KR20160010401A - Support roller, method for molding glass plate, method for manufacturing glass plate, and device for manufacturing glass plate - Google Patents

Abstract

A support roll for supporting a glass ribbon on a strip plate, comprising: a rotary member in contact with the glass ribbon; a shaft member having a refrigerant passage therein and rotating together with the rotary member; Wherein the rotary member is formed of ceramics and a heat transfer member having a higher thermal conductivity than the rotary member is disposed and arranged between the protruding member and the rotary member Supporting roll.

Description

Technical Field [0001] The present invention relates to a support roll, a method of forming a glass plate, a method of manufacturing a glass plate, and an apparatus for manufacturing a glass plate.

The present invention relates to a support roll, a method of forming a glass plate, a method of manufacturing a glass plate, and a manufacturing apparatus of a glass plate.

The forming method of the glass plate has a step of forming the molten glass into a glass ribbon in the form of a strip. Glass ribbon thinner than the equilibrium thickness tends to decrease in the width direction. Thus, in order to keep the thickness of the glass ribbon at a desired thickness, a support roll which applies tension in the width direction to the glass ribbon is used (see, for example, Patent Document 1). The support rolls are used in pairs and press on both side edges of the glass ribbon. A plurality of pairs of support rolls are arranged at intervals along the moving direction of the glass ribbon. The support roll has a rotary member at its distal end which is in contact with the glass ribbon, and the rotary member is rotated, whereby the glass ribbon is fed out in a predetermined direction. The glass ribbon is gradually cooled and hardened while moving in a predetermined direction.

Japanese Laid-Open Patent Publication No. 2011-225386

Conventional rotary members are formed of a metal material and have low heat resistance. On the other hand, there is a problem that the rotating member formed of ceramics tends to be cracked by the temperature gradient.

SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and it is an object of the present invention to provide a support roll capable of suppressing cracking of a rotating member made of ceramics.

In order to solve the above problems, according to one aspect of the present invention,

A support roll for supporting a ribbon glass ribbon,

A rotating member in contact with the glass ribbon,

A shaft member having a refrigerant passage therein and rotating together with the rotary member;

And a projecting member projecting from an outer periphery of the shaft member,

The rotating member is formed of ceramics,

A support roll is provided between the protruding member and the rotary member in which a heat transfer member having a higher thermal conductivity than the rotary member is disposed.

According to one aspect of the present invention, it is possible to provide a support roll capable of suppressing cracking of the rotating member made of ceramics.

1 is a partial cross-sectional view showing a glass sheet forming apparatus according to an embodiment of the present invention.
Fig. 2 is a plan view showing a lower structure of the glass sheet forming apparatus of Fig. 1; Fig.
3 is a cross-sectional view showing a support roll according to an embodiment of the present invention.
Fig. 4 is a graph showing the time variation of the wettability of the molten glass with respect to the sintered bodies according to Examples 1 to 4; Fig.
5 is a cross-sectional view showing a rotating member according to a modification.
Fig. 6 is a view showing the dimensions of the convex shape of the rotating member of Fig. 5;
Fig. 7 is another diagram showing the dimensions of the convex shape of the rotating member of Fig. 5;
8 is a cross-sectional view showing a rotating member according to another modified example.

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the following drawings, the same or corresponding components are denoted by the same or corresponding reference numerals, and a description thereof will be omitted.

1 is a partial cross-sectional view showing a glass sheet forming apparatus according to an embodiment of the present invention. Fig. 2 is a plan view showing a lower structure of the glass sheet forming apparatus of Fig. 1; Fig.

The molding apparatus 10 forms the molten glass into a glass ribbon 14 in the form of a strip. The molding apparatus 10 includes a bath 20 accommodating a molten metal (for example, molten tin) 16, and a molten metal 16, which is continuously supplied on the molten metal 16, (X direction in Fig. 2) on the surface of the substrate 1 and formed into a strip-shaped plate. After the glass ribbon 14 is cooled in the process of flowing in a predetermined direction (X direction in FIG. 2), it is pulled up from the molten metal by the lift-out roll, is thrown in the throat furnace, And is cut into a predetermined size shape by a cutter to be a glass plate as a product.

The molding apparatus 10 includes a bath 20 for accommodating the molten metal 16, a ceiling 22 formed above the bath 20, and a side wall 22 for blocking the gap between the bath 20 and the ceiling 22, (24), and the like. A gas supply path 32 is formed in the ceiling 22 and a heater 34 as a heating source is inserted into the gas supply path 32.

The gas supply path 32 supplies a reducing gas to the space above the molten metal 16 to prevent the molten metal 16 from being oxidized. The reducing gas contains, for example, 1 to 15% by volume of hydrogen gas and 85 to 99% by volume of nitrogen gas.

A plurality of heaters 34 are formed above the molten metal 16 and the glass ribbon 14 at intervals in the moving direction and the width direction of the glass ribbon 14. [ The output of the heater 34 is controlled so that the temperature of the glass ribbon 14 decreases from the upstream side toward the downstream side. The output of the heater 34 is controlled so that the thickness of the glass ribbon 14 becomes uniform in the width direction (Y direction).

The molding apparatus 10 has a support roll 40 which is used for suppressing shrinkage in the width direction of the glass ribbon 14 in the form of a strip. The support rolls 40 are used in pairs and press the opposite side edges of the glass ribbon 14. A plurality of pairs of support rolls 40 are arranged at intervals along the moving direction of the glass ribbon 14. [ The support roll 40 has a rotary member 42 at its distal end portion that makes contact with the glass ribbon 14 and the rotary member 42 rotates so that the glass ribbon 14 is fed in a predetermined direction. The glass ribbon 14 is gradually cooled and hardened while moving in a predetermined direction.

3 is a cross-sectional view showing a support roll according to an embodiment of the present invention. The support roll 40 includes a rotary member 42, a shaft member 44, a flange 46 as a projecting member, a heat transfer member 48, a pressing member 50, a first elastic member 54, a heat insulating member 60 A seam abutting member 64, a second elastic body 66, and the like.

The rotating member 42 may be provided on the outer periphery of a gear wheel-shaped protrusion 43 that contacts the glass ribbon 14, for example, as shown in Fig. 1, in order to suppress the slip of the glass ribbon 14 . The shape of the convex portion of the projections and depressions 43 on the cogwheel is not particularly limited, but may be formed in a tapered shape (for example, a quadrangular pyramid shape) as shown in Fig. 3, for example. As shown in Fig. 1, the projections and depressions 43 on the toothed wheels are formed in a row in the thickness direction (Y direction in Fig. 1) of the outer periphery of the rotary member 42, but may be formed in a plurality of rows.

The rotary member 42 does not have a refrigerant passage therein. Since the shaft member 44 inserted into the through hole of the rotary member 42 is a member different from the rotary member 42, the refrigerant flow path 45 formed in the shaft member 44 is in contact with the rotary member 42 And is a refrigerant passage formed outside.

The rotating member 42 is formed of ceramics having higher heat resistance than metallic materials. The ceramics of the rotating member 42 is not particularly limited, but silicon carbide (SiC) ceramics, silicon nitride (Si ₃ N ₄ ) ceramics, or the like is used, for example. Silicon carbide or silicon nitride has a high resistance to the droplets of the molten metal 16 and the vapor of the molten metal 16, and is excellent in high-temperature strength and creep characteristics.

The type of the ceramics of the rotary member 42 is selected according to the kind of the glass or the like. For example, in the case of alkali-free glass, silicon nitride ceramics having excellent heat shock resistance is preferable because the glass has a high molding temperature. Silicon nitride ceramics are excellent in that they have low reactivity with alkali-free glass. On the other hand, in the case of soda lime glass, besides silicon nitride ceramics, silicon carbide ceramics or alumina ceramics can be used.

In the case of alkali-free glass, at least the portion of the rotary member 42 that contacts the glass ribbon 14 may be silicon nitride ceramics, and the entire rotary member 42 may not be silicon nitride ceramics. For example, a layer of silicon nitride ceramics may be formed on a substrate made of ceramics other than silicon nitride ceramics.

The silicon nitride ceramics may be a sintered body obtained by sintering a molded body made of a mixed powder containing a powder of silicon nitride and a powder of a sintering aid. Examples of the sintering method include a normal pressure sintering method, a pressure sintering method (including hot press sintering and gas pressure sintering), and the like. As the sintering aid, at least one selected from alumina (Al ₂ O ₃ ), magnesia (MgO), titania (TiO ₂ ), zirconia (ZrO ₂ ) and yttria (Y ₂ O ₃ ) do.

The silicon nitride ceramics preferably has a content of aluminum (Al) of 0.1 mass% or less, preferably 1 mass% or less, a content of magnesium (Mg) of 0.7 mass% or less, preferably 0.7 mass% or less, The content may be 0.9 mass% or less, preferably 0.9 mass% or less. When the Al content, the Mg content and the Ti content are in the above ranges, the reactivity between the rotating member 42 and the glass ribbon 14 is low and the rotating member 42 and the glass ribbon 14 do not adhere well, Loses. The Al content, Mg content and Ti content may each be 0 mass%.

The silicon nitride ceramics has a content of zirconium (Zr) of 3.5 mass% or less, preferably 3.5 mass% or less, a content of yttrium (Y) of 0.5 mass% or more, preferably 0.5 mass% or more, Preferably less than 10% by mass. Zr or Y is a component which does not diffuse well with the glass ribbon 14 as compared with Al, Mg, and Ti. By being contained in the above range, sintering of the silicon nitride powder can be promoted. Zr may be an optional component, and the Zr content may be 0 mass%.

The silicon nitride ceramics of the present embodiment is a sintered body obtained by a normal-pressure sintering method or a pressure sintering method, but may be a sintered body obtained by a reaction sintering method. The reaction sintering method is a method of heating a shaped body molded from powder of metal silicon (Si) in a nitrogen atmosphere. Since the reaction sintering method does not use a sintering aid, a high purity sintered body can be obtained and the durability of the sintered body to the glass ribbon 14 can be improved.

The glass plate, which is a product, is not particularly limited, but may be a flat panel display (FPD) such as a liquid crystal display (LCD), a plasma display (PDP), or an organic EL display. BACKGROUND ART [0002] In recent years, thinning of FPD has been progressing, and thinning of a glass plate for FPD is progressing. In particular, in the case of a glass substrate for a display substrate, a glass plate of preferably 0.7 mm or less, more preferably 0.3 mm or less, further preferably 0.2 mm or less, particularly preferably 0.1 mm or less is desired. As a result, the thickness of the glass ribbon 14 becomes thinner, the shrinking force in the width direction of the glass ribbon 14 becomes strong, and the forming temperature of the glass ribbon 14 becomes high. The support roll 40 of the present embodiment is disposed between the rotary member 42 and the flange 46 as a protruding member and a heat transfer member 48 having a higher thermal conductivity than the rotary member 42 is disposed It is possible to suppress cracking of the rotary member 42 and is suitable for forming a glass plate for an FPD.

The kind of the glass plate as the product is not particularly limited. The composition of the glass plate is, for example, expressed in mass% based on the oxide, and includes 50 to 75% of SiO ₂ , 0.1 to 24% of Al ₂ O ₃ , 0 to 12% of B ₂ O ₃ , 0 to 10 , 0 to 14.5% of CaO, 0 to 24% of SrO, 0 to 13.5% of BaO, 0 to 20% of Na ₂ O, 0 to 20% of K ₂ O, 0 to 5% of ZrO ₂ , + CaO + SrO + BaO: 5 to 29.5%, and Na ₂ O + K ₂ O: 0 to 20%.

The glass plate may be formed of, for example, alkali-free glass. The alkali-free glass is a glass substantially containing no alkali metal oxide (Na ₂ O, K ₂ O, Li ₂ O, etc.). In the alkali-free glass, the total content of the alkali metal oxide may be 0.1% by mass or less.

The alkali-free glass may be, for example, expressed in mass% based on the oxide, SiO ₂ 50 to 70% (preferably 50 to 66%), Al ₂ O ₃ 10.5 to 24%, B ₂ O ₃ : 0 , MgO: 0 to 10% (preferably 0 to 8%), CaO: 0 to 14.5%, SrO: 0 to 24%, BaO: 0 to 13.5%, ZrO ₂ : 0 to 5% + CaO + SrO + BaO: 8 to 29.5% (preferably 9 to 29.5%).

The alkali-free glass preferably contains 58 to 66% of SiO ₂ , 15 to 22% of Al ₂ O _{3, and} 15 to 22% of B ₂ O ₃ : SiO ₂ in terms of% by mass based on the oxide when the high distortion point and high solubility are both satisfied. 5 to 12%, MgO: 0 to 8%, CaO: 0 to 9%, SrO: 3 to 12.5%, BaO: 0 to 2% and MgO + CaO + SrO + BaO: 9 to 18%.

In order to obtain a particularly high distortion point, the alkali-free glass preferably contains 54 to 73% of SiO ₂ , 10.5 to 22.5% of Al ₂ O ₃ , B ₂ O ₃ : 0% of SiO ₂ , , CaO: 0 to 9%, SrO: 0 to 16%, BaO: 0 to 2.5%, MgO + CaO + SrO + BaO: 8 to 26%.

1, the shaft member 44 is connected to a driving device 36 which passes through the side wall 24 and is disposed outside the side wall 24. As shown in Fig. The drive unit 36 is constituted by a motor, a speed reducer, and the like, and rotates the shaft member 44 about the center line of the shaft member 44. The shaft member 44 is inserted into the through hole formed at the center of the rotary member 42 and rotates together with the rotary member 42.

The shaft member 44 may be formed of, for example, a metal material in a cylindrical shape, and has therein a refrigerant passage 45 through which refrigerant such as water passes. The refrigerant may be a fluid or air.

The flange 46 may be integrally formed with the shaft member 44. The flange 46 protrudes in the radial direction of the rotary member 42 from the outer periphery of the shaft member 44 in the middle of the shaft member 44. A branch path 47 branched from the refrigerant flow path 45 of the shaft member 44 is formed on the inner periphery of the flange 46 and the branch path 47 extends to the vicinity of the outer periphery of the flange 46. The flange 46 is cooled by the refrigerant passing through the branch passage 47.

The heat transfer member 48 is formed, for example, in a ring shape. The inner diameter of the heat transfer member 48 is larger than the outer diameter of the shaft member 44 and the heat transfer member 48 does not contact the shaft member 44. The heat transfer member 48 is positioned by the positioning groove 49 formed on the side of the flange 46 on the side of the rotary member 42. [

The heat transfer member 48 is formed between the flange 46 and the rotary member 42 and has a thermal conductivity higher than that of the rotary member 42. The heat transfer member 48 transfers the heat of the rotary member 42, (46). The outer circumference of the rotary member 42 is maintained at a temperature at which the glass ribbon 14 does not adhere to the outer circumference of the rotary member 42, thereby reducing the rotational torque.

Here, the thermal conductivity of the heat transfer member 48 and the thermal conductivity of the rotary member 42 are measured at the temperature at which the support roll 40 is used. At the operating temperature of the support roll 40, the heat conductivity of the heat transfer member 48 is preferably 30 to 200 W / (m 占 폚).

Since the flange 46 cools the heat transfer member 48 and the heat transfer member 48 cools the rotary member 42 from the side surface, The temperature gradient in the radial direction of the rotating member 42 becomes gentle, and breakage due to thermal stress of the rotating member 42 can be suppressed.

The heat conductive member 48 may have a higher thermal conductivity than the rotary member 42, and may be made of, for example, metal or carbon. The metal or carbon is softer than the ceramics, and the heat transfer member 48 and the rotary member 42 are easy to come into close contact with each other. Therefore, the contact heat resistance is low and the heat transfer efficiency is good. From the viewpoint of heat resistance, carbon is particularly preferable.

When the heat transfer member 48 is formed of the same material as the flange 46, the heat transfer member 48 and the flange 46 may be integrally formed.

The pressing member 50 presses the rotary member 42 against the heat conductive member 48 to lower the contact thermal resistance between the heat conductive member 48 and the rotary member 42. [ The pressing member 50 is disposed on the side opposite to the heat transfer member 48 with respect to the rotary member 42 as a reference.

The pressing member 50 is constituted by, for example, a pressing member main body 51 and a contact portion 52. The pressing member main body 51 is formed of, for example, metal, and the shaft member 44 is inserted into the through hole formed at the central portion of the pressing member main body 51. The contact portion 52 may be formed in a ring shape like the heat transfer member 48. The outer diameter of the contact portion 52 is larger than the inner diameter of the shaft member 44 and the contact portion 52 does not contact the shaft member 44 and the opposite side of the contact portion of the heat transfer member 48 in the rotary member 42 Press intensively. The contact portion 52 is formed of metal or carbon. From the viewpoint of heat resistance, carbon is particularly preferable. The contact portion 52 is positioned by the positioning groove 53 formed on the side of the rotation member 42 side of the pressing member main body 51. When the contact portion 52 is formed of the same material as the pressing member main body 51, the contact portion 52 and the pressing member main body 51 may be integrally formed.

The first elastic body 54 elastically supports the pressing member 50 which can be freely displaced in the axial direction of the shaft member 44 toward the rotary member 42. The first elastic member 54 is formed of, for example, a disc spring, and the shaft member 44 is inserted into the through hole formed in the first elastic member 54. The shaft member 44 has a screw shaft portion 44a and the first elastic body 54 between the first nut 58 screwed to the screw shaft portion 44a and the rotary member 42 is smaller than the natural state Respectively. The rotary member 42 is always pressed against the heat conductive member 48 by the pressing member 50 when the dimensional change occurs due to a temperature change or the like.

The first elastic body 54 of the present embodiment is constituted by a disc spring, but may be constituted by a coil spring. The configuration of the first elastic body 54 is not particularly limited. In this case, by fastening the first nut 58, the first nut 58 presses the pressing member 50, and the pressing member 50 is rotated by the rotating member 42 ) To the heat transfer member (48).

The heat insulating member 60 is formed, for example, normally. The heat insulating member 60 may be divided into a plurality of divided bodies (for example, two semi-divided bodies) in the circumferential direction in view of workability and cost.

The heat insulating member 60 is disposed between the inner periphery of the rotary member 42 and the outer periphery of the shaft member 44 and has a thermal conductivity lower than that of the rotary member 42, 44). The temperature gradient in the radial direction of the rotating member 42 becomes more gentle and breakage due to the thermal stress of the rotating member 42 can be suppressed.

Here, the thermal conductivity of the heat insulating member 60 and the thermal conductivity of the rotating member 42 are measured at the use temperature of the support roll 40. With respect to the use temperature of the support roll 40, the thermal conductivity of the heat insulating member 60 is preferably 0.01 to 30 W / (m 占 폚).

The material of the heat insulating member 60 is not particularly limited as long as the thermal conductivity is lower than that of the material of the rotary member 42, but a slate or the like is used, for example. The slate may be, for example, a natural slate made of rock such as slate, or an artificial slate mixed with a fiber material in cement.

The outer circumferential surface of the heat insulating member 60 is a contact surface that contacts the inner circumferential surface of the rotary member 42 and has a tapered shape whose diameter decreases toward the flange 46 along the center line of the rotary member 42. [ Likewise, the inner circumferential surface of the rotary member 42 is a contact surface that contacts the outer circumferential surface of the heat insulating member 60, and has a taper shape having a smaller diameter toward the flange 46 along the center line of the rotary member 42. [ Shaking between the heat insulating member 60 and the rotary member 42 can be reduced if the contact surfaces of at least one of the heat insulating member 60 and the rotary member 42 that are in contact with each other are tapered. The direction of the taper may be reversed, and each contact surface may be tapered so that the diameter increases toward the flange 46 along the center line of the rotary member 42. [

The seam abutting member 64 abuts against the center line of the heat insulating member 60 and the center line of the shaft member 44 and is formed normally for example by the inner circumference of the heat insulating member 60 and the center line of the shaft member 44 And is disposed between the outer periphery. The shaft abutment member 64 may be made of metal in the same manner as the shaft member 44. The clearance between the seam abutting member 64 and the shaft member 44 can be set to be narrow and the seam abutting member 64 and the shaft member 44 can be set to be narrow, Can be reduced.

The seam abutting member 64 serves to align the positions of the plurality of divided bodies when the heat insulating member 60 is divided into a plurality of divided bodies in the circumferential direction.

The outer circumferential surface of the seam abutting member 64 is in contact with the inner circumferential surface of the heat insulating member 60 and has a tapered shape whose diameter decreases toward the flange 46 along the center line of the rotary member 42. [ Similarly, the inner circumferential surface of the heat insulating member 60 is in contact with the outer circumferential surface of the seam abutting member 64, and is tapered so that the diameter becomes smaller toward the flange 46 along the center line of the rotary member 42. [ It is possible to reduce the shaking of the seam abutting member 64 and the heat insulating member 60 if the contact surfaces of at least one of the seam abutting member 64 and the heat insulating member 60 which are in contact with each other are tapered. The direction of the taper may be reversed, and each contact surface may be tapered so that the diameter increases toward the flange 46 along the center line of the rotary member 42. [

In the present embodiment, the seam abutting member 64 is disposed between the inner periphery of the heat insulating member 60 and the outer periphery of the shaft member 44, but the seam abutting member 64 may not be provided, There may be a slight clearance between the inner periphery of the shaft member 44 and the outer periphery of the shaft member 44. [

The second elastic member 66 is provided with a heat insulating member 60 which can freely displace in the axial direction of the shaft member 44 via a seam abutting member 64 which can freely displace in the axial direction of the shaft member 44 ) Toward the flange (46). The second elastic body 66 is constituted by, for example, a disc spring, and the shaft member 44 is inserted into the through hole formed in the second elastic body 66. The second elastic body 66 is arranged between the second nut 68 screwed to the screw shaft portion 44a of the shaft member 44 and the seam abutment member 64 in a state where the second elastic body 66 is smaller than the natural state. It is possible to prevent separation of the seam abutting member 64 and the heat insulating member 60 and to prevent separation of the heat insulating member 60 and the rotating member 42 when a dimensional change occurs due to a temperature change or the like .

The second elastic body 66 of the present embodiment is constituted by a disc spring, but may be constituted by a coil spring, and the configuration of the second elastic body 66 is not particularly limited. The second elastic body 66 comes into contact with the heat insulating member 60 and elastically supports the heat insulating member 60 toward the flange 46. [ In this case, by tightening the second nut 68, the seam abutting member 64 and the heat insulating member 60 come into close contact with each other, and the heat insulating member 60 and the rotary member 42 are in close contact with each other.

Considering the formability of the glass ribbon 14, the support roll 40 of the present embodiment is designed so that the forming range (the glass ribbon 14 has a viscosity range of 10 ^4.5 to 10 ^7.5 dPa · s (Glass ribbon 14 has a viscosity range of 10 ^4.5 to 10 ^7.65 dPa · s) and the first low temperature region (glass ribbon 14 has a viscosity range of 10 ^6.7 to 10 ^7.65 dPa · s) ^More preferably in the range of viscosity range of ^7.5 dPa · s) and in the second low temperature range (viscosity range of glass ribbon 14 of more than 10 ^7.5 to 10 ^7.65 dPa · s). In the case of alkali-free glass, the viscosity range of the glass ribbon 14 is 10 ^4.5 to 10 ^7.5 dPa s, the glass ribbon 14 corresponds to a temperature range of 946 to 1200 ° C, ^The viscosity range of ^6.7 to 10 ^7.65 dPa · s corresponds to the temperature range of 937 to 1000 ° C. of the glass ribbon 14 and the viscosity range of the glass ribbon 14 of more than 10 ^7.5 to 10 ^7.65 dPa · s , And the glass ribbon 14 corresponds to a temperature range of 937 캜 to 946 캜.

Further, the support roll 40 may be used in combination with a support roll having a general structure, or may be used in a part of a molding station, a first low temperature zone, and a second low temperature zone.

Example

In Examples 1 to 4, the relationship between the wettability of the sintered body with respect to the molten glass and the impurities contained in the sintered body was examined.

The test piece for evaluation and the test plate were manufactured by processing a sintered body of silicon nitride (Si ₃ N ₄ ) vapors different from each other.

The content of impurities in the sintered body was measured by analyzing a specimen cut out in a square shape from the sintered body by glow discharge mass spectrometry. The impurities to be measured are aluminum (Al), magnesium (Mg), titanium (Ti), zirconium (Zr), and yttrium (Y) contained as a sintering aid.

The wettability of the sintered body to the molten glass was measured by a high temperature wettability tester (WET1200, manufactured by ULVAC KK). Concretely, each glass piece of an alkali-free glass (AN100, manufactured by Asahi Glass Co., Ltd.) was placed on a test plate having a thickness of 1 mm and heated in a nitrogen atmosphere to 1150 캜 for 10 minutes and maintained at 1150 캜 for 10 minutes After the molten glass was produced, the temperature was dropped from 1150 캜 to 1050 캜 for 90 seconds and maintained at 1050 캜 to measure the contact angle of the droplet. The measurement was carried out at the time point at which the temperature was dropped to 1050 占 폚, and after 2 hours, 4 hours, 6 hours, and 8 hours from the point of time. The larger the contact angle, the less the molten glass is wetted to the sintered body, and thus the reactivity between the molten glass and the sintered body is low. Further, the smaller the change in the contact angle over time, the more easily wetting is likely to last.

The evaluation results are shown in Table 1 and Fig. 4, the vertical axis represents the contact angle (DEG), and the horizontal axis represents elapsed time (h: hours). Further, 10000 mass ppm is 1 mass%.

As is clear from Table 1 and Fig. 4, the Al content is 0.1 mass% or less, preferably less than 0.1 mass%, the Mg content is 0.7 mass% or less, preferably 0.7 mass% or less, the Ti content is 0.9 mass% Preferably less than 0.9 mass%, a Zr content of 3.5 mass% or less, preferably less than 3.5 mass%, a Y content of 0.5 mass% or more and 10 mass% or less, preferably 0.5 mass% or less and 10 mass% or less , The time change of the contact angle is small, and the contact angle after 8 hours is large, so that good durability can be obtained.

While the embodiments of the support roll, the method of manufacturing the glass plate, and the apparatus of manufacturing the glass plate have been described above, the present invention is not limited to the above embodiment. The present invention can be modified or improved within the scope of the spirit of the claims.

For example, the support roll 40 of the above embodiment is used in the float process for molding the glass ribbon 14 on the molten metal 16, but may be used in other molding processes, for example in the fusion process .

The rotary member 42 of the above-described embodiment has a gear wheel concavity on the outer periphery, but may not have a gear wheel concavity on the outer circumference. Since the refrigerant does not flow inside the rotary member, the glass ribbon is not strongly cooled in the vicinity of the rotary member, so that it is hard to be hardened. Therefore, even if there is no unevenness on the toothed wheel, the rotating member is easy to push the glass ribbon, and the shrinkage of the glass ribbon in the width direction can be suppressed.

5 is a cross-sectional view showing a rotating member according to a modification. Fig. 6 is a view showing the dimensions of the convex shape of the rotating member of Fig. 5; Fig. 7 is another diagram showing the dimensions of the convex shape of the rotating member of Fig. 5;

The rotating member 242 shown in Fig. 5 is used in place of the rotating member 42 shown in Fig. The outer circumferential surface of the rotary member 242 is a curved shape whose cross-sectional shape is convex outward in the radial direction, and the axially central portion protrudes radially outward from both axial end portions. The outer circumferential surface of the rotary member 242 has the same cross-sectional shape over the entire circumference. Since there are no concavities and convexities on the cogwheel, it is not broken well and molding and processing costs are reduced.

For example, as shown in Fig. 6, the radius of curvature Ra of the convex curved shape is preferably R1 to R100 mm, more preferably R3 to R50 mm, and R5 To R30 mm is more preferable, and R10 to R20 mm is particularly preferable. 7, the radius of curvature Rb of the axially central portion and the radius of curvature Rc of both end portions of the axial direction may be complex R in the convex curved image. At this time, the curvature radii Rb and Rc are preferably R1 to R100 mm, more preferably R3 to R50 mm, further preferably R5 to R30 mm, and particularly preferably R10 to R20 mm. Further, in the convex curved image, a flat portion may be provided on a part of the convex curved image, but a flat portion is preferable because the grip with the glass ribbon 14 is stabilized.

Considering the gripping force with the glass ribbon 14, the width d in the radial direction of the rotary member 242 in the convex curved image shown in Fig. 6 is preferably 0.5 mm or more, more preferably 1 mm or more , More preferably 2 mm or more. Similarly, the radial width d of the rotary member 242 in the convex curved image is preferably 5 mm or less, more preferably 4 mm or less.

The radius r of the rotary member 242 shown in Fig. 6 is preferably 100 mm or more in consideration of prevention of contact between the flange 46 and the glass ribbon 14 and the horizontality of the shaft member 44, More preferably not less than 180 mm and more preferably not more than 350 mm in consideration of the positional adjustment of the rotary member 242 and the glass ribbon 14 and the fine adjustment of the rotational speed of the rotary member 242, More preferably 300 mm or less, and even more preferably 270 mm or less.

The thickness w of the rotating member 242 is preferably 5 mm or more, more preferably 10 mm or more, more preferably 15 mm or more, and more preferably 30 mm or more, in view of the gripping force with the glass ribbon 14 It is preferably not more than 120 mm, more preferably not more than 100 mm, further preferably not more than 80 mm, more preferably not more than 60 mm, in consideration of improvement in flatness of the glass ribbon 14 and prevention of unnecessary increase in grip width More preferably 40 mm or less.

8 is a cross-sectional view showing a rotating member according to another modified example. The rotating member 342 shown in Fig. 8 is used in place of the rotating member 42 shown in Fig. The cross-sectional shape of the outer circumferential surface of the rotary member 342 is flat, and the rotary member 342 has a smooth boundary portion having a round cross-sectional shape between the outer circumferential surface and the side surface. The boundary portion is formed by a chamfer or the like.

In the modified example shown in Fig. 5 or the modified example shown in Fig. 8, a plurality of projections each having a height of 0.1 to 10 mm may be formed on the outer peripheral surface of the rotary member, or a plurality of grooves having a depth of 0.1 to 10 mm may be formed on the outer peripheral surface of the rotary member . Both the projection and the groove may be formed on the outer peripheral surface of the rotary member. The height of the projection and the depth of the groove are measured with the outer peripheral surface of the rotary member serving as a reference surface. The height of the projection and the depth of the groove are smaller than the radius r shown in Fig. 6, the radius of curvature Ra shown in Fig. 6, and the radius of curvature Rb, Rc shown in Fig.

The present application claims priority based on Japanese Patent Application No. 2013-104378 filed on May 16, 2013, and Japanese Patent Application No. 2013-104378 is hereby incorporated by reference in its entirety.

10: Molding device
40: support roll
42: rotating member
43: unevenness
44:
46: flange (protruding member)
48:
50: pressing member
51: pressing member main body
52:
54: first elastic body
60:
64: Seam abutment member
66: Second elastic body

Claims (15)

A support roll for supporting a ribbon glass ribbon,
A rotating member in contact with the glass ribbon,
A shaft member having a refrigerant passage therein and rotating together with the rotary member;
And a projecting member projecting from an outer periphery of the shaft member,
The rotating member is formed of ceramics,
And a heat transfer member having a higher thermal conductivity than the rotary member is disposed between the protruding member and the rotary member. The method according to claim 1,
And a pressing member for pressing the rotating member against the heat transfer member. 3. The method of claim 2,
And a first elastic body for elastically supporting the pressing member, which is freely displaceable in the axial direction of the shaft member, toward the rotating member. 4. The method according to any one of claims 1 to 3,
Wherein the shaft member is inserted into a through hole formed in the rotating member,
Wherein a heat insulating member having a thermal conductivity lower than that of the rotary member is disposed between the inner periphery of the rotary member and the outer periphery of the shaft member. 5. The method of claim 4,
Wherein a contact surface of the rotary member with the heat insulating member is tapered. The method according to claim 4 or 5,
And the contact surface of the heat insulating member with the rotary member is tapered. The method according to claim 5 or 6,
And a second elastic body for elastically supporting the heat insulating member capable of freely displacing in the axial direction of the shaft member toward the protruding member. 8. The method according to any one of claims 1 to 7,
Wherein at least a portion of the rotating member which is in contact with the glass ribbon is formed of silicon nitride ceramics. 9. The method of claim 8,
Wherein the silicon nitride ceramics is a sintered body having a content of aluminum (Al) of 0.1 mass% or less, a content of magnesium (Mg) of 0.7 mass% or less, and a content of titanium (Ti) of 0.9 mass% or less. 10. The method of claim 9,
Wherein the silicon nitride ceramics has a content of zirconium (Zr) of 3.5 mass% or less and a content of yttrium (Y) of 0.5 mass% or more and 10 mass% or less. 11. The method according to any one of claims 1 to 10,
Wherein the outer circumferential surface of the rotating member is formed in a curved shape having a convex shape in the cross-sectional shape over the entire circumference in the radial direction outward. 11. The method according to any one of claims 1 to 10,
Wherein the rotating member has a gear-like concavo-convex on its outer periphery. A method of forming a glass plate having a step of supporting a glass ribbon on a strip plate by using the support roll according to any one of claims 1 to 12. A manufacturing method of a glass plate having a step of supporting a glass ribbon on a strip plate by using the support roll described in any one of claims 1 to 12 and thereafter a step of cooling and cutting the glass ribbon . A molding apparatus for a glass plate having the support roll according to any one of claims 1 to 12.

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