KR100868929B1 - Detergent composition containing powder extract and its manufacturing method - Google Patents

Abstract

The present invention is not only economically effective, but also an environmentally friendly effect and the effect of increasing the practical value, and also has a good cleaning effect, the effect of protecting the skin and the effect that can be easily rinsed with a small amount of water at the time of hemg and its preparation It is an object to provide a method. To this end, the present invention provides a detergent composition containing the powder extract obtained by extracting and enzymatically reacting the powder with sugars and salts, and then filtering the powder. In addition, the present invention (a) adding the powder to the purified water and extracting the first while stirring; (b) adding the purified water, sugars and salt to the primary extract prepared in step (a) by adding 2 while stirring Extracting tea; (c) enzymatically reacting the other components of the powder using an enzyme contained in the powder; And (d) filtering the enzyme reaction solution obtained in step (c) to obtain a powder extract.

Powder Extract, Cleanser

Description

Cleansing composition comprising powder extract and a method for preparing the same

1 is a flow chart showing the manufacturing process of the powder extract, the active ingredient of the cleaning composition according to an embodiment of the present invention.

Figure 2 shows the components contained in the powder extract prepared according to one embodiment of the present invention.

The present invention relates to a cleaning composition containing the powder extract and a method for producing the same. More specifically, the present invention relates to a cleaning composition containing a powder extract obtained by filtering and extracting the powder with sugars and salts, and then to a method for producing the same.

In general, detergents are used to completely remove contaminants from the object to be cleaned. They provide many conveniences to human life in hygiene and aesthetics. In recent years, the consumption of detergents has increased greatly with the improvement of life. It is a trend. However, the use of such a cleaning agent is a cause of environmental pollution because the rate of biodegradation of the cleaning agent is slow, and the damage to the skin generated when using the cleaning agent has emerged as a serious problem.

In particular, the surfactant, which is the main raw material of the detergent used so far, has a washing action due to emulsification, wetting, and penetrating action on the skin surface, and it is irritating to the skin and damages the skin tissue, and has a risk of bacterial infection. In addition, there is a problem that the surfactant remains in the tableware to remove the contaminants in the kitchen may have a harmful effect on the human body.

Therefore, in recent years, raw materials for preparing environmentally friendly cleaners with low toxicity to the environment, high biodegradability, and safe for skin have been developed, and new detergent compositions using such environmentally friendly raw materials have been developed. Conventional techniques related to this include kitchen detergent compositions containing chitosan obtained through a refining process in shells of crustaceans and insects, and methods for preparing the detergents (Korean Patent No. 0486861), such as wheatweed, bellflower, and palm oil fatty acids. There is a natural detergent composition (Korean Patent Publication No. 2004-0099828) using a natural plant, there is a cosmetic detergent composition (Korean Patent No. 0163118) containing the milky skin extract obtained from the elm.

However, the raw materials of the eco-friendly detergent composition that has been developed and used so far have the advantages of excellent eco-friendliness, but the cost of the raw materials is expensive and the cleaning effect is low, and there is a problem of causing skin irritation and damage. Therefore, it is urgent to develop a new detergent composition that is environmentally friendly, low in cost of raw materials, and has an excellent cleaning effect and does not cause skin irritation or damage.

On the other hand, wheat is a valuable food for humans, carbohydrates and proteins predominantly, and contains a lot of trace elements calcium and phosphorus compared to other grains. These wheat can be divided into bran, endosperm and germ, which is the main part of the wheat flour production, most of which is starch, and the wheat is ingested after milling. Also, embryos contain a lot of nutrients such as lipids, proteins, and vitamin E, account for about 2.5% of wheat grains, and are mainly used for health foods. Peels are mainly removed during the milling process of wheat. It is called red-dog or wheat bran and is mainly used for fertilizer and feed.

These wheats have carbohydrates, starch and protein, which are hydrophilic polymers that adsorb all molecules. Gluten, a major component of wheat protein, is a combination of gliadin and glutenine. It has a strong viscosity and is used to make foods such as bread and noodles. In addition, the flour made by milling wheat has a whitening effect and exfoliating effect, which is used for the beauty of women, and has the property of adsorbing harmful ingredients, and thus is used for removing pesticides of fruits.

However, there is no example of using powder used for fertilizer and feed as a raw material of the cleaning composition.

It is an object of the present invention to provide a cleaning composition and a method for preparing the cleaning composition having improved cleaning power, environmentally friendly and excellent skin protection effect.

In order to achieve the object of the present invention as described above, the present invention provides a detergent composition containing the powder extract obtained by the extraction and enzymatic reaction of the powder with sugars and salts.

In addition, the present invention,

(a) adding powder to purified water and performing primary extraction with stirring;

(b) additionally adding purified water, sugars and salts to the primary extract prepared in step (a) to perform secondary extraction while stirring;

(c) enzymatically reacting the other components of the powder using an enzyme contained in the powder; And

(d) filtering the enzyme reaction solution obtained in step (c) provides a method for producing a cleaning composition containing a powder extract comprising the step of obtaining a powder extract.

Hereinafter, a cleaning composition containing the powder extract of the present invention and a method for preparing the cleaning composition will be described in more detail.

When explaining step by step the preparation method of a cleaning composition containing a powder extract according to the present invention.

First step: first extraction

In order to prepare a cleaning composition containing a powder extract according to the present invention, first, the primary extract of powder is prepared while stirring by adding purified water to a solvent capable of dissolving the powder.

Powder refers to the part of wheat, which is divided into bran, endosperm and germ, which is a part of the skin that is generally removed during the milling process, also called wheat bran. The powder contains a substantial portion of essential nutrients, such as vitamins, minerals, amino acids and dietary fiber, and in particular, 70 to 80% of bioactive substances such as antioxidants present in wheat. However, until now these powders have only been used for fertilizers or feed. On the other hand, in the present invention, the powder can be used as a raw material of the cleaning composition. The powder according to the present invention can be used in the milling process of the mill, and can also be easily purchased and used on the market.

The primary extract of the powder according to the present invention can be prepared by adding purified water to the powder while stirring, the purified water can be added to an amount capable of sufficiently dissolving the powder, pH 6.0 ~ 7.0 can be used . If the pH is lower than 6.0, there may be a problem that the cleaning power may be significantly reduced due to acidic substances accumulated in proteins or fatty acids or failure to neutralize the oil component.If the pH is higher than 7.0, the fat content of the skin is also removed. Becomes rough, and the problem that the epidermal cells of the hand are peeled off may occur. Therefore, neutral conditions of pH 6.0-7.0 can minimize skin damage, improve cleansing and facilitate rinsing.

The agitation may be performed at an appropriate temperature and agitation speed for a suitable time without disrupting the cell wall of the powder while giving other changes to the powder component. Preferably the agitation may be performed by adding purified water to the powder for 0.5 to 2 hours at 25 ~ 30 ℃ at a stirring speed of 1500 ~ 2000 rpm, more preferably at 1800 rpm at a temperature of 25 ℃ for 1 hour Can be.

Second step: second extraction

Purified water, sugars and salts are further added to the primary extract prepared in the first step to prepare a secondary extract of powder while stirring.

The purified water may be used in the same manner as the purified water used in the first step pH 6.0 ~ 7.0, the saccharide is used for the stability of the powder. That is, maltose converted by amylase plays an important role of neutralizing and decomposing the wastes accumulated in proteins and fatty acids. The addition of the sugar activates the conversion to maltose. In addition, the separation of the water-soluble dietary fiber (eg, pentosan, pectin, etc.) contained in the powder to facilitate the formation of the network "gel" to promote the role of a thickener, wherein the gel and the thickener is added sugar Its dehydration and water holding capacity ensure that the major ingredients in the powder are well preserved and stabilized. Sugars that can be used in the present invention is not limited thereto, but may be used such as white sugar, brown sugar, brown sugar and oligosaccharides, preferably black sugar.

The salt is used to promote the formation of gluten, a major protein in wheat, which is a protein formed by the combination of gliadin and glutenin, and when water is sufficiently absorbed, it forms a thread-like substance and then expands. Cross radially to form a network. The formed network is responsible for absorbing fat, the gluten will produce a gas and the generated gas will again form a fine bubble. The formed fine bubbles attack the contaminants of the cleaning object to reduce the surface tension between the cleaning object and the contaminants to play a cleaning function.

The type of salt that can be used in the present invention is not limited thereto, but salt may be used, and sun salt may be preferably used.

In addition, the purified water, sugars and salts may be added to 80 to 120 parts by weight, 0.1 to 3 parts by weight and 0.1 to 3 parts by weight with respect to 100 parts by weight of the primary extract prepared in the first step, the stirring is It may be performed for 1 to 3 hours at 25 ~ 30 ℃ at a stirring speed of 450 ~ 750 rpm, preferably at 600 rpm for 25 hours at a temperature of 25 ℃. As described above, the agitation for the second extraction is performed at a relatively low speed, in order to destroy the cell wall of the powder and extract proteins and polysaccharides of wheat, which are biopolymers, without destroying the components.

Step 3: enzyme reaction step

The secondary extract prepared in the second step is hydrolyzed and fat, protein and starch in the powder by the enzymes present in the powder while still standing for 12-48 hours at a temperature of 25 ~ 30 ℃ without stirring process Enzyme reaction as much as possible. Preferably, the reaction is allowed to stand at a temperature of 25 ° C. for 24 hours. At this time, the second extract is allowed to stand to allow various enzymes to be separated from the powder, and to maintain a relatively low temperature of 25 ~ 30 ℃ to maximize the effect of the enzyme reaction. The glycosylation and transfer refers to a step in which the components in the powder are hydrolyzed by various enzymes present in the powder of the secondary extract, and then the components are glycosylated and transferred to the components having excellent washing action.

Representative enzymes present in powder include lipase, amylase, and protease. The lipase refers to an enzyme that breaks down fat into fatty acids and glycerol. In particular, the powder is rich in calcium and albumin, which serves to further activate the lipolytic action of the lipase.

In addition, the amylase is one of representative glycosylase enzymes, which refers to an enzyme that randomly hydrolyzes the internal bond of starch and converts it into sugar such as glucose, maltose, and low molecular weight dextrin. Protease is one of proteolytic enzymes, which refers to an enzyme that converts a protein into an amino acid via a peptide, and serves to promote liquefaction and glycation of powder.

Water-soluble dietary fiber, such as pentosan, pectin, gum and mucosa, in powders that have undergone saccharification and transition through the enzymatic reaction as described above, have good absorption and are easily combined with water to aggregate fat to cause precipitation reaction. Maltose, that is, glycosylated and transferred from starch by amylase, acts to neutralize waste products, which are acidic substances in which proteins and fatty acids are accumulated, to be easily decomposed and toxins. In addition, the carbohydrate of the powder is a polysaccharide and when dissolved and transferred to water, the viscosity increases to absorb, absorb and remove oil or odor.

Fourth Step: Filtration Step

When the enzyme reaction step is completed in the third step, the prepared enzyme reaction solution is recovered, the precipitated sediment and the supernatant are separated and filtered according to a conventional method.

The filtration may be performed by centrifugation or using activated carbon, and may be performed using a filter, and preferably, 200 mesh.

In addition, the powder extract obtained by filtration according to the above method may further contain a preservative and preservatives, etc. in order to suppress the growth of yeast, mold and bacteria. In one embodiment of the present invention, sodium benzoate was added as the preservative, and phenoxy ethanol was added as the preservative.

Therefore, the powder extract prepared as described above may prepare a cleaning composition containing the powder extract of the present invention according to the manufacturing method of the cleaning composition known in the art.

Furthermore, a detergent composition containing the powder extract of the present invention is added to the powder extract of the present invention prepared by the above method by adding a surfactant, a solubilizer, a fragrance, and other additives generally used in the preparation of the detergent composition. Can be prepared.

The present invention also provides a cleaning composition containing the powder extract obtained by extracting and enzymatically reacting the powder with sugars and salts.

The powder extract may be obtained by the method described above, the powder extract may be contained in 60 to 99 parts by weight, preferably 75 to 85 parts by weight based on 100 parts by weight of the detergent composition.

Furthermore, the cleaning composition according to the present invention has 60 to 99 parts by weight of powdered extract, 10 to 20 parts by weight of surfactant, 0.5 to 4 parts by weight of solubilizer, 0.01 to 1 parts by weight of preservative, 0.01% of fragrance based on 100 parts by weight of the cleaning composition. It can contain -1 weight part, 0.1-3 weight part of skin protection agents, 0.1-3 weight part of stabilizers, and 0.1-3 weight part of a viscosity enhancer.

The cleaning composition containing the powder extract according to the present invention and its preparation method have the following excellent effects.

First, the detergent composition according to the present invention is economically superior. The detergent composition containing the powder extract according to the present invention can reduce the cost of the raw material by using the powder used as a by-product of the wheat to be used only for fertilizer or feed to the manufacture of the detergent to obtain an economic effect.

Second, the cleaning composition according to the present invention is environmentally friendly. The detergent composition containing the powder extract according to the present invention has an effect of reducing environmental pollution caused by a conventional synthetic detergent having low biodegradability by using an extract extracted from nature having a fast biodegradation rate. In addition, since the by-products generated in the process of manufacturing the powder extract according to the present invention can be recovered and used as a fertilizer or feed has the advantage that the cost of the by-product treatment is not required separately.

Third, the cleaning composition according to the present invention is excellent in cleaning power. Since the water-soluble dietary fiber contained as an active ingredient in the cleaning composition according to the present invention contains a phenol component combined with fibrin, it not only has antioxidant activity but also has properties of adsorbing fat. In addition, the maltose contained in the detergent composition helps to easily decompose by neutralizing the waste material is an acidic substance accumulated protein or fatty acids. In addition, carbohydrate polysaccharides are viscous when dissolved and dissolved in water, and the material may function to coalesce, absorb, and remove oil or odors.

Fourth, the cleaning composition according to the present invention has a skin protective effect. Generally, when commercially available synthetic and natural cleansers are added, skin protectants are added separately. Even when commercially available cleaning composition according to the present invention can be added to the skin protection agent to maximize the skin protection effect. However, since the powder extract, which is an active ingredient of the cleaning composition according to the present invention, contains essential nutrients such as glycerin, vitamins and minerals, it has excellent skin protection effect in itself.

Fifth, the cleaning composition according to the present invention has the advantage of excellent rinsing property. General synthetic and natural detergent compositions have the disadvantage of using large amounts of water for rinsing. On the other hand, the detergent composition according to the present invention has an excellent effect that can be easily rinsed even with a small amount of water.

Therefore, the cleaning composition according to the present invention can be used as a cleaning composition, such as cosmetics, kitchen, body, laundry and shampoo for removing contaminants to be cleaned.

Hereinafter, the present invention will be described in detail by examples. However, these examples are intended to illustrate the present invention in more detail, the scope of the present invention is not limited to these examples.

< Example  1>

According to the invention Powder  Preparation of Cleaning Composition Containing Extract

<1-1> First Extraction Step

In order to prepare a detergent composition containing a powder extract according to the present invention, the present inventors first mix 500 liters of purified water having a pH of 6.5 with 50 kg of powder produced in the final stage of the milling process, and then, at a temperature of 25 ° C. at 1800 rpm. Stirring for 1 hour to prepare a primary extract.

<1-2> Secondary Extraction Step

To the primary extract prepared in Example <1-1>, 500 ml of purified water having a pH of 6.5, 10 kg of brown sugar, and 3 kg of sun salt were further added, followed by stirring for 2 hours at a temperature of 25 ° C. at 600 rpm to obtain a secondary extract. Prepared.

<1-3> enzyme reaction step

The secondary extract prepared in Example <1-2> was subjected to enzyme reaction while standing at a temperature of 25 ° C. for 24 hours without stirring. That is, the fat, protein and starch in the powder are hydrolyzed by enzymes, such as lipase, protease and amylase, which are present in the powder of the secondary extract prepared in Example <1-2>, so that they can be glycosylated and transferred to components having excellent cleaning power. After the enzymatic reaction, the enzyme reaction solution was prepared.

<1-4> filtration step

After leaving the enzyme reaction solution obtained in Example <1-3> to precipitate impurities not dissolved in the solvent, the impurities were removed by filtering the supernatant of the precipitated aqueous solution using 200 mesh (mesh). Powder extract was obtained. Thereafter, to the powder extract obtained above, sodium benzoate, a growth inhibitor of yeast and mold, and phenoxy ethanol for sterilization of bacteria, etc. were added to a concentration of 0.1%, followed by sufficient stirring. According to the conventional method for preparing a detergent composition known in the art, a detergent composition containing the powder extract of the present invention was prepared. The method of preparing a powder extract for preparing the detergent composition according to the present invention is shown in FIG. 1, and the components contained in the powder extract of the present invention are shown in FIG. 2.

< Example  2>

According to the invention Powder  Preparation of Cleaning Composition Containing Extract

A detergent composition containing a powder extract was prepared by further mixing a powder extract prepared in Example 1 with a surfactant, a solubilizer, an edible preservative, a perfume, a skin protectant, a stabilizer and a viscosity enhancer. The components of the detergent composition according to the present invention are as described in Table 1 below.

ingredient Composition ratio (parts by weight) Remarks 1. Powder Extract 80.0 2. Surfactant-Anionic: linear alkylbenzene sulfonate (LAS), fatty alcohol sulfate (FAS), fatty alcohol ether sulfate (FAES), alpha-olefin sulfonate (AOS)-nonionic: fatty acid alkanol amide ( FAA), fatty amine oxide (FAO), polyoxyethylene alkyl ether (AE) 15.0 Hydrophilic 3. Solubilizer (ethanol) 1.8 4.Edible preservative (sodium benzoate and phenoxyethanol) 0.1 5. Spices (lemon) 0.1 6. Skin protectants (Jojoba oil) 1.0 7. Stabilizers (Amine oxide) 1.0 8. Viscosity Enhancer (Hydroxyethyl cellulose) 1.0 Sum 100.0

As described above, the cleaning composition containing the powder extract prepared by the method according to the present invention has the effect of increasing the economic value as well as the eco-friendly effect and its practical value by using the powder which is the processing by-product of wheat. In addition, it has an excellent cleaning effect, protecting the skin and the effect of being easy to rinse with a small amount of water when rinsing, it can be widely used as a cleaning composition for cosmetics, kitchen, laundry, body and shampoo.

Although the present invention has been described with reference to the embodiments, these are merely exemplary, and those skilled in the art will understand that various modifications and equivalent embodiments are possible therefrom. Therefore, the true technical protection scope of the present invention will be defined by the technical spirit of the appended claims.

Claims (11)

delete delete delete (a) adding powder to purified water and performing primary extraction with stirring; (b) additionally adding purified water, sugars and salts to the primary extract prepared in step (a) to perform secondary extraction while stirring; (c) enzymatically reacting the other components of the powder using an enzyme contained in the powder; And (d) filtering the enzyme reaction solution obtained in step (c) to obtain a powder extract comprising the step of preparing a cleaning composition containing a powder extract. The powder extract according to claim 4, wherein the first extraction of step (a) is performed at a temperature of 25 to 30 ° C. at 1500 to 2000 rpm using purified water of pH 6.0 to 7.0 for 5 hours. The manufacturing method of the cleaning composition containing these. According to claim 4, wherein the sugar of step (b) is selected from the group consisting of white sugar, brown sugar, brown sugar and oligosaccharides, the salt of step (b) is a detergent containing a powder extract, characterized in that the sun salt. Method of Preparation of the Composition. The powder extract according to claim 4, wherein the secondary extraction of step (b) is performed for 1 to 3 hours at a temperature of 25 to 30 ° C at 450 to 750 rpm using purified water at pH 6.0 to 7.0. The manufacturing method of the cleaning composition containing these. The method of claim 4, wherein the enzyme is a lipase, protease or amylase. According to claim 4, wherein the enzymatic reaction of step (c) is a method for producing a detergent composition containing a powder extract, characterized in that carried out for 12 to 48 hours at 25 ~ 30 ℃. The method of claim 4, wherein the enzymatic reaction of step (c) comprises saccharifying and transferring the secondary extract prepared in step (b). delete

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