JPH0663710A - Continuous casting equipment - Google Patents
Continuous casting equipmentInfo
- Publication number
- JPH0663710A JPH0663710A JP23651392A JP23651392A JPH0663710A JP H0663710 A JPH0663710 A JP H0663710A JP 23651392 A JP23651392 A JP 23651392A JP 23651392 A JP23651392 A JP 23651392A JP H0663710 A JPH0663710 A JP H0663710A
- Authority
- JP
- Japan
- Prior art keywords
- crucible
- molten metal
- continuous casting
- groove
- casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009749 continuous casting Methods 0.000 title claims description 22
- 239000002184 metal Substances 0.000 claims abstract description 31
- 229910052751 metal Inorganic materials 0.000 claims abstract description 31
- 238000005266 casting Methods 0.000 claims abstract description 25
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 20
- 239000000956 alloy Substances 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 238000005275 alloying Methods 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002893 slag Substances 0.000 abstract description 16
- 238000010276 construction Methods 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 229910002804 graphite Inorganic materials 0.000 description 9
- 239000010439 graphite Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 5
- 239000011449 brick Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000005587 bubbling Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910017985 Cu—Zr Inorganic materials 0.000 description 1
- 229910001093 Zr alloy Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Landscapes
- Continuous Casting (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は連続鋳造装置に関し、特
に、所定の合金成分に満たない規格外鋳塊の発生を低減
すると共に、鋳塊の品質を向上させることができる連続
鋳造装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a continuous casting apparatus, and more particularly, to a continuous casting apparatus capable of improving the quality of ingots while reducing the occurrence of substandard ingots which do not meet a predetermined alloy composition.
【0002】[0002]
【従来の技術】一般に、銅,及び銅合金の鋳造は、連続
的に鋳造する全連続鋳造方式,或いは断続的に鋳造する
半連続鋳造方式によって行われる。2. Description of the Related Art Generally, copper and copper alloys are cast by a continuous casting method of continuous casting or a semi-continuous casting method of intermittent casting.
【0003】全連続鋳造方式において、溶湯に合金元素
を添加配合する場合、機械的,或いは人的な方法によっ
て移送されている溶湯に合金元素を粒状,粉状,及び線
状の状態で供給することにより行われている。このと
き、合金元素の添加量が多い場合には複数の添加口から
行い、また、高融点,難拡散の合金元素を添加する場合
には、拡散時間を得るために鋳造速度を遅くしたり、鋳
込み位置より上流に添加したり、或いは、ガスバブリン
グ等で攪拌を加えたりしている。このような方法で合金
成分が均一で、しかも合金成分が所定の成分規格を満た
すように合金元素を添加配合している。In the all continuous casting method, when alloying elements are added to the molten metal, the alloying elements are supplied in a granular, powdery or linear state to the molten metal being transferred by a mechanical or human method. It is done by. At this time, when the addition amount of the alloy element is large, it is carried out from a plurality of addition ports, and when the alloy element having a high melting point and difficult diffusion is added, the casting speed is slowed down to obtain the diffusion time, It is added upstream from the casting position, or is agitated by gas bubbling or the like. By such a method, alloying elements are added and blended so that the alloying components are uniform and the alloying components satisfy predetermined component specifications.
【0004】[0004]
【発明が解決しようとする課題】しかし、従来の連続鋳
造方式によると、鋳込み位置より上流で合金元素を添加
配合しているため、鋳造開始時,及び終了時に成分規格
範囲に満たない鋳塊が発生し、製品歩留りを低下させて
いる。また、合金元素が炉に移送されると、合金元素が
酸化して炉壁に付着し、これが微量不純物として長く鋳
塊に残留したり、或いは、酸化して浮遊したものはスラ
グ介在物として鋳塊に巻き込まれ、鋳塊の品質を低下さ
せるという問題もある。更に、合金成分が所定の成分規
格を満たすようにガスバブリング等で攪拌を行ったり、
低濃度から高濃度までの合金組成が得られるように複数
の配合箇所を設けているため、装置全体が複雑化し、作
業工数が増加して、作業ミスを誘発する原因となってい
る。However, according to the conventional continuous casting method, since the alloying elements are added and blended upstream from the casting position, ingots that do not meet the component specification range at the start and end of casting may be formed. Occurs, reducing the product yield. Further, when the alloy elements are transferred to the furnace, the alloy elements are oxidized and adhere to the furnace wall, and these remain as trace impurities in the ingot for a long time, or those that are oxidized and floated are cast as slag inclusions. There is also a problem that the quality of the ingot is deteriorated by being caught in the ingot. Furthermore, stirring is performed by gas bubbling, etc. so that the alloy components meet the prescribed component standards,
Since a plurality of blending points are provided so that an alloy composition with a low concentration to a high concentration can be obtained, the entire apparatus becomes complicated and the number of working steps increases, which causes a working error.
【0005】従って、本発明の目的は成分規格範囲に満
たない鋳塊の発生を低減して、製品歩留りを向上させる
ことができる連続鋳造装置を提供することである。Therefore, it is an object of the present invention to provide a continuous casting apparatus which can reduce the production of ingots that do not meet the component specification range and improve the product yield.
【0006】本発明の他の目的はスラグの鋳塊への混入
巻き込みを防いで鋳塊の品質を向上させることができる
連続鋳造装置を提供することである。Another object of the present invention is to provide a continuous casting apparatus capable of preventing entrainment of slag in the ingot and improving the quality of the ingot.
【0007】本発明の更に他の目的は装置全体の構造を
簡略化することができる連続鋳造装置を提供することで
ある。Still another object of the present invention is to provide a continuous casting apparatus which can simplify the structure of the entire apparatus.
【0008】[0008]
【課題を解決するための手段】本発明は上記問題点に鑑
み、成分規格範囲に満たない鋳塊の発生を低減して、製
品歩留りを向上させると共に、スラグの鋳塊への混入巻
き込みを防いで鋳塊の品質を向上させ、且つ構造を簡略
化しながら合金成分が成分規格を満足できるようにする
ため、溶湯が通過する溝と、溝の所定の位置に設けら
れ、合金元素を添加配合するルツボと、ルツボの溶湯が
通過する部分,及びルツボの上流側,及び下流側の溝に
それぞれ配置された複数のフィルターと、ルツボの外周
に設けられ、ルツボの内部の溶湯を間接的に加熱する加
熱手段を有した配合樋を、鋳造ラインの最後部に設けた
連続鋳造装置を提供するものである。In view of the above problems, the present invention reduces the occurrence of ingots that do not meet the component specification range, improves the product yield, and prevents the inclusion of slag in the ingots. In order to improve the quality of the ingot and to allow the alloy component to satisfy the component standard while simplifying the structure, it is provided in the groove through which the molten metal passes and at a predetermined position of the groove, and the alloy element is added and blended. The crucible, a portion through which the molten metal of the crucible passes, and a plurality of filters respectively arranged in the upstream and downstream grooves of the crucible, and the crucible's outer periphery, which indirectly heats the molten metal inside the crucible. The present invention provides a continuous casting device in which a compound gutter having a heating means is provided at the end of a casting line.
【0009】上記フィルターは、耐酸化性の炭化珪素
(SiC)より成る。また、溝に配置された複数のフィ
ルターは、溝の上流側から下流側にかけてメッシュが細
かくなるように構成されている。The filter is made of oxidation resistant silicon carbide (SiC). Further, the plurality of filters arranged in the groove are configured so that the mesh becomes finer from the upstream side to the downstream side of the groove.
【0010】[0010]
【作用】上記構成に基づく本発明の連続鋳造装置による
と、配合樋を装置最後部に設けて鋳造直前に合金元素を
添加配合するようにしたため、鋳造開始時,及び終了時
において、成分規格範囲に満たない鋳塊の発生を低減す
ることができ、製品歩留りを向上させることができる。
また、ルツボの内部で合金元素を添加配合するようにし
たため、合金元素がスラグとなった場合、フィルターが
堰の役目をなし、スラグをルツボ内に残留させる。従っ
て、スラグの鋳塊への混入巻き込みを防いで鋳塊の品質
を向上させることができる。更に、溝に複数のフィルタ
ーが設けられているため、前述のスラグの濾過作用に加
えて通過時に溶湯を攪拌することができ、合金元素を溶
湯に均一に拡散させることができ、更に、ルツボの外周
に加熱手段が設けられているため、拡散効果を更に高め
ることができる。According to the continuous casting apparatus of the present invention having the above-mentioned structure, the mixing trough is provided at the end of the apparatus so that the alloying elements are added and mixed immediately before the casting. It is possible to reduce the generation of ingots that do not meet the requirements, and improve the product yield.
Further, since the alloying elements are added and blended inside the crucible, when the alloying elements become slag, the filter acts as a weir, and the slag remains in the crucible. Therefore, it is possible to prevent the inclusion of slag in the ingot and improve the quality of the ingot. Furthermore, since a plurality of filters are provided in the groove, in addition to the filtering action of the slag described above, the molten metal can be agitated when passing through, and the alloying elements can be uniformly diffused in the molten metal. Since the heating means is provided on the outer circumference, the diffusion effect can be further enhanced.
【0011】[0011]
【実施例】以下、本発明の連続鋳造装置について、添付
図面を参照しながら詳細に説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS The continuous casting apparatus of the present invention will be described in detail below with reference to the accompanying drawings.
【0012】図1(a),(b) には、本発明の一実施例の連
続鋳造装置の配合樋30が示されている。この配合樋3
0は、溶解炉,移送樋,保持炉等より構成される鋳造設
備本体の最後部に設けられている。1 (a) and 1 (b) show a compound gutter 30 of a continuous casting apparatus according to an embodiment of the present invention. This mix gutter 3
0 is provided at the rearmost part of the casting equipment body including a melting furnace, a transfer gutter, and a holding furnace.
【0013】次に、配合樋30を詳細に説明する。配合
樋30は、樋枠16と、当該樋枠16の内部に積み上げ
られた異形レンガ17と、異形レンガ17の内部に形成
された樋溝21と、これらの上部を閉塞する上蓋18を
有して構成されている。Next, the compound gutter 30 will be described in detail. The compound gutter 30 has a gutter frame 16, a deformed brick 17 stacked inside the gutter frame 16, a gutter groove 21 formed inside the deformed brick 17, and an upper lid 18 that closes these upper parts. Is configured.
【0014】樋溝21は、溶湯19を通過させるもので
あり、合金元素を投入配合する略円形のプール部21a
を有している。プール部21aの上流側には荒フィルタ
ー1が、また、プール部21aの下流側には2枚の細フ
ィルター4,5がそれぞれ配置され、更に、プール部2
1aの内部の溶湯19には中フィルター2,3を有した
黒鉛性ルツボ6が配置されている。The trough 21 allows the molten metal 19 to pass therethrough, and has a substantially circular pool portion 21a into which an alloy element is added and mixed.
have. The rough filter 1 is arranged on the upstream side of the pool portion 21a, and the two thin filters 4 and 5 are arranged on the downstream side of the pool portion 21a.
A graphite crucible 6 having medium filters 2 and 3 is arranged in the molten metal 19 inside 1a.
【0015】異形レンガ17は、プール部21aの外周
に6個のテコランダムヒーター7,8,9,10,1
1,12と、下流側の底部に溶湯19を鋳造ストッパー
13を介して鋳型20に送り込む鋳造ノズル14を有し
て構成されている。The odd-shaped bricks 17 are composed of six tecorundum heaters 7, 8, 9, 10, 1 on the outer circumference of the pool portion 21a.
1, 12 and a casting nozzle 14 for feeding the molten metal 19 to the mold 20 via the casting stopper 13 at the bottom portion on the downstream side.
【0016】以下、Cu−Zr鋳造の場合の本発明の具
体的な動作を説明する。配合樋30の溝21に溶湯(C
u)19が移送されると、溶湯19は、まず、荒フィル
ター1と黒鉛性ルツボ6の中フィルター2で不純物を濾
過され、プール部21aに移送される。The specific operation of the present invention in the case of Cu-Zr casting will be described below. Molten metal (C
When u) 19 is transferred, the molten metal 19 is first filtered for impurities by the rough filter 1 and the middle filter 2 of the graphite crucible 6 and transferred to the pool portion 21a.
【0017】プール部21aに溶湯19が移送される
と、これにプール部21aの上部からZrの合金元素を
添加配合する。この配合によって溶湯19に温度低下が
生じるが、プール部21aの外周に位置するテコランダ
ムヒーター7,8,9,10,11,12が黒鉛性ルツ
ボ6を間接的(溶湯に接しないで)加熱しているため、
これを防ぐことができる。このため、Zrの合金元素を
溶湯19に確実に配合させることができる。When the molten metal 19 is transferred to the pool portion 21a, an alloy element of Zr is added and mixed into the molten metal 19 from the upper portion of the pool portion 21a. Although a temperature drop occurs in the molten metal 19 due to this mixing, the tecorundum heaters 7, 8, 9, 10, 11, 12 located on the outer periphery of the pool portion 21a heat the graphite crucible 6 indirectly (without contacting the molten metal). Because
This can be prevented. Therefore, the Zr alloy element can be reliably mixed into the molten metal 19.
【0018】黒鉛性ルツボ6でZrが配合された溶湯1
9は、黒鉛性ルツボ6の中フィルター3と2枚の細フィ
ルター4,5を順次通過することで攪拌され、合金元素
の拡散が促進されると共に、フィルター3,4,5を通
過するたびに酸化したスラグが捕捉され、清浄される。
このようにスラグ等のないクリーン化された溶湯19
は、鋳造ストッパー13,及び鋳造ノズル14を介して
鋳型20に送り込まれ、冷却されて鋳塊15となる。Molten metal 1 containing Zr in a graphite crucible 6
9 is agitated by sequentially passing through the medium filter 3 of the graphite crucible 6 and the two fine filters 4 and 5, and the diffusion of alloying elements is promoted. Oxidized slag is captured and cleaned.
Cleaned molten metal 19 without slag
Is sent to the mold 20 through the casting stopper 13 and the casting nozzle 14 and cooled to become the ingot 15.
【0019】このように本発明の連続鋳造装置は、鋳込
み直前に配合攪拌することで鋳造開始時,及び終了時に
おいて、成分規格範囲に満たない鋳塊の発生を低減し
て、製品歩留りを向上させることができる。As described above, in the continuous casting apparatus of the present invention, by mixing and stirring immediately before casting, the generation of ingots that do not meet the component specification range at the start and end of casting is reduced, and the product yield is improved. Can be made.
【0020】また、黒鉛性ルツボ6の内部で合金元素を
添加配合するようにしたため、合金元素がスラグとなっ
た場合、フィルター2,3が堰の役目をなし、スラグを
ルツボ内に残留させることができ、その結果、スラグの
鋳塊への混入巻き込みを防いで鋳塊の品質を向上させる
ことができる。また、合金鋳造終了時に黒鉛性ルツボ6
を引き上げると、一挙に酸化スラグを除去することがで
きる。Further, since the alloying elements are added and blended inside the graphite crucible 6, when the alloying elements become slag, the filters 2 and 3 function as a weir, and the slag remains in the crucible. As a result, the inclusion of slag in the ingot can be prevented and the quality of the ingot can be improved. Also, when the alloy casting is completed, the graphite crucible 6
By pulling up, the oxidized slag can be removed all at once.
【0021】更に、樋溝1にフィルター3,4,5が設
けられているため、前述のスラグの濾過作用に加えて通
過時に溶湯19を攪拌することができ、合金元素を溶湯
19に均一に拡散させることができ、更に、黒鉛性ルツ
ボ6の外周にテコランダムヒーター7,8,9,10,
11,12が設けられているため、拡散効果を更に高め
ることができる。Further, since the trough 1 is provided with the filters 3, 4, and 5, the molten metal 19 can be agitated at the time of passage in addition to the filtering action of the slag described above, and the alloy elements are uniformly distributed in the molten metal 19. It can be diffused, and in addition, on the outer periphery of the graphite crucible 6, tecorundum heaters 7, 8, 9, 10,
Since 11 and 12 are provided, the diffusion effect can be further enhanced.
【0022】加えて、鋳込み開始時点で樋の温度が低い
と、当然流れてくる溶湯も冷えてしまい、鋳造ノズルの
詰まりや、樋内部での凝固等のトラブルが発生するが、
テコランダムヒーター7,8,9,10,11,12を
使い、鋳込み開始前に予め樋内部を加熱しておくと上記
トラブルを回避することができる。In addition, if the temperature of the gutter is low at the start of casting, naturally the molten metal also cools, causing problems such as clogging of the casting nozzle and solidification inside the gutter.
The above troubles can be avoided by using the tecorundum heaters 7, 8, 9, 10, 11, 12 to preheat the inside of the gutter before starting casting.
【0023】尚、上記実施例では、Zrの配合について
説明したが、この他に活性合金(例えば、Ti,C
r),及び高融点合金(例えば、Nb)等の配合にも応
用することができる。Although the Zr composition is described in the above embodiment, other active alloys (for example, Ti, C
r), and high melting point alloys (for example, Nb) and the like can also be applied.
【0024】[0024]
【発明の効果】以上説明したように、本発明の連続鋳造
装置によると、溶湯が通過する溝と、溝の所定の位置に
設けられ、合金元素を添加配合するルツボと、ルツボの
溶湯が通過する部分,及び溝のルツボの上流側,及び下
流側にそれぞれ配置された複数のフィルターと、ルツボ
の外周に設けられ、ルツボの内部の溶湯を間接的に加熱
する加熱手段を有した配合樋を、鋳造ラインの最後部に
設けたため、成分規格範囲に満たない鋳塊の発生を低減
して、製品歩留りを向上させると共に、スラグの鋳塊へ
の混入巻き込みを防いで鋳塊の品質を向上させ、且つ構
造を簡略化しながら合金成分が成分規格を満足させるこ
とができる。As described above, according to the continuous casting apparatus of the present invention, the groove through which the molten metal passes, the crucible which is provided at a predetermined position of the groove and which is mixed with the alloy element, and the molten metal of the crucible pass through. A mixing trough having a plurality of filters arranged on the upstream side and the downstream side of the crucible of the portion and the groove, and a heating means provided on the outer circumference of the crucible and indirectly heating the molten metal inside the crucible. Since it is provided at the end of the casting line, it reduces the occurrence of ingots that do not meet the component specification range, improves the product yield, and prevents entrainment of slag in the ingot and improves the quality of the ingot. In addition, the alloy component can satisfy the component standard while simplifying the structure.
【図1】本発明の一実施例に係る連続鋳造装置の配合樋
を示す説明図。FIG. 1 is an explanatory view showing a mixing gutter of a continuous casting apparatus according to an embodiment of the present invention.
1 荒フィルター 2,3 中フ
ィルター 4,5 細フィルター 6 黒鉛
性ルツボ 7,8,9,10,11,12 テコランダムヒーター 13 鋳造ストッパー 14 鋳造
ノズル 15 鋳塊 16 樋枠 17 異形レンガ 18 上蓋 19 溶湯 20 鋳型 30 配合樋1 Rough filter 2,3 Medium filter 4,5 Fine filter 6 Graphite crucible 7,8,9,10,11,12 Teco random heater 13 Casting stopper 14 Casting nozzle 15 Ingot 16 Gutter frame 17 Deformed brick 18 Upper lid 19 Molten metal 20 Mold 30 Mixing gutter
Claims (3)
最後部に、合金元素を添加配合する配合樋が設けられ、 前記配合樋は、溶湯が通過する溝と、当該溝の所定の位
置に設けられ、前記合金元素を添加配合するルツボと、
前記ルツボの前記溶湯が通過する部分,及び前記ルツボ
の上流側,及び下流側の前記溝にそれぞれ配置された複
数のフィルターと、前記ルツボの外周に設けられ、前記
ルツボの内部の前記溶湯を間接的に加熱する加熱手段を
有していることを特徴とする連続鋳造装置。1. A mixing gutter for adding and mixing alloying elements is provided at the end of a casting line for casting copper and copper alloys, wherein the mixing gutter is a groove through which molten metal passes and a predetermined position of the groove. And a crucible to which the alloy element is added and blended,
A portion of the crucible through which the molten metal passes, and a plurality of filters respectively arranged in the grooves on the upstream side and the downstream side of the crucible, and on the outer circumference of the crucible, the molten metal inside the crucible is indirectly connected. A continuous casting apparatus having a heating means for selectively heating.
より成る構成の請求項1の連続鋳造装置。2. The filter is made of silicon carbide (SiC).
The continuous casting device according to claim 1, wherein the continuous casting device comprises:
側から下流側にかけてメッシュが細かくなるように構成
されている請求項1の連続鋳造装置。3. The continuous casting apparatus according to claim 1, wherein the plurality of filters are configured such that the mesh becomes finer from the upstream side to the downstream side of the groove.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23651392A JPH0663710A (en) | 1992-08-12 | 1992-08-12 | Continuous casting equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23651392A JPH0663710A (en) | 1992-08-12 | 1992-08-12 | Continuous casting equipment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0663710A true JPH0663710A (en) | 1994-03-08 |
Family
ID=17001823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23651392A Pending JPH0663710A (en) | 1992-08-12 | 1992-08-12 | Continuous casting equipment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0663710A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009069782A1 (en) | 2007-11-30 | 2009-06-04 | The Furukawa Electric Co., Ltd. | Method of regulating composition of molten metal during continuous casting and apparatus therefor |
-
1992
- 1992-08-12 JP JP23651392A patent/JPH0663710A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009069782A1 (en) | 2007-11-30 | 2009-06-04 | The Furukawa Electric Co., Ltd. | Method of regulating composition of molten metal during continuous casting and apparatus therefor |
| US8201614B2 (en) | 2007-11-30 | 2012-06-19 | The Furukawa Electric Co., Ltd. | Method and an apparatus of controlling chemical composition of a molten metal during continuous casting |
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