KR20060026377A - Method for preparing germanium-containing water using loess - Google Patents

Abstract

The present invention relates to a process for producing germanium-containing water and germanium-containing by-products (hereinafter referred to as fine powder ocher solution) from loess distributed between natural lands and between doses (ocher after repeated high temperature and cooling). Germanium (70 (20.55%), 72 (27.37%), 73 (7.67%), 74 (36.74%), 76 (7.67%)) distributed between ocher or doses Make water of same size and weight), apply redness (赤 熱: red moon phenomenon), and immerse in groundwater (spring water) in red state to produce oxidized water-soluble organic germanium (hereinafter referred to as germanium-containing water). In this way, organic germanium is used as an auxiliary material to improve immune system and skin beauty by acting to increase the oxygen concentration of the human body to enhance immunity.

To this end, the present invention is a step of making dumplings between loess or dose, drying the dumplings at room temperature for more than 24 hours, or drying them by applying heat, and applying the heat when glowing dumplings to charcoal, coal, electricity, and gas Step, the dandelion is glowing at 750 ° C-930 ° C for 30-60 minutes, the dumped water is completely submerged in groundwater (spring water) to extract and organically extract germanium oxide, and the extracted germanium-containing water The step of filtering, separating the by-products left after the production of germanium-containing water, and stirring them into a liquid in the form of fine particles after stirring, separating them separately. The method of controlling the concentration ratio, and the properties of the liquid in the form of particulates separated from such germanium-containing water and by-products are 70,72,73,74,76. Jingeot is characterized as having achieved the properties of the box contents.

Water soluble germanium. Glowing. Immune system. Taking liver. ocher. Dumpling.

Description

{Production Method of Germanium containing side product, Germanium containing water from bok-yong-kan, yellow soil of surface.}

The present invention relates to a method for producing germanium-containing water and germanium-containing by-products from the ocher doses distributed on the natural surface of the earth. Specifically, germanium is a carbon group element belonging to group 4B of the periodic table and has an element symbol (Ge), an atom. No. 32, melting point (melting point): 958.5 degrees C, boiling point (boiling point): 2700 degrees C. A non-metallic submetallic element, broadly and thinly divided in the earth's crust, and also contained in certain plants. It is stable in air, but oxidizes when heated above red heat. The conventional method of extracting the blast furnace is a method obtained as a by-product during the smelting of sulfide minerals, burning germanium-containing stones to form oxides, and sintering by adding coal and salt to sinter germanium and cadmium.

This is absorbed by sulfuric acid, zinc powder is used, cadmium is removed, dried and roasted, and then distilled with hydrochloric acid to obtain germanium chloride, and the method of collecting coal briquettes during coal combustion adds sodium carbonate and lime and mixes copper oxide. Germanium collects in the slag. There is a conventional method for obtaining germanium chloride by distilling hydrochloric acid and sulfuric acid in an aqueous solution of iron chloride while chlorine is passed through the powder of this slag. Application number 10-1999-0031010 published in Korea contains germanium from natural germanium ore. Natural germanium ore is pulverized with 200-250 mesh, dried at 100-110 ° C for 1-2 hours, cooled in air and calcined at 1050-1100 ° C for 4-5 hours. After the sample is cooled in air, distilled water is added so that the sample becomes 0.5-1 kg / L, followed by stirring for 30-40 minutes, followed by filtration.

This conventional technology has the disadvantage of excessive investment in the enormous facility of the smelting process and the environmental cleanup cost of the by-products generated in the smelting process, and the two methods mentioned above are methods to obtain powder germanium, Application No. 10-1999-0031010 is a method of obtaining a germanium-containing water from natural germanium ore can be found to be composed of the present invention and other manufacturing methods, there is a disadvantage in that excessive manufacturing costs.

The present invention is inexpensive without affecting the environment by using a feature that can be oxidized by applying red heat, which is an inherent property of germanium, using the ocher containing germanium and the dose between the natural surface to solve the above problems It is an object of the present invention to provide a method for producing germanium-containing water at production cost.

In order to achieve the above object, the present invention provides a method for producing germanium-containing water, which comprises steps of making dumplings between loess or dosing, drying the dumplings at room temperature for at least 24 hours, or drying them by applying heat, and dumping the dumplings. Charging medium to charcoal, coal, electricity, and gas, glowing dumplings at 750 ° C-930 ° C for 30 minutes-60 minutes, and flooding the dumplings in the ground with water (spring water) Extracting and extracting germanium oxide, filtering the extracted germanium-containing water, separating the by-products after the production of the germanium-containing water, stirring the precipitates, and separating them into a liquid in a particulate state. To control the germanium-containing concentration ratio of the germanium-containing water by submerging it into groundwater, The properties of the fine particle state of the solid-liquid separation is characterized jingeot made to have the characteristics of information, comprising a germanium 70,72,73,74,76.

Unstable state in which the germanium elements distributed in the dump are oxidized when applied with red heat (coal, coal, electricity, gas) that can make heat from the uncontaminated loess to the ground. Leads to

At this time, when the water (water immersion) in water (immersion) is rapidly infiltrated inside the dumplings, the steamed water is leaked out of the dumplings while the swollen dumplings expand and evaporate at high temperatures.

At this time, the oxidized unstable germanium element also flows out with the expanded water vapor so that the dump dump is dissolved in a large amount in the stored water.

This is filtered to make germanium-containing water, and the by-products in the form of particulates from the by-products (precipitates) generated after filtration can be reused as an accelerating raw material of the manufactured product through the stirring process after precipitation. It can be used as auxiliary material for promoting functional activity and drinking water.

In order to include the technical components of the present invention, the following instruments and materials are listed in alphabetical order.

A dumplings made of egg-sized weight of uncontaminated ocher and liver.

B. Furnace that can apply heat (electric furnace, gas furnace, charcoal)

C. Uncontaminated Groundwater (Spring Water)

D. Container for holding "C"

E. Filtration Device

Make a dump (A) and apply it to the red (B) by putting an appropriate amount of dump dump (A) into the furnace (B) where it can be heated and dried after being naturally dried or heated at room temperature which is well ventilated for more than 24 hours. do.

At this time, the glowing time of the dumpling (A) is kept in the glowing state for 30 minutes to 60 minutes and the glowing temperature is maintained from 750 ° C to 930 ° C, and then the dumpling (A) in the glowing state contains the groundwater (C) Inject the appropriate amount in the red state inside.

At this time, the dump end A performs work to be submerged deeply in complete water.

Submerged in the red dumplings (A) in water, the water boils, the water penetrates into the glowing dumplings (A), expands, and expands the germanium oxide contained in the oxidized dumplings (A). It flows out of the dump end (A) with water and is organically distributed in the water in an oxidized state in the submerged water.

In this case, to increase the germanium moisture content, the germanium moisture content concentration can be adjusted by adjusting the amount of the dump end (A) and the water (C).

The by-products left after producing the germanium-containing water can be used as a function-promoting raw material for products produced differently in the state of containing water by separating the particulate form after precipitation through the stirring process.

As mentioned above, the reason why the dandelion temperature is kept in the range of 750 degrees C to 930 degrees C is because the lowest temperature at which the dandelion is glowing starts at 750 degrees C and the oxidation temperature of germanium starts at 750 degrees C. It was found that when it was above the melting point (melting point: melting point), the germanium melted and changed into an ingot, which prevented oxidation.

The concentration of germanium-containing water obtained by the above manufacturing method can be obtained as shown below, and the analysis results in the following example are requested by the inventor to the third-party Inha University ultra-precision bioseparation technology research center. Added.

View 1

Germanium-Containing Water Extraction Conditions

1. Standard Sample Conditions

1) Germanium Gemstone: 1.70kg

2) Yellow soil dump: 1.60kg

3) Standard water (spring water): 8 liters each

4) Glowing temperature: 750 ° C-930 ° C

5) Glowing time: 30 minutes-60 minutes

Germanium-containing water was prepared under the same conditions as in Example 1, and three samples of raw water (standard water), 2 liters of germanium gemstone extract, and 2 liters of ocher extract were obtained.

View 2

(Germanium Content Analysis Report)

Analytical Institution: Inha University (Super Precision Bioseparation Technology Research Center)

Analysis equipment: ICP-M, S

Date of Analysis: August 12, 2004

Raw water and extracted sample analysis results

Five kinds distributed in nature

Only 72 and 74 (70 (20.55%), 72 (27.37%), 73 (7.67%), 74 (36.74%) and 76 (7.67%)) were analyzed.

According to the analysis results above, two types of Ge72 and Ge74 analysis results show that the extraction of loess is about 160 times that of germanium in comparison with raw water, and it can be seen that all five kinds in nature are extracted. It can be estimated to be more than 200 times.

In the present invention, there is a disadvantage in that a large amount of germanium-containing water can not be manufactured by a method of producing germanium-containing water in an environmentally friendly way without excessive facility investment and chemical materials, but at a low cost and very environmentally friendly. Good quality germanium-containing water can be extracted, and the by-product of this is an environmentally friendly way of complete combustion and returning the yellow earth back to nature.

Claims (2)

0. The step of making a dumpling about the size (weight) of chicken eggs in the ocher containing liver containing germanium. 0. Naturally drying or heat drying the dumpling at room temperature for at least 24 hours. 0. The step of heating medium when glowing dumplings is charcoal, coal, electricity and gas. 0. When glowing dumplings, keep the temperature at 750 ° C-930 ° C for 30-60 minutes. 0. The step of extracting the organic germanium by immersing the red dumpling in water in a red state. 0. Filtering the water containing germanium extracted. 0. Separation of by-products remaining in the germanium-containing water, followed by stirring to separate the precipitate into a particulate liquid. 0. A method of controlling the germanium-containing concentration ratio of germanium-containing water by immersing in groundwater (spring water) while adjusting the amount of the red state such as taking ocher. The particulate liquid in the germanium-containing water and water-containing by-products obtained in claim 1 having the content and properties contained in germanium 70, 72, 73, 74, and 76.