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KR20060055256A - Functional sterilization and deodorizing paint using nano silver and charcoal - Google Patents

Functional sterilization and deodorizing paint using nano silver and charcoal Download PDF

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KR20060055256A
KR20060055256A KR1020040094821A KR20040094821A KR20060055256A KR 20060055256 A KR20060055256 A KR 20060055256A KR 1020040094821 A KR1020040094821 A KR 1020040094821A KR 20040094821 A KR20040094821 A KR 20040094821A KR 20060055256 A KR20060055256 A KR 20060055256A
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charcoal
nano silver
deodorizing
silver
paint
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KR100626176B1 (en
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박진우
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/14Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80Processes for incorporating ingredients

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

본 발명은 다공성 구조로 각종 유해가스에 대한 탈취력을 가진 숯 분말과 나노은의 특성인 강력한 살균력을 이용하여 탈취와 항균, 살균효과가 동시에 나타나면서 도포후 건조된 나노은, 숯 도료의 검은 표면이 나노 은의 입자에 의해 시각적으로 반짝이므로 귀금속인 은을 통한 피착면의 미적 부가가치도 부수적으로 누리게 되는 나노 은과 숯을 이용한 기능성 살균, 탈취도료에 관한 것이다.The present invention is a porous structure of the deodorizing, antimicrobial, and sterilizing effect simultaneously using the charcoal powder having a deodorizing power for various harmful gases and nano silver, while appearing at the same time deodorizing, antimicrobial, and sterilizing effect, the black surface of the charcoal paint is nano silver It is related to functional sterilization and deodorizing paint using nano silver and charcoal, which is visually sparkled by particles, and thus additionally enjoys the aesthetic added value of the deposited surface through the precious metal silver.

고속 교반기 속에 아크릴 에멀젼바인더 30%와 폴리비닐부티랄(poly vinyl butyral)30%로 혼합 처리된 수용액 1000㎖를 투입하고 입자크기가 250nm士10%인 나노 은을 분산시킨 용액20㎖와 입도가 350매쉬인 활성숯 또는 참숯250g, 입도가 350매쉬인 음이온석 50g의 비율로 혼합, 합성하고 상온에서 1000rpm의속도로 고속 교반하여 제조되는 것을 특징으로 한다.In a high-speed stirrer, 1000 ml of an aqueous solution mixed with 30% of an acrylic emulsion binder and 30% of polyvinyl butyral were added, and 20 ml of a particle size of 250 nm 10% of nano silver was dispersed and 350 of particle size. It is characterized in that it is prepared by mixing and synthesizing at a rate of 250g mash activated charcoal or true charcoal, 50g particle size 350g anion stone at a speed of 1000rpm at room temperature.

숯 분말, 나노은, 음이온석,Charcoal powder, nano silver, anion stone,

Description

나노 은과 숯을 이용한 기능성 살균, 탈취도료{omitted}Functional sterilization and deodorant coating using nano silver and charcoal

숯을 이용하는 종래 기술은 숯 자체의 기공을 이용하여 탈취효과를 얻는데 섭씨 1200도 이상의 고온에서 생산된 숯을 고체상이나 다양한 크기로 분쇄한 숯 분말을 이용하여 각종 탈취나 정화, 정수 목적으로 사용하고 있다.Conventional technology using charcoal is used for various deodorization, purification, and water purification purposes by using charcoal powder pulverized in solid phase or various sizes to produce deodorizing effect by using pores of charcoal itself. .

그러나 습도가 높은 곳의 숯이나 침수된 숯은 시간이 경과됨에 따라 숯의 기공 속 환경조건이 세균이 번식하기 좋은 습도와 환경으로 인해 차츰 곰팡이가 발생하게 되는 것을 볼 수 있다.However, as charcoal in high humidity or submerged charcoal, as time passes, it can be seen that the environmental conditions in the pores of charcoal gradually grow mold due to the humidity and environment where bacteria can grow.

숯 자체의 성분은 곰팡이를 발생시키지 않지만 기공 속에 흡착된 유기물질을 먹이로 하는 세균과 곰팡이가 다수 발생함으로 숯의 기공 속에 세균이 번식하게 되고 그 부산물의 부패로 인해 숯의 고유기능인 탈취력이 급격하게 떨어지는 부작용이 나타남으로써 통상 이를 폐기하거나 세균을 분리시키기 위하여 물로 씻어내고 건조시키는 과정을 거치는 번거로움이 발생하게 되는 것이다.Charcoal itself does not generate mold, but many bacteria and molds feed on organic substances adsorbed in the pores, causing bacteria to multiply in the pores of the char. As a result of falling side effects, it is usually a hassle to go through the process of washing with water and drying in order to discard it or to separate bacteria.

또한 기존의 수성용 도료는 물을 대량 포함하고 있으므로 부패의 위험에 항상 노출되어 있다고 할 수 있는데. 기존 수성 도료는 자체부패를 막기 위하여 포르말린이 주성분인 각종 화학방부제, 유기항균제를 사용하고 있으며 이는 제품의 화 학적 안전성, 내산성을 일으켜 제품의 질을 떨어뜨리고 있다.In addition, existing waterborne paints contain large amounts of water, which means that they are always exposed to the risk of corruption. Existing water-based paints use various chemical preservatives and organic antimicrobial agents, the main component of which is formalin, in order to prevent its own decay.

특히 각종 화학적 방부제는 독소작용으로 인해 인체와 자연 생태계를 위협하고 우리의 거주환경에 치명적 악영향을 초래할 수 있으므로 그 사용을 최대한 억제 하여야 한다.In particular, various chemical preservatives should be suppressed as much as possible because they can threaten the human body and natural ecosystem due to toxin action and cause fatal adverse effects on our living environment.

숯과 나노 은, 음이온석 광물을 주원료로 이용하여 우리의 일상생활 속 각종 건축물이나 가구류 등에서 발생하는 유해가스나 악취등 유해성분의 탈취, 공기정화, 각종 세균에 대한 살균, 탈취, 등의 제거 효율이 우수하게 나타나는 친환경 기능성 수성용 도료를 제조하여 이를 실내건축물에 적용 도포하고 건조시키면 주원료인 숯과 나노은, 등 첨가된 기능성물질의 작용과 효과로 공기정화작용, 항균작용, 음이온방출, 원적외선방출, 온혈작용 등을 하여 각종 건축물에서 발생하는 유해가스를 제거하고, 공기를 정화시키며 공기 중의 부유세균까지 흡착, 살균하므로 우리의 생활주거공간을 좀 더 안전하고 쾌적한 공간으로 만들기 위한 기능성 살균, 탈취도료를 제공 하고자 한다Using charcoal, nano silver and anion minerals as the main raw materials, the efficiency of deodorization, air purification, sterilization and deodorization of various bacteria such as harmful gases and odors generated in various buildings and furniture in our daily life This excellent eco-friendly functional aqueous paint is produced, applied to indoor building, applied and dried, and the air purification effect, antibacterial effect, anion emission, far infrared emission, It removes harmful gases generated in various buildings by warming blood, cleans the air, and absorbs and sterilizes airborne bacteria in the air, so we use functional sterilization and deodorant paints to make our living space safer and more comfortable. Wish to provide

본 발명은 다공성 구조로 탈취력을 가진 숯 분말과 나노은의 특성인 강력한 살균력을 이용하여 공기정화와 더불어 기공 속에 흡착된 세균을 효과적으로 살균하는 기능성 은,숯 도료제조에 관한 것으로 그 구성과 작용은 다음과 같다.The present invention relates to the production of functional silver and charcoal paint which effectively sterilizes bacteria adsorbed in pores with air purification by using strong sterilizing power of charcoal powder and nano silver having a deodorizing power with a porous structure. same.

섭씨 1200도 이상의 고온에서 생산된 활성숯이나 참숯을(325매쉬 크기) 분쇄한 숯 분말을 사용하고 있는데 주성분이 탄소로 된 숯 자체의 성분은 곰팡이를 발 생시키지 않지만 숯의 특성인 다공성 구조로 인해 각종 기체 및 각종 유기화합물이 자연 흡착된다.Activated charcoal or charcoal (325 mesh size) pulverized using charcoal powder produced at a high temperature of more than 1200 degrees Celsius is used.The charcoal itself, whose main component is carbon, does not cause mold, but due to the porous structure of charcoal, Gases and various organic compounds are naturally adsorbed.

이 흡착된 유기물질을 먹이로 하는 곰팡이가 숯의 기공 속에 다수 발생할 수 있는데 기공속에 흡착된 유기물질을 먹이로 하는 세균과 곰팡이가 다수 발생함으로 숯의 기공 속에 세균이 번식하게 되고 그 부산물의 부패로 인해 숯의 고유기능인 탈취성능이 현저히 떨어지는 결과가 나타나게 되는데 이런 세균류를 근본적으로 효과 있게 제거하기 위하여 숯을 항균처리할 필요가 있다.The fungus feeding the adsorbed organic materials can occur in the pores of the char.Because a lot of bacteria and molds are fed to the organic substances adsorbed in the pores, bacteria grow in the pores of the char. Due to the intrinsic function of charcoal deodorization performance is markedly reduced results, it is necessary to antibacterial treatment charcoal in order to effectively remove these bacteria.

이런 유해세균은 숯 자체의 능력으로 어느 정도 감소시킬 수 있지만 많은 유기물이 흡착되었거나 습도가 높은 곳에서는 전혀 효과를 기대할 수 없다.These harmful bacteria can be reduced to some extent by the ability of the charcoal itself, but no effect can be expected at all where many organic substances are adsorbed or in high humidity.

따라서 인위적으로 좀 더 강력하고 효과적으로 살균, 항균 능력을 부여해야 할 필요성이 있다고 할 수 있다.Therefore, there is a need to give artificially more powerful and effective sterilization and antibacterial ability.

일반적으로 실버는 전도성이 뛰어나고 정전기 및 전자파를 차단하며 수맥차단 효과가 있으며 인체에 무해하여 고대로 부터 독성감지 및 항균, 살균효과가 반영구적으로 나타나는 무기 물질임이 각종실험을 통해 알려지고 있다.In general, silver has excellent conductivity, blocks static electricity and electromagnetic waves, has a water vein blocking effect, and is known to be a semi-permanent inorganic substance exhibiting toxicity, antimicrobial, and sterilizing effects from ancient times.

통상 은을 통해서 각종 세균에 대한 항균력을 가지게 하려면 약200ppm의 은 이온 농도를 확보해야 하는데 이를 손쉽게 정량화하기 위하여 본 기능성 도료는 나노은을 사용하였다. 나노은 은 순도 99.99%의 은을 고전압을 통해 폭발 시킬 때 발생하는 250나노 크기로 분해된 은 입자를 모은 것으로 순수 은 입자이므로 이를 계량하여 균일한 농도비를 손쉽게 얻을 수 있다.In general, in order to have antibacterial activity against various bacteria through silver, it is necessary to secure a silver ion concentration of about 200ppm. In order to easily quantify this functional coating, nano silver was used. Nano silver is a collection of 250 nanoparticles of silver decomposed to a high purity of 99.99% silver by exploding through high voltage, so pure silver particles can be easily measured to obtain a uniform concentration ratio.

인체에 전혀 무해하면서도 강력한 살균, 항균성을 가진 순수 은궤를 수용성 액화하기 위하여 다음과 같이 실시하였다.In order to liquefy pure silver ace, which is harmless to human body and has strong sterilization and antibacterial effect, it was carried out as follows.

순도99.99%인 실버와이어의 양쪽 끝 즉 양극에 변압기를 통해 저장된 전기에너지를 펄스로 압축한 후 고전압 스위치를 통하여 15만 볼트의 고밀도전류를 순간적으로 금속 와이어에 인가하면 극히 높은 온도 상태인 플라즈마가 발생하는데 이렇게 생성된 저항발열을 통해 실버를 기화 또는 이온화시켜 150nm- 250nm크기로 분해된 나노은 입자를 얻었다.After compressing the electric energy stored through the transformer at both ends of the silver wire, which is 99.99% purity, with a pulse, and applying a high-density current of 150,000 volts to the metal wire through a high voltage switch, an extremely high temperature plasma is generated. However, through the generated heat of resistance, silver was vaporized or ionized to obtain nanosilver particles decomposed to a size of 150nm-250nm.

또한 얻어진 나노 실버입자를 포집하여 물에 분산시킴으로 나노 은이 포함된 수용액을 제조하였다.In addition, the obtained nano silver particles were collected and dispersed in water to prepare an aqueous solution containing nano silver.

이렇게 전기플라즈마 법으로 얻어진 나노은 은 기존의 극약성 질산염과 가성소다를 첨가하여 추출하는 물리적, 화학적 방법으로 얻는 콜로이드 은용액이나 포르말린이 주성분인 방부제나 유기 항균제를 첨가하여 제품화 했을 때 발생하는 인체에 대한 유해성과 제품 속에 내재된 오염원의 잠재 환경 위험성을 피하면서도 강력한 살균과 항균 작용을 하는 바람직한 방법으로 순수 은 을 친환경적으로 이용하는 차별적인 나노 실버기술인 것이다.The nano silver obtained by the electroplasmic method is a colloidal silver solution obtained by the physical and chemical method of extracting by adding the existing ultra weak nitrate and caustic soda or the formalin-based preservative or organic antibacterial agent. It is a differentiated nano silver technology that uses pure silver in an environmentally friendly way, with strong sterilization and antibacterial action, while avoiding the hazards and potential environmental hazards of the pollutants inherent in the product.

음이온이 대량 발생하는 음이온 전기석 광물을 첨가하였는데 음이온 광물의 특성과 효과는 성문 화학사전 (삼광 인쇄사 편저)에 잘 나타나있다. 1880년 노벨 물리학상을 수상했던 퀴리부부 중 남편 피에르 퀴리씨가 형 자크와 함께 전기석 결정에서 끊임없이 0.06m의 미약전류인 음이온이 항상 방출되는 것을 발견하였는데 본 발명은 분말화 (350매쉬) 한 전기석을 첨가하여 음이온을 대량 방출하는 기능성 살균, 탈취제를 제조하였다. Anion tourmaline minerals with large anions are added, and the characteristics and effects of anion minerals are well represented in Sungmun Chemical Dictionary (ed by Samkwang Printing Company). Among the Curie couples, who won the Nobel Prize for Physics in 1880, their husband, Pierre Curie, found out that with Jacques, he constantly released 0.06 m of weak currents in the tourmaline crystals. The present invention adds a powdered (350 mesh) tourmaline. To prepare a functional sterilization, deodorant to release a large amount of anions.                     

본 기능성 도료에 사용하는 수용성 바인더는 친환경 아크릴 에멀젼바인더 30%와 무독성 폴리비닐부티랄(poly vinyl butyral) 30%로 혼합 처리된 수용액인데 특히 폴리비닐부티랄(poly vinyl butyral)은 중합체, 수산기, 지방족화합물이며 산업안전보건규정(MSDS)에서 흡입, 피부접촉, 눈 접촉, 섭취, 에 대한 부작용과 반응성이 없고 유럽연합(EC)과 미국산업안전보건청 분류에도 발암성, 유해위험성=0 인 미규정 물질로, 물성이 안정된 수용성이며 접착력이 있으나 상호 밀도가 낮음으로 인해 기체 투과력이 있는 폴리비닐부티랄 을 이용하여 숯과 은을 피착 면에 부착시키는 접착제로 사용함으로 숯의 기공성을 확보하여 각종 실내건축자재 및 생활공간에서 발생하는 유해가스가 숯의 기공 속으로 원활하게 침투, 흡착되는 구조를 가지게 하여 숯의 고유기능인 탈취력을 저해 하지 않았다.The water-soluble binder used in this functional paint is an aqueous solution mixed with 30% environmentally friendly acrylic emulsion binder and 30% non-toxic polyvinyl butyral. Especially, polyvinyl butyral is a polymer, hydroxyl group or aliphatic compound. It is a compound that is not reactive with adverse effects on inhalation, skin contact, eye contact, ingestion, and in the Occupational Safety and Health Regulation (MSDS) and is carcinogenic and hazardous risk = 0 in the classifications of the European Union and the United States Occupational Safety and Health. As a material, it is water-soluble and stable in physical properties, but has low mutual density, so it is used as an adhesive to attach charcoal and silver to the adhered surface by using polyvinyl butyral with gas permeability. Deodorizing power, which is a unique feature of charcoal, has a structure that allows harmful gas generated from building materials and living spaces to penetrate and adsorb into the pores of charcoal smoothly. I did not interfere.

상기 각 물질을 합성하고 혼합한 본 기능성 나노은, 숯 도료의 적용 실시예는 다음과 같다.Examples of application of the present functional nano silver and charcoal paints synthesized and mixed with each material are as follows.

(실시예)(Example)

공정1Process 1

고속 교반기속에 아크릴 에멀젼바인더 30%와 폴리비닐부티랄(poly vinyl butyral) 30%로 혼합 처리된 수용액 1000㎖를 투입한다.1000 ml of an aqueous solution mixed with 30% acrylic emulsion binder and 30% polyvinyl butyral was added to a high speed stirrer.

공정2Process 2

나노은을 분산시킨 수용액20㎖를 1공정에 혼합하여 총량 대비 나노은 이온농도가 200ppm이 되게 한다.20 ml of the aqueous solution in which the nano silver is dispersed is mixed in one step so that the nano silver ion concentration is 200 ppm to the total amount.

공정3 Process 3                     

입도크기가 350매쉬인 숯 250g을 계량 한다.Weigh 250 g of charcoal with a particle size of 350 mesh.

공정4Process 4

입도크기가 350매쉬인 음이온석 50g을 계량 한다.Weigh 50 g of anionic stones with a particle size of 350 mesh.

공정5Process 5

계량된 2, 3, 4, 공정의 원료를 1공정의 교반기에 투입하고 고속교반기를 작동하여 1000rpm 의 속도로 믹싱 교반한 후 준비된 용기에 담고 밀봉한다.Weighed 2, 3, 4, the raw material of the process is put into the stirrer of the first step, the mixing and stirring at a speed of 1000rpm by operating a high speed stirrer and sealed in a prepared container.

상기 기능성 나노 은, 숯 도료의 시편을 한국과학기술 연구소(KIST) 대기자원연구소에서 탈취 시험한 결과 벤젠과 ,포름알데히드를 흡착 제거하는 탈취효율이 대단히 우수하다고 기재된 논문을 공식 공문으로 수령하였으며 상기 기능성 나노은, 숯 도료의 세균에 대한 살균력 시험을 위해 한국 원사직물 연구원에 의뢰한 결과 99.9%의 살균력을 나타내고 있는 시험 성적서를 교부 수령 받은바 이는 본 기능성 나노은, 숯 도료의 효과를 객관적으로 증명한다 하겠다.As a result of the deodorization test of the functional nano silver and charcoal paint specimens at the Korea Institute of Science and Technology (KIST) Air Resources Research Institute, the official official received a paper stating that the deodorization efficiency of adsorption and removal of benzene and formaldehyde was very excellent. As a result of requesting the test of sterilizing ability against bacteria of nano silver and charcoal paint, we received a test report showing 99.9% of sterilizing power. This will objectively prove the effect of this functional nano silver and charcoal paint.

본 기능성 나노 은 숯 도료는 실내 마감재 시공전의 천장, 벽면, 바닥, 등의 표면에 분포하므로 시멘트의 강알칼리 독성을 중화 차폐하며 실내의 각종 건축자재에서 발생하는 유해가스를 흡착 제거함으로 별도의 탈취제와 살균제가 필요 없게 하였고, 또한 강한 자극취 발생 장소 등에도 활성 숯의 기공이 넓은 면적에 도포, 노출됨으로 정화기능이 탁월하게 나타나고 있으며 숨 쉬는 다수의 숯 기공과 나노실버와 음이온석 등의 작용에 의해 유기 산화 화합물의 탈취는 물론하고 각종 생활 악취, 기체매연, 부유성 먼지, 등을 흡착, 정화, 탈취하며 나노 은에 의한 공기살 균과, 전기석 광물로 인한 음이온, 원적외선방출 등 습도조절, 세포활성작용, 등의 효능이 일체적이고, 반영구적으로 나타나게 하였으며 친환경적이고 인체에 유익하여 쾌적한 생활환경을 손쉽게 누릴 수 있게 한 삶의 질을 향상 시킬 수 있는 새로운 개념의 기능성 살균, 탈취 도료이다.This functional nano silver charcoal paint is distributed on the surface of ceiling, wall, floor, etc. before construction of interior finishing materials, neutralizing and shielding strong alkali toxicity of cement and adsorbing and removing harmful gases from various building materials in the room. In addition, the pores of activated charcoal are applied and exposed to a large area for strong irritant odor, and the cleansing function is excellent, and the organic oxidation is performed by the action of many breathing char pores and nano silver and anion stone. As well as deodorizing the compound, it adsorbs, purifies and deodorizes various odors, gaseous smoke, floating dust, etc. Efficacy of the back and the effect appeared in a semi-permanent, eco-friendly and beneficial to the human body A new concept of functionality easy sterilization, deodorizing coatings which can be one to improve the quality of life, so enjoy.

본 도료의 응용으로는 실내건축재료, 및 콘크리트 바닥, 합판, 실내인테리어, 산업제품, 생활용품, 초배지, 벽지, 등의 각종 형상의 안팎 표면에 부착 되어져 각종악취차폐, 공기정화, 음이온방출, 등의 목적으로 사용할 수 있으며 각종 캐릭터 상품 속에 부착 동봉함으로써 차량이나 실내의 공기 정화와 담배냄새탈취, 살균, 음이온, 원적외선, 방출을 위한 용도로 사용되어질 수 있다.Applications of this paint include interior building materials, concrete floors, plywood, interior interiors, industrial products, household goods, paper plates, wallpaper, etc., attached to the inside and outside surfaces of various odors, air purification, anion release, etc. It can be used for the purpose of enclosing attached to various character goods, and can be used for air purification and deodorization, sterilization, anion, far infrared rays, emission of vehicle or indoor.

특히 건조된 나노은, 숯 도료의 검은 표면이 나노은 입자(150nm- 250nm 크기) 에 의해 시각적으로 반짝이게 됨으로 살균, 탈취와 더불어 귀금속인 은을 통한 고급스런 시각적 느낌을 강하게 줌으로 피착면의 미적 부가가치도 크게 높일 수 있다.In particular, the black surface of dried nano silver and charcoal paint is visually shimmered by nano silver particles (150nm-250nm size), so as to sterilize and deodorize, and give a high-quality visual feeling through silver, which is a precious metal. It can be greatly increased.

Claims (1)

고속 교반기속에 아크릴 에멀젼 바인더 30%와 폴리비닐부티랄(poly vinyl butyral) 30%로 혼합 처리된 수용액 1000㎖를 투입하고, 나노 은(150nm- 250nm 크기)을 분산시킨 용액 20㎖를 투입, 교반하면서 숯 분말(350매쉬) 250g과 음이온석 분말(350매쉬) 50g 을 혼합, 교반 하여 이루어지는 것을 특징으로 하는 기능성 나노 은, 숯 도료Into a high speed stirrer, 1000 ml of an aqueous solution mixed with 30% of an acrylic emulsion binder and 30% of polyvinyl butyral were added, and 20 ml of a solution in which nano silver (150 nm-250 nm size) was dispersed was added and stirred. Functional nano silver and charcoal paint, characterized by mixing and stirring 250 g of charcoal powder (350 mash) and 50 g of anionic stone powder (350 mash)
KR1020040094821A 2004-11-16 2004-11-16 Functional paint made using nano silver and charcoal Expired - Fee Related KR100626176B1 (en)

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US8158032B2 (en) * 2010-08-20 2012-04-17 Xerox Corporation Silver nanoparticle ink composition for highly conductive features with enhanced mechanical properties
KR102008851B1 (en) * 2018-06-01 2019-08-07 신호현 Funtional Wall Paper

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KR100509454B1 (en) * 2002-03-22 2005-08-24 이종학 bio-sheet material and its manufacturing method and apparatus
KR20030093389A (en) * 2002-05-29 2003-12-11 장혁수 Lining paper, wallpaper and method for producing the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8158032B2 (en) * 2010-08-20 2012-04-17 Xerox Corporation Silver nanoparticle ink composition for highly conductive features with enhanced mechanical properties
KR102008851B1 (en) * 2018-06-01 2019-08-07 신호현 Funtional Wall Paper

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