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JP6920241B2 - Mixed composition and its production method - Google Patents

Mixed composition and its production method Download PDF

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JP6920241B2
JP6920241B2 JP2018059543A JP2018059543A JP6920241B2 JP 6920241 B2 JP6920241 B2 JP 6920241B2 JP 2018059543 A JP2018059543 A JP 2018059543A JP 2018059543 A JP2018059543 A JP 2018059543A JP 6920241 B2 JP6920241 B2 JP 6920241B2
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wheat flour
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flour
mixed composition
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JP2019170173A (en
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さやか 片桐
さやか 片桐
祐二 田上
祐二 田上
伊藤 浩一
浩一 伊藤
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Nisshin Seifun Premix Inc
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Description

本発明は、ベーカリー食品の製造に使用可能なミックス組成物に関し、詳細には、国内産麦小麦粉を用いたミックス組成物に関する。 The present invention relates to a mixed composition that can be used in the production of bakery foods, and more particularly to a mixed composition using domestic wheat flour.

国内産麦小麦粉、特に、生産量の多い中力系の国内産麦小麦粉は、主に外国産麦を使用した薄力粉と比較して、蛋白含量が多く、性質も異なるため、ヒキが強い、あるいはボリュームが出にくいとされ、従来ベーカリー食品、特にスポンジケーキ、クッキー、マフィン等のケーキ類には不適とされていた。 Domestic wheat flour, especially medium-strength domestic wheat flour with a large amount of production, has a higher protein content and different properties compared to soft flour mainly using foreign wheat, so it has a strong hiki or It is said that the volume is hard to come out, and it has been considered unsuitable for bakery foods, especially cakes such as sponge cakes, cookies and muffins.

一方で、近年の消費者の自然志向、健康志向の高まりを背景に、国内産麦小麦粉が持つ安心感や健康的なイメージから、消費者の間には国内産麦小麦粉を用いたケーキ類などのベーカリー食品に対する需要が高まっている。 On the other hand, against the background of consumers' growing nature and health consciousness in recent years, from the sense of security and healthy image of domestic wheat flour, cakes using domestic wheat flour are among consumers. Demand for bakery foods is increasing.

特許文献1には、製パンに不適とされている原料から作られた小麦粉に対し、加熱及び加熱に準ずる処理を施して製パンに適したものとする方法が記載され、該小麦粉として、国内産小麦(DW)から作られた薄力又は中力小麦粉が記載されている。特許文献1の実施例2では、DWのチホク小麦から作られた小麦粉を60〜69℃の温度で18分間保熱処理して得た熱処理粉と、該保熱処理が施されていない該小麦粉(無処理小麦粉)とを、熱処理粉が内数で40%(重量%)を占めるように混合して熱処理混合粉を得、該熱処理混合粉を用いて製パンを行っており、そうして得られたパンの外観及び内相が、無処理小麦粉のみを用いた場合に比して良好であったとされている。 Patent Document 1 describes a method in which wheat flour made from a raw material unsuitable for bread making is heated and treated in a manner similar to heating to make it suitable for bread making. Light or medium flour made from wheat (DW) is listed. In Example 2 of Patent Document 1, a heat-treated flour obtained by heat-retaining wheat flour made from DW chihoku wheat at a temperature of 60 to 69 ° C. for 18 minutes and the wheat flour not subjected to the heat-retaining heat treatment (none). Treated wheat flour) is mixed so that the heat-treated flour occupies 40% (% by weight) of the inside to obtain a heat-treated mixed flour, and bread is made using the heat-treated mixed flour, and thus obtained. It is said that the appearance and internal phase of the bread were better than when only untreated wheat flour was used.

特許文献2には、外観及び食感が良好なケーキ類を提供可能な熱処理小麦粉として、グルテンバイタリティ及び平均粒径が特定範囲にある中力粉及び/又は薄力粉からなる熱処理小麦粉が記載されている。特許文献2の実施例では、中力系の国内産麦小麦粉(日清製粉(株)製、商品名「白龍」)を、該小麦粉の品温が80〜100℃となる条件で熱処理して熱処理小麦粉を得、該熱処理小麦粉を用いてスポンジケーキを製造している(特許文献2の〔0024〕)。特許文献2には、熱処理された国内産麦小麦粉(熱処理国内産麦小麦粉)と熱処理されていない国内産麦小麦粉(非熱処理国内産麦小麦粉)とを併用してケーキ類を製造することは記載されていない。 Patent Document 2 describes heat-treated wheat flour composed of medium-strength flour and / or weak-strength flour having gluten vitality and an average particle size within a specific range as heat-treated wheat flour capable of providing cakes having a good appearance and texture. .. In the example of Patent Document 2, a medium-strength domestic wheat flour (manufactured by Nisshin Flour Co., Ltd., trade name "Hakuryu") is heat-treated under the condition that the product temperature of the flour is 80 to 100 ° C. Heat-treated wheat flour is obtained, and a sponge cake is produced using the heat-treated wheat flour (Patent Document 2 [0024]). Patent Document 2 describes that cakes are produced by using heat-treated domestic wheat flour (heat-treated domestic wheat flour) and non-heat-treated domestic wheat flour (non-heat-treated domestic wheat flour) in combination. It has not been.

特許文献3には、湿熱処理小麦粉を用いた麺類の製造方法として、各種生地材料を混合して生地を調製する場合に、湿熱処理小麦粉以外の生地材料に、品温95〜155℃の範囲で所定時間湿熱処理した湿熱処理小麦粉を添加する工程を有する製造方法が記載されている。特許文献3の実施例では、国内産麦小麦粉と外国産麦小麦粉との混合粉(日本製粉(株)製、さぬき菊)に、外国産麦小麦粉(日本製粉(株)製、ダイヤ)を湿熱処理して得られた湿熱処理小麦粉を添加し、生地を調製している。特許文献3に記載の製造方法によれば、硬さ、粘弾性のバランス、つるみなど、麺類に特有の特性が向上するとされている。特許文献3には、ベーカリー食品については記載されていない。 Patent Document 3 describes that, as a method for producing noodles using wet-heated wheat flour, when a dough is prepared by mixing various dough materials, a dough material other than the wet-heated wheat flour is used in a product temperature range of 95 to 155 ° C. A production method including a step of adding wet-heated wheat flour that has been wet-heated for a predetermined time is described. In the example of Patent Document 3, foreign wheat flour (manufactured by Nippon Flour Mills Co., Ltd., diamond) is moistened with a mixed flour of domestic wheat flour and foreign wheat flour (manufactured by Nippon Flour Mills Co., Ltd., Sanuki chrysanthemum). The dough is prepared by adding the wet heat-treated wheat flour obtained by heat treatment. According to the manufacturing method described in Patent Document 3, it is said that the characteristics peculiar to noodles such as hardness, viscoelastic balance, and smoothness are improved. Patent Document 3 does not describe bakery foods.

特開平7−50973号公報Japanese Unexamined Patent Publication No. 7-50973 特開平11−332454号公報Japanese Unexamined Patent Publication No. 11-332454 特開2014−135945号公報Japanese Unexamined Patent Publication No. 2014-135945

近年、外国産麦小麦粉よりも安心感の高い国内産麦小麦粉を用いたベーカリー食品に対する需要が高まっているが、国内産麦小麦粉を用いた従来のベーカリー食品、特にケーキ類は、国内産麦小麦粉の特性に起因して、ボリュームに乏しい、ヒキがあるといった問題があり、品質の点で改善の余地があった。国内産麦小麦粉を用いながらも、外国産麦小麦粉を用いた場合と同等以上の品質のベーカリー食品を安定的に提供し得る技術は未だ提供されていない。 In recent years, there has been an increasing demand for bakery foods using domestic wheat flour, which is more secure than foreign wheat flour. However, conventional bakery foods using domestic wheat flour, especially cakes, are made from domestic wheat flour. Due to the characteristics of, there were problems such as poor volume and flour, and there was room for improvement in terms of quality. While using domestic wheat flour, there is still no technology that can stably provide bakery foods of the same or higher quality than when foreign wheat flour is used.

本発明の課題は、国内産麦小麦粉を用いながらも、外国産麦小麦粉を用いた場合と同等以上の品質のベーカリー食品を製造可能なミックス組成物及びその製造方法を提供することにある。 An object of the present invention is to provide a mixed composition capable of producing a bakery food having a quality equal to or higher than that of using foreign wheat flour while using domestic wheat flour, and a method for producing the same.

本発明者らは、前記課題を解決するべく種々検討した結果、ミックス組成物に含有される穀粉類として、熱処理されていない国内産麦小麦粉(非熱処理国内産麦小麦粉)に加え、グルテンバイタリティが特定範囲にある熱処理小麦粉(好ましくは熱処理国内産麦小麦粉)を特定の比率で併用することで、主に外国産麦を使用した薄力粉に匹敵する非常に品質の良いベーカリー食品を製造できることを知見した。 As a result of various studies to solve the above problems, the present inventors have found that the flours contained in the mixed composition include gluten vitality in addition to domestic wheat flour that has not been heat-treated (non-heat-treated domestic wheat flour). It was found that by using heat-treated wheat flour in a specific range (preferably heat-treated domestic wheat flour) in a specific ratio, it is possible to produce very high-quality bakery foods that are comparable to soft flour mainly using foreign wheat. ..

本発明は、前記知見に基づきなされたもので、穀粉類を含有し、該穀粉類に、グルテンバイタリティ30〜52%の熱処理小麦粉と非熱処理国内産麦小麦粉とが含まれ、且つ該熱処理小麦粉の含有量が、該非熱処理国内産麦小麦粉の20〜500質量%であるミックス組成物である。 The present invention has been made based on the above findings, and contains flours, and the flours include heat-treated wheat flour having a gluten vitality of 30 to 52% and non-heat-treated domestic wheat flour, and the heat-treated wheat flour. It is a mixed composition having a content of 20 to 500% by mass of the non-heat-treated domestic wheat flour.

また本発明は、穀粉類を含有し、該穀粉類に、熱処理小麦粉及び非熱処理国内産麦小麦粉が含まれ、且つ該熱処理小麦粉の含有量が、該非熱処理国内産麦小麦粉の20〜500質量%である、ミックス組成物の製造方法であって、小麦粉をその品温が80℃以上となる条件で熱処理して熱処理小麦粉を得る熱処理工程と、前記熱処理工程で得られた熱処理小麦粉と非熱処理国内産麦小麦粉とを混合する工程とを有する、ミックス組成物の製造方法である。 Further, the present invention contains flours, and the flours contain heat-treated wheat flour and non-heat-treated domestic wheat flour, and the content of the heat-treated wheat flour is 20 to 500% by mass of the non-heat-treated domestic wheat flour. This is a method for producing a mixed composition, which is a heat treatment step of heat-treating wheat flour under the condition that the product temperature is 80 ° C. or higher to obtain heat-treated wheat flour, and the heat-treated wheat flour and non-heat-treated domestic products obtained in the heat treatment step. It is a method for producing a mixed composition, which comprises a step of mixing with wheat flour.

本発明によれば、国内産麦小麦粉を用いながらも、外国産麦小麦粉を用いた場合と同等以上の高品質のベーカリー食品が得られる。 According to the present invention, it is possible to obtain a bakery food having a quality equal to or higher than that when foreign wheat flour is used while using domestic wheat flour.

本発明の主たる特徴の1つは、国内産麦小麦粉を使用する点にあるところ、近年、食の安全性に対する国民の意識の高まりにより、種々の小麦粉含有食品において、外国産麦小麦粉よりも国内産麦小麦粉を選択する気運が非常に高まっており、本発明はこうした国内産麦小麦粉に対するニーズにマッチした待望の技術であるといえる。 One of the main features of the present invention is the use of domestic wheat flour. In recent years, due to the growing public awareness of food safety, various wheat flour-containing foods are domestically produced rather than foreign wheat flour. The momentum for selecting wheat flour from wheat flour has increased significantly, and it can be said that the present invention is a long-awaited technique that matches the needs for such domestic wheat flour.

本発明のミックス組成物は穀粉類を含有する。本発明で用いる穀粉類には、穀粉及び澱粉が包含される。前記穀粉としては、例えば、薄力粉、中力粉、強力粉、小麦全粒粉、デュラムセモリナ等の小麦粉;ライ麦粉、米粉、コーンフラワー、コーングリッツ等の小麦粉以外が挙げられる。前記穀粉には、熱処理されていない非熱処理穀粉の他、熱処理された熱処理穀粉が包含される。前記澱粉としては、例えば、コーンスターチ、ワキシーコーンスターチ、タピオカ澱粉、馬鈴薯澱粉、小麦澱粉、米澱粉等の未加工澱粉;該未加工澱粉に油脂加工、α化、エーテル化、エステル化、架橋、酸化等の処理の1つ以上を施した加工澱粉が挙げられる。 The mixed composition of the present invention contains flours. The flours used in the present invention include flour and starch. Examples of the flour include flours such as soft flour, medium-strength flour, strong flour, whole wheat flour, and duram semolina; and flours other than rye flour, rice flour, corn flour, and corn grits. The flour includes non-heat-treated flour that has not been heat-treated, as well as heat-treated flour that has been heat-treated. Examples of the starch include unmodified starch such as corn starch, waxy corn starch, tapioca starch, horse belly starch, wheat starch, rice starch, etc .; Examples include modified starch that has been subjected to one or more of the above treatments.

穀粉類は、典型的には、本発明のミックス組成物の主体をなすものである。本発明のミックス組成物における穀粉類の含有量は、該ミックス組成物の全質量に対して、好ましくは10質量%以上、より好ましくは20〜70質量%であり、100質量%即ち該ミックス組成物の全部が穀粉類でもよい。 Flours are typically the subject of the mixed compositions of the present invention. The content of flours in the mixed composition of the present invention is preferably 10% by mass or more, more preferably 20 to 70% by mass, and 100% by mass, that is, the mixed composition, based on the total mass of the mixed composition. All of the things may be flours.

本発明のミックス組成物は、該ミックス組成物に含有される穀粉類に、熱処理小麦粉及び非熱処理国内産麦小麦粉が含まれている点で特徴付けられる。本発明で用いる熱処理小麦粉は熱処理された小麦粉であり、熱処理が施される小麦粉(原料小麦粉)の原料となる小麦の産地は問わない。即ち、本発明で用いる熱処理小麦粉は、原料小麦粉である国内産麦小麦粉を熱処理してなる熱処理国内産麦小麦粉を含んでいてもよく、原料小麦粉である外国産麦小麦粉を熱処理してなる熱処理外国産麦小麦粉を含んでいてもよく、双方を含んでいてもよい。一方、本発明で用いる非熱処理国内産麦小麦粉は、熱処理されていない国内産麦小麦粉であり、原料となる小麦が国内産(日本産)麦に限定される。小麦の品質は、栽培される土壌や気候などの影響を受けて大きく変化し、同じ品種の小麦でも産地が異なれば品質が異なる。国内産麦と外国産麦とにおいても品質に大きな違いがある。 The mixed composition of the present invention is characterized in that the flours contained in the mixed composition contain heat-treated wheat flour and non-heat-treated domestic wheat flour. The heat-treated wheat flour used in the present invention is heat-treated wheat flour, and the origin of wheat that is the raw material of the heat-treated wheat flour (raw wheat flour) does not matter. That is, the heat-treated wheat flour used in the present invention may contain heat-treated domestic wheat flour obtained by heat-treating domestic wheat flour, which is the raw material flour, and is not heat-treated by heat-treating foreign wheat flour, which is the raw material flour. It may contain domestic wheat flour or both. On the other hand, the non-heat-treated domestic wheat flour used in the present invention is domestic wheat flour that has not been heat-treated, and the wheat as a raw material is limited to domestic (Japanese) wheat. The quality of wheat changes greatly due to the influence of the soil and climate in which it is cultivated, and even if the same variety of wheat is produced in different regions, the quality will differ. There is also a big difference in quality between domestic and foreign wheat.

本発明で用いる国内産麦小麦粉の原料となる小麦としては、現存する国内産小麦品種、及びそれらから派生した小麦品種(現存する国内産小麦品種の品種改良で生まれた小麦品種)の双方を用いることができる。本発明では、現存する国内産小麦品種及びその派生品種からなる群から選択される小麦品種を原料とする国内産麦小麦粉の1種を単独で、又は2種以上を組み合わせて用いることができる。 As the wheat used as a raw material for the domestic wheat flour used in the present invention, both existing domestic wheat varieties and wheat varieties derived from them (wheat varieties produced by breeding existing domestic wheat varieties) are used. be able to. In the present invention, one kind of domestic wheat flour made from a wheat variety selected from the group consisting of existing domestic wheat varieties and derivative varieties thereof can be used alone or in combination of two or more kinds.

前記の現存する国内産小麦品種としては、現在までに日本で品種登録された小麦品種として下記のものを例示できる。
あおばの恋、あきたっこ、アブクマワセ、あやひかり、イワイノダイチ、キタカミコムギ、きたさちほ、キタノカオリ、きたほなみ、きたもえ、キタ力ミコムギ、きぬあかり、きぬあずま、きぬいろは、きぬの波、キヌヒメ、コユキコムギ、さとのそら、さぬきの夢2000、さぬきの夢2009、しゅんよう、シラサギコムギ、シラネコムギ、シロガネコムギ、せときらら、タイセツコムギ、タクネコムギ、ダブル8号、タマイズミ、チクゴイズミ、ちくしW2号、チホクコムギ、つるきち、つるぴかり、ナンブコムギ、ニシノカオリ、ニシホナミ、ネノリゴシ、ネバリゴシ、ハナマンテ、ハルイブ、はるきらり、はるひので、ハルユタカ、ハレイブキ、ハレユタカ、バンドウワセ、フウセツ、ふくあかり、ふくさやか、ふくはるか、ふくほのか、ホクシン、ホロシリコムギ、もち姫、ゆきちから、ゆきはるか、ゆめあかり、ユメアサヒ、ゆめかおり、ゆめきらり、ユメシホウ、ユメセイキ、ゆめちから、銀河のちから、香育21号、春のかがやき、春よ恋、長崎W2号、東海103号、東海104号、東山42号、農林61号、福井県大3号、利根3号、ダブレ8号、ミナミノカオリ。
Examples of the existing domestic wheat varieties include the following as wheat varieties registered in Japan to date.
Aoba no Koi, Akitakko, Abukumawase, Aya Hikari, Iwaino Daichi, Kitakami Wheat, Kita Sachiho, Kitano Kaori, Kita Honami, Kitamoe, Kita Riki Mi Wheat, Kinu Akari, Kinu Azuma, Kinuiro, Kinu Wave, Kinuhime, Koyuki Wheat, Sato Nosora, Sanuki no Yume 2000, Sanuki no Yume 2009, Shunyo, Shirasagi Wheat, Shirane Wheat, Shirogane Wheat, Setorara, Taisetsu Wheat, Takune Wheat, Double No. 8, Tamaizumi, Chikugoizumi, Chikushi W2, Chihoku Wheat, Tsurukichi Pikari, Nambu Wheat, Nishino Kaori, Nishihonami, Nenorigoshi, Nebarigoshi, Hanamante, Haruibu, Harukirari, Haruhi no So, Haruyutaka, Hareibuki, Hareyutaka, Bandowase, Fuusetsu, Fukuakari, Fukusayaka Hime, Yukichikara, Yukiharu, Yume Akari, Yumeasahi, Yumekaori, Yumekirari, Yumeshihou, Yumeseiki, Yumechikara, Galactic Power, Kaiku 21, Spring Brightness, Haruyo Koi, Nagasaki W2, Tokai 103, Tokai No. 104, Higashiyama No. 42, Agriculture and Forestry No. 61, Fukui Prefecture University No. 3, Tone No. 3, Double No. 8, Minamino Kaori.

国内産小麦品種は、品種の特性や製粉性等の観点から、薄力系又は中力系と強力系とに大別される。本発明で用いる国内産麦小麦粉の原料となる小麦は、中力系が好ましい。中力系の国内産小麦品種は通常、蛋白含量が7.5〜10.5質量%である。前記の国内産小麦品種のうち、中力系として本発明で好ましく用いられるものとして、きたほなみ、シロガネコムギ、チクゴイズミを例示できる。 Domestic wheat varieties are roughly classified into weak or medium-strength varieties and strong varieties from the viewpoint of varietal characteristics and milling properties. The wheat used as a raw material for the domestic wheat flour used in the present invention is preferably medium-strength. Medium-strength domestic wheat varieties usually have a protein content of 7.5-10.5% by mass. Among the above-mentioned domestic wheat varieties, Kitahonami, Shirogane wheat, and Chikugoizumi can be exemplified as those preferably used in the present invention as medium-strength varieties.

本発明で用いる熱処理小麦粉の少なくとも一部、好ましくは全部が、グルテンバイタリティが30〜52%の範囲にある特定熱処理小麦粉である。斯かる特定熱処理小麦粉を含有しないミックス組成物では、外国産麦小麦粉を用いた場合と同等以上の品質のベーカリー食品を製造することは困難である。尚、前記特定熱処理小麦粉は前述した通り、熱処理国内産麦小麦粉であってもよく、熱処理外国産麦小麦粉であってもよいが、特に熱処理国内産麦小麦粉である場合は、その特定熱処理小麦粉たる熱処理国内産麦小麦粉のグルテンバイタリティは、好ましくは30〜51%、より好ましくは35〜47%、さらに好ましくは38〜42%である。 At least a part, preferably all of the heat-treated wheat flour used in the present invention is a specific heat-treated wheat flour having a gluten vitality in the range of 30 to 52%. With such a mixed composition not containing the specific heat-treated wheat flour, it is difficult to produce a bakery food having a quality equal to or higher than that when foreign wheat flour is used. As described above, the specific heat-treated wheat flour may be heat-treated domestic wheat flour or heat-treated foreign wheat flour, but in particular, when it is heat-treated domestic wheat flour, it is the specific heat-treated wheat flour. The gluten vitality of the heat-treated domestic wheat flour is preferably 30 to 51%, more preferably 35 to 47%, still more preferably 38 to 42%.

本明細書でいうグルテンバイタリティは下記方法により測定される。下記のグルテンバイタリティの測定方法は、(1)小麦粉の可溶性粗蛋白質含量の測定、(2)小麦粉の全粗蛋白質含量の測定、(3)グルテンバイタリティの算出の順で行われる。 The gluten vitality referred to in the present specification is measured by the following method. The following method for measuring gluten vitality is carried out in the order of (1) measurement of soluble crude protein content of wheat flour, (2) measurement of total crude protein content of wheat flour, and (3) calculation of gluten vitality.

<グルテンバイタリティの測定方法>
(1)小麦粉の可溶性粗蛋白質含量の測定:
(1−a)100mL容のビーカーに試料(小麦粉)を2g精秤して入れる。
(1−b)前記ビーカーに0.05規定酢酸40mLを加えて、室温で60分間攪拌して懸濁液を調製する。
(1−c)前記(1−b)で得た懸濁液を遠沈管に移して、5000rpmで5分間遠心分離を行った後、濾紙を用いて濾過し、濾液を回収する。
(1−d)前記ビーカーを0.05規定酢酸40mLで洗い、その洗液を遠沈管に移して、5000rpmで5分間遠心分離を行った後、濾紙を用いて濾過し、濾液を回収する。
(1−e)前記(1−c)及び(1−d)で回収した濾液を一緒にして0.05規定酢酸で100mLにメスアップする。
(1−f)ティケーター社(スウェーデン)のケルテックオートシステムのケルダールチューブに前記(1−e)で得られた液体の25mLをホールピペットで入れて、分解促進剤(日本ゼネラル株式会社製「ケルタブC」;硫酸カリウム:硫酸銅=9:1(重量比)1錠及び濃硫酸15mLを加える。
(1−g)前記ケルテックオートシステムに組み込まれているケルテック分解炉(DIGESTION SYSTEM 20 1015型) を用いて、ダイヤル4で1時間分解処理を行い、さらにダイヤル9又は10で1時間分解処理を自動的に行った後、この分解処理に続いて連続的に且つ自動的に、同じケルテックオートシステムに組み込まれているケルテック蒸留滴定システム(KJELTEC AUTO 1030型) を用いて、その分解処理を行った液体を蒸留及び滴定して(滴定には0.1規定硫酸を使用)、下記数式(1)により、試料(小麦粉)の可溶性粗蛋白質含量を求める。
<Measurement method of gluten vitality>
(1) Measurement of soluble crude protein content of wheat flour:
(1-a) Weigh 2 g of the sample (flour) into a 100 mL beaker.
(1-b) Add 40 mL of 0.05N acetic acid to the beaker and stir at room temperature for 60 minutes to prepare a suspension.
(1-c) The suspension obtained in (1-b) above is transferred to a centrifuge tube, centrifuged at 5000 rpm for 5 minutes, and then filtered using a filter paper to collect the filtrate.
(1-d) The beaker is washed with 40 mL of 0.05N acetic acid, the washing liquid is transferred to a centrifuge tube, centrifuged at 5000 rpm for 5 minutes, and then filtered using a filter paper to collect the filtrate.
(1-e) The filtrates recovered in (1-c) and (1-d) are combined and volumetric flasked to 100 mL with 0.05N acetic acid.
(1-f) 25 mL of the liquid obtained in (1-e) above was put into a Kjeldahl tube of Keltec Auto System of Ticker (Sweden) with a whole pipette, and a decomposition accelerator ("Keltab" manufactured by Nippon General Co., Ltd. C ”; Potassium sulfate: Copper sulfate = 9: 1 (weight ratio) 1 tablet and 15 mL of concentrated sulfuric acid are added.
(1-g) Using the Keltec decomposition furnace (DIGESTION SYSTEM 20 1015 type) built into the Keltec auto system, dial 4 is used for 1 hour disassembly processing, and dial 9 or 10 is used for 1 hour disassembly processing. After the decomposition process is performed automatically, the decomposition process is continuously and automatically performed using the Keltec distillation titration system (KJELTEC AUTO 1030 type) incorporated in the same Keltec auto system. The liquid is distilled and titrated (0.1 standard sulfuric acid is used for titration), and the soluble crude protein content of the sample (wheat flour) is determined by the following formula (1).

〔数1〕
可溶性粗蛋白質含量(%)
=0.14×(T−B)×F×N×(100/S)×(1/25) …(1)
前記数式(1)中、
T=滴定に要した0.1規定硫酸の量(mL)
B=ブランクの滴定に要した0.1規定硫酸の量(mL)
F=滴定に用いた0.1規定硫酸の力価(用時に測定するか又は力価の表示のある市販品を用いる)
N=窒素蛋白質換算係数(5.70)
S=試料の秤取量(g)
[Number 1]
Soluble crude protein content (%)
= 0.14 x (TB) x F x N x (100 / S) x (1/25) ... (1)
In the formula (1),
T = 0.1 amount of sulfuric acid required for titration (mL)
B = 0.1 amount of sulfuric acid required for blank titration (mL)
F = Titer of 0.1 specified sulfuric acid used for titration (measured at the time of use or use a commercially available product with a titer indication)
N = Nitrogen protein conversion factor (5.70)
S = Weighing amount of sample (g)

(2)小麦粉の全粗蛋白質含量の測定:
(2−a)前記(1)で用いたのと同じティケーター社のケルテックオートシステムのケルダールチューブに、試料(小麦粉)を0.5g精秤して入れ、これに前記(1−f)で用いたのと同じ分解促進剤1錠及び濃硫酸5mLを加える。
(2−b)前記(1)で用いたのと同じケルテックオートシステムのケルテック分解炉を用いて、ダイヤル9又は10で1時間分解処理を自動的に行った後、この分解処理に続いて連続的にかつ自動的に、同じケルテックオートシステムに組み込まれている前記(1)で用いたのと同じケルテック蒸留滴定システムを用いて、前記で分解処理を行った液体を蒸留及び滴定して(滴定には0.1規定硫酸を使用)、下記数式(2)により、試料(小麦粉)の全粗蛋白質含量を求める。
(2) Measurement of total crude protein content of wheat flour:
(2-a) 0.5 g of the sample (flour) was precisely weighed and placed in the Kjeldahl tube of the Kjeldahl Auto System manufactured by Ticker Co., Ltd., which was used in the above (1). Add 1 tablet of the same decomposition accelerator and 5 mL of concentrated sulfuric acid as used.
(2-b) Using the same Keltec auto system Keltec decomposition furnace used in (1) above, the disassembly process was automatically performed for 1 hour with dial 9 or 10, and then this disassembly process was followed. Continuously and automatically, using the same Keltec distillation titration system used in (1) above, which is incorporated in the same Keltec auto system, the liquid subjected to the decomposition treatment described above is distilled and titrated. (Use 0.1N sulfuric acid for titration), and determine the total crude protein content of the sample (wheat flour) by the following formula (2).

〔数2〕
全粗蛋白質含量(%)=(0.14×T×F×N)/S …(2)
前記数式(2)中、
T=滴定に要した0.1規定硫酸の量(mL)
F=滴定に用いた0.1規定硫酸の力価(用時に測定)
N=窒素蛋白質換算係数(5.70)
S=試料の秤取量(g)
[Number 2]
Total crude protein content (%) = (0.14 x T x F x N) / S ... (2)
In the formula (2),
T = 0.1 amount of sulfuric acid required for titration (mL)
F = Titer of 0.1 specified sulfuric acid used for titration (measured at the time of use)
N = Nitrogen protein conversion factor (5.70)
S = Weighing amount of sample (g)

(3)グルテンバイタリティの算出:
前記(1)で求めた試料(小麦粉)の可溶性粗蛋白質含量及び前記(2)で求めた試料(小麦粉)の全粗蛋白質含量から、下記数式(3)により、試料(小麦粉)のグルテンバイタリティを求める。
(3) Calculation of gluten vitality:
From the soluble crude protein content of the sample (wheat flour) obtained in (1) above and the total crude protein content of the sample (wheat flour) obtained in (2) above, the gluten vitality of the sample (wheat flour) can be determined by the following mathematical formula (3). Ask.

〔数3〕
グルテンバイタリティ(%)
=(可溶性粗蛋白質含量/全粗蛋白質含量)×100 …(3)
[Number 3]
Gluten vitality (%)
= (Soluble crude protein content / total crude protein content) x 100 ... (3)

本発明で用いる前記特定熱処理小麦粉(グルテンバイタリティが30〜52%の熱処理小麦粉)は、国内産麦小麦粉(非熱処理国内産麦小麦粉)又は外国産麦小麦粉(非熱処理外国産麦小麦粉)を熱処理することで得られる。この熱処理には、乾熱処理と湿熱処理があるところ、本発明で用いる前記特定熱処理小麦粉はいずれの熱処理が施されたものでもよい。 The specific heat-treated wheat flour (heat-treated wheat flour having a gluten vitality of 30 to 52%) used in the present invention heat-treats domestic wheat flour (non-heat-treated domestic wheat flour) or foreign wheat flour (non-heat-treated foreign wheat flour). It can be obtained by. This heat treatment includes a dry heat treatment and a wet heat treatment, and the specific heat-treated wheat flour used in the present invention may be any heat treatment.

乾熱処理は、処理対象(小麦粉)を水分無添加の条件で加熱する処理であり、処理対象中の水分を積極的に蒸発させる処理である。乾熱処理は、例えば、オーブンでの加熱、焙焼窯での加熱、乾燥器を用いる加熱、熱風を吹き付ける熱風乾燥、高温低湿度環境での放置などによって実施することができる。 The dry heat treatment is a process of heating the object to be treated (wheat flour) under the condition of no addition of water, and is a process of positively evaporating the water in the object to be treated. The dry heat treatment can be carried out by, for example, heating in an oven, heating in a roasting kiln, heating using a dryer, hot air drying by blowing hot air, leaving in a high temperature and low humidity environment, and the like.

湿熱処理は、処理対象(小麦粉)の水分を維持しながら、又は処理対象に水分を加えながら、処理対象を加熱する処理である。湿熱処理において、処理対象に加える水分としては、水、水蒸気を用いることができ、水蒸気としては飽和水蒸気が好ましく用いられる。湿熱処理における加熱方法は特に制限されず、例えば、熱風などの熱媒体を処理対象に直接接触させる方法、処理対象を高湿度雰囲気下において間接的に加熱する方法が挙げられる。湿熱処理の実施装置は特に制限されず、例えば、オートクレーブ、スチームオーブン、一軸又は二軸型エクストルーダーが挙げられる。 The moist heat treatment is a process of heating the treatment target while maintaining the water content of the treatment target (wheat flour) or adding water to the treatment target. In the moist heat treatment, water and steam can be used as the water to be added to the treatment target, and saturated steam is preferably used as the steam. The heating method in the moist heat treatment is not particularly limited, and examples thereof include a method in which a heat medium such as hot air is brought into direct contact with the treatment target, and a method in which the treatment target is indirectly heated in a high humidity atmosphere. The device for performing the moist heat treatment is not particularly limited, and examples thereof include an autoclave, a steam oven, and a uniaxial or biaxial extruder.

グルテンバイタリティが30〜52%の前記特定熱処理小麦粉の製造方法(小麦粉の熱処理方法)の好ましい一例として、国内産麦又は外国産麦小麦粉(原料小麦粉)をその品温が80℃以上、好ましくは90〜115℃となる条件で熱処理(乾熱処理又は湿熱処理)する方法が挙げられる。この原料小麦粉の熱処理としては湿熱処理が好ましく、特に下記の、密閉容器内に飽和水蒸気を導入する湿熱処理が好ましい。 As a preferable example of the method for producing the specific heat-treated wheat flour having a gluten vitality of 30 to 52% (heat treatment method for wheat flour), domestic wheat or foreign wheat flour (raw wheat flour) has a product temperature of 80 ° C. or higher, preferably 90. Examples thereof include a method of heat treatment (dry heat treatment or wet heat treatment) under the condition of ~ 115 ° C. As the heat treatment of the raw wheat flour, a wet heat treatment is preferable, and in particular, the following wet heat treatment in which saturated steam is introduced into a closed container is preferable.

前記の品温80℃以上の熱処理を湿熱処理によって行う場合、例えば、温度120〜125℃の飽和水蒸気を導入した加圧状態の密閉容器に処理対象(小麦粉)を導入する方法によって行うことができる。斯かる方法において、密閉容器中での処理対象の滞留時間は、好ましくは2〜60秒間、より好ましくは4〜20秒間であり、また、密閉容器から排出された直後の処理対象の品温は、80℃以上であり、好ましくは90〜115℃、より好ましくは100〜110℃である。 When the heat treatment at a product temperature of 80 ° C. or higher is performed by wet heat treatment, for example, it can be performed by a method of introducing a treatment target (wheat flour) into a closed container in a pressurized state in which saturated steam having a temperature of 120 to 125 ° C. is introduced. .. In such a method, the residence time of the treatment target in the closed container is preferably 2 to 60 seconds, more preferably 4 to 20 seconds, and the product temperature of the treatment target immediately after being discharged from the closed container is , 80 ° C. or higher, preferably 90 to 115 ° C., more preferably 100 to 110 ° C.

前記の密閉容器内に飽和水蒸気を導入する湿熱処理は、例えば、特開平3−83567号公報に記載されているような密閉系撹拌機を用いて実施し得る。この密閉系撹拌機は、処理対象(小麦粉)の投入口及び排出口並びにこれらを結ぶ処理対象の移送路を有する密閉式の円筒形圧力容器と、該移送路内に飽和水蒸気を導入する機構とを具備し、該移送路内に、処理対象の移送方向に延びる撹拌軸と該撹拌軸の周囲に螺旋状に植設された撹拌羽根とを含んで構成される攪拌機が設けられ、該攪拌機によって該移送路内の処理対象を撹拌可能になされている。この撹拌機は、あくまで前記移送路内の処理対象を撹拌するための部材であって、処理対象を前記排出口へ押し出すための押出具ではなく、前記密閉系撹拌機は、そのような押出具(エクストルーダーが備えるスクリューに相当する部材)は具備していない。前記密閉系撹拌機を用いた小麦粉の湿熱処理は、該小麦粉を攪拌しながら移送する攪拌移送過程で該小麦粉に飽和水蒸気を直接当てる工程を含むものであり、斯かる湿熱処理においては、小麦粉流量3000kg/hの時に、水蒸気流量を210〜260kg/hとすることが好ましい。 The moist heat treatment for introducing saturated steam into the closed container can be carried out using, for example, a closed system agitator as described in JP-A-3-83567. This closed system agitator has a closed cylindrical pressure vessel having an input port and an discharge port for a processing target (wheat flour), a transfer path for the processing target connecting them, and a mechanism for introducing saturated steam into the transfer path. A stirrer including a stirring shaft extending in the transfer direction of the processing target and a stirring blade spirally planted around the stirring shaft is provided in the transfer path. The processing target in the transfer path can be agitated. This agitator is a member for agitating the processing object in the transfer path to the last, and is not an extruder for pushing the processing object to the discharge port. The closed system agitator is such an extruder. (Member corresponding to the screw provided in the extruder) is not provided. The wet heat treatment of wheat flour using the closed system stirrer includes a step of directly applying saturated steam to the wheat flour in a stirring transfer process of transferring the wheat flour while stirring. In such a wet heat treatment, the flow rate of wheat flour At 3000 kg / h, the water vapor flow rate is preferably 210-260 kg / h.

本発明のミックス組成物が含有する穀粉類には前述した通り、グルテンバイタリティ30〜52%の特定熱処理小麦粉と非熱処理国内産麦小麦粉とが含まれるところ、該特定熱処理小麦粉の含有量は、非熱処理国内産麦小麦粉の全質量に対し20〜500質量%、好ましくは25〜400質量%、より好ましくは60〜150質量%である。斯かる特定熱処理小麦粉の対非熱処理国内産麦小麦粉含有量が20質量%未満では、特定熱処理小麦粉を使用する意義に乏しく、非熱処理国内産麦小麦粉を使用して高品質のベーカリー食品を製造することが困難になるおそれがある。また、特定熱処理小麦粉の対非熱処理国内産麦小麦粉含有量が500質量%を超えると、ベーカリー食品のボリュームが出ないおそれがある。 As described above, the flours contained in the mixed composition of the present invention include the specified heat-treated wheat flour having a gluten vitality of 30 to 52% and the non-heat-treated domestic wheat flour, and the content of the specified heat-treated wheat flour is not. It is 20 to 500% by mass, preferably 25 to 400% by mass, and more preferably 60 to 150% by mass with respect to the total mass of the heat-treated domestic wheat flour. If the content of the non-heat-treated domestic wheat flour is less than 20% by mass, the use of the specific heat-treated wheat flour is not meaningful, and the non-heat-treated domestic wheat flour is used to produce high-quality bakery foods. Can be difficult. Further, if the content of the non-heat-treated domestic wheat flour in the specific heat-treated wheat flour exceeds 500% by mass, the volume of the bakery food may not be produced.

また、本発明のミックス組成物が含有する穀粉類におけるグルテンバイタリティ30〜52%の熱処理小麦粉の含有率、即ち該穀粉類の全質量に対する前記特定熱処理小麦粉の質量の割合は、好ましくは10〜80質量%、より好ましくは30〜60質量%である。穀粉類における前記特定熱処理小麦粉の含有率が低すぎると、前記特定熱処理小麦粉と併用される非熱処理国内産麦小麦粉が相対的に多くなるため、外国産麦小麦粉を用いた場合と同等以上の高品質のベーカリー食品を得ることが困難となり、逆に該占有率が高すぎると、特にベーカリー食品のボリュームが乏しいものとなり、また、製造コストの点でも不利になるおそれがある。 Further, the content of the heat-treated wheat flour having a gluten vitality of 30 to 52% in the flours contained in the mixed composition of the present invention, that is, the ratio of the mass of the specific heat-treated wheat flour to the total mass of the flours is preferably 10 to 80. It is by mass, more preferably 30 to 60% by mass. If the content of the specified heat-treated wheat flour in the flours is too low, the amount of non-heat-treated domestic wheat flour used in combination with the specific heat-treated wheat flour is relatively large, so that the content is as high as or higher than that when foreign wheat flour is used. It becomes difficult to obtain quality bakery foods, and conversely, if the occupancy rate is too high, the volume of bakery foods becomes particularly poor, and there is a risk of being disadvantageous in terms of manufacturing cost.

また、本発明のミックス組成物が含有する穀粉類における非熱処理国内産麦小麦粉の含有率、即ち該穀粉類の全質量に対する非熱処理国内産麦小麦粉の質量の割合は、好ましくは10〜80質量%、より好ましくは30〜60質量%である。 Further, the content of the non-heat-treated domestic wheat flour in the flours contained in the mixed composition of the present invention, that is, the ratio of the mass of the non-heat-treated domestic wheat flour to the total mass of the flours is preferably 10 to 80 mass. %, More preferably 30 to 60% by mass.

本発明で用いる前記特定熱処理小麦粉(グルテンバイタリティ30〜52%の熱処理小麦粉)は、前述した通り、原料小麦粉の原料となる小麦の産地を問わず、熱処理外国産麦小麦粉を含んでいてもよいが、国内産麦小麦粉の積極使用の観点から、少なくとも熱処理国内産麦小麦粉を含むことが好ましい。その場合、本発明のミックス組成物において、前記特定熱処理小麦粉における熱処理国内産麦小麦粉の含有率、即ち該ミックス組成物中の前記特定熱処理小麦粉の全質量に対する熱処理国内産麦小麦粉の質量の割合は、好ましくは80質量%以上、より好ましくは100質量%であり、ミックス組成物中の前記特定熱処理小麦粉の全部が熱処理国内産麦小麦粉であることが特に好ましい。 As described above, the specific heat-treated wheat flour (heat-treated wheat flour having a gluten vitality of 30 to 52%) used in the present invention may contain heat-treated foreign wheat flour regardless of the origin of the wheat that is the raw material of the raw wheat flour. From the viewpoint of active use of domestic wheat flour, it is preferable to contain at least heat-treated domestic wheat flour. In that case, in the mixed composition of the present invention, the content of the heat-treated domestic wheat flour in the specified heat-treated wheat flour, that is, the ratio of the mass of the heat-treated domestic wheat flour to the total mass of the heat-treated domestic wheat flour in the mixed composition is It is preferably 80% by mass or more, more preferably 100% by mass, and it is particularly preferable that all of the specified heat-treated wheat flour in the mixed composition is heat-treated domestic wheat flour.

また、本発明のミックス組成物が含有する穀粉類における前記特定熱処理国内産麦小麦粉と非熱処理国内産麦小麦粉との合計の含有率は、国内産麦小麦粉の積極使用の観点から、好ましくは30質量%以上、より好ましくは40質量%以上、特に好ましくは50〜100質量%である。 Further, the total content of the specified heat-treated domestic wheat flour and the non-heat-treated domestic wheat flour in the flours contained in the mixed composition of the present invention is preferably 30 from the viewpoint of active use of the domestic wheat flour. It is by mass or more, more preferably 40% by mass or more, and particularly preferably 50 to 100% by mass.

本発明のミックス組成物が含有する穀粉類には、前述した熱処理又は非熱処理国内産麦小麦粉に加え、さらに熱処理されていない非熱処理外国産麦小麦粉が含まれていてもよい。非熱処理外国産麦小麦粉としては、ケーキ類などのベーカリー食品への適性を考慮すると、薄力粉が好ましい。本発明のミックス組成物が含有する穀粉類における非熱処理外国産麦小麦粉の含有率、即ち該穀粉類の全質量に対する非熱処理外国産麦小麦粉の質量の割合は、国内産麦小麦粉の積極使用とケーキ類の品質とのバランス等の観点から、好ましくは40質量%以下である。 The flours contained in the mixed composition of the present invention may contain non-heat-treated foreign wheat flour that has not been heat-treated, in addition to the heat-treated or non-heat-treated domestic wheat flour described above. As the non-heat-treated foreign wheat flour, soft flour is preferable in consideration of suitability for bakery foods such as cakes. The content of non-heat-treated foreign wheat flour in the flours contained in the mixed composition of the present invention, that is, the ratio of the mass of the non-heat-treated foreign wheat flour to the total mass of the flours is based on the active use of domestic wheat flour. From the viewpoint of balance with the quality of cakes, it is preferably 40% by mass or less.

本発明のミックス組成物は、穀粉類以外の他の成分を含有してもよい。他の成分としては、例えば、砂糖、ぶどう糖、オリゴ糖、麦芽糖、トレハロース、果糖等の糖類;グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチン、有機酸モノグリセリド、ステアロイル乳酸ナトリウム、ステアロイル乳酸カルシウム等の乳化剤;グルテン、グリアジン、グルテニン(以上、小麦蛋白質)、全卵、卵白、卵黄(以上、卵蛋白質)、脱脂粉乳、ホエー蛋白(以上、乳蛋白質)、大豆蛋白質、ゼラチン等の蛋白素材;動物油脂、植物油脂等の油脂類;卵粉等の乾燥卵、増粘多糖類等、膨張剤、乳原料、香料、食塩、酵素、色素等が挙げられ、製造するベーカリー食品の種類等に応じて、これらの1種を単独で又は2種以上を組み合わせて適宜の量で用いることができる。 The mixed composition of the present invention may contain ingredients other than flours. Other ingredients include, for example, sugars such as sugar, glucose, oligosaccharide, malt sugar, trehalose, and fructose; glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, lecithin, organic acid monoglyceride, stearoyl lactic acid. Emulsifiers such as sodium and stearoyl calcium lactate; gluten, glycerin, glutenin (above, wheat protein), whole egg, egg white, egg yolk (above, egg protein), defatted milk powder, whey protein (above, milk protein), soybean protein, gelatin Protein materials such as animal fats and oils, oils and fats such as vegetable fats and oils; dried eggs such as egg powder, thickening polysaccharides, swelling agents, dairy raw materials, fragrances, salt, enzymes, pigments, etc. One of these can be used alone or in combination of two or more in an appropriate amount, depending on the type and the like.

本発明のミックス組成物は、前記特定熱処理小麦粉及び非熱処理国内産麦小麦粉を含む各種成分を混合することによって得られる。本発明のミックス組成物の常温常圧下での形態は、粉末状、顆粒状などの粉体である。 The mixed composition of the present invention is obtained by mixing various components including the specific heat-treated wheat flour and non-heat-treated domestic wheat flour. The form of the mixed composition of the present invention under normal temperature and pressure is a powder such as powder or granules.

本発明のミックス組成物の製造方法の一例として、1)小麦粉(非熱処理国内産麦小麦粉又は非熱処理外国産麦小麦粉)をその品温が80℃以上、好ましくは85〜115℃となる条件で熱処理(乾熱処理又は湿熱処理)して、グルテンバイタリティ30〜52%の特定熱処理小麦粉を得る熱処理工程と、2)該熱処理工程で得られた特定熱処理小麦粉と、別途用意した非熱処理国内産麦小麦粉とを混合する工程とを有する製造方法が挙げられる。斯かる製造方法において、前記熱処理としては湿熱処理が好ましい。この湿熱処理の詳細については前述した通りである。 As an example of the method for producing the mixed composition of the present invention, 1) wheat flour (non-heat-treated domestic wheat flour or non-heat-treated foreign wheat flour) is prepared under the condition that the product temperature is 80 ° C. or higher, preferably 85 to 115 ° C. A heat treatment step of heat-treating (dry heat treatment or wet heat treatment) to obtain a specific heat-treated wheat flour having a gluten vitality of 30 to 52%, 2) a specific heat-treated wheat flour obtained in the heat treatment step, and a separately prepared non-heat-treated domestic wheat flour. Examples thereof include a manufacturing method having a step of mixing and. In such a production method, the heat treatment is preferably a wet heat treatment. The details of this wet heat treatment are as described above.

本発明のミックス組成物は、ベーカリー食品の製造に用いることができる。ベーカリー食品は、穀粉類(穀粉及び澱粉)を主原料とし、これに必要に応じてイーストや膨張剤(ベーキングパウダー等)、水、食塩、砂糖などの副原料を加えて得られた発酵又は非発酵生地を、焼成、蒸し、フライ等の加熱処理に供して得られる食品である。本発明が適用可能なベーカリー食品として、例えば、パン類;ピザ類;ケーキ類;ワッフル、シュー、ビスケット、どら焼き、焼き饅頭等の和洋焼き菓子;ドーナツ等の揚げ菓子等が挙げられる。パン類としては、食パン(例えばロールパン、白パン、黒パン、フランスパン、乾パン、コッペパン、クロワッサン等)、調理パン、菓子パン、蒸しパン等が挙げられる。ケーキ類としては、スポンジケーキ、バターケーキ、ロールケーキ、ホットケーキ、ブッセ、バームクーヘン、パウンドケーキ、チーズケーキ、スナックケーキ、マフィン、バー、クッキー、パンケーキ等が挙げられる。 The mixed composition of the present invention can be used in the production of bakery foods. Bakery foods are fermented or non-fermented obtained by using flour (flour and starch) as the main ingredient and adding auxiliary ingredients such as yeast, leavening agent (baking powder, etc.), water, salt, and sugar as needed. It is a food obtained by subjecting fermented dough to heat treatment such as baking, steaming, and frying. Examples of bakery foods to which the present invention can be applied include breads; pizzas; cakes; waffles, shoes, biscuits, dorayaki, Japanese and Western baked confectioneries such as roasted buns; and fried confectioneries such as donuts. Examples of breads include breads (for example, roll breads, white breads, black breads, French breads, dry breads, coppe breads, croissants, etc.), cooked breads, sweet breads, steamed breads, and the like. Examples of cakes include sponge cakes, butter cakes, roll cakes, hot cakes, busses, balmkuchens, pound cakes, cheese cakes, snack cakes, muffins, bars, cookies, pancakes and the like.

本発明のミックス組成物は特にケーキ類に好ましい。ここでいう、ケーキ類は通常、「薄力粉を主体とする穀粉類」を用いて製造されたベーカリー食品のことを指す。本発明のミックス組成物における穀粉類は必ずしも薄力粉を主体とするものではないが、該ミックス組成物を用いることで、従来品と同等以上の高品質のケーキ類を製造することができる。前記の「薄力粉を主体とする穀粉類」において、薄力粉の含有量は、該穀粉類の全質量に対して、好ましくは30質量%以上、より好ましくは50質量%以上である。本発明のミックス組成物が適用可能なケーキ類として、例えば、スポンジケーキ、バターケーキ、ロールケーキ、ホットケーキ、ブッセ、バームクーヘン、パウンドケーキ、チーズケーキ、スナックケーキ、マフィン、バー、クッキー、パンケーキ、スフレ、スコーン、ワッフル、カステラ、どら焼きが挙げられる。本発明が特に好適なケーキ類として、マフィン、スポンジケーキ、クッキーを例示できる。 The mixed composition of the present invention is particularly preferable for cakes. The cakes referred to here usually refer to bakery foods produced using "flours mainly composed of soft flour". The flours in the mixed composition of the present invention are not necessarily mainly made of soft flour, but by using the mixed composition, high quality cakes equal to or higher than the conventional products can be produced. In the above-mentioned "flours mainly composed of cake flour", the content of the cake flour is preferably 30% by mass or more, more preferably 50% by mass or more, based on the total mass of the cake flour. Cakes to which the mixed composition of the present invention can be applied include, for example, sponge cakes, butter cakes, roll cakes, hot cakes, busses, balmkuchens, pound cakes, cheese cakes, snack cakes, muffins, bars, cookies, pancakes, etc. Examples include pancakes, scones, waffles, cakes and pancakes. Muffins, sponge cakes, and cookies can be exemplified as cakes for which the present invention is particularly suitable.

本発明のミックス組成物を用いたケーキ類等のベーカリー食品の製造は、常法に従って行うことができる。本発明のミックス組成物を用いたベーカリー食品の製造方法の一例として、該ミックス組成物に液体を加えて生地を調製し、該生地を成形し加熱する工程を有する製造方法が挙げられる。前記製造方法において、生地を調製する際にミックス組成物に添加する液体としては、例えば水、牛乳、卵等が挙げられ、これらの1種を単独で又は2種以上を組み合わせて用いることができる。また、前記製造方法において、生地の加熱方法は、典型的には、焼成である。また、前記製造方法においては、必要に応じ、調製した生地を加熱(焼成)する前に、常法に従って発酵させてもよい。 The production of bakery foods such as cakes using the mixed composition of the present invention can be carried out according to a conventional method. As an example of a method for producing a bakery food product using the mixed composition of the present invention, there is a production method having a step of adding a liquid to the mixed composition to prepare a dough, molding the dough, and heating the dough. In the above-mentioned production method, examples of the liquid to be added to the mixed composition when preparing the dough include water, milk, eggs and the like, and one of these can be used alone or in combination of two or more. .. Further, in the above-mentioned production method, the method for heating the dough is typically baking. Further, in the above-mentioned production method, if necessary, the prepared dough may be fermented according to a conventional method before being heated (baked).

以下、実施例を挙げて、本発明をさらに詳細に説明するが、本発明は下記の実施例に限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to the following examples.

〔実施例1〜6及び比較例1〜4〕
下記表1の配合で原材料を混合して、ミックス組成物を製造した。使用した原材料の詳細は下記の通り。
・非熱処理国内産麦小麦粉:中力系(日清製粉(株)製、商品名「薫風」)
・熱処理小麦粉:下記方法により製造したもの
・薄力粉:薄力系の外国産麦小麦粉(日清製粉(株)製、商品名「フラワー」)
[Examples 1 to 6 and Comparative Examples 1 to 4]
The raw materials were mixed according to the formulation shown in Table 1 below to prepare a mixed composition. Details of the raw materials used are as follows.
・ Non-heat-treated domestic wheat flour: Medium-strength (manufactured by Nisshin Seifun Co., Ltd., trade name “Kaoru”)
・ Heat-treated wheat flour: manufactured by the following method ・ Weak flour: Weak foreign wheat flour (manufactured by Nisshin Seifun Co., Ltd., trade name “Flower”)

(熱処理小麦粉の製造方法)
原料小麦粉として、各実施例で非熱処理国内産麦小麦粉として用いたものと同じもの又は薄力粉として用いたものと同じものを用いた。原料小麦粉に対し、前記の密閉系撹拌機を用いた飽和水蒸気による湿熱処理を施して、グルテンバイタリティ(GV)が41%である熱処理国内産麦小麦粉と、GVが52%である熱処理外国産麦小麦粉とを製造した。湿熱処理の条件は下記の通り。
・飽和水蒸気の温度:120〜125℃
・密閉系撹拌機中での処理対象の滞留時間:10秒間
・密閉系撹拌機から排出された直後の処理対象の品温:90〜115℃
・密閉系撹拌機における小麦粉流量:3000kg/h
・密閉系撹拌機における水蒸気流量:210〜260kg/h
(Manufacturing method of heat-treated wheat flour)
As the raw material wheat flour, the same one used as the non-heat-treated domestic wheat flour or the same one used as the soft flour in each example was used. The raw wheat flour is subjected to moist heat treatment with saturated steam using the above-mentioned closed system stirrer, and heat-treated domestic wheat flour having a gluten vitality (GV) of 41% and heat-treated foreign wheat having a GV of 52%. Manufactured with flour. The conditions for moist heat treatment are as follows.
-Saturated water vapor temperature: 120-125 ° C
・ Dwelling time of the object to be treated in the closed system agitator: 10 seconds ・ Product temperature of the object to be processed immediately after being discharged from the closed system agitator: 90 to 115 ° C.
-Flour flow rate in a closed stirrer: 3000 kg / h
-Steam flow rate in a closed system stirrer: 210-260 kg / h

〔実施例7〜10及び比較例5〜6〕
熱処理国内産麦小麦粉を変更した以外は実施例2と同様にして、ミックス組成物を製造した。実施例7〜10及び比較例5〜6で使用した熱処理国内産麦小麦粉は、前記(熱処理小麦粉の製造方法)に従い、湿熱処理の条件を適宜変更して製造したもので、下記表2に示すように、GVが相互に異なる。
[Examples 7 to 10 and Comparative Examples 5 to 6]
A mixed composition was produced in the same manner as in Example 2 except that the heat-treated domestic wheat flour was changed. The heat-treated domestic wheat flour used in Examples 7 to 10 and Comparative Examples 5 to 6 was produced by appropriately changing the conditions of wet heat treatment in accordance with the above (method for producing heat-treated wheat flour), and is shown in Table 2 below. As such, GVs are different from each other.

〔試験例1〕
各実施例及び比較例のミックス組成物を用いて、ケーキ類の一種であるマフィンを製造した。具体的には下記の配合で、ミックス組成物を含む原材料をミキシングし、マフィン生地を調製した。10分間のフロアタイムをとった後、グラシン紙にマフィン生地を55gずつ注下し、所定形状に成形し、190℃にて18分間焼成してマフィンを製造した。
マフィン生地の配合:ミックス組成物100質量部、砂糖60質量部、ベーキングパウダー4質量部、食塩1.2質量部、全卵30質量部、牛乳75質量部、マーガリン40質量部
製造したマフィンを室温で30分放置した後、訓練された専門のパネラー10名に、マフィンのボリューム、食感、内相をそれぞれ下記評価基準で評価してもらった。その結果を10名の評価点の平均値として下記表1及び表2に示す。
[Test Example 1]
Muffins, which are a kind of cakes, were produced using the mixed compositions of each Example and Comparative Example. Specifically, the raw materials including the mixed composition were mixed with the following composition to prepare a muffin dough. After taking a floor time of 10 minutes, 55 g of muffin dough was poured into glassine paper, formed into a predetermined shape, and baked at 190 ° C. for 18 minutes to produce muffins.
Muffin dough composition: 100 parts by mass of mixed composition, 60 parts by mass of sugar, 4 parts by mass of baking powder, 1.2 parts by mass of salt, 30 parts by mass of whole egg, 75 parts by mass of milk, 40 parts by mass of margarine After leaving it for 30 minutes, 10 trained professional panelists evaluated the volume, texture, and internal phase of the muffins according to the following evaluation criteria. The results are shown in Tables 1 and 2 below as the average value of the evaluation points of 10 people.

<ボリュームの評価基準>
5点:非常にボリュームがあり、極めて良好。
4点:ボリュームがあり、良好。
3点:ややボリュームに乏しいが、問題ないレベル。
2点:ボリュームに乏しく、不良。
1点:非常にボリュームに乏しく、極めて不良。
<食感の評価基準>
5点:しっとりふんわりしていて、非常に口どけが良く、極めて良好。
4点:しっとりふんわりしていて、口どけが良く、良好。
3点:ややパサつきがあり又はややくちゃついているが、問題ないレベル。
2点:パサつきがある又はくちゃついていて、口どけがやや悪く、不良。
1点:パサつきがある又はくちゃついていて、口どけが悪く、極めて不良。
<内相の評価基準>
5点:目が非常に均一で細かく、極めて良好。
4点:目が均一で細かく、良好。
3点:やや目が不均一で粗いが、問題ないレベル。
2点:目が不均一で粗く、不良。
1点:目が非常に不均一で粗く、極めて不良。
<Volume evaluation criteria>
5 points: Very voluminous and very good.
4 points: There is volume and it is good.
3 points: The volume is a little poor, but there is no problem.
2 points: Poor volume and poor.
1 point: Very poor volume and extremely poor.
<Evaluation criteria for texture>
5 points: Moist and fluffy, very smooth and very good.
4 points: Moist and fluffy, good in the mouth and good.
3 points: Somewhat dry or slightly messed up, but no problem.
2 points: Dry or crumpled, slightly bad mouthfeel, poor.
1 point: Dry or crumpled, poor mouthfeel, extremely poor.
<Evaluation criteria for internal phase>
5 points: Very uniform and fine eyes, very good.
4 points: The eyes are uniform, fine and good.
3 points: The eyes are slightly uneven and rough, but there is no problem.
2 points: The eyes are uneven, rough and defective.
1 point: The eyes are very uneven and coarse, and very poor.

Figure 0006920241
Figure 0006920241

Figure 0006920241
Figure 0006920241

〔実施例11〕
ミックス組成を下記表3のように変更した以外は実施例2と同様にして、ミックス組成物を製造した。
[Example 11]
A mixed composition was produced in the same manner as in Example 2 except that the mixed composition was changed as shown in Table 3 below.

〔試験例2〕
実施例11及び比較例2のミックス組成物を用いて、ケーキ類の一種であるスポンジケーキを下記方法により製造した。製造中間体であるスポンジケーキ生地の配合は下記の通り。
スポンジケーキ生地の配合:ミックス組成物100質量部、砂糖135質量部、全卵180質量部、牛乳18質量部、バター18質量部
製造直後のスポンジケーキを室温で90分放置した後、所定の製品ボックスに入れて蓋をして12時間以上保管した。訓練された専門のパネラー10名に、保管されていたスポンジケーキのボリューム、食感、内相をそれぞれ前記評価基準で評価してもらった。その結果を10名の評価点の平均値として下記表3に示す。
[Test Example 2]
Using the mixed compositions of Example 11 and Comparative Example 2, a sponge cake, which is a kind of cakes, was produced by the following method. The composition of the sponge cake dough, which is a manufacturing intermediate, is as follows.
Formulation of sponge cake dough: 100 parts by mass of mixed composition, 135 parts by mass of sugar, 180 parts by mass of whole egg, 18 parts by mass of milk, 18 parts by mass of butter The sponge cake immediately after production is left at room temperature for 90 minutes, and then a predetermined product. It was placed in a box, covered, and stored for 12 hours or more. Ten trained professional panelists evaluated the volume, texture, and internal phase of the stored sponge cake according to the above evaluation criteria. The results are shown in Table 3 below as the average value of the evaluation points of 10 people.

(スポンジケーキの製造方法)
(1)軽くほぐした全卵及び砂糖をミキサーボールに入れて、該ミキサーボールの内容物の品温を23〜25℃に保ちながらホイッパーで混合し、該内容物をその比重が0.26±0.01になるまで泡立てた。
(2)予め篩で一度篩っておいたミックス組成物を前記(1)のミキサーボールの内容物に加え、かたまりが生じないように均一に混ぜ合わせて、該内容物の比重を0.38±0.01とした。
(3)牛乳及びバターを一緒に湯煎で溶かしたものを前記(2)のミキサーボールの内容物に加え、さらに混ぜ合わせて、均一で滑らかな状態の比重0.43±0.01のスポンジケーキ生地を調製した。
(4)前記(3)のスポンジケーキ生地を5号型に350g分注し、180℃のオーブンで30分間焼成し、スポンジケーキを得た。
(Manufacturing method of sponge cake)
(1) Lightly loosened whole eggs and sugar are placed in a mixer bowl and mixed with a whipper while maintaining the product temperature of the contents of the mixer bowl at 23 to 25 ° C., and the specific gravity of the contents is 0.26 ±. Whisk until 0.01.
(2) The mixed composition that has been sieved once with a sieve is added to the contents of the mixer ball of (1) above, and the mixture is uniformly mixed so as not to form lumps, and the specific gravity of the contents is 0.38. It was set to ± 0.01.
(3) Milk and butter melted together in a water bath are added to the contents of the mixer bowl of (2) above, and further mixed to make a sponge cake with a uniform and smooth specific density of 0.43 ± 0.01. The dough was prepared.
(4) 350 g of the sponge cake dough of the above (3) was dispensed into a No. 5 mold and baked in an oven at 180 ° C. for 30 minutes to obtain a sponge cake.

Figure 0006920241
Figure 0006920241

〔試験例3〕
実施例11及び比較例2のミックス組成物を用いて、ケーキ類の一種であるクッキーを下記方法により製造した。製造中間体であるクッキー生地の配合は下記の通り。
クッキー生地の配合:ミックス組成物100質量部、ベーキングパウダー0.5質量部、バター60質量部、砂糖45質量部、食塩0.5質量部、全卵18質量部
製造直後のクッキーを室温で60分放置した後、所定の製品ボックスに入れて蓋をして12時間以上保管した。訓練された専門のパネラー10名に、保管されていたクッキーの食感を下記評価基準で評価してもらった。その結果を10名の評価点の平均値として下記表4に示す。
[Test Example 3]
Using the mixed compositions of Example 11 and Comparative Example 2, cookies, which are a kind of cakes, were produced by the following method. The composition of the cookie dough, which is a manufacturing intermediate, is as follows.
Mixing of cookie dough: 100 parts by mass of mixed composition, 0.5 parts by mass of baking powder, 60 parts by mass of butter, 45 parts by mass of sugar, 0.5 parts by mass of salt, 18 parts by mass of whole egg 60 parts by mass of cookie immediately after production at room temperature After leaving it for a minute, it was placed in a predetermined product box, covered, and stored for 12 hours or more. We asked 10 trained professional panelists to evaluate the texture of the stored cookies according to the following evaluation criteria. The results are shown in Table 4 below as the average value of the evaluation points of 10 people.

(クッキーの製造方法)
(1)バター、砂糖及び食塩をミキサーボールに入れて、均一なクリーム状になるようにビーターで混合した。
(2)ほぐした全卵を前記(1)のミキサーボールの内容物に徐々に加えながら均一に混合し、該内容物の比重を0.82±0.02に調整した。
(3)ミックス組成物及びベーキングパウダーを予め篩で一度ふるい、かたまりが生じないように前記(2)の内容物に均一に混ぜ合わせてクッキー生地を得た。
(4)ミキサーボールからクッキー生地を取り出し、乾燥しないように所定のボックスに入れて、庫内温度5℃の冷蔵庫で一晩冷却保管した。
(5)冷却したクッキー生地を冷蔵庫から取り出し、麺棒で3mmの厚さに均一に延ばし、直径7cmのステンレス製円形型を用いて抜き、天板に等間隔に並べた。
(6)180℃に余熱したオーブンの庫内で前記(5)のクッキー生地を15分間焼成し、クッキーを得た。
(How to make cookies)
(1) Butter, sugar and salt were put in a mixer bowl and mixed with a beater so as to form a uniform cream.
(2) The loosened whole egg was uniformly mixed while gradually adding to the contents of the mixer bowl of (1) above, and the specific gravity of the contents was adjusted to 0.82 ± 0.02.
(3) The mixed composition and baking powder were sieved once in advance with a sieve and uniformly mixed with the contents of the above (2) so as not to form lumps to obtain a cookie dough.
(4) The cookie dough was taken out from the mixer bowl, placed in a predetermined box so as not to dry, and cooled and stored overnight in a refrigerator having an internal temperature of 5 ° C.
(5) The cooled cookie dough was taken out from the refrigerator, spread uniformly to a thickness of 3 mm with a rolling pin, pulled out using a stainless steel circular mold having a diameter of 7 cm, and arranged at equal intervals on the top plate.
(6) The cookie dough of (5) above was baked for 15 minutes in an oven preheated to 180 ° C. to obtain cookies.

<クッキーの食感の評価基準>
5点:口溶けがよく、且つ崩れるような脆さがあり、極めて良好。
4点:口溶けがややよく、且つ崩れるような脆さがややあり、良好。
3点:しっとり感若しくは口溶けにやや劣るか、又は崩れるような脆さがわずかであるが、問題ないレベル。
2点:しっとり感若しくは口溶けに劣るか、又は崩れるような脆さがなく、不良。
1点:しっとり感がなく、口溶けも悪く、崩れるような脆さもなく、極めて不良。
<Evaluation criteria for cookie texture>
5 points: Very good, with good melting in the mouth and brittleness that causes it to crumble.
4 points: Good because it melts in the mouth and has some brittleness that causes it to crumble.
3 points: Moist feeling, slightly inferior to melting in the mouth, or slight brittleness that causes it to crumble, but there is no problem.
2 points: Poor moistness or melting in the mouth, or no brittleness that causes it to crumble.
1 point: No moist feeling, poor melting in the mouth, no brittleness that collapses, and extremely poor.

Figure 0006920241
Figure 0006920241

Claims (7)

穀粉類を含有し、該穀粉類に、グルテンバイタリティ30〜52%の熱処理小麦粉と非熱処理国内産麦小麦粉とが含まれ、且つ該熱処理小麦粉の含有量が、該非熱処理国内産麦小麦粉の20〜500質量%であるミックス組成物。 It contains flours, and the flours contain heat-treated wheat flour having a gluten vitality of 30 to 52% and non-heat-treated domestic wheat flour, and the content of the heat-treated wheat flour is 20 to 20 to that of the non-heat-treated domestic wheat flour. A mixed composition of 500% by mass. 前記穀粉類における前記熱処理小麦粉の含有率が、10〜80質量%である請求項1に記載のミックス組成物。 The mixed composition according to claim 1, wherein the content of the heat-treated wheat flour in the flours is 10 to 80% by mass. 前記熱処理小麦粉が熱処理国内産麦小麦粉を含む請求項1又は2に記載のミックス組成物。 The mixed composition according to claim 1 or 2, wherein the heat-treated wheat flour contains heat-treated domestic wheat flour. 前記熱処理小麦粉における前記熱処理国内産麦小麦粉の含有率が、80質量%以上である請求項3に記載のミックス組成物。 The mixed composition according to claim 3, wherein the content of the heat-treated domestic wheat flour in the heat-treated wheat flour is 80% by mass or more. 前記穀粉類における前記熱処理国内産麦小麦粉と前記非熱処理国内産麦小麦粉との合計の含有率が、50質量%以上である請求項3又は4に記載のミックス組成物。 The mixed composition according to claim 3 or 4, wherein the total content of the heat-treated domestic wheat flour and the non-heat-treated domestic wheat flour in the flours is 50% by mass or more. ベーカリー食品用である請求項1〜5のいずれか1項に記載のミックス組成物。 The mixed composition according to any one of claims 1 to 5, which is for bakery foods. 前記ベーカリー食品が、マフィン、スポンジケーキ又はクッキーである請求項6に記載のミックス組成物。 The mixed composition according to claim 6, wherein the bakery food is a muffin, a sponge cake or a cookie.
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