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KR20120040411A - Treatment method of the tunneling waste water - Google Patents

Treatment method of the tunneling waste water Download PDF

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KR20120040411A
KR20120040411A KR1020100101810A KR20100101810A KR20120040411A KR 20120040411 A KR20120040411 A KR 20120040411A KR 1020100101810 A KR1020100101810 A KR 1020100101810A KR 20100101810 A KR20100101810 A KR 20100101810A KR 20120040411 A KR20120040411 A KR 20120040411A
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wastewater
suspended solids
tunnel
sludge
flocculant
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조중진
박원재
박정호
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(주)상산
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/02Fluid flow conditions

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  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

본 발명은 터널굴착폐수 중의 부유물질을 응집제를 사용하여 응집시켜 분리, 제거시키는 터널굴착폐수의 처리 방법에 있어서 터널굴착폐수를 공기주입구가 배설된 관형 반응기(1)에서 응결제와 반응시켜 응결반응을 개시하고 이를 관형 응집기(2) 중에서 고분자 응집조제와 반응시켜 응집반응이 완료되도록 한 후 침전조(3)에서 응집된 부유물질을 침전시켜 스럿지로 만들고 이 스럿지를 분리 제거하여 터널폐수 중의 부유물질 함량을 제거시키는 터널굴착폐수의 처리방법에 관한 것이다. 본 발명의 방법은 터널굴착폐수의 처리 시간을 단축시키고 폐수처리 설비 규모가 축소되어 생산성 향상에 기여할 수 있다.The present invention relates to a method for treating tunnel drilling wastewater in which the suspended solids in the tunnel drilling waste water are flocculated by using a flocculant and separated and removed. Initiate and react with the polymer coagulant in the tubular agglomerator (2) to complete the coagulation reaction, precipitate the flocculated suspended solids in the sedimentation tank (3) to make a sludge, and remove the sludge to remove the suspended solids content in the tunnel wastewater The present invention relates to a method for treating tunnel excavation wastewater. The method of the present invention can shorten the treatment time of the tunneling wastewater and reduce the scale of the wastewater treatment plant, thereby contributing to the improvement of productivity.

Description

터널굴착폐수의 처리 방법 {treatment method of the tunneling waste water} {Treatment method of the tunneling waste water}

본 발명은 터널굴착시 발생되는 폐수의 처리 방법에 관한 것이다. 구체적으로는 터널굴착폐수 중의 부유물질을 분리 제거하는 방법에 관한 것이다.
The present invention relates to a method for treating wastewater generated during tunnel excavation. Specifically, the present invention relates to a method for separating and removing suspended solids in tunnel drilling wastewater.

도로 건설시 터널도 다수 건설되게 되는데 터널굴착시에는 다량의 작업 용수와 화공약품이 사용되고, 분진 등 미세 토분이 지하수와 함께 배출되므로 다량의 굴착 폐수가 발생하게 된다. 터널굴착규모에 따라 차이가 있기는 하지만 굴착기간 중 매일 수백~수천kl 규모로 터널굴착폐수가 발생된다. 터널굴착폐수는 석분, 토사류 등의 무기질 물질과 콘크리트작업 중 유입되는 시멘트류의 강알칼리성 물질이 주종을 이루는 오염물질이 다량 함유되어 있어 터널굴착폐수를 외부로 배출하고자 하는 경우 폐수의 오염도를 배출이용기준에 맞도록 오염도를 낮추어 배출시켜야 한다. 우리나라의 수질 오염물질 배출기준은 수질환경 보전 및(법률 제4260호)에 따라 규제되고 있는데 폐수 배출시설에서 배출되는 오염물질의 배출허용기준은 아래와 같다.
In the construction of roads, a number of tunnels will be constructed. In tunnel excavation, a large amount of working water and chemicals are used, and a large amount of excavated wastewater is generated since fine soil such as dust is discharged together with groundwater. Although it varies depending on the size of tunnel excavation, tunnel excavation wastewater is generated on the scale of hundreds to thousands kl every day during the excavation period. Tunnel excavated wastewater contains a large amount of minerals such as stone powder, earth and sand, and contaminants that are mainly composed of strong alkaline substances in cement, which are introduced during concrete work. Pollution should be lowered and discharged to meet the standard. Korea's water pollutant emission standards are regulated according to the Water Environment Conservation Act (Law 4260), and the emission limit standards for pollutants emitted from wastewater discharge facilities are as follows.

가. 생물화학적 산소요구량, 화학적 산소요구량, 부유물질end. Biochemical oxygen demand, chemical oxygen demand, suspended solids

Figure pat00001

Figure pat00001

나. 패놀류 등 수질 오염물질I. Water pollutants such as panols

Figure pat00002

Figure pat00002

터널폐수의 부유물질 발생농도는 지역 및 작업조건에 따라 차이가 있지만 일반적으로 200~10000ppm 범위에 있으며 평균적으로 1500~3000ppm 정도인 것으로 조사된 바 있다(울산-포항 간 고속도로 건설사용 환경 영향 평가서. 한국도로공사 발행). 터널폐수는 배출허용기준에 맞추어 주기 위해서는 폐수의 산도(PH) 및 부유물질의 함량을 낮추어 주어야 한다. 부유물질의 함량을 낮추어 주기 위해서 종래에는 펌프로 뽑아낸 터널굴착폐수를 반응조로 보내고 반응조에 응집제를 투입, 응집반응을 개시하도록 한 후 응집조로 보내 응집반응을 완결시키고 이를 침전조로 보내 응집제에 의해 응집된 부유물질을 침전시켜 스럿지로 만들어주고 스럿지와 물을 여과 분리한 후 스럿지와 분리된 폐수를 외부로 배출하고 있다(도 2).The concentration of suspended solids in tunnel wastewater varies depending on the region and working conditions, but it is generally in the range of 200 ~ 10000ppm and on average 1500 ~ 3000ppm (Ulsan-Pohang Expressway, Environmental Impact Assessment. Issued by the Korea Expressway Corporation). Tunnel wastewater must lower the acidity (PH) and suspended solids content of the wastewater in order to meet the emission limits. In order to lower the content of suspended solids, conventionally, the tunnel excavated wastewater extracted by the pump is sent to the reaction tank, the coagulant is introduced into the reaction tank, and the coagulation reaction is started. The suspended solids are precipitated to make sludge, and the sludge and water are separated by filtration and the sludge and wastewater separated from the sludge are discharged to the outside (FIG. 2).

상에 종래의 폐수처리방법은 콘크리트 구조물로 된 반응조, 응집조 및 침전조 등 3개의 대형 구조물을 구비하여야 하므로 넓은 면적의 수처저장을 구비하여야 하고 응집조에서의 교반 공정으로 많은 동력비가 소요될 뿐 아니라 그 처리시간도 오래 걸리는 문제가 있다.
In the conventional wastewater treatment method, three large structures such as a reaction tank, a condensation tank, and a sedimentation tank made of concrete structures must be provided, and thus, a large area of storage must be provided, and a lot of power costs are required for the stirring process in the agglomeration tank. The processing time also takes a long time.

본 발명의 과제는 터널굴착폐수 중의 부유물질을 분리 제거하는 방법에 있어서 작은 규모의 시설을 사용하면서 저비용으로 짧은 처리시간 내에 터널굴착폐수 중의 부유물질함량을 낮추어 줄 수 있는 터널굴착폐수 처리방법을 제공하는 있다.
SUMMARY OF THE INVENTION An object of the present invention is to provide a method for treating tunneled wastewater, which can lower the content of suspended solids in tunneled wastewater within a short treatment time at a low cost while using a small-scale facility in a method for separating and removing suspended solids in tunneled wastewater. There is.

본 발명은 터널폐수 중의 부유물질을 분리, 제거하는데 있어 도 2에 도시되어 있는 전통적인 방법 즉 폐수를 콘크리트 구조물로 된 반응조에서 응집반응을 일으키게 하여 응집조로 보내어 응집조에서 응집을 완료시킨 후 침전조로 보내고 침전조에서 부유물질을 스럿지로 형성시키고 이 스럿지를 분리, 제거하는 방법을 개선하여 종래 콘크리트 반응조와 응집조 대신 파이프(pipe) 형상의 관형 반응기와 관형 응집기를 이용하여 응집반응을 진행시킨 후 응집반응이 완료된 폐수를 침전조로 보내 부유물질의 침전물을 스럿지로 만들고 이 스럿지를 분리, 제거하는 터널폐수의 처리방법에 관한 것이다.
In the present invention, in the separation and removal of suspended solids in tunnel wastewater, the traditional method shown in FIG. The flotation material is formed into sludge in the settling tank and the method of separating and removing the sludge is improved so that the flocculation reaction is carried out using a pipe-shaped tubular reactor and a tubular flocculator instead of the conventional concrete reactor and the flocculation tank. The present invention relates to a method for treating tunnel wastewater by sending the completed wastewater to the sedimentation tank to make sludge of suspended solids into sludge and separating and removing the sludge.

본 발명의 방법은 터널폐수 중의 부유물질 응집반응을 빠르게 진행시켜 줄 수 있어 폐수처리시간을 단축시키고, 대규모 반응조와 응집조의 설치가 필요없게 되며, 응집조의 운영비가 절감되며 폐수처리설비의 규모가 축소되어 생산성 향상에도 기여할 수 있는 효과가 있다.
The method of the present invention can accelerate the flocculation reaction of the suspended solids in the tunnel wastewater, thereby shortening the wastewater treatment time, eliminating the need for the installation of large-scale reactors and flocculation tanks, reducing the operating costs of the flocculation tanks and reducing the scale of the wastewater treatment facilities. Therefore, there is an effect that can contribute to productivity improvement.

도 1은 본 발명에 따른 폐수의 처리과정을 나타낸 공정도이다.
도 2는 비교예에 따른 폐수의 처리과정을 나타낸 공정도이다.
1 is a process chart showing the treatment of wastewater according to the present invention.
2 is a process chart showing a treatment process of wastewater according to a comparative example.

이하 실시예와 비교예를 들어 본 발명을 구체적으로 설명한다.
Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples.

[[ 실시예Example ]]

1일 폐수발생량 700톤(시간당 29.2㎥)인 작업현장에서 펌핑되어 배출되는 COD 185.5ppm이고 부유물질(suspended solid:이하 s.s라 한다.) 207.8ppm인 터널굴착폐수를 공기 주입구와 응집제 주입구가 배설된 구경 120mm, 길이 2m 크기인 폴리염화비닐수지 재질의 관형 반응기(1)로 도입한다.The tunnel excavated wastewater with 185.5ppm COD and suspended solids (hereinafter referred to as ss) discharged by pumping from the work site with 700 tons of wastewater generated per day (29.2㎥ per hour) is provided with air inlet and coagulant inlet. It is introduced into a tubular reactor (1) made of polyvinyl chloride resin having a diameter of 120 mm and a length of 2 m.

공기 주입구(4)를 통하여 압축공기를 0.1㎥/min의 속도로 주입하고 폴리염화알미늄(응집제)을 100ppm의 농도가 유지되도록 응집제 주입구(5)는 통하여 주입한다. 그러면 압축공기에 의한 공기방울에 의한 버블링 효과로 이송되는 폐수에 와류(whirlpool)가 형성되면서 응집제(폴리염화알미늄)와 S.S는 빠른 속도로 응집반응을 일으킨다.Compressed air is injected through the air inlet 4 at a rate of 0.1 m 3 / min and polyaluminum chloride (coagulant) is injected through the coagulant inlet 5 so as to maintain a concentration of 100 ppm. Then, whirlpool (whirlpool) is formed in the wastewater conveyed by the bubbling effect by air bubbles by compressed air, and the flocculant (polyaluminum chloride) and S.S cause the flocculation reaction at a high speed.

관형 반응기(1)를 통과한 폐수를 고분자 응집조제 주입구(6)가 구비된 구경 160m, 길이 2m인 관형 응집기(2)로 보내고 고분자 응집조제인 폴리아크릴아미드(polyacrylamide) 0.2ppm의 농도가 유지되도록 투입한다. 폐수가 관형 반응기(1)와 관형 응집기(2)를 통과한 시간은 2분이었다. 응집반응이 개시된 상기 폐수를 침전조 70㎥ 크기의 침전조(3)로 보내 응집물을 침전시켰다 폐수는 침전조에서 2시간 침전시킨다. 전체 작업시간은 2시간 2분 소요되었다. 응집스럿지를 제거한 폐수의 COD 함량은 7ppm, S.S 3.5ppm이었다. 폴리염화알미늄은 1일 70kg이 소요되고 고분자 응집조제(폴리아크릴아미이드)는 1일 1.4kg이 소요되었다.
The wastewater passed through the tubular reactor (1) is sent to a tubular agglomerator (2) having a diameter of 160 m and a length of 2 m provided with a polymer coagulant injection port (6) and maintained at a concentration of 0.2 ppm of polyacrylamide as a polymer coagulant. Insert as much as possible. The wastewater passed through the tubular reactor 1 and the tubular flocculator 2 for 2 minutes. The wastewater in which the flocculation reaction was initiated was sent to a sedimentation tank 3 having a size of 70 m 3 to precipitate the aggregate. The waste water was precipitated in the sedimentation tank for 2 hours. The entire work took two hours and two minutes. The COD content of the wastewater from which flocculated sludge was removed was 7 ppm and SS 3.5 ppm. The polyaluminum chloride took 70 kg per day and the polymer coagulant aid (polyacrylamide) took 1.4 kg per day.

[[ 비교예Comparative example ]]

1일 폐수발생량 700톤(시간당 29.2㎥)인 작업현장에서 펌핑되어 배출되는 COD 185.5ppm이고 S.S 207.8ppm인 터널굴착폐수를 2.2kw × 3.8V 용량의 교반기가 구비된 2m × 2.4m × 2m 크기의 반응조(7)로 보낸다. 폐수를 교반기(9)로 교반하면서 응집제(폴리염화알미늄)를 100ppm의 농도가 유지되도록 주입하고 16분간 교반시켜 응집반응을 진행시킨다. 응집반응이 개시된 상기 폐수를 2.2kw × 3.8V 용량의 교반기(10)가 구비된 2m × 2.4m × 2m 크기의 응집조(8)로 보낸다. 교반기(10)로 교반하면서 고분자 응집조제(폴리아크릴아미드)를 0.2ppm의 농도가 유지되도록 투입한 후 16분간 교반시켜준 후 폐수를 70㎥ 크기의 침전조(3)로 보낸다. 침전조(3)에서 2시간 침전시켜 스럿지를 분리한 후 폐수의 COD 함량은 8ppm, S.S 함량은 18ppm이었다. 상기 비교예의 설비 규모는 환경부에서 정하고 있는 오염물질의 배출 허가를 위한 배출허용 설비기준에 따른 것이다. 상기 실시예와 비교예의 폐수처리결과를 대비해 보면 아래 표 1에 나타낸 바와 같다.
COD 185.5ppm and SS 207.8ppm tunnel excavated wastewater discharged by pumping from the work site with 700 tons (29.2㎥ / hour) of wastewater per day was 2m × 2.4m × 2m with stirrer of 2.2kw × 3.8V It is sent to the reactor (7). While the wastewater is stirred with the stirrer (9), a flocculant (polyaluminum chloride) is injected to maintain a concentration of 100 ppm and stirred for 16 minutes to proceed with the flocculation reaction. The wastewater, in which the flocculation reaction is initiated, is sent to a 2m × 2.4m × 2m flocculation tank 8 equipped with a stirrer 10 having a capacity of 2.2kw × 3.8V. While stirring with a stirrer (10), a polymer coagulant (polyacrylamide) was added to maintain a concentration of 0.2 ppm, and stirred for 16 minutes, and then the wastewater was sent to a 70 m3 precipitation tank (3). After sedimentation was performed for 2 hours in the settling tank (3), the wastewater had a COD content of 8 ppm and an SS content of 18 ppm. The installation scale of the comparative example is based on the discharge allowance facility standard for permitting the discharge of pollutants determined by the Ministry of Environment. Compared with the wastewater treatment results of the Example and Comparative Example is shown in Table 1 below.

< 폐수처리결과 ><Wastewater Treatment Results> 항목Item 비교예Comparative example 실시예Example 폐수처리량 (톤/일)Wastewater Treatment Volume (tons / day) 700700 700700 폐수오염도Wastewater Pollution Degree COD(ppm)COD (ppm) 185.5.185.5. 185.5185.5 S.S(ppm)S.S (ppm) 207.8207.8 207.8207.8 처리 후 오염도Pollution degree after treatment COD(ppm)COD (ppm) 88 77 S.S(ppm)S.S (ppm) 1818 3.53.5 응집제소요량Coagulant Requirements 폴리염화알미륨Polyaluminum chloride 70kg70 kg 70kg70 kg 폴리아크릴이미드Polyacrylimide 1.4kg1.4 kg 1.4kg1.4 kg 처리시간Processing time 2시간 32분2 hours 32 minutes 2시간 2분2 hours 2 minutes

설비규모


Equipment scale
반응조Reactor 2m x 2.4m x 2m 1기2m x 2.4m x 2m 1 unit 12cm x 2m 파이프1기12cm x 2m pipe
응집조Agglomeration tank 2m x 2.4m x 2m 1기2m x 2.4m x 2m 1 unit 16cm x 2m 파이프1기1 16cm x 2m Pipe 침전조Sedimentation tank 70㎥70㎥ 70㎥70㎥ 교반기agitator 2.2kw x 3.8v 2대2 x 2.2kw x 3.8v -- 압축공기Compressed air -- 0.1㎥/min0.1㎥ / min

* 설비유지를 위한 부지 면적은 비교예의 경우 실시예에 비하여 3배 이상 소요됨.
* The site area for facility maintenance takes more than three times compared to the example in the case of the comparative example.

본 발명에서는 관형의 반응기와 관형의 응집기를 사용함으로써 펌핑되어 배출되는 폐수파이프와 관형의 반응기와 관형의 응집기를 하나의 관으로 연결사용이 가능하게 되어 터널굴착폐수를 하나의 관을 통하여 침전조까지 배출하게 되므로 작업효율을 높여줄 수 있게 된다. 하나의 라인(Line)으로 연결된 반응기에서는 밀폐된 공간에서 압축공기에 의한 버블링(bubbling) 효과로 폐수의 흐름에 와류를 일으켜 응집반응을 빠르게 진행시켜 응집반응시간을 단축시켜 줄 수 있는 이점이 있고 폐수처리설비의 규모를 작게 유지시켜줄 수 있는 이점이 있다.In the present invention, by using the tubular reactor and tubular agglomerator, the wastewater pipe and the tubular reactor and tubular agglomerator which are pumped and discharged can be connected and used as a single pipe, and the tunnel excavated wastewater is discharged to the settling tank through one pipe. It will be able to increase the work efficiency. In a reactor connected by one line, there is an advantage in that the condensation reaction can be accelerated by vortexing the wastewater flow due to the bubbling effect of compressed air in a confined space, thereby shortening the aggregation reaction time. There is an advantage that can keep the scale of the waste water treatment plant small.

관형의 반응기는 라인리엑터(Line Reactor)로, 관형의 응집기는 라인믹서(Line mixer)로 호칭될 수 있다.
The tubular reactor may be referred to as a line reactor, and the tubular aggregate may be referred to as a line mixer.

1 : 관형 반응기
2 : 관형 응집기
3 : 침전조
4 : 공기 주입구
5 : 응집제 주입구
6 : 고분자 응집조제 주입구
7 : 반응조
8 : 응집조
9, 10 : 교반기
"

Figure pat00003
" 는 폐수의 흐름 방향을 표시한 것이다.1: tubular reactor
2: tubular agglomerator
3: settling tank
4: air inlet
5: flocculant injection hole
6: injection of polymer coagulant aid
7: reactor
8: coagulation tank
9, 10: Stirrer
"
Figure pat00003
Indicates the flow direction of the waste water.

Claims (2)

터널굴착폐수 중의 부유물질을 응집제를 사용하여 응집시켜 분리, 제거시키는 터널굴착폐수의 처리 방법에 있어서, 배출되는 터널굴착폐수를 공기 주입구가 배설된 관형 반응기(1)로 이송하고 관형 반응기(1)에서 공기주입에 의해 형성되는 폐수의 와류 중에서 응집제와 반응시켜 응집반응을 개시하고 폐수를 관형 응집기(2) 중에서 고분자 응집조제와 반응시켜 응집반응이 완료되도록 한 후 침전조(3)에서 응집된 부유물질을 침전시켜 스럿지로 만들고 이 스럿지를 분리 제거하여 터널폐수 중의 부유물질함량을 제거시키는 터널굴착폐수의 처리방법
In the tunneling wastewater treatment method in which suspended solids in the tunneling wastewater are flocculated by using a flocculant, separated and removed, the discharged tunneling wastewater is transferred to a tubular reactor (1) having an air inlet and the tubular reactor (1). In the vortex of the wastewater formed by the air injection, the flocculation reaction is initiated by reacting the flocculant with the flocculant in the tubular flocculator (2), and the flocculation flotation in the settling tank (3) after the flocculation reaction is completed. Sedimentation material to make a sludge, this sludge is separated and removed to remove the suspended solids in the tunnel wastewater treatment method
제1항에 있어서 응집제가 폴리염화알미늄이고 고분자 응집조제가 폴리아크릴아미드인 터널굴착폐수의 처리방법The method of treating tunnel excavation wastewater according to claim 1, wherein the flocculant is polyaluminum chloride and the polymer flocculent aid is polyacrylamide.
KR1020100101810A 2010-10-19 2010-10-19 Treatment method of the tunneling waste water Ceased KR20120040411A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103274512A (en) * 2013-06-25 2013-09-04 遵义清顺源环保有限责任公司 Mine waste water treatment agent
CN105481155A (en) * 2015-11-11 2016-04-13 北京四海富通能源科技有限公司 Processing equipment for oil-field produced water
KR101966432B1 (en) 2018-08-31 2019-04-22 주식회사 태영건설 Digging waste water treating method having high efficiency of admixture·flock sedimentation equipment
CN110540275A (en) * 2019-09-19 2019-12-06 中铁环境科技工程有限公司 Application of hole slag material in tunnel sewage treatment
CN112158994A (en) * 2020-09-27 2021-01-01 襄阳精瑞恒业机械有限公司 Method for treating accumulated water in tunnel construction of slag raking machine

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103274512A (en) * 2013-06-25 2013-09-04 遵义清顺源环保有限责任公司 Mine waste water treatment agent
CN105481155A (en) * 2015-11-11 2016-04-13 北京四海富通能源科技有限公司 Processing equipment for oil-field produced water
KR101966432B1 (en) 2018-08-31 2019-04-22 주식회사 태영건설 Digging waste water treating method having high efficiency of admixture·flock sedimentation equipment
CN110540275A (en) * 2019-09-19 2019-12-06 中铁环境科技工程有限公司 Application of hole slag material in tunnel sewage treatment
CN112158994A (en) * 2020-09-27 2021-01-01 襄阳精瑞恒业机械有限公司 Method for treating accumulated water in tunnel construction of slag raking machine

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