KR20010112574A - 여러 유기용매에 가용성인, 다양한 분자량의 폴리피롤제조방법 - Google Patents

여러 유기용매에 가용성인, 다양한 분자량의 폴리피롤제조방법 Download PDF

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Publication number: KR20010112574A
Authority: KR; South Korea
Prior art keywords: acid; polypyrrole; sodium salt; dopant; molecular weight
Prior art date: 2000-06-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

KR1020000031719A

Other languages

English (en)

Korean (ko)

Inventor

오응주

장관식

Original Assignee

오응주

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-06-09

Filing date

2000-06-09

Publication date

2001-12-20

2000-06-09 Application filed by 오응주 filed Critical 오응주

2000-06-09 Priority to KR1020000031719A priority Critical patent/KR20010112574A/ko

2001-06-09 Priority to PCT/KR2001/000982 priority patent/WO2002010251A1/fr

2001-06-09 Priority to AU64353/01A priority patent/AU6435301A/en

2001-12-20 Publication of KR20010112574A publication Critical patent/KR20010112574A/ko

Status Pending legal-status Critical Current

Links

229920000128 polypyrrole Polymers 0.000 title claims abstract description 116
238000000034 method Methods 0.000 title claims abstract description 41
239000003960 organic solvent Substances 0.000 title claims abstract description 27
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 50
239000002019 doping agent Substances 0.000 claims abstract description 34
239000000178 monomer Substances 0.000 claims abstract description 23
OGYMWUMPVDTUCW-UHFFFAOYSA-N 2,2-bis(2-ethylhexyl)-3-sulfobutanedioic acid Chemical compound CCCCC(CC)CC(C(O)=O)(C(C(O)=O)S(O)(=O)=O)CC(CC)CCCC OGYMWUMPVDTUCW-UHFFFAOYSA-N 0.000 claims abstract description 21
238000004519 manufacturing process Methods 0.000 claims abstract description 21
239000007800 oxidant agent Substances 0.000 claims abstract description 19
150000003839 salts Chemical class 0.000 claims abstract description 11
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 36
-1 Isoalkyl Chemical group 0.000 claims description 33
239000002253 acid Substances 0.000 claims description 28
KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 20
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 18
229910001870 ammonium persulfate Inorganic materials 0.000 claims description 18
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 16
159000000000 sodium salts Chemical class 0.000 claims description 16
125000000217 alkyl group Chemical group 0.000 claims description 15
125000004183 alkoxy alkyl group Chemical group 0.000 claims description 14
239000002904 solvent Substances 0.000 claims description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 12
238000006243 chemical reaction Methods 0.000 claims description 12
125000003342 alkenyl group Chemical group 0.000 claims description 11
125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 11
125000004391 aryl sulfonyl group Chemical group 0.000 claims description 11
230000007935 neutral effect Effects 0.000 claims description 11
238000003786 synthesis reaction Methods 0.000 claims description 11
125000003545 alkoxy group Chemical group 0.000 claims description 10
150000001343 alkyl silanes Chemical class 0.000 claims description 10
125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 10
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
238000006116 polymerization reaction Methods 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 8
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
230000015572 biosynthetic process Effects 0.000 claims description 7
239000012286 potassium permanganate Substances 0.000 claims description 7
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
125000003118 aryl group Chemical group 0.000 claims description 6
IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical group [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 claims description 6
RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 6
LHOWRPZTCLUDOI-UHFFFAOYSA-K iron(3+);triperchlorate Chemical compound [Fe+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O LHOWRPZTCLUDOI-UHFFFAOYSA-K 0.000 claims description 6
229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 6
230000001590 oxidative effect Effects 0.000 claims description 6
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 5
238000001035 drying Methods 0.000 claims description 5
239000000203 mixture Substances 0.000 claims description 5
230000035484 reaction time Effects 0.000 claims description 5
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
235000019253 formic acid Nutrition 0.000 claims description 4
150000002500 ions Chemical class 0.000 claims description 4
ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluenecarboxylic acid Natural products CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 claims description 4
LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 claims description 2
LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims description 2
WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 claims description 2
PTKWYSNDTXDBIZ-UHFFFAOYSA-N 9,10-dioxoanthracene-1,2-disulfonic acid Chemical compound C1=CC=C2C(=O)C3=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC=C3C(=O)C2=C1 PTKWYSNDTXDBIZ-UHFFFAOYSA-N 0.000 claims description 2
POPBYCBXVLHSKO-UHFFFAOYSA-N 9,10-dioxoanthracene-1-carboxylic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(=O)O POPBYCBXVLHSKO-UHFFFAOYSA-N 0.000 claims description 2
JAJIPIAHCFBEPI-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O JAJIPIAHCFBEPI-UHFFFAOYSA-N 0.000 claims description 2
229910019142 PO4 Inorganic materials 0.000 claims description 2
QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 claims description 2
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 2
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
VJVNWXUZZOBHRZ-UHFFFAOYSA-N benzene phosphoric acid Chemical compound P(=O)(O)(O)O.P(=O)(O)(O)O.P(=O)(O)(O)O.C1=CC=CC=C1 VJVNWXUZZOBHRZ-UHFFFAOYSA-N 0.000 claims description 2
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 2
229940092714 benzenesulfonic acid Drugs 0.000 claims description 2
150000007942 carboxylates Chemical group 0.000 claims description 2
CSVUNXDXKHELCR-UHFFFAOYSA-L disodium;3-carboxy-4-oxidobenzenesulfonate Chemical compound [Na+].[Na+].OC(=O)C1=CC(S([O-])(=O)=O)=CC=C1[O-] CSVUNXDXKHELCR-UHFFFAOYSA-L 0.000 claims description 2
UZVGFAUPMODEBR-UHFFFAOYSA-L disodium;9,10-dioxoanthracene-1,2-disulfonate Chemical compound [Na+].[Na+].C1=CC=C2C(=O)C3=C(S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=C3C(=O)C2=C1 UZVGFAUPMODEBR-UHFFFAOYSA-L 0.000 claims description 2
JOQAMSDLZYQHMX-UHFFFAOYSA-L disodium;dioxido-oxo-phenyl-$l^{5}-phosphane Chemical compound [Na+].[Na+].[O-]P([O-])(=O)C1=CC=CC=C1 JOQAMSDLZYQHMX-UHFFFAOYSA-L 0.000 claims description 2
PTEWEFISOFMTTD-UHFFFAOYSA-L disodium;naphthalene-1,2-disulfonate Chemical compound [Na+].[Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=C21 PTEWEFISOFMTTD-UHFFFAOYSA-L 0.000 claims description 2
239000012046 mixed solvent Substances 0.000 claims description 2
YOOYVODKUBZAPO-UHFFFAOYSA-N naphthalen-1-ylphosphonic acid Chemical compound C1=CC=C2C(P(O)(=O)O)=CC=CC2=C1 YOOYVODKUBZAPO-UHFFFAOYSA-N 0.000 claims description 2
YZMHQCWXYHARLS-UHFFFAOYSA-N naphthalene-1,2-disulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC=C21 YZMHQCWXYHARLS-UHFFFAOYSA-N 0.000 claims description 2
PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims description 2
LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
239000010452 phosphate Chemical group 0.000 claims description 2
230000000379 polymerizing effect Effects 0.000 claims description 2
WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 claims description 2
SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 claims description 2
MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims description 2
WEGDVNIPLOLRJC-UHFFFAOYSA-M sodium;naphthalene-1-carboxylate Chemical compound [Na+].C1=CC=C2C(C(=O)[O-])=CC=CC2=C1 WEGDVNIPLOLRJC-UHFFFAOYSA-M 0.000 claims description 2
HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 claims description 2
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 2
125000005138 alkoxysulfonyl group Chemical group 0.000 claims 7
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 5
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 5
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 5
239000011575 calcium Substances 0.000 claims 5
229910052791 calcium Inorganic materials 0.000 claims 5
229910052744 lithium Inorganic materials 0.000 claims 5
239000011777 magnesium Substances 0.000 claims 5
229910052749 magnesium Inorganic materials 0.000 claims 5
239000011591 potassium Substances 0.000 claims 5
229910052700 potassium Inorganic materials 0.000 claims 5
239000011734 sodium Substances 0.000 claims 5
229910052708 sodium Inorganic materials 0.000 claims 5
125000004448 alkyl carbonyl group Chemical group 0.000 claims 3
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims 2
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims 2
NNRUIHHKOIYTEO-UHFFFAOYSA-N (9,10-dioxoanthracen-1-yl)phosphonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2P(O)(=O)O NNRUIHHKOIYTEO-UHFFFAOYSA-N 0.000 claims 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims 1
229910052921 ammonium sulfate Inorganic materials 0.000 claims 1
235000011130 ammonium sulphate Nutrition 0.000 claims 1
235000010233 benzoic acid Nutrition 0.000 claims 1
229960004365 benzoic acid Drugs 0.000 claims 1
125000004432 carbon atom Chemical group C* 0.000 claims 1
239000000126 substance Substances 0.000 abstract description 10
239000006096 absorbing agent Substances 0.000 abstract description 6
239000000463 material Substances 0.000 abstract description 6
239000011248 coating agent Substances 0.000 abstract description 5
238000000576 coating method Methods 0.000 abstract description 5
238000010438 heat treatment Methods 0.000 abstract description 4
239000003990 capacitor Substances 0.000 abstract description 3
239000002121 nanofiber Substances 0.000 abstract description 3
230000003287 optical effect Effects 0.000 abstract description 3
239000005518 polymer electrolyte Substances 0.000 abstract description 3
230000035939 shock Effects 0.000 abstract description 3
238000003860 storage Methods 0.000 abstract description 3
230000005525 hole transport Effects 0.000 abstract description 2
238000005536 corrosion prevention Methods 0.000 abstract 1
238000001291 vacuum drying Methods 0.000 abstract 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 20
239000000243 solution Substances 0.000 description 19
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 16
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 13
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
239000012153 distilled water Substances 0.000 description 10
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 10
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
238000005259 measurement Methods 0.000 description 9
WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 8
229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 8
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 8
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 5
235000019441 ethanol Nutrition 0.000 description 5
RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 5
ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 4
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 4
229940071161 dodecylbenzenesulfonate Drugs 0.000 description 4
238000002848 electrochemical method Methods 0.000 description 4
229940035429 isobutyl alcohol Drugs 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
239000000843 powder Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
RHQDFWAXVIIEBN-UHFFFAOYSA-N Trifluoroethanol Chemical compound OCC(F)(F)F RHQDFWAXVIIEBN-UHFFFAOYSA-N 0.000 description 3
230000003993 interaction Effects 0.000 description 3
ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
DHIXFTVGHROZHD-UHFFFAOYSA-N 2-ethylhexane-1-sulfonic acid Chemical compound CCCCC(CC)CS(O)(=O)=O DHIXFTVGHROZHD-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000008901 benefit Effects 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
229940055577 oleyl alcohol Drugs 0.000 description 2
XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
239000003973 paint Substances 0.000 description 2
WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 2
125000000168 pyrrolyl group Chemical group 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
VVUYACHOOBAEDK-UHFFFAOYSA-N C(C)C(CC(C(C(=O)O)S(=O)(=O)O)(C(=O)O)CC(CCCC)CC)CCCC.S(=O)(=O)(O)C(C(=O)O)CC(=O)O Chemical compound C(C)C(CC(C(C(=O)O)S(=O)(=O)O)(C(=O)O)CC(CCCC)CC)CCCC.S(=O)(=O)(O)C(C(=O)O)CC(=O)O VVUYACHOOBAEDK-UHFFFAOYSA-N 0.000 description 1
238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
238000001157 Fourier transform infrared spectrum Methods 0.000 description 1
SCTPOPIAANRORZ-UHFFFAOYSA-N OP(O)(O)=O.O=C1c2ccccc2C(=O)c2ccccc12 Chemical compound OP(O)(O)=O.O=C1c2ccccc2C(=O)c2ccccc12 SCTPOPIAANRORZ-UHFFFAOYSA-N 0.000 description 1
HOCHJWBNDOKTEV-UHFFFAOYSA-K [Na+].C(C)C(CC(C(C(=O)[O-])S(=O)(=O)[O-])(C(=O)[O-])CC(CCCC)CC)CCCC.[Na+].[Na+] Chemical compound [Na+].C(C)C(CC(C(C(=O)[O-])S(=O)(=O)[O-])(C(=O)[O-])CC(CCCC)CC)CCCC.[Na+].[Na+] HOCHJWBNDOKTEV-UHFFFAOYSA-K 0.000 description 1
239000005456 alcohol based solvent Substances 0.000 description 1
235000019445 benzyl alcohol Nutrition 0.000 description 1
PVGGIXIKFFHCOS-UHFFFAOYSA-N bis(2-ethylhexyl) sulfate Chemical compound CCCCC(CC)COS(=O)(=O)OCC(CC)CCCC PVGGIXIKFFHCOS-UHFFFAOYSA-N 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
238000005266 casting Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
229920001940 conductive polymer Polymers 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
ZDGGJQMSELMHLK-UHFFFAOYSA-N m-Trifluoromethylhippuric acid Chemical compound OC(=O)CNC(=O)C1=CC=CC(C(F)(F)F)=C1 ZDGGJQMSELMHLK-UHFFFAOYSA-N 0.000 description 1
238000001465 metallisation Methods 0.000 description 1
229920000767 polyaniline Polymers 0.000 description 1
230000008569 process Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
125000000542 sulfonic acid group Chemical group 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical group C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

KR1020000031719A 2000-06-09 2000-06-09 여러 유기용매에 가용성인, 다양한 분자량의 폴리피롤제조방법 Pending KR20010112574A (ko)

Priority Applications (3)

Application Number	Priority Date	Filing Date	Title
KR1020000031719A KR20010112574A (ko)	2000-06-09	2000-06-09	여러 유기용매에 가용성인, 다양한 분자량의 폴리피롤제조방법
PCT/KR2001/000982 WO2002010251A1 (fr)	2000-06-09	2001-06-09	Technique de preparation de polypyrrole
AU64353/01A AU6435301A (en)	2000-06-09	2001-06-09	Method for making polypyrrole

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
KR1020000031719A KR20010112574A (ko)	2000-06-09	2000-06-09	여러 유기용매에 가용성인, 다양한 분자량의 폴리피롤제조방법

Publications (1)

Publication Number	Publication Date
KR20010112574A true KR20010112574A (ko)	2001-12-20

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Application Number	Title	Priority Date	Filing Date
KR1020000031719A Pending KR20010112574A (ko)	2000-06-09	2000-06-09	여러 유기용매에 가용성인, 다양한 분자량의 폴리피롤제조방법

Country Status (3)

Country	Link
KR (1)	KR20010112574A (fr)
AU (1)	AU6435301A (fr)
WO (1)	WO2002010251A1 (fr)

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KR100437198B1 (ko) *	2001-02-23	2004-06-23	장관식	높은 용해성을 갖는 수용성 폴리피롤 및 그것의 제조방법
KR100684034B1 (ko) *	2002-05-15	2007-02-16	이종영	전도성고분자 조성물 및 그 제조방법
WO2009091184A2 (fr)	2008-01-17	2009-07-23		Polymère conducteur soluble et son procédé de préparation
CN113713782A (zh) *	2021-08-16	2021-11-30	中化学朗正环保科技有限公司	用于废水吸附的银@聚吡咯复合材料及其制备方法和应用

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EP1688462B1 (fr) *	2003-11-28	2011-09-28	Idemitsu Kosan Co., Ltd.	Composition de polyaniline conductrice, procede de production et objet moule dans ladite composition
CN101893595A (zh) *	2010-06-25	2010-11-24	中国农业大学	一种化学修饰电极及其制备及快速测定植物油酸价的方法
CN114621463B (zh) *	2022-03-25	2023-07-28	武汉工程大学	一种具有压缩传感性能的聚氨酯聚吡咯复合凝胶及其制备方法

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2000
- 2000-06-09 KR KR1020000031719A patent/KR20010112574A/ko active Pending
2001
- 2001-06-09 WO PCT/KR2001/000982 patent/WO2002010251A1/fr not_active Ceased
- 2001-06-09 AU AU64353/01A patent/AU6435301A/en not_active Abandoned

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KR100437198B1 (ko) *	2001-02-23	2004-06-23	장관식	높은 용해성을 갖는 수용성 폴리피롤 및 그것의 제조방법
KR100684034B1 (ko) *	2002-05-15	2007-02-16	이종영	전도성고분자 조성물 및 그 제조방법
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CN113713782A (zh) *	2021-08-16	2021-11-30	中化学朗正环保科技有限公司	用于废水吸附的银@聚吡咯复合材料及其制备方法和应用
CN113713782B (zh) *	2021-08-16	2024-02-06	中化学朗正环保科技有限公司	用于废水吸附的银@聚吡咯复合材料及其制备方法和应用

Also Published As

Publication number	Publication date
WO2002010251A1 (fr)	2002-02-07
AU6435301A (en)	2002-02-13

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US20250051511A1 (en)	2025-02-13	Indanedione-based conjugated polymer for polymer solar cell donor, and polymer solar cell comprising same
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