention is to solve the above-mentioned problems, and it is an object of the present invention to provide a hypochlorous acid having a microacid level, which is excellent in bactericidal effect of the water to be treated, The present invention also provides an electrolytic apparatus equipped with an auxiliary electrode having a novel structure.

본 발명의 일 특징에 따르면, 묽은 염산이 주입되는 전해공간(102)과, 피처리수가 유입 및 배출되는 희석공간(104)이 내부에 구획형성되며, 상기 전해공간(102)과 희석공간(104) 사이에는 전해공간(102)에서 생성되는 전해물질이 희석공간(104)으로 배출되는 전해물질배출공(105)이 형성된 하우징(100); 상기 전해공간(102)에 구비되어, 전해공간(102)으로 유입되는 염산을 전기분해하는 메인전극(200); 및 상기 희석공간(104)에 구비되어 상기 희석공간(104)에서 생성되는 염산을 전기분해하는 보조전극(300);을 포함하여 이루어진 것을 특징으로 하는 보조전극이 구비된 전해장치가 제공된다.
According to an aspect of the present invention, there is provided an electrolytic cell in which diluted hydrochloric acid is injected and a dilution space 104 into which the for-treatment water is introduced and discharged, A housing 100 having an electrolyte discharge hole 105 through which an electrolytic substance generated in an electrolytic space 102 is discharged into a dilution space 104; A main electrode 200 provided in the electrolysis space 102 to electrolyze hydrochloric acid flowing into the electrolysis space 102; And an auxiliary electrode (300) provided in the dilution space (104) to electrolyze hydrochloric acid generated in the dilution space (104).

본 발명의 다른 특징에 따르면, 상기 보조전극(300)은 나선형상으로 형성된다.
According to another aspect of the present invention, the auxiliary electrode 300 is formed in a spiral shape.

본 발명의 또 다른 특징에 따르면, 상기 희석공간(104)의 내주면에는 나선형 교반돌기(108)가 돌출형성된다.
According to another aspect of the present invention, a helical stirring protrusion (108) protrudes from the inner circumferential surface of the dilution space (104).

이상과 같은 구성을 가지는 희석공간(104)에 존재되는 염산이 보조전극(300)에 의해 전기분해되어 차아염소산이 추가적으로 발생되기 때문에, 차아염소산수 농도도 증가되고 pH도 상승되어, 농도가 높은 미산성의 차아염소산수를 생성할 수 있다. 따라서 피처리수가 효과적으로 살균되고, 배관의 세척효과도 우수하다. Since the hydrochloric acid present in the dilution space 104 having the above-described configuration is electrolyzed by the auxiliary electrode 300 to generate additional hypochlorous acid, the hypochlorous acid concentration is increased and the pH is also increased, An acidic hypochlorous acid water can be produced. Therefore, the water to be treated is sterilized effectively, and the cleaning effect of the pipe is excellent.

또한, 보조전극(300)이 나선형으로 형성된 경우에는 전해공간(102)에서 생성되어 희석공간(104)으로 유입된 염소가스와 피처리수가 상기 보조전극(300)에 부딪혀서 교반되는 효과를 얻을 수 있으며, 이에 따라 염소가스가 미분화되어 염소가스의 용해도가 높아지고 차아염소산수의 생성효율이 향상된다. In addition, when the auxiliary electrode 300 is spirally formed, the chlorine gas generated in the electrolysis space 102 and introduced into the dilution space 104 and the for-treatment water are mixed with the auxiliary electrode 300, , Whereby the chlorine gas is undifferentiated, the solubility of the chlorine gas is increased, and the production efficiency of hypochlorous acid water is improved.

또, 희석공간(104)에 나선형 교반돌기(108)가 형성된 경우에는 염소가스와 피처리수의 교반효율이 상승되어, 차아염소산수의 생성효율이 한층 더 향상된다. When the spiral agitating protrusion 108 is formed in the dilution space 104, the stirring efficiency of the chlorine gas and the water to be treated is increased, and the hypochlorous acid water production efficiency is further improved.

도 1은 본 발명의 제1실시예를 보인 단면도
도 2는 상기 실시예의 사용상태 단면도
도 3은 본 발명의 제2실시예를 보인 단면도
도 4는 본 발명의 제3실시예를 보인 단면도
1 is a cross-sectional view showing a first embodiment of the present invention;
Figure 2 is a cross-sectional view of the use state of the embodiment
3 is a cross-sectional view showing a second embodiment of the present invention
4 is a cross-sectional view showing a third embodiment of the present invention

이하에서 도면을 참조하여 본 발명의 바람직한 실시예를 설명한다. Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings.

도 1은 본 발명의 제1실시예를 보인 단면도이고, 도 2는 사용상태를 보인 도면도이다. 본 발명은 도시된 바와 같이, 내부에 전해공간(102)과, 희석공간(104)이 형성되는 하우징(100)과, 전해공간(102)에 구비되는 한 쌍의 메인전극(200)과, 희석공간(104)에 구비되는 한 쌍의 보조전극(2300)을 포함하여 이루어진다. FIG. 1 is a sectional view showing a first embodiment of the present invention, and FIG. 2 is a view showing a used state. A housing 100 in which an electrolytic space 102 and a dilution space 104 are formed, a pair of main electrodes 200 provided in the electrolytic space 102, And a pair of auxiliary electrodes 2300 provided in the space 104.

상기 하우징(100)은 상하로 긴 원통체형상의 하우징본체(110)와 하우징본체(110)의 상, 하단부에 각각 나사결합되는 상부캡(120)과 하부캡(130)으로 이루어진다. 따라서 하우징본체(110)에 상부캡(120)과 하부캡(130)을 결합시키면 하우징 (100) 내부에 외부와 구획되는 내부공간이 형성된다.The housing 100 includes a housing body 110 having a long cylindrical shape and an upper cap 120 and a lower cap 130 which are screwed to upper and lower ends of the housing body 110, respectively. Accordingly, when the upper cap 120 and the lower cap 130 are coupled to the housing main body 110, an inner space is formed inside the housing 100 to be separated from the outside.

상기 하우징본체(110)의 내부에는 하우징(100) 내부공간을 상하로 구획하는 구획벽(130)이 형성되고, 이 구획벽(130)에 의해 하우징(100)의 내부공간은 상측의 전해공간(102)과 하측의 희석공간(104)으로 구획된다. 이러한 구획벽(130)에는 전해공간(102)에서 생성되는 염소가스를 비롯한 수소가스 등을 포함하는 전해물질이 희석공간(104)으로 배출되는 전해물질배출공(105)이 형성된다.A partition wall 130 separating upper and lower spaces of the inner space of the housing 100 is formed in the housing main body 110. The inner space of the housing 100 is partitioned by the partition wall 130 into an electrolytic space 102) and a lower dilution space (104). The partition wall 130 is formed with an electrolytic material discharge hole 105 through which electrolytic material including hydrogen gas and the like including chlorine gas generated in the electrolytic space 102 is discharged into the dilution space 104.

그리고 상기 하우징본체(110)의 희석공간(104) 측에는 물, 즉, 피처리수가 유입되는 입수구(112)와, 물을 외부로 배출시키는 배수구(114)가 형성된다. In the dilution space 104 side of the housing main body 110, a water inlet 112 into which water, that is, water to be treated flows, and a water outlet 114 through which water is discharged to the outside are formed.

한편, 상기 전해공간(102)에는 염산을 전기분해하기 위한 메인전극(200)이 내장된다. 메인전극(200)은 +, - 전극이 쌍을 이루도록 내장되는데, 본 실시예에서는 1쌍의 전극이 구비된 것으로 도시되었으나, 전극이 다수 쌍 구비될 수도 있다. 바람직하게는 도시된 바와 같이, 메인전극(200)은 상부캡(120)에 고정결합되며, 상부캡(120)에는 전해공간(102)으로 묽은 염산을 주입하기 위한 염산주입구(106)가 형성된다. Meanwhile, a main electrode 200 for electrolyzing hydrochloric acid is built in the electrolytic space 102. The main electrode 200 is formed so as to form a pair of + and - electrodes. In this embodiment, a pair of electrodes is provided, but a plurality of electrodes may be provided. The main electrode 200 is fixedly coupled to the upper cap 120 and the upper cap 120 is formed with a hydrochloric acid inlet 106 for injecting diluted hydrochloric acid into the electrolysis space 102 .

그리고 상기 희석공간(104)에는 보조전극(300)이 내장된다. 보조전극(300) 역시 +, - 전극이 쌍을 이루도록 내장되는데, 보조전극(300)은 하부캡(130)에 고정결합된다.
The auxiliary electrode 300 is embedded in the dilution space 104. The auxiliary electrode 300 is also built in pairs so that the auxiliary electrode 300 is fixedly coupled to the lower cap 130.

이러한 구성을 가지는 본 발명은 다음과 같이 작동된다.The present invention having such a configuration operates as follows.

본 발명은 피처리수가 이송되는 배관 상에 설치되거나 또는 피처리수가 저장된 저장공간 내부에 설치된다. 도 2는 본 발명이 피처리수가 이송되는 배관(2) 상에 설치된 것으로 도시되었는데, 이 경우에는 하우징(100)의 입수구(112)와 배수구(114)가 배관(2)에 연결된다. 미 설명 부호 9는 염산저장탱크와 염산주입구(106) 사이에 연결되는 염산공급관이다.The present invention is installed on the piping to which the for-treatment water is to be transferred or is installed inside the storage space where the for-treatment water is stored. In this case, the inlet port 112 and the drain port 114 of the housing 100 are connected to the pipeline 2. In this case, the inlet port 112 and the drain port 114 of the housing 100 are connected to the pipeline 2. Reference numeral 9 is a hydrochloric acid supply pipe connected between the hydrochloric acid storage tank and the hydrochloric acid inlet 106.

상기 염산주입구(106)를 통해 전해공간(102)으로 묽은 염산이 주입되고 메인전극(200)에 전류가 인가되면, 전해공간(102)으로 유입되는 묽은 염산이 전기분해되어 염소가스가 발생된다. 발생된 염소가스는 전해물질배출공(105)을 통해 희석공간(104)으로 유입되어 희석공간(104) 내부의 피처리수에 용해되어 차아염소산이 생성된다. 이와 같이 염소가스가 물에 용해되어 차아염소산이 생성되므로 최종적으로 차아염소산수가 생성된다. When dilute hydrochloric acid is injected into the electrolytic space 102 through the hydrochloric acid inlet 106 and current is applied to the main electrode 200, dilute hydrochloric acid flowing into the electrolytic space 102 is electrolyzed to generate chlorine gas. The generated chlorine gas flows into the dilution space 104 through the electrolyte discharge hole 105 and is dissolved in the water to be treated in the dilution space 104 to generate hypochlorous acid. In this way, chlorine gas is dissolved in water and hypochlorous acid is produced, so that hypochlorous acid water is finally produced.

한편, 전술한 바와 같이, 염소가스에 의해 차아염소산이 생성되는 과정에서 염소가스의 일부가 염산으로 재생성되는데, 이때 발생되는 염산은 보조전극(300)에 의해 희석공간(104)에서 전기분해되며, 이에 따라 차아염소산이 추가로 생성된다. Meanwhile, as described above, in the process of generating hypochlorous acid by chlorine gas, a part of the chlorine gas is regenerated into hydrochloric acid. The hydrochloric acid generated at this time is electrolyzed in the dilution space 104 by the auxiliary electrode 300, Thus, hypochlorous acid is additionally produced.

이와 같이 보조전극(300)에 의해 희석공간(104)의 염산이 전기분해됨에 따라 차아염소산수의 pH가 상승되고, 차아염소산수의 차아염소산농도가 증가된다. 따라서 고농도의 미산성 차아염소산수를 얻게 되며, 이에 따라 피처리수 및 피처리수가 이송되는 배관이 살균되고, 배관 내부에 부착된 슬러리도 효과적으로 제거된다.
As the hydrochloric acid in the dilution space 104 is electrolyzed by the auxiliary electrode 300, the pH of the hypochlorous acid water is increased and the hypochlorous acid concentration of the hypochlorous acid water is increased. Therefore, a high concentration of hypochlorous acid water is obtained, whereby the piping to be treated and the water to be treated are sterilized, and the slurry attached to the inside of the piping is also effectively removed.

이하에서는 본 발명의 다른 실시예를 설명하되, 전술한 실시예와 동일한 구성 및 효과에 대해서는 설명을 생략한다. Hereinafter, other embodiments of the present invention will be described, and the same structures and effects as those of the above-described embodiments will not be described.

도 3은 발명의 제2실시예를 보인 것으로서, 상기 하우징본체(110)는 전해공간을 형성하는 제1하우징본체(116)와 제1하우징본체(116)의 하단부에 결합되어 희석공간(102)을 형성하는 제2하우징본체(118)로 분할형성되고, 제1하우징본체(116)의 바닥면에 전해물질배출공(105)이 형성된다. FIG. 3 shows a second embodiment of the present invention. The housing body 110 includes a first housing body 116 that forms an electrolytic space and a second housing body 116 that is coupled to a lower end of the first housing body 116, And an electrolyte discharge hole 105 is formed on the bottom surface of the first housing body 116. The electrolyte discharge hole 105 is formed in the bottom surface of the first housing body 116. [

또한, 본 실시예에서는 보조전극(300)이 나선형상으로 꼬아진 형상을 갖는다. 이와 같이 보조전극(300)이 나선형상을 가지면, 보조전극(300)에 의해 전해공간(102)에서 배출되는 염소가스와 피처리수가 보조전극(300)에 부딪혀서 교반되는 교반효과를 얻을 수 있는데, 이에 따라 염소가스가 미분화되어 피처리수에 용해되는 용해도가 높아지고, 차아염소산이 생성되는 차아염소산의 생성효율이 향상된다.
Also, in this embodiment, the auxiliary electrode 300 has a spiral twisted shape. When the auxiliary electrode 300 has a spiral shape, the auxiliary electrode 300 can obtain a stirring effect in which the chlorine gas discharged from the electrolysis space 102 and the for-treatment water collide against the auxiliary electrode 300, As a result, the chlorine gas is undifferentiated, the solubility in the for-treatment water is increased, and the production efficiency of hypochlorous acid in which hypochlorous acid is produced is improved.

도 4는 본 발명의 제3실시예를 보인 것으로서, 상기 제2하우징본체(118)의 내주면에 나선형 교반돌기(108)가 돌출형성된다. FIG. 4 shows a third embodiment of the present invention. A spiral stirring protrusion 108 protrudes from the inner circumferential surface of the second housing body 118.

이와 같이 교반돌기(108)가 형성되면, 염소가스와 피처리수의 교반효율이 한층 더 상승되고, 이에 따라 차아염소산의 생성효율도 한층 더 향상된다. When the stirring projections 108 are formed in this manner, the stirring efficiency of the chlorine gas and the water to be treated is further increased, and the efficiency of producing hypochlorous acid is further improved.

Claims (3)

묽은 염산이 주입되는 전해공간(102)과, 피처리수가 유입 및 배출되는 희석공간(104)이 내부에 구획형성되며, 상기 전해공간(102)과 희석공간(104) 사이에는 전해공간(102)에서 생성되는 전해물질이 희석공간(104)으로 배출되는 전해물질배출공(105)이 형성된 하우징(100);
상기 전해공간(102)에 구비되어, 전해공간(102)으로 유입되는 염산을 전기분해하는 메인전극(200); 및
상기 희석공간(104)에 구비되어 상기 희석공간(104)에서 생성되는 염산을 전기분해하는 보조전극(300);을 포함하여 이루어진 것을 특징으로 하는 보조전극이 구비된 전해장치.
An electrolytic space 102 into which diluted hydrochloric acid is injected and a dilution space 104 into which a to-be-treated water flows are formed in the interior of the electrolytic space 102. Between the electrolytic space 102 and the dilution space 104, A housing 100 in which an electrolytic material discharge hole 105 through which an electrolytic substance generated in the electrolytic cell 100 is discharged into a dilution space 104 is formed;
A main electrode 200 provided in the electrolysis space 102 to electrolyze hydrochloric acid flowing into the electrolysis space 102; And
And an auxiliary electrode (300) provided in the dilution space (104) to electrolyze hydrochloric acid generated in the dilution space (104).
제1항에 있어서,
상기 보조전극(300)은 나선형상으로 형성된 것을 특징으로 하는 보조전극이 구비된 전해장치.
The method according to claim 1,
Wherein the auxiliary electrode (300) is formed in a spiral shape.
제1항 또는 제2항에 있어서,
상기 희석공간(104)의 내주면에는 나선형 교반돌기(108)가 돌출형성된 것을 특징으로 하는 보조전극이 구비된 전해장치. 3. The method according to claim 1 or 2,
And a spiral stirring protrusion (108) protrudes from the inner peripheral surface of the dilution space (104).
KR1020140130474A 2014-09-29 2014-09-29 Electrolysis apparatus with assistant electrode Ceased KR20160037631A (en)

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