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KR20080105734A - Copper wiring formation method of semiconductor device - Google Patents

Copper wiring formation method of semiconductor device Download PDF

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KR20080105734A
KR20080105734A KR1020070053710A KR20070053710A KR20080105734A KR 20080105734 A KR20080105734 A KR 20080105734A KR 1020070053710 A KR1020070053710 A KR 1020070053710A KR 20070053710 A KR20070053710 A KR 20070053710A KR 20080105734 A KR20080105734 A KR 20080105734A
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insulating film
inter
film
forming
copper wiring
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황종택
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주식회사 동부하이텍
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76822Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc.
    • H01L21/76825Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc. by exposing the layer to particle radiation, e.g. ion implantation, irradiation with UV light or electrons etc.
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76829Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
    • H01L21/76831Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers in via holes or trenches, e.g. non-conductive sidewall liners
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76841Barrier, adhesion or liner layers
    • H01L21/76843Barrier, adhesion or liner layers formed in openings in a dielectric
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76877Filling of holes, grooves or trenches, e.g. vias, with conductive material

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

본 발명은 반도체 소자의 구리배선 형성 방법에 관한 것이다. The present invention relates to a method for forming copper wiring of a semiconductor device.

본 발명은, 기판상에 배선간절연막을 형성하는 제1단계와, 상기 배선간절연막내에 비아홀 및 트렌치를 형성하는 제2단계와, 상기 비아홀 및 상기 트렌치 내벽을 포함하는 상기 배선간절연막 표면에 대해 특정 원소의 임플란트를 실시하여 확산방지층을 형성하는 제3단계와, 상기 확산방지층상에 배리어막을 형성하는 제4단계와, 상기 비아홀 및 상기 트렌치내에 구리배선막을 매립하여 형성하는 제5단계와, 상기 배선간절연막 상부의 상기 구리배선막, 상기 배리어막 및 상기 확산방지층을 제거하는 제6단계를 포함한다. The present invention relates to a first step of forming an inter-wire insulating film on a substrate, a second step of forming a via hole and a trench in the inter-wire insulating film, and a surface of the inter-wire insulating film including the via hole and the inner wall of the trench. A third step of forming a diffusion barrier layer by implanting a specific element, a fourth step of forming a barrier layer on the diffusion barrier layer, and a fifth step of embedding a copper wiring layer in the via hole and the trench; And removing the copper wiring film, the barrier film, and the diffusion barrier layer on the inter-wire insulating film.

따라서, 배리어막의 원소가 배선간절연막내로 확산되어 유전상수를 증가시키는 것을 방지할 수 있게 되므로, 신호 지연 문제를 방지하여 제조되는 반도체 소자의 신뢰성을 향상시킬 수 있는 효과가 있다. Therefore, since the element of the barrier film can be prevented from being diffused into the inter-wire insulating film to increase the dielectric constant, it is possible to prevent the signal delay problem and to improve the reliability of the manufactured semiconductor device.

Description

반도체 소자의 구리배선 형성 방법{METHOD FOR FORMING COPPER METAL LINE OF SEMICONDUCTOR DEVICE}Copper wiring formation method of semiconductor device {METHOD FOR FORMING COPPER METAL LINE OF SEMICONDUCTOR DEVICE}

도 1a 내지 도 1g는 종래의 반도체 소자의 구리배선 형성 방법을 순차적으로 보여주는 공정 단면도, 1A through 1G are cross-sectional views sequentially illustrating a method of forming a copper wiring of a conventional semiconductor device;

도 2a 내지 도 2h는 본 발명에 따른 반도체 소자의 구리배선 형성 방법을 순차적으로 보여주는 공정 단면도이다. 2A through 2H are cross-sectional views sequentially illustrating a method of forming copper wirings of a semiconductor device according to the present invention.

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

10 : 기판 10a : 층간절연막10 substrate 10a interlayer insulating film

20 : 배선간절연막 20a : 비아홀20: interwire insulating film 20a: via hole

20b : 트렌치 22 : 확산방지층20b: trench 22: diffusion barrier layer

30 : 배리어막 40 : 구리배선막30 barrier film 40 copper wiring film

본 발명은 반도체 소자의 구리배선 형성 방법에 관한 것으로서, 더욱 상세하게는 다공성 물질로 이루어지는 배선간절연막의 표면에 대해 임플란트를 실시하여 확산방지층을 형성함으로써 추후의 고온 공정시에 인접된 박막으로부터 원소가 확 산되는 것을 차단하여 해당 배선간절연막의 유전상수 값이 증가되는 것을 방지할 수 있는 반도체 소자의 구리배선 형성 방법에 관한 것이다. BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for forming a copper wiring of a semiconductor device, and more particularly, to form a diffusion barrier layer by implanting a surface of an inter-wire insulating film made of a porous material, thereby forming elements from adjacent thin films at a later high temperature process. The present invention relates to a method for forming a copper wiring of a semiconductor device which can prevent diffusion and prevent an increase in the dielectric constant value of the inter-wire insulating film.

일반적으로, 최근 들어 반도체 소자의 고성능화가 요구되면서 기존의 알루미늄(Al) 보다 전도성이 우수한 구리(Cu)를 이용하여 금속배선을 형성하고 있으며, 구리배선의 경우에는 식각(etching) 공정을 이용한 패터닝(patterning)이 용이하지 않기 때문에 통상적인 섭트랙티브(subtractive) 패터닝 방식을 대신하여 다마신(damascene) 공정을 이용하여 패터닝하게 된다. In general, in recent years, as the performance of semiconductor devices is required, metal wires are formed using copper (Cu), which is more conductive than conventional aluminum (Al). In the case of copper wires, patterning using an etching process is performed. Since patterning is not easy, patterning is performed using a damascene process instead of a conventional subtractive patterning method.

도 1a 내지 도 1h는 종래의 구리배선 형성 방법을 순차적으로 보여주는 공정 단면도이다. 1A to 1H are cross-sectional views sequentially illustrating a method of forming a conventional copper wiring.

먼저, 도 1a와 같이, 하부배선(미도시) 및 층간절연막(10a)을 포함하는 기판(10)상에 구리배선 형성을 위한 배선간절연막(20)을 증착(deposition)하여 형성한다. First, as shown in FIG. 1A, an interwire insulating film 20 for forming copper wiring is deposited on a substrate 10 including a lower wiring (not shown) and an interlayer insulating film 10a.

그 후, 도 1b와 같이, 사진 식각 공정을 통해 해당 배선간절연막(20)의 일부를 관통되도록 제거하여 비아홀(via hole)(20a)을 형성하며, 또한 또 한 차례의 사진 식각 공정을 통해 도 1c와 같이 비아홀(20a)의 상부 일부를 제거하여 트렌치(trench)(20b)를 형성한다. Thereafter, as illustrated in FIG. 1B, a portion of the inter-wire insulating layer 20 is removed to pass through the photolithography process to form a via hole 20a, and through another photolithography process. As shown in 1c, a portion of the upper portion of the via hole 20a is removed to form a trench 20b.

물론, 비아홀(20a) 형성시에 기판(10)상의 층간절연막(10a) 부분까지 제거하여 형성하게 된다. Of course, even when the via hole 20a is formed, the portion of the interlayer insulating film 10a on the substrate 10 is removed.

그 다음, 도 1d와 같이, 비아홀(20a) 및 트렌치(20b) 내벽을 포함하는 배선간절연막(20)의 전면에 대해 배리어(barrier)막(30)을 증착하여 형성하며, 해당 배 리어막(30)은 이후 구리배선막(40) 형성시에 구리 원소의 확산을 막는 역할을 하게 되고, 통상 탄탈 나이트라이드(TaN) 또는 탄탈늄(Ta)을 이용하여 형성하게 된다. Next, as shown in FIG. 1D, a barrier film 30 is formed on the entire surface of the inter-wire insulating film 20 including the via hole 20a and the inner wall of the trench 20b, and the barrier film 30 is formed. 30 serves to prevent the diffusion of copper elements when the copper wiring film 40 is formed, and is typically formed using tantalum nitride (TaN) or tantalum (Ta).

이어서, 도 1e와 같이, 배리어막(30)상의 비아홀(20a) 및 트렌치(20b) 내부에 대해 전기화학도금법(Electro Chemical Plating : ECP)을 이용하여 구리막을 매립함으로써 구리배선막(40)을 형성한다. Subsequently, as shown in FIG. 1E, the copper wiring film 40 is formed by embedding the copper film in the via hole 20a and the trench 20b on the barrier film 30 by using electrochemical plating (ECP). do.

이때, 구리막 매립 전에 먼저 증착법 또는 전기화학도금법을 이용하여 배리어막(30)상에 다소 얇은 구리시드(seed)층(미도시)을 형성하여 이후 구리배선막(40)이 원활히 형성되도록 할 수 있다. At this time, before the copper film is embedded, a rather thin copper seed layer (not shown) may be formed on the barrier layer 30 by using a deposition method or an electrochemical plating method so that the copper wiring layer 40 may be smoothly formed thereafter. have.

그 다음, 도 1f와 같이, 배선간절연막(20) 상부에 존재하는 구리배선막(40) 및 배리어막(30)을 CMP(Chemical Mechanical polishing) 공정을 통해 제거하여 평탄화한다. Next, as shown in FIG. 1F, the copper wiring film 40 and the barrier film 30 on the inter-wire insulating film 20 are removed and planarized by a chemical mechanical polishing (CMP) process.

그 후, 도 1g와 같이, 구리배선막(40)내의 스트레스(stress)를 완화하기 위해 어닐링 열처리(annealing heat treatment)를 실시한다. Thereafter, as shown in FIG. 1G, annealing heat treatment is performed to relieve stress in the copper wiring film 40.

이로써, 최종적인 구리배선막(40)을 통해 구리배선이 완성되게 된다. As a result, the copper wiring is completed through the final copper wiring film 40.

한편, 최근 들어 반도체 소자의 고기능화 및 고집적화의 진행에 따라 디자인룰(design rule)이 작아지면서 금속배선, 즉 구리배선간의 거리도 좁아지고 있으며, 따라서 금속배선간을 절연하는 배선간절연막(20)으로 기존에 사용되던 실리콘 옥사이드(SiO2)로는 신호 지연 문제가 발생되게 된다. On the other hand, in recent years, as the semiconductor device becomes more functional and highly integrated, as design rules become smaller, the distance between metal wires, that is, copper wires, is also narrowing. Conventional silicon oxide (SiO 2 ) causes signal delay problems.

따라서, 이러한 신호 지연 문제를 해결하기 위해 배선간절연막(20)으로 다공 성(porous) 물질이어서 낮은 유전상수 값(k)을 갖는 카본 도핑 실리콘 옥사이드(carbon-doped SiO2)로 대체하여 이용하고 있다. Therefore, in order to solve such a signal delay problem, the interlayer insulating film 20 is a porous material and is replaced with a carbon-doped SiO 2 having a low dielectric constant value (k). .

그러나, 카본 도핑 실리콘 옥사이드는 결정조직 내부에 기공이 다량 존재하는 다공성 물질이므로, 구리배선막(40) 형성 후에 진행하는 어닐링 고온 공정시에 배리어막(30)인 탄탈 나이트라이드(TaN) 또는 탄탈늄(Ta)내의 원소들이 해당 배선간절연막(20)내로 확산되어 기공을 채우게 됨으로써 배선간절연막(20)의 유전상수 값을 증가시켜, 신호 지연 문제를 발생시키고, 제조되는 반도체 소자의 신뢰성을 저하시키는 문제점이 있었다. However, since the carbon doped silicon oxide is a porous material in which a large amount of pores exist in the crystal structure, tantalum nitride (TaN) or tantalum, which is the barrier layer 30 during the annealing high temperature process, which proceeds after the copper wiring film 40 is formed. Elements in (Ta) diffuse into the inter-wire insulating film 20 to fill the pores, thereby increasing the dielectric constant value of the inter-wire insulating film 20, causing signal delay problems, and lowering the reliability of the semiconductor device to be manufactured. There was a problem.

본 발명은 상기와 같은 제반 문제점을 해결하기 위하여 창안된 것으로서, 배리어막의 형성 전에 배선간절연막 표면에 대해 임플란트(implant)를 실시하여 표면측에 확산방지층을 형성함으로써 이후 고온 공정시에 배리어막내의 원소가 배선간절연막으로 확산되어 유전상수 값을 증가시키는 것을 방지할 수 있는 반도체 소자의 구리배선 형성 방법을 제공하는데 그 목적이 있다. The present invention has been devised to solve the above problems. An implant is formed on the surface of an inter-wiring insulating film before the barrier film is formed to form a diffusion barrier layer on the surface side, so that the element in the barrier film at a later high temperature process is formed. SUMMARY OF THE INVENTION An object of the present invention is to provide a method for forming a copper wiring of a semiconductor device capable of preventing the diffusion of a dielectric into the inter-wire insulating film and increasing the dielectric constant value.

본 발명의 상기 목적과 여러가지 장점은 이 기술분야에 숙련된 사람들에 의해 첨부된 도면을 참조하여 아래에 기술되는 발명의 바람직한 실시예로부터 더욱 명확하게 될 것이다.The above objects and various advantages of the present invention will become more apparent from the preferred embodiments of the invention described below with reference to the accompanying drawings by those skilled in the art.

상술한 목적을 달성하기 위한 본 발명의 반도체 소자의 구리배선 형성 방법 은, 기판상에 배선간절연막을 형성하는 제1단계와, 상기 배선간절연막내에 비아홀 및 트렌치를 형성하는 제2단계와, 상기 비아홀 및 상기 트렌치 내벽을 포함하는 상기 배선간절연막 표면에 대해 특정 원소의 임플란트를 실시하여 확산방지층을 형성하는 제3단계와, 상기 확산방지층상에 배리어막을 형성하는 제4단계와, 상기 비아홀 및 상기 트렌치내에 구리배선막을 매립하여 형성하는 제5단계와, 상기 배선간절연막 상부의 상기 구리배선막, 상기 배리어막 및 상기 확산방지층을 제거하는 제6단계를 포함한다. A method for forming a copper wiring of a semiconductor device of the present invention for achieving the above object includes a first step of forming an inter-wire insulating film on a substrate, a second step of forming a via hole and a trench in the inter-wire insulating film, and A third step of forming a diffusion barrier layer by implanting a specific element on the surface of the inter-wire insulating layer including the via hole and the inner wall of the trench, and a fourth step of forming a barrier layer on the diffusion barrier layer, the via hole and the And a fifth step of embedding a copper wiring film in the trench, and a sixth step of removing the copper wiring film, the barrier film, and the diffusion barrier layer on the inter-wire insulating film.

이하, 첨부된 도면을 참조로 본 발명의 바람직한 실시예를 상세히 설명하기로 한다. Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 2a 내지 도 2h는 본 발명에 따른 반도체 소자의 구리배선 형성 방법을 순차적으로 보여주는 공정 단면도이다. 2A through 2H are cross-sectional views sequentially illustrating a method of forming copper wirings of a semiconductor device according to the present invention.

먼저, 도 2a와 같이, 하부배선(미도시) 및 층간절연막(10a)을 포함하는 기판(10)상에 배선간절연막(20)을 형성하며, 해당 배선간절연막(20)으로는 다공성으로 저유전상수(low-k) 물질인 카본 도핑 실리콘 옥사이드(carbon-doped SiO2)가 이용되게 된다. First, as shown in FIG. 2A, an interwire insulating film 20 is formed on a substrate 10 including a lower wiring (not shown) and an interlayer insulating film 10a, and the interwire insulating film 20 is made of porous oil. Low-k carbon-doped silicon oxide (carbon-doped SiO 2 ) will be used.

그 후, 도 2b와 같이, 해당 배선간절연막(20)을 관통하도록 비아홀(20a)을 형성하고, 또한 도 2c와 같이 해당 비아홀(20a)의 상부 일부를 제거하여 트렌치(20b)를 형성한다. Thereafter, as shown in FIG. 2B, the via hole 20a is formed to penetrate the inter-wire insulating film 20, and as shown in FIG. 2C, a portion of the upper portion of the via hole 20a is removed to form the trench 20b.

다음으로, 도 2d와 같이, 비아홀(20a) 및 트렌치(20b) 내벽을 포함하는 배선 간절연막(20)의 표면에 대해 임플란트(implant) 공정을 실시하여 특정 원소를 도핑시킴으로써 표면측에 확산방지층(22)을 형성하며, 해당 확산방지층(22)은 추후의 어닐링 열처리시에 배리어막(30)의 원소가 배선간절연막(20)측으로 확산되는 것을 차단하게 된다. Next, as shown in FIG. 2D, an implant process is performed on the surface of the inter-wire insulating film 20 including the via hole 20a and the inner wall of the trench 20b to dope a specific element, thereby preventing the diffusion prevention layer ( 22), and the diffusion barrier layer 22 prevents the elements of the barrier film 30 from diffusing to the inter-wire insulating film 20 during the subsequent annealing heat treatment.

즉, 특정 원소가 이온 주입되어 배선간절연막(20) 표면측 내부의 기공들에 삽입되어 치밀한 결정구조를 형성하는 것에 의해 확산방지층(22)을 형성하게 되며, 이때 도핑되는 도펀트(dopant)로는 질소(N) 원소를 이용할 수 있고, 확산방지층(22)은 약 500Å 정도의 두께를 갖도록 형성할 수 있으며, 임플란트 공정조건은 이온주입에너지 20~300keV, 이온주입량(즉, 도즈(doze)량) 3E13~3E14atoms/㎠로 실시할 수 있다. That is, a specific element is ion-implanted to insert into the pores inside the surface side of the inter-wire insulating film 20 to form a dense crystal structure, thereby forming the diffusion barrier layer 22, wherein the doped dopant is nitrogen Element (N) may be used, and the diffusion barrier layer 22 may be formed to have a thickness of about 500 kPa, and the implant process conditions include ion implantation energy of 20 to 300 keV and ion implantation amount (ie, dose) 3E13. 3E14 atoms / cm 2.

그 다음, 도 2e와 같이, 확산방지층(22)상의 전면에 대해 배리어막(30)을 형성하며, 해당 배리어막(30)은 이후의 구리배선막(40) 형성시에 구리 원소의 확산을 막는 역할을 하며, 통상 탄탈 나이트라이드(TaN) 또는 탄탈늄(Ta)으로 형성되게 된다. Next, as shown in FIG. 2E, a barrier film 30 is formed on the entire surface of the diffusion barrier layer 22, and the barrier film 30 prevents diffusion of copper elements during subsequent formation of the copper wiring film 40. It plays a role and is usually formed of tantalum nitride (TaN) or tantalum (Ta).

그 후, 도 2f와 같이, 비아홀(20a) 및 트렌치(20b) 내부에 전기화학도금법을 이용하여 구리막을 매립함으로써 구리배선막(40)을 형성한다. Thereafter, as shown in FIG. 2F, the copper wiring film 40 is formed by embedding the copper film in the via hole 20a and the trench 20b by using an electrochemical plating method.

다음으로, 도 2g와 같이, 배선간절연막(20) 상부에 존재하는 구리배선막(40), 배리어막(30) 및 확산방지층(22)을 CMP 공정을 통해 제거하여 평탄화한다. Next, as shown in FIG. 2G, the copper wiring film 40, the barrier film 30, and the diffusion barrier layer 22 on the inter-wire insulating film 20 are removed and planarized through the CMP process.

그 다음, 도 2h와 같이, 구리배선막(40)내의 스트레스를 완화하기 위해 어닐링 열처리를 실시한다. Next, as shown in FIG. 2H, annealing heat treatment is performed to relieve stress in the copper wiring film 40.

이로써, 최종적인 구리배선막(40)을 통해 구리배선이 완성되게 된다. As a result, the copper wiring is completed through the final copper wiring film 40.

이상과 같은 본 발명에 의하면, 배리어막(30)의 형성 전에 배선간절연막(20)의 표면에 대해 임플란트 공정을 실시하여 확산방지층(22)을 형성함으로써 추후의 어닐링 열처리시에 배리어막(30)내의 원소가 배선간절연막(20)내로 확산되어 배선간절연막(20)의 유전상수 값을 증가시켜 신호 지연 문제를 발생시키고 제조되는 반도체 소자의 신뢰성을 저하시키는 것을 방지할 수 있게 된다. According to the present invention as described above, the diffusion barrier layer 22 is formed by performing an implant process on the surface of the inter-wire insulating film 20 before the barrier film 30 is formed, so that the barrier film 30 during the subsequent annealing heat treatment. Elements within the diffusion can be diffused into the inter-wire insulating film 20 to increase the dielectric constant value of the inter-wire insulating film 20, thereby preventing the signal delay problem and reducing the reliability of the manufactured semiconductor device.

이상, 상기 내용은 본 발명의 바람직한 일 실시예를 단지 예시한 것으로 본 발명의 당업자는 본 발명의 요지를 변경시킴이 없이 본 발명에 대한 수정과 변경을 가할 수 있음을 인지해야 한다.In the foregoing description, it should be understood that those skilled in the art can make modifications and changes to the present invention without changing the gist of the present invention as merely illustrative of a preferred embodiment of the present invention.

본 발명에 따르면, 배리어막의 원소가 배선간절연막내로 확산되어 유전상수를 증가시키는 것을 방지할 수 있게 되므로, 신호 지연 문제를 방지하여 제조되는 반도체 소자의 신뢰성을 향상시킬 수 있는 효과가 달성될 수 있다. According to the present invention, since the elements of the barrier film can be prevented from being diffused into the inter-wire insulating film to increase the dielectric constant, the effect of preventing the signal delay problem and improving the reliability of the manufactured semiconductor device can be achieved. .

Claims (4)

기판상에 배선간절연막을 형성하는 제1단계와, A first step of forming an inter-wire insulating film on the substrate; 상기 배선간절연막내에 비아홀 및 트렌치를 형성하는 제2단계와, Forming a via hole and a trench in the inter-wire insulating film; 상기 비아홀 및 상기 트렌치 내벽을 포함하는 상기 배선간절연막 표면에 대해 특정 원소의 임플란트를 실시하여 확산방지층을 형성하는 제3단계와, A third step of forming a diffusion barrier layer by implanting a specific element onto the surface of the inter-wire insulating film including the via hole and the inner wall of the trench; 상기 확산방지층상에 배리어막을 형성하는 제4단계와, Forming a barrier film on the diffusion barrier layer; 상기 비아홀 및 상기 트렌치내에 구리배선막을 매립하여 형성하는 제5단계와, A fifth step of embedding a copper wiring film in the via hole and the trench; 상기 배선간절연막 상부의 상기 구리배선막, 상기 배리어막 및 상기 확산방지층을 제거하는 제6단계를 포함하는 반도체 소자의 구리배선 형성 방법. And a sixth step of removing the copper wiring film, the barrier film, and the diffusion barrier layer on the inter-wire insulating film. 제 1 항에 있어서, The method of claim 1, 상기 제3단계에서, In the third step, 상기 특정 원소는 질소(N) 원소인 것을 특징으로 하는 반도체 소자의 구리배선 형성 방법. And the specific element is a nitrogen (N) element. 제 1 항 또는 제 2 항에 있어서, The method according to claim 1 or 2, 상기 제3단계에서, In the third step, 상기 임플란트 공정조건은 이온주입에너지 20~300keV, 이온주입량 3E13~3E14atoms/㎠으로 실시하는 것을 특징으로 하는 반도체 소자의 구리배선 형성 방법. The implant process conditions are the copper implantation method of the semiconductor device, characterized in that the ion implantation energy 20 ~ 300keV, ion implantation amount 3E13 ~ 3E14 atoms / ㎠. 제 1 항 또는 제 2 항에 있어서, The method according to claim 1 or 2, 상기 제3단계에서, In the third step, 상기 확산방지층은 400~600Å 두께로 형성하는 것을 특징으로 하는 반도체 소자의 구리배선 형성 방법. The diffusion barrier layer is a copper wiring forming method of a semiconductor device, characterized in that formed in a thickness of 400 ~ 600Å.
KR1020070053710A 2007-06-01 2007-06-01 Copper wiring formation method of semiconductor device Ceased KR20080105734A (en)

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