KR20160023514A - Detergent composition comprising Galactomyces ferment filtrate - Google Patents

Abstract

The present invention relates to a detergent composition comprising a fermented filtrate of galactomyces, for reducing stimulation with respect to the skin, and providing effects in protecting the skin. More specifically, the present invention relates to a detergent composition, comprising, with respect to the total weight of the composition, 5-50 wt% of a surfactant, and 0.001-1 wt% of a glactomyces fermented filtrate. The detergent composition of the present invention has excellent cleansing power and rinsing properties. In addition, the composition has the reduced stimulation of the skin, significant feeling of use, and moisturizing properties, by converting profilaggrin to a natural moisturizing factor due to the galactomyces fermented filtrate, and preventing polysaccharide ingredients from evaporating the moisture on the skin surface.

Description

A detergent composition comprising a Galactomyces fermented filtrate,

The present invention relates to a detergent composition containing a fermentation filtrate of galactomyces to reduce irritation to the skin and impart a skin protection effect.

Liquid detergent compositions used as kitchen detergents are variously known, and many of them are commercialized. The detergent developed so far mainly focuses on the cleaning effect and does not consider the skin stability. In some cases, the skin-sensitive consumer may cause dermatitis. In addition, these detergent compositions may cause damage to the skin due to contact with the skin of the hand, which may be somewhat different depending on the constitution, and cause irritation to cause the hand to become rough.

For example, Korean Patent Laid-Open Publication No. 2003-43356 discloses a liquid detergent composition containing a polyoxyethylene lauryl ether (n = 9) nonionic surfactant, but in the case of the nonionic surfactant used, Which is a conventional salt catalyst such as KOH, has a disadvantage in that the distribution of the molar number of EO (Ethylene Oxide) is wide and the skin stability such as skin irritation is still not secured.

Accordingly, attempts have been made to improve the problem of skin irritation and moisturization caused by surfactants through a combination of mild surfactants and other additives (polymers, water-soluble proteins, etc.). Conventional detergent compositions increase the feeling of use and increase the moisturizing effect or permeate the water-soluble proteins into the skin to give a skin mild effect through the polymer. However, it is difficult to apply to the kitchen detergent due to high price compared to the effect. The rinsing property is reduced. In addition, there is a problem that the polymer can not be used as the safest one type of kitchen detergent under the domestic kitchen detergent classification standard.

A problem to be solved by the present invention is to provide a detergent composition which is excellent in detergency and rinsability, minimizes skin irritation, and has improved moisturizing and feeling.

The present invention provides a detergent composition comprising from 5 to 50% by weight of a surfactant based on the total weight of the composition and from 0.001 to 1% by weight of a galactomithase fermentation filtrate. Preferably, the surfactant may include at least one selected from the group consisting of an anionic surfactant, a nonionic surfactant, and an amphoteric surfactant.

The present inventors have conducted studies to solve the problem of irritating the skin and damaging the skin when using the kitchen detergent. In the case of using a combination of the galactomainse fermented filtrate and the specific surfactant, The skin irritation is minimized, the moisturizing property and the feeling are improved, and the present invention has been completed.

In the present invention, Galactomyces is a yeast of the genus Saccharomyces , and the galactomithase fermentation filtrate used in the present invention is a precursor of natural moisturizing factor (NMF) Profilaggrin can be converted into a natural moisturizing factor to help maintain skin moisturization. In addition, the polysaccharide component contained in galactomain prevents moisture from being evaporated from the surface of the skin, so that the skin is not dried and an excellent skin moisturizing effect can be obtained. In the present invention, the galactomithase fermentation filtrate can be produced by a conventional method, and is not particularly limited. For example, a culture obtained by culturing a strain of Galactomyces at 15 to 20 ° C for 2 to 3 days Sterilization process and filtration through membrane filtration can be used at a concentration of 0.001 ~ 1%.

In the present invention, the surfactant is preferably contained in an amount of 10 to 40% by weight, more preferably 10 to 35% by weight. If the amount of the surfactant is less than 5% by weight, the detergency and the rinsability are poor. If the surfactant is more than 50% by weight, skin irritation may become severe.

In the present invention, the galactomeyse fermentation filtrate may be contained in an amount of preferably 0.001 to 0.1% by weight, more preferably 0.001 to 0.01% by weight. When the content of the galactomaines fermented filtrate is less than 0.001% by weight, the moisturizing and protecting effect of the skin decreases. When the content is more than 1% by weight, the washing power and the rinsing property are decreased.

In the present invention, the surfactant may be an anionic surfactant; And nonionic surfactants, amphoteric surfactants, or mixtures thereof. In this case, a synergistic effect is exerted on the washing power, as compared with the case where the anionic surfactant known to have excellent washing power is used alone. The weight ratio of the anionic surfactant to the nonionic surfactant, amphoteric surfactant, or mixture thereof is 1: 0.1 to 10, preferably 1: 0.5 to 8 (nonionic surfactant, amphoteric surfactant, Mixture: anionic surfactant). If the weight ratio of the anion surfactant in the weight ratio of 1: 0.1 to 10 (nonionic surfactant, amphoteric surfactant, or mixture thereof: anionic surfactant) is less than 0.1, the detergency and rinsability will decrease, There is a problem that skin irritation is compromised.

The anionic surfactant may be contained in an amount of 1 to 30% by weight, preferably 3 to 20% by weight, more preferably 5 to 15% by weight based on the total weight of the composition. The nonionic surfactant, amphoteric surfactant, or a mixture thereof may be contained in an amount of 1 to 20% by weight, preferably 3 to 17% by weight, more preferably 5 to 15% by weight based on the total weight of the composition. In the combination of the surfactant at a specific weight ratio as described above, the detergent composition of the present invention is excellent in skin moisturizing and skin protecting effect, and the cleaning power can also be remarkably increased.

The pH of the detergent composition of the present invention is 6 to 11.

The anionic surfactant included in the present invention to exert the washing power is not particularly limited as long as it can be used in a conventional cosmetic composition, and examples thereof include fatty acid soap (sodium laurate, sodium palmitate, etc.); Higher alkyl sulfate ester salts (sodium lauryl sulfate, potassium lauryl sulfate and the like); Alkyl ether sulfuric acid ester salts (POE-laurylsulfuric triethanolamine, POE-laurylsulfate, etc.); N-acyl sarcosinate (such as sodium lauroyl sarcosine); Higher fatty acid amide sulfonates (N-myristoyl-N-methyltaurin sodium, coconut fatty acid methyltauride sodium, laurylmethyltauride sodium and the like); Phosphoric acid ester salts (sodium POE-oleyl ether phosphate, POE-stearyl ether phosphoric acid, etc.); Sulfosuccinic acid salts (sodium di-2-ethylhexylsulfosuccinate, sodium monooroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauroyl polypropylene glycol sulfosuccinic acid and the like); Alkylbenzenesulfonates (sodium linear decylbenzenesulfonate, triethanolamine linear decylbenzenesulfonate, linear decylbenzenesulfonic acid, etc.); Higher fatty acid ester sulfuric acid ester salts (such as hardened coconut oil fatty acid glycerin sodium sulfate); N-acyl glutamate (monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamic acid, etc.); Sulfuric acid oil (lot oil, etc.); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether carboxylate; ? -olefin sulfonate; Higher fatty acid ester sulfonates; Secondary alcohol sulfuric acid ester salts; Higher fatty acid alkylolamide sulfates; Sodium lauroyl monoethanolamide succinate; N-palmitoyl aspartic acid ditriethanol amine; and casein sodium. The higher fatty acid refers to a fatty acid having a carbon number of C8 to C22. The anionic surfactant may be in the form of a salt, preferably a sodium salt.

Preferably, the anionic surfactant may comprise a sulfate anionic surfactant. The sulfate anionic surfactant may be selected from the group consisting of alkyl sulfates (preferably alkyl sulfates having C8 to C16 alkyl groups), alkyl ether sulfates (preferably alkyl ether sulfates having C12 to C16 alkyl groups), C1 to C20 primary or secondary alcohols Sulfuric acid monoester compounds of coconut oil fatty alcohol, tallow fatty alcohol, oleyl alcohol or C1 to C20 oxo alcohol, sulfuric acid monoester compounds of aliphatic primary alcohols containing 1 to 6 ethylene oxides, ethoxylated 2 A sulfuric acid monoester compound of a car alcohol or an alkylphenol, a sulfated fatty acid alkanolamide, a sulfated fatty acid monoglyceride, and the like can be used. More preferably, the anionic surfactant may be an alkylsulfate having a C8-C16 alkyl group. When such a specific anionic surfactant is used, the detergent composition of the present invention is excellent in skin moisturizing and skin protecting effect, and can also significantly increase detergency.

In the present invention, the nonionic surfactant may be a lipophilic nonionic surfactant or a hydrophilic nonionic surfactant, and is not particularly limited as long as it can be used in a conventional cosmetic composition. Examples of the lipophilic nonionic surfactants include sorbitan fatty acid esters (sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monostearate, Sesquioleoleate, sorbitan trioleate, penta-2-ethylhexyl acid diglycerol sorbitan, tetra-2-ethylhexyl acid diglycerol sorbitan and the like); Glycerin polyglycerin fatty acids (monosaccharic fatty acid glycerin, monoelucic acid glycerin, sesquioleic acid glycerin, monostearic acid glycerin,?,? '- oleic acid pyroglutamic acid glycerin, monostearic acid glycerin malic acid, etc.); Propylene glycol fatty acid esters (such as propylene glycol monostearate); Hardened castor oil derivatives; Sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan tetraoleate, and the like); hydrophilic nonionic surfactants such as polyoxyethylene sorbitan fatty acid esters (polyoxyethylene sorbitan fatty acid esters); POE-sorbit fatty acid esters (POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol monostearate, and the like); POE-glycerin fatty acid esters (POE-glycerin monostearate, POE-glycerin monoisostearate, POE-glycerin triisostearate, etc.); POE-fatty acid esters (POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic molds (Pluronic and the like); POE / POP-alkyl ethers (POE / POP-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether and the like); Tetra POE tetra POP-ethylenediamine condensation products (such as Tetronic); POE-castor oil-hardened castor oil derivative (POE-castor oil, POE-hardened castor oil, POE-hardened castor oil free monoisostearate, POE-hardened castor oil free triisostearate, POE-hardened castor oil free monopyrroglutamate monoisoprene Stearic acid diester, POE-hardened castor oil free maleic acid); POE beeswax / lanolin derivatives (POE-sorbitol beeswax); Alkanolamides (coconut fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid esters; POE-alkylamines; POE-fatty acid amide; Sucrose fatty acid esters; Alkylethoxydimethylamine oxides; And trioleyl phosphoric acid. However, the present invention is not limited thereto.

Preferably, the nonionic surfactant is selected from the group consisting of primary or secondary alcohol-based nonionic surfactants, alkylpolyglycoside nonionic surfactants, and fatty acid amide-based nonionic surfactants containing ethylene glycol in an amount of 1 to 25 moles For example, ammonia amide, monoethanol amide, diethanol amide, or isopropanol amide), and the like may be used. More preferably, the nonionic surfactant may be an alkylpolyglycoside nonionic surfactant having a straight-chain or branched alkyl group having 8 to 22 carbon atoms.

In the present invention, the amphoteric surfactant is not particularly limited as long as it can be used in a conventional cosmetic composition, and includes 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium , 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, and the like; And betaine surfactants such as 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkyl betaine, amide betaine, sulfobetaine and the like And the like may be used. Preferably, the amphoteric surfactant may be a fatty acid amide based betaine of C8 to 22, an alkyl amineoxyid of amine type of C8 to 22, or a mixture thereof, and more preferably, an alkylamine oxide may be used have.

The detergent compositions of the present invention may further comprise an electrolyte to control pH and viscosity in a surfactant system, increase cleaning and foaming power, and enhance dispersion stability. The electrolyte may be at least one selected from the group consisting of sodium chloride, potassium chloride, monopotassium phosphate, dipotassium phosphate, sodium citrate, and potassium citrate, but is not limited thereto. Preferably, sodium chloride may be used as the electrolyte. The electrolyte may be contained in an amount of 1 to 10% by weight, preferably 1 to 8% by weight, more preferably 1 to 5% by weight based on the total weight of the composition. When the amount of the electrolyte is less than 1% by weight, the washing power, the foaming power and the rinsing ability are deteriorated. When the amount is more than 10% by weight,

The detergent composition of the present invention may further comprise less than 5% by weight based on the total weight of the composition of a water soluble protein, polymer, or mixture thereof. The polymer enhances feeling and moisturizing, while the water-soluble protein penetrates the skin and softens the skin. Preferably, the water-soluble protein, polymer, or mixture thereof may comprise less than 3% by weight, more preferably less than 1% by weight, and most preferably none at all. The use of polymers and water-soluble proteins reduces the rinseability, and the polymer is not the safest one-class kitchen detergent in the domestic kitchen detergent classification standard. In addition, since the skin care / moisturizing effect is excellently exerted only by the galactomyces fermented filtrate, it is most preferable that the detergent composition of the present invention does not contain a water-soluble protein or polymer.

The present invention relates to a detergent composition comprising 1 to 20% by weight of alkyl ether sulfate, 1 to 10% by weight alkyl amine oxide, 1 to 10% by weight alkylpolyglucoside, and 0.001 to 1% by weight of galactomithase fermentation filtrate, Lt; / RTI > The weight ratio of alkyl amine oxide and alkyl polyglucoside to alkyl ether sulfate may be 1: 0.1 to 10 (alkylamine oxide and alkyl polyglucoside: alkyl ether sulfate). The detergent composition having the above composition ratio is excellent in detergency and rinsing properties, has less irritation to the skin, and is most excellent in moisture retention and feeling. The detergent composition may further comprise 1 to 10% by weight of electrolyte relative to the total weight of the composition to control pH and viscosity in the surfactant system, increase cleaning and foaming power, and increase dispersion stability.

The present invention also relates to (s1) adding and stirring a nonionic surfactant, an amphoteric surfactant, or a mixture thereof to an aqueous phase together with an electrolyte; (s2) adding an anionic surfactant to the product of step (s1) and stirring; (s3) adding a galactomyces fermentation filtrate to the product of step (s2) and mixing the mixture. The manufacturing method of the present invention can equally be applied to the composition of the detergent composition.

The detergent composition of the present invention is excellent in detergency and rinsing properties, and is converted into a natural moisturizing factor by Galactomyces fermented filtrate, prevents polysaccharide component from evaporating moisture from the skin surface, Excellent in moisturizing and feeling.

Fig. 1 is a graph showing the results of a 10-day evaluation of skin moisturizing properties by comparing a kitchen detergent containing a galactomeyse fermentation filtrate with a control.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

Experimental Example 1: Usability comparison evaluation of existing kitchen detergent and detergent composition of the present invention

The existing kitchen detergent containing no Galactomisse fermentation filtrate was used as Comparative Example 1, and the usability was compared with a kitchen detergent containing Galactomyces fermented filtrate (Example 1). The kitchen detergent composition of Example 1 was prepared by adding alkylamine oxide, alkyl polyglucoside, and sodium citrate to the aqueous phase and stirring, adding alkyl ether sulfate and stirring, adding and mixing the galactomies fermented filtrate .

The Galactomithase fermentation filtrate used in this experiment was obtained by culturing the Galactomyces sp. Strain cultured at 15-20 ° C for 2-3 days and sterilized and filtered through membrane filtration to obtain a concentration of 0.001-1% Respectively.

Twenty subjects in the sample were compared using two detergents and evaluated by a sensory evaluation method that gave a score on a 5 - point scale. The composition ratios of Comparative Example 1 and Example 1 are shown in Table 1 below, and the results of sensory evaluation are shown in Table 2 below.

Category (% by weight) Comparative Example 1 Example 1 Alkyl ether sulfate 9.24 9.24 Alkyl amine oxide 3.14 3.14 Alkylpolyglucoside 4.63 4.63 Sodium citrate 2 2 Galactomisses fermentation filtrate - 0.002 incense q.s. q.s. pH adjusting agent q.s. q.s. Purified water To 100 To 100

Bubble power Cleaning power Rinsing power Moisturizing/
Skin protection Freshness Non-magnetic Overall
satisfaction Comparative Example 1 4.17 4.21 4.15 3.10 3.64 3.75 4.09 Example 1 4.32 4.23 4.30 4.25 4.43 4.56 4.57

The detergent composition of Example 1 exhibited the same or better performance in terms of cleaning / rinsing of the foam power, cleaning power, and rinsing power compared to the conventional kitchen detergent, and it was confirmed that the feeling of use such as moisturizing / skin protection, freshness and stimulation was improved.

Experimental Example 2: Usability comparison evaluation between the conventional hand wash product and the detergent composition of the present invention

The existing hand wash product was compared with the kitchen detergent (Example 1) containing the Galactomescence fermented filtrate as Comparative Example 2 and compared with the usability. Handwash uses mild surfactant compared to kitchen detergent, and it is actually evaluated as feeling mild. As in Experimental Example 1, 20 samples were used in comparison with each other, and the scores were given on a scale of 5 points. The composition ratios of Comparative Example 2 and Example 1 are shown in Table 3 below, and the results of sensory evaluation are shown in Table 4 below.

Category (% by weight) Comparative Example 2 Example 1 Alkyl ether sulfate 9.45 9.24 Alkyl amine oxide 3.14 3.14 Alkylpolyglucoside 4.63 4.63 Alkyl hydro- 1.5 - Acrylate copolymer 2.4 - Sodium citrate 0.2 2 Galactomisses fermentation filtrate - 0.002 incense q.s. q.s. pH adjusting agent q.s. q.s. Purified water To 100 To 100

Bubble power Cleaning power Deodorizing force Rinsing power Moisturizing/
Skin protection Freshness Non-magnetic Overall
satisfaction Comparative Example 2 3.81 3.93 4.11 4.01 3.90 3.95 3.88 3.65 Example 1 4.12 4.43 4.20 4.32 3.90 3.96 3.94 3.82

The detergent composition of Example 1 was superior to the hand wash (Comparative Example 2) in terms of cleaning / rinsing properties such as foam, washing, and rinsing power, and the feeling of use such as moisturizing / skin protection, Can be confirmed.

Experimental Example 3: Evaluation of moisturizing ability of existing detergents and detergent compositions of the present invention

The moisturizing property evaluation was carried out in comparison with the existing kitchen detergent product (Comparative Example 3) containing no Galactomyces fermented filtrate as Example 1 and the kitchen detergent containing Galactomyces fermented filtrate as Example 1. Ten subjects were rinsed with detergent diluted with Habak once daily for 10 days, and washed three times (wash-off). FIG. 1 is a graph showing the results of comparing and evaluating skin moisturizing properties when Example 1 and Comparative Example 3 were used for 10 days.

As a result of evaluation, the existing kitchen detergent (Comparative Example 3) inhibited the moisturization of the skin from the 1st day (the moisturizing rate was -), whereas the composition containing the Galactomyces fermented filtrate did not inhibit skin moisturization until day 3 . In addition, the composition containing the Galactomyces fermented filtrate had a lower degree of inhibiting the moisture retention even after the fourth day than that of Comparative Example 3.

EXPERIMENTAL EXAMPLE 4 Evaluation of Usability According to Content of Galactomith Fermented Filtrate

The following experiment was carried out to determine the proper content of the Galactomyces fermentation filtrate in the detergent composition of the present invention. The content of the galactomose fermented filtrate was adjusted to 0.0001 to 10% by controlling the content of the surfactant, the controlling agent, the flavor, and other additives in the same manner as in the above Experimental Example, To evaluate moisturizing / skin protection, washing power and rinsing power.

Table 5 shows the content of Galactomyces fermented filtrate of Comparative Example 4 and Examples 2 to 7, Table 6 shows the evaluation criteria of the dish washing force, Table 7 shows the rinsing force evaluation standard, Table 8 shows the moisturizing / skin protection evaluation criteria, Table 9 The results of evaluating the usability of Comparative Example 4 and Examples 2 to 7 were shown.

Category (% by weight) Comparative Example 4 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Galactomisses fermentation filtrate - 0.0001 0.001 0.01 0.1 One 10

Criteria for evaluating dish washing power Number of dishes washed Evaluation standard sign Less than 1 Inadequate × 2 to 3 usually △ 4 to 6 Great ○ 7 or more very best ◎

Rinse power evaluation criteria Rinse water volume used (ml) Evaluation standard sign More than 500ml Inadequate × 400 ~ 500ml usually △ 300 ~ 400ml Great ○ 300ml or less very best ◎

Moisture / skin protection evaluation criteria Evaluator score average Evaluation standard sign 3.0 or less Inadequate × 3.0 to 3.5 usually △ 3.5 ~ 4.0 Great ○ 4.0 or higher very best ◎

division Comparative Example 4 Example 2 3 4 5 6 7 Cleaning power (number of dishes) ◎ ◎ ◎ ◎ ◎ ◎ ○ Rinsing power ○ ○ ○ ○ ○ ○ △ Moisturizing / Skin Protection ○ ○ ◎ ◎ ◎ ◎ ◎

In the case of Example 2, there was no increase in the moisturizing effect as compared with the comparative example, and in Example 7, the washing power and the rinsing power were lower than those of the comparative example. In the case of Examples 3 to 6, the washing power and the rinsing power were maintained and the moisture retention was increased.

Claims (10)

From 5 to 50% by weight of a surfactant based on the total weight of the composition, and from 0.001 to 1% by weight of a galactomithase fermentation filtrate. The composition of claim 1, wherein the surfactant is an anionic surfactant; And a detergent composition comprising a nonionic surfactant, an amphoteric surfactant, or a mixture thereof. The composition of claim 2, wherein the weight ratio of the anionic surfactant to the nonionic surfactant, amphoteric surfactant, or mixture thereof is 1: 0.1-10 (a nonionic surfactant, an amphoteric surfactant, Surfactant). ≪ / RTI > 3. The composition of claim 2, wherein the anionic surfactant is present in an amount of 1 to 30% by weight relative to the total weight of the composition; And 1 to 20% by weight of a nonionic surfactant, an amphoteric surfactant, or a mixture thereof. The detergent composition of claim 1, wherein the composition further comprises an electrolyte. 2. The detergent composition of claim 1, wherein the composition comprises less than 5% by weight of a water soluble protein, polymer, or mixture thereof, based on the total weight of the composition. Wherein the composition comprises from 1 to 20% by weight of alkylether sulfate, from 1 to 10% by weight alkylamine oxide, from 1 to 10% by weight alkylpolyglucoside, and from 0.001 to 1% by weight of galactomithase fermentation filtrate. The detergent composition according to claim 7, wherein the weight ratio of alkyl amine oxide and alkyl polyglucoside to alkyl ether sulfate is 1: 0.1-10 (alkylamine oxide and alkyl polyglucoside: alkyl ether sulfate). (s1) adding to the aqueous phase a non-ionic surfactant, an amphoteric surfactant, or a mixture thereof with an electrolyte and stirring;
(s2) adding an anionic surfactant to the product of step (s1) and stirring;
(s3) adding a galactomeyse fermentation filtrate to the product of step (s2) and mixing
≪ / RTI > 10. The composition of claim 9, wherein the weight ratio of the anionic surfactant to the nonionic surfactant, amphoteric surfactant, or mixture thereof is 1: 0.1-10 (a nonionic surfactant, an amphoteric surfactant, Surfactant). ≪ / RTI >

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