JP6796013B2 - Oily makeup cosmetics - Google Patents

Description

The present invention relates to an oil-based make-up cosmetic that spreads well during application, is not sticky after application, and has a smooth feel and long-lasting makeup.

As oil-based make-up cosmetics, those that not only obtain a good feeling of use but also have excellent long-lasting cosmetic effect over time have been studied. For example, by combining crosslinked organopolysiloxane with organic silicone resin, volatile silicone, non-volatile liquid oil and powder with a specific particle size, a good feeling of use can be obtained and the cosmetic effect can be sustained. Durability by forming irregularities on the surface of the coating film and retaining the air film by combining excellent cosmetic technology (see Patent Document 1), non-volatile oil agent and water-repellent resin powder, oil-soluble silicone resin, volatile solvent, etc. There was a technique for cosmetics having excellent properties (see Patent Document 2).

Japanese Unexamined Patent Publication No. 2001-302456 WO2003 / 075863

However, the technique of Patent Document 1 is excellent in long-lasting makeup, but because it contains a large amount of organic silicone resin, it is not possible to obtain good spreadability at the time of application, and there is a large change in usability between the start of application and after application. Therefore, the burden on the skin was heavy, and a good usability could not be obtained. Further, in the technique of Patent Document 2, by containing a water-repellent resin powder or a water-repellent surface-treated powder, the water-sliding property and the water-repellent resistance are excellent, but a good usability cannot be obtained and the makeup lasts. It wasn't enough.

Therefore, an object of the present invention is to provide an oil-based cosmetic having excellent long-lasting makeup, good spreadability at the time of application, and a smooth feeling of use after application.

As a result of diligent studies, the present inventors have obtained a silicone resin powder, a volatile oil agent containing a non-volatile silicone having a viscosity of 5 to 50 centimeters at 25 ° C., an isododecane, and a film forming agent having a siloxane chain as a main chain. By combining and containing in a specific ratio, it spreads well at the start of application and has an excellent soft focus effect. Furthermore, the silicone resin powder absorbs non-volatile silicone and the volatile oil agent volatilizes, so that the oil agent becomes We have found that an oil-based make-up cosmetic that changes from a spreading feeling to a feeling of rolling powder on the skin and has a smooth feeling after application has been found, and has led to the completion of the present invention. It was.

That is, the present invention has the following components (A) to (D);
(A) Silicone resin powder (B) Non-volatile silicone having a viscosity of 5 to 50 cm Stokes at 25 ° C. (C) Volatile oil containing isododecane (D) Contains a silicone film-forming agent having a siloxane chain as the main chain. The content of the component (A) is 10 to 30% by mass, the content of the component (C) is 5 to 30% by mass, and the content of the component (D) is 1 to 10% by mass. The present invention provides an oil-based make-up cosmetic having a mass ratio of the component (A) to the component (B) of 1: 1 to 1: 6.

Further, the present invention provides an oil-based make-up cosmetic having an average particle size of the component (A) of 5 to 15 μm.

Further, it provides an oil-based make-up cosmetic in which the component (D) is one or more selected from trimethylsiloxysilicic acid and polymethylsilsesquioxane.

In addition, it provides oily make-up cosmetics that are any of blush, foundation, white powder, and concealer.

Further, the present invention provides an oil-based make-up cosmetic that is filled in a container with a coated body.

The oil-based make-up cosmetic of the present invention spreads well when applied, has an excellent soft focus effect, is not sticky after application, and has a smooth feel and long-lasting makeup.

Hereinafter, the present invention will be described in detail.

The oil-based make-up cosmetic of the present invention is a make-up cosmetic containing an oil-based component as a main component, and more specifically, a make-up cosmetic having an oil as a continuous phase.

The silicone resin powder of the component (A) used in the present invention has a three-dimensional crosslinked structure obtained by cross-linking an organopolysiloxane, and is, for example, a reticulated silicone, a crosslinked silicone, or a composite thereof. Examples thereof include silicone powders such as crosslinked silicone and reticulated silicone block copolymers, and in particular, from the viewpoint of obtaining a smooth feel after application, the co-weight of the crosslinked silicone and reticulated silicone block. A powder such as a coalescence is preferable.

By absorbing the component (B), the component (A) in the present invention changes from a feeling of use in which the oil agent spreads and spreads to a feeling of use in which powder is rolled on the skin. Therefore, the component (B) is more than its own weight. It is preferably a powder that can absorb oil. The oil absorption can be evaluated according to, for example, the measurement method of JIS K5101.
Further, the component (A) of the present invention preferably has an average particle size of 5 to 15 μm, more preferably 5 to 12 μm, from the viewpoint of obtaining good spreadability during application and a smooth feeling after application. preferable. The average particle size of the component (A) can be measured by the electric resistance method.

Specific examples of the component (A) include, for example, a (dimethicone / vinyldimethicone) crosspolymer, a (vinyldimethicone / methicone silsesquioxane) crosspolymer, represented by an INCI name (International Nomenclature Cosmetic Ingredient labeling names). Dimethicone / vinyldiphenyldimethicone / silsesquioxane) Cross-polymer and the like can be mentioned. Above all, from the viewpoint of obtaining a smooth feeling after application, (dimethicone / vinyldimethicone) crosspolymer, (vinyldimethicone / methicone silsesquioxane) crosspolymer, (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) ) Cross polymer or the like is preferable. Examples of commercially available products include KSP-100, 101, 102, 105, 300 (all manufactured by Shin-Etsu Chemical Co., Ltd.), Trefil E505, E506, E701 (all manufactured by Toray Dow Corning Co., Ltd.) and the like. .. Among them, KSP-100 (average particle diameter 5 μm), 101 (average particle diameter 12 μm) and the like are preferable.

The content of the component (A) used in the present invention is preferably 10 to 30% by mass (hereinafter abbreviated as%), and further 15 to 30% from the viewpoint of obtaining a smooth feel after application and a soft focus effect. More preferable.

The non-volatile silicone of the component (B) used in the present invention having a viscosity of 5 to 50 centimeters at 25 ° C. can be used without particular limitation as long as it is usually used for cosmetics. Specific examples thereof include dimethylpolysiloxane and methylphenylpolysiloxane. Examples of commercially available products include KF-96A-6CS, KF-96-10CS, KF-96-50CS, and KF-56 (all manufactured by Shin-Etsu Chemical Co., Ltd.).

In the present invention, when the component (A) absorbs the component (B), a change in the feeling of use at the start of application and after application can be obtained, and there is an action of imparting a smooth feeling of use after application. That is, the content of the component (B) is determined by the oil absorption amount of the component (A) in the present invention. Since the component (A) of the present invention absorbs the component (B), there is no stickiness peculiar to oil-based makeup cosmetics, and a smooth feeling of use can be obtained after application.

The content mass ratio of the component (A) and the component (B) used in the present invention is from the viewpoint that the component (A) absorbs the component (B), and the spread and spread are good and the feeling of use after application is smooth. A: B = 1: 1 to 1: 6 is preferable, and 1: 1 to 1: 5 is more preferable.

The volatile oil agent containing isododecane of the component (C) used in the present invention requires isododecane and is volatile at 25 ° C. The component (C) of the present invention may be used only with isododecane, or may be used in combination with isododecane and other volatile oil agents. The ingredient (C) of the present invention can be used without particular limitation as long as it is usually used in cosmetics. Specifically, for example, in addition to isododecane, volatile hydrocarbon oils such as light liquid isoparaffin, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyltrimethicone, caprylyltrimethicone, dimethylpolysiloxane, decamethyltetra. Examples thereof include volatile silicone oils such as siloxane and ethyltrisiloxane, and one or more of these may be contained. As commercially available products, as light liquid isoparaffin, Isopar H (manufactured by Esso Chemical Co., Ltd.), ISODODECANE (manufactured by IMCD (INEOS OLIGOMERS)), Isohexadecane (manufactured by Unichema), IP Solvent 1620MU, IP Solvent 2028MU, IP Solvent 2835 ( All are manufactured by Idemitsu Kosan Co., Ltd.), TSF405 (manufactured by Toshiba Silicon Co., Ltd.), SH245, DC345 (manufactured by Toray Doukoning Co., Ltd.), KF-995 (manufactured by Shin-Etsu Chemical Co., Ltd.), and methyl as decamethylcyclopentasiloxane. Silicon TMF-1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.) as trimeticon, KF-96L-2CS (manufactured by Shin-Etsu Chemical Co., Ltd.) as dimethylpolysiloxane, KF-96L-1 as decamethyltetrasiloxane .5CS (manufactured by Shin-Etsu Chemical Co., Ltd.) and SILSOFT ETS (manufactured by Momentive Performance Materials) as ethyltrisiloxane.

The content of the component (C) used in the present invention is preferably 5 to 30%, more preferably 7 to 20%, from the viewpoint of good spreadability and a change in usability at the start of application and after application. .. The content of isododecane in the component (C) is preferably 30 to 100%, more preferably 60 to 100%.

The silicone film forming agent having the siloxane chain of the component (D) used in the present invention as the main chain has an organopolysiloxane structure as the main chain and has a continuous linear or branched structure, and is crosslinked. You may be doing it. The film formation in the present invention is not particularly limited as long as it forms a film, but a solution prepared by dissolving 40% of a silicone resin in a soluble solvent is applied to a glass plate with a 400 μm-thick applicator and at room temperature. It means that a film is formed after drying for 24 hours, and it is a component used especially for improving the longevity of makeup. Specific examples of the component (D) of the present invention include trimethylsiloxysilicic acid and polymethylsilsesquioxane. The trimethylsiloxysilicic acid is represented by [(CH ₃ ) ₃ SiO _1/2 ] x [SiO ₂ ] y (X is 1 to 3, Y is 0.5 to 8), and is a polymethylsil. The sesquioxane has a structure consisting of _1.5 units of R ¹ SiO and _0.5 units of R ² SiO (in the formula, it represents a substituted or unsubstituted monovalent hydrocarbon group). As commercially available products, as trimethylsiloxysilicic acid, silicon X-21-5250 (50% decamethylcyclopentasiloxane solution), KF-7312T (60% methyltrimethicone solution), KF-7312J (50% decamethylcyclo). Pentasiloxane solution), KF-7312K (60% dimethicone solution), KF-9021 (50% decamethylcyclopentasiloxane solution) (all manufactured by Shinetsu Chemical Industry Co., Ltd.), SR1000 (manufactured by Momentive Performance Materials Japan) )), Examples of polymethylsilsesquioxane include SILFORM FLEXIBLE RESIN (manufactured by Momentive Performance Materials Japan).

The content of the component (D) used in the present invention is preferably 1 to 10%, more preferably 3 to 8%, from the viewpoint of makeup retention and soft focus effect.

The oil-based make-up cosmetic of the present invention may contain an aqueous component such as water or a polyhydric alcohol, but in order not to impair the effects of the present invention, the content of the aqueous component is substantially water of 1% or less. It does not include.

The oil-based make-up cosmetic of the present invention is not particularly limited, but may have various properties and product forms depending on the intended purpose. Examples of the properties include liquid and semi-solid, and from the viewpoint of good spreadability during coating, solid oil is preferably 1% or less, and more preferably liquid at 25 ° C. As the product form, for example, cheek, foundation, white powder, concealer and the like can be used, and cheek and foundation are more preferable in terms of exerting the effects of the present invention.

The form of the oil-based make-up cosmetic of the present invention is not particularly limited, and various forms can be used. For example, a container with an applicator, a bottle container, a jar container, a resin plate, a gold plate, a compact container or other dish-shaped container, a tube container, or a dispenser container in which an applicator such as a gloss tip or a brush is provided on the lid of the container. And so on. In particular, since the present invention contains volatile oil, a highly airtight one is preferable. In addition, a container with a coating body is suitable because it can be applied directly to the skin and does not stain the hands.

In addition to the above components (A) to (D), the outer layer portion of the present invention contains oily components other than the components (B) to (D) and powders other than (A) as long as the effects of the present invention are not impaired. , Surfactants, aqueous components, UV absorbers, moisturizers, antioxidants, cosmetological components, preservatives, pigments, fragrances and other commonly known components can be contained.

The oily components include hydrocarbons, fats and oils, hydrogenated oils, ester oils, fatty acids, regardless of the properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc. originating from animal oils, vegetable oils, synthetic oils, etc. Classes, higher alcohols, silicone oils, fluorooils, lanolin derivatives and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, polyisobutylene and polybutene, fats and oils such as olive oil, castor oil, mink oil and macadamian nut oil, jojoba oil, cetyl 2-ethylhexaneate and tri2- Glyceryl ethylhexanoate, diglyceryl isostearate, diglyceryl diisostearate, diglyceryl triisostearate, diglyceryl tetraisostearate, isotridecyl isononanoate, isostearyl lactate, octyldodecyl lactate, oleyl lactate, stearyl lactate, diisostearyl malate , Isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, pentaerythrite rosinate, neopentyl glycol dioctanoate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, phytosterol fatty acid ester and other esters, stearic acid, lauric acid. , Fatty acids such as myristic acid, behenic acid, isostearic acid, oleic acid, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, high polymerization degree methylphenylpolysiloxane, cross-linked type Methylpolysiloxane, polyoxy-modified organopolysiloxane, cross-linked polyether-modified methylpolysiloxane, methacryl-modified polysiloxane, stearyl-modified methylpolysiloxane, oleyl-modified methylpolysiloxane, behenyl-modified methylpolysiloxane, polyvinylpyrrolidone-modified methylpolysiloxane, high Degree of Polymerization Silicones such as dimethylpolysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, alkoxy-modified polysiloxane, crosslinked organopolysiloxane, fluorine-modified polysiloxane, perfluorodecane, perfluorooctane, Fluoro oils such as perfluoropolyether, lanolin derivatives such as lanolin, lanolin acetate, lanolin fatty acid isopropyl, and lanolin alcohol can be mentioned, and one or more of these can be used.

As the powder, if it is a powder generally used for cosmetics, it has a spherical shape, a plate shape, a needle shape, etc., a smoke atom shape, fine particles, a pigment grade particle size, a porous particle, a non-porous particle, etc. The structure is not particularly limited, and examples thereof include inorganic powders, glittering powders, organic powders, pigment powders, metal powders, and composite powders. Specifically, for example, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered products, chromium oxide, chromium hydroxide, dark blue, ultramarine, etc. Colored inorganic pigments, talc, white mica, gold mica, red mica, black mica, synthetic mica, silk mica (serisite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide, magnesium oxide , Zirconium oxide, clay, aluminum silicate, aluminum magnesium metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride and other white constituent powders, titanium dioxide coating Mica, titanium dioxide-coated bismuth oxychloride, iron oxide-treated mica titanium, navy blue-treated mica titanium, carmine-treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene Bright powder such as terephthalate / polymethylmethacrylate laminated film powder, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene-acrylic copolymer resin Synthetic resins such as synthetic resins such as, polypropylene resins, organic polymer resin powders such as urethane resins, organic low molecular weight powders such as zinc stearate and N-acyllysine, natural organic powders such as silk powder and cellulose powder, red 201 Organic pigment powders such as No., Red No. 202, Red No. 205, Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Black No. 401, Brown No. 201, Purple 401 No., Blue No. 1, Blue No. 2, Blue No. 203, Blue No. 205, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Green No. 401, Green No. 402, Yellow No. 4, Yellow No. 5, Yellow No. 202 (1), Yellow No. 202 (2), Yellow No. 203, Yellow No. 402, Yellow No. 403 (1), Yellow No. 406, Yellow No. 407, Orange 205, Orange 402, Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1), Red No. 106, Red No. 227, Red No. 230 (1), Red No. 231, Red No. 401, Red No. 502, Red Zirconium, barium or aluminum such as 503, red 504, red 506, etc. Organic pigment powder such as Mureki, metal powder such as aluminum powder, gold powder, silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, zinc oxide containing dioxide Examples thereof include composite powders such as silicon, and one or more of these powders can be used. If necessary, fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, etc. Surface treatment may be performed by a known method using collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants and the like, or a compounded product may be used.

The surfactant is not particularly limited as long as it is a surfactant generally used in cosmetics, such as a nonionic surfactant, an anionic surfactant, a cationic surfactant, and an amphoteric surfactant. Can be used. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, Examples thereof include polyether-modified organopolysiloxane and lecithin.

The aqueous component may be any component that is soluble in water, and in addition to water, for example, alcohols such as ethyl alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol, tripropylene glycol, etc. Examples thereof include glycols such as polyethylene glycol, glycerols such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.

Examples of the ultraviolet absorber include benzophenone-based, PABA-based, silicic acid-based, and salicylic acid-based ultraviolet absorbers, such as 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, and paramethoxycineric acid 2. -Ethylhexyl, 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, hexyl diethylaminohydroxybenzoyl benzoate, bisethylhexyloxyphenol methoxyphenyl triazine, etc. Be done.

Examples of the moisturizing agent include proteins, mucopolysaccharides, collagen, elastin, keratin and the like, examples of the antioxidant include α-tocopherol, ascorbic acid and the like, and examples of the beauty ingredient include vitamins. , Anti-inflammatory agents, crude drugs and the like, and examples of preservatives include paraoxybenzoic acid ester, phenoxyethanol, 1,2-pentanediol and the like.

The method for producing an oil-based make-up cosmetic of the present invention is not particularly limited, but for example, the components (A) to (D) and other arbitrary components are uniformly mixed and dispersed, and the container is filled with the components (A) to (D). Can be obtained.

Hereinafter, the present invention will be described in detail with reference to examples. It should be noted that these do not limit the present invention in any way.
Examples 1 to 13, Comparative Examples 1 to 10: Oily teak (container with coating body)
Adjust the oily cheeks having the compositions shown in Tables 1 to 4 below. Smooth feeling after application, b. Good spread and spread, c. Have makeup, d. The soft focus effect is evaluated by the following evaluation method, and the evaluation results are shown in Tables 1 to 4.

* 1: KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 2: KSP-101 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 3: KSP-300 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 4: Ganz Pearl GMI-0804 (manufactured by Aica Kogyo Co., Ltd.)
* 5: Silicone TMF-1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 6: SILFORM FLEXIBLE RESIN (manufactured by Momentive Performance Materials Japan)
* 7: Silicone KP-543 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A. Ingredients (5) to (16) are uniformly mixed.
B. (1) to (4) and (17) to (24) are added to A, and the mixture is uniformly mixed and dispersed.
C. B was filled in a container with a coating body to obtain an oily teak.

(Evaluation methods)
For the following items (a) to (d), each sample was tested for use by 10 specialized panels. Regarding a, it was evaluated according to the following criteria whether the feeling of use in which the oil agent spreads and spreads at the start of application changes to a smooth feeling of use in which the powder rolls on the skin after application. With regard to (b) and (c), each panel evaluated and scored on a five-point scale according to the following absolute criteria, and the average value was calculated from the total score of all the panels and judged according to the following criteria. Regarding b, the good spreadability at the time of application was evaluated. Regarding c, after applying each sample and having the panel live a normal life, it was evaluated whether or not the cosmetic film had collapsed 6 hours later. Regarding d, it was evaluated according to the following criteria whether or not the decorative film was finished as a mat and the unevenness was corrected to make it inconspicuous.

(Evaluation item)
I. Smooth usability after application Judgment criteria (judgment)
◎: Feel the change in usability at the start of application and after application
A smooth feeling of use can be obtained. ○: There is a change in the feeling of use at the start of application and after application.
No smooth feel is obtained △: There is a change in usability between the start of application and after application,
It doesn't fit well and feels sticky. ×: No change in usability between the start of application and after application
It doesn't fit well and feels sticky

(Evaluation item)
B. Good growth and spread c. Makeup

Absolute evaluation criteria (score): (evaluation)
5: Very good 4: Good 3: Normal 2: Bad 1: Very bad Judgment criteria (judgment): (Average score)
◎: More than 4 points: Very good ○: More than 2.5 points and 4 points or less: Good △: More than 1 point and 2.5 points or less: Slightly defective ×: 1 point or less: Defective

(Evaluation item)
D. Soft focus effect Judgment criteria (judgment)
◎: The decorative film is finished on the mat and the unevenness is corrected. ○: The decorative film is not finished on the mat, but the unevenness is corrected. △: The decorative film is not finished on the mat and the unevenness is not sufficiently corrected. Can be seen ×: The decorative film is not finished on the mat, and unevenness is conspicuous.

As is clear from the results in Tables 1 to 4, the oil-based teak of the examples spreads well during application, has a non-greasy and smooth feel after application, has a long-lasting makeup, and has an excellent soft focus effect. there were. On the other hand, in Comparative Example 1 in which the content of the component (A) is different, the oil absorption of the component (B) by the component (A) is insufficient, so that a smooth feeling of use after application cannot be obtained, and the soft focus effect is obtained. I wasn't satisfied with it. Further, in Comparative Example 2 which does not contain the component (A), since the oil absorption of the component (B) by the component (A) is insufficient, a smooth feeling of use after application cannot be obtained, and the good spreadability is satisfied. I couldn't get anything. Further, in Comparative Example 3 in which the content mass ratio of the component (A) and the component (B) does not satisfy 1: 1 to 1: 6, the oil absorption of the component (B) by the component (A) is insufficient, and therefore after application. I couldn't get a smooth feeling of use, and I couldn't get a satisfactory soft focus effect. In Comparative Examples 4 and 5 which did not contain the component (B), a smooth feeling of use after application was not obtained, and a satisfactory one was not obtained in terms of good spreadability during application. In Comparative Example 6 which does not contain the component (C) isododecane and Comparative Example 7 in which the content of the component (C) is different, neither of them gives a smooth feeling of use after application and is satisfied with the good spreadability during application. I couldn't get anything. Comparative Example 8 in which the component (D) is excessively contained is sticky from the time of application, and good spreadability at the time of application cannot be obtained, and a product having a smooth feel after application cannot be obtained. It was. Further, in Comparative Examples 9 and 10 which did not contain the component (D), none of them had makeup and was not satisfactory in the soft focus effect.

Example 14: Oil-based foundation (shaking type bottle container)
Fraction (%)
(1) (Vinyldimethicone / methicone silsesquioxane)
Cross polymer * 1 7
(2) (Vinyldimethicone / methicone silsesquioxane)
Cross polymer * 2 3
(3) Dimethylpolysiloxane (6 mm ² / s, 25 ° C) 50
(4) Isododecane 7
(5) Decamethylcyclopentasiloxane 7
(6) Trimethylsiloxysilicic acid 3
(7) Ethylhexyl methoxycinnamate 3
(8) Ethanol 7
(9) PEG-9 Polydimethylsiloxyethyl Dimethicone 0.3
(10) Isotridecyl isononanoate Remaining amount (11) Avocado oil 0.1
(12) Tocopherol 0.1
(13) Zinc oxide (average particle size 25 nm) 1
(14) Titanium oxide (average particle size 270 nm) 6
(15) Yellow iron oxide 1
(16) Black iron oxide 0.1
(17) Bengala 0.5
(18) Boron Nitride 0.5
(19) Talc 0.5

(Production method)
A. Ingredients (3) to (12) are uniformly mixed.
B. (1) to (2) and (13) to (19) are added to A, and the mixture is uniformly mixed and dispersed.
C. B was filled in a shaking container to obtain an oil-based foundation.

The obtained oil-based foundation had excellent long-lasting makeup, good spreadability during application, a smooth feel after application, and an excellent soft focus effect.

Example 15: Oil-based concealer (glass jar container)
Fraction (%)
(1) (Vinyldimethicone / methicone silsesquioxane)
Cross polymer * 1 15
(2) Dimethylpolysiloxane (50 mm ² / s, 25 ° C) 15
(3) Isododecane 5
(4) Polymethylsilsesquioxane * 6 8
(5) Heavy liquid isoparaffin 3
(6) 1,3-Butylene bricol 3
(7) Lecithin 0.5
(8) Glyceryl tri2-ethylhexanoate Remaining amount (9) Dextrin palmitate 1.5
(10) Cholesterol 0.1
(11) Zinc oxide 5
(12) Titanium oxide 15
(13) Iron oxide 1
(14) Plate-shaped barium sulfate 1
(15) Mica 20
(16) Silica 1

(Production method)
A. The components (8) and (9) are heated to 80 ° C. and uniformly mixed and dissolved.
B. (1) to (7) and (10) to (16) are added to A, and the mixture is uniformly mixed and dispersed at room temperature.
C. B was filled in a glass jar to obtain an oil-based concealer.

The obtained oil-based concealer had excellent long-lasting makeup, good spreadability during application, a smooth feel after application, and an excellent soft focus effect.

Example 16: Oily white powder (dispenser tube container)
Fraction (%)
(1) (Vinyldimethicone / methicone silsesquioxane)
Cross polymer * 1 30
(2) Dimethylpolysiloxane (6 mm ² / s, 25 ° C) 30
(3) Isododecane 10
(4) Methyltrimethicone (boiling point 191 ° C) * 5 10
(5) Trimethylsiloxysilicic acid 1
(6) Ethylhexyl methoxycinnamate 3
(7) Phenoxyethanol 0.5
(8) Isotridecyl isononanoate Remaining amount (9) N-stearoyldihydrosphingosine 0.1
(10) Jojoba oil 0.1
(11) Boron Nitride 1
(12) Talc 8
(13) Lauroyl lysine 2
(14) Titanium oxide coated mica 2

(Production method)
A. Ingredients (2) to (10) are uniformly mixed.
B. (1), (11) to (14) are added to A, and the mixture is uniformly mixed and dispersed.
C. B was filled in a dispenser tube container to obtain an oily white powder.

The obtained oil-based white powder had excellent long-lasting makeup, good spreadability during application, a smooth feel after application, and an excellent soft focus effect.

Claims (5)

The following components (A) to (D);
(A) Silicone resin powder (B) Contains a volatile oil agent (D) a film-forming agent having a siloxane chain as a main chain, which contains a non-volatile silicone (C) isododecane having a viscosity of 5 to 50 cm Stokes at 25 ° C. The content of the component (A) is 10 to 30% by mass, the content of the component (C) is 5 to 30% by mass, and the content of the component (D) is 1 to 10% by mass. An oil-based make-up cosmetic having a mass ratio of the component (A) to the component (B) of 1: 1 to 1: 6. The oily make-up cosmetic according to claim 1, wherein the average particle size of the component (A) is 5 to 15 μm. The oily make-up cosmetic according to claim 1 or 2, wherein the component (D) is one or more selected from trimethylsiloxysilicic acid and polymethylsilsesquioxane. The oily make-up cosmetic according to any one of claims 1 to 3, which is one of cheek, foundation, white powder, and concealer. The oily make-up cosmetic according to any one of claims 1 to 4, which is filled in a container with a coated body.