KR20100067604A - Composition for the oxidative dyeing containing natural materials - Google Patents

Abstract

The present invention relates to a one-part oxidative hair dye composition containing natural ingredients, and more particularly, to a one-part oxidized hair dye composition containing one or more mixtures selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root and nasturtium. Regarding the hair dye composition according to the present invention, the hair dye composition according to the present invention contains natural ingredients, and has a significant effect on stimulating the irritation and stabilizing the scalp. It protects the hair afterwards and minimizes the feeling of damage.

Description

Composition for the oxidative dyeing containing natural materials

The present invention relates to a one-part oxidative hair dye composition containing natural ingredients, and more particularly, to a one-part oxidized hair dye composition containing one or more mixtures selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root and nasturtium. It is about.

Hair dyes are classified into permanent hair dyes, semi-permanent hair dyes, temporary hair dyes and other hair dyes depending on how long the dyed color lasts.

The permanent hair dye is generally referred to as an “oxidized hair dye”, and is a principle of displaying color by oxidation of a dye using an oxidized dye. Oxidized hair dyes are composed of one type, but are generally composed of a single dye and an oxidant. The first hair dye contains colorant dye precursors and couplers as dyes for coloring, and contains alkaline agents such as ammonia and monoethanolamine, which swell hair and promote the decomposition of hydrogen peroxide, causing oxidation. In addition, a chelating agent is used for the purpose of controlling the oxidation reaction of the dye using a reducing agent or an antioxidant and blocking the metal ions. In addition, hair conditioning agents and fragrances such as patty alcohols, surfactants or cationic polymers are included. Hydrogen peroxide contained in the oxidant, the second agent, decomposes the melanin in the hair to brighten the color of the hair and promotes the oxidation reaction of the dye.

Semi-permanent hair dyes are the principle of dyeing hair using acid dyes or basic dyes which are non-oxidizing dyes. These dyes do not undergo an oxidative polymerization reaction and are colored as themselves and are attached to the hair by ionic bonds with amino acids of the hair to dye the hair. It is relatively large in size compared to oxidized dyes and does not penetrate deep into the hair.

Temporary hair dye is a pigment or pearl is attached to the surface of the hair using a film forming agent to temporarily impart a coloring effect to the hair.

Other hair dyes include hair dyes using vegetable natural dyes such as henna, indigo and chamomile, metallic hair dyes which dye the hair by oxidation of silver nitrate and lead acetate.

The permanent hair dye is classified into a two-part oxidative hair dye and a one-type oxidative hair dye depending on the formulation. Two-part oxidizing hair dyes are divided into cream, lotion, and liquid by the first agent, and divided into creams, lotions, and liquid by the oxidant. After leaving for a certain period of time, wash it off with shampoo and dye it. In contrast, one-type oxidative hair dyes are generally in the form of powders or pastes, mixed with water at a rate just prior to use, applied to the hair, and then dyed by rinsing with shampoo after standing for a certain time.

Two-part oxidizing hair dyes generally exhibit color by causing oxidation polymerization reaction between dyes contained in one agent by mixing one agent and two agents. In addition, the melanin pigment in the hair is decomposed by the hydrogen peroxide contained in the second agent, thereby decolorizing the hair, thereby brightening the background color of the hair, thereby providing a more vivid color. On the other hand, type 1 oxidizing hair dyes are mixed with water to decompose oxidizing agents such as sodium perborate, sodium percarbonate, acetic acid peroxide, potassium permanganate and sodium peroxide, resulting in an oxidation polymerization reaction with an oxidizing dye, and the oxidant dissolves in water. Hydrogen peroxide generated as it decomposes the melanin pigment in the hair and decolorizes the hair, thereby brightening the background color of the hair.

The one-type oxidative hair dye has the advantage of not having to mix the oxidant separately and the low cost of production at low cost, but it has the advantage of enabling the oxidation polymerization before the oxidative dye penetrates into the hair size of the molecule When the increase in the dyeing in the hair is also reduced, the color persistence after dyeing is also inherent problems with the conventional two-type oxidation type hair dye.

In order to solve the above problems, the present inventors have made continuous research on the method of improving the dyeability and color persistence of the one-type oxidative hair dye, and as a natural ingredient, it is selected from green tea polysaccharide, cyanopolysaccharide, peony, lotus root and nasturtium. One or two or more mixtures have been found to have surprising effects on improving dyeability, improving color persistence, and alleviating hair damage due to dyeing, and have completed the present invention.

Accordingly, an object of the present invention is to provide a one-part oxidative hair dye composition containing a natural component capable of improving dyeing and color persistence and alleviating hair damage, and a mixed additive for an oxidative hair dye containing the natural component.

In order to achieve the above object, the present invention provides a one-part oxidized hair dye composition containing a natural component, which is one or two or more mixtures selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, and nasturtium, and an oxidizing type containing the natural component. Provided is a mixed additive for hair dye.

Hereinafter, the present invention will be described in detail.

The present invention relates to an oxidizing hair dye composition comprising an oxidizing dye precursor, a coupler, and an oxidizing agent containing an oxidizing agent.

The one-type oxidative hair dye may be powdered with one or more natural ingredients selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root and nasturtium; extract; concentrate; Or a mixture thereof; provides a one-part oxidative hair dye composition, characterized in that it is contained in the form of, wherein the natural component is further contained as a mixed additive for the oxidative hair dye.

More specifically, the present invention provides a green tea polysaccharide to an oxidative dye precursor, a coupler and a one-type oxidative hair dye including an oxidizing agent, a thickening agent, a chelating agent, a flavoring agent, a surfactant, a pH adjusting agent, a stabilizer, a dispersing oil agent, and a hair protectant. Choose from green tea polysaccharides, polysaccharides, peony, lotus root and nasturtium in mixed additives for oxidative hair dyes using one or more natural ingredients selected from polysaccharides, peony, lotus root, lotus root and mixed with oxidative hair dye. By using one or more natural ingredients to improve the dyeing to the hair to provide an oxidative hair dye composition for improving color expression and persistence.

The present invention relates to a one-part oxidizing hair dye composition comprising an oxidizing dye precursor, a coupler and an oxidizing agent, a thickener, a chelating agent, a flavoring agent, a surfactant, a pH adjusting agent, a stabilizer, a dispersing oil agent, and a hair protectant.

The one-type oxidative hair dye may be powdered with one or more natural ingredients selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root and nasturtium; extract; concentrate; Or a mixture thereof; and is characterized in that it is a one-part oxidizing hair dye composition containing in the form of.

In the green tea polysaccharide according to the present invention, after removing chlorophyll and low molecular weight polyphenols from the pulverized green tea powder by solvent extraction process, the green tea polysaccharide extract obtained by hydrothermal extraction was concentrated under reduced pressure to remove low molecular weight free protein by ultrafiltration. The final ultrafiltration concentrate was vacuum-dried the green tea polysaccharide precipitated through the precipitation reaction to obtain a green tea polysaccharide in powder form, the polysaccharide polysaccharide concentrated under reduced pressure to concentrate the extract solution added to the dried cypress leaves under ultrafiltration The molecular weight of the free protein was removed, and the final ultrafiltration concentrate was vacuum dried on the precipitated polysaccharide to obtain a powdered polysaccharide.

Peony is Paeonia belonging to the Paeoniaceae family Lactiflora varieties, whose cultivation is older than peonies, in which herbal roots are washed and dried or soaked in boiling water and dried and then dried and called peony or peony, especially the root of peony is called Peony It is called Count. The peony according to the present invention was used to grind the dried peony into a grinder, but may also be used in the form of an extract extracted using water or an organic solvent, or a mixed solvent of an organic solvent and water.

Lotus root refers to the root of the lotus which is a perennial myelin of the water lilies, the lotus root according to the present invention can be used in the form of lotus root powder prepared by grinding the dried lotus root in the grinder with an average particle size of 36 to 39 ㎛. In the present invention, 36 to 39 ㎛ size powder was used in consideration of the ease of mixing with hair dye, etc., but the present invention is not limited to particles of this size and may be smaller or larger powders, and extracted with water or organic solvent. Lotus root extract or the lotus root extract can be concentrated and used as a lotus root concentrate. The organic solvent may be one or more selected from the group consisting of ethanol, methanol, butanol, ether, ethyl acetate and chloroform, or a mixed solvent of these organic solvents and water may be used.

Nasturtium ( Eclipta prostrate ) is a perennial herb of asteraceae, 10-70 cm high. The stem grows straight and has bristles all over, and the branches come out from the lobular leaf juice, and one branch grows again at the tip of the branch. Leaves are broad-leaved, no or defoliated, very short, willow-shaped, sharp acute, 3-10 cm long, 5-25 mm wide, with firm hairs on both sides, thick veins close to the base, and fine teeth on the edges. Flowers are head-headed, 1 to 2 per acre in August to September, around 1 cm in diameter, 2 to 4.5 cm in diameter, and guns are bell-shaped, 5 mm long and 6 to 7 mm wide, but fruit ripens. By about 11 mm in diameter, there are 5 to 6 total pieces, green, long oval, and sharp. Tongue flower is white, 2.5-3 mm long, 0.4 mm butterfly, flat or divided into two. Normalization is light green with 4 corollas. Fruits ripen in black, about 2.8 mm long, snow-flaked, triangular but different in four ridges, white projections and no tubular. When the grass is broken, black juice flows down, so it is called a black fish. It grows wild in low mountains and fields in south central Japan. Outposts are wedellalactone, nicotine and coumarin compounds. The outpost contains saponins, nicotine, tannins, vitamin A, ecliptine, and various types of tripene compounds (such as α-terthienyl methanol and its acetate esters) .The leaves contain wedellalactone and demethylwedelolactone. -7-glucoside). The nasturtium according to the present invention was used to pulverize the well after drying the nasturtium well, but may also be used in the form of an extract extracted using water or an organic solvent, or a mixed solvent of an organic solvent and water.

The one-part oxidized hair dye composition of the present invention may include the natural component in a one-part oxidized hair dye or a mixed additive for an oxidized hair dye, and the natural ingredient according to the present invention is 0.01 to 50 based on the total weight of the hair dye composition. It is contained in weight percent, it is characterized by containing 0.01 to 100% by weight relative to the total weight relative to the total weight of the mixed additive.

The natural component is contained in 0.01 to 50% by weight, preferably 0.1 to 30% by weight relative to the total weight of the one-part hair dye composition. When the content of the natural product is less than 0.01% by weight, the dyeability, color persistence improvement or hair damage alleviation and irritation relaxation properties are not effectively exhibited. If the content is more than 50% by weight, the oxidation polymerization reaction of the dye is suppressed so that the color is not properly formed. It is preferable to use it in the range.

In addition, the natural component may be further contained as a mixed additive for the oxidative hair dye, the mixed additive for the oxidative hair dye contains 0.01 to 50% by weight relative to the total weight of the mixed additive, preferably 0.1 To 30% by weight. If the content of the natural product is less than 0.01% by weight is not effective in improving the dyeability, color sustainability and hair damage, if the content exceeds 50% by weight inhibits the oxidation polymerization reaction of the dye is not made properly, the above range It can be used to relieve hair damage after dyeing, it is also effective in alleviating the irritation caused by dyeing.

The one-part oxidation oxidation hair dye composition according to the present invention contains an oxidized dye precursor and a coupler, and preferably contains two or more oxidized dye precursors and a coupler.

As the oxidized dye precursor and coupler, most oxidized dye precursors and couplers currently known may be used. Such kind of oxidation dye precursor is not particularly limited, but o-aminophenol, p-aminophenol, p-phenylenediamine, toluene hydrochloride, 2,5-diamine, p-phenylenediamine hydrochloride, toluene-2 , 5-diamine, p-phenylenediamine sulfate, p-methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate and p-phenylenediamine sulfate Can be. As the coupler, 2-methyl-5-hydroxyethyl aminophenol, p-amino-o-cresol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m-phenylenediamine hydrochloride, m -Phenylenediamine, alpha -naphthol, resorcinol, 2-methylresorcinol and the like can be used. It can be used in combination with the oxidizing dye precursor to give the hair a variety of shades.

The mono-type oxidative hair dye composition of the present invention may include direct dyes or natural dyes within the scope of not impairing the object of the present invention, and the direct dyes are arianol dyes and p-nitro. Henna, -o-phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-p-phenylenediamine hydrochloride and other vegetable dyes (Henna) may be used, and as a natural dye, various raw materials such as green tea, turmeric, logwood, gardenia, cochineal, cacao, red yeast, henna and safflower may be used.

In addition, the component normally used for a hair dye can be used for the 1-type oxidation type hair dye composition of this invention within the range which does not impair the effect of this invention. For example, antioxidants, metal containment agents, solvents, surfactants, thickeners, fragrances and conditioning agents and the like are used, but are not particularly limited to those that can be commonly used in hair dyes.

Examples of the antioxidant include butyl hydroxyanisole, dibutyl hydroxytoluene, tertiary butyl hydroquinone and tocopherols. Examples of the metal blocking agent include EDTA, disodium ID, tetrasodium ID, Ethane (EDTA), pentasodium pentate, and the like. Examples of the solvent include ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol, and diethylene glycol. An activator, anionic surfactant, or nonionic surfactant may be used. As the thickener, higher alcohols having 12 to 22 carbon atoms may be used alone or in combination, and polymer thickeners, nonionic polymers and anionic polymers, and paraffins may be used. And hard flow isoparaffin and the like, and a conditioning agent may be a cationic polymer, a quaternized ammonium salt or silyl. And the like can be used.

The oxidant of the one-part type oxidation hair dye composition according to the present invention is characterized in that it is selected from the peroxide group, wherein the peroxide group is sodium perborate, sodium percarbonate, acetic acid peroxide, potassium permanganate, ammonium persulfate, potassium persulfate, peroxide At least one selected from sodium sulfate, calcium peroxide, barium peroxide and sodium peroxide can be selected and used.

The present invention is a powder of one or more natural ingredients selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, nasturtium; extract; concentrate; Or a mixture thereof; provides a hair dye set comprising a single-part oxidized hair dye or a mixed additive for an oxidized hair dye.

The present invention comprises a) powder of one or more natural ingredients selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, nasturtium; extract; concentrate; Or mixing a one-part oxidative hair dye containing 0.01 to 50% by weight relative to the total weight in the form of a mixture thereof with water;

b) applying the dye to the hair using an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed; And

c) After the dyeing the hair wrapped with a hair protection film, left at room temperature for 10 to 30 minutes to wash the dyed hair with a rinse and shampoo, and drying and treating step; using a one-type oxidative hair dye set comprising a Provide a staining method.

More specifically, the 1-part oxidative hair dye according to the present invention is mixed with water at a ratio of 1:10, and then twice the amount of hair is applied to the hair and left for 30 minutes, which is a typical hair dye leaving time, and then dyed. The washed hair is washed with a rinse agent and a shampoo, dried and finished.

In addition, the present invention comprises the steps of: a) mixing an oxidizing dye precursor, coupler, a one-part oxidizing hair dye containing an oxidizing agent with water;

b) powder the at least one natural ingredient selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, nasturtium in the hair dye; extract; concentrate; Or mixing the mixed additive for the oxidative hair dye containing 0.01 to 100% by weight based on the total weight of the mixed additive for the oxidative hair dye in the form of a mixture thereof;

c) applying the dye to the hair using an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed with the mixed additive mixed; And

d) after the dyeing the hair wrapped with a hair protection film, left for 10 to 30 minutes at room temperature to wash the dyed hair with a rinse agent and a shampoo agent, and then drying;

It provides a dyeing method using a one-part oxidation type hair dye set comprising a.

More specifically, after mixing a conventional one-part oxidative hair dye and water at a ratio of 10 g: 100 g, the amount of double the hair weight after mixing together the mixed additive for oxidative hair dye according to the present invention by 1 g. It is applied to the hair and left for 30 minutes, which is a conventional hair dye leaving time, and then the dyed hair is washed with a rinse agent and a shampoo, dried and finished.

The one-type oxidative hair dye according to the present invention contains natural ingredients, which are one or two or more mixtures selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, and nasturtium. It has a significant effect on stability and can also be pleasantly smelled by its unique scent.

The one-type oxidative hair dye according to the present invention has a high affinity for hair with natural ingredients contained in the hair dye, thereby improving the dyeing property of the hair, which is excellent in dyeing, and prevents color fading of dyed hair and sustains vivid colors. This has an excellent effect. In addition, by protecting the hair after dyeing and minimizing the feeling of damage is excellent hair damage reduction effect and has the effect of enabling natural dyeing.

The present invention will be described in more detail by the following examples and experimental examples. However, the following Examples and Experimental Examples are only for better understanding of the present invention, and the scope of the present invention is not limited by these Examples and Experimental Examples in any sense.

[ Production Example  One] Green tea polysaccharide  Produce

The green tea polysaccharide according to the present invention is dispersed in 150 L of 95% (v / v) ethanol in 10 kg of green tea powder (d50 = 100 to 100 µm) prepared by grinding, sieving and classifying dried green tea leaves by a solvent extraction process. The mixed solution prepared by stirring at room temperature was centrifuged to recover green tea residue from which chlorophyll and low molecular weight polyphenols were removed. The recovered residue was dried after repeating the solvent extraction step once. 125 L of water was added to the green tea powder from which chlorophyll and low molecular weight polyphenols were removed by the solvent extraction process, and stirred at 35 ° C. for 7 hours to proceed with hot water extraction.

The obtained green tea polysaccharide extract was filtered and recovered using a filter press, and then concentrated under reduced pressure at 62 ° C. to be 1/10 of the initial volume. Subsequently, the green tea polysaccharide concentrate was ultrafiltered (molecular weight CUT OFF: 30,000 Daltons) to remove low molecular weight free protein, and 5 times the volume of ethanol of the final ultrafiltration concentrate was gradually added at a rate of 100 ml / min to ethanol precipitation. Proceeded. The precipitated green tea polysaccharide was vacuum dried at 45 ° to obtain 250 g of green tea polysaccharide in powder form.

[ Production Example  2] Polysaccharide  Produce

The polysaccharide polysaccharide according to the present invention was washed with 10 kg of dried cypress leaves, and then extracted by stirring at room temperature for 24 hours by adding 20 L of water. The obtained extract was filtered and recovered using a filter press, and then concentrated under reduced pressure at 50 ° C. to be 1/10 of the initial volume.

Subsequently, the concentrate was ultrafiltered (molecular weight CUT OFF: 30,000 Daltons) to remove low molecular weight free protein, and 5 times the volume of ethanol of the final ultrafiltration concentrate was gradually added at a rate of 100 ml / min to proceed with ethanol precipitation. It was. The precipitated polysaccharide was vacuum dried at 45 ° to obtain 430 g of the polysaccharide polysaccharide in powder form.

[ Production Example  3] peony powder

The peony powder was prepared by drying 5 kg peony well in a grinder to an average particle size of 36 to 39 μm. In the present invention, in consideration of the ease of mixing with the hair dye, 36 to 39㎛ sized powder was used.

[ Production Example  4] Lotus root powder

5 kg of dried lotus root was ground in a mill to an average particle size of 36 to 39 μm to prepare lotus root powder. In the present invention, 36 to 39 ㎛ size powder was used in consideration of the ease of mixing with the hair dye.

[ Production Example  5] nasturtium powder

5 kg of nasturtium was well dried and then ground in a grinder to an average particle size of 36 to 39 μm to prepare a nasturtium powder. In the present invention, 36 to 39 ㎛ size powder was used in consideration of the ease of mixing with the hair dye.

 [ Example  1 to 17 and Comparative example  One]

Using the natural ingredients prepared in Preparation Examples 1 to 5 to prepare a hair dye of Examples 1 to 8 and Comparative Example 1 in the composition of Table 1.

In addition, the mixed additive for the oxidative hair dye was prepared in the composition of Table 2 using the natural ingredients prepared in Preparation Examples 1 to 5.

[ Test Example  1] Dyeability evaluation

(1) Examples 1 to 8 and the comparative evaluation of the adhesion salt hair dye composition of Example 1

In order to evaluate the dyeing power of the hair dye compositions of Examples 1 to 8 and Comparative Example 1, the one-part hair dye composition of Examples 1 to 8 and Comparative Example 1 of Table 1 was mixed with water in a 1:10 ratio. 2 times the weight of the hair was taken and evenly applied to 12 cm long human hair. Hair was used that contained about 30% of gray hair.

After the hair dye was applied to the hair, the hair was left for 30 minutes, which is a conventional hair dye leaving time, and then washed with running water using a shampoo solution for 1 minute and dried using a hair dryer. The dried hair was measured for color using a colorimeter (hunter model Labscan XE). The results were compared using the L ^* value, which is the brightness value measured by the color difference meter. The larger the L ^* value, the brighter the color. The smaller the color, the darker the color. Therefore, the smaller the L ^* value after staining, the better the dyeability.

As shown in Table 3, the natural component of one or two or more mixtures selected from green tea polysaccharide, polysaccharide, peony, lotus root, and nasturtium in the hair dye composition according to the present invention has a high affinity for hair and thus has excellent dyeing properties. I could confirm it.

(2) Evaluation of the dyeing power of the compositions of Examples 9 to 17

Evaluation of the dyeing power of the compositions of Examples 9 to 17 was measured after mixing together the composition of Examples 9 to 17 when mixing the formulation of the formulation 1 hair dye of Comparative Example 1 with water of 10 g: 100 g 2 times the weight of the hair was taken and evenly applied to 12 cm long human hair. Hair was used that contained about 30% of gray hair.

After the hair dye was applied to the hair, the hair was left for 30 minutes, which is a conventional hair dye leaving time, and then washed with running water using a shampoo solution for 1 minute and dried using a hair dryer. The dried hair was measured for color using a colorimeter (hunter model Labscan XE). The results were compared using the L ^* value, which is the brightness value measured by the color difference meter. The larger the L ^* value, the brighter the color. The smaller the color, the darker the color. Therefore, the smaller the L ^* value after staining, the better the dyeability.

As shown in Table 4, a mixed hair dye containing a natural component of one or two or more mixtures selected from green tea polysaccharide, polysaccharide, peony, lotus root, nasturtium according to the present invention in an oxidative hair dye composition composed of a one-part formulation When the additives are mixed, the natural component has high affinity to the hair, and thus it was confirmed that the dyeing is excellent.

 [ Test Example  2] color persistence evaluation

The hair dyed in Test Example 1 was added to the shampoo solution, shaken at a speed of 200 rpm for 30 minutes using a shaker, and then rinsed with running water for 1 minute and dried with a hair dryer. After drying, the L ^* value was measured using a color difference meter, and color persistence was evaluated using the ΔL ^* value, which is a difference from the brightness values of Tables 3 and 4. Smaller ΔL ^* values indicate better color persistence. The results are shown in Table 5 below.

As shown in Table 5, the hair dyed when adding the natural ingredients of one or two or more mixtures selected from green tea polysaccharide, cyanopolysaccharide, peony, lotus root, nasturtium of the present invention to the one-type oxidative hair dye or hair dye It was confirmed that the excellent color persistence of the vivid color was excellent.

[ Test Example  3] hair Feeling of damage  evaluation

In order to evaluate the hair damage of the hair dye containing the compositions of Examples 1 to 17 and Comparative Example 1 to the damage of the hair, 5 professional panel evaluated the hair dyed according to the following criteria, The results are shown in Table 6 below.

As shown in Table 6 above, when the natural component of one or two or more mixtures selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, and nasturtium of the present invention is added to a one-part type oxidizing hair dye or a mixed additive for hair dye, After dyeing, it was confirmed that the hair damage reduction effect was excellent by protecting the hair and minimizing the feeling of damage.

Claims (9)

In the oxidation type hair dye composition comprising an oxidizing dye precursor, a coupler, an oxidizing agent containing one agent type, The one-type oxidative hair dye may be powdered with one or more natural ingredients selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root and nasturtium; extract; concentrate; Or a mixture thereof; a one-part oxidizing hair dye composition, characterized in that it is contained in the form of. The method of claim 1, The natural component is a one-component oxidation type hair dye composition, characterized in that contained in 0.01 to 50% by weight relative to the total weight of the hair dye composition. The method of claim 1, The natural component is a one-part oxidative hair dye composition, characterized in that it is further contained as a mixed additive for the oxidative hair dye. The method of claim 3, wherein The natural component is a one-component oxidation type hair dye composition, characterized in that contained in 0.01 to 100% by weight based on the total weight of the mixed additive. The method of claim 1, The oxidizing agent of the hair dye composition is a one-type oxidation type hair dye composition, characterized in that selected from the peroxide group. The method of claim 5, The peroxide group is characterized in that at least one selected from sodium perborate, sodium percarbonate, acetic acid peroxide, potassium permanganate, ammonium persulfate, potassium persulfate, sodium persulfate, calcium peroxide, barium peroxide and sodium peroxide Formulation Oxidative Hair Dye Composition. Powder one or more natural ingredients selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root and nasturtium; extract; concentrate; Or a mixture thereof; a hair dye set comprising: a one-part oxidative hair dye or a mixed additive for an oxidative hair dye. a) powder of one or more natural ingredients selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, nasturtium; extract; concentrate; Or mixing the one-part oxidative hair dye containing 0.01 to 50% by weight relative to the total weight in the form of a mixture thereof with water; b) applying the dye to the hair using an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed; And c) after the dyeing the hair wrapped with a hair protection film, left for 10 to 30 minutes at room temperature to wash the dyed hair with a rinse agent and shampoo, and drying and then treating step; Dyeing method using a one-type oxidative hair dye set comprising a. a) mixing a one-part oxidizing hair dye containing an oxidizing dye precursor, a coupler and an oxidizing agent with water; b) powder the at least one natural ingredient selected from green tea polysaccharide, polysaccharide polysaccharide, peony, lotus root, nasturtium in the hair dye; extract; concentrate; Or mixing the mixed additive for the oxidative hair dye containing 0.01 to 100% by weight based on the total weight of the mixed additive for the oxidative hair dye in the form of a mixture thereof; c) applying the dye to the hair using an amount of 20 to 30 parts by weight based on 100 parts by weight of the hair to be dyed with the mixed additive mixed; And d) after the dyeing the hair wrapped with a hair protection film, left for 10 to 30 minutes at room temperature to wash the dyed hair with a rinse agent and a shampoo agent, and then drying; Dyeing method using a one-type oxidative hair dye set comprising a.