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JP7011820B2 - Adhesive tape and manufacturing method of adhesive tape - Google Patents

Adhesive tape and manufacturing method of adhesive tape Download PDF

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JP7011820B2
JP7011820B2 JP2018088224A JP2018088224A JP7011820B2 JP 7011820 B2 JP7011820 B2 JP 7011820B2 JP 2018088224 A JP2018088224 A JP 2018088224A JP 2018088224 A JP2018088224 A JP 2018088224A JP 7011820 B2 JP7011820 B2 JP 7011820B2
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adhesive tape
pressure
base material
sensitive adhesive
material layer
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JP2019194279A (en
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尚吉 濱野
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Kyodo Giken Chemical Co Ltd
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Kyodo Giken Chemical Co Ltd
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Priority to DE102019110753.9A priority patent/DE102019110753B4/en
Priority to KR1020190048165A priority patent/KR102210182B1/en
Priority to CN201910353200.8A priority patent/CN110423565B/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/24Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241Polyolefin, e.g.rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2477/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/31Applications of adhesives in processes or use of adhesives in the form of films or foils as a masking tape for painting
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Adhesive Tapes (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Description

本発明は,粘着テープ(両面粘着テープを含む)及び粘着テープの製造方法に関し,より詳細には,建築内外装,建築塗装,車両塗装等においてマスキングや養生用に使用される粘着テープ,梱包等に使用される粘着テープのように,手切れ性を有することが求められる粘着テープにおいて,手切れ性を維持しつつ,基材層の伸縮防止と引張り強さの向上を図ることで,貼着後の位置ずれ及び剥離,ロール状に巻き取った際のテレスコープ状(竹の子状)の変型を防止し得る粘着テープ及びその製造方法に関する。 The present invention relates to an adhesive tape (including double-sided adhesive tape) and a method for manufacturing the adhesive tape, and more specifically, an adhesive tape used for masking and curing in building interior / exterior, building painting, vehicle painting, etc., packaging, etc. For adhesive tapes that are required to have hand-cutting properties, such as the adhesive tapes used in The present invention relates to an adhesive tape capable of preventing subsequent misalignment and peeling, and deformation of a telescope-like (bamboo child-like) when wound into a roll, and a method for manufacturing the same.

前述した建築内外装,建築塗装,車両塗装等においてマスキング及び養生のために使用される粘着テープは,一般に,基材層となるフィルムの片面に粘着剤を塗布した片面テープが使用されている。 As the adhesive tape used for masking and curing in the above-mentioned interior / exterior of buildings, architectural painting, vehicle painting, etc., a single-sided tape in which an adhesive is applied to one side of a film to be a base material layer is generally used.

このような粘着テープ100は,図8に示すように,粘着剤層130が内側,基材層120が外側となるように巻き芯140等にロール状に巻かれた状態で提供されており,使用時,ユーザーは粘着テープ100をロールから必要な長さを引き出し,被着物に貼着した後,所望の箇所で切断して貼着する。 As shown in FIG. 8, such an adhesive tape 100 is provided in a state of being rolled into a winding core 140 or the like so that the adhesive layer 130 is on the inside and the base material layer 120 is on the outside. At the time of use, the user pulls out the required length of the adhesive tape 100 from the roll, attaches it to the adherend, and then cuts and attaches the adhesive tape 100 at a desired portion.

このような粘着テープ100の切断に際しては,鋸歯状の刃を持つ専用のカッターの使用又は,はさみあるいはカッターナイフ等の刃物の使用により切断することもできるが,切断する度にこのような刃物等を使用することの煩雑さを回避するために,手でも簡単に切ることができる「手切れ性」を有する粘着テープが要望されている。 When cutting such an adhesive tape 100, it is possible to cut by using a dedicated cutter having a sawtooth-shaped blade or by using a blade such as scissors or a cutter knife, but such a blade or the like is used every time the tape is cut. In order to avoid the complexity of using the adhesive tape, there is a demand for an adhesive tape having "hand-cutting property" that can be easily cut by hand.

このような手切れ性を有する粘着テープとして,和紙,繊維織物(以下「割布」と言う。),及び,切れ目となるエンボスを付けた合成樹脂フィルムを基材層とした粘着テープ等がある。 Adhesive tapes having such hand-cutting properties include Japanese paper, textile fabrics (hereinafter referred to as "split cloth"), and adhesive tapes using a synthetic resin film with embossed cuts as a base material. ..

特に,粘着テープを手で切る場合,粘着テープの長手方向に対し直交する方向に直線状に切断できることが要望されており,このような要求を満たす粘着テープとしては,基材層を前述した割布によって構成した,所謂「布テープ」が主流で,一部に,粘着テープの長手方向と直交する方向に凹溝を形成して手切れ性を付与したポリオレフィン系樹脂フィルムを基材層としたものが提供されている。 In particular, when the adhesive tape is cut by hand, it is required that the adhesive tape can be cut linearly in a direction orthogonal to the longitudinal direction of the adhesive tape. The so-called "cloth tape" made of cloth is the mainstream, and a polyolefin-based resin film having a concave groove formed in a direction orthogonal to the longitudinal direction of the adhesive tape to impart hand-cutting property is used as a base material layer. Things are offered.

前述の布テープでは,スフ(レーヨン)又は,ポリエステル等の繊維を,経糸と緯糸を異なる太さで織って形成した割布の両面又は片面に,厚さ10~40μm程度のPEフィルムをラミネートしたものが基材層として使用されている。 In the above-mentioned cloth tape, a PE film having a thickness of about 10 to 40 μm is laminated on both sides or one side of a split cloth formed by weaving fibers such as suhu (rayon) or polyester with different thicknesses of warps and wefts. Is used as a substrate layer.

このように経糸と緯糸を織ることによって製造される割布を備えた基材層を使用した布テープでは,手で切った場合でも,割布の経糸又は緯糸の長さ方向に直線状に切断することができる。 In the cloth tape using the base material layer provided with the split cloth produced by weaving the warp and weft in this way, even if it is cut by hand, it is cut linearly in the length direction of the warp or weft of the split cloth. can do.

しかし,このような布テープでは,前述した構造から,基材層を得るためには,予め織っておいた割布を,PEフィルムとラミネートする工程が必要となり,製造工程が多工程となる結果,布テープは高価となる。 However, with such a cloth tape, in order to obtain a base material layer from the above-mentioned structure, a step of laminating a pre-woven split cloth with a PE film is required, resulting in a multi-step manufacturing process. , Cloth tape is expensive.

そこで,単層の合成樹脂フィルムを基材層としつつ,手で切った場合であっても,幅方向に直線状に切断することができる工夫がされた粘着テープも提案されている。 Therefore, an adhesive tape has been proposed in which a single-layer synthetic resin film is used as a base material and can be cut linearly in the width direction even when cut by hand.

このような粘着テープ100として,図9に示すように一方の面を平滑面121と成すと共に,他方の面を粘着テープの長手方向と直交する方向に多数の凹溝123が所定間隔で形成された凹凸面122としたポリオレフィン樹脂フィルムを基材層120とし,この基材層120の前記凹凸面122に,粘着剤を塗布して粘着剤層130を形成した粘着テープが提案されている(特許文献1)。 As shown in FIG. 9, as such an adhesive tape 100, one surface is formed as a smooth surface 121, and a large number of concave grooves 123 are formed on the other surface in a direction orthogonal to the longitudinal direction of the adhesive tape at predetermined intervals. A pressure-sensitive adhesive tape has been proposed in which a polyolefin resin film having an uneven surface 122 is used as a base material layer 120, and an adhesive is applied to the uneven surface 122 of the base material layer 120 to form an adhesive layer 130 (Patent). Document 1).

また,前述したように凹凸面122を備えたポリオレフィン樹脂フィルムを基材層120とした粘着テープ100において,手切れ性を維持しつつ,粘着テープ100の長手方向への伸びを低減させるための構造を備えた粘着テープ100も提案されている。 Further, as described above, in the adhesive tape 100 having the polyolefin resin film provided with the uneven surface 122 as the base material layer 120, the structure for reducing the elongation of the adhesive tape 100 in the longitudinal direction while maintaining the hand-cutting property. The adhesive tape 100 provided with the above is also proposed.

このような粘着テープ100として,図10に示すように,ポリオレフィン樹脂フィルム製基材層120の凹凸面122上に形成する粘着剤層130を,不織布又は割布135と粘着剤131とによって形成することを提案したものがある(特許文献2)。 As such an adhesive tape 100, as shown in FIG. 10, the adhesive layer 130 formed on the uneven surface 122 of the polyolefin resin film base material layer 120 is formed by the non-woven fabric or the split cloth 135 and the adhesive 131. There is a proposal for this (Patent Document 2).

また,図11に示すように,ポリオレフィン樹脂フィルム製基材層120の凹凸面122に,数平均分子量が10,000以上でガラス転移温度が0~80℃であるポリエステル系樹脂136を塗布した後に,アクリル系の粘着剤を塗布して,粘着剤層130を形成した粘着テープも提案されている(特許文献3)。 Further, as shown in FIG. 11, after applying a polyester resin 136 having a number average molecular weight of 10,000 or more and a glass transition temperature of 0 to 80 ° C. on the uneven surface 122 of the base layer 120 made of a polyolefin resin film. A pressure-sensitive adhesive tape having an pressure-sensitive adhesive layer 130 formed by applying an acrylic pressure-sensitive adhesive has also been proposed (Patent Document 3).

特開平3-47885号公報Japanese Unexamined Patent Publication No. 3-47885 特開平9-137133号公報Japanese Unexamined Patent Publication No. 9-137133 実開2001-172586号公報Actual Opening 2001-172586 Gazette

前掲の特許文献1として紹介した粘着テープ100(図9)では,基材層120として使用するポリオレフィン樹脂フィルムの凹凸面122に,粘着テープ100の長手方向と直交する方向に凹溝123が形成されていることから,粘着テープ100を手で切った場合であっても,基材層120が凹溝123に沿って裂けることで,直線状にきれいに切断することができるようになっている。 In the adhesive tape 100 (FIG. 9) introduced as Patent Document 1 described above, a concave groove 123 is formed on the uneven surface 122 of the polyolefin resin film used as the base material layer 120 in a direction orthogonal to the longitudinal direction of the adhesive tape 100. Therefore, even when the adhesive tape 100 is cut by hand, the base material layer 120 can be cut neatly in a straight line by tearing along the concave groove 123.

しかし,特許文献1に記載の粘着テープ100が基材層120として採用するポリオレフィン樹脂フィルムは,無延伸でありそれ自体,紙又は割布等に比較して伸縮性に富んでいるだけでなく,粘着テープ100の長手方向と直交方向に凹溝123が形成されていることで,肉薄となっている凹溝123の形成部分で基材層120は更に伸び易くなっている。 However, the polyolefin resin film adopted by the adhesive tape 100 described in Patent Document 1 as the base material layer 120 is not only non-stretched and itself is rich in elasticity as compared with paper or split cloth. Since the concave groove 123 is formed in the direction orthogonal to the longitudinal direction of the adhesive tape 100, the base material layer 120 is more easily stretched in the formed portion of the concave groove 123 which is thin.

その結果,このような粘着テープ100にあっては,図8に示したようなロール状に巻かれている状態から必要な長さのテープを引き出す際,あるいは手で切断する際に粘着テープ100の基材層120が長手方向に伸びてしまい,このようにして伸びた状態で被着物に貼着されることとなる。 As a result, in such an adhesive tape 100, the adhesive tape 100 is used when the tape of a required length is pulled out from the rolled state as shown in FIG. 8 or when the tape is cut by hand. The base material layer 120 of the above is stretched in the longitudinal direction, and is attached to the adherend in such a stretched state.

そして,基材層が伸びた状態で貼着された粘着テープ100は,基材層120が元の形状に復帰しようとして縮むことで,経時と共に被着物上の貼着位置にずれが生じ,あるいは,粘着テープ100の端部が浮きあがって剥離してしまう等の問題が生じ,このような粘着テープを塗装の際のマスキングに使用すれば,塗装位置がずれてしまう。 Then, the adhesive tape 100 attached with the base material layer stretched shrinks in an attempt to return to the original shape of the base material layer 120, so that the attachment position on the adherend shifts with time, or There are problems such as the end of the adhesive tape 100 being lifted and peeled off, and if such an adhesive tape is used for masking during painting, the coating position will shift.

また,特許文献1に記載の粘着テープ100で基材層120として使用するポリオレフィン樹脂フィルムは,前述したように長手方向に伸びやすく,しかも,基材層に対する粘着剤の塗布時に90~110℃に加熱して乾燥されることから,その後にロール状に巻き取る際の張力によって,0.3~1%程度延伸された状態で巻き芯140に巻き取られる。 Further, the polyolefin resin film used as the base material layer 120 in the pressure-sensitive adhesive tape 100 described in Patent Document 1 is easily stretched in the longitudinal direction as described above, and is heated to 90 to 110 ° C. when the pressure-sensitive adhesive is applied to the base material layer. Since it is heated and dried, it is wound around the winding core 140 in a state of being stretched by about 0.3 to 1% due to the tension when it is subsequently wound into a roll shape.

その結果,ロール状に巻き取った後に粘着テープ100が長手方向に収縮することで,粘着テープ100のロールは図12に示すようにテレスコープ状(竹の子状)に変型する不良が生じ易くなっている。 As a result, the adhesive tape 100 shrinks in the longitudinal direction after being wound into a roll shape, so that the roll of the adhesive tape 100 tends to be deformed into a telescope shape (bamboo shoot shape) as shown in FIG. There is.

一方,このようなテレスコープ状(竹の子状)の変形を防止するために粘着テープ100を低張力で巻き取ると,空気の巻き込みにより巻き巣(空洞)が生じ易くなり,何れも外観不良となって製品としては出荷できず,このようにして生じる不良率は,最大で約1~7%に及ぶために歩留りが悪い。 On the other hand, if the adhesive tape 100 is wound with low tension in order to prevent such deformation of the telescope shape (bamboo shoot shape), cavities (cavities) are likely to occur due to the entrainment of air, and both of them have a poor appearance. It cannot be shipped as a product, and the defect rate generated in this way reaches a maximum of about 1 to 7%, resulting in poor yield.

さらに,マスキング又は養生用に使用される粘着テープでは,塗装等の作業が完了した後は,これを被着物より剥離・除去することが必要となるが,手切れ性を付与するために長手方向と直交する方向に前述した凹溝123が形成されたポリオレフィン樹脂フィルムを基材層120とした前述の粘着テープ100は,被着物から剥離する作業中にも伸びやすく,かつ,切れやすいことから,剥離作業が煩雑となる。 Furthermore, with adhesive tape used for masking or curing, it is necessary to peel off and remove it from the adherend after the work such as painting is completed, but in order to impart hand-cutting property, it is necessary to remove it in the longitudinal direction. The above-mentioned adhesive tape 100 having the above-mentioned polyolefin resin film having the concave groove 123 formed in the direction orthogonal to the above-mentioned base layer 120 is easy to stretch and cut even during the work of peeling from the adherend. The peeling work becomes complicated.

このように,片面に凹溝123が形成されたポリオレフィン樹脂フィルムを基材層120とした特許文献1に記載の粘着テープ100では,長手方向に伸び易く,その結果,前述した各種の問題が生じることから,このような粘着テープ100の長手方向の伸びを抑制することが要望されている。 As described above, the adhesive tape 100 described in Patent Document 1 in which the polyolefin resin film having the concave groove 123 formed on one side as the base material layer 120 is easily stretched in the longitudinal direction, and as a result, the above-mentioned various problems occur. Therefore, it is required to suppress the elongation of the adhesive tape 100 in the longitudinal direction.

このような伸びを抑制する方法としては,凹溝123の深さを浅くすることあるいは,基材層120とするポリオレフィン樹脂フィルム全体を厚くすることも考えられるが,この構成では,粘着テープ100の長手方向の伸びを抑制することはできるものの,粘着テープ100の手切れ性が低下してしまい,特にポリオレフィン樹脂フィルム全体の厚みを厚くする構成では,被着物の表面に対する追従性が低下することで剥離等が生じ易くなる。 As a method of suppressing such elongation, it is conceivable to make the depth of the concave groove 123 shallow or to make the entire polyolefin resin film as the base material layer 120 thick, but in this configuration, the adhesive tape 100 Although it is possible to suppress elongation in the longitudinal direction, the hand-cutting property of the adhesive tape 100 is reduced, and particularly in a configuration in which the thickness of the entire polyolefin resin film is increased, the followability to the surface of the adherend is reduced. Peeling or the like is likely to occur.

これに対し,前掲の特許文献2に記載されている粘着テープ(図10)では,粘着剤層130に不織布又は割布135を埋設して粘着剤層130を強化することにより,粘着テープ100の長手方向における伸びの発生を抑制している。 On the other hand, in the adhesive tape (FIG. 10) described in Patent Document 2 described above, the adhesive tape 100 is made by embedding a non-woven fabric or a split cloth 135 in the adhesive layer 130 to strengthen the adhesive layer 130. It suppresses the occurrence of elongation in the longitudinal direction.

しかし,この構成では,不織布又は割布135と粘着剤131を一体化させて粘着剤層130を形成する作業が必要で,図13に示すように,不織布又は割布135と粘着剤131を工程紙150上にラミネートするなどして粘着剤層130を形成した後,基材層120となるポリオレフィン樹脂フィルムに積層する等の作業が必要となることから,前述した布テープの場合と同様,製造時の工程数が増えて製造コストが嵩む結果,粘着テープ100が高価なものとなる。 However, in this configuration, it is necessary to integrate the non-woven fabric or split cloth 135 and the adhesive 131 to form the pressure-sensitive adhesive layer 130, and as shown in FIG. 13, the non-woven fabric or split cloth 135 and the pressure-sensitive adhesive 131 are stepped. Since it is necessary to form the adhesive layer 130 by laminating it on the paper 150 and then laminating it on the polyolefin resin film to be the base material layer 120, it is manufactured in the same manner as in the case of the cloth tape described above. As a result of the increase in the number of steps and the increase in manufacturing cost, the adhesive tape 100 becomes expensive.

しかも,粘着剤層130に不織布又は割布135を埋没させた構造では,伸びを抑制することはできるものの,手切れ性が大幅に低下する。 Moreover, in the structure in which the non-woven fabric or the split cloth 135 is embedded in the pressure-sensitive adhesive layer 130, the elongation can be suppressed, but the hand-cutting property is significantly reduced.

しかも,不織布又は割布135の埋没によって粘着剤層130の変形性が大幅に低下することから,被着部の表面に対する追従性が低下し,剥離又は浮きが生じ易く,マスキングテープとしての機能が損なわれる可能性もある。 Moreover, since the deformability of the adhesive layer 130 is significantly reduced by burying the non-woven fabric or the split cloth 135, the followability to the surface of the adhered portion is lowered, peeling or floating is likely to occur, and the function as a masking tape is obtained. It can also be compromised.

更に,図11に示したようにポリオレフィン樹脂フィルム製の基材層120に設けた凹凸面122に,粘着剤を塗布する前にポリエステル系樹脂136を塗布した前掲の特許文献3に記載の構成では,伸びは抑制できるかもしれないが,手切れ性は大幅に低下するか,または殆ど失われてしまうと考えられる。 Further, as shown in FIG. 11, in the configuration described in Patent Document 3 described above, the polyester resin 136 is applied to the uneven surface 122 provided on the base layer 120 made of the polyolefin resin film before the adhesive is applied. , Elongation may be suppressed, but it is considered that the hand-cutting property is significantly reduced or almost lost.

また,下地層としてポリエステル系樹脂136を塗布した後に,これに続けて溶剤型の粘着剤を塗布して粘着剤層130を形成すると,下地のポリエステル系樹脂136が粘着剤131内の溶剤に侵され,異常を生じる,所謂「ソルベントアタック」によりポリエステル系樹脂136が軟化してしまい,伸びの抑制効果が得られなくなることから,製造方法あるいは材質等についても制約を受けるものと考えられる。 Further, when the polyester resin 136 is applied as the base layer and then the solvent type pressure-sensitive adhesive is applied to form the pressure-sensitive adhesive layer 130, the base polyester-based resin 136 invades the solvent in the pressure-sensitive adhesive 131. Therefore, the polyester resin 136 is softened by the so-called "solvent attack" that causes an abnormality, and the effect of suppressing elongation cannot be obtained. Therefore, it is considered that the manufacturing method or the material is also restricted.

また,特許文献1~3に記載の粘着テープは,基材にポリオリフェン系のプラスチックを使用しており,通気性が不十分であるため,貼着時に被着の表面と粘着テープ100間にエアーを抱き込み易く,見た目の美しさに欠けると共に,抱き込まれたエアーの膨張や,被着物からのアウトガス,基材の熱膨張などが複合し,粘着テープ100の膨れや剥離の要因となり易い問題が有った。 Further, the adhesive tapes described in Patent Documents 1 to 3 use a polyoliphen-based plastic as a base material and have insufficient air permeability. Therefore, when the adhesive tape is attached, it is between the surface of the adherend and the adhesive tape 100. It is easy to embrace air and lacks the beauty of appearance, and the expansion of the embraced air, the outgas from the adherend, the thermal expansion of the base material, etc. are combined, and it is easy to cause the adhesive tape 100 to swell or peel off. There was a problem.

そこで本発明は,上記従来技術における欠点を解消するためになされたものであり,前述したように一方の面を平滑面に,他方の面を凹凸面に形成したポリオレフィン樹脂フィルムを基材層とし,該基材層の凹凸面に粘着剤層を形成した粘着テープにおいて,該粘着テープの幅方向の手切れ性を維持しつつ,長手方向の伸びの抑制,具体的には伸びを70%以下,好ましくは50%以下,より好ましくは30%以下に抑制するとともに,引張強度が向上,具体的には100 (N/50mm幅)以上,好ましくは130(N/50mm幅)以上に向上された粘着テープを提供することにより,貼着後の位置ずれ又は剥離を防止すると共に,ロール状に巻かれた粘着テープが図12に示すようなテレスコープ状(竹の子状)に変形することを防止でき,かつ,塗装作業等の終了後,被着物より剥離する際の作業性が良好で,さらに,通気性を有する粘着テープ(両面粘着テープを含む)及び粘着テープの製造方法を提供することを目的とする。 Therefore, the present invention has been made to eliminate the above-mentioned drawbacks in the prior art, and as described above, a polyolefin resin film having one surface formed as a smooth surface and the other surface as an uneven surface is used as a base material layer. In the adhesive tape in which the adhesive layer is formed on the uneven surface of the base material layer, the elongation in the longitudinal direction is suppressed while maintaining the hand-cutting property in the width direction of the adhesive tape, specifically, the elongation is 70% or less. The tensile strength was improved, preferably 100 (N / 50 mm width) or more, preferably 130 (N / 50 mm width) or more, while suppressing it to 50% or less, more preferably 30% or less. By providing the adhesive tape, it is possible to prevent the adhesive tape from being displaced or peeled off after being attached, and to prevent the adhesive tape wound in a roll shape from being deformed into a telescope shape (bamboo child shape) as shown in FIG. Moreover, it is an object of the present invention to provide a method for manufacturing an adhesive tape (including a double-sided adhesive tape) and an adhesive tape, which have good workability when peeled from an adherend after completion of painting work and the like, and have breathability. And.

以下に,課題を解決するための手段を,発明を実施するための形態で使用する符号と共に記載する。この符号は,特許請求の範囲の記載と発明を実施するための形態の記載との対応を明らかにするために記載したものであり,言うまでもなく,本願発明の技術的範囲の解釈に制限的に用いられるものではない。 The means for solving the problem are described below together with the reference numerals used in the embodiment for carrying out the invention. This reference numeral is described for clarifying the correspondence between the description of the scope of claims and the description of the form for carrying out the invention, and it goes without saying that the reference numerals are limited to the interpretation of the technical scope of the present invention. Not used.

上記目的を達成するために,本発明の粘着テープ10は,
片面に粘着テープの長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層20と,前記基材層20の前記凹凸面22上に形成された粘着剤層30を備え,前記基材層20及び前記粘着剤層30に繊維片32が分散され,前記基材層20及び粘着剤層30を構成する樹脂と前記繊維片32との間に生じた隙間又は前記繊維片32が有する孔による通気性を有していることを特徴とする(請求項1,図1参照)。
In order to achieve the above object, the adhesive tape 10 of the present invention is used.
A base material layer 20 made of an unstretched polyolefin resin film having uneven surfaces 22 having a plurality of concave grooves 23 formed at predetermined intervals on one side in a direction orthogonal to the longitudinal direction of the adhesive tape, and the base material layer 20. The resin having the pressure-sensitive adhesive layer 30 formed on the uneven surface 22 of the above, and the fiber pieces 32 being dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30, constituting the base material layer 20 and the pressure-sensitive adhesive layer 30. It is characterized by having air permeability due to a gap formed between the fiber piece 32 and the fiber piece 32 or a hole possessed by the fiber piece 32 (see claim 1 and FIG. 1).

また,本発明の粘着テープ10は,前記粘着剤層30,30’を前記基材層20の両面に形成し,前記基材層20及び前記粘着剤層30,30’に繊維片32が分散され,前記基材層20及び粘着剤層30,30’を構成する樹脂と前記繊維片32との間に生じた隙間又は前記繊維片32が有する孔による通気性を有した両面粘着テープ10’としてもよい(請求項2,図2参照)。 Further, in the adhesive tape 10 of the present invention, the pressure-sensitive adhesive layers 30 and 30'are formed on both surfaces of the base material layer 20, and the fiber pieces 32 are dispersed in the base material layer 20 and the pressure-sensitive adhesive layers 30 and 30'. The double-sided adhesive tape 10'has breathability due to the gap formed between the resin constituting the base material layer 20 and the pressure-sensitive adhesive layers 30 and 30'and the fiber piece 32 or the holes of the fiber piece 32 . (See claim 2 and FIG. 2).

さらに,前記両面粘着テープ10’は,前記基材層20が,両面に前記凹凸面22,22’を有するものとしても良い。(請求項3,図3参照)。 Further, in the double-sided adhesive tape 10', the base material layer 20 may have the uneven surfaces 22 and 22'on both sides. (See claims 3 and 3).

なお,本発明において『繊維片』には,短繊維の単体又は,短繊維又は長繊維の断片等から成るモノフィラメントの他,モノフィラメントを撚り合わせて得たマルチフィラメント(糸)の断片を含む。 In the present invention, the "fiber piece" includes a single filament of a short fiber, a monofilament composed of a fragment of a short fiber or a fragment of a long fiber, and a fragment of a multifilament (thread) obtained by twisting a monofilament.

前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)が,粘着剤31の固形分100重量部に対し,前記繊維片32を0.5~10重量部,好ましくは1~5重量部含有することを特徴とする(請求項4,図1)。 The pressure-sensitive adhesive layer 30 (in the case of double-sided adhesive tape 10', the pressure-sensitive adhesive layers 30, 30') preferably contains 0.5 to 10 parts by weight of the fiber piece 32 with respect to 100 parts by weight of the solid content of the pressure-sensitive adhesive 31. Is characterized by containing 1 to 5 parts by weight (claim 4, FIG. 1).

前記繊維片32としては,繊維径が0.05~100デニール(0.01~200μm径),好ましくは1~10デニール(15~60μm)より好ましくは0.5~4デニール(3~40μm)のものを使用することができる(請求項5)。 The fiber piece 32 has a fiber diameter of 0.05 to 100 denier (0.01 to 200 μm diameter), preferably 1 to 10 denier (15 to 60 μm), and more preferably 0.5 to 4 denier (3 to 40 μm). Can be used (claim 5).

なお,「デニール」とは,9000mの糸の質量をグラム単位で表したものであり,上記「デニール」の1/9の値が,JIS及びISOで使用する「テックス」(1000mの糸の質量をグラム単位で表したもの)に対応する。 The "denier" is the mass of a 9000 m thread expressed in grams, and the value of 1/9 of the above "denier" is the "tex" (mass of a 1000 m thread) used in JIS and ISO. Is expressed in grams).

また,前記繊維片32の長さは,1~10mm,好ましくは1~7mm,より好ましくは2~5mmのものが使用可能である(請求項6)。 Further, a fiber piece 32 having a length of 1 to 10 mm, preferably 1 to 7 mm, and more preferably 2 to 5 mm can be used (claim 6).

なお,前記繊維径及び繊維長は,各種のものを混合して用いることができる。 It should be noted that various fiber diameters and fiber lengths can be mixed and used.

更に,前記基材層が,前記基材層固形分100重量部に対し,前記繊維片を0.2~10重量部,好ましくは0.5~3重量部含有することを特徴とする(請求項7,図1)。 Further, the base material layer is characterized by containing 0.2 to 10 parts by weight, preferably 0.5 to 3 parts by weight, of the fiber pieces with respect to 100 parts by weight of the solid content of the base material layer (claimed). Item 7, Fig. 1).

上記本発明の粘着テープ10及び両面粘着テープ10’は,粘着テープの長手方向の伸びを30%以下,好ましくは20%以下,より好ましくは16%以下とする(請求項8)。 In the adhesive tape 10 and the double-sided adhesive tape 10'of the present invention, the elongation of the adhesive tape in the longitudinal direction is 30% or less, preferably 20% or less, and more preferably 16% or less (claim 8).

また,粘着テープの長手方向の引張強さが100(N/50mm幅)以上であることが好ましい(請求項9)。 Further, it is preferable that the tensile strength of the adhesive tape in the longitudinal direction is 100 (N / 50 mm width) or more (claim 9).

本発明の粘着テープ10の前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)は,厚み方向の全体に亘り繊維片32が均一に分散されたものとしても良いが(図1参照),好ましくは,被着物に対する貼着側(紙面下側)において前記繊維片32の分散量が減少する構成とすることが好ましい(請求項10,図4及び5参照,両面粘着テープ10’については図示せず。)。 The pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10', the pressure-sensitive adhesive layers 30, 30') of the pressure-sensitive adhesive tape 10 of the present invention may have fiber pieces 32 uniformly dispersed over the entire thickness direction. (See FIG. 1), preferably, the dispersion amount of the fiber pieces 32 is reduced on the side to be adhered to the adherend (lower side of the paper surface) (see claims 10, FIGS. 4 and 5, both sides). The adhesive tape 10'is not shown).

更に,前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)は,基材層20との貼着側(図面上側)において前記繊維片32の分散量が減少する構成とすることが好ましい(請求項11,図5参照,両面粘着テープ10’については図示せず。)。 Further, in the pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10', the pressure-sensitive adhesive layers 30 and 30'), the amount of the fiber pieces 32 dispersed on the side to be attached to the base material layer 20 (upper side of the drawing) is reduced. It is preferable to have a configuration (see claim 11, FIG. 5, the double-sided adhesive tape 10'is not shown).

なお,基材層20及び粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)に分散させる前記繊維片32としては,アクリル系,PET,オレフィン系樹脂,レーヨン,ビニロン,ナイロンの群から選択されたいずれかの材質から成るものを使用でき,該繊維片32の一種を,又は二種以上を混合したものを,前記粘着剤層30に分散させるものとしても良い(請求項12)。 The fiber pieces 32 to be dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10', the pressure-sensitive adhesive layers 30 and 30') include acrylic, PET, olefin-based resin, rayon, and vinylon. , A material made of any material selected from the group of nylon can be used, and one of the fiber pieces 32 or a mixture of two or more of the fiber pieces 32 may be dispersed in the pressure-sensitive adhesive layer 30 (. Claim 12).

前記繊維片32が,中空繊維片であることが好ましい(請求項13)。 It is preferable that the fiber piece 32 is a hollow fiber piece (claim 13).

前記繊維片32が,粘着テープの長手方向に沿って層状に分散されたものとしても良い(請求項14,図6参照)。 The fiber pieces 32 may be dispersed in layers along the longitudinal direction of the adhesive tape (see claim 14 and FIG. 6).

また,本発明の粘着テープ10の製造方法は,
片面に粘着テープの長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層20の前記凹凸面22に,粘着剤を積層して粘着剤層30を形成すると共に,前記基材層20及び前記粘着剤層30に,繊維片32を分散させて,前記基材層20及び粘着剤層30を構成する樹脂と前記繊維片32との間に生じた隙間又は前記繊維片32が有する孔により通気性を持たせたことを特徴とする(請求項15)。
Further, the method for manufacturing the adhesive tape 10 of the present invention is as follows.
On the uneven surface 22 of the base material layer 20 made of an unstretched polyolefin resin film having an uneven surface 22 in which a plurality of concave grooves 23 are formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on one side. A resin constituting the base material layer 20 and the pressure-sensitive adhesive layer 30 by laminating the pressure-sensitive adhesive to form the pressure-sensitive adhesive layer 30 and dispersing the fiber pieces 32 in the base material layer 20 and the pressure-sensitive adhesive layer 30. It is characterized in that the air permeability is provided by the gap formed between the fiber piece 32 and the fiber piece 32 or the hole provided in the fiber piece 32 (claim 15).

また,前記基材層20の両面に,粘着剤を積層して粘着剤層30,30’を形成すると共に,前記基材層20及び前記粘着剤層30,30’に,繊維片32を分散させて,前記基材層20及び粘着剤層30,30’を構成する樹脂と前記繊維片32との間に生じた隙間又は前記繊維片32が有する孔により通気性を持たせても良い(請求項16)。 Further, an adhesive is laminated on both surfaces of the base material layer 20 to form the pressure-sensitive adhesive layers 30 and 30', and the fiber pieces 32 are dispersed in the base material layer 20 and the pressure-sensitive adhesive layers 30 and 30'. It may be allowed to have air permeability by a gap formed between the resin constituting the base material layer 20 and the pressure-sensitive adhesive layers 30 and 30'and the fiber piece 32 or a hole provided in the fiber piece 32 (. 16).

さらに,前記基材層20が両面に粘着テープの長手方向と直交する方向に複数本の凹溝23が所定間隔で形成された凹凸面22を有する未延伸のポリオレフィン樹脂製フィルムから成るものでも良い(請求項17)。 Further, the base material layer 20 may be made of an unstretched polyolefin resin film having uneven surfaces 22 having a plurality of concave grooves 23 formed at predetermined intervals on both sides in a direction orthogonal to the longitudinal direction of the adhesive tape. (Claim 17).

前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)の形成は,前記繊維片32の分散量を変化させた複数種類の粘着剤を多層に積層することにより,被着物との接着面側で前記繊維片32の分散量が減少する前記粘着剤層30を形成するものとしても良い(請求項18,図4及び図5参照,両面粘着テープ10’については図示せず。)。 The pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10', the pressure-sensitive adhesive layers 30, 30') is formed by laminating a plurality of types of pressure-sensitive adhesives having different dispersion amounts of the fiber pieces 32 in multiple layers. The pressure-sensitive adhesive layer 30 in which the dispersion amount of the fiber pieces 32 is reduced may be formed on the adhesive surface side with the adherend (see claim 18, FIGS. 4 and 5, and the double-sided adhesive tape 10'is shown in FIG. I can't show it.)

また,同様に繊維片32の分散量を変化させた複数種類の粘着剤を多層に積層して,前記基材層20の前記凹凸面22との接着面側で前記繊維片32の分散量が減少する前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)を形成するものとしても良い(請求項19,図5参照,両面粘着テープ10’については図示せず。)。 Similarly, a plurality of types of adhesives having different dispersion amounts of the fiber pieces 32 are laminated in multiple layers, and the dispersion amount of the fiber pieces 32 is increased on the adhesive surface side of the base material layer 20 with the uneven surface 22. The adhesive layer 30 (in the case of the double-sided adhesive tape 10', the adhesive layers 30, 30') may be formed to be reduced (see claim 19, FIG. 5, the double-sided adhesive tape 10'is not shown. .).

以上で説明した本発明の構成により,本発明の粘着テープ10(両面粘着テープ10’を含む)では,以下の顕著な効果を得ることかできた。 With the configuration of the present invention described above, the adhesive tape 10 (including the double-sided adhesive tape 10') of the present invention could obtain the following remarkable effects.

上述の構成を有する本発明の粘着テープ10(及び両面粘着テープ10’)は,幅方向の手切れ性を維持しつつ,長手方向の伸びを小さくし,さらに,通気性を有することができた。 The adhesive tape 10 (and double-sided adhesive tape 10') of the present invention having the above-mentioned configuration was able to reduce the elongation in the longitudinal direction while maintaining the hand-cutting property in the width direction, and further to have breathability. ..

このような繊維片の分散による伸びの抑制は,繊維の分散によって前記基材層及び前記粘着剤層が高架橋となったかのような挙動を示す(本明細書においてこのような挙動を示す状態を「疑似架橋状態」という)ことで,物理的に伸びが抑制されるものであり,化学的な架橋と比べて,粘着力に寄与する官能基等を塞ぐことがなく,粘着力の発現を低下させることがない点で有利である。 The suppression of elongation due to the dispersion of the fiber pieces behaves as if the base material layer and the pressure-sensitive adhesive layer were hypercrosslinked due to the dispersion of the fibers. By "pseudo-crosslinking state"), the elongation is physically suppressed, and compared to chemical cross-linking, the functional groups that contribute to the adhesive force are not blocked, and the development of the adhesive force is reduced. It is advantageous in that it never happens.

このように,本発明の粘着テープ10(及び両面粘着テープ10’)は,長手方向の伸びを小さくできたことで,ロール状に巻かれた状態から引き出す際に伸び難く,伸びた状態で貼着された粘着テープが縮むことで生じる貼着位置のずれ,端部の浮き上がりによる剥離の発生を防止でき,また,巻き巣の発生を防止するためにテンションを掛けて巻き取った場合であっても伸びが生じ難いことから,ロール状に巻き取られた後に粘着テープ10(及び,両面粘着テープ10’)が縮むことで生じるテレスコープ状(竹の子状)の変形についても好適に防止することができ,これにより不良品の発生を抑制して歩留りを向上させることができた。 As described above, the adhesive tape 10 (and the double-sided adhesive tape 10') of the present invention can be stretched in a stretched state because it is difficult to stretch when pulled out from the rolled state because the adhesive tape 10 (and the double-sided adhesive tape 10') can be stretched in the longitudinal direction. It is possible to prevent the sticking position from shifting due to the shrinkage of the adhered adhesive tape and the peeling due to the floating of the end, and when the adhesive tape is wound with tension to prevent the formation of winding cavities. Since it is difficult for the adhesive tape to stretch, it is possible to suitably prevent the telescope-like (bamboo child-like) deformation caused by the shrinkage of the adhesive tape 10 (and the double-sided adhesive tape 10') after being wound into a roll shape. As a result, it was possible to suppress the occurrence of defective products and improve the yield.

また,粘着テープ10(及び,両面粘着テープ10’)の長手方向における引張り強度を向上させることができたことから,例えば塗装等の作業が終了した後,マスキングテープとして使用していた粘着テープ10(及び,両面粘着テープ10’)を被着物から剥離・除去する際に,粘着テープを破断等させることなく容易に剥離・除去することが可能である。 Further, since the tensile strength of the adhesive tape 10 (and the double-sided adhesive tape 10') in the longitudinal direction could be improved, the adhesive tape 10 used as a masking tape after the work such as painting was completed, for example. (And, when the double-sided adhesive tape 10') is peeled off / removed from the adherend, the adhesive tape can be easily peeled off / removed without breaking.

また,本発明の粘着テープ10(及び両面粘着テープ10’)は,通気性を有することから,貼着時に発生するエアーの抱き込みを防止することができ,貼着後の見た目が綺麗であるだけでなく被着物のアウトガスや抱き込んだエアーの膨張等による剥離の問題も生じない粘着テープ10(及び両面粘着テープ10’)を提供することができた。 Further, since the adhesive tape 10 (and the double-sided adhesive tape 10') of the present invention has breathability, it is possible to prevent the air generated at the time of sticking from being embraced, and the appearance after sticking is beautiful. Not only that, it was possible to provide the adhesive tape 10 (and the double-sided adhesive tape 10') that does not cause the problem of peeling due to the outgas of the adherend or the expansion of the embraced air.

本発明の粘着テープ10(及び両面粘着テープ10’)の通気性については,例えば,基材層及び粘着剤層を構成する樹脂と分散された繊維片32との間に生じた僅かな隙間又は,繊維片が有する孔等に沿って空気が抜けていくことが推察される。 Regarding the breathability of the adhesive tape 10 (and the double-sided adhesive tape 10') of the present invention, for example, a slight gap formed between the resin constituting the base material layer and the adhesive layer and the dispersed fiber piece 32 or , It is inferred that air escapes along the holes of the fiber pieces.

また,特に,繊維片32の添加量を粘着剤31の固形分100重量部に対し,0.5~10重量部,好ましくは1~5重量部又は,前記基材層固形分100重量部に対し,前記繊維片を0.2~10重量部含有するのみでよいという,比較的少量であり,また,分散させる繊維片32として0.05~100デニールという比較的細径のものを使用することで,粘着テープ10(及び両面粘着テープ10’)の手切れ性を殆ど犠牲にすることなく,粘着テープ10(及び両面粘着テープ10’)の伸びの抑制と引張り強度の向上を得ることができた。 Further, in particular, the amount of the fiber piece 32 added is 0.5 to 10 parts by weight, preferably 1 to 5 parts by weight, or 100 parts by weight of the base material layer solid content with respect to 100 parts by weight of the solid content of the pressure-sensitive adhesive 31. On the other hand, the amount of the fiber piece is relatively small, that is, only 0.2 to 10 parts by weight of the fiber piece is contained, and the fiber piece 32 to be dispersed has a relatively small diameter of 0.05 to 100 denier. This makes it possible to suppress the elongation of the adhesive tape 10 (and the double-sided adhesive tape 10') and improve the tensile strength without sacrificing the hand-cutting property of the adhesive tape 10 (and the double-sided adhesive tape 10'). did it.

粘着剤31に添加する繊維片32を,1~10mm,好ましくは1~7mm,より好ましくは2~5mmという比較的短いものを使用したことで,粘着剤に対する繊維片32の分散が容易である一方,この長さの繊維片の分散でも必要な伸び率の抑制と引張強さの向上を得ることができた。 By using a relatively short fiber piece 32 to be added to the pressure-sensitive adhesive 31, which is 1 to 10 mm, preferably 1 to 7 mm, and more preferably 2 to 5 mm, the fiber piece 32 can be easily dispersed in the pressure-sensitive adhesive. On the other hand, even with the dispersion of fiber pieces of this length, it was possible to obtain the necessary suppression of elongation and improvement of tensile strength.

前記基材層20の凹凸面22に,前記粘着テープ10の長手方向と平行な方向に複数本の凹溝(図示せず)を所定間隔で形成した構成では,粘着テープ10の幅方向の手切れ性のみならず,長手方向の手切れ性についても付与することができた。 In the configuration in which a plurality of concave grooves (not shown) are formed on the uneven surface 22 of the base material layer 20 in a direction parallel to the longitudinal direction of the adhesive tape 10 at predetermined intervals, the hands in the width direction of the adhesive tape 10 are formed. Not only the cutting property but also the hand cutting property in the longitudinal direction could be imparted.

前記粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)中の前記繊維片32の分散量を,被着物との接着面側で減少させた構成とした例では,繊維片32の分散によっても被着物に対する良好な接着性を維持することができた。 In the example in which the dispersion amount of the fiber pieces 32 in the adhesive layer 30 (in the case of the double-sided adhesive tape 10', the adhesive layers 30, 30') is reduced on the adhesive surface side with the adherend, the configuration is such that the dispersion amount is reduced. Good adhesion to the adherend could be maintained even by the dispersion of the fiber pieces 32.

また,粘着剤層30(両面粘着テープ10’の場合,粘着剤層30,30’)中の前記繊維片32の分散量を,基材層20の凹凸面22との接着面側でも減少させた構成とした例では,基材層20の凹凸面22と粘着剤層30間の強固な接着を得ることができ,被着物より粘着テープ10を剥がす際に,層間剥離が生じて粘着剤層30の一部が被着物の表面に付着したまま残る,所謂「糊残り」の発生についても好適に防止することができた。 Further, the amount of the fiber pieces 32 dispersed in the pressure-sensitive adhesive layer 30 (in the case of the double-sided pressure-sensitive adhesive tape 10', the pressure-sensitive adhesive layers 30 and 30') is also reduced on the adhesive surface side of the base material layer 20 with the uneven surface 22. In the example of the above configuration, strong adhesion can be obtained between the uneven surface 22 of the base material layer 20 and the pressure-sensitive adhesive layer 30, and when the pressure-sensitive adhesive tape 10 is peeled off from the adherend, delamination occurs and the pressure-sensitive adhesive layer is formed. It was also possible to suitably prevent the generation of so-called "glue residue" in which a part of 30 remains attached to the surface of the adherend.

さらに,従来の基材層としての工程が多く,コストの高い繊維を縦横(経緯)に織る事なく,既存の織物型テープの代替ともなる粘着テープが得られ,高い経済効果をもたらす。 Furthermore, since there are many processes as a conventional base material layer, an adhesive tape that can replace the existing woven fabric type tape can be obtained without weaving expensive fibers vertically and horizontally (warp and weft), which brings about a high economic effect.

なお,上記課題を解決するため基材層として過去に試みられたポリプロピレンとポリエチレンの混合樹脂においては,融点の違いから,押し出しフィルムに発生するたわみ,巻取りのしわ,ラインでのしわ(アバラ,フレアとも呼ばれる)が多発していたが,ポリプロピレンに代替する本願の繊維片により,上記効果を達成すると共に,このようなしわの発生をきわめて少ないものとすることができた。 In the polypropylene and polyethylene mixed resin, which has been tried in the past as a base material layer to solve the above problems, the deflection generated in the extruded film, the wrinkles in the winding, and the wrinkles in the line (Abara,) due to the difference in melting point. Although flare) occurred frequently, the fiber pieces of the present application, which replace polypropylene, were able to achieve the above effects and minimize the occurrence of such wrinkles.

本発明の第1実施形態の粘着テープ10の断面模式図。FIG. 6 is a schematic cross-sectional view of the adhesive tape 10 according to the first embodiment of the present invention. 本発明の第2実施形態の両面粘着テープ10’の断面模式図。FIG. 6 is a schematic cross-sectional view of the double-sided adhesive tape 10'of the second embodiment of the present invention. 本発明の第3実施形態の両面粘着テープ10’の断面模式図。FIG. 6 is a schematic cross-sectional view of the double-sided adhesive tape 10'of the third embodiment of the present invention. 本発明のさらに別の実施形態の粘着テープ10の断面模式図。FIG. 6 is a schematic cross-sectional view of the adhesive tape 10 according to still another embodiment of the present invention. 本発明のさらに別の実施形態の粘着テープ10の断面模式図。FIG. 6 is a schematic cross-sectional view of the adhesive tape 10 according to still another embodiment of the present invention. 本発明のさらに別の実施形態の粘着テープ10の断面模式図。FIG. 6 is a schematic cross-sectional view of the adhesive tape 10 according to still another embodiment of the present invention. 基材層となるポリオレフィン樹脂フィルムの製造方法の説明図。The explanatory view of the manufacturing method of the polyolefin resin film which becomes a base material layer. ロール状に巻き取った状態の粘着テープの斜視図。A perspective view of the adhesive tape wound into a roll. 従来の粘着テープの説明図(特許文献1に対応)。Explanatory drawing of conventional adhesive tape (corresponding to patent document 1). 従来の粘着テープの説明図(特許文献2に対応)。Explanatory drawing of conventional adhesive tape (corresponding to patent document 2). 従来の粘着テープの説明図(特許文献3に対応)。Explanatory drawing of conventional adhesive tape (corresponding to patent document 3). テレスコープ状(竹の子状)に変形した粘着テープの説明図。Explanatory drawing of the adhesive tape deformed into a telescope shape (bamboo shoot shape). 従来の粘着テープの製造方法の説明図(特許文献2の図3に対応)。Explanatory drawing of the conventional method of manufacturing an adhesive tape (corresponding to FIG. 3 of Patent Document 2).

次に,本発明の実施形態につき添付図面を参照しながら説明する。 Next, an embodiment of the present invention will be described with reference to the accompanying drawings.

〔全体構造〕
本発明の第1実施形態としては,例えば,図1に示すように一方の面を平滑面21とし,他方の面に粘着テープの長手方向と直交する方向の多数の凹溝23が形成された凹凸面22としたポリオレフィン樹脂フィルムを基材層20とし,この基材層20の凹凸面22に,粘着剤層30を設けた,手切れ性を有する粘着テープ10とすることができる。
[Overall structure]
In the first embodiment of the present invention, for example, as shown in FIG. 1, one surface is a smooth surface 21, and a large number of concave grooves 23 in a direction orthogonal to the longitudinal direction of the adhesive tape are formed on the other surface. The polyolefin resin film having the uneven surface 22 can be used as the base material layer 20, and the adhesive tape 10 having the adhesive layer 30 provided on the uneven surface 22 of the base material layer 20 can be used.

そして,本発明の粘着テープ10は,前述の基材層20及び粘着剤層30に繊維片32を分散させることにより,手切れ性を維持しつつ粘着テープ10の長手方向の伸びの抑制と,引張強さを向上させ,さらに,通気性を持たせた,一例として総厚み120~600μmの粘着テープである。なお,総厚みはこれに限定されず,用途等に応じて適宜の厚さに設定し得る。 The adhesive tape 10 of the present invention is formed by dispersing the fiber pieces 32 in the above-mentioned base material layer 20 and the adhesive layer 30 to suppress the elongation of the adhesive tape 10 in the longitudinal direction while maintaining the hand-cutting property. As an example, it is an adhesive tape having a total thickness of 120 to 600 μm, which has improved tensile strength and further has breathability. The total thickness is not limited to this, and can be set to an appropriate thickness depending on the application and the like.

また,本発明の第2実施形態として,例えば,図2に示すように,一方の面を平滑面21とし,他方の面に粘着テープの長手方向と直交する方向の多数の凹溝23が形成された凹凸面22としたポリオレフィン樹脂フィルムを基材層20とし,この基材層20の両面に,粘着剤層30,30’を設け,前記基材層20及び前記粘着剤層30,30’の粘着剤中に繊維片32が分散された,通気性及び手切れ性を有する両面粘着テープ10’とすることができる。 Further, as a second embodiment of the present invention, for example, as shown in FIG. 2, one surface is a smooth surface 21, and a large number of concave grooves 23 in a direction orthogonal to the longitudinal direction of the adhesive tape are formed on the other surface. The polyolefin resin film having the uneven surface 22 as the surface is used as the base material layer 20, and the pressure-sensitive adhesive layers 30 and 30'are provided on both surfaces of the base material layer 20, and the base material layer 20 and the pressure-sensitive adhesive layers 30 and 30' are provided. The double-sided adhesive tape 10'with breathability and hand-cutting property, in which the fiber pieces 32 are dispersed in the adhesive of the above, can be obtained.

さらに,本発明の第3実施形態として,図3に示すように,両面を粘着テープの長手方向と直交する方向の多数の凹溝23,23’が形成された凹凸面22,22’としたポリオレフィン樹脂フィルムを基材層20とし,この基材層20の両面に,粘着剤層30,30’を設け,前記基材層20及び前記粘着剤層30,30’の粘着剤中に繊維片32が分散された,通気性及び手切れ性を有する両面粘着テープ10’とすることもできる。 Further, as a third embodiment of the present invention, as shown in FIG. 3, both sides are concave-convex surfaces 22, 22'in which a large number of concave grooves 23, 23'in the direction orthogonal to the longitudinal direction of the adhesive tape are formed. A polyolefin resin film is used as a base material layer 20, and pressure-sensitive adhesive layers 30 and 30'are provided on both sides of the base material layer 20. Fiber pieces are contained in the pressure-sensitive adhesive of the base material layer 20 and the pressure-sensitive adhesive layer 30 and 30'. It can also be a double-sided adhesive tape 10'with 32 dispersed, breathable and hand-cutting property.

〔基材層〕
本発明の粘着テープ10及び両面粘着テープ10’で基材層20として使用するフィルムは,未延伸のポリオレフィン樹脂のフィルムであり,これは公知のポリオレフィン樹脂を使用して製造することかできる。
[Base layer]
The film used as the base material layer 20 in the adhesive tape 10 and the double-sided adhesive tape 10'of the present invention is an unstretched polyolefin resin film, which can be produced by using a known polyolefin resin.

このようなポリオレフィン樹脂としては,例えばポリエチレン樹脂,ポリプロピレン樹脂,エチレンとプロピレンとの共重合体樹脂,エチレン及び/又はプロピレンと他の一種または二種以上のα-オレフィンとの共重合体樹脂などを例示することができる。 Examples of such polyolefin resins include polyethylene resins, polypropylene resins, copolymer resins of ethylene and propylene, and copolymer resins of ethylene and / or propylene with one or more other α-olefins. It can be exemplified.

このうちのα-オレフィンとしては,例えばブテン-1,ペンテン-1,ヘキセン-1,ヘプテン-1,オクテン-1,ノネン-1,4-メチルペンテン-1,デセン-1等を挙げることができる。 Examples of the α-olefin include butene-1, pentene-1, hexene-1, heptene-1, octene-1, nonene-1, 4-methylpentene-1, and decene-1. ..

好ましいポリオレフィン樹脂の例としては,ポリエチレン樹脂を挙げることができる。 A polyethylene resin can be mentioned as an example of a preferable polyolefin resin.

ポリオレフィン樹脂の分子量は,フィルムに成形し得る範囲であれば特に制限されないが,樹脂の流れ性を表す尺度であるメルトインデックスで表すと,一般に0.2~20g/10分の範囲,好ましくは1~10g/10分(いずれも荷重2.16kg,温度190℃)の範囲である。 The molecular weight of the polyolefin resin is not particularly limited as long as it can be formed into a film, but when expressed by the melt index, which is a measure of the flowability of the resin, it is generally in the range of 0.2 to 20 g / 10 minutes, preferably 1. It is in the range of ~ 10 g / 10 minutes (load 2.16 kg, temperature 190 ° C.).

本発明の粘着テープ10及び両面粘着テープ10’の基材層20となる前述のポリオレフィン樹脂のシートの厚さは,一例として40~400μmの範囲であるが,この厚さに限定されず,用途等に応じて適宜の厚さに設定し得る。 The thickness of the above-mentioned polyolefin resin sheet serving as the base material layer 20 of the adhesive tape 10 and the double-sided adhesive tape 10'of the present invention is, for example, in the range of 40 to 400 μm, but is not limited to this thickness and is used. It can be set to an appropriate thickness according to the above.

このポリオレフィン樹脂シートは,一方の面を平滑面21とし,他方の面を凹凸面22としており,この凹凸面22に,粘着テープ10の長手方向に対し直交方向を成す凹溝23が多数形成されている。 In this polyolefin resin sheet, one surface is a smooth surface 21 and the other surface is an uneven surface 22, and a large number of concave grooves 23 forming orthogonal directions with respect to the longitudinal direction of the adhesive tape 10 are formed on the uneven surface 22. ing.

また,両面粘着テープ10’の場合,前記ポリオレフィン樹脂シートの両面を凹凸面22,22’とし,この凹凸面22,22’に,粘着テープ10の長手方向に対し直交方向を成す凹溝23が多数形成されているものとしても良い。 Further, in the case of the double-sided adhesive tape 10', both sides of the polyolefin resin sheet are made uneven surfaces 22 and 22', and the concave and convex grooves 23 forming orthogonal directions with respect to the longitudinal direction of the adhesive tape 10 are formed on the uneven surfaces 22 and 22'. It may be formed in large numbers.

この凹溝23は,粘着テープ10を手で切断する際に基材層20に破断が生じる位置となるもので,このような手による切断を可能と成すものであれば,その断面形状は,図示したようなV字状の他,矩形状,(半)円形状等,如何なる形状であっても良く,その深さも,特に限定されるものではないが,前述したシート厚40~400μmのポリオレフィン樹脂のシートを基材層20として使用する場合,深さは,30μm未満では手切れ性が損なわれることから,30~300μm,好ましくは40~120μmの凹溝23を形成し,凹溝23の形成部分における肉厚を,10~100μmとすることが好ましい。 The concave groove 23 is a position where the base material layer 20 is broken when the adhesive tape 10 is cut by hand, and if the groove 23 can be cut by hand, the cross-sectional shape thereof is In addition to the V-shape as shown in the figure, any shape such as a rectangular shape or a (semi-) circular shape may be used, and the depth thereof is not particularly limited, but the above-mentioned polyolefin having a sheet thickness of 40 to 400 μm is not particularly limited. When the resin sheet is used as the base material layer 20, if the depth is less than 30 μm, the hand-cutting property is impaired. Therefore, a concave groove 23 of 30 to 300 μm, preferably 40 to 120 μm is formed, and the concave groove 23 is formed. The wall thickness at the formed portion is preferably 10 to 100 μm.

この凹溝23の間隔は,0.5mm未満では粘着テープ10の長手方向に強度が不足し,5mmを超えると本来の手切れ性が不十分となる可能性があることから,一例として0.5~5mm,好ましくは0.6~1.4mm間隔に設定することができる。但し,これよりも広く,又は狭く形成しても良い。 If the distance between the concave grooves 23 is less than 0.5 mm, the strength is insufficient in the longitudinal direction of the adhesive tape 10, and if it exceeds 5 mm, the original hand-cutting property may be insufficient. Therefore, as an example, 0. It can be set at intervals of 5 to 5 mm, preferably 0.6 to 1.4 mm. However, it may be formed wider or narrower than this.

前述したポリオレフィン樹脂を原料として,一方の面を平滑面21,他方の面を凹凸面22としたポリオレフィン樹脂シートを製造する方法の一例を,図7に示す。 FIG. 7 shows an example of a method for producing a polyolefin resin sheet using the above-mentioned polyolefin resin as a raw material, with one surface as a smooth surface 21 and the other surface as an uneven surface 22.

図7に示す例では,予め繊維片32と混練したポリオレフィン樹脂を溶融して押出機50の押出ダイ51よりフィルム状に押出した後,押し出されたフィルムが未だ完全に室温まで冷却されていない状態でエンボスロール61とゴムロール62間を通過させることにより,ゴムロール62との接触側に平滑面21,エンボスロール61との接触側にエンボスロール61の表面に設けた凸条61aに対応する形状の凹溝23を形成している。 In the example shown in FIG. 7, the polyolefin resin kneaded with the fiber piece 32 in advance is melted and extruded into a film from the extrusion die 51 of the extruder 50, and then the extruded film is not completely cooled to room temperature. By passing between the embossed roll 61 and the rubber roll 62, a smooth surface 21 is provided on the contact side with the rubber roll 62, and a concave portion having a shape corresponding to the ridge 61a provided on the surface of the embossed roll 61 on the contact side with the embossed roll 61. It forms a groove 23.

なお,基材層20の両面に凹凸面22,22’を形成する場合は,例えば,前記ゴムロール62の代わりにエンボスロール61’を用意し,前記エンボスロール61とエンボスロール61’間を通過させることにより,両面に凹溝23,23’を形成することができる。 When forming the uneven surfaces 22 and 22'on both sides of the base material layer 20, for example, an embossed roll 61'is prepared instead of the rubber roll 62 and passed between the embossed roll 61 and the embossed roll 61'. As a result, recessed grooves 23, 23'can be formed on both sides.

粘着剤との馴染みを良好なものとして層間剥離が生じることを防止するために,ポリオレフィン樹脂フィルムに形成した凹凸面22には,図7に示すように,放電電極64と,平滑な表面を有する処理ロール65間を通過させる際にコロナ放電処理を行うものとしても良い。 As shown in FIG. 7, the uneven surface 22 formed on the polyolefin resin film has a discharge electrode 64 and a smooth surface in order to improve the compatibility with the pressure-sensitive adhesive and prevent delamination from occurring. The corona discharge treatment may be performed when passing between the treatment rolls 65.

このようにコロナ放電処理を行うことで,凹凸面22と後述する粘着剤31との親和性(凹凸面に対する接着剤の投錨性,凹凸面のぬれ性)を向上させることができ,粘着テープ10を被着物より剥離する際に層間剥離が生じて粘着剤が被着物の表面上に残る,所謂「糊残り」の発生を防止することができる。 By performing the corona discharge treatment in this way, the affinity between the uneven surface 22 and the adhesive 31 described later (the anchoring property of the adhesive on the uneven surface and the wettability of the uneven surface) can be improved, and the adhesive tape 10 can be improved. It is possible to prevent the occurrence of so-called "glue residue", in which delamination occurs when the adhesive is peeled off from the adherend and the adhesive remains on the surface of the adherend.

なお,前述したように凹凸面22に対するコロナ放電処理は,粘着剤層30との馴染みを良好とする上で好ましいが,本発明の粘着テープ10においてこのコロナ放電処理は必須ではなく,必要に応じて処理を行うものすれば良い。 As described above, the corona discharge treatment on the uneven surface 22 is preferable in order to improve the compatibility with the pressure-sensitive adhesive layer 30, but the corona discharge treatment is not essential for the adhesive tape 10 of the present invention, and if necessary. It suffices to process it.

基材層20のダイン数(濡れ指数)は,平滑面21に対し凹凸面22の方が大きくなっていることが好ましく,好ましいダイン数(濡れ指数)は一例として平滑面21で30Dyn/cm以下,凹凸面22で35Dyn/cm以上であり,平滑面21の濡れ指数が30Dyn/cmより大きいと,粘着テープ10をロール状に巻き取った際に平滑面21と粘着剤層30が必要以上に強固に接着してしまう,所謂「ブロッキング現象」の発生によって,粘着テープ10を展開することが困難となる。 The number of dyne (wetting index) of the base material layer 20 is preferably larger on the uneven surface 22 than on the smooth surface 21, and the preferable number of dyne (wetting index) is 30 Dyn / cm or less on the smooth surface 21 as an example. If the uneven surface 22 is 35 Dyn / cm or more and the wettability index of the smooth surface 21 is larger than 30 Dyn / cm, the smooth surface 21 and the adhesive layer 30 become more than necessary when the adhesive tape 10 is wound into a roll. The occurrence of the so-called "blocking phenomenon", which causes strong adhesion, makes it difficult to deploy the adhesive tape 10.

一方,凹凸面22のぬれ指数が35Dyn/cm未満であると,凹凸面22に対する粘着剤31の接着力が不足して,前述した「糊残り」等が生じる原因となる。 On the other hand, if the wetting index of the uneven surface 22 is less than 35 Dyn / cm, the adhesive force of the adhesive 31 to the uneven surface 22 is insufficient, which causes the above-mentioned “glue residue” and the like.

なお,凹凸面22に対する粘着剤層30の親和性を高めるための方法としては,前述したコロナ放電処理の他に,プライマーを塗布する方法もある。 In addition to the above-mentioned corona discharge treatment, there is also a method of applying a primer as a method for increasing the affinity of the pressure-sensitive adhesive layer 30 with respect to the uneven surface 22.

このようなプライマーの塗布による親和性の向上も良く知られた方法であり,プライマーとしては既知の各種のもの,例えばニトリルゴム等のゴム系のプライマー,アクリル樹脂系のプライマーなどを使用することができる。 Improving the affinity by applying such a primer is also a well-known method, and various known primers such as rubber-based primers such as nitrile rubber and acrylic resin-based primers can be used. can.

なお,前述したコロナ放電処理と同様,本発明ではプライマーの塗布も必須ではなく,必要に応じて適宜行うことができ,また,前述したコロナ放電処理に代え,又はコロナ放電処理と併用してプライマー塗布を行っても良い。 As with the above-mentioned corona discharge treatment, the application of a primer is not essential in the present invention and can be appropriately performed as needed, and the primer can be used instead of the above-mentioned corona discharge treatment or in combination with the above-mentioned corona discharge treatment. You may apply it.

また,本発明の基材層20には,繊維片32が添加されるが,繊維片32の一次分散は,マスターバッチでポリオレフィン樹脂と混練を得て,押出機ホッパーへと供給される。用いられる繊維片32は,ポリオレフィン樹脂の熱溶融温度200℃域を超えていなければならず,この観点からは,ポリエステル系(Tg220℃),ナイロン(Tg220℃),アクリル系(熱硬化),で最も好ましいのは熱溶融とは無縁なレーヨンが好ましいが,防水性の観点からは,ポリプロピレン系,ポリエステル系が好ましい。 Further, the fiber piece 32 is added to the base material layer 20 of the present invention, and the primary dispersion of the fiber piece 32 is kneaded with the polyolefin resin in a masterbatch and supplied to the extruder hopper. The fiber piece 32 used must have a heat melting temperature of the polyolefin resin in the range of 200 ° C., and from this viewpoint, polyester-based (Tg220 ° C.), nylon (Tg220 ° C.), and acrylic-based (thermosetting). The most preferable is rayon, which is unrelated to heat melting, but from the viewpoint of waterproofness, polypropylene-based and polyester-based are preferable.

繊維片32の分散した基材層20は,未延伸のポリオレフィン樹脂のフィルムであり,これは公知のポリオレフィン樹脂を使用して製造することができる。 The base material layer 20 in which the fiber pieces 32 are dispersed is an unstretched polyolefin resin film, which can be produced by using a known polyolefin resin.

〔粘着剤層〕
以上のように構成されたポリオレフィン樹脂のフィルムから成る基材層20の凹凸面22に,また,両面粘着テープとする場合には基材層20の両面に,繊維片32が分散された粘着剤層30が形成される。
[Adhesive layer]
A pressure-sensitive adhesive in which fiber pieces 32 are dispersed on the uneven surface 22 of the base material layer 20 made of the polyolefin resin film configured as described above, or on both sides of the base material layer 20 in the case of double-sided adhesive tape. The layer 30 is formed.

粘着剤
粘着剤層30を構成する粘着剤としては,既知の各種の粘着剤を使用可能であり,一例としてアクリル系粘着剤,ビニルエーテル系粘着剤,シリコーン系粘着剤,ゴム系粘着剤等を挙げることができる。
Adhesives As the adhesives constituting the adhesive layer 30, various known adhesives can be used, and examples thereof include acrylic adhesives, vinyl ether adhesives, silicone adhesives, and rubber adhesives. be able to.

使用する粘着剤の形態も特に制限されず,溶液型粘着剤,エマルジョン型粘着剤,ホットメルト型粘着剤等のいずれの型のものを使用しても良い。 The form of the pressure-sensitive adhesive to be used is not particularly limited, and any type of pressure-sensitive adhesive, emulsion-type pressure-sensitive adhesive, hot-melt-type pressure-sensitive adhesive, or the like may be used.

粘着剤層の積層方法
前述した粘着剤層30の形成は,例えば,図1に示す本発明の第1実施形態のように,予め繊維を分散させておいた粘着剤を,前述した基材層20の凹凸面22に塗布することにより,あるいは工程紙上に塗布した後,前記基材層20の凹凸面22に転写することにより形成する。
Method for Laminating the Adhesive Layer In the formation of the adhesive layer 30 described above, for example, as in the first embodiment of the present invention shown in FIG. 1, a pressure-sensitive adhesive in which fibers are dispersed in advance is used as a base material layer described above. It is formed by applying it to the uneven surface 22 of 20 or by transferring it to the uneven surface 22 of the base material layer 20 after applying it on process paper.

この粘着剤層30は,図1に示すように繊維片32が分散された粘着剤を1層塗工することにより形成した単層の粘着剤層30によって形成するものとしても良いが,好ましくは,図4及び図5に示すように繊維片32の分散量が異なる複数種類の粘着剤を2層以上塗工して,粘着剤層30の厚み方向における繊維片32の分散量に勾配を持たせるものとしても良い。 As shown in FIG. 1, the pressure-sensitive adhesive layer 30 may be formed by a single-layer pressure-sensitive adhesive layer 30 formed by applying one layer of a pressure-sensitive adhesive in which fiber pieces 32 are dispersed, but is preferable. , As shown in FIGS. 4 and 5, two or more layers of a plurality of types of adhesives having different dispersion amounts of the fiber pieces 32 are applied, and the dispersion amount of the fiber pieces 32 in the thickness direction of the pressure-sensitive adhesive layer 30 has a gradient. It may be used as a material.

前述した繊維片32は,これを基材層20及び粘着剤層30中に分散させることにより,通気性を有し,さらに,基材層20及び粘着剤層30が補強されて伸びが低減すると共に引張強さの向上を得ることができる一方で,粘着剤層30に前述した疑似架橋を生じさせ,被着物の表面に対する追従性及び接着力を低下させる原因となり得る。 The fiber piece 32 described above has air permeability by dispersing it in the base material layer 20 and the pressure-sensitive adhesive layer 30, and further, the base material layer 20 and the pressure-sensitive adhesive layer 30 are reinforced to reduce the elongation. At the same time, it is possible to obtain an improvement in tensile strength, which may cause the above-mentioned pseudo-crosslinking in the pressure-sensitive adhesive layer 30 and cause a decrease in followability and adhesive force to the surface of the adherend.

そこで,図4に示すように粘着剤層30のうち,基材層20側(紙面上側)を相対的に繊維片32の含有量が多い粘着剤を積層して形成した粘着剤層(図示の例では繊維片含有粘着剤層301)とする一方,被着物と接着する側(紙面下側)を繊維片32の添加量が少ない粘着剤を積層して形成した粘着剤層(図示の例では繊維片少量含有粘着剤層302)とした,複層構造の粘着剤層を形成するものとしても良い。 Therefore, as shown in FIG. 4, of the pressure-sensitive adhesive layer 30, the pressure-sensitive adhesive layer formed by laminating a pressure-sensitive adhesive having a relatively high content of fiber pieces 32 on the base material layer 20 side (upper side of the paper surface) (not shown). In the example, the pressure-sensitive adhesive layer 301) is used, while the side to be adhered to the adherend (lower side of the paper surface) is a pressure-sensitive adhesive layer formed by laminating a pressure-sensitive adhesive having a small amount of the fiber pieces 32 added (in the example shown in the figure). The pressure-sensitive adhesive layer containing a small amount of fiber pieces 302) may be used to form a pressure-sensitive adhesive layer having a multi-layer structure.

また,図5に示すように,基材層と粘着剤層間の層間剥離を防止するために,粘着剤層30の厚み方向中央部に繊維片32の分散量が相対的に多い粘着剤を積層して形成した粘着剤層(図示の例では繊維片含有粘着剤層301)を設ける一方,これを中心としてその外側に繊維片の分散量が少ない粘着剤を塗布,積層して形成した粘着剤層(図示の例では第1の繊維片少量含有粘着剤層302a,第2の繊維片少量含有粘着剤層302b)を形成した三層構造の粘着剤層30を形成し,被着物との接着性を向上させるのみならず,基材層20との接着性を向上させるものとしても良い。 Further, as shown in FIG. 5, in order to prevent delamination between the base material layer and the pressure-sensitive adhesive layer, a pressure-sensitive adhesive having a relatively large dispersion amount of the fiber pieces 32 is laminated on the central portion of the pressure-sensitive adhesive layer 30 in the thickness direction. While the pressure-sensitive adhesive layer (fiber piece-containing pressure-sensitive adhesive layer 301 in the illustrated example) is provided, a pressure-sensitive adhesive formed by applying and laminating a pressure-sensitive adhesive having a small dispersion amount of fiber pieces on the outside of the pressure-sensitive adhesive layer is provided. A three-layered pressure-sensitive adhesive layer 30 is formed by forming a layer (in the illustrated example, the first fiber piece small amount-containing adhesive layer 302a and the second fiber piece small amount-containing pressure-sensitive adhesive layer 302b), and the adhesive layer 30 is adhered to the adherend. Not only the property may be improved, but also the adhesiveness with the base material layer 20 may be improved.

なお,上述した複層構造の粘着剤層は,本発明の両面粘着テープ10’にも適用できる。なお,基材層20の両面に積層された粘着剤層30,30’のうち一方のみを上述の複層構造としても良く,双方を上述の複層構造としても良い(図示せず)。 The above-mentioned multi-layered pressure-sensitive adhesive layer can also be applied to the double-sided pressure-sensitive adhesive tape 10'of the present invention. Only one of the pressure-sensitive adhesive layers 30 and 30'laminated on both sides of the base material layer 20 may have the above-mentioned multi-layer structure, and both may have the above-mentioned multi-layer structure (not shown).

このようにして得られた粘着テープ10は,既知の粘着テープと同様,図8に示すように例えば25m,50mといった所定の長さを巻き取って形成したロールの状態で提供される。 The adhesive tape 10 thus obtained is provided in the form of a roll formed by winding a predetermined length such as 25 m or 50 m as shown in FIG. 8, similarly to the known adhesive tape.

ロール状に巻き取った状態で粘着テープを提供する場合,粘着剤としてゴム系粘着剤を使用する場合又は,粘着剤の塗布量が多い場合等には,粘着テープ10の展開性を向上させるために,基材層20の平滑面21に既知の剥離剤を塗布する等しても良い。 To improve the expandability of the adhesive tape 10 when the adhesive tape is provided in a rolled state, when a rubber-based adhesive is used as the adhesive, or when the amount of the adhesive applied is large. A known release agent may be applied to the smooth surface 21 of the base material layer 20.

また,本発明は,図2又は図3に示すように,基材層20の両面に粘着剤層30を積層することで両面粘着テープ10’とすることができる。 Further, as shown in FIG. 2 or 3, the present invention can form a double-sided adhesive tape 10'by laminating the pressure-sensitive adhesive layer 30 on both sides of the base material layer 20.

例えば,図2に示す,基材層20の平滑面21及び凹凸面22の両面に粘着剤層30を積層した第2実施形態の両面粘着テープ10’については,例として,以下の方法により製造することができる。 For example, the double-sided adhesive tape 10'of the second embodiment in which the pressure-sensitive adhesive layer 30 is laminated on both sides of the smooth surface 21 and the uneven surface 22 of the base material layer 20 shown in FIG. 2 is manufactured by the following method as an example. can do.

剥離シートに,予め繊維片32を分散させておいた粘着剤を,キスロールコーター,グラビアコーター,ナイフコーター,リバースロールコーター等により,塗布し,乾燥する。 The adhesive on which the fiber pieces 32 are dispersed in advance is applied to the release sheet with a kiss roll coater, a gravure coater, a knife coater, a reverse roll coater, or the like, and dried.

これに,前述の図7を参照して説明した方法で製造した,繊維片32が分散された基材層20を積層し,巻き込んでいく。 The base material layer 20 in which the fiber pieces 32 are dispersed, which is manufactured by the method described with reference to FIG. 7 described above, is laminated and entangled therein.

さらに,これを巻き戻しながら,前記基材層20上に,前記予め繊維片32を分散させておいた粘着剤をキスロールコーター,グラビアコーター,ナイフコーター,リバースロールコーター等により塗布し,乾燥後に巻き上げる。 Further, while rewinding this, the adhesive having the fiber pieces 32 dispersed in advance is applied onto the base material layer 20 with a kiss roll coater, a gravure coater, a knife coater, a reverse roll coater, or the like, and after drying. Wind up.

本発明の両面粘着テープ10’は,片面または両面が前記剥離シートで覆われ,巻き上げられたテープもしくはシート形状で提供される。 The double-sided adhesive tape 10'of the present invention is provided in the form of a rolled-up tape or sheet in which one or both sides are covered with the release sheet.

前記剥離シートとしては,紙に樹脂をアンカーコートしたもの,ポリエチレン,ポリプロピレン等よりなる剥離性の高い樹脂シート等よりなり,所望により表面にシリコーン系材料等の剥離剤を塗布したものが使用される。 As the release sheet, a sheet in which a resin is anchor-coated on paper, a resin sheet having high peelability made of polyethylene, polypropylene, or the like is used, and a sheet in which a release agent such as a silicone-based material is coated on the surface is used if desired. ..

〔繊維片〕
基材層20及び粘着剤層30中に分散される前述の繊維片32としては,例えば,アクリル,ポリエチレン,ポリプロピレン,ポリエチレンテレフタレート,6-ナイロン,6,6-ナイロン,ポリパラフェニレンテレフタルアミド,ポリアクリルニトリル,PMMA(ポリメタクリル酸メチル),ビニロン,レーヨン,麻,絹,毛等の繊維を挙げることができる。
[Fiber pieces]
Examples of the fiber pieces 32 dispersed in the base material layer 20 and the pressure-sensitive adhesive layer 30 include acrylic, polyethylene, polypropylene, polyethylene terephthalate, 6-nylon, 6,6-nylon, polyparaphenylene terephthalamide, and poly. Examples include fibers such as acrylic nitrile, PMMA (polymethyl methacrylate), vinylon, rayon, hemp, silk, and hair.

この繊維片32は,綿又は麻,羊毛等の短繊維の単体又は,これら短繊維又は絹又は化学繊維等の長繊維の断片等から成るモノフィラメントであっても良く,又は,モノフィラメントを撚り合わせて得たマルチフィラメント(糸)の断片であっても良い。 The fiber piece 32 may be a single piece of short fibers such as cotton or linen or wool, or a monofilament composed of these short fibers or fragments of long fibers such as silk or chemical fibers, or the monofilaments may be twisted together. It may be a fragment of the obtained multifilament (thread).

これらのうち特にレーヨン,ナイロン,ポリエチレン,ポリプロピレン,ポリエチレンテレフタレートに代表されるポリエステル系や,アクリル系の繊維片の使用は,基材層20とするポリオレフィン樹脂フィルムとの接着性,耐熱性,耐溶剤性等の観点から好ましい。 Of these, the use of polyester-based or acrylic-based fiber pieces typified by rayon, nylon, polyethylene, polypropylene, and polyethylene terephthalate is particularly effective in adhering to the polyolefin resin film used as the base material layer 20, heat resistance, and solvent resistance. It is preferable from the viewpoint of sex and the like.

これらの原料から成る繊維片32は,単一の原料から成る繊維片32のみを単独で使用してもよいが,異なる原料で製造された複数種類の繊維片32を2種類以上混ぜて使用するものとしても良い。 As the fiber piece 32 made of these raw materials, only the fiber piece 32 made of a single raw material may be used alone, but a plurality of types of fiber pieces 32 manufactured from different raw materials may be mixed and used. It may be a thing.

また,繊維片32は,着色したものを使用することもでき,あるいは予め着色しておいた原料を使用して製造した繊維片32を使用することもできる。 Further, as the fiber piece 32, a colored fiber piece 32 can be used, or a fiber piece 32 manufactured by using a pre-colored raw material can be used.

粘着剤層30への繊維片32の添加量は,得られる粘着テープ10の,粘着力,靱性,手切れ性・手触り(柔らかさ)等の観点から,粘着テープの粘着剤固形分100重量部に対し,0.5~10重量部とすることが好ましく,より好ましくは1~5重量部である。 The amount of the fiber piece 32 added to the pressure-sensitive adhesive layer 30 is 100 parts by weight of the pressure-sensitive adhesive solid content of the pressure-sensitive adhesive tape 10 from the viewpoints of adhesive strength, toughness, hand-cutting property, touch (softness), and the like. On the other hand, it is preferably 0.5 to 10 parts by weight, and more preferably 1 to 5 parts by weight.

また,基材層20における繊維片の添加量としては,前記基材層固形分100重量部に対し,0.2~10重量部,好ましくは,0.5~3重量部である。 The amount of the fiber pieces added to the base material layer 20 is 0.2 to 10 parts by weight, preferably 0.5 to 3 parts by weight, based on 100 parts by weight of the solid content of the base material layer.

なお,本発明で繊維片32として使用する材質としては,粘着剤として後述のアクリル系のものを使用する場合,アクリル系のものの使用が好ましく,また,アクリル系の繊維片の使用は耐熱性,耐水性の点でも好ましい。 As the material used as the fiber piece 32 in the present invention, when an acrylic material described later is used as the adhesive, it is preferable to use an acrylic material, and the acrylic fiber piece is heat resistant. It is also preferable in terms of water resistance.

また,耐水性の点ではポリエステル系のものの使用も好ましく,また,耐熱性の点ではレーヨン繊維も好適に使用できる。 Further, it is preferable to use a polyester fiber in terms of water resistance, and rayon fiber can also be preferably used in terms of heat resistance.

また,通気性の観点から,繊維片32として,繊維内部が中空となっている(断面に孔が存在する構造を有する)中空繊維片を使用することが好ましい。 Further, from the viewpoint of air permeability, it is preferable to use as the fiber piece 32 a hollow fiber piece in which the inside of the fiber is hollow (having a structure having holes in the cross section).

本発明で使用される中空繊維片は,単糸繊維が中空を有するものであれば特に限定されず,繊維の表面に多数の微細孔を有した多孔性の中空繊維片でもよく,また,表面に多数の微細孔を有しない非多孔性の中空繊維片であってもよい。 The hollow fiber piece used in the present invention is not particularly limited as long as the single yarn fiber has a hollow shape, and may be a porous hollow fiber piece having a large number of micropores on the surface of the fiber, or the surface thereof. It may be a non-porous hollow fiber piece that does not have a large number of micropores.

本発明に使用される中空繊維片としては,例えば,麻,綿等の天然繊維の他,ポリエステル,ナイロン,アクリル,塩化ビニル等の合成繊維の内部を中空にしたものが好適である。 As the hollow fiber piece used in the present invention, for example, in addition to natural fibers such as hemp and cotton, synthetic fibers such as polyester, nylon, acrylic and vinyl chloride are preferably hollow.

なお,中空繊維片の単糸の断面形状については,中空断面であれば特に限定されず,丸,三角,四角が例示される。 The cross-sectional shape of the single yarn of the hollow fiber piece is not particularly limited as long as it is a hollow cross section, and examples thereof include circles, triangles, and squares.

また,本発明の粘着テープ10は,図6に示すように,基材層及び粘着剤層に含有された繊維片32を,粘着テープ10の長手方向に沿って層状に分散させても良い。 Further, in the adhesive tape 10 of the present invention, as shown in FIG. 6, the fiber pieces 32 contained in the base material layer and the adhesive layer may be dispersed in layers along the longitudinal direction of the adhesive tape 10.

この場合,テープの厚み方向よりも長手方向への通気性が向上し,例えば,貼着時に抱き込んだエアーを,テープの厚み方向の他,長手方向に効率良く逃がす(排出する)ことができる。 In this case, the air permeability in the longitudinal direction is improved rather than the thickness direction of the tape, and for example, the air embraced at the time of sticking can be efficiently released (discharged) in the longitudinal direction as well as the thickness direction of the tape. ..

10 粘着テープ(10’ 両面粘着テープ)
20 基材層(ポリオレフィン樹脂シート)
21 平滑面
22,22’ 凹凸面
23,23’ 凹溝
30,30’ 粘着剤層
301 繊維片含有粘着剤層
302 繊維片少量含有粘着剤層
302a 第1の繊維片少量含有粘着剤層
302b 第2の繊維片少量含有粘着剤層
31 粘着剤
32 繊維片
40 巻き芯
50 押出機
51 押出ダイ
61,61’ エンボスロール
61a 凸条
62 ゴムロール
64 放電電極
65 処理ロール
100 粘着テープ
120 基材層
121 平滑面
122 凹凸面
123 凹溝
130 粘着剤層
131 粘着剤
135 不織布又は割布
136 ポリエステル系樹脂
140 巻き芯
150 工程紙
10 Adhesive tape (10'double-sided adhesive tape)
20 Base material layer (polyolefin resin sheet)
21 Smooth surface 22, 22'Concave surface 23, 23'Concave groove 30, 30' Adhesive layer 301 Fiber fragment-containing adhesive layer 302 Fiber fragment-containing adhesive layer 302a First fiber fragment-containing adhesive layer 302b First 2 Adhesive layer containing a small amount of fiber pieces 31 Adhesive 32 Fiber pieces 40 Winding core 50 Extruder 51 Extruding dies 61, 61'Embossed roll 61a Convex 62 Rubber roll 64 Discharge electrode 65 Treatment roll 100 Adhesive tape 120 Base material layer 121 Smooth Surface 122 Concavo-convex surface 123 Concave groove 130 Adhesive layer 131 Adhesive 135 Non-woven fabric or split cloth 136 Polyester resin 140 Roll core 150 Process paper

Claims (19)

片面に粘着テープの長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層と,
前記基材層の前記凹凸面上に形成された粘着剤層を備え,
前記基材層及び前記粘着剤層に,繊維片が分散され,前記基材層及び粘着剤層を構成する樹脂と前記繊維片との間に生じた隙間又は前記繊維片が有する孔による通気性を有していることを特徴とする粘着テープ。
A base material layer made of an unstretched polyolefin resin film having a concavo-convex surface in which a plurality of concave grooves are formed at predetermined intervals on one side in a direction orthogonal to the longitudinal direction of the adhesive tape.
A pressure-sensitive adhesive layer formed on the uneven surface of the base material layer is provided.
Fiber pieces are dispersed in the base material layer and the pressure-sensitive adhesive layer, and the air permeability is caused by the gaps formed between the resin constituting the base material layer and the pressure-sensitive adhesive layer and the fiber pieces or the holes possessed by the fiber pieces . Adhesive tape characterized by having.
前記粘着剤層が前記基材層の両面に形成され,
前記基材層及び前記粘着剤層に繊維片が分散され,前記基材層及び粘着剤層を構成する樹脂と前記繊維片との間に生じた隙間又は前記繊維片が有する孔による通気性を有していることを特徴とする請求項1記載の粘着テープ。
The pressure-sensitive adhesive layer is formed on both sides of the base material layer,
The fiber pieces are dispersed in the base material layer and the pressure-sensitive adhesive layer, and the air permeability is provided by the gaps formed between the resin constituting the base material layer and the pressure-sensitive adhesive layer and the fiber pieces or the holes possessed by the fiber pieces . The adhesive tape according to claim 1, wherein the adhesive tape is provided.
前記基材層が,両面に前記凹凸面を有することを特徴とする請求項2記載の粘着テープ。 The adhesive tape according to claim 2, wherein the base material layer has the uneven surfaces on both sides. 前記粘着剤層が,粘着剤の固形分100重量部に対し,前記繊維片を0.5~10重量部含有することを特徴とする請求項1~3いずれか1項記載の粘着テープ。 The pressure-sensitive adhesive tape according to any one of claims 1 to 3, wherein the pressure-sensitive adhesive layer contains 0.5 to 10 parts by weight of the fiber pieces with respect to 100 parts by weight of the solid content of the pressure-sensitive adhesive. 前記繊維片の繊維径が,0.05~100デニールであることを特徴とする請求項1~4いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 4, wherein the fiber diameter of the fiber piece is 0.05 to 100 denier. 前記繊維片の長さが1~10mmであることを特徴とする請求項1~5いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 5, wherein the length of the fiber piece is 1 to 10 mm. 前記基材層が,前記基材層固形分100重量部に対し,前記繊維片を0.2~10重量部含有することを特徴とする請求項1~6いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 6, wherein the base material layer contains 0.2 to 10 parts by weight of the fiber pieces with respect to 100 parts by weight of the base material layer solid content. 粘着テープの長手方向の伸びが30%以下である請求項1~7いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 7, wherein the adhesive tape has an elongation of 30% or less in the longitudinal direction. 粘着テープの長手方向の引張強さが100(N/50mm幅)以上であることを特徴とする請求項1~8いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 8, wherein the adhesive tape has a tensile strength in the longitudinal direction of 100 (N / 50 mm width) or more. 前記粘着剤層が,被着物に対する貼着側において前記繊維片の分散量が減少する構成であることを特徴とする請求項1~9いずれか1項記載の粘着テープ。 The pressure-sensitive adhesive tape according to any one of claims 1 to 9, wherein the pressure-sensitive adhesive layer has a structure in which the amount of dispersed fibers of the fiber pieces is reduced on the side to be adhered to an adherend. 前記粘着剤層が,基材層との貼着側において前記繊維片の分散量が減少する構成であることを特徴とする請求項10記載の粘着テープ。 The pressure-sensitive adhesive tape according to claim 10, wherein the pressure-sensitive adhesive layer has a structure in which the amount of dispersion of the fiber pieces is reduced on the side to be adhered to the base material layer. 前記繊維片が,PET,オレフィン系樹脂,レーヨン,ビニロン,ナイロンの群から選択されたいずれかの材質から成り,該繊維片の一種を,又は二種以上を混合したものを,前記粘着剤層に分散させたことを特徴とする請求項1~11いずれか1項記載の粘着テープ。 The fiber piece is made of any material selected from the group of PET, olefin resin, rayon, vinylon, and nylon, and one type of the fiber piece or a mixture of two or more types is used as the pressure-sensitive adhesive layer. The adhesive tape according to any one of claims 1 to 11, wherein the adhesive tape is dispersed in. 前記繊維片が中空繊維片であることを特徴とする請求項1~12いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 12, wherein the fiber piece is a hollow fiber piece. 前記繊維片が,粘着テープの長手方向に沿って層状に分散されたことを特徴とする請求項1~13いずれか1項記載の粘着テープ。 The adhesive tape according to any one of claims 1 to 13, wherein the fiber pieces are dispersed in a layer along the longitudinal direction of the adhesive tape. 片面に粘着テープの長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成る基材層の前記凹凸面に,粘着剤を積層して粘着剤層を形成する共に,前記基材層及び前記粘着剤層に,繊維片を分散させて,前記基材層及び粘着剤層を構成する樹脂と前記繊維片との間に生じた隙間又は前記繊維片が有する孔により通気性を持たせたことを特徴とする粘着テープの製造方法。 Adhesive is laminated on the uneven surface of a base material layer made of an unstretched polyolefin resin film having an uneven surface in which a plurality of concave grooves are formed at predetermined intervals in a direction orthogonal to the longitudinal direction of the adhesive tape on one side. The pressure-sensitive adhesive layer was formed, and the fiber pieces were dispersed in the base material layer and the pressure-sensitive adhesive layer, and formed between the resin constituting the base material layer and the pressure-sensitive adhesive layer and the fiber pieces. A method for producing an adhesive tape, which comprises providing breathability through a gap or a hole contained in the fiber piece . 前記基材層の両面に,粘着剤を積層して粘着剤層を形成すると共に,前記基材層及び前記粘着剤層に,繊維片を分散させて,前記基材層及び粘着剤層を構成する樹脂と前記繊維片との間に生じた隙間又は前記繊維片が有する孔により通気性を持たせたことを特徴とする請求項15記載の粘着テープの製造方法。 Adhesives are laminated on both sides of the base material layer to form a pressure-sensitive adhesive layer, and fiber pieces are dispersed in the base material layer and the pressure-sensitive adhesive layer to form the base material layer and the pressure-sensitive adhesive layer. The method for producing an adhesive tape according to claim 15, wherein the adhesive tape is made breathable by a gap formed between the resin and the fiber piece or a hole contained in the fiber piece. 前記基材層が,両面に粘着テープの長手方向と直交する方向に複数本の凹溝が所定間隔で形成された凹凸面を有する未延伸のポリオレフィン樹脂製フィルムから成ることを特徴とする請求項16記載の粘着テープの製造方法。 The claim is characterized in that the base material layer is made of an unstretched polyolefin resin film having uneven surfaces having a plurality of concave grooves formed at predetermined intervals on both sides in a direction orthogonal to the longitudinal direction of the adhesive tape. 16. The method for manufacturing an adhesive tape according to 16. 前記繊維片の分散量を変化させた複数種類の粘着剤を多層に積層して,被着物との接着面側で前記繊維片の分散量が減少する前記粘着剤層を形成したことを特徴とする請求項15~17いずれか1項記載の粘着テープの製造方法。 It is characterized in that a plurality of types of adhesives having different dispersion amounts of the fiber pieces are laminated in multiple layers to form the pressure-sensitive adhesive layer in which the dispersion amount of the fiber pieces is reduced on the adhesive surface side with the adherend. The method for manufacturing an adhesive tape according to any one of claims 15 to 17. 前記繊維片の分散量を変化させた複数種類の粘着剤を多層に積層して,前記基材層の前記凹凸面との接着面側で前記繊維片の分散量が減少する前記粘着剤層を形成したことを特徴とする請求項15~18いずれか1項記載の粘着テープの製造方法。 A plurality of types of adhesives having different dispersion amounts of the fiber pieces are laminated in multiple layers, and the pressure-sensitive adhesive layer in which the dispersion amount of the fiber pieces is reduced on the adhesive surface side of the base material layer with the uneven surface is formed. The method for producing an adhesive tape according to any one of claims 15 to 18, wherein the adhesive tape is formed.
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