KR20000050064A - The process of amino acid liquid compost from high concentration organic waste water and molasses - Google Patents
The process of amino acid liquid compost from high concentration organic waste water and molasses Download PDFInfo
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- KR20000050064A KR20000050064A KR1020000025691A KR20000025691A KR20000050064A KR 20000050064 A KR20000050064 A KR 20000050064A KR 1020000025691 A KR1020000025691 A KR 1020000025691A KR 20000025691 A KR20000025691 A KR 20000025691A KR 20000050064 A KR20000050064 A KR 20000050064A
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- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 9
- 235000013379 molasses Nutrition 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 5
- 238000000034 method Methods 0.000 title description 2
- 239000002361 compost Substances 0.000 title 1
- 239000010815 organic waste Substances 0.000 title 1
- 241000894006 Bacteria Species 0.000 claims abstract description 16
- 239000002351 wastewater Substances 0.000 claims abstract description 15
- 230000000243 photosynthetic effect Effects 0.000 claims abstract description 14
- 239000003337 fertilizer Substances 0.000 claims abstract description 12
- 238000000855 fermentation Methods 0.000 claims abstract description 8
- 230000004151 fermentation Effects 0.000 claims abstract description 8
- 239000005416 organic matter Substances 0.000 claims abstract description 8
- 230000001954 sterilising effect Effects 0.000 claims abstract description 8
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 4
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 4
- 238000005273 aeration Methods 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 6
- 239000011573 trace mineral Substances 0.000 claims description 6
- 235000013619 trace mineral Nutrition 0.000 claims description 6
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 235000013305 food Nutrition 0.000 claims description 4
- 244000144972 livestock Species 0.000 claims description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 4
- 241000233866 Fungi Species 0.000 claims description 3
- 244000005700 microbiome Species 0.000 claims description 3
- 230000001717 pathogenic effect Effects 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 229960002685 biotin Drugs 0.000 claims description 2
- 235000020958 biotin Nutrition 0.000 claims description 2
- 239000011616 biotin Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 235000010755 mineral Nutrition 0.000 claims description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 2
- 235000011009 potassium phosphates Nutrition 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000005286 illumination Methods 0.000 abstract description 2
- 230000004913 activation Effects 0.000 abstract 1
- 230000005070 ripening Effects 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 102000018997 Growth Hormone Human genes 0.000 description 1
- 108010051696 Growth Hormone Proteins 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 241001554096 Thiospirillum Species 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- 235000013527 bean curd Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000000122 growth hormone Substances 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F7/00—Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/08—Organic fertilisers containing added bacterial cultures, mycelia or the like
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
- C05F17/40—Treatment of liquids or slurries
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Fertilizers (AREA)
Abstract
본 발명은 고농도 유기물질 폐수를 수거하여 당밀과 혼합, 분해, 당화 및 중화 과정을 거치고 난 후, 고농도 유기물질 폐수 처리에 최적인 광합성 세균을 사용하여 발효 숙성 시키며 세균의 활성화를 위하여 멸균처리 후 일정 온도 및 조명을 유지시키면 고품질 최저가의 아미노산 액체 비료를 생산하는 방법을 제시한다.The present invention collects high concentration organic matter wastewater, undergoes mixing, decomposition, saccharification and neutralization with molasses, fermentation and ripening using photosynthetic bacteria that are optimal for treating high concentration organic matter wastewater, and then sterilization treatment for activation of bacteria. Maintaining temperature and illumination suggests a method for producing high quality, lowest cost amino acid liquid fertilizers.
Description
통상 액체 비료 제조 방법으로는 병원성 사상균을 살균하지 않고 자연 발효 숙성 제조 하거나 또는 살균을 하여 호기성 세균( Bacillus Bacteria) 등을 첨가한 후 대량의 공기를 공급하여 발효 숙성하고 있는 현실인바, 고농도 유기 물질 폐수에는 혐기성 세균인 광합성 세균이 아니고는 처리가 불가하며 많은 경비의 부담과 고 품질 및 대량 생산을 기대할 수 없었다.In general, liquid fertilizer manufacturing method does not sterilize pathogenic filamentous fungi, but it is a natural fermentation preparation or sterilization by adding aerobic bacteria (Bacillus Bacteria) and then fermenting and fermenting a large amount of air. No anaerobic bacteria, photosynthetic bacteria, could not be processed, and high cost and high quality and mass production could not be expected.
본 발명은 각종 산업체에서 발생되고 있는 고농도 유기 물질 폐수를 재활용하여 이를 농산물의 품질 개선을 위하여 광합성 세균을 이용한 고품질의 아미노산 액체 비료를 제조토록 함으로서 경제적 이점과 더불어 환경오염 감소 등에 일신된 효과를 제공하고자 하는 것이다.The present invention is to recycle high-concentration organic material wastewater generated in various industries and to produce high quality amino acid liquid fertilizer using photosynthetic bacteria to improve the quality of agricultural products. It is.
제1도는 본 발명 고농도 유기 물질 폐수와 당밀을 주제로 한 아미노산 액체 비료의 제조 공정도1 is a manufacturing process chart of the amino acid liquid fertilizer based on the present invention high concentration organic matter wastewater and molasses
도면의 주요 부호에 대한 설명Description of the main symbols in the drawings
1 당밀 저장조 2 축산 폐수 저장조1 Molasses reservoir 2 Livestock wastewater reservoir
3 식품 폐수 저장조 3a 이송 펌프3 Food Wastewater Reservoir 3a Transfer Pump
3b 이송 펌프 4 혼합 산화 폭기조3b transfer pump 4 mixed oxidizing aeration tank
5 혼합 산화 폭기조 5a 이송 펌프5 mixed oxidation aeration tank 5a transfer pump
6 브로와 7 분해 당화조6 bro and 7 decomposition saccharification tank
7a 교반기 7b 이송 펌프7a stirrer 7b transfer pump
8 중화조 8a 교반기8 neutralizer 8a stirrer
9 중화조 9a 이송 펌프9 Neutralizer 9a Transfer Pump
9b 교반기 10 자외선 살균조9b Stirrer 10 UV Sterilizer
11 보이러 12 발효조11 Boilers 12 Fermenters
12a 이송펌프 (순환용) 12b 이송 펌프12a transfer pump (for circulation) 12b transfer pump
13 숙성조 13a 이송 펌프13 Aging Bath 13a Transfer Pump
14 침전조 15 탈수기14 Sedimentation Tank 15 Dehydrator
15a 이송 펌프 16 미량 원소 혼합조15a transfer pump 16 trace element mixing tank
16a 교반기 17 미량 원소 혼합조16a Stirrer 17 Trace Elements Mixing Tank
17a 교반기 17b 이송 펌프17a stirrer 17b transfer pump
18 액체 비료 저장조 19 액체 비료 저장조18 Liquid Fertilizer Storage Tank 19 Liquid Fertilizer Storage Tank
본 발명은 식품, 수산, 축산, 축 분뇨, 두부, 우유, 기타 산업체에서 발생된 고농도 유기 물질폐수에 당밀을 첨가하여 혼합, 산화, 당화, 중화 후 자외선 조사(1000-1500 LUX)를 실시, 살균하며 광합성 세균(Thiospirillum, Rhodothiospirillum, 홍색비유황세균)을 폐수 혼합액에 첨가 후 발효, 숙성이 최대로 활성화되면 광합성 세균이 혼입 된 아미노산 액체 비료(비타민, 핵산, 성장 호르몬, 포도당)가 제조되어 이를 사용하면 작물에 흡수성이 빠르고, 뿌리도 충실해져 성장을 돕고, 재배된 과실 또는 야채의 맛, 색상, 신선도가 월등하며, 작물의 연작이 가능하고, 특히 냉해에도 강력한 효과가 있으며, 양질의 토양을 유지 할 수 있는 기대 효과를 유도한 것이다.The present invention adds molasses to high concentration organic matter wastewater generated from food, fisheries, livestock, livestock manure, tofu, milk, and other industries, and performs ultraviolet sterilization (1000-1500 LUX) after mixing, oxidation, saccharification, and neutralization. When the photosynthetic bacteria (Thiospirillum, Rhodothiospirillum, red non-sulfur bacteria) are added to the wastewater mixture and fermented and matured to the maximum, the amino acid liquid fertilizer (vitamin, nucleic acid, growth hormone, glucose) mixed with photosynthetic bacteria is prepared and used. Its fast absorbency in crops, its roots are enriched to support growth, the taste, color and freshness of cultivated fruits or vegetables are excellent, and it is possible to cultivate crops, especially in cold water, and to maintain good soil. It is expected to have the expected effect.
제 1실시 예First embodiment
고농도 유기 물질 폐수와 당밀을 주제로 한 아미노산 액체 비료의 제조 방법Manufacturing method of amino acid liquid fertilizer on the theme of high concentration organic matter wastewater and molasses
제 1도는 고농도 유기 물질 폐수와 당밀을 이용한 아미노산 액체 비료 재생 가공 공정도로서 당밀 저장조(1) 축산 폐수 저장조(2) 식품 폐수 저장조(3)에 원료 액을 이송 펌프(3a)로 각각 주입한다.FIG. 1 is a flow chart of amino acid liquid fertilizer regeneration process using high concentration organic matter wastewater and molasses.
이 때 제조 혼합 중량 비율은 당밀 2: 축산 폐수 4: 식품 폐수 4의 비율로 하여 이송 펌프(3b)로 혼합 산화 폭기조(4)(5)로 보내지며 부로와(6)를 작동하여 24시간 혼합 산화 폭기 하면 BOD 10,000 ppm가 5,000 ppm로 떨어진다.At this time, the weight ratio of the manufactured mixture is molasses 2: livestock wastewater 4: food wastewater 4, and is sent to the mixed oxidation aeration tank 4, 5 by the transfer pump 3b, and the broth 6 is operated for 24 hours. Oxidation aeration causes 10,000 ppm of BOD to drop to 5,000 ppm.
이 처리액을 이송 펌프(5a)로 분해 당화조(7)로 이송하여 PH가 3이 되도록 황산(H2SO4)을 주입 후 교반기(7a)를 2시간 작동 교반한다. 처리된 액체를 이송 펌프(7b)를 사용하여 중화조 (8)(9)로 보낸 후 탄산소다 (Na2CO3)를 첨가하여 PH가 7이 되도록 중화처리하며 교반기 (8a)(9b)를 2시간 작동 교반한다.The treatment liquid is transferred to the decomposition saccharification tank 7 by the transfer pump 5a, and sulfuric acid (H 2 SO 4 ) is injected to have a pH of 3, and then the agitator 7a is stirred for 2 hours. The treated liquid is sent to a neutralization tank (8) (9) using a transfer pump (7b), and then neutralized by adding sodium carbonate (Na 2 CO 3 ) to a pH of 7 and the agitator (8a) (9b) Stir for 2 hours of operation.
운전 초기에는 광합성 세균 500 ppm/ton과 미생물 성장소 (NH2)2CO3(0.02%), 인산제일칼륨(KH2PO4) (0.02%), 미강분 (0.02%),미네랄(0.01%), BIOTIN (0.02%)을 각각 자외선 살균조 상부로 투입하면서 중화된 처리수를 이송 펌프 (9a)로 자외선 살균조(1000-1500 LUX, 다단 향류식 유출기)(10)로 이송과 동시에 자외선 살균 조명을 실시하면 병원성, 사상균은 사멸되고 광 에너지를 기호하는 광합성 세균은 활성화되면서 자외선 살균조 배출구를 통하여 발효조(12)로 낙하 저장된다.In the early stages of operation, 500 ppm / ton of photosynthetic bacteria and microorganisms (NH 2 ) 2 CO 3 (0.02%), potassium phosphate (KH 2 PO 4 ) (0.02%), rice bran (0.02%), minerals (0.01%) ) And BIOTIN (0.02%) are added to the upper part of the UV sterilization tank, and the neutralized treated water is transferred to the UV sterilization tank (1000-1500 LUX, multi-stage counterflow type outlet) 10 with a transfer pump (9a). When the germicidal illumination is carried out, pathogenic, filamentous fungi are killed and photosynthetic bacteria that symbolize light energy are activated and dropped into the fermentation tank 12 through the ultraviolet sterilization outlet.
보이러(12)를 가동하여 발효조(12) 숙성조(13)의 액체의 온도가 30'C가 되도록 조절하여 발효조 (12)에는 하루에 한번 광합성 세균 500 ppm/ton을 첨가하여 5일간 계속하며 이송 펌프(12b)를 통하여 숙성조(13)로 보내지며 광합성 세균 50 ppm/ton을 2일간 첨가하여 숙성 완료 한다.Boiler 12 is operated to adjust the temperature of the liquid in the fermentation tank 12 and the aging tank 13 to 30'C. The fermentation tank 12 is added with 500 ppm / ton of photosynthetic bacteria once a day for 5 days. It is sent to the aging tank 13 through the transfer pump (12b) to complete the aging by adding 50 ppm / ton photosynthetic bacteria for 2 days.
숙성 완료 후, 이송 펌프(13a)를 통하여 침전조(14)로 보내지며 탱크 용량의 20% 정도를 발효조(12)로 반송하여 주고 80%의 량은 탈수기(15)로 탈수한다.After the aging is completed, it is sent to the settling tank 14 through the transfer pump 13a to return about 20% of the tank capacity to the fermentation tank 12 and the amount of 80% is dewatered by the dehydrator 15.
탈수된 처리수를 이송 펌프(15a)로 미량 원소 혼합조 (16)(17)로 이송하여 미량 원소 적정량을 첨가하여 교반기(16a)(17a)로 혼합 교반 후 이송 펌프(17b)로 광합성 세균이 혼용된 액체 아미노산 액체 비료를 저장조 (18)(19)로 이송 저장한다.The dehydrated treated water is transferred to the trace element mixing tank (16) (17) by the transfer pump (15a), an appropriate amount of trace elements is added, mixed and stirred by the stirrers (16a) (17a), and photosynthetic bacteria are transferred to the transfer pump (17b). Mixed liquid amino acid liquid fertilizer is transferred to reservoirs 18 and 19 for storage.
광합성 세균을 활용하여 생산된 유기질 액체 비료를 사용함으로써 토양의 산성화를 막고, 식물에 유익한 영양분 및 미생물의 공급으로 고품질의 농산물 증대에 기여하고, 각종 고농도 유기질 폐수를 원료로 하여 재활용함으로써 환경 오염을 줄이는데 일신된 효과를 보일 수 있다.By using organic liquid fertilizer produced using photosynthetic bacteria, it prevents acidification of soil, contributes to the increase of high quality agricultural products by supplying nutrients and microorganisms that are beneficial to plants, and reduces environmental pollution by recycling various high concentration organic wastewater as raw materials. The effect can be renewed.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20030016527A (en) * | 2001-08-21 | 2003-03-03 | 윤창규 | Production of microbial fertilizer from food waste and its microbial fertilizer |
| US7776124B2 (en) | 2005-10-14 | 2010-08-17 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| CN109265235A (en) * | 2018-09-06 | 2019-01-25 | 广西桉盛丰肥业有限公司 | Special fertilizer with insecticidal activity |
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| JPH05168456A (en) * | 1991-12-24 | 1993-07-02 | Teruo Higa | Method for treating waste liquor from production of alcohol |
| JPH0672788A (en) * | 1992-06-16 | 1994-03-15 | Sanko Sangyo:Yugen | Production of organic fermented matter |
| KR980009424A (en) * | 1996-07-12 | 1998-04-30 | 구희국 | Compressed bodies of composite soil conditioner and method for producing the same |
| KR100207061B1 (en) * | 1997-01-27 | 1999-07-01 | 김문수 | A feeding and fertilizing of microbial composition |
| KR100298785B1 (en) * | 1999-02-12 | 2001-09-13 | 이 종 헌 | Organic mixed fertilizer and its manufacturing method |
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|---|---|---|---|---|
| JPH05168456A (en) * | 1991-12-24 | 1993-07-02 | Teruo Higa | Method for treating waste liquor from production of alcohol |
| JPH0672788A (en) * | 1992-06-16 | 1994-03-15 | Sanko Sangyo:Yugen | Production of organic fermented matter |
| KR980009424A (en) * | 1996-07-12 | 1998-04-30 | 구희국 | Compressed bodies of composite soil conditioner and method for producing the same |
| KR100207061B1 (en) * | 1997-01-27 | 1999-07-01 | 김문수 | A feeding and fertilizing of microbial composition |
| KR100298785B1 (en) * | 1999-02-12 | 2001-09-13 | 이 종 헌 | Organic mixed fertilizer and its manufacturing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030016527A (en) * | 2001-08-21 | 2003-03-03 | 윤창규 | Production of microbial fertilizer from food waste and its microbial fertilizer |
| US7776124B2 (en) | 2005-10-14 | 2010-08-17 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| US7811352B2 (en) | 2005-10-14 | 2010-10-12 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| CN109265235A (en) * | 2018-09-06 | 2019-01-25 | 广西桉盛丰肥业有限公司 | Special fertilizer with insecticidal activity |
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