KR20000006600A - Preparing method for wastewater purifying agent - Google Patents
Preparing method for wastewater purifying agent Download PDFInfo
- Publication number
- KR20000006600A KR20000006600A KR1019980048274A KR19980048274A KR20000006600A KR 20000006600 A KR20000006600 A KR 20000006600A KR 1019980048274 A KR1019980048274 A KR 1019980048274A KR 19980048274 A KR19980048274 A KR 19980048274A KR 20000006600 A KR20000006600 A KR 20000006600A
- Authority
- KR
- South Korea
- Prior art keywords
- wastewater
- powder
- water
- loess
- quicklime
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000012629 purifying agent Substances 0.000 title abstract description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000000843 powder Substances 0.000 claims abstract description 35
- 239000000292 calcium oxide Substances 0.000 claims abstract description 30
- 238000000746 purification Methods 0.000 claims abstract description 22
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 12
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940082569 selenite Drugs 0.000 claims abstract description 11
- MCAHWIHFGHIESP-UHFFFAOYSA-L selenite(2-) Chemical compound [O-][Se]([O-])=O MCAHWIHFGHIESP-UHFFFAOYSA-L 0.000 claims abstract description 11
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 10
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000032683 aging Effects 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 235000012255 calcium oxide Nutrition 0.000 claims description 28
- 229910052732 germanium Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 4
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 4
- 239000004571 lime Substances 0.000 abstract 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000019645 odor Nutrition 0.000 description 7
- 239000010802 sludge Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 244000144972 livestock Species 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000005273 aeration Methods 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 238000003911 water pollution Methods 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 239000003053 toxin Substances 0.000 description 4
- 231100000765 toxin Toxicity 0.000 description 4
- 108700012359 toxins Proteins 0.000 description 4
- 238000007865 diluting Methods 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 230000005070 ripening Effects 0.000 description 3
- 239000013535 sea water Substances 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- 241000195628 Chlorophyta Species 0.000 description 2
- 241000206572 Rhodophyta Species 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- -1 rivers Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 230000008674 spewing Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009271 trench method Methods 0.000 description 1
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/005—Systems or processes based on supernatural or anthroposophic principles, cosmic or terrestrial radiation, geomancy or rhabdomancy
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/307—Treatment of water, waste water, or sewage by irradiation with X-rays or gamma radiation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Public Health (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Toxicology (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
본 발명은 자연에서 무한대의 추출과 대량가공할 수 있는 자연광물질과 황토를 이용하여, 신속하며 지속적인 정화작용을 일으키고, 저비용으로 대량 추출가능하며, 별도의 설비가 요구되지 않고 기존 정화시설을 이용할 수 있어 사용이 극히 간편하게 되며, 총량 규제없이 방대한 처리가 가능하여 해수의 정화능력까지 갖게 되며, 2차적인 수질오염의 염려가 없으며, 처리대상에 제한을 받지 않는 등의 효율적인 정화가 이루어지도록 한 오폐수 정화제 제조방법에 관한 것이다.The present invention utilizes natural minerals and loess which can be infinitely extracted and mass processed in nature, causing rapid and continuous purification, mass extraction at low cost, and can use existing purification facilities without requiring additional equipment. As it is extremely easy to use, it can be treated extensively without regulating the total amount, and it has the ability to purify sea water, and there is no fear of secondary water pollution, and it is effective to purify wastewater without restriction on the treatment target. It relates to a manufacturing method.
일반적으로 부양화되어가는 토양과 하천 및 상수원의 수질오염은 일상생활에서 배출하는 생활폐수를 비롯하여 산업폐기물, 축산폐기물 등에서 비롯되고 있다.In general, the water pollution of the soil, rivers, and water supplies that are being boosted comes from industrial wastes, industrial wastes, and livestock wastes.
이러한 각종 오폐수는 최종 종말처리장에서 일괄처리하는 것이 아니라 원인발생지에서 차단 정화시켜 파괴되어 가는 자연생태계와 하천, 호수의 수질오염을 근본적으로 해결하려는 추세이다.These various wastewaters are not processed at the end-of-the-end treatment plant, but are tending to fundamentally solve water pollution of natural ecosystems, rivers, and lakes that are being destroyed by being cleaned and destroyed at the cause.
종래의 오폐수 정화방법을 몇가지 예를 들면, 가장 일반적이고 처리수질이 대체로 양호하며 온도에 대한 적응력이 뛰어나는 표준활성 슬러지법, 폭기시간을 24시간 이상유지하도록 하여 유입수 부하변동에 적응력이 뛰어나고 장기폭기에 의한 미생물의 자산화로 슬러지 생산량이 적고 비교적 운전이 간편하게 되는 장기폭기법, 폭기조내에 접촉재를 충진하여 접촉표면에 부착된 다량의 미생물을 이용하여 유기물질을 처리하는 접촉폭기법, 토양내에 묻혀있는 트렌치의 모관으로 오,폐수를 이동시켜 토양미생물을 이용하여 유기물질을 처리하는 모관트렌치공법, 생활잡배수와 분뇨오수를 함께 모아서 혐기성 및 호기성 박테리아에 의해 분해시킨 후 염소살균처리한 다음 방류하는 합병정화처리공법, 및 펜톤산화와 전기전해에 의한 폐수처리방법 등을 들 수 있다.Some examples of conventional wastewater purification methods are the most common, generally treated water quality, standard activated sludge method that is highly adaptable to temperature, and maintains aeration time for more than 24 hours, and is adaptable to influent load fluctuations and long-term aeration. Long-term aeration method that produces less sludge and is relatively easy to operate due to the assetization of microorganisms by contact, Contact aeration method that processes organic materials using a large amount of microorganisms attached to the contact surface by filling contact material in aeration tank, buried in soil A capillary trench method that moves soil and wastewater to trenches to process organic materials using soil microorganisms, and collects various wastewater and manure sewage together, decomposes them by anaerobic and aerobic bacteria, and then disinfects them with chlorine and then discharges them. Treatment method, and wastewater treatment method by fenton oxidation and electrolysis Can be mentioned.
그러나 이러한 방법들은 다음과 같은 문제점을 안고 있었다.However, these methods had the following problems.
즉, 유입수 부하변동에 적응력이 떨어지고, 산소공급으로 인한 전력소비량이 많으며, 상태가 악화된 후 안정화되는 시간이 오래 걸리며, 운전이 복잡하여 유지관리가 어렵고, 전문기술이 필요하게 되는 등의 단점이 있었으며, 특히 각종 산업체로 부터 발생하는 난분해성 폐수는 상기 일반적으로 사용되는 화학적처리 및 생물학적처리 방법으로는 적정처리하기가 어렵게 되는 폐단이 있었다.In other words, it has low adaptability to influent load fluctuations, high power consumption due to oxygen supply, long stabilization after deterioration, complicated operation, difficult maintenance, and requires specialized skills. Particularly, the hardly degradable wastewater generated from various industries has a waste stage which is difficult to be properly treated by the chemical treatment and biological treatment methods generally used.
난분해성 폐수는 화학폐수, 염색폐수, 침출수 등으로 대표되며 이들 폐수는 현행처리방법으로는 환경규제치를 만족시키기에 한계가 있다.Refractory wastewater is represented by chemical wastewater, dyeing wastewater, and leachate, and these wastewaters have limitations in satisfying environmental regulations by current treatment methods.
다시 말해 종래에는 특히 고농도, 난분해성 유기물의 처리함에 있어서, 장시간의 처리시간이 요구되고, 처리수의 재사용이 불가능하며, 시설 및 운전유지비가 과다하게 되며, 폐수처리장의 설치면적 및 슬러지발생량이 증대되며, 최종 방류수에 따른 2차오염의 염려가 있게 되는 등의 효율적인 처리가 불가능하였다.In other words, in the prior art, especially in the treatment of high concentration, hardly decomposable organic matter, a long treatment time is required, the reuse of the treated water is impossible, the facility and operation maintenance costs are excessive, the installation area and the amount of sludge generation in the wastewater treatment plant are increased. In addition, efficient treatment such as fear of secondary pollution according to the final discharged water was not possible.
본 발명은 상술한 종래의 문제점을 해결하기 위하여 안출한 것으로서, 본 발명의 목적은 자연에서 무한대의 추출과 대량가공할 수 있는 자연광물질과 황토를 이용하여, 신속하며 지속적인 정화작용을 일으키고, 저비용으로 대량 추출가능하며, 별도의 설비가 요구되지 않고 기존 정화시설을 이용할 수 있어 사용이 극히 간편하게 되며, 총량 규제없이 방대한 처리가 가능하여 해수의 정화능력까지 갖게 되며, 2차적인 수질오염의 염려가 없으며, 처리대상에 제한을 받지 않는 등의 효율적인 정화가 이루어지도록 한 오폐수 정화제 제조방법을 제공하는 데 있다.The present invention has been made to solve the above-mentioned problems, the object of the present invention using natural minerals and loess that can be infinitely extracted and mass processed in nature, causing a rapid and continuous purification, and at a low cost It is possible to extract large quantities and use existing purification facilities without requiring additional facilities, and it is very simple to use, and it is possible to have extensive treatment without regulating the total amount, and to have seawater purification ability, and there is no fear of secondary water pollution. In addition, the present invention provides a method for preparing a waste water purifying agent which enables efficient purification such as being not limited to a treatment target.
상기 목적을 달성하기 위한 본 발명의 오폐수 정화제 제조방법은, 수분을 함유한 분말상의 황토에 산화칼슘과 산화마그네슘을 함유한 분말상의 생석회를 소정의 비율로 배합 및 숙성시켜 얻어지도록 한 것을 특징으로 한다.The wastewater purification agent manufacturing method of the present invention for achieving the above object is characterized in that it is obtained by blending and ripening powdered quicklime containing calcium oxide and magnesium oxide in a predetermined ratio in powdery ocher containing moisture. .
또한, 폐수에 함유된 중금속을 중화시키도록 상기 황토와 생석회에 미량의 유기성 게르마늄분, 아셀렌산염분, 맥반석을 추가로 혼입 및 숙성시켜 얻어지도록 한 것을 특징으로 한다.In addition, a small amount of organic germanium powder, selenite powder, and ganbanite are additionally mixed and aged in the loess and quicklime to neutralize heavy metals contained in the wastewater.
이하 본 발명의 바람직한 실시예를 상술하면 다음과 같다.Hereinafter, a preferred embodiment of the present invention will be described in detail.
본 발명의 오폐수 정화제 제조방법은, 황토분과 생석회분을 주성분으로 하여 이를 소정의 비율로 배합 및 숙성시켜 분말상의 정화제가 제조되도록 하였다.In the method for preparing wastewater purification agent of the present invention, ocher powder and quicklime powder are used as the main components, and the mixture is mixed and aged at a predetermined ratio to prepare a powdery purification agent.
상기 황토분은 수분율 10~20% 함유한 황토분이고, 생석회분은 산화칼슘90%이상 산화마그네슘 알카리성분 80%이상 함유한 것이다.The ocher powder is an ocher powder containing 10 to 20% of moisture content, and the quicklime is a calcium oxide containing 90% or more of magnesium oxide or more.
이 때 상기 황토와 생석회의 비율은 약 6:4인 것이 바람직하다.At this time, the ratio of the loess and quicklime is preferably about 6: 4.
또한, 오폐수에 함유된 중금속을 중화시키는 것이 가능하도록 상기 황토와 생석회에 미량의 유기성 게르마늄, 아셀렌산염(SELENITE), 맥반석을 추가로 혼입 및 숙성시켜 제조되도록 하였다.In addition, a small amount of organic germanium, selenite (SELENITE), and elvan were added to the loess and quicklime so as to neutralize heavy metals contained in the wastewater.
이 때 상기 유기성 게르마늄은 약 0.5%, 아셀렌산염은 약 0.5%, 맥반석은 약 2%인 것이 바람직하다.In this case, the organic germanium is preferably about 0.5%, the selenite is about 0.5%, and the elvan is about 2%.
상기 물질중 황토는 열에 강한 수많은 미생물이 함유되어 있어 많은 방사능을 방사시키거나 방부제 효력이 있음은 주지된 사실이고, 생석회는 산화칼슘이 주성분으로서 수분과 결합하면 높은 열을 발생시키게 되는 특성 및 악취를 제거시키는 효력이 있으며, 유기성 게르마늄은 원적외선 방사능 물질을 지속적으로 발생시켜 중금속을 중화시키는 효력이 있으며, 맥반석은 원수에 미네랄을 공급함과 동시에 원수를 청명하게 하는 효력이 있으며, 아셀렌산염분은 원수의 중금속을 중화하는 효력이 있다.It is well known that ocher contains a large number of microorganisms resistant to heat, and thus emits a lot of radioactivity or has a preservative effect. Quicklime has a characteristic and odor that generates high heat when calcium oxide is combined with moisture as a main component. Organic germanium has the effect of neutralizing heavy metals by continuously generating far-infrared radioactive material, and the macnite has the effect of supplying minerals to raw water and clearing the raw water. Has the effect of neutralizing heavy metals.
또한, 상기 황토를 비롯한 광물질은 자연에서 무한대로 추출함과 대량가공이 가능하다.In addition, the minerals, including the loess is possible to extract and mass processing to infinity in nature.
이러한 방법으로 얻어진 본 발명에 따른 오폐수 중화제를 이하에서는 일명 로미콜파우더(LOMICALL POWDER: LOESS MINERALIZATION CALL POWDER)라고 칭하기로 한다.The wastewater neutralizer according to the present invention obtained in this way will be hereinafter referred to as LOMICALL POWDER (LOESS MINERALIZATION CALL POWDER).
이하 보다 구체적인 실시예를 상술한다.Hereinafter, more specific embodiments will be described in detail.
[실시예 1]Example 1
수분을 10~20%함유한 분말상의 황토 60%에 산화칼슘90%이상 산화마그네슘 알카리성분 80%이상 함유한 분말상의 생석회 40%를 배합하고, 이를 교반기에 넣어 열이 완전히 상승한 때까지 서서히 교반시키는 숙성과정을 통해 서로간에 화학작용이 일어나게 하며, 그 숙정작용이 완전히 끝나고 열이 소멸된 후 얻어지도록 한다.60% of powdery yellow soil containing 10 ~ 20% water is mixed with 40% of quicklime containing powdered calcium oxide 90% or more and magnesium oxide component 80% or more and put into a stirrer to stir until heat is completely raised. Through the aging process, chemical reactions take place with each other, and are obtained after the completion of the fermentation process and heat dissipation.
이 때 상기 황토와 생석회를 배합 및 교반시키게 되면, 상기 황토분에 함유된 수분과 생석회의 작용에 의해 약 5분 경과후에는 약 250~300℃ 정도의 높은 열이 발생되면서 서로간에 숙성작용인 화학작용이 일어나게 되는 것이다.At this time, when the ocher and quicklime are mixed and stirred, after about 5 minutes due to the action of moisture and quicklime contained in the ocher powder, high heat of about 250-300 ° C. is generated, and the chemicals are aged. The action will take place.
[실시예 2]Example 2
수분을 10~20%함유한 분말상의 황토 60%에 산화칼슘90%이상 산화마그네슘 알카리성분 80%이상 함유한 분말상의 생석회 37%를 배합하고, 이에 분말상의 아셀렌산염 약 1%, 분말상의 맥반석 약 2%를 혼입시키며, 이를 교반기에 넣어 열이 완전히 상승한 때까지 서서히 교반시키는 숙성과정을 통해 서로간에 화학작용이 일어나게 하며, 그 숙정작용이 완전히 끝나고 열이 소멸된 후 얻어지도록 한다.60% powdered ocher containing 10 ~ 20% water is mixed with 37% powdered quicklime containing more than 90% calcium oxide and 80% magnesium oxide component, about 1% powdered selenite, powdered elvan Incorporate about 2%, and put it in the stirrer to allow the chemistry to take place with each other through the aging process to slowly stir until the heat is completely raised, and to be obtained after the aging is completely completed and the heat disappears.
이 때 상기 아셀렌산염 및 맥반석은 상기 황토분에 함유된 수분과 생석회의 작용에 의해 발생되는 약 250~300℃ 정도의 높은 열과 작용 및 숙성되면서 중금속까지 중화시킬 수 있는 로미콜파우더가 탄생된다.At this time, the selenite and elvan are produced with mica col powder capable of neutralizing heavy metals while being heated and acted upon by high heat of about 250 to 300 ° C. generated by the action of moisture and quicklime contained in the ocher powder.
[실시예 3]Example 3
수분을 10~20%함유한 분말상의 황토 60%와, 산화칼슘90%이상 산화마그네슘 알카리성분 80%이상 함유한 분말상의 생석회 37%와, 분말상의 아셀렌산염 약 0.5%와, 분말상의 맥반석 약 2%에 분말상의 유기성 게르마늄 약 0,5%를 더 혼입시키고, 이를 교반기에 넣어 열이 완전히 상승한 때까지 서서히 교반시키는 숙성과정을 통해 서로간에 화학작용이 일어나게 하며, 그 숙정작용이 완전히 끝나고 열이 소멸된 후 로미콜파우더가 얻어지도록 한다.60% of powdered ocher containing 10 to 20% water, 37% of powdered quicklime containing more than 90% of magnesium oxide and more than 80% magnesium oxide component, about 0.5% of powdered selenite, about 0.5% of powdery elvan 2% of organic organic germanium in powder is mixed with 0,5%, and it is put into a stirrer and gradually stirred until the heat is completely raised, thereby allowing chemical reactions to occur between each other. After extinction, the lomicol powder is obtained.
이 때 상기 아셀렌산염, 맥반석, 및 게르마늄은 상기 황토분에 함유된 수분과 생석회의 작용에 의해 발생되는 약 250~300℃ 정도의 높은 열과 작용 및 숙성되면서 보다 강력한 중금속까지 중화시킬 수 있는 로미콜파우더가 얻어지게 된다.At this time, the selenite, elvan, and germanium can be neutralized to a more powerful heavy metal while acting and aging at about 250 to 300 ° C. with high heat generated by the action of moisture and quicklime contained in the ocher powder. Powder is obtained.
상기와 같은 방법으로 제조된 본 발명의 작용효과를 설명한다.It demonstrates the effect of the present invention prepared by the above method.
본 발명의 오폐수 정화제인 로미콜파우더는 정화할 원수 1ton당 약 1kg이 투입된다.In the waste water purifying agent of the present invention, lomico powder is added about 1 kg per 1 ton of raw water to be purified.
그러면, 오폐수인 원수는 로미콜파우더와 급격히 반응하면서 신속한 시간(약 30초~3분) 내에 정화작용을 완료시키게 된다.Then, the raw water, which is the waste water, reacts rapidly with the Lomicol powder and completes the purification operation in a short time (about 30 seconds to 3 minutes).
즉, 원수에 함유된 각종 유해 유기물질 및 무기물질이 숙성으로 생성된 로미콜파우더의 구성인자들과 반응하면서 소멸되거나 침전되거나 무해인자로 환원 및 치환되는 작용에 의해 순식간에 맑은 물로 정화되고, 또한 악취까지 제거된다.That is, various harmful organic substances and inorganic substances contained in raw water are quickly purified by clear water by reacting with constituent factors of lomico powder produced by aging and reducing or replacing them with harmless factors. Odor is removed.
또한, 이 과정을 통해 정화된 물은 로미콜파우더를 구성하는 각종 광물질과의 작용에 의해 원적외선이 지속적으로 방사되고 미네랄이 형성되며 영양소가 공급되어져 살아있는 물로 활성화되고, 아울러 물의 투명도가 증대된다.In addition, the water purified through this process is activated by the action of the various minerals constituting the Lomicol powder in the far infrared rays, the minerals are formed, the nutrients are supplied to the living water, and the water transparency is increased.
한편, 본 발명의 로미콜파우더는 1회 투입으로 약 3~7회까지 반복사용이 가능하다.On the other hand, the lomi call powder of the present invention can be repeatedly used up to about 3 to 7 times by one input.
즉, 각종 오폐수 및 축산폐수를 탱크 또는 기존의 오폐수 처리시설에 담고 로미콜파우더를 투입하면 약 30초~3분이 경과 후 맑은 물로 침전이 이루어짐과 동시에 악취가 제거되고, 그 침전된 슬러지(SLUSH)에 다시 각종 오폐수 및 축산폐수 등을 담아 희석시켜 소정의 시간을 경과시키게 되면 다시 맑은 물로 침전이 이루어짐과 동시에 악취가 제거되는 것으로 약 3~6회까지의 반복정화가 가능하게 되며, 또한 최초 침전이 끝난 맑은 물에 다시 각종 오폐수 및 축산폐수를 담고 같은 방법으로 희석하여 약 30초~3분이 경과하게 되면 상기와 같이 다시 정화가 이루어지게 된다.In other words, if you put various wastewater and livestock wastewater in a tank or existing wastewater treatment facility, and put Lomicol powder, after about 30 seconds to 3 minutes, the precipitate is formed with clear water and the odor is removed and the precipitated sludge (SLUSH) After diluting with various wastewater and livestock wastewater in a predetermined time, it is possible to settle with clear water again and remove odors, and it is possible to repeat the purification up to 3 ~ 6 times. After finishing the clean water and diluting the wastewater and livestock wastewater in the same way and diluting in the same way, about 30 seconds to 3 minutes has elapsed as described above.
본 발명은 상기와 같이 정화되기 때문에 로미콜파우더가 혼합된 슬러지는 지속적으로 그 슬러지의 독성 및 악취를 제거하고 개선하게 되어 종래에서와 같이 침전된 슬러지의 처리가 특정 폐기물로 분류되지 않고, 퇴비 또는 쓰레기 매립지 등의 복토용으로 재활용될 수 있으며, 또한 정화된 맑은 물을 하천 등지에 방류하였을 경우 그 방류된 맑은 물이 그 하천 등지의 물과 작용하여 지속적으로 정화작용을 하게 되는 효과를 얻게 된다.Since the present invention is purified as described above, the sludge mixed with lomcol powder continuously removes and improves the toxic and odor of the sludge, so that the treatment of the sludge precipitated is not classified as a specific waste, but compost or The land can be recycled for landfills, such as landfills, and when the purified clear water is discharged into rivers, the discharged clear water works with the water of the streams to continuously purify.
한편, 본 발명의 정화제인 로미콜파우더는 연안어장, 해저생물, 각갑류 등을 소멸시키는 바다의 적조, 담수에서 부폐성 독소를 분출시켜 악취 및 수질을 오염시키며 식수원까지 지대한 피해를 유발시키는 녹조, 및 갯바위에 발생되어 정착성 수산생물 등을 서식불능케하는 백조현상 까지도 방역 소멸하고 정화시킬 수 있게 되고, 또한 육지의 하천 등에서 바다로 흘러들어 누적, 적층, 퇴적되어 오염된 바다의 갯벌, 담수의 오염된 퇴적층, 및 하천바닥의 오염된 퇴적층까지 자연정화작용이 이루어질 수 있게 작용 및 개선하여 자정능력을 되살리게 하며, 그 퇴적층의 악취를 제거하게 되는 놀라운 효력을 발휘하게 된다.On the other hand, lomkol powder of the present invention is a red algae of the sea to extinguish coastal fisheries, seabed creatures, shellfish, etc., green algae to spew odor and water quality by spewing obsolete toxins from fresh water, causing great damage to drinking water source, In addition, the swan phenomenon that occurs on the rocks of the sea and makes it impossible to inhabit the settled aquatic organisms can be prevented and removed. The contaminated sediment, and the contaminated sediment of the riverbed to the natural purification action can be performed and improved to restore the self-cleaning ability, and has an amazing effect of removing the odor of the sediment.
즉, 적조현상을 예로 들면, 종래에는 황토살포 방법이 있으나, 이 방법은 적조균을 파괴하지 못하고 단지 흡착하여 침강시키는 것으로서 황토가 바닥에 가라앉아 피복된 적조균이 부패되면서 암모니아, 유화수소, 매탄가스 등의 강한 독소를 분출하며 그 독소가 빈산소수괴 현상을 형성하여 생물이 서식할 수 없는 지경에 이루게 되는 문제점을 안고 있었다.In other words, red tide is an example of the conventional red clay spray method, but this method does not destroy the red tide bacteria, but only by adsorbing and settling. Strong toxins such as gas were ejected, and the toxins had a problem of forming an oxygen lump, which caused the organisms to inhabit.
그러나, 본 발명의 로미콜파우더는 종래의 단순한 항토살포방법과는 달리 적조균의 세포를 완전파괴하여 침강시키기 때문에 부패성 독소를 분출시키지 않으면서도 침강된 로미콜파우더가 오염된 갯벌을 개선하고 원상태로 복원시킬 수 있게 된다.However, the lomicol powder of the present invention, unlike the conventional simple anti-earth spraying method, completely destroys the cells of the red tide bacteria and settles the sedimentary romicol powder without spouting toxins without spouting, thus improving the tidal flat contaminated tidal flat. It can be restored.
예를 들어 본 발명의 로미콜파우더를 사용한 적조균 방재방법을 설명하면, 방역선에 탱크를 설치하고 펌프를 이용하여 바닷물을 끌어올린 다음 로미콜파우더를 그 물에 희석시켜 희석된 물을 고압살수기 또는 다단식 고압펌프를 이용한 소방호스로 방역선 등의 선박을 고속전진시키면서 전후좌우에서 대량으로 광범위하게 살포하는 방법이기 때문에 거의 모든 연안에 정박되어 있는 선박에 시설하여 본 발명품을 사용하할 경우 신속한 시간에 적조균의 방역제거 및 완전소멸 작업이 이루어질 수 있다.For example, the method for preventing red tide bacteria using the lomkol powder of the present invention, by installing a tank on the quarantine line, using a pump to pull up the sea water, and then dilute the lomcol powder in the water to pressurize the diluted water Alternatively, it is a method of spraying a large quantity of spraying vessels such as quarantine ships at high speed and widespread while using a multi-stage high pressure pump as a fire hose. Prevention and elimination of red tide bacteria can be done.
또한, 담수 및 호수 등의 녹조제거 및 완전소멸 작업도 상기와 같은 방법을 이용하거나 작은배에 시설하여 사용하여도 방역소멸 작업이 가능하게 되고, 이에 따라 종래의 방역작업에 비해 적은 비용으로 신속하고 효율적인 적조나 녹조를 제거소멸시킬 수 있다.Also, algae removal and complete annihilation operations such as freshwater and lakes are also possible by using the same method as described above or by installing them in small boats. Efficient red and green algae can be removed and destroyed.
한편, 본 발명의 로미콜파우더를 깨끗한 물에 희석하여 약 3일 동안 침전한 다음 맑은 물만을 추출해 그 물에 야채 등을 씻어 김치를 담글 경우 알맞은 산성을 유지하게 되어 실온에서도 장시간 보관할 수 있고, 항상 신선한 맛과 향을 유지시키게 된다.On the other hand, the lomicol powder of the present invention is diluted in clean water and precipitated for about 3 days, and then extracted with only clear water to wash vegetables and the like in water to maintain proper acidity, so that it can be stored for a long time even at room temperature. It keeps the fresh taste and aroma.
또한, 본 발명의 로미콜파우더는 화공약품이 아닌 순수한 광물질과 황토가 혼합 숙성된 물질이기 때문에 천연 방부제의 역할도 할 수 있다.In addition, the lomico powder of the present invention may also act as a natural preservative because it is a material that is mixed with aged pure minerals and loess, not chemicals.
참고로 아래의 표 1은 본 발명의 로미콜파우더를 사용하여 축산폐수를 정화시킨 결과의 시험데이터이고, 표 2는 본 발명의 로미콜파우더를 사용하여 하천수를 정화시킨 결과의 시험데이터이다.For reference, Table 1 below is test data of the result of purifying livestock wastewater using the lomicol powder of the present invention, and Table 2 is test data of the result of purifying river water using the lomicol powder of the present invention.
이상에서 설명한 바와 같이 본 발명의 오폐수 정화제 제조방법은, 수분을 함유한 분말상의 황토에 산화칼슘과 산화마그네슘을 함유한 분말상의 생석회를 소정의 비율로 배합 및 숙성시켜 얻어지게 하거나, 또는 폐수에 함유된 중금속을 중화시키도록 상기 황토와 생석회에 미량의 유기성 게르마늄분, 아셀렌산염분, 맥반석을 추가로 혼입 및 숙성시켜 얻어지도록 한 것에 의해, 자연에서 무한대의 추출과 대량가공이 가능하게 되고, 신속하며 지속적인 정화작용을 일으키며, 저비용으로 대량 추출가능하며, 별도의 설비가 요구되지 않고 기존 정화시설을 이용할 수 있어 사용이 극히 간편하게 되며, 총량 규제없이 방대한 처리가 가능하여 해수의 정화능력까지 갖게 되며, 2차적인 수질오염의 염려가 없으며, 처리대상에 제한을 받지 않는 등의 효과가 있다.As described above, the method for producing wastewater purifying agent of the present invention is obtained by mixing and ripening powdery quicklime containing calcium oxide and magnesium oxide in a predetermined ratio or containing it in wastewater. By incorporating and ripening a small amount of organic germanium powder, selenite powder, and ganbanite in the loess and quicklime to neutralize the heavy metals, it is possible to infinitely extract and process large quantities in nature. It causes continuous purification, extracts large quantities at low cost, and can use existing purification facilities without requiring additional equipment. There is no fear of secondary water pollution, and the effect is not restricted to the treatment target. All.
본 발명은 기재된 구체예에 대해서만 상세히 설명되었지만 본 발명의 사상과 범위내에서 변형이나 변경할 수 있음은 본 발명이 속하는 분야의 당업자에게는 명백한 것이며, 그러한 변형이나 변경은 첨부한 특허청구범위에 속한다 할 것이다.Although the invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that modifications and variations can be made within the spirit and scope of the invention, and such variations or modifications will belong to the appended claims. .
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019980048274A KR20000006600A (en) | 1998-11-11 | 1998-11-11 | Preparing method for wastewater purifying agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019980048274A KR20000006600A (en) | 1998-11-11 | 1998-11-11 | Preparing method for wastewater purifying agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20000006600A true KR20000006600A (en) | 2000-02-07 |
Family
ID=19557918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019980048274A Ceased KR20000006600A (en) | 1998-11-11 | 1998-11-11 | Preparing method for wastewater purifying agent |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR20000006600A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000074946A (en) * | 1999-05-27 | 2000-12-15 | 박재홍 | Waterworks the quality of water improvement purification powder making method |
| KR20030003955A (en) * | 2001-07-04 | 2003-01-14 | 양한춘 | The substance make improvement seawater and bottom of the coast |
| KR100450882B1 (en) * | 2001-12-27 | 2004-10-02 | 강철호 | Organic waste cleanser and method of recycling organic waste |
| KR100484561B1 (en) * | 2001-09-28 | 2005-04-22 | 주식회사 대동그린산업 | The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification |
-
1998
- 1998-11-11 KR KR1019980048274A patent/KR20000006600A/en not_active Ceased
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000074946A (en) * | 1999-05-27 | 2000-12-15 | 박재홍 | Waterworks the quality of water improvement purification powder making method |
| KR20030003955A (en) * | 2001-07-04 | 2003-01-14 | 양한춘 | The substance make improvement seawater and bottom of the coast |
| KR100484561B1 (en) * | 2001-09-28 | 2005-04-22 | 주식회사 대동그린산업 | The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification |
| KR100450882B1 (en) * | 2001-12-27 | 2004-10-02 | 강철호 | Organic waste cleanser and method of recycling organic waste |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0513352B1 (en) | Method of cleaning soil water | |
| US5614102A (en) | Method for purifying sewage | |
| OB et al. | Bioremediation of polluted wastewater influent: Phosphorus and nitrogen removal | |
| CA2431106A1 (en) | Electrolytic treatment of aqueous media | |
| Jochimsen et al. | Combined oxidative and biological treatment for separated streams of tannery wastewater | |
| US6207059B1 (en) | Process for treating wastewater | |
| NO321172B1 (en) | Use of soil alkali peroxides for immobilization of phosphate and heavy metals in water, soil, sediments and / or sludge | |
| Asia et al. | Characterization and treatment of sludge from the petroleum industry | |
| Abou Seeda et al. | Microorganism as a tool of bioremediation technology for cleaning waste and industrial water | |
| WO1999021801B1 (en) | Method for water purification based on the fenton reaction | |
| CA3133969A1 (en) | Sewage treatment method | |
| CN112707379A (en) | Method for treating high ammonia nitrogen wastewater and recovering ammonia and magnesium ammonium phosphate reactor suitable for method | |
| Amenu | Characterization of wastewater and evaluation of the effectiveness of the wastewater tratment systems | |
| KR20000006600A (en) | Preparing method for wastewater purifying agent | |
| Malovanyy et al. | Reagent purification of the processing industry enterprises effluents | |
| Affiang et al. | Environmental effects ofthe main constituents of tannery effluents (A review) | |
| RU2162059C1 (en) | Method of removing heavy metals from waste waters from solid domestic waste dumps | |
| KR20010106587A (en) | A reform material for polluted seawater or polluted shore of estuary greentos | |
| KR101306805B1 (en) | The method and Treatment process of Wastewater containing organic matter and nitrogen compounds-livestock wastewater, digestive wastewater, food wastewater | |
| KR20030048735A (en) | A disposal method of food garbage drainage | |
| Zaman et al. | Pharmaceutical waste water treatment and the efficiency of ETP in context of Bangladesh | |
| KR100414945B1 (en) | a method of biological waste water treatment | |
| Show | Seafood wastewater treatment | |
| CN215517101U (en) | Tannery effluent disposal system | |
| Middleton | Advanced wastewater treatment technology in water reuse |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19981111 |
|
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 19981111 Comment text: Request for Examination of Application |
|
| G15R | Request for early publication | ||
| PG1501 | Laying open of application |
Comment text: Request for Early Opening Patent event code: PG15011R01I Patent event date: 19991120 |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20000928 Patent event code: PE09021S01D |
|
| E601 | Decision to refuse application | ||
| PE0601 | Decision on rejection of patent |
Patent event date: 20010726 Comment text: Decision to Refuse Application Patent event code: PE06012S01D Patent event date: 20000928 Comment text: Notification of reason for refusal Patent event code: PE06011S01I |