KR20070077156A - Method for producing fungicide by acidic electrolytic water composition - Google Patents
Method for producing fungicide by acidic electrolytic water composition Download PDFInfo
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- KR20070077156A KR20070077156A KR1020070061444A KR20070061444A KR20070077156A KR 20070077156 A KR20070077156 A KR 20070077156A KR 1020070061444 A KR1020070061444 A KR 1020070061444A KR 20070061444 A KR20070061444 A KR 20070061444A KR 20070077156 A KR20070077156 A KR 20070077156A
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- electrolyzed water
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 53
- 239000000203 mixture Substances 0.000 title claims abstract description 9
- 230000000855 fungicidal effect Effects 0.000 title claims description 11
- 239000000417 fungicide Substances 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000011593 sulfur Substances 0.000 claims abstract description 38
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 38
- 239000007788 liquid Substances 0.000 claims abstract description 29
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000460 chlorine Substances 0.000 claims description 12
- 229910052801 chlorine Inorganic materials 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 150000003463 sulfur Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 abstract description 9
- 239000002253 acid Substances 0.000 abstract description 6
- 230000001954 sterilising effect Effects 0.000 abstract description 6
- 238000004070 electrodeposition Methods 0.000 abstract description 5
- 239000012773 agricultural material Substances 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 3
- 230000002688 persistence Effects 0.000 abstract description 2
- 241000607479 Yersinia pestis Species 0.000 abstract 2
- 230000035699 permeability Effects 0.000 abstract 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 11
- 239000000575 pesticide Substances 0.000 description 10
- 239000000645 desinfectant Substances 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 201000010099 disease Diseases 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
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- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 244000000010 microbial pathogen Species 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 244000063299 Bacillus subtilis Species 0.000 description 2
- 235000014469 Bacillus subtilis Nutrition 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- 241000221785 Erysiphales Species 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000009313 farming Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002674 ointment Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001360526 Escherichia coli ATCC 25922 Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 239000003674 animal food additive Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
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- 229940124536 anticoccidial agent Drugs 0.000 description 1
- 239000003096 antiparasitic agent Substances 0.000 description 1
- 230000001640 apoptogenic effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000000812 cholinergic antagonist Substances 0.000 description 1
- 239000003224 coccidiostatic agent Substances 0.000 description 1
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- 150000002500 ions Chemical class 0.000 description 1
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- 238000009533 lab test Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- HSMVPDGQOIQYSR-UHFFFAOYSA-N n-[4-chloro-2-(trifluoromethyl)phenyl]-1-imidazol-1-yl-2-propoxyethanimine Chemical compound C1=CN=CN1C(COCCC)=NC1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
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- 235000013311 vegetables Nutrition 0.000 description 1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
- C02F2001/46185—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Hydrology & Water Resources (AREA)
- Electrochemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
물에 전해조제를 첨가하고 이를 전기분해하여 얻어지는 산성전해수는 차아염소산을 함유하고 있어 작물 병해균을 제어할 수 있는 주요 친환경농자재로 사용되나, 작물에의 전착성, 침투성, 유효성분의 지속성 등이 약하여 방제효과가 부족하였다. 본 발명은, 이를 개선하기 위한 것으로서 전기의 산성전해수에 본 발명의 액상유황을 가하여 살균력을 대폭 상승시킨 전해수조성물을 제공함으로서 이의 사용으로 병해방제효과를 높여 고 품질, 고 소득의 친환경농업을 영위할 수 있게 한다.Acid electrolyzed water obtained by adding electrolytic aid to water and electrolyzing it is used as a major eco-friendly agricultural material that can control crop pests because it contains hypochlorous acid, but the electrodeposition to crops, permeability, persistence of active ingredients, etc. It was weak and lacked control effect. The present invention provides an electrolytic water composition which significantly increases sterilization power by adding the liquid sulfur of the present invention to an electric acidic electrolyzed water to improve this, thereby increasing the pest control effect and operating eco-friendly agriculture of high quality and high income. To be able.
Description
도 1은 본 발명의 산성전해수 조성물의 제조에 사용되는 전해수생성장치를 설명하기 위한 구성도1 is a block diagram for explaining the electrolytic water generating device used in the production of the acidic electrolytic water composition of the present invention
도 2는 본 발명의 액상유황의 제조방법을 나타내는 개략도Figure 2 is a schematic diagram showing a method for producing liquid sulfur of the present invention
(도면의 주요부분에 대한 부호설명)(Code description of main parts of drawing)
10...급수관, 11...급수펌프, 12...유량조절변, 23,43...전자변, 13...유량센서, 14..피전해수도입관, 21...전해조제, 22,42...정량펌프, 24...전해조제공급관, 30...유격막전해조, 31..음극, 32...양극, 33...이온투과격막, 34,35...전극실, 36...알칼리수도출관, 37...산성수도출관, 38...역지변, 40...액상유황탱크, 41...액상유황, 44...액상유황공급관, A, B...혼합부10 ... water supply pipe, 11 ... water supply pump, 12 ... flow control valve, 23,43 ... electronic valve, 13 ... flow sensor, 14 .... , 22,42 quantitative pumps, 24 electrolyte feed tubes, 30 diaphragm electrolyzers, 31 cathodes, 32 anodes, 33 ion-permeable membranes, 34, 35 Electrode chamber, 36 alkaline water pipe, 37 acid water pipe, 38 reverse valve, 40 liquid sulfur tank, 41 liquid sulfur, 44 liquid sulfur supply pipe, A, B ... mixing part
본 발명은 농작물 병해 방제용 살균제 제조방법에 관한 것으로, 상세하게는 물을 전기분해하여 생성되는 산성전해수의 조성물에 의한 살균제 제조방법에 관한 것이다.The present invention relates to a method for producing a fungicide for controlling crop diseases, and more particularly, to a method for producing a fungicide using a composition of acidic electrolyzed water produced by electrolysis of water.
물을 전기분해하면, 양극 측에서는 산성전해수가 생성되고, 음극 측에서는 알카리성전해수가 생성된다. 그중 물에 소금이나 염화칼륨을 첨가하여(0.2％이하) 전해한 pH가 2.7이하인 산성전해수는 차아염소산(HOCl)을 함유하고 있어 세균, 곰팡이, 바이러스 등 미생물을 순식간에 살균할 수 있는 성능이 있기 때문에 식품산업의 위생관리를 위한 소독제, 농업분야의 작물병해를 일으키는 병원성 미생물의 제어에 이용되고 있다. 특히, 산성전해수는 인체에 거의 무해하고, 잔류성이 없기 때문에 채소, 과일, 화훼 등 농업분야에 있어 친환경농산물을 생산할 수 있는 농자재로서 용도가 확대되고 있다. 그러나 병원성 미생물의 살균과 병해발생 예방을 위하여 작물의 잎과 줄기에 산성전해수를 살포하게 되면 잎과 줄기의 큐티클층 으로 인해 잎과 줄기를 충분히 적시지 못하고 흘러 떨어지게 되고 붙어있는 것도 곧 햇빛과 공기에 분해되어 지속성이 유지되지 못하기 때문에 , 산성전해수는 강한 살균력을 가지고 있음에도 불구하고 농약살균제에 비하여 방제가가 낮게 나타나는 문제점이 있었다.When water is electrolyzed, acidic electrolyzed water is produced on the anode side, and alkaline electrolyzed water is produced on the cathode side. Among these, acidic electrolyzed water with salt or potassium chloride (less than 0.2%) and electrolyzed pH of 2.7 or less contains hypochlorous acid (HOCl), which has the ability to sterilize microorganisms such as bacteria, fungi and viruses in an instant. It is used for disinfectant for hygiene management of food industry and control of pathogenic microorganisms causing crop diseases in agriculture. In particular, acidic electrolyzed water is almost harmless to the human body and has no residual property, and thus its use is expanding as an agricultural material capable of producing eco-friendly agricultural products in agricultural fields such as vegetables, fruits, and flowers. However, when acidic electrolytic water is sprayed on the leaves and stems of the pathogens to prevent pathogenic microorganisms and prevent disease, the cuticle layers of the leaves and stems do not wet the leaves and stems sufficiently, and they fall on the sunlight and air. Since the decomposition is not sustained, the acidic electrolyzed water has a problem that the control value is lower than the pesticide disinfectant despite the strong sterilizing power.
산성전해수에 의한 오이 흰가루병 방제효과시험을 예로 들면 산성전해수를 7일 간격으로 살포한 시험구와 농약살균제(표준 : 트리후민 2,000배)를 7일 간격으로 살포한 시험구의 방제가를 비교하여 보면 전자는 58.1, 후자는 93.4로서 산성전해수 살포구와 농약 살포구간에 큰 차이가 있음을 알 수 있다.For example, the control effect of cucumber powdery mildew caused by acidic electrolyzed water is compared with the control value of the test sprayed with acidic electrolyzed water every 7 days and the test sprayed with pesticide disinfectant (standard: 2,000 times of trifumin) every 7 days. The latter, 93.4, shows a significant difference between acidic electrolyzed water spray and pesticide spray.
이를 개선하기 위한 대안으로 산성전해수를 좀 더 자주 3일 간격으로 살포하는 방법, 농약살균제를 표준량의 1/2정도로 감소하여 산성전해수에 첨가하여 시용하는 방법, 산성전해수의 작물표면에 부착전개를 위하여 전착제를 첨가하여 시용하 는 방법 등이 사용되고 있다. 산성전해수에의 농약 1/2혼용 사용은 농약살균제 표준량 시용에 비하여 열등한 방제효과를 보였지만 일반 물에의 1/2혼용보다는 우수한 효과를 나타내어, 저농약 농산물생산 방법으로는 유효하였지만 무농약 친환경농산물을 생산하는 것에는 미치지 못하고, 산성전해수를 3일 간격으로 살포하면 방제가가 81.4로 상승하여 비교적 높은 효과를 나타내었으나 잦은 살포에 따른 관리의 어려움과 과습에 의한 성장장애 등의 역효과가 발생할 수 있는 단점이 있으며, 전착제의 첨가는 산성전해수를 작물의 표면에 전착시켜 주는 작용에 의하여 2∼3％의 방제가가 상승할 뿐 뚜렷한 개선 효과를 나타내지 못하고 있다.As an alternative to improve this, the acidic electrolyzed water is sprayed more frequently every 3 days, the pesticide disinfectant is reduced to about half of the standard amount and added to the acidic electrolyzed water, and the acidic electrolyzed water is applied to the crop surface. The method of adding and applying an electrodeposition agent is used. Mixed use of pesticides in acidic electrolyzed water showed inferior control effect compared to the standard application of pesticide disinfectant, but showed superior effect than mixed in 1/2 of general water, which was effective as a method for producing low pesticide agricultural products, but produced no pesticide-friendly agricultural products. However, if the acidic electrolyzed water is sprayed every 3 days, the control value is increased to 81.4, which shows a relatively high effect, but there are disadvantages such as difficulty in management and frequent impairment of growth due to excessive humidity. The addition of the electrodeposition agent did not show a noticeable improvement effect as the control value of 2% to 3% increased due to the action of electrodepositing the acidic electrolyzed water on the surface of the crop.
본 발명은 상기와 같은 문제점을 해결하기 위하여 안출된 것으로서, 인체에 독성이 극히 약하거나 전무하지만 병원성 미생물에는 살균효과가 있는 물질을 산성전해수에 첨가함으로서, 산성전해수에 함유된 차아염소산 등의 유효염소와 전기의 물질에 의하여 살균의 상승효과와 지속성을 유지시켜 주어 산성전해수의 살포회수를 감소시키고, 안전한 농작물을 생산을 보증할 수 있으며 농약살균제 수준의 방제가를 얻을 수 있는 산성전해수 조성물에 의한 살균제 제조방법을 제공하는 것을 목적으로 한다.The present invention has been made in order to solve the above problems, by adding a substance having a bactericidal effect to the pathogenic microorganisms to the acidic electrolyzed water, which is extremely weak or non-toxic to the human body, effective chlorine such as hypochlorous acid contained in the acidic electrolyzed water Sterilizer by acidic electrolyzed water composition which can maintain the synergistic effect and persistence of sterilization by reducing the electric acid and electricity, reduce the number of times of spreading of acidic electrolyzed water, guarantee the production of safe crops and obtain the control value of pesticide disinfectant It is an object to provide a manufacturing method.
상기와 같은 목적을 달성하기 위하여, 본 발명에 의한 살균제는 물을 전기분해하여 생성된 산성전해수를 유효성분으로 하고, 전기의 산성전해수에 계면활성제가 투입된 액상유황제제를 첨가함에 의하여 제조된다. 즉, 본 발명은 물을 전기분 해하여 산성전해수를 얻는 공정과 전기의 액상유황제를 얻는 공정과 전기 산성전해수에 전기의 액상유황제제를 첨가하여 전기 산성전해수의 표면장력을 낮추어 작물의 잎과 줄기에 전착하기 쉽게 하고, 살균력을 상승시키는 것을 특징으로 하는 살균제의 제조방법을 제공하는 것이다.In order to achieve the above object, the disinfectant according to the present invention is prepared by adding an acidic electrolyzed water produced by electrolyzing water as an active ingredient and adding a liquid sulfur agent in which a surfactant is added to the acidic electrolyzed water. That is, the present invention is a process of obtaining an acidic electrolyzed water by electrolyzing water and a process of obtaining an electrically liquid sulfur agent and adding an electrically liquid sulfur agent to the electrically acidic electrolyzed water to lower the surface tension of the electrolytic acidic electrolyzed water, It is to provide a method for producing a fungicide, characterized in that the electrodeposition to the stem easy to increase, sterilizing power.
본 발명에 공하는 산성전해수는 0.05∼0.1％의 소금이나 염화칼륨 용액을 전해하여 양극 측에서 생성되는 것으로, pH 2.7 이하, 유효염소량이 적어도 30∼50ppm(mg/ℓ)인 것이 바람직하다. 유효염소량이 50ppm이상이면 작물에 산화적 손상을 입힐 수 있고, 그 이하이면 살포시의 공기접촉에 의한 차아염소산의 분해로 인해 살균력이 약화될 수 있다.The acidic electrolyzed water according to the present invention is produced on the anode side by electrolysis of 0.05 to 0.1% of salt or potassium chloride solution, and preferably has a pH of 2.7 or less and an effective amount of at least 30 to 50 ppm (mg / L). If the effective chlorine amount is 50ppm or more, it may cause oxidative damage to the crop, and if it is less than that, the sterilizing power may be weakened due to decomposition of hypochlorous acid by air contact during spraying.
본 발명에 공하는 액상유황은 유황원광을 분쇄하여 침전법, 기화법 또는 세정법에 의하여 불순물과 비소와 같은 독성물질이 제거되어 99.5％이상의 순도를 갖는 유황을 0.1∼ 0.2미크론의 나노급으로 분쇄하여 계면활성제를 첨가하여 유황이 1 ∼ 2％ 함유된 코로이드 상의 용액을 지칭하는 것이다.Liquid sulfur according to the present invention is pulverized sulfur ore to remove toxic substances such as impurities and arsenic by precipitation method, vaporization method or washing method, sulfur having a purity of 99.5% or more to 0.1-0.2 micron nano-grade The addition of a surfactant refers to a solution of the colloidal phase containing 1-2% of sulfur.
상기의 방법으로 제독된 유황은 인체의 개선(옴)치료제로, 동물에게는 피부용 기생충박멸 연고제, 경구투여용으로는 변통약, 항콕시듐제 등으로 사용되고 있으며, 일부 한방에서는 변통약으로 사람에게 투여되기도 하는 것으로 적정한 처방은 인체에 해를 가져다주지 아니하는 물질이다.Sulfur detoxified by the above method is used as an ointment for the improvement of the human body, and it is used as an antiparasitic ointment for skin parasites for animals, and as an antispasmodic drug for anti-oral administration, and an anticoccidial agent. Proper prescription is a substance that does not harm the human body.
유황은 사료첨가물과 친환경농자재로 등록되어 있다.Sulfur is registered as a feed additive and eco-friendly agricultural material.
본 발명자가 시험기관에 의뢰한 전기 액상유황의 살균시험에 의하면 대장균(E. COli ATCC 25922)은 1ppm의 용액에서 30초 이내에 99.8％, 10ppm에서 99.9％이 상이 살균되었고, 황색포도상구균((S. aureus ATCC6538)은 1ppm 용액에서 30초 이내에 99.8％, 20ppm에서 99.9％이상이 살균되는 제균 효과를 나타내었으나, 작물병해를 유발하는 사상균과 고초균 등 아포형성균은 30ppm 용액에서 5분이 경과하여도 제균효과가 발현되지 않았다. 실험실적 시험에서는 5분 이내에서 99.9％이상의 살균효과가 발현되지 않으면 유효한 살균제로 인정되지 않는다.According to the electric liquid sulfur sterilization test commissioned by the present inventors, E. coli ATCC 25922 was sterilized in 99.8% and 10.9 % at 10 ppm in 1 ppm of solution, and Staphylococcus aureus (( S aureus ATCC6538) showed the bactericidal effect of 99.8% and 19.9% at 20ppm in 1ppm solution, but the apoptotic bacteria such as filamentous fungi and Bacillus subtilis caused 5 minutes in 30ppm solution In the laboratory test, if more than 99.9% of bactericidal effect is not expressed within 5 minutes, it is not recognized as an effective bactericide.
그러나 전기의 액상유황을 전기의 산성전해수로 희석할 경우 30ppm에서 사상균과 고초균 등이 1분이내에 99.9％이상 살균되는 효과를 보였다.However, when diluting the liquid liquid sulfur with acidic acidic electrolytic water, the fungus and Bacillus subtilis were sterilized more than 99.9% within 1 minute at 30ppm.
상기의 시험데이터에 의하여 본 발명의 살균제에는 안전치를 고려하여 유황함량이 40ppm이상 함유되도록 하였다.According to the test data described above, the fungicide of the present invention was considered to have a sulfur content of 40 ppm or more.
전기 액상유황을 제조하기위하여 투입되는 계면활성제는 전기 산성전해수의 성상에 영향을 미치지 아니하는 것을 선택하는 것이 바람직하다. 음이온계, 양이온계 계면활성제는 산성전해수의 유효염소 농도와 산화환원전위(ORP: Oxidation Reduction Potential)를 저하시키는 경향을 보였으나, 비이온계는 그러하지 아니하였다. 비이온계 중에서는 트윈 80(Poly oxyethylene sorbitan mono-oleate)이 식품첨가물로 인가되어 있고, 적은 량으로도 계면활성이 높아 최적이었다. 전기 계면활성제는 액상유황을 콜로이드 상으로 유지하는데 에도 효과를 주지만, 산성전해수를 작물에 살포하였을 시 전착효과를 높이는 작용을 하게 된다. 본 발명의 살균제에는 계면활성제가 적어도 1ppm 이상 함유토록 하였다.It is preferable that the surfactant added to prepare the electrolytic sulfur does not affect the properties of the electrolytic acid. Anionic and cationic surfactants tended to lower the effective chlorine concentration and acid reduction potential (ORP) of acidic electrolyzed water, but nonionics did not. Among the nonionics, Tween 80 (Poly oxyethylene sorbitan mono-oleate) was applied as a food additive and it was optimal because of its low surface activity. Electrical surfactants are also effective in maintaining liquid sulfur in the colloidal phase, but when the acidic electrolyzed water is sprayed on the crop, it increases the electrodeposition effect. The fungicide of the present invention contained at least 1 ppm or more of surfactant.
전기의 액상유황을 전기의 산성전해수에 첨가함에 의하여 성상을 조사한 바 살균효과를 나타내는 유효염소, 산화환원전위 및 pH에 하등의 영향을 미치지 아니 하였다.The addition of the above-mentioned liquid sulfur to the acidic electrolyzed water showed no effect on the effective chlorine, redox potential, and pH.
이하, 본 발명의 실시 예를 도면을 참조하여 상세히 설명한다.Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
도 1은 본 발명에 따른 전해수생성장치와 생성된 산성전해수예 액상유황을 첨가하여 산성전해수조성물을 제조하는 구성도이고, 도 2는 액상유황을 제조하는 방법에 관한 것이다.1 is a configuration diagram for preparing an acidic electrolyzed water composition by adding an electrolytic water generating device according to the present invention and the resulting acidic electrolytic water example liquid sulfur, Figure 2 relates to a method for producing a liquid sulfur.
도시 된 바와 같이 전해수생성장치의 전원스위치(도시되지 않음)를 켜면, 원수용 급수펌프11 전 해조제액펌프22가 가동되어 전해조제액21이 혼합희석부23에서 원수에 첨가된다. 전해조제액으로는 일가염화물인 염화나트륨(NaCl)이나 염화칼륨(KCl)의 10％ ∼ 포화수용액이 사용되며 바람직한 농도는 20％내외이다. 농작물 재배에는 알칼리성전해수가 토양 관주용으로 사용되는데, 염화나트륨을 전해조제로 사용하면 나트륨이온이 알칼리성전해수에 함유되어 작물에 나쁜 영향을 주기 때문에 농작물 재배용 전해수생성에는 염화칼륨을 전해조제액으로 한다. 원수에 전해조제액이 첨가된 피전해수의 전해조제액의 농도는 0.05 ∼ 0.1％가 바람직한 수준이다.When the power switch (not shown) of the electrolytic water generating device is turned on as shown, the raw water feed pump 11 electrolytic solution pump 22 is activated so that the
피전해수는 피전해수도입관14을 통하여 전해조30에 유입된다. 전기의 전해조는 이온투과격막33에 의하여 양분 구획되어 있고 각각의 구획실에는 양극32과 음극31이 식설되어 있다.유량센서13는 피전해수도입관14을 흘러 전해조30에 유입되는 피전해수의 유량을 감지한다.The electrolyzed water is introduced into the
전해조30에 공급된 피전해수는 직류전원을 가하면 양극32이 식설되어 있는 양극실35에서 전해되어 염화칼륨의 염소이온(Cl-)은 양극32에 전자를 내어주고 산 화되어 염소(Cl2)가 되고, 염소가 물에 용해되어 차아염소산(HOCl)과 염산(HCl)이 생성되어 양극실35로부터 도출관37을 통하여 도출되는 산성전해수는 pH 2.2 ∼ 2.7, 유효염소량이 20 ∼ 120ppm인 차아염소산수가 되어 살균기능을 갖게 된다.The electrolyzed water supplied to the
2Cl- → Cl2 + 2e- , Cl2 + H2O → HOCl + HCl2Cl- → Cl2 + 2e-, Cl2 + H2O → HOCl + HCl
본 발명에 공하는 산성전해수의 적정 유효염소량은 30ppm내외로서, 이의 농도는 전해조제액 및 원수의 공급량 조정에 의하여 달성된다.The appropriate effective chlorine amount of the acidic electrolyzed water according to the present invention is about 30 ppm, and its concentration is achieved by adjusting the supply amounts of the electrolyte preparation and the raw water.
도 2에 도시된 바와 같이 본 발명에 의하여 조제된 액상유황41은 액상유황탱크40에 저장하여 두었다가 전해수생성장치의 운전개시와 동시에 액상유황펌프42가 작동되게 하여, 액상유황41이 액상유황공급관44을 통해 도출관37으로 도출되는 산성전해수와 혼합부A에서 혼합되어 주출관44를 통해 살균제탱크50에 취수된다.As shown in FIG. 2, the liquid sulfur 41 prepared according to the present invention is stored in the
유효염소량이 30∼50ppm인 산성전해수를 분당 2.5ℓ씩 생성되도록 한 전해수생성장치에서, 본 발명의 살균제에 유황이 40ppm 함유되도록 하기위해 서는 유황함량이 1％인 액상유황51을 조제하여 이를 분당 10㎖씩 액상유황펌프42로 산성전해수 도출관37에 공급되어야 한다. 그리고 본 발명의 살균제에 1ppm의 계면활성제가 함유되기 위해서는 액상유황에 250ppm이상의 계면활성제가 투입되어야 한다.In the electrolyzed water generator, which produces 2.5 liters of acidic electrolyzed water having an effective chlorine content of 30 to 50 ppm per minute, in order to contain 40 ppm of sulfur in the fungicide of the present invention, a
또한 본 발명의 액상유황은 콜로이드 분산상을 유지하여 유황의 침전을 방지하고, 병원성미생물과의 접촉을 최대한 높이기 위해서는 0.1∼0.2미크론 정도로 극세화하는 것이 바람직하다.In addition, the liquid sulfur of the present invention is preferably micronized to about 0.1 to 0.2 microns in order to maintain the colloidal dispersed phase to prevent the precipitation of sulfur and to maximize contact with pathogenic microorganisms.
탱크50에 취수된 본 발명의 살균제51를 적의의 설비에 의하여 작물에 살포하면 병해를 방지하게 된다.When the
본 발명의 살균제를 이용한 오이 흰가루병에 대한 방제효과 시험에 의하면 살포간격을 7일로 하였을 경우 방제가가 83.2％로서 산성전해수 단독 살포 58.1％에 비하여 대폭 개선되었으며, 대조구인 농약살포구의 90.5％에는 이르지 못하였으나, 농약 성능 평가 기준에는 통과한 우수한 방제효과를 나타내었다.According to the control effect test for cucumber powdery mildew using the fungicide of the present invention, when the spray interval was 7 days, the control value was 83.2%, which was significantly improved compared to 58.1% of the acidic electrolyzed water spray alone, and it did not reach 90.5% of the control pesticide sprayer. However, the pesticide performance evaluation criteria showed an excellent control effect.
상기의 실시 예는 유격막 전해수생성장치에서 생성되는 강산성전해수에 관한 일예이나, 유격막 약산성전해수, 무격막 미산성전해수에도 동일하게 적용될 수 있다.The above embodiment is an example of the strong acidic electrolyzed water generated by the diaphragm electrolyzed water generating device, but may also be applied to the diaphragm weakly acidic electrolyzed water and the non-diaphragm nonacidic electrolyzed water.
상술한 바와 같이 본 발명에 따르면, 전해수생성장치로부터 생성되는 산성전해수에 콜로이드 액상유황을 첨가하여 조제한 살균제를 작물의 병해방제에 사용하여 산성전해수 단독 시용에 비하여 월등히 높은 병해 방제효과를 얻을 수 있게 됨으로서, 종래의 산성전해수에 의한 친환경농법이 가지는 잦은 살포에 따른 노동부하 과중 등 관리상의 문제와 작물생육상의 부작용을 개선할 수 있게 되어, 작물수확의 증대와 품질향상으로 농가소득이 증대되는 친환경농업을 안심하고 영위할 수 있는 효과를 가져다준다.As described above, according to the present invention, by using the disinfectant prepared by adding colloidal liquid sulfur to the acidic electrolyzed water generated from the electrolyzed water generating device for the disease control of the crop, it is possible to obtain a much higher effect of controlling the disease than the application of the acidic electrolyzed water alone. In addition, it is possible to improve the management problems such as overload of labor due to the frequent spreading of the eco-friendly farming method by the acidic electrolyzed water and the side effects of crop growth, and the eco-friendly farming where the farm income is increased by increasing crop harvest and quality. It brings the effect that you can run with confidence.
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