KR102296880B1 - three-dimensional color - Google Patents
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- KR102296880B1 KR102296880B1 KR1020190159802A KR20190159802A KR102296880B1 KR 102296880 B1 KR102296880 B1 KR 102296880B1 KR 1020190159802 A KR1020190159802 A KR 1020190159802A KR 20190159802 A KR20190159802 A KR 20190159802A KR 102296880 B1 KR102296880 B1 KR 102296880B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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Abstract
본 발명은 그림물감에 관한 것으로, 보다 상세하게는 물, 착색제, 액상의 점증제로 이루어진 그림물감 조성물로 입체감있는 그림을 그릴 수 있고 장기적으로 점증현상, 분리현상, 침전현상, 응집현상 등이 적은 안전한 입체 그림물감을 제공하는 것을 특징으로 한다.
이를 위한 본 발명은, 그림물감에 있어서, 음이온성 고분자 물질 또는 양이온성 고분자 물질이 혼합된 점증제와 착색제, 습윤제로 이루어져 있다.The present invention relates to paints, and more particularly, it is possible to draw a three-dimensional picture with a color composition consisting of water, a colorant, and a liquid thickener, and in the long term, it is a safe It is characterized in that it provides a three-dimensional painting.
The present invention for this purpose is composed of a thickener, a colorant, and a wetting agent in which an anionic polymer material or a cationic polymer material is mixed in the coloring matter.
Description
본 발명은 그림물감에 관한 것으로, 보다 상세하게는 물, 착색제, 액상의 점증제로 이루어진 그림물감 조성물로 입체감있는 그림을 그릴 수 있고 장기적으로 점증현상, 분리현상, 침전현상, 응집현상등이 없는 경시안정성이 우수한 입체 그림물감을 제공하는 것을 특징으로 한다.The present invention relates to paints, and more particularly, it is possible to draw a three-dimensional picture with a color composition consisting of water, a colorant, and a liquid thickener, and in the long term, there is no thickening, separation, precipitation, agglomeration, etc. It is characterized in that it provides a three-dimensional painting with excellent stability.
통상적인 물감은 아라비아고무, 그리세린, 물엿, 가용성 전분의 호재 등에 안료와 수산화 알루미나, 침강성 바륨, 탄산바륨, 탄산칼슘, 탄산마그네슘 등을 혼합 조제하여서 되므로 내수성이 취약하여 같은 곳을 두 번 이상 증색하면 먼저 도색한 부분이 용해되므로 얼룩이 생겨 평면적인 그림물감으로 밖에 사용할 수 없었다.Conventional paints are prepared by mixing pigments, alumina hydroxide, precipitated barium, barium carbonate, calcium carbonate, and magnesium carbonate, etc. with the ingredients of gum arabic, glycerin, starch syrup, and soluble starch. If you do, the first painted part will dissolve, causing stains and you can only use it as a flat paint.
이와같은 결점을 보완하기 위해 기존의 물감을 사용할 때마다 합성수지 에멀존 또는 반죽상의 메디움(Medium)을 섞어 잘 타서 물감으로 사용하므로서 내수성을 가지게 하고 중색하여도 얼룩이지지 않게하여 입체화가 되도록 한 물감이 있으나 이것은 반죽상의 메디움 자체가 ＂폴리아크릴산 에스텔 에밀졸＂ ＂폴리비닐알콜＂ ＂폴리옥시에틸렌 오레일 에에테르＂ 등을 혼합한 것이므로 개봉하면 쉬이 굳어지고 사용할 때마다 수채화의 물감에 타서 사용하기에 매우 불편하였고, 쓰다 남은 그림물감도 쉬이 굳어져 폐기해야하는 등의 결점이 있었다.In order to compensate for these drawbacks, whenever using existing paints, a synthetic resin emulsion or dough-like medium is mixed and used as a paint to have water resistance, and there are paints that are made three-dimensional by not staining even when mixed. This is because the dough-like medium itself is a mixture of “polyacrylic acid ester emylsol”, “polyvinyl alcohol” and “polyoxyethylene oleyl ether”, so it hardens easily when opened and gets burned with watercolor paint every time you use it, making it very inconvenient to use. Also, there were drawbacks such as the use of paints that were left behind were easily hardened and had to be discarded.
공지의 예로서, 채색시 입체감을 표현할 수 있도록 대한민국 등록특허 제10-154837900호가 개시되어 있다.As a known example, Korean Patent Registration No. 10-154837900 is disclosed to express a three-dimensional effect when coloring.
상기 공지의 예는 황토를 이용하여 접착력과 강도가 강하며, 다양하게 디자인의 입체 표현을 할 수 있는 장식용 점착성 젤 조성물에 관한 것으로, 전체 조성물 100 중량부에 대하여 황토 55～65 중량부, 물 10～20 중량부, 바인더 20～30 중량부를 포함하고 있다.The known example relates to a decorative adhesive gel composition that has strong adhesion and strength using loess and can express various designs in three dimensions, and 55 to 65 parts by weight of loess, 10 parts by weight of water, based on 100 parts by weight of the total composition. -20 parts by weight and 20-30 parts by weight of the binder.
그러나, 황토 등은 시간의 경과에 따라 불안정하여 분리현상, 침전형상, 응집현등의 문제가 발생하고, 물감 제조시에도 황토가 분말상으로 공급되어 물에 용해하기가 어려워 장시간 교반해주거나, 작업시 분말이라 비산에 의해 작업자의 건강에도 문제가 된다. However, loess, etc., is unstable over time, causing problems such as separation, sedimentation, and agglomeration. Because it is a powder, it is a problem for the health of workers due to scattering.
또한, 그림물감에는 점증제로서 일반적으로 잔탄검, 알긴산나트륨, 셀룰로스같은 분말상의 점증제를 사용하고 있으나, 이들 분말상 점증제는 물에 용해하기가 어려워 1시간 이상 장시간 교반해주거나, 가열을 해야 하는 제조상의 어려움이 있고, 또한 작업시 분말이라 비산에 의해 작업자 건강에도 문제가 된다. In addition, as thickeners for coloring, powdery thickeners such as xanthan gum, sodium alginate, and cellulose are generally used. There is a difficulty in manufacturing, and it is also a problem for the health of workers due to scattering because it is a powder during work.
나아가, 흐름성을 적게하려고 고점도의 물감을 만들기 위해 더 많은 양의 점증제를 넣어 주면 장시간 교반, 가열등의 문제점들이 배가 된다.Furthermore, if a larger amount of thickener is added to make high-viscosity paint to reduce flowability, problems such as stirring and heating for a long time are doubled.
본 발명은 전술한 문제점을 해결하기 위해 안출된 것으로서, 본 발명은 음이온 또는 양이온성의 고분자물질을 액상의 용매에 유화제를 사용하여 에멀젼 형태로 그림물감에 점증제로 제공하여, 사용시 흐름성이 없는 고점도의 그림물감이 되어 입체감있는 그림을 그릴 수 있고 장기적으로도 점증현상, 분리현상, 침전현상, 응집현상 등이 없는 경시적으로 안정한 입체 그림물감을 제공한다.The present invention has been devised to solve the above problems, and the present invention provides an anionic or cationic polymer material in an emulsion form using an emulsifier in a liquid solvent as a thickener for coloring, which has no flowability when used. It becomes a paint color and provides a three-dimensional picture that is stable over time without gradation, separation, sedimentation, or agglomeration in the long term.
전술한 목적을 달성하기 위한 본 발명은, 물에 음이온성 고분자 물질 또는 양이온성 고분자 물질이 혼합된 액상의 점증제(애멀젼형태)와 착색제, 습윤제 등으로 이루어진 것을 특징으로 한다.The present invention for achieving the above object is characterized in that it consists of a liquid thickener (emulsion form) in which an anionic polymer material or a cationic polymer material is mixed with water, a colorant, a wetting agent, and the like.
또한, 본 발명에 적용된 그림물감을 100 중량부로 할 때 액상의 점증제 0.5~20 중량부, 착색제는 0.5~20 중량부, 습윤제 5~30 중량부, 물 50~90 중량부가 적용되는 것을 특징으로 한다.In addition, when the coloring applied in the present invention is 100 parts by weight, 0.5-20 parts by weight of a liquid thickener, 0.5-20 parts by weight of a colorant, 5-30 parts by weight of a wetting agent, and 50-90 parts by weight of water are applied. do.
또한, 본 발명에 적용된 점증제는 용매와 유화제를 더 포함하여 조성되는 것을 특징으로 한다.In addition, the thickener applied to the present invention is characterized in that the composition further comprises a solvent and an emulsifier.
본 발명에 따른 입체 그림물감은 흐름성이 없기 때문에 입구가 넓은 저장용기를 사용하여 남김없이 100% 사용이 가능하고, 용기가 엎어져도 용기로부터 흘러내리지 않기 때문에 주변을 오염시키지 않는 효과가 발생한다.Since the three-dimensional paint according to the present invention has no flow, it can be used 100% without leaving a storage container with a wide mouth, and does not flow down from the container even if the container is overturned, so it does not pollute the surroundings.
또한, 흐름성이 없기 때문에 손가락이나 붓으로 많은 양을 찍어 사용해도 사용중에 흘러내리지 않아 안심하고 사용이 가능하고, 나아가 적당량을 덜어서 손으로 던질 수 있는 놀이도 가능하며, 손가락이나 붓 등으로 도포시에도 매끄럽게 발림성도 양호한 효과가 발생한다.In addition, since there is no flow, it does not flow down during use even if you take a large amount with your finger or brush, and you can use it with confidence. It also produces a smooth application and good effect.
이하, 본 발명에 따른 하나의 바람직한 실시 예를 통해 상세히 설명한다.Hereinafter, it will be described in detail through one preferred embodiment according to the present invention.
먼저, 본 발명을 설명하기 전 본 발명에 적용된 구성성분에 대하여 설명한다.First, the components applied to the present invention will be described before describing the present invention.
본 발명에 적용된 용제(용매)는 다른 물질을 용해시켜서 균일한 용액을 만드는 액체로, 물감 제작에 사용될 경우, 고체를 녹여 액상으로 하거나 점도가 높은 액체의 점도를 낮추는데 사용된다.The solvent (solvent) applied to the present invention is a liquid that makes a uniform solution by dissolving other substances. When used in the production of paints, it is used to melt a solid into a liquid or to lower the viscosity of a high-viscosity liquid.
구체적으로 수지를 비롯한 각종 고착제의 용해 및 제작에 사용하는 물감의 점도조성, 표면의 광택개선, 밑층과의 점착성의 조정 등에 사용한다.Specifically, it is used for the viscosity composition of paints used for dissolving and manufacturing various fixing agents including resins, improving the gloss of the surface, and adjusting the adhesion with the underlying layer.
이러한 용제에는 고착제의 차이에 따라 유성(유기용제)과 수성(물)이 있다.These solvents are classified into oil-based (organic solvent) and water-based (water) depending on the difference in the fixing agent.
본 발명에 적용된 수성 용제는 물이 사용되며, 물은 증류수를 사용한다. 증류수는 물을 가열했을 때 발생하는 수증기를 모아서 만든 것으로 완전 순수물의 PH7의 중성이 바람직하고, Water is used as the aqueous solvent applied to the present invention, and distilled water is used as the water. Distilled water is made by collecting water vapor generated when water is heated.
지하수나 수돗물은 유기물과 무기물, 미생물 등이 함유되어 있기 때문에 이를 사용하게 되면 물성 변화나 화학반응이 일어나기 때문이다. This is because groundwater or tap water contains organic matter, inorganic matter, and microorganisms.
순도가 높은 물이 필요할 때는 한번 증류한 물을 1차 증류수, 두 번 증류한 것을 2차 증류수, 세 번 증류한 것을 3차 증류수라고 하는데 수채화 물감을 만들 때는 3차 증류수를 사용하는 것이 좋다.When high-purity water is needed, water distilled once is called primary distilled water, twice distilled water is called secondary distilled water, and distilled water three times is called tertiary distilled water.
본 발명에서는 물감을 100 중량부로 할 때, 물 50~90 중량부가 적용되는 것이 바람직하다.In the present invention, when 100 parts by weight of the paint, 50 to 90 parts by weight of water is preferably applied.
습윤제는 글리세린, 프로필렌글리콜 같은 글리콜류를 단독 또는 혼합하여 사용할 수 있고, 물과 혼합되어 사용될 수도 있다.The wetting agent may be used alone or in combination with glycols such as glycerin and propylene glycol, or may be used in combination with water.
본 발명에 적용된 습윤제는 물 또는 글리콜류를 단독 내지 혼합하여 사용할 수 있으며, 투입량은 완성된 물감을 100 중량부로 할 때 5 ~ 30 중량부가 투입된다.The wetting agent applied to the present invention can be used alone or by mixing water or glycols, and the amount is 5 to 30 parts by weight when 100 parts by weight of the finished paint is added.
본 발명에 적용되는 점증제는 점도를 유지하거나 제품의 안정성 유지, 안료의 입자 고착 및 광택효과를 위해 사용되는 것으로, 점증제로 음이온 또는 양이온성의 고분자물질을 액상의 용매에 유화제를 사용하여 에멀젼 형태로 만든 액상의 점증제를 사용하면 흐름성이 없는 신규의 입체감(볼륨감)있는 그림물감 조성물이 가능하다.The thickener applied to the present invention is used for maintaining viscosity or product stability, fixing particles of pigments and lustering effect. By using the prepared liquid thickener, it is possible to create a new three-dimensional (volume) color composition without flow.
본 발명의 액상 점증제는 음이온성 고분자물질 또는 양이온성 고분자물질, 용매, 유화제로 구성된 조성물이다.The liquid thickener of the present invention is a composition composed of an anionic or cationic polymer, a solvent, and an emulsifier.
액상점증제에 사용되는 음이온성 고분자물질은 소듐폴리아크릴레이트, acryloyldimethyl Taurate Copolymer, ATBS copolymer 등을 단독 또는 혼합하여 완성된 점증제를 100 중량부로 할 때, 1~40 중량부가 적용되며, 양이온성 고분자물질은 Polyquaternium 등을 1~40 중량부로 사용가능하다.The anionic polymer material used in the liquid thickener is 100 parts by weight of the thickener prepared by mixing sodium polyacrylate, acryloyldimethyl Taurate Copolymer, ATBS copolymer, etc. alone or mixed, 1 to 40 parts by weight is applied, and cationic polymer The material can be used in an amount of 1 to 40 parts by weight of Polyquaternium or the like.
액상 점증제에 사용하는 용매(케리어액체)는 미네랄오일 (mineral oil), isohexadecane, Hydrogenated Polydecene, Octylstearate, Propylene Glycol Dicaprate/Dicaprylate (에스터오일)등을 단독 또는 혼합하여 10~80 중량부 사용가능하며, 액상 점증제에 사용하는 유화제로서는 트리데실알코올의 폴리에칠렌글라이콜에테르를 1~30 중량부를 사용하여 액상의 점증제를 수득한다. The solvent (carrier liquid) used in the liquid thickener can be used alone or in 10 to 80 parts by weight by mixing mineral oil, isohexadecane, Hydrogenated Polydecene, Octylstearate, Propylene Glycol Dicaprate/Dicaprylate (ester oil), etc. As an emulsifier used in the liquid thickener, 1 to 30 parts by weight of polyethylene glycol ether of tridecyl alcohol is used to obtain a liquid thickener.
일예로 액상 점증제는 음이온고분자 물질로 SNF사의 Flocare ET36, 76, 100등이 양이온고분자 물질로는 SNF사의 Flocare ET1037, ET1537G 등이 적용될 수 있다.For example, the liquid thickener may be an anionic polymer material, such as SNF's Flocare ET36, 76, or 100, and SNF's Flocare ET1037, ET1537G, etc. may be applied as a cationic polymer material.
또한, 이러한 액상 점증제의 사용량은 물감을 100중량부로 할 때 0.5~20 중량부 보다 바람직하게는 1~10 중량부가 적용될 수 있다.In addition, when the amount of the liquid thickener used is 100 parts by weight of the paint, 0.5 to 20 parts by weight, more preferably 1 to 10 parts by weight, may be applied.
본 발명에서 0.5중량부 이하에서는 흐름성으로 인해 입체적인 그림을 그릴 수가 없다.In the present invention, it is not possible to draw a three-dimensional picture due to flowability at 0.5 parts by weight or less.
또한, 20 중량부 이상을 첨가하면 너무 점도가 높아 혼합이 불가능하게 된다.In addition, if 20 parts by weight or more is added, the viscosity is too high and mixing is impossible.
한편, 본 발명은 위와 같은 점증제, 습윤제, 물 외에 색상을 구현하는 착색제가 적용되고, 착색제는 물감을 100 중량부로 할 때 0.5~20 중량부가 적용된다.On the other hand, in the present invention, a colorant that implements a color other than the thickener, wetting agent, and water as described above is applied, and 0.5-20 parts by weight of the colorant is applied when 100 parts by weight of the paint is used.
본 발명에 적용된 착색제로 사용되는 안료는 유기안료, 무기안료, 금속안료, 형광안료 등이 사용가능하다. As the pigment used as the colorant applied to the present invention, organic pigments, inorganic pigments, metal pigments, fluorescent pigments, and the like can be used.
본 발명에 적용되는 유기안료는 유기화합물(有機化合物)인 안료이며, 물에 불용성인 염료, 또는 물에 가용성인 염료를 금속염류 등의 침전제(沈澱劑)로 불용성으로 한 것(게이크(안료)라 한다) 등이 쓰인다. The organic pigment applied to the present invention is a pigment that is an organic compound, and a dye that is insoluble in water or a dye that is soluble in water is made insoluble with a precipitating agent such as metal salt (Gake (pigment) )), etc. are used.
무기안료와 비교하여 일반적으로 착색력이 크고 색상이 선명한 것이 많다. 또 색의 범위는 치환기로서 변화시킬 수 있으며, 열안정성은 무기안료보다 뒤떨어지며, 300℃이상의 가열착색조건에서는 사용할 수 없다. Compared with inorganic pigments, there are many things that generally have greater coloring power and vivid colors. In addition, the range of colors can be changed as a substituent, and the thermal stability is inferior to that of inorganic pigments, and it cannot be used under heating and coloring conditions of 300°C or higher.
합성 직후의 입자가 조대(祖大)한 조안료(祖顔料)를 농황산(10～20배)으로 용해하고, 용액을 대량의 찬물에 주입하여 미세한 입자를 석출시키면 안료에 큰 착색력과 선명도를 줄 수가 있다. Dissolve the coarse pigment immediately after synthesis with concentrated sulfuric acid (10 to 20 times), and pour the solution into a large amount of cold water to precipitate fine particles. can be
이와 같은 처리(處理)를 안료화(顔料化)(미립자화(微粒子化))라고 한다. 푸탈로시아닌, 디옥사딘, 안트라키논계 등의 유기안료에는 자주 응용된다. Such treatment is called pigmentation (顔料化) (fine particle formation). It is often applied to organic pigments such as phthalocyanine, dioxadine, and anthraquinone.
본 발명에서는 유기안료의 일 종류인 형광안료가 적용될 수 있다.In the present invention, a fluorescent pigment, which is a kind of organic pigment, may be applied.
형광안료는 주광중의 자외부에서 가시광선 단파장영역의 자,청,청록(380mm ~ 640mm)의 광에 의해서 아주 선명한 색상을 띄는 것으로서, 주광 또는 주광유사한 조명에 의해서 극히 광휘성의 색을 뛰는 안료가 주광형광안료 또는 유기형광안료로 분류한다.Fluorescent pigments show very vivid colors by the light of purple, blue, and cyan (380mm ~ 640mm) in the short wavelength range of visible light in the ultraviolet of the main light. It is classified as a main fluorescent pigment or an organic fluorescent pigment.
유기형광안료는 형광염료를 합성수지로 고용화한 것으로 통상의 안료와 차이를 지닌다. Organic fluorescent pigments are different from ordinary pigments in that fluorescent dyes are dissolved in synthetic resins.
무기안료는 천연산 또는 합성으로 만들어지는 무기화합물로 착색안료에 한해서 말하면 일반적으로 은폐력이 커서 열이나 약품 또는 광에 대해서 안정하다. Inorganic pigments are natural or synthetic inorganic compounds, and when it comes to colored pigments, they generally have high hiding power and are stable against heat, chemicals, or light.
유기안료에 비해 색수가 적으므로 착색력이 작고 색이 선명하지 않으며, 코스트는 비교적 저렴하다.Compared to organic pigments, since the number of colors is small, the coloring power is small, the colors are not clear, and the cost is relatively low.
금속안료는 무기안료의 일 분류로서 메탈링효과와 유효가스나 수분의 침투방지, 그리고 자외선, 적외선을 차단하여 도막의 분해를 막는 역할을 수행한다.Metallic pigments are a class of inorganic pigments and play a role in preventing the decomposition of the coating film by blocking the metalling effect, preventing penetration of active gas or moisture, and blocking ultraviolet and infrared rays.
본 발명은 위와 같은 특성을 갖는 성분을 이용하여 본 발명을 달성하게 된다.The present invention achieves the present invention by using a component having the above characteristics.
다음은 본 발명의 일 실시예에 대해 설명한다. Next, an embodiment of the present invention will be described.
일 실시예는 본 발명에 따른 조성물과 일반적인 물감의 상태를 비교하였다.An example compared the state of the composition according to the present invention and general paints.
(실시예 1)(Example 1)
물 85중량부 85 parts by weight of water
CI pigment Yellow 12(착색제) 10중량부CI pigment Yellow 12 (colorant) 10 parts by weight
음이온성고분자 1중량부1 part by weight of anionic polymer
글리세린 4중량부4 parts by weight of glycerin
위의 원재료를 넣고 교반기를 이용하여 실온에서 30분간 교반하여 노랑색의 그림물감 조성물을 만들었다.The above raw materials were added and stirred at room temperature for 30 minutes using a stirrer to make a yellow coloring composition.
(실시예 2)(Example 2)
물 85중량부 85 parts by weight of water
CI pigment Yellow 12(착색제) 10중량부CI pigment Yellow 12 (colorant) 10 parts by weight
양이온성고분자 1중량부1 part by weight of cationic polymer
글리세린 4중량부4 parts by weight of glycerin
위의 원재료를 넣고 교반기를 이용하여 실온에서 30분간 교반하여 노랑색의 그림물감 조성물을 만들었다The above raw materials were added and stirred at room temperature for 30 minutes using a stirrer to make a yellow coloring composition.
(비교예1)(Comparative Example 1)
물 85중량부 85 parts by weight of water
CI pigment Yellow 12(착색제) 10중량부CI pigment Yellow 12 (colorant) 10 parts by weight
잔탄검 1중량부1 part by weight of xanthan gum
글리세린 4중량부4 parts by weight of glycerin
위의 원재료를 넣고 교반기를 이용하여 실온에서 30분간 교반하여 노랑색의 그림물감 조성물을 만들었다. The above raw materials were added and stirred at room temperature for 30 minutes using a stirrer to make a yellow coloring composition.
(비교예2)(Comparative Example 2)
물 85중량부 85 parts by weight of water
CI pigment Yellow 12(착색제) 10중량부CI pigment Yellow 12 (colorant) 10 parts by weight
잔탄검 2중량부2 parts by weight of xanthan gum
글리세린 4중량부4 parts by weight of glycerin
(비교예3)(Comparative Example 3)
물 85중량부 85 parts by weight of water
CI pigment Yellow 12(착색제) 10중량부CI pigment Yellow 12 (colorant) 10 parts by weight
알긴산나트륨 1중량부1 part by weight of sodium alginate
글리세린 4중량부4 parts by weight of glycerin
위의 원재료를 넣고 교반기를 이용하여 실온에서 30분간 교반하여 노랑색의 그림물감 조성물을 만들었다.The above raw materials were added and stirred at room temperature for 30 minutes using a stirrer to make a yellow coloring composition.
상기와 같이 실시예 및 비교예를 통하여 흐름성 실험을 육안으로 관찰하였다.As described above, the flowability test was visually observed through Examples and Comparative Examples.
각각의 물감 2g을 A4용지에 놓은후 90도 직각을 세웠을경우 물감이 흐르는지 여부를 육안으로 관찰했다.After placing 2g of each paint on A4 paper, it was visually observed whether or not the paint flowed when standing at a right angle of 90 degrees.
비교예2는 비교예1에 사용한 점증제를 2배로 높여서 점도를 높여도 물감은 흘러 내렸다.In Comparative Example 2, the paint flowed down even if the viscosity was increased by doubling the thickener used in Comparative Example 1.
위와 같은 상기 표의 결과에서 파악되듯이 본 발명에 따른 물감은 흐름성 및 분산성이 우수함을 알 수 있다.As can be seen from the results of the above table, it can be seen that the paint according to the present invention has excellent flowability and dispersibility.
본 발명은 그 정신 또는 주요한 특징으로부터 일탈하는 일없이, 다른 여러가지 형태로 실시할 수 있다. 그 때문에, 전술한 실시 예는 모든 점에서 단순한 내용으로 이해하거나, 한정적으로 해석해서는 안된다. 본 발명의 범위는 특허 청구의 범위에 의하여 나타내는 것으로써, 명세서 본문에 의해서는 아무런 구속도 되지 않는다. 다시, 특허 청구범위의 균등 범위에 속하는 변형이나 변경은, 모두 본 발명의 범위 내의 것이다.The present invention can be embodied in other various forms without departing from the spirit or main characteristics thereof. Therefore, the above-described embodiment should not be understood as a simple content in all respects or interpreted limitedly. The scope of the present invention is indicated by the claims, and is not limited by the text of the specification. Again, all modifications and changes that fall within the scope of equivalents of the claims are within the scope of the present invention.
Claims (3)
음이온성 고분자 물질이 1~40 중량부 또는 Polyquaternium이 사용된 양이온성 고분자 물질이 1~40 중량부로 혼합되고,
용매(케리어액체)는 미네랄오일(mineral oil), isohexadecane, Hydrogenated Polydecene, Octylstearate, Propylene Glycol Dicaprate/Dicaprylate(에스터오일)을 단독 또는 혼합하여 10~80 중량부가 적용되며,
유화제는 트리데실알코올의 폴리에칠렌글라이콜에테르가 1~30 중량부로 혼합되어 이루어진 점증제와,
착색제와,
습윤제를 포함하여 이루어진 입체 그림물감에 있어서,
상기 그림물감을 100 중량부로 할 때 점증제 0.5~20 중량부, 착색제는 0.5~20 중량부, 습윤제 5~30 중량부, 물 50~90 중량부가 적용되는 것을 특징으로 하는 입체 그림물감.When 100 parts by weight of sodium polyacrylate, acryloyldimethyl Taurate Copolymer, or ATBS copolymer alone or mixed,
1-40 parts by weight of the anionic polymer material or 1-40 parts by weight of the cationic polymer material using Polyquaternium,
The solvent (carrier liquid) is 10 to 80 parts by weight of mineral oil, isohexadecane, Hydrogenated Polydecene, Octylstearate, Propylene Glycol Dicaprate/Dicaprylate (ester oil) alone or mixed,
The emulsifier is a thickener made by mixing 1 to 30 parts by weight of polyethylene glycol ether of tridecyl alcohol,
colorant and
In the three-dimensional paint comprising a wetting agent,
When the color is 100 parts by weight, 0.5-20 parts by weight of a thickener, 0.5-20 parts by weight of a colorant, 5-30 parts by weight of a wetting agent, and 50-90 parts by weight of water are applied.
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