KR20030011454A - Multi-functional bioceramic composition and multi-functional bioceramic ball made of the same - Google Patents
Multi-functional bioceramic composition and multi-functional bioceramic ball made of the same Download PDFInfo
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- 239000003462 bioceramic Substances 0.000 title claims abstract description 28
- 239000000203 mixture Substances 0.000 title claims abstract description 18
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 11
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 11
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 11
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052709 silver Inorganic materials 0.000 claims abstract description 8
- 239000004332 silver Substances 0.000 claims abstract description 8
- 239000010977 jade Substances 0.000 claims abstract description 7
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 5
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 claims abstract description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 5
- 239000011734 sodium Substances 0.000 claims abstract description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 239000011148 porous material Substances 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 230000006872 improvement Effects 0.000 abstract description 3
- 241000251468 Actinopterygii Species 0.000 abstract description 2
- 238000009360 aquaculture Methods 0.000 abstract description 2
- 244000144974 aquaculture Species 0.000 abstract description 2
- 235000013361 beverage Nutrition 0.000 abstract description 2
- 230000036571 hydration Effects 0.000 abstract description 2
- 238000006703 hydration reaction Methods 0.000 abstract description 2
- 239000002689 soil Substances 0.000 abstract description 2
- 238000004065 wastewater treatment Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 19
- 150000001450 anions Chemical class 0.000 description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 description 10
- 239000011707 mineral Substances 0.000 description 10
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000010304 firing Methods 0.000 description 5
- 241000588724 Escherichia coli Species 0.000 description 4
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 4
- 229910010293 ceramic material Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
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- 239000012768 molten material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 241001360526 Escherichia coli ATCC 25922 Species 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003302 ferromagnetic material Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000005291 magnetic effect Effects 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000013212 metal-organic material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002887 superconductor Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/03—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
- C04B35/04—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
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Abstract
본 발명은 산화마그네슘(MgO) 30~35 중량%, 산화알루미늄(Al2O3) 15~25 중량%, 산화규소(SiO2) 18~22 중량%, 산화칼륨(K2O) 5~10 중량%, 옥(玉) 5~7 중량%, 산화제1철(Fe2O3) 3~6 중량%, 산화나트륨(Na2O3) 2~5 중량%, 탄산칼슘(CaCO3) 2~5 중량%, 맥반석 2∼5 중량%, 활성탄 2∼5 중량%, 화합수(H2O) 1~3 중량%, 은(Ag) 0.1 중량% 이하, 산화베릴륨(BeO) 0.1 중량% 이하, 산화티탄(TiO2) 0.05중량% 이하를 포함하는 다기능 바이오 세라믹 조성물 및 이를 이용한 세라믹볼에 관한 것이다. 본 발명의 바이오 세라믹은 정수기의 기능수화 즉 하우징 내부의 단계종류별로 쌓은 세라믹이 하나의 세라믹으로 대체가능하며, 수족관, 양어장 및 양식장등의 수질개선용으로 사용되며, 식품가공업, 식음료 업체, 하,폐수 처리, 토양개선 및 각종 기능성 세라믹 제품에 사용가능하다.In the present invention, magnesium oxide (MgO) 30 to 35% by weight, aluminum oxide (Al 2 O 3 ) 15 to 25% by weight, silicon oxide (SiO 2 ) 18 to 22% by weight, potassium oxide (K 2 O) 5 to 10 % By weight, 5-7% by weight of jade, 3-6% by weight of ferrous oxide (Fe 2 O 3 ), 2-5% by weight of sodium oxide (Na 2 O 3 ), calcium carbonate (CaCO 3 ) 2 ~ 5 wt%, elvanite 2-5 wt%, activated carbon 2-5 wt%, compounded water (H 2 O) 1-3 wt%, silver (Ag) 0.1 wt% or less, beryllium oxide (BeO) 0.1 wt% or less, Titanium oxide (TiO 2 ) relates to a multifunctional bio-ceramic composition containing 0.05% by weight or less and a ceramic ball using the same. Bio-ceramic of the present invention is a functional hydration of the water purifier, that is, the ceramic stacked in each step type in the housing can be replaced with a single ceramic, used for water quality improvement of aquariums, fish farms and aquaculture farms, food processing industry, food and beverage companies, summer, It can be used for wastewater treatment, soil improvement and various functional ceramic products.
Description
본 발명은 바이오 세라믹에 관한 것으로, 특히 다기능 바이오 세라믹 조성물 및 그 조성물로 제조된 다기능 바이오 세라믹볼에 관한 것이다.The present invention relates to a bio-ceramic, and more particularly, to a multi-functional bio-ceramic composition and a multi-functional bio-ceramic ball made of the composition.
일반적으로 세라믹이란 무기물질을 주원료로 사용하는 산화물, 질화물, 탄화물 등의 재료를 뜻하는 것으로 이러한 재료는 금속재료, 유기재료에 비하여 내식성, 내열성, 내마모성 등이 매우 크며 다양한 기능을 가지는 현대공업재료 중 가장 중요한 위치를 차지한다.In general, ceramic refers to materials such as oxides, nitrides, carbides, etc., which use inorganic materials as the main raw materials. These materials have much higher corrosion resistance, heat resistance, and abrasion resistance than metal materials and organic materials, and have various functions. Occupies the most important position.
컴퓨터의 기억소자 및 전자공업의 필수품인 반도체, 강유전체, 강자성체는 물론 원자력공업의 재료, 핵특성재료, 방사선 차폐재료, 항공우조공학의 특수 무기제품 등 세라믹의 용도는 매우 넓다. 우리 주변의 시멘트, 유리, 법랑, 내화물, 단열재, 건축용 점토제품, 도자기 등이 고전적인 세라믹의 예이며, TV의 CRT와 유리섬유 등은 우리생활에 없어서는 안되는 세라믹 제품들의 예이다.The use of ceramics such as semiconductors, ferroelectrics and ferromagnetic materials, which are essentials for computer memory devices and electronics industry, as well as materials for nuclear industry, nuclear characteristic materials, radiation shielding materials, and special inorganic products in aerospace engineering, is very wide. Cement, glass, enamel, refractory, insulation, building clay products, ceramics, etc. around us are classic ceramics, and TV CRT and fiberglass are examples of ceramic products that are indispensable in our lives.
이러한 세라믹을 제조방법에 따라 분류하면 내화재료, 소결재료, 수경재료, 용융재료, 단결정, 박막재료 등이 있다.When such ceramics are classified according to manufacturing methods, there are refractory materials, sintered materials, hydraulic materials, molten materials, single crystals, thin film materials, and the like.
내화재료란 일반적으로 고온에 견디는 물질을 말하는 것으로 1000 ℃ 이상의 고온에서 연화하지 않고 그 강도를 유지하며, 화학적 반응 등에도 견딜 수 있는 재료로서 내화벽돌 및 금속 용해용 도가니 등에 사용된다.A refractory material generally refers to a material that withstands high temperatures. The refractory material does not soften at a high temperature of 1000 ° C. or higher, and is used for refractory bricks and crucibles for melting metals.
소결재료란 분말체를 원하는 형상으로 성형한 후 가열하면 서로 단단히 결합하여 치밀화하는 현상을 이용하여 만든 재료로, 고체의 분말을 틀속에 넣고 프레스로 적당히 눌러 단단하게 만든 다음 그 물질의 녹는점에 가까운 온도로 가열했을 때, 분말이 서로 접한 부분에서 접합이 이루어지거나 일부가 증착하여 서로 연결되어 한 덩어리가 된다. 대부분의 세라믹 재료는 이와 같은 소결 공정을 거쳐 제조되며, 대표적인 예로서는 도자기와 파인세라믹 재료의 대표인 알루미나, 지르코니아, 탄화규소, 질화규소 등이 있다.A sintered material is a material made by forming a powder into a desired shape and then tightly bonding to each other when heated to make it compact. A solid powder is put in a mold and pressed by a press to make it hard and then close to the melting point of the material. When heated to a temperature, the powders are bonded together in contact with each other, or some of them are deposited and connected together to form a mass. Most ceramic materials are manufactured through this sintering process, and representative examples thereof include alumina, zirconia, silicon carbide, and silicon nitride, which are representative of ceramics and fine ceramic materials.
수경재료란 물과 반응하여 경화하는 재료로서 대표적으로 시멘트가 있다. 용융재료의 대표적인 예로서 유리가 있다. 유리는 무기질의 용융체를 냉각할 때 결정화하지 않고 단단한 상태로 과냉각될 수 있는 물질이다. 단결정이란 결정 전체가 일정한 결정축을 따라 규칙적으로 생성된 세라믹 재료, 다른 세라믹 재료들이 다결정체인데 비하여 하나의 결정으로만 이루어졌기 때문에 물질의 고유한 특성을 약화시키는 결함이 존재하지 아니하므로 가장 이상적인 재료이다.Hydroponic material is a material that reacts with water to cure and typically includes cement. Representative examples of molten materials include glass. Glass is a material that can be supercooled in a solid state without crystallization when cooling the inorganic melt. The single crystal is the ideal material because the whole crystal is a ceramic material that is regularly produced along a certain crystal axis, and other ceramic materials are made of only one crystal. .
박막재료란 기계 가공으로는 실현이 불가능한 두께 수 ㎛이하의 얇은 막을 여러 가지 방법으로 기판위에 형성시켜 목적하는 물성을 나타내게한 재료로서 반도체, 화합물 반도체, 절연체, 자성체, 초전도체 등의 박막이 있다.A thin film material is a material in which a thin film having a thickness of several micrometers or less, which cannot be realized by machining, is formed on a substrate in various ways to exhibit desired physical properties. There are thin films such as semiconductors, compound semiconductors, insulators, magnetic materials, and superconductors.
현재 상품화 되어있는 기능성 세라믹으로는 게르마늄, 맥반석등 원적외선 방사세라믹, 세레사이트-견운모를 가공 소성시킨 항균세라믹, 산화마그네슘, 산화칼슘 등 알칼리 발생 세라믹, 옥(玉)등 광물자체의 기능석, 음이온, 경수연화 등 단일 세라믹으로 사용중이다.Functional ceramics currently commercialized include germanium, far-infrared radiation ceramics such as ganban stone, antibacterial ceramics processed and calcined with cerite-mica, alkali-generating ceramics such as magnesium oxide, calcium oxide, functional stones of minerals such as jade, jade, It is used as a single ceramic such as hard water softening.
음이온이란 중성원자 또는 전자단에서 전자가 상실된 것을 양이온이라고 하고 전자가 더해진 것을 음이온이라고 한다. 물질에서 전자가 이탈하면 산화현상을 일으키게 되는데 이를 부패라고 한다. 인체는 대부분 수분으로 이루어져있고 이는 수소화 산소의 화합물이다. 그런데 수소는 전자를 상실하기 쉬운 성질을 가지고 있어 이 수소전자의 상실은 인체의 산화현상으로 노화의 원인과 건강의 약화를 가져온다. 현대의 이슈가 되고 있는 제3의 생명체, 공기중의 비타민 음이온의 지속적인 공급이 인체에 필요하다는 것은 의학계의 상식으로 되어있다.Anions are called cations for which electrons are lost in a neutral atom or electron group, and anions for which electrons are added are called anions. When electrons escape from the material, they cause oxidation, which is called decay. The human body consists mostly of water, a compound of hydrogenated oxygen. However, since hydrogen has a property of easily losing electrons, the loss of hydrogen electrons is an oxidation phenomenon of the human body, leading to aging and weakening of health. It is common sense in the medical community that the human body needs a constant supply of vitamins in the air, the third life that has become a modern issue.
높은 산에 올라가면 기분이 좋고 상쾌한 것은 음이온이 충만하기 때문이다. 제니센은 비록 도심지 같은 곳에서 사용하더라도 강한 자장의 영향으로 전자량이 중가되어 음이온으로 주위가 쌓여져 인체에 음이온을 충분히 공급할 수 있도록 해야만 인체나 동식물의 생성력과 건강이 강력히 유지된다. 보통 음이온 수치가 200을 넘으면 강한 이온활동을 하는 것이다.When you climb a high mountain, you feel good and refreshed because you are full of negative ions. Even though it is used in the city center, the strong magnetic field affects the amount of electrons and the surroundings are accumulated with negative ions so that the anion can be sufficiently supplied to the human body. Usually, when the anion level exceeds 200, it is a strong ion activity.
이렇듯 종래의 세라믹은 각 단일 세라믹으로 단일 기능을 발휘하였으나, 본 발명의 바이오 세라믹은 하나의 세라믹볼 자체가 여러 세라믹의 기능을 종합하므로 단순히 단일 특수광물을 분쇄 소성한 것이 아니라 여러 광물의 특성을 분석하고 서로간의 상호작용을 중시하여 얻은 성분조성물이다. 즉, 아무리 좋은 광물들이라도 서로 상호작용을 방해할 수도 있고 또 소성중 화합이 안되는 경우도 있음에 단순히 특수광물에서 추출한 성분만을 결합했다고 보면 안되며 함유량, 광물종류 등을 선별하여 작업을 하였으며, 각 성분은 화학성분이 아닌 천연 광물만을 사용하여 기술적 경제적 이점을 추구하였다.As described above, the conventional ceramics exhibited a single function with each single ceramic. However, the bio-ceramic of the present invention analyzes the characteristics of various minerals instead of simply pulverizing and firing a single special mineral since one ceramic ball itself combines the functions of several ceramics. It is a component composition obtained by placing importance on interactions with each other. In other words, no matter how good minerals may interfere with each other and may not be compatible during firing, it should not be regarded as simply combining components extracted from special minerals. Silver pursued a technical and economic advantage using only natural minerals, not chemicals.
따라서, 본 발명의 목적은 하나의 세라믹에서 단일 기능을 하던 바이오 세라믹이 아니라 하나의 세라믹으로 다기능을 종합적으로 강력 발생시키는 다기능 바이오 세라믹 조성물과 그 조성물로 제조된 다기능 바이오 세라믹볼을 제공하는데 있다.Accordingly, it is an object of the present invention to provide a multifunctional bioceramic composition and a multifunctional bioceramic ball made of the composition, which generates a multifunctional force strongly in a single ceramic rather than a bioceramic having a single function in one ceramic.
상기 목적뿐만 아니라 기존의 단일기능의 세라믹보다 각 기능의 작용이 좋은 바이오 세라믹을 제공하기 위하여, 본 발명의 다기능 바이오 세라믹 조성물은 산화마그네슘(MgO) 30~35 중량%, 산화알루미늄(Al2O3) 15~25 중량%, 산화규소(SiO2) 18~22 중량%, 산화칼륨(K2O) 5~10 중량%, 옥(玉) 5~7 중량%, 산화제1철(Fe2O3) 3~6 중량%, 산화나트륨(Na2O3) 2~5 중량%, 탄산칼슘(CaCO3) 2~5 중량%, 맥반석 2∼5 중량%, 활성탄 2∼5 중량%, 화합수(H2O) 1~3 중량%, 은(Ag) 0.1 중량% 이하, 산화베릴륨(BeO) 0.1 중량% 이하, 산화티탄(TiO2) 0.05중량% 이하를 포함하는 것에 특징이있다.In addition to the above purpose, in order to provide a bio-ceramic having a better function of each function than the conventional single-function ceramic, the multifunctional bio-ceramic composition of the present invention is magnesium oxide (MgO) 30 to 35% by weight, aluminum oxide (Al 2 O 3 ) 15-25 weight%, silicon oxide (SiO 2 ) 18-22 weight%, potassium oxide (K 2 O) 5-10 weight%, jade 5-7 weight%, ferrous oxide (Fe 2 O 3 ) 3-6% by weight, 2-5% by weight sodium oxide (Na 2 O 3 ), 2-5% by weight calcium carbonate (CaCO 3 ), 2-5% by weight elvanite, 2-5% by weight activated carbon, compound water ( H 2 O) 1 to 3% by weight, silver (Ag) 0.1% by weight or less, beryllium oxide (BeO) 0.1% by weight or less, and titanium oxide (TiO 2 ) 0.05% by weight or less.
상기 세라믹 조성물로 제조된 다기능 바이오 세라믹볼은 직경 3~7mm의 크기로 성형되며 다공성이 우수한 점에 특징이 있다.The multifunctional bio-ceramic ball made of the ceramic composition is shaped to a size of 3 to 7 mm in diameter and is characterized by excellent porosity.
본 발명의 바이오 세라믹 조성물 및 그 조성물로 제조된 세라믹볼을 좀 더 상세히 설명하면 다음과 같다.Referring to the bio-ceramic composition of the present invention and the ceramic ball made of the composition in more detail as follows.
본 발명에 따른 다기능의 바이오 세라믹 조성물은 산화마그네슘(MgO) 30~35 중량%, 산화알루미늄(Al2O3) 15~25 중량%, 산화규소(SiO2) 18~22 중량%, 산화칼륨(K2O) 5~10 중량%, 옥(玉) 5~7 중량%, 산화제1철(Fe2O3) 3~6 중량%, 산화나트륨(Na2O3) 2~5 중량%, 탄산칼슘(CaCO3) 2~5 중량%, 맥반석 2∼5 중량%, 활성탄 2∼5 중량%, 화합수(H2O) 1~3 중량%, 은(Ag) 0.1 중량% 이하, 산화베릴륨(BeO) 0.1 중량% 이하, 산화티탄(TiO2) 0.05중량% 이하를 포함한다.Multifunctional bioceramic composition according to the present invention is 30 to 35% by weight magnesium oxide (MgO), 15 to 25% by weight aluminum oxide (Al 2 O 3 ), 18 to 22% by weight silicon oxide (SiO 2 ), potassium oxide ( K 2 O) 5-10 wt%, jade 5-7 wt%, ferrous oxide (Fe 2 O 3 ) 3-6 wt%, sodium oxide (Na 2 O 3 ) 2-5 wt%, carbonic acid 2-5% by weight of calcium (CaCO 3 ), 2-5% by weight of ganbanite, 2-5% by weight of activated carbon, 1-3% by weight of compound water (H 2 O), 0.1% by weight or less of silver (Ag), beryllium oxide ( BeO) 0.1 wt% or less, titanium oxide (TiO 2 ) 0.05 wt% or less.
본 발명에 따른 다기능 바이오 세라믹볼은 상기 바이오 세라믹 조성물을 직경 3~7mm의 크기로 성형하며 우수한 다공성을 가진다.Multi-functional bio-ceramic ball according to the present invention is molded to the size of the bio-ceramic composition 3-7mm in diameter and has excellent porosity.
본 발명의 다기능 바이오 세라믹의 성형/소성과정은 다음과 같다.The molding / firing process of the multifunctional bioceramic of the present invention is as follows.
먼저, 각 천연광물을 적당히 분쇄한다. 이때, 은의 함유는 맥박석에 은도금한후 분쇄하므로 자연스런 믹싱작업이 포함된다. 적당히 분쇄된 각 광물을 200매쉬의 분말로 분쇄한후 볼형태로 성형한다. 이때 볼성형시 화합수에는 이온자화수, 원적외선방사수, 키토산의 혼합물을 사용한다. 그 다음 약 970℃에서 1차 소성을 실시한다. 다공질로 만들기 위해 와목을 함유시키며 소성도에서 녹아 없어지는 카본을 섞어 가열하면 그것들이 타고 없어진 자리가 다공질이 된다. 볼의 크기는 자유스럽게 조절되며, 크기가 작을수록 그 기능은 증대된다. 소성후 로에서 꺼내 상온에서 약 4시간가량 식힌다. 이때 볼의 성형과정에서 함량차이 및 이그로스가 가능하므로 사용목적에 따라 세라믹볼을 제조할 수 있다.First, each natural mineral is pulverized appropriately. At this time, the silver is pulverized after the silver plating on the pulse stone, so natural mixing is included. Each appropriately ground mineral is ground into 200 mesh powder and then shaped into a ball. In this case, a mixture of ionized water, far-infrared radiation water and chitosan is used as the compound water during ball molding. Then, primary firing is performed at about 970 ° C. In order to make it porous, it contains a tree and mixes the carbon which is dissolved in the baking degree and heats it, and the place where they burned out becomes porous. The size of the ball is freely adjusted, and the smaller the size, the greater the function. After firing, take it out of the furnace and let it cool for about 4 hours at room temperature. At this time, since the difference in content and e-gross is possible in the molding process of the ball, it is possible to manufacture a ceramic ball according to the purpose of use.
본 발명에 따른 다기능 바이오 세라믹볼의 특징을 살펴보면, pH 7.8이상의 천연알칼리로 원적외선 방사율이 92% 이상이고, 탈취율은 91% 이상, 음이온을 방사하며 열화상은 높으며, 항균작용으로 대장균은 98.7%, 녹농균 97.6%, 살모렐라는 98%가 제거되며 자화기능이 있다.Looking at the characteristics of the multi-functional bio-ceramic ball according to the present invention, the far-infrared emissivity is 92% or more with a natural alkali of pH 7.8 or more, the deodorization rate is 91% or more, radiates anion and high thermal image, E. coli 98.7% by antibacterial action, Pseudomonas aeruginosa 97.6%, salmonella 98% is removed and has a magnetization function.
이하 본 발명에서 제조된 바이오 세라믹 조성물을 이용한 세라믹볼을 한국원적외선협회에 의뢰하여 대장균 및 녹농균에 의한 항균시험, 방사율, 방사에너지, 음이온 발생수에 대하여 시험하였다.The ceramic ball using the bio-ceramic composition prepared in the present invention was commissioned by the Korea Far Infrared Association and tested for antibacterial test, emissivity, radiation energy, and anion generating water by E. coli and Pseudomonas aeruginosa.
먼저 본 시험에 사용된 바이오 세라믹은 산화마그네슘(MgO) 32 중량%, 산화알루미늄(Al2O3) 20 중량%, 산화규소(SiO2) 20 중량%, 산화칼륨(K2O) 6 중량%, 옥(玉) 5 중량%, 산화제1철(Fe2O3) 4 중량%, 산화나트륨(Na2O3) 3 중량%, 탄산칼슘(CaCO3) 3 중량%, 맥반석 2 중량%, 활성탄 2 중량%, 화합수(H2O) 1.5 중량%, 은(Ag) 1 중량%, 산화베릴륨(BeO) 0.483 중량%, 산화티탄(TiO2) 0.017 중량%의 조성으로 바이오 세라믹볼을 제조하였다.First of all, the bio ceramics used in this test were 32% by weight of magnesium oxide (MgO), 20% by weight of aluminum oxide (Al 2 O 3 ), 20% by weight of silicon oxide (SiO 2 ), and 6% by weight of potassium oxide (K 2 O). , 5% by weight of jade, 4% by weight of ferrous oxide (Fe 2 O 3 ), 3 % by weight of sodium oxide (Na 2 O 3 ), 3% by weight of calcium carbonate (CaCO 3 ), 2% by weight of elvan Bio ceramic ball was prepared in the composition of 2 % by weight, 1.5% by weight of H 2 O, 1% by weight of silver (Ag), 0.483% by weight of beryllium oxide (BeO), and 0.017% by weight of titanium oxide (TiO 2 ). .
시험 1Test 1
대장균 및 녹농균에 의한 항균시험Antibacterial test by Escherichia coli and Pseudomonas aeruginosa
시험방법 : KFIA-FI-1002Test Method: KFIA-FI-1002
사용균주 :Escherichia coliATCC 25922Use strain: Escherichia coli ATCC 25922
Pseudomonas aseruginosaATCC 15442 Pseudomonas aseruginosa ATCC 15442
시험결과Test result
(주) 1) Blank : 시료를 넣지 않은 상태에서 측정한 것이다.(Note) 1) Blank: Measured without sample.
2) 배지상의 균수는 희석배수를 곱하여 산출한 것이다.2) The number of bacteria on the medium is calculated by multiplying the dilution factor.
시험 2Test 2
방사율 및 방사에너지에 대한 시험Emissivity and Radiation Energy Test
본 시험은 37℃에서 시험하였으며 FT-IR Spectrometer를 이용한 BLACK BODY대비 측정결과이다.This test was conducted at 37 ℃ and it is a result of measuring the black body using FT-IR Spectrometer.
시험 3Test 3
음이온 방출에 대한 시험Test for Anion Release
시험방법 : KFIA-FI-1042Test Method: KFIA-FI-1042
시험편 : 10(g)Test piece: 10 (g)
전하입자 측정장치를 이용하여 실내온도 28 ℃, 습도 47%, 대기중 음이온수 106/cc 조건에서 시험하였으며 측정대상물에서 방출되는 음이온을 측정하여 단위체적당 이온수로 표시한 결과이다.It was tested under the condition of room temperature 28 ℃, humidity 47%, anion water 106 / cc using charge particle measuring device, and the anion released from the measured object was measured and expressed in the number of ions per unit volume.
시험결과Test result
상술한 바와 같이, 본 발명에서는 하나의 세라믹볼 자체가 여러 세라믹의 기능을 가지며, 단순히 단일 특수광물을 분쇄 소성한 것이 아니라 여러광물의 특성을 분석하고 서로간의 상호작용을 고려하여 바이오 세라믹볼을 제조할 수 있다.As described above, in the present invention, a single ceramic ball itself has a function of several ceramics, and not only a single special mineral is pulverized and fired, but also bio-ceramic balls are manufactured by analyzing the characteristics of various minerals and considering the interaction between them. can do.
또한, 본 발명에서 제조된 바이오 세라믹 볼은 정수기의 기능수화 즉 하우징 내부의 단계종류별로 쌓은 세라믹이 하나의 세라믹으로 대체가능하며, 수족관, 양어장 및 양식장등의 수질개선용으로 사용되며, 식품가공업, 식음료 업체, 하,폐수 처리, 토양개선 및 각종 기능성 세라믹 제품에 사용가능하다.In addition, the bio-ceramic ball produced in the present invention is a functional hydration of the water purifier, that is, the ceramic stacked in each step type inside the housing can be replaced with a single ceramic, used for improving the water quality of aquariums, fish farms and aquaculture farms, food processing industry, It can be used for food and beverage companies, sewage and wastewater treatment, soil improvement and various functional ceramic products.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020010046897A KR20030011454A (en) | 2001-08-03 | 2001-08-03 | Multi-functional bioceramic composition and multi-functional bioceramic ball made of the same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020010046897A KR20030011454A (en) | 2001-08-03 | 2001-08-03 | Multi-functional bioceramic composition and multi-functional bioceramic ball made of the same |
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| Publication Number | Publication Date |
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| KR20030011454A true KR20030011454A (en) | 2003-02-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020010046897A Ceased KR20030011454A (en) | 2001-08-03 | 2001-08-03 | Multi-functional bioceramic composition and multi-functional bioceramic ball made of the same |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030077914A (en) * | 2002-03-27 | 2003-10-04 | 김규태 | Bioceramic |
| KR100493886B1 (en) * | 2003-10-29 | 2005-06-10 | 김덕환 | Cataplasm for medical heat and compounds therefor |
| KR100702065B1 (en) * | 2006-03-28 | 2007-04-02 | 주식회사한국지씨엠 | Water treatment powder for simultaneous removal of suspended solids, nitrogen and phosphorus |
| KR100826315B1 (en) * | 2007-05-10 | 2008-04-30 | 강명수 | Ozonation Composition |
| KR100843350B1 (en) * | 2007-04-26 | 2008-07-03 | 오세원 | Antimicrobial clay composition having excellent water absorption and pollen containing same |
| KR20160014264A (en) | 2014-07-29 | 2016-02-11 | 이재환 | Environmental friendly ceramic ball and manufacturing method thereof |
-
2001
- 2001-08-03 KR KR1020010046897A patent/KR20030011454A/en not_active Ceased
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030077914A (en) * | 2002-03-27 | 2003-10-04 | 김규태 | Bioceramic |
| KR100493886B1 (en) * | 2003-10-29 | 2005-06-10 | 김덕환 | Cataplasm for medical heat and compounds therefor |
| KR100702065B1 (en) * | 2006-03-28 | 2007-04-02 | 주식회사한국지씨엠 | Water treatment powder for simultaneous removal of suspended solids, nitrogen and phosphorus |
| KR100843350B1 (en) * | 2007-04-26 | 2008-07-03 | 오세원 | Antimicrobial clay composition having excellent water absorption and pollen containing same |
| KR100826315B1 (en) * | 2007-05-10 | 2008-04-30 | 강명수 | Ozonation Composition |
| KR20160014264A (en) | 2014-07-29 | 2016-02-11 | 이재환 | Environmental friendly ceramic ball and manufacturing method thereof |
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