KR20040051111A - Oil-Based Ink Composite for Ballpoint Pen - Google Patents
Oil-Based Ink Composite for Ballpoint Pen Download PDFInfo
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- KR20040051111A KR20040051111A KR1020020078958A KR20020078958A KR20040051111A KR 20040051111 A KR20040051111 A KR 20040051111A KR 1020020078958 A KR1020020078958 A KR 1020020078958A KR 20020078958 A KR20020078958 A KR 20020078958A KR 20040051111 A KR20040051111 A KR 20040051111A
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- ink
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- 239000002131 composite material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 24
- 239000010419 fine particle Substances 0.000 claims abstract description 20
- 239000002952 polymeric resin Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 20
- -1 polyethylene Polymers 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- 239000004793 Polystyrene Substances 0.000 claims abstract description 4
- 239000001913 cellulose Substances 0.000 claims abstract description 4
- 229920002678 cellulose Polymers 0.000 claims abstract description 4
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- 229920002223 polystyrene Polymers 0.000 claims abstract description 4
- 239000004698 Polyethylene Substances 0.000 claims abstract description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 3
- 229920000728 polyester Polymers 0.000 claims abstract description 3
- 229920000573 polyethylene Polymers 0.000 claims abstract description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 3
- 239000004814 polyurethane Substances 0.000 claims abstract description 3
- 229920002635 polyurethane Polymers 0.000 claims abstract description 3
- 239000003086 colorant Substances 0.000 claims description 9
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002576 ketones Chemical class 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 229960005323 phenoxyethanol Drugs 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 3
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000975 dye Substances 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 235000019445 benzyl alcohol Nutrition 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000000057 synthetic resin Substances 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 229920003082 Povidone K 90 Polymers 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/18—Writing inks specially adapted for ball-point writing instruments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
외관으로부터 잉크색의 식별이 가능하여 외관을 아름답게 하는 것이 가능하고 필기시의 찌꺼기가 생기지 않으며 보관시 잉크의 흘러내림 현상이 없도록, 착색제인 염료성분에 고분자수지 미립자를 전중량에 대하여 0.1∼40중량% 첨가하여 이루어지는 유성볼펜용 잉크조성물을 제공한다.It is possible to distinguish the color of the ink from the appearance so that the appearance can be made beautiful, no debris during writing and no dropping out of ink during storage. It provides the ink composition for oil-based ballpoint pen which is added by%.
고분자수지 미립자는 평균입자경이 대략 0.1∼10㎛ 정도 범위인 것을 사용하고, 폴리에틸렌, 폴리프로필렌, 폴리에스테르, 폴리스티렌, 폴리아크릴, 폴리메틸메타크릴레이트, 폴리우레탄, 결정셀룰로오스 등의 수지가 사용 가능하다.As the polymer resin fine particles, those having an average particle diameter of about 0.1 to 10 μm are used, and resins such as polyethylene, polypropylene, polyester, polystyrene, polyacryl, polymethyl methacrylate, polyurethane, and crystalline cellulose can be used. .
Description
본 발명은 유성볼펜용 잉크조성물에 관한 것으로, 보다 상세하게는 염료성분에 고분자수지 미립자를 포함하므로 고분자수지 미립자의 굴절률 차이에 의하여 잉크의 색상이 표면으로 반사되어 투명수지로 이루어진 잉크저장관에서 외관색으로 잉크의 색상구별이 가능하고 필기감이 부드러우며 잉크찌꺼기가 생기지 않고 보관시 잉크가 흘러내리는 현상이 없는 유성볼펜용 잉크조성물에 관한 것이다.The present invention relates to an ink composition for an oil ballpoint pen, and more specifically, since the dye component includes polymer resin fine particles, the color of the ink is reflected to the surface by the difference in refractive index of the polymer resin fine particles, which is apparent in an ink reservoir tube made of transparent resin. The present invention relates to an ink composition for an oil ballpoint pen capable of distinguishing colors of ink by color, having a soft writing feeling, no ink dregs, and no ink flowing down upon storage.
종래의 유성볼펜은 필기구의 잉크저장관 표면으로 보이는 외관색이 잉크의 색상에 관계없이 모두 검정색으로 보이므로, 별도의 색상부재로 외통이나 캡, 마개, 클립 등을 제조하여 필기구의 잉크색상을 용이하게 구별할 수 있도록 구성한다.Conventional oil ballpoint pens are all black, regardless of the color of the ink. It can be configured to be easily distinguished.
상기와 같은 종래 유성볼펜에 있어서는 잉크의 색상별로 각각 다른 색상부재를 조립하므로, 조립작업시 주의를 요하고, 색상부재가 잘못 조립된 경우에는 사용자가 원치않는 색상으로 필기를 하게 될 우려가 있다.In the conventional planetary ball-point pen as described above, since different color members are assembled for each color of ink, caution is required when assembling, and when the color members are incorrectly assembled, the user may write in an unwanted color.
따라서 최근에는 안료잉크를 사용하거나 안료를 일정량 투입하여 외관색을 잉크의 색상과 유사하도록 개선한 유성볼펜이 개발되어 제공된다.Therefore, in recent years, an oil-based ballpoint pen which has improved the appearance color to be similar to the color of ink by using a pigment ink or by adding a certain amount of pigment is provided.
그러나 안료잉크의 경우에는 경시적인 안정성이 나쁘므로 장기간 보관하는 경우에는 잉크의 색상이 변하게 될 우려가 있다. 그런데 외관색을 잉크의 색상에 근접하게 하기 위해서는 안료의 첨가량이 많아야 하므로, 안정성의 면에서 많은 문제를 내포하게 된다.However, in the case of pigment ink, the stability over time is bad, so there is a fear that the color of the ink changes when stored for a long time. However, in order to bring the exterior color closer to the color of the ink, the amount of the pigment added must be large, which causes many problems in terms of stability.
그리고 일본국 공개특허공보 특개2001-294796호에는 안료를 전조성물에 대하여 일정량 첨가하여 잉크의 찌꺼기나 번짐성을 개선한 안료를 포함하는 유성볼펜용 잉크에 대하여 기재되어 있으나, 외관색의 개선에 대한 기재는 없다.Japanese Patent Laid-Open No. 2001-294796 discloses an oil-based ballpoint pen ink containing a pigment in which a certain amount of the pigment is added to the precursor composition to improve the ink residue or bleeding. There is no description.
본 발명의 목적은 상기와 같은 문제점을 해결하기 위한 것으로서, 외관색의 식별이 가능함은 물론 아름답게 하는 것이 가능하고 필기시의 찌꺼기가 생기지 않으며 보관시 잉크의 흘러내림 현상이 없도록 염료성분에 고분자수지 미립자를 첨가하여 이루어지는 유성볼펜용 잉크조성물을 제공하기 위한 것이다.An object of the present invention is to solve the above problems, it is possible to distinguish the appearance color, as well as to be beautiful, do not produce a residue during writing and storage of the ink in the dye component so that the ink does not flow phenomenon It is to provide an ink composition for an oil-based ballpoint pen made by adding.
본 발명이 제안하는 유성볼펜용 잉크조성물은 착색제인 염료성분에 고분자수지 미립자를 전중량에 대하여 0.1∼40중량% 첨가하여 이루어진다.The ink composition for the oil ballpoint pen proposed by the present invention is prepared by adding 0.1 to 40% by weight of polymer resin fine particles to the total weight of a dye component as a colorant.
상기한 고분자수지 미립자는 평균입자경이 대략 0.1∼10㎛ 정도 범위인 것을 사용하여 이루어진다.The above-mentioned polymer resin fine particles are formed using those having an average particle diameter of approximately 0.1 to 10 mu m.
상기에서 고분자수지 미립자의 평균입자경이 0.1㎛ 미만인 경우에는 외관색의 구별이 어렵고, 10㎛ 이상인 경우에는 필기선단에서의 유출이 어렵고 필기감도 좋지 않다.When the average particle diameter of the polymer resin fine particles is less than 0.1㎛, it is difficult to distinguish the appearance color, and when the average particle diameter is 10㎛ or more, the outflow from the writing tip is difficult and the writing feeling is not good.
상기한 고분자수지 미립자로는 폴리에틸렌, 폴리프로필렌, 폴리에스테르, 폴리스티렌, 폴리아크릴, 폴리메틸메타크릴레이트, 폴리우레탄, 결정셀룰로오스 등의 수지가 사용 가능하며, 유성볼펜에 사용하는 용제에 용해가 되지 않는 수지이면 사용 가능하다.As the polymer resin fine particles, resins such as polyethylene, polypropylene, polyester, polystyrene, polyacryl, polymethyl methacrylate, polyurethane, crystalline cellulose, and the like can be used, and they are insoluble in a solvent used in an oil ballpoint pen. If it is resin, it can be used.
상기에서 고분자수지 미립자의 첨가량이 전중량에 대하여 0.1중량% 미만인 경우에는 외관색의 구별이 어렵고, 40중량%를 초과하면 잉크의 점도 및 필기감에 나쁜 영향을 주게 되어 실용적으로 사용이 어렵다.When the amount of the polymer resin fine particles added is less than 0.1% by weight based on the total weight, it is difficult to distinguish the appearance color, and when the amount of the polymer resin fine particles exceeds 40% by weight, the viscosity of the ink and the writing feeling are adversely affected.
본 발명의 유성볼펜용 잉크조성물에 있어서, 첨가하는 착색제로는 일반적으로 유성볼펜용 잉크에서 사용하고 있는 염료가 모두 사용 가능하다. 예를 들면 SPILON BLACK GMH-sp, SPILON VIOLET C-RH, SPILON YELLOW-C-GNH, SPILON RED C-BH, SPILON RED C-GH, SPT ORANGE 6, SPT RED 533(이상 상품명으로 일본국 호도가야가가쿠고교 가부시키가이샤 제품임), VALIFAST BLACK #3804, VALFAST VIOLET #1701, VALIFAST YELLOW #3102, VALIFAST YELLOW #1109, VALIFAST RED #1308, VALIFAST RED #1320(이상 상품명으로 일본국 오리엔트가가쿠고교 가부시키가이샤 제품임) 등이 사용 가능하다.In the ink composition for the oil ballpoint pen of the present invention, as the coloring agent to be added, generally all dyes used in the ink for the oil ballpoint pen can be used. For example, SPILON BLACK GMH-sp, SPILON VIOLET C-RH, SPILON YELLOW-C-GNH, SPILON RED C-BH, SPILON RED C-GH, SPT ORANGE 6, SPT RED 533 Kaku Kogyo Co., Ltd.), VALIFAST BLACK # 3804, VALFAST VIOLET # 1701, VALIFAST YELLOW # 3102, VALIFAST YELLOW # 1109, VALIFAST RED # 1308, VALIFAST RED # 1320 Kaisha's products).
상기한 착색제의 첨가량은 전중량에 대하여 10∼50중량%를 사용하는 것이 바람직하다. 상기에서 착색제의 첨가량은 염료성분에 첨가되는 고분자수지 미립자를 포함하지 않은 순수한 염료의 양이다.As for the addition amount of said coloring agent, it is preferable to use 10-50 weight% with respect to whole weight. The amount of the colorant added is the amount of the pure dye that does not contain the polymer resin fine particles added to the dye component.
그리고 본 발명의 유성볼펜용 잉크조성물에 있어서, 주로 사용하는 유기용제로는 일반적으로 유성볼펜용 잉크에 사용하는 용제가 사용 가능하며, 상기한 착색제를 용해 또는 분산하는 고비점용제가 사용 가능하다. 예를 들면 벤질알콜, 페녹시에탄올 외에 카비톨류, 셀로솔브류, 글리콜류, 글리콜에테르류 등이 사용 가능하며, 이들 중에서 선택하여 단독 또는 2종이상을 혼합하여 사용하는 것이 가능하다.In the ink composition for the oil ballpoint pen according to the present invention, as the organic solvent mainly used, a solvent generally used in the oil ballpoint pen ink may be used, and a high boiling point solvent for dissolving or dispersing the colorant may be used. For example, in addition to benzyl alcohol and phenoxyethanol, carbitols, cellosolves, glycols, glycol ethers, etc. can be used, and it can select from these and can use individually or in mixture of 2 or more types.
상기한 유기용제의 첨가량은 전중량에 대하여 30∼80중량%를 사용하는 것이 바람직하다.It is preferable to use 30-80 weight% of addition amounts of the said organic solvent with respect to the total weight.
본 발명의 유성볼펜용 잉크조성물에 있어서, 첨가되는 수지는 점도를 조정하기 위한 것으로 일반적으로 유성볼펜용 잉크에 사용하는 점도조정용 수지가 모두 사용 가능하다. 예를 들면 케톤수지, 말레인수지, 에스텔검, 알키드수지, 페놀수지, 로진수지, 텔펜수지, 폴리비닐피롤리돈, 폴리비닐부티랄 등이 사용 가능하며, 이들 중에서 선택하여 단독 또는 2종이상을 혼합하여 사용하는 것이 가능하다.In the ink composition for the oil ballpoint pen of the present invention, the resin to be added is for adjusting the viscosity, and in general, all of the resin for viscosity adjustment used in the oil ballpoint pen ink can be used. For example, ketone resins, male resins, ester gums, alkyd resins, phenol resins, rosin resins, telpen resins, polyvinylpyrrolidone, polyvinyl butyral, and the like can be used. It is possible to use a mixture.
그리고 본 발명의 유성볼펜용 잉크조성물은 필요에 따라서 방청제, 방부제, 윤활제 등 일반적으로 유성볼펜용 잉크에 사용하는 기타 첨가제를 첨가하는 것도 가능하다.The ink composition for the oil ballpoint pen according to the present invention may be added with other additives generally used in ink for oil ballpoint pens, such as a rust inhibitor, a preservative, and a lubricant, as necessary.
상기와 같이 이루어지는 본 발명의 유성볼펜용 잉크조성물에 있어서는 굴절률의 차이가 있는 고분자수지 미립자를 첨가하는 것에 의하여 잉크색이 표면으로 반사되어 투명 합성수지로 제조되는 잉크저장관의 외부에서 잉크색과 동일한 외관색으로 시인된다.In the ink composition for the oil ballpoint pen according to the present invention as described above, the appearance of the same color as the ink color on the outside of the ink storage tube made of transparent synthetic resin by reflecting the ink color to the surface by adding polymer resin fine particles having a difference in refractive index It is visually recognized.
다음으로 본 발명에 따른 유성볼펜용 잉크조성물의 실시예에 대하여 설명한다.Next, an embodiment of the ink composition for an oil ballpoint pen according to the present invention will be described.
(실시예 1)(Example 1)
착색제로서 SPT ORANGE 6 15.0중량%, SPILON RED C-BH 5.0중량%, SPILON RED C-GH 5.0중량%, SPILON YELLOW C-GH(이상 상품명;일본국 호도가야가가쿠고교 가부시키가이샤 제품) 2.0중량%, 유기용제로서 벤질알콜 9.9중량%, 2-페녹시에탄올 40.0중량%, 올레인산 3.0중량%, 점도조정제 수지로서 HILAC 111(상품명;히타치합성수지사 제품, 케톤수지) 15.0중량%, PVP K90(상품명;ISP 케미칼 주식회사 제품, 폴리비닐피롤리돈) 0.1중량%, 고분자수지 미립자로서 FLO-BEAD LE-1080(상품명;일본국 스미토모세이카케미칼 가부시키가이샤 제품, 저밀도폴리에틸렌 입자, 평균입자경 6㎛) 5.0중량%를 70℃에서 8시간 가열 교반하여 용해시킨 후 여과하여 적색의 유성볼펜용 잉크조성물을 얻었다.SPT ORANGE 6 15.0% by weight, SPILON RED C-BH 5.0% by weight, SPILON RED C-GH 5.0% by weight, SPILON YELLOW C-GH (above brand name; product made in Japan Hodogaya Chemical Co., Ltd.) 2.0 weight %, Benzyl alcohol 9.9% by weight, 2-phenoxyethanol 40.0% by weight, oleic acid 3.0% by weight, 15.0% by weight of HILAC 111 (trade name; manufactured by Hitachi Synthetic Resin, Ketone Resin), PVP K90 (brand name) ;, (ISP Chemical Co., Ltd. product, polyvinylpyrrolidone) 0.1 weight%, FLO-BEAD LE-1080 (brand name; Japan Sumitomo Seika Chemical Co., Ltd., low density polyethylene particle, average particle diameter 6 micrometers) 5.0 weight as polymer resin microparticles | fine-particles The mixture was dissolved by heating and stirring at 70 ° C. for 8 hours, followed by filtration to obtain a red oil-based ink composition.
(실시예 2)(Example 2)
착색제로서 SPT RED 533(상품명;일본국 호도가야가가쿠고교 가부시키가이샤 제품) 15.0중량%, VALIFAST YELLOW 1109(상품명;일본국 오리엔트가가쿠고교 가부시키가이샤 제품) 5.0중량%, 유기용제로서 벤질알콜 11.9중량%, 페녹시에탄올 40.0중량%, 올레인산 3.0중량%, 점도조정제 수지로서 HILAC 111(상품명;히타치합성수지사 제품, 케톤수지) 15.0중량%, PVP K90(상품명;ISP 케미칼 주식회사 제품, 폴리비닐피롤리돈) 0.1중량%, 고분자수지 미립자로서 SX-130(상품명;일본국 소겐가가쿠 가부시키가이샤 제품, 가교형 폴리스티렌 입자, 평균입자경 13㎛) 10.0중량%를 70℃에서 8시간 가열 교반하여 용해시킨 후 여과하여 적색의 유성볼펜용 잉크조성물을 얻었다.15.0 weight% of SPT RED 533 (brand name; product of Japan Hodogaya Chemical Co., Ltd.), VALIFAST YELLOW 1109 (brand name; product of Japan Orient Chemical Co., Ltd. product) 5.0 weight%, benzyl alcohol as organic solvent 11.9% by weight, 40.0% by weight of phenoxyethanol, 3.0% by weight of oleic acid, 15.0% by weight of HILAC 111 (trade name; product of Hitachi Synthetic Resin, Ketone Resin), PVP K90 (trade name; product of ISP Chemical Co., Ltd., polyvinylpi 10.0% by weight of SX-130 (trade name; Sogengagaku Co., Ltd., cross-linked polystyrene particles, average particle diameter: 13 µm) was dissolved by heating and stirring at 70 ° C for 8 hours as a polymer resin fine particle. Filtration was carried out to obtain a red ink composition for oil-based ballpoint pens.
(실시예 3)(Example 3)
착색제로서 SPT RED 533(상품명;일본국 호도가야가가쿠고교 가부시키가이샤 제품) 20.0중량%, 유기용제로서 벤질알콜 11.9중량%, 2-페녹시에탄올 48.0중량%, 올레인산 3.0중량%, 점도조정제 수지로서 HILAC 111(상품명;히타치합성수지사 제품, 케톤수지) 15.0중량%, PVP K120(상품명;ISP 케미칼 주식회사 제품, 폴리비닐피롤리돈) 0.1중량%, 고분자수지 미립자로서 AVICEL RC-N81(상품명;일본국 아사히카세이고교 가부시키가이샤 제품, 결정셀룰로오스, 평균입자경 8∼10㎛) 2.0중량%를 70℃에서 8시간 가열 교반하여 용해시킨 후 여과하여 적색의 유성볼펜용 잉크조성물을 얻었다.SPT RED 533 (brand name; Hodogaya Chemical Co., Ltd.) 20.0 weight% as a coloring agent, 11.9 weight% of benzyl alcohol, 48.0 weight% of 2-phenoxyethanol, 3.0 weight% of oleic acid, a viscosity modifier resin as an organic solvent As a HILAC 111 (trade name; manufactured by Hitachi Synthetic Resin, Ketone Resin), 15.0 wt%, PVP K120 (trade name; manufactured by ISP Chemical Co., Ltd., polyvinylpyrrolidone), 0.1 wt%, AVICEL RC-N81 (brand name; Japan) 2.0 weight% of Asahi Kasei Kogyo Co., Ltd., crystalline cellulose, average particle diameter of 8-10 micrometers) was melt | dissolved by heating and stirring at 70 degreeC for 8 hours, and it filtered and obtained the ink composition for red oil ballpoint pens.
(비교예 1)(Comparative Example 1)
상기한 실시예 1에서 고분자수지 미립자인 FLO-BEAD LE-1080을 제외시키고, 그 양만큼을 용제인 벤질알콜을 추가하여 실시예 1과 마찬가지로 70℃에서 8시간 가열 교반하여 용해시킨 후 여과하여 적색의 유성볼펜용 잉크조성물을 얻었다.Except FLO-BEAD LE-1080, which is a polymer resin fine particle in Example 1, and added the amount of the benzyl alcohol as a solvent and dissolved by heating and stirring at 70 ℃ for 8 hours as in Example 1, filtered and then red An ink composition for oily ballpoint pen was obtained.
(비교예 2)(Comparative Example 2)
상기한 실시예 2에서 고분자수지 미립자인 SX-130을 제외시키고, 그 양만큼을 용제인 벤질알콜을 추가하여 실시예 2와 마찬가지로 70℃에서 8시간 가열 교반하여 용해시킨 후 여과하여 적색의 유성볼펜용 잉크조성물을 얻었다.In Example 2, except for SX-130, which is a polymer resin fine particle, the amount was added to benzyl alcohol as a solvent and dissolved by heating and stirring at 70 ° C. for 8 hours as in Example 2, followed by filtration and red oil ballpoint pen. An ink composition was obtained.
상기와 같이 얻어진 실시예 1, 실시예 2, 실시예 3, 비교예 1, 비교예 2의 유성볼펜용 잉크조성물을 투명색 폴리프로필렌수지로 제조한 잉크저장관에 충진하여 볼경 0.7㎜, 1.0㎜, 1.2㎜의 볼펜 리필을 제조하고, 이를 동아연필주식회사에서 제조하여 판매중인 유성볼펜(상품명;마이볼)의 부품을 이용하여 시제품을 만들어외관검사와 필기시험을 행하고, 그 결과를 다음의 표 1에 나타낸다.The ink compositions for the oil ballpoint pens of Examples 1, 2, 3, Comparative Example 1 and Comparative Example 2 obtained as described above were filled in an ink reservoir tube made of transparent polypropylene resin, and the ball diameters of 0.7 mm, 1.0 mm, 1.2mm ballpoint pen refills were prepared, prototypes were made using parts of oil-based ballpoint pens (trade name: Myball) manufactured and sold by Dong-A Pencil Co., Ltd., and visual inspection and writing test were performed. Indicates.
상기에서 외관색은 육안으로 관찰하여 색상의 구별이 가능하고 선명한 잉크색을 나타내는 경우에는 "○"로 나타내고, 선명하진 않지만 색상구별이 가능한 경우에는 "△"로 나타내고, 색상구별이 어려운 경우에는 "×"로 나타낸다.In the above, the appearance color is visually observed and is indicated by "○" when the color can be distinguished and shows a vivid ink color, and when it is not clear but can be distinguished by "△", when color discrimination is difficult, " X ".
또 찌꺼기발생은 필기시험기에서 필기를 행하여 필기선에 찌꺼기가 발생하는 정도와 팁에서 잉크뭉침 상태를 육안으로 관찰하고, 필기선과 팁에 잉크뭉침이 없이 깨끗한 경우에는 "○"로 나타내고, 필기선에는 잉크찌꺼기가 없으나 팁에 잉크뭉침이 있는 경우에는 "△"로 나타내고, 팁에 잉크뭉침이 심하고 필기선에 찌꺼기가 떨어져 오염이 발생하는 경우에는 "×"로 나타낸다.Debris generation is performed by writing in a writing tester and visually observing the degree of debris on the writing line and the ink agglomeration state at the tip. When the ink is clean without ink agglomeration on the writing line and the tip, it is indicated as "○". When there is no ink residue but there is agglomeration at the tip, it is represented by "△", and when the ink is bad at the tip and the dregs fall to the writing line, it is represented as "x".
그리고 잉크흘러내림은 팁을 아래로 향하게 하여 50℃에서 24시간을 유지하면서 잉크의 흘러내린 상태를 육안으로 관찰하고, 잉크의 흘러내림이 발생하지 않는 경우에는 "○"로 나타내고, 잉크의 흘러내림이 약간 발생한 경우에는 "△"로 나타내고, 잉크의 흘러내림이 심한 경우에는 "×"로 나타낸다.The ink flow is visually observed when the ink flows down while keeping the tip downward and at 24 ° C. for 24 hours. When no ink flow occurs, the ink flow is indicated by “○” and the ink flows down. When this slightly occurs, it is represented by "(triangle | delta)", and when ink flows down severely, it is represented by "x".
상기한 표 1로부터 알 수 있는 바와 같이, 비교예 1 및 비교예 2에 비하여 본 발명에 따른 실시예 1, 실시예 2, 실시예 3 모두 외관색이나 찌꺼기 발생의 정도, 잉크흘러내림의 정도가 양호한 것으로 확인되었다.As can be seen from the above Table 1, compared with Comparative Example 1 and Comparative Example 2, Examples 1, 2, and 3 according to the present invention had the appearance color, the degree of dregs, and the degree of ink dripping It was confirmed to be good.
상기에서는 본 발명에 따른 유성볼펜용 잉크조성물의 바람직한 실시예에 대하여 설명하였지만, 본 발명은 이에 한정되는 것이 아니고 특허청구범위와 발명의 상세한 설명의 범위 안에서 여러가지로 변형하여 실시하는 것이 가능하고, 이 또한 본 발명의 범위에 속한다.In the above, a preferred embodiment of the ink composition for an oil ballpoint pen according to the present invention has been described, but the present invention is not limited thereto, and various modifications can be made within the scope of the claims and the detailed description of the invention. It belongs to the scope of the present invention.
상기와 같이 이루어지는 본 발명에 따른 유성볼펜용 잉크조성물에 의하면, 굴절률의 차이가 있는 고분자수지 미립자를 첨가하므로 잉크색이 표면으로 반사하여 외관색이 잉크색에 가깝게 시인되어 투명색의 잉크저장관(리필)을 사용하는 경우 별도의 색상부재를 사용하지 않아도 된다. 나아가 잉크색이 외관색으로 시인되므로 외관이 아름다운 유성볼펜을 제공하는 것이 가능하다.According to the ink composition for the oil ballpoint pen according to the present invention made as described above, since the polymer resin fine particles having a difference in refractive index is added, the ink color is reflected to the surface, and the external color is visually recognized to be close to the ink color. ), It is not necessary to use a separate color member. Furthermore, since the ink color is visually recognized as the external color, it is possible to provide an oil ballpoint pen with a beautiful external appearance.
또 첨가하는 고분자수지 미립자의 평균입자경이 대략 0.1∼10㎛ 정도 범위이므로, 필기감이 양호하고 부드럽다.Moreover, since the average particle diameter of the polymer resin microparticles | fine-particles to add is about 0.1-10 micrometers range, writing feeling is favorable and it is smooth.
그리고 본 발명에 따른 유성볼펜용 잉크조성물에 의하면, 필기시에 찌꺼기가 발생하지 않으며, 잉크의 흘러내림현상이 발생하지 않는 유성볼펜을 제조하는 것이 가능하다.In addition, according to the ink composition for the oil-based ballpoint pen according to the present invention, it is possible to manufacture the oil-based ballpoint pen which does not generate dregs during writing and does not cause the ink flowing down phenomenon.
Claims (4)
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| KR1020020078958A KR20040051111A (en) | 2002-12-12 | 2002-12-12 | Oil-Based Ink Composite for Ballpoint Pen |
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| Application Number | Priority Date | Filing Date | Title |
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| KR1020020078958A KR20040051111A (en) | 2002-12-12 | 2002-12-12 | Oil-Based Ink Composite for Ballpoint Pen |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212234A (en) * | 2014-09-10 | 2014-12-17 | 黄山新力油墨科技有限公司 | Alcohol-soluble type flexograhic printing ink |
| JP2017226180A (en) * | 2016-06-24 | 2017-12-28 | 株式会社パイロットコーポレーション | Aqueous ball point pen |
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| JPH06287493A (en) * | 1993-04-07 | 1994-10-11 | Canon Inc | Ink and recording device using the same |
| JPH07150098A (en) * | 1993-12-02 | 1995-06-13 | Toyobo Co Ltd | Water-based fluorescent ink |
| JPH08259862A (en) * | 1995-03-22 | 1996-10-08 | Toyobo Co Ltd | Ink jet recording ink |
| JPH0967531A (en) * | 1994-10-21 | 1997-03-11 | Hitachi Maxell Ltd | Fluorescent ink composition and fluorescent mark formed by the fluorescent ink composition |
| US6271285B1 (en) * | 1997-03-28 | 2001-08-07 | Seiko Epson Corporation | Ink composition for ink jet recording |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH06287493A (en) * | 1993-04-07 | 1994-10-11 | Canon Inc | Ink and recording device using the same |
| JPH07150098A (en) * | 1993-12-02 | 1995-06-13 | Toyobo Co Ltd | Water-based fluorescent ink |
| JPH0967531A (en) * | 1994-10-21 | 1997-03-11 | Hitachi Maxell Ltd | Fluorescent ink composition and fluorescent mark formed by the fluorescent ink composition |
| JPH08259862A (en) * | 1995-03-22 | 1996-10-08 | Toyobo Co Ltd | Ink jet recording ink |
| US6271285B1 (en) * | 1997-03-28 | 2001-08-07 | Seiko Epson Corporation | Ink composition for ink jet recording |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104212234A (en) * | 2014-09-10 | 2014-12-17 | 黄山新力油墨科技有限公司 | Alcohol-soluble type flexograhic printing ink |
| JP2017226180A (en) * | 2016-06-24 | 2017-12-28 | 株式会社パイロットコーポレーション | Aqueous ball point pen |
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