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KR0160843B1 - Spray insecticide paint - Google Patents

Spray insecticide paint

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Publication number
KR0160843B1
KR0160843B1 KR1019950024885A KR19950024885A KR0160843B1 KR 0160843 B1 KR0160843 B1 KR 0160843B1 KR 1019950024885 A KR1019950024885 A KR 1019950024885A KR 19950024885 A KR19950024885 A KR 19950024885A KR 0160843 B1 KR0160843 B1 KR 0160843B1
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South Korea
Prior art keywords
insecticide
spray
paint
present
spray insecticide
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Expired - Fee Related
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KR1019950024885A
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Korean (ko)
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KR970010901A (en
Inventor
장봉석
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안민동
국보제약주식회사
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Priority to KR1019950024885A priority Critical patent/KR0160843B1/en
Priority to TW085110411A priority patent/TW401452B/en
Publication of KR970010901A publication Critical patent/KR970010901A/en
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Publication of KR0160843B1 publication Critical patent/KR0160843B1/en
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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06Aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/006Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Insects & Arthropods (AREA)
  • Food Science & Technology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

본 발명은 접촉작용에 의해 살충효과를 나타내는 피레스로이드계 살충성분 0.1-2.5%, 유성 아크릴수지 5-10%, 곤충유인제 0.01-0.1%, 추진제 30-60%, 용제 30-50%를 함유하는 통상의 분사식 살충제의 제조방법에 따라서 제조된 분사살충식 페인트에 관한 것이며, 본 발명에 의하여 인체나 온혈동물에는 무해하며, 해충에만 지속적인 살충효과를 가지는 특성을 가지는 살충제가 얻어진다.The present invention contains 0.1-2.5% of pyrethroid insecticides, 5-10% of oily acrylic resins, 0.01-0.1% of insect attractants, 30-60% of propellants, and 30-50% of solvents. The present invention relates to a spray insecticide paint prepared in accordance with a conventional method for producing a spray insecticide, the present invention is harmless to humans and warm-blooded animals, the insecticide having a characteristic of having a persistent insecticidal effect only to pests is obtained.

Description

분사식 살충페인트Spray insecticide paint

본 발명의 분사식 살충페인트 및 그 제조방법에 관한 것이다.The present invention relates to a spray insecticide paint and a method of manufacturing the same.

특히 본 발명은 피레스로이드(Pyrethroides)계 살충성분인 델타메트린(Deltamethrin), 퍼메트린(Permethrin) 및 사이퍼메트린(Cypermethrin)에서 선택된 피레스로이드계 살충성분을 함유하고, 바퀴벌레의 유인성분인 프로필 사이클로헥실 아세테이트(Propyl cyclohexylacetate) 및 파리의 유인성분인 Z-9-트리코셈(Z-9-Tricoseme) 및 개미의 유인성분인 메틸 4-메틸피롤-2-카르복실이트(Methyl 4-methylpyrrole-2-carboxylate)를 함유하고 통상의 수지성분, 추진제 및 용제를 함유하는 분사식 살충페인트 및 그 제조방법에 관한 것이다.In particular, the present invention contains a pyrethroid insecticide selected from deltamethrin, Permethrin and Cypermethrin, which is a pyrethroides insecticide, and is a propyl cyclohexyl acetate which is an attractant of cockroaches. (Propyl cyclohexylacetate) and Z-9-Tricoseme, an attractant of flies, and methyl 4-methylpyrrole-2-carboxylate, an attractant of ants The present invention relates to a spray insecticide paint containing a conventional resin component, a propellant and a solvent, and a method for producing the same.

종래에는 살충성분을 용제 및 추진제와 함께 분사식 용기에 충진하여 단순히 분사시켜서 해충을 구제하여 왔다.Conventionally, pests have been controlled by simply spraying the pesticidal ingredients together with a solvent and a propellant into a spray container.

또한 불란서 특허 제 1,050, 895호 및 2,593,821호에는 접촉에 의하여 살충효력이 생기는 도료의 제조방법에 관하여 개시되어 있다.In addition, French Patent Nos. 1,050, 895 and 2,593, 821 disclose a method for producing a paint in which insecticidal effects are caused by contact.

이들 특허에서는 제조된 페인트의 살충작용은 건조후 조성성분들중 하나의 극성에 의하여 다공성의 얇은 막을 형성하고 이 다공을 통하여 살충성분이 염기의 표면장력 효과에 따라 표면으로 이동하면서 나타나도록 설계되어 있다.In these patents, the insecticidal action of the prepared paint is designed to form a thin porous film by the polarity of one of the components after drying, and through this pore the insecticide moves to the surface according to the surface tension effect of the base. .

또한 불란서 특허 제 7139852호에는 벽지나 벽의 마감재에 사용할 수 있는 접촉에 의한 살충유약의 제조방법에 관하여 개시되어 있다.In addition, French Patent No. 7139852 discloses a method for preparing insecticidal glaze by contact which can be used for wallpaper or wall finishing material.

이 방법에 따르면 살충성분 용액을 섭씨 80도 정도에서 1 내지 12 퍼센트로 유기용제에 희석하여 벽지나 벽의 마감재에 도포하게 되어 있다.According to this method, the pesticide solution is diluted to 1 to 12 percent in an organic solvent at about 80 degrees Celsius and applied to the wall or wall finish.

이들 살충성분을 첨가한 유약과 도료들은 해충(바퀴벌레, 파리, 개미)을 퇴치하는 데 적극적이지 못하며 단지, 칠해진 곳을 해충이 지나가거나 또는 긁어 먹어야만한다.Glazes and paints containing these pesticides are not active in combating pests (cockroaches, flies, ants), but only need to pass or scrape over the painted areas.

이들 특허들에서 사용된 살충성분이 다공성 피막을 형성한 유약 및 도료들은 해충퇴치를 위하여 소극저인 방법들이다.Glazes and paints in which the pesticidal components used in these patents form a porous coating are methods that are very low for combating pests.

본 발명자들은 사람이나 가축들에게는 해를 적게하며, 해충에게는 치명적인 약효를 나타내는 피레스로이드계 살충제들을 사용하고, 여기에 바퀴벌레의 유인성분인 프로필사이클로헥실아세테이트, 파리의 유인성분인 Z-9-트리코셈 및 개미의 유인성분인 메틸-4-메틸-피롤-2-카르복실레이트를 첨가하고 여기에 유성아크릴수지, 추진제 및 용제를 함께 첨가하여 분사식으로 설계하면, 이들을 분사하여 페인트식으로 분사도포하면 해충들을 적극적으로 유인하여 살충효과를 극대화할 수 있는 놀라운 사실을 발견하여 본 발명을 완성하였다.The present inventors use pyrethroid-type insecticides that are less harmful to humans and livestock and have a lethal effect on pests, and include propylcyclohexyl acetate, which is an attractant of cockroaches, and Z-9-tricosem, which is an attractant of flies. And methyl-4-methyl-pyrrole-2-carboxylate, which is an attractant of ants, and oily acrylic resin, a propellant, and a solvent, are added together to design a spray type. Actively attracted them to find a surprising fact that can maximize the insecticidal effect has completed the present invention.

피레스로이드계 살충성분은 공기, 햇빛 및 열에 의하여 분해되어지는 성질을 가지고 있어서 환경오염을 일으키지않고 또한 일정기간동안 약효가 지속되어 잔류효과를 나타나므로써, 해충을 방제하기 위하여 살충제를 자주 뿌려주는 번거로움과 경제적인 손실도 줄일 수 있다.Pyrethroid insecticides are decomposed by air, sunlight and heat, so they do not cause environmental pollution and have a long-lasting effect, resulting in residual effects, so that they are often sprayed with pesticides to control pests. And economic losses can also be reduced.

이들 피레스로이드계 살충제들은 냉혈동물 및 곤충류에게는 접촉에 의하여 치명적인 손상을 일으키나 사람, 가축 및 애완동물들에게는 치명적이지않는 안전한 약제이다.These pyrethroid insecticides are safe agents that cause fatal damage by contact with cold blooded animals and insects, but are not lethal to humans, livestock and pets.

따라서 본 발명은 피레스로이드계 살충성분을 살충성분으로 함유하고 해충유인제, 유성 아크릴수지, 추진제 및 용제를 함유함을 특징으로 하는 분사식 살충페인트를 제공하는 것이다.Accordingly, the present invention provides a spray insecticide paint, characterized in that it contains a pyrethroid-based insecticide component as a pesticide component and contains a pest attractant, an oily acrylic resin, a propellant and a solvent.

본 발명의 다른 목적은 피레스로이드계 살충성분을 살충성분으로 함유하고 해충유인제, 유성아크릴수지, 추진제 및 용제를 함유함을 특징으로 하는 분사식 살충페인트의 제조방법을 제공하는 것이다.Another object of the present invention is to provide a method for producing a spray insecticide paint, characterized in that it contains a pyrethroid-based pesticide component as a pesticide component, and contains a pest attraction agent, an oily acrylic resin, a propellant and a solvent.

본 발명에서 사용될 수 있는 용제로는 1,4-디옥산, 1,1,1-트리킬로로에탄, 메탄올 및 에탄올에서 선택된 용제이다.Solvents that can be used in the present invention are solvents selected from 1,4-dioxane, 1,1,1-trikiloethane, methanol and ethanol.

다음에 실시예로서 본 발명은 더욱 상세히 설명한다.Next, the present invention will be described in more detail by way of examples.

본 명세서에서 사용된 %는 모두 중량%이다.All percentages used herein are in weight percent.

[실시예 1]Example 1

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 2]Example 2

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 3]Example 3

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 4]Example 4

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 5]Example 5

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 6]Example 6

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 7]Example 7

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 8]Example 8

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[실시예 9]Example 9

상기의 성분을 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 분사식 살충페인트를 제조한다.The above components are injected into a spray pressure vessel according to a conventional spraying insecticide preparation method to prepare a spray insecticide paint.

[비교예][Comparative Example]

상기의 성분을 통상의 니스의 제조방법에 따라서 살충니스를 제조한다.The insecticide varnish is prepared according to the conventional method for producing varnish.

[실험예]Experimental Example

바퀴벌레에 대한 살충효과 및 잔류효과의 비교실험 결과는 표 1과 같으며, A사 제품은 30일이 경과하면 죽은 바퀴벌레의 수가 감소하나 본발명의 제품은 스프레이한 후 상자는 60일이 경과하여도 살충 및 지속효과가 유지되고 있다.The results of the comparative experiments of pesticidal and residual effects on cockroaches are shown in Table 1.The number of dead cockroaches decreased after 30 days for the A company, but the box after 60 days after spraying the product of the present invention. Insecticidal and lasting effects are maintained.

파리에 대한 살충효과 및 잔류효과의 비교실험결과는 표 2와 같으며 이 결과에서도 A사제품은 60일 경과하면 죽은 파리의 수가 급격히 감소하지만, 본 발명의 제품은 60일이 경과한 후에도 살충 및 지속효과가 유지됨을 알 수 있다.Comparative results of the insecticidal and residual effects on flies are shown in Table 2, and in this result, the number of dead flies decreases rapidly after 60 days in the company A, but the product of the present invention is effective after 60 days. It can be seen that the sustaining effect is maintained.

Claims (2)

접촉작용에 의해 살충효과를 나타내는 피레스로이드계 살충성분 0.1-2.5%, 유성 아크릴수지 5-10%, 곤충유인제 0.01-0.1%, 추진제 30-60%, 용제 30-50%를 함유하며 통상의 분사식 살충제의 제조방법에 따라서 분사식 압력용기에 주입하여 제조된 것을 특징으로 하는 분사식 살충페인트.It contains 0.1-2.5% of pyrethroid insecticides, 5-10% of oily acrylic resins, 0.01-0.1% of insect attractants, 30-60% of propellants, and 30-50% of solvents. Spraying insecticide paint, characterized in that prepared by injecting in a spray-type pressure vessel according to the manufacturing method of the spraying insecticide. 제1항에 있어서, 피레스로이드계 살충제로서 델타메트린, 퍼메트린, 사이퍼메트린에서 선택된 살충제를 사용하고, 곤충유인제로서 프로필 사이클로헥실아세테이트, Z-9-트리코센 및 메틸 4-메틸-피롤-2-카르복실레이트에서 선택된 곤충 유인제를 사용하고, 용제로서 1,4-디옥산, 1,1,1-트리클로로에탄, 메탄올 및 에탄올에서 선택된 용제를 사용하여 제조된 분사식 살충페인트.A pesticide selected from deltamethrin, permethrin, cypermethrin is used as a pyrethroid insecticide, and propyl cyclohexyl acetate, Z-9-tricosene and methyl 4-methyl-pyrrole-2 are used as insect attractants. Spray insecticidal paint prepared using an insect attractant selected from carboxylates and a solvent selected from 1,4-dioxane, 1,1,1-trichloroethane, methanol and ethanol as solvents.
KR1019950024885A 1995-08-12 1995-08-12 Spray insecticide paint Expired - Fee Related KR0160843B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1019950024885A KR0160843B1 (en) 1995-08-12 1995-08-12 Spray insecticide paint
TW085110411A TW401452B (en) 1995-08-12 1996-08-27 Spray-type insecticidal paint and the process for the preparation thereof

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Application Number Priority Date Filing Date Title
KR1019950024885A KR0160843B1 (en) 1995-08-12 1995-08-12 Spray insecticide paint

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KR970010901A KR970010901A (en) 1997-03-27
KR0160843B1 true KR0160843B1 (en) 1998-11-16

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TW401452B (en) 2000-08-11

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