KR100533198B1 - 저유전성 질화규소막 및 그 형성 방법, 반도체 장치 및 그제조 방법 - Google Patents
저유전성 질화규소막 및 그 형성 방법, 반도체 장치 및 그제조 방법 Download PDFInfo
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- KR100533198B1 KR100533198B1 KR10-2003-7002396A KR20037002396A KR100533198B1 KR 100533198 B1 KR100533198 B1 KR 100533198B1 KR 20037002396 A KR20037002396 A KR 20037002396A KR 100533198 B1 KR100533198 B1 KR 100533198B1
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Abstract
Description
| 기판 온도 | 200 ℃ - 400 ℃ |
| 플라즈마 전력 | 100 W - 1000 W/27 MHz |
| 챔버 압력 | 13.3 Pa(100 mTorr) |
| 유기 Si원의 유량 | 0.1 cc/min |
| NH3의 유량 | 50 SCCM |
| Ar의 유량 | 200 SCCM |
| 기화기 온도 | 80 ℃ - 120 ℃ |
Claims (30)
- 반응 챔버 내에 기판을 도입하는 단계;상기 반응 챔버 내에 가스원으로서 유기 실라제인 결합을 포함하는 유기 Si 화합물을 공급하는 단계; 및CVD 공정에 의해서 상기 가스원으로부터 상기 기판의 표면 상에 주요 구성 원소로서 Si, N, C 및 H를 함유한 SiNCH 막을 증착하는 단계; 를 포함하며,상기 CVD 공정은 상기 유기 Si 화합물에 포함된 유기 실라제인 결합이 실질적으로 상기 SiNCH 막 내에 보존되도록 수행되는 것을 특징으로 하는 질화규소막 형성 방법.
- 제 1 항에 있어서,상기 유기 Si 화합물은 (SiR1)nNR2, (SiR1NR2)n 및 (SiR1(NR2)1.5)n 중 어느 한 구조식을 갖는데, 여기서 n은 1 이상의 정수이고, R1 및 R2는 각각 수소이거나 메틸기와 같은 알킬기, 페놀기와 같은 고리형 탄화수소기 및 비닐기 중 어느 하나인 것을 특징으로 하는 질화규소막 형성 방법.
- 제 1 항에 있어서,상기 SiNCH 막은 그 안에 Si-C 결합과 Si-N 결합을 포함하는 것을 특징으로 하는 질화규소막 형성 방법.
- 제 1 항에 있어서,상기 SiNCH 막을 증착하는 단계는 상기 유기 Si 화합물의 플라즈마 중합 반응 공정을 포함하는 것을 특징으로 하는 질화규소막 형성 방법.
- 삭제
- 제 1 항에 있어서,상기 SiNCH 막을 증착하는 단계는 상기 유기 Si 화합물의 열분해 중합 반응 공정에 의해서 수행되는 것을 특징으로 하는 질화규소막 형성 방법.
- 삭제
- 제 1 항에 있어서,상기 유기 Si 화합물에 N을 함유한 추가의 가스원을 공급하는 단계를 더 포함하며,상기 SiNCH 막을 증착하는 단계는 상기 추가의 가스원의 플라즈마를 형성하는 단계, 및 상기 플라즈마를 상기 반응 챔버 내에 공급하는 단계를 포함하는 것을 특징으로 하는 질화규소막 형성 방법.
- 기판 상에 에칭 정지막을 증착하는 단계;상기 에칭 정지막 상에 층간 절연막을 증착하는 단계; 및상기 층간 절연막을 패터닝하여 개구를 형성하는 단계; 를 포함하며,상기 에칭 정지막을 증착하는 단계는,처리 장치의 반응 챔버 내에 상기 기판을 도입하는 단계;상기 반응 챔버 내에 가스원으로서 유기 실라제인 결합을 포함하는 유기 Si 화합물을 공급하는 단계; 및상기 반응 챔버에서 CVD 공정에 의해서 상기 유기 Si 화합물로부터 상기 기판의 표면 상에 상기 에칭 정지막으로서 SiNCH 막을 증착하는 단계; 를 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 9 항에 있어서,상기 유기 Si 화합물은 (SiR1)nNR2, (SiR1NR2)n 및 (SiR1(NR2)1.5)n 중 어느 한 구조식을 갖는데, 여기서 n은 1 이상의 정수이고, R1 및 R2는 각각 수소이거나 메틸기와 같은 알킬기, 페놀기와 같은 고리형 탄화수소기 및 비닐기 중 어느 하나인 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 9 항에 있어서,상기 SiNCH 막을 증착하는 단계는 상기 유기 Si 화합물에 포함된 유기 실라제인 결합이 실질적으로 상기 SiNCH 막 내에 보존되도록 수행되는 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 9 항에 있어서,상기 SiNCH 막을 증착하는 단계는 상기 유기 Si 화합물의 플라즈마 중합 반응 공정을 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 삭제
- 제 9 항에 있어서,상기 SiNCH 막을 증착하는 단계는 상기 유기 Si 화합물의 열 중합 반응 공정을 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 삭제
- 제 9 항에 있어서,상기 유기 Si 화합물 외에도 상기 반응 챔버 내에 N을 함유한 추가의 가스원을 공급하는 단계를 더 포함하며,상기 SiNCH 막을 증착하는 단계는 상기 추가의 가스원의 플라즈마를 형성하는 단계, 및 상기 플라즈마를 상기 반응 챔버 내에 공급하는 단계를 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 9 항에 있어서,상기 개구를 통해 상기 함몰부가 채워지도록 상기 층간 절연막 상에 전도체층을 증착하는 단계; 및화학 기계적 연마 공정에 의해서 상기 층간 절연막 위에 있는 상기 전도체층의 일부분을 제거하는 단계; 를 더 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 17 항에 있어서,상기 전도체층은 Cu층을 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 9 항에 있어서,상기 층간 절연막은 유기 절연막 및 무기 절연막 중 어느 하나를 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 9 항에 있어서,상기 층간 절연막은 유기 산화규소막 및 F가 도핑된 SiO2 막 중 어느 하나를 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 제 9 항에 있어서,상기 함몰부는 배선 그루브와 콘택 홀을 포함하는 것을 특징으로 하는 반도체 장치 제조 방법.
- 삭제
- 삭제
- 삭제
- 삭제
- 삭제
- 기판 및 상기 기판 상에 형성되는 다층 배선 구조체를 포함하는 반도체 장치에 있어서,상기 다층 배선 구조체는 에칭 정지막과, 상기 에칭 정지막 상에 형성되는 층간 절연막과, 상기 층간 절연막에 형성되는 배선 그루브와, 상기 배선 그루브에 대응해서 상기 층간 절연막에 형성되는 콘택 홀과, 상기 배선 그루브와 상기 콘택 홀을 채우는 전도체 패턴을 포함하며,상기 에칭 정지막은 SiNCH 막을 포함하고 CnHm으로 표현되는 임의의 원자단을 포함하며, 상기 임의의 원자단은 Si 원자에 결합되고,상기 SiNCH 막은 그 안에 고리형 실라제인 결합을 포함하는 것을 특징으로 하는 반도체 장치.
- 반응 챔버에 기판을 도입하는 단계;상기 반응 챔버 내에 가스원으로 유기 실라제인 결합을 포함하는 유기 Si 화합물을 공급하는 단계;상기 가스원에 에너지를 공급하는 단계; 및상기 기판 상에 Si, N, C, H 를 주요 구성 원소로 하는 SiNCH 막을 증착하는 단계; 를 포함하고,상기 가스원에 에너지를 공급하는 단계는 상기 가스원의 가스 분자에 배분되는 에너지가 실라제인 결합의 결합 에너지 이하인 것을 특징으로 하는 질화규소막 형성 방법.
- 제 28 항에 있어서,상기 에너지는 고주파 전력인 것을 특징으로 하는 질화규소막 형성 방법.
- 제 28 항 또는 제 29 항에 있어서,상기 SiNCH 막의 비유전율은 5.5 이하인 것을 특징으로 하는 질화규소막 형성 방법.
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| JPJP-P-2000-00248922 | 2000-08-18 | ||
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| PCT/JP2001/007061 WO2002017374A1 (en) | 2000-08-18 | 2001-08-16 | Low-dielectric silicon nitride film and method of forming the same, semiconductor device and fabrication process thereof |
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| DE4212501C1 (en) * | 1992-04-14 | 1993-08-05 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De | Deposition of silicon nitride polymer layer on substrate - using linear or cyclic silazane in gas, giving good quality and high coating ratio |
| JPH06244172A (ja) * | 1993-02-18 | 1994-09-02 | Toray Ind Inc | 多層配線構成体 |
| JP2641385B2 (ja) * | 1993-09-24 | 1997-08-13 | アプライド マテリアルズ インコーポレイテッド | 膜形成方法 |
| US5413813A (en) * | 1993-11-23 | 1995-05-09 | Enichem S.P.A. | CVD of silicon-based ceramic materials on internal surface of a reactor |
| FR2759362B1 (fr) * | 1997-02-10 | 1999-03-12 | Saint Gobain Vitrage | Substrat transparent muni d'au moins une couche mince a base de nitrure ou d'oxynitrure de silicium et son procede d'obtention |
| JPH1116904A (ja) * | 1997-06-26 | 1999-01-22 | Mitsubishi Electric Corp | 半導体装置及びその製造方法 |
| WO1999004911A1 (en) * | 1997-07-28 | 1999-02-04 | Massachusetts Institute Of Technology | Pyrolytic chemical vapor deposition of silicone films |
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| US6635583B2 (en) * | 1998-10-01 | 2003-10-21 | Applied Materials, Inc. | Silicon carbide deposition for use as a low-dielectric constant anti-reflective coating |
| GB0001179D0 (en) * | 2000-01-19 | 2000-03-08 | Trikon Holdings Ltd | Methods & apparatus for forming a film on a substrate |
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| EP1130633A1 (en) * | 2000-02-29 | 2001-09-05 | STMicroelectronics S.r.l. | A method of depositing silicon oxynitride polimer layers |
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| US6617690B1 (en) * | 2002-08-14 | 2003-09-09 | Ibm Corporation | Interconnect structures containing stress adjustment cap layer |
-
2001
- 2001-08-16 WO PCT/JP2001/007061 patent/WO2002017374A1/en not_active Ceased
- 2001-08-16 AU AU2001278749A patent/AU2001278749A1/en not_active Abandoned
- 2001-08-16 KR KR10-2003-7002396A patent/KR100533198B1/ko not_active Expired - Fee Related
- 2001-08-16 DE DE60127973T patent/DE60127973T2/de not_active Expired - Lifetime
- 2001-08-16 CN CNB018140505A patent/CN100431110C/zh not_active Expired - Fee Related
- 2001-08-16 JP JP2002521345A patent/JP4048112B2/ja not_active Expired - Fee Related
- 2001-08-16 EP EP01956920A patent/EP1316108B9/en not_active Expired - Lifetime
- 2001-08-17 TW TW090120274A patent/TW554442B/zh not_active IP Right Cessation
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|---|---|
| JP2004507108A (ja) | 2004-03-04 |
| KR20030064743A (ko) | 2003-08-02 |
| EP1316108A4 (en) | 2005-10-26 |
| DE60127973D1 (de) | 2007-05-31 |
| EP1316108A1 (en) | 2003-06-04 |
| EP1316108B9 (en) | 2007-10-03 |
| WO2002017374A1 (en) | 2002-02-28 |
| US20030162412A1 (en) | 2003-08-28 |
| DE60127973T2 (de) | 2008-01-17 |
| TW554442B (en) | 2003-09-21 |
| CN1446374A (zh) | 2003-10-01 |
| EP1316108B1 (en) | 2007-04-18 |
| CN100431110C (zh) | 2008-11-05 |
| AU2001278749A1 (en) | 2002-03-04 |
| US6890869B2 (en) | 2005-05-10 |
| JP4048112B2 (ja) | 2008-02-13 |
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