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JP6499990B2 - Electrolyzed water generator - Google Patents

Electrolyzed water generator Download PDF

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JP6499990B2
JP6499990B2 JP2016065631A JP2016065631A JP6499990B2 JP 6499990 B2 JP6499990 B2 JP 6499990B2 JP 2016065631 A JP2016065631 A JP 2016065631A JP 2016065631 A JP2016065631 A JP 2016065631A JP 6499990 B2 JP6499990 B2 JP 6499990B2
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濱村 圭一
圭一 濱村
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島崎電機株式会社
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この発明は各種の洗浄用及び殺菌・消毒用として使用される電解水生成装置に関する。 This invention relates to electrolytic aquatic NaruSo location to be used for cleaning and disinfection of the various.

従来例えば特許文献1及び非特許文献1に示される電解水生成装置のように、陰極,陽極の電極間にイオン交換膜を介して食塩水等の電解液(電解質溶液)を循環させる中間室(電解液室)を設け、その両側に水を供給排出させる陰極室(カソード室)と陽極室(アノード室)を形成し、陰極室と陽極室からナトリウムイオン水(還元水)と塩素イオン水(酸化水)をそれぞれ取出して洗浄水又は殺菌水として使用する3室型電解システムが知られている。そして上記還元水及び酸化水は1室型(無隔膜)電解システム又は2室型電解システムによって得られるアルカリ水や酸性水と比較してイオン活性力が高く、優れた洗浄力や殺菌力、脱臭・脱色作用を備えていることが知られており、特に高還元水又は高酸化水と称されている。   Conventionally, as in the electrolyzed water generators disclosed in, for example, Patent Document 1 and Non-Patent Document 1, an intermediate chamber in which an electrolyte solution (electrolyte solution) such as saline is circulated between the cathode and anode electrodes via an ion exchange membrane ( An electrolyte chamber is provided, and a cathode chamber (cathode chamber) and an anode chamber (anode chamber) for supplying and discharging water are formed on both sides of the chamber, and sodium ion water (reduced water) and chlorine ion water ( There is known a three-chamber electrolysis system in which (oxidized water) is taken out and used as washing water or sterilizing water. The reduced water and oxidized water have higher ionic activity than alkaline water and acidic water obtained by a one-chamber (separate membrane) electrolysis system or a two-chamber electrolysis system, and have excellent detergency, sterilization power, and deodorization. -It is known to have a decolorizing action, and is particularly called highly reduced water or highly oxidized water.

特許第3793114号公報Japanese Patent No. 3793114

http://www.redox.co.jp/?page_id=9(3室型電解システムのしくみ)http://www.redox.co.jp/?page_id=9 (How the three-chamber electrolysis system works)

しかし上記の従来の3室型の電解槽を用いた装置では、電解液(食塩水)を電解質タンクと電解槽の中間室との間で循環させるために、電解液中に塩酸が生成され(H+Cl→2HCl)且つ蓄積される(濃度が高くなる)ため、電解水生成装置の周辺に塩酸ガス(塩化水素)による強い刺激臭が充満し、電解水の生成場所や使用する作業空間、その他の居住スペース等の環境の悪化を招くほか、各種機器類や取扱い品に酸化や腐蝕による損傷、故障等を生じさせ又は機器類の耐久性を損ねるという欠点がある。 However, in the apparatus using the conventional three-chamber type electrolytic cell, hydrochloric acid is generated in the electrolytic solution in order to circulate the electrolytic solution (saline solution) between the electrolytic tank and the intermediate chamber of the electrolytic cell ( (H 2 + Cl 2 → 2HCl) and accumulated (concentration becomes higher), the area around the electrolyzed water generator is filled with a strong irritating odor due to hydrochloric acid gas (hydrogen chloride), and the electrolyzed water is generated and used in the working space. In addition to deteriorating the environment such as other living spaces, there are drawbacks in that various devices and products handled are damaged or broken by oxidation or corrosion, or the durability of the devices is impaired.

他方、前記高還元水や高酸化水はその洗浄力や殺菌力に優れているため、医療施設や介護福祉施設等における手指の洗浄や除菌等に使用される例があるが、既述のように強い塩酸臭や塩酸ガスの影響が懸念されて生成された電解水を容器に移して貯留したものが使用されていた。   On the other hand, since the highly reduced water and highly oxidized water are excellent in detergency and sterilizing power, there are examples used for washing and sterilization of fingers in medical facilities and care welfare facilities. In this way, the electrolyzed water produced by fearing the influence of strong hydrochloric acid odor and hydrochloric acid gas was transferred to a container and stored.

また従来の電解装置は、各種機器類やシーツ類の洗浄、洗濯や殺菌等に使用されるため電解槽や塩水(電解質)タンクも大型で全体として大型であるため、洗面所や施設の入口等に簡単に設置して、一般のユーザーや来訪者等の利用に供する電解水を電解装置から直接供給する装置は市販されておらず、その提供が望まれていた。   In addition, since conventional electrolyzers are used for cleaning, washing, sterilizing, etc. of various equipment and sheets, the electrolytic tank and salt water (electrolyte) tank are large and large as a whole. However, an apparatus that directly supplies electrolyzed water for use by general users, visitors, and the like from an electrolyzer is not commercially available, and the provision thereof has been desired.

上記課題を解決するための本発明の電解水生成装置は、第1に電解槽1を酸性水を生成する酸性電解槽1Aと還元水を生成する還元電解槽1Bとに分離して形成し、各電解槽1A,1Bに陰イオン透過性の隔膜3aと陽イオン透過性の隔膜3bとをそれぞれ介して一対の陽電極8aと陰電極8bを対応させて配置し、両電極8a,8bの一方の側に電解液を導入排出する電解液室4a,4bを形成し、他方の側に水を導入排出して酸性水又は還元水を生成させる陽極室6又は陰極室7のいずれかを形成し、電解液である食塩水を貯留し且つ各電解液室4a,4bに接続して循環供給する塩水タンクを設けてなる電解水生成装置において、左右方向に横長で天板及び周壁により外部より遮蔽されたボックス状のケースの41内に密閉状態で閉蓋できる蓋付きの前記塩水タンク2を設け、上記ケース41内の塩水タンク2の底部に電解液循環駆動用のポンプ11を取付け固定し、前記ケース41内の他方の端部にはプレート状に組合された電解槽1を左右方向に設置し、上記電解槽1と塩水タンク2間の電解液循環用の配管と同電解槽1の陰極室7と陽極室6の給排水用の配管を前記ケース41内に密閉状態で収納させてなることを特徴としている。 Electrolytic aquatic NaruSo location of the present invention for solving the aforementioned problems is formed by separating the electrolytic cell 1 to the first in a reduction electrolysis tank 1B to generate an acidic electrolytic bath 1A and reduced water generating acid water A pair of positive electrode 8a and negative electrode 8b are arranged in each electrolytic cell 1A, 1B through an anion permeable diaphragm 3a and a cation permeable diaphragm 3b, respectively. Electrolyte chambers 4a and 4b for introducing and discharging the electrolyte are formed on one side, and either the anode chamber 6 or the cathode chamber 7 for introducing and discharging water to generate acidic water or reduced water is formed on the other side. In the electrolyzed water generating apparatus comprising a salt water tank that stores salt water that is an electrolytic solution and that circulates and connects to each of the electrolytic solution chambers 4a and 4b. Closed in a sealed state in a shielded box-shaped case 41 The salt water tank 2 with a lid is provided, an electrolyte circulation driving pump 11 is attached and fixed to the bottom of the salt water tank 2 in the case 41, and the other end in the case 41 is combined in a plate shape. The electrolytic cell 1 is installed in the left-right direction, and the piping for circulating the electrolyte between the electrolytic cell 1 and the salt water tank 2 and the water supply / drainage piping of the cathode chamber 7 and the anode chamber 6 of the electrolytic cell 1 are provided in the case 41. It is characterized by being housed in a sealed state .

に、陰極室7と陽極室6に接続される各排出配管に、ケース41の外部に取付けられる還元水と酸化水の各取出管18a,18bに接続し、還元水と酸化水手指洗浄及び手指消毒用であることを特徴としている。 Second, the discharge pipe connected to the cathode chamber 7 and the anode chamber 6, the take-out tube 18a of reduced water and acid water attached to the outside of the case 41, connects to 18b, acid water and reducing water finger It is used for cleaning and hand sanitization.

に、電解槽1の陰極室7及び陽極室6への給水配管をケース41の外部からの水道配管に接続し、両室に水道水を供給することを特徴としている。 Third, it is characterized by connecting the water supply pipe to the cathode chamber 7 and an anode compartment 6 of the cell 1 to the water supply pipe from the outside of the outside case 41, to supply the tap water to both chambers.

に、電解槽1の陰極室7及び陽極室6への給水配管と接続され、両室への供給水を貯留して必要に応じて給水する給水タンク66をケース41に設置し、携帯移動可能に構成したことを特徴としている。 Fourth, it is connected to the water supply pipe to the cathode chamber 7 and an anode compartment 6 of the cell 1, established the water supply tank 66 to the water supply to according to the need by storing the water supplied to both chambers to the case 41, the portable It is configured to be movable.

以上のように構成される本発明によれば、塩水タンクと電解槽間を循環する電解質にNaHCO ,CaCO,KCO等の抑制剤を添加することにより、電解質中の塩酸の蓄積が抑制され、電解液から塩酸が蒸散することによる塩酸臭の発生や塩酸ガスの発生が抑制され、塩酸臭による環境問題や塩酸ガスによる周辺機器等の損傷、故障や耐久性の低下等が防止できる。 According to the onset bright configured as described above, by adding NaHCO 3, CaCO 3, K inhibitors such as 2 CO 3 in the electrolyte circulating between brine tank and the electrolytic cell, the hydrochloric acid in the electrolyte Accumulation is suppressed, generation of hydrochloric acid odor and hydrochloric acid gas due to evaporation of hydrochloric acid from the electrolyte is suppressed, environmental problems due to hydrochloric acid odor, damage to peripheral equipment, etc. due to hydrochloric acid gas, failure, deterioration of durability, etc. Can be prevented.

電解槽を酸性電解槽と還元電解槽にとに分けて形成した装置では、酸性水と還元水を互いに他方に影響されることなく単独で、しかも自由な品質調整が可能な状態で取出し供給ができる利点がある。   In an apparatus formed by dividing the electrolytic cell into an acidic electrolytic cell and a reducing electrolytic cell, the acidic water and the reduced water can be taken out and supplied independently without being influenced by each other and in a state where free quality adjustment is possible. There are advantages you can do.

また電解水生成のための電解槽,電解質タンク配管等を外部から遮蔽して小型化した電解水生成装置のケース内に設置することで、医療施設、介護・福祉施設、学校その他の施設の手洗所,洗面所出入り口等の公衆の居住空間における手指消毒用としても問題なく容易に設置、採用でき、電解水生成装置から直接電解水を供給して利用できる利点がある。   In addition, by installing the electrolyzer for generating electrolyzed water, the electrolyte tank piping, etc. inside the case of the electrolyzed water generating device that is miniaturized by shielding it from outside, hand washing of medical facilities, nursing / welfare facilities, schools and other facilities It can be easily installed and adopted without any problems for hand sanitization in public living spaces such as entrances and exits of toilets and toilets, and has the advantage of being able to supply and use electrolyzed water directly from the electrolyzed water generator.

本発明の方法の実施に用いる電解水生成装置の基本構成を示す配線・配管図である。It is a wiring and piping diagram which shows the basic composition of the electrolyzed water generating apparatus used for implementation of the method of this invention. 本発明装置の正面断面図である。It is front sectional drawing of this invention apparatus. 本発明装置の平面図である。It is a top view of this invention apparatus. 本発明装置の右側面図である。It is a right view of this invention apparatus. 本発明装置のディスプレイに示される表示内容とその流れの1例を示す説明図である。It is explanatory drawing which shows an example of the display content shown on the display of this invention apparatus, and its flow. 食塩水のみの電解液と重曹を添加した本発明方法の電解液での実施結果をpH値その他の計測値で対比した表である。It is the table | surface which compared the implementation result with the electrolyte solution of the method of this invention which added the electrolyte solution and sodium bicarbonate only of salt solution with pH value and other measured values. 本発明装置の他の実施例を示す配線・配管図である。It is a wiring and piping figure which shows the other Example of this invention apparatus.

以下本発明の実施形態につき図1に示す基本構成につき説明する。ちなみに図1の電解水生成装置の電解槽と塩水(電解質)タンク等の構成及びその作動原理は前記特許文献1及び非特許文献1と共通するものである。 The following described embodiments Nitsu away view 1 of the present invention will indicate to basic configuration. Incidentally, the configurations and operating principles of the electrolytic tank and the salt water (electrolyte) tank of the electrolyzed water generating device of FIG. 1 are the same as those in Patent Document 1 and Non-Patent Document 1.

この装置は3室型の電解槽1と該電解槽1に電解質(液)となる食塩水を貯留して循環供給する塩水タンク2を備えており、電解槽1は縦長でプレート状の直方体(ブロック状)に形成されており、その中央には左右のイオン透過性の隔膜(陰イオン交換膜3a,陽イオン交換膜3b)に仕切られた縦長の中間室(電解液室)4が形成され、さらにその左右両側には陽極室6と陰極室7が形成されている。上記各隔膜3の外側に沿って通水性を備えたシート状の陽,陰の各電極8a,8bが設けられている。   This apparatus includes a three-chamber type electrolytic cell 1 and a salt water tank 2 that stores and circulates a salt water as an electrolyte (liquid) in the electrolytic cell 1 for circulation. The electrolytic cell 1 is a vertically long plate-shaped rectangular parallelepiped ( A vertically long intermediate chamber (electrolyte chamber) 4 partitioned by left and right ion-permeable diaphragms (anion exchange membrane 3a, cation exchange membrane 3b) is formed at the center. Further, an anode chamber 6 and a cathode chamber 7 are formed on both the left and right sides. Sheet-like positive and negative electrodes 8a and 8b having water permeability are provided along the outer sides of the respective diaphragms 3.

塩水タンク2と中間室4の上下の間は食塩水(電解質)を循環させる循環路(配管)9a,9bで接続され、塩水タンク2下部と中間室4の上部を接続する供給側循環路9aには、食塩水を循環供給するポンプ11と流量調節用のバルブ12とが順次設けられている。また塩水タンク2の下部には、塩水タンク2内の塩水が繰り返し使用の結果電解機能が低下した時点で、食塩水を交換するために排出するドレンバルブ13付のドレン管14が設置されている。16は塩水タンク2に設けられた食塩水のレベルを検出するレベルセンサーである。   The upper and lower sides of the salt water tank 2 and the intermediate chamber 4 are connected by circulation paths (piping) 9 a and 9 b for circulating salt water (electrolyte), and the supply side circulation path 9 a connecting the lower part of the salt water tank 2 and the upper part of the intermediate chamber 4. Are sequentially provided with a pump 11 for circulating and supplying a saline solution and a valve 12 for adjusting the flow rate. In addition, a drain pipe 14 with a drain valve 13 is provided at the lower part of the salt water tank 2 to discharge the salt water when the salt water in the salt water tank 2 is repeatedly used and the electrolytic function is reduced. . Reference numeral 16 denotes a level sensor that detects the level of the salt solution provided in the salt water tank 2.

また陽極室6と陰極室7の下部には水道水を供給する給水管17より分岐した分岐管17a,17bがそれぞれ接続され、同じく両室6,7の上部には各室で生成された電解水(プラスイオンが溶け込む高還元水とマイナスイオンが溶け込む高酸化水)を取出すための取出管18a,18bがそれぞれ接続され、各取出管18a,18bの先端側には噴出ノズル又は噴出ノズルを兼ねた噴出口(いずれも図示しない)が設けられている。   Further, branch pipes 17a and 17b branched from a water supply pipe 17 for supplying tap water are connected to the lower part of the anode chamber 6 and the cathode chamber 7, respectively. Extraction pipes 18a and 18b for taking out water (highly reduced water in which positive ions are dissolved and high oxidized water in which negative ions are dissolved) are connected to each other, and the front ends of the respective extraction pipes 18a and 18b also serve as an ejection nozzle or an ejection nozzle. A spout (not shown) is provided.

上記給水管17には、上流側からメインバルブ19,減圧弁21,給水(ON,OFF)用電磁バルブ22が順次設けられ、各分岐管17a,17bには流量調節用のバルブ23a,23bがそれぞれ設けられている。また給水回路17側又は取出管18a,18bのいずれかに取出水を温水化(例えば35℃に)するための加温装置(図示しない)を設けてもよい。   A main valve 19, a pressure reducing valve 21, and a water supply (ON, OFF) electromagnetic valve 22 are sequentially provided in the water supply pipe 17 from the upstream side, and flow control valves 23a, 23b are provided in the branch pipes 17a, 17b. Each is provided. Moreover, you may provide the heating apparatus (not shown) for warming extraction water (for example, to 35 degreeC) to either the water supply circuit 17 side or extraction pipe 18a, 18b.

次に上記電解槽1内の電解作動及び給排水,電解水取出しその他の制御を行うための電気系統について説明すると、電源は100VのAC電源が使用され、電解電極8a,8bに接続される電解回路24と各種の作動制御に使用される制御回路26とに分岐されている。   Next, a description will be given of an electric system for performing electrolysis operation and supply / drainage, electrolyzed water extraction and other controls in the electrolyzer 1. The electrolysis circuit uses a 100V AC power source and is connected to the electrolysis electrodes 8a and 8b. 24 and a control circuit 26 used for various operation controls.

電解回路24は電極8a,8bにDC電源を付与するためその末端は陽電極8a,陰電極8bに接続されるが、基端部側よりメインスイッチ27,コンバーター(電解電源)28,電極切換用の切換スイッチ29が介設されている。上記コンバーター28はAC−DC変換のほか、例えばDC出力電圧を12Vに変圧し6Aの定電流で出力する機能を備えている。ここで定電流で出力するのは、電解負荷に応じて電圧を変化させるためのものである。また切換スイッチ29は電解作動の継続によって各電極に付着するスケールを上記切換によって分離除去するために設けられている。   Since the electrolytic circuit 24 applies DC power to the electrodes 8a and 8b, the ends thereof are connected to the positive electrode 8a and the negative electrode 8b, but the main switch 27, the converter (electrolytic power source) 28, and electrode switching are connected from the base end side. The changeover switch 29 is interposed. In addition to AC-DC conversion, the converter 28 has a function of, for example, transforming a DC output voltage to 12 V and outputting it at a constant current of 6A. The output at a constant current here is for changing the voltage according to the electrolytic load. The changeover switch 29 is provided to separate and remove the scale adhering to each electrode by the continuation of the electrolytic operation.

他方、制御回路26側には、例えばDC24Vで30Wの出力を行う制御電源用のコンバーター31が設けられ、その出力側にはポンプ11や給水電磁バルブ22、その他の機器やスイッチ類を入力信号に応じて制御するためのプログラムを備えた制御装置32が設けられている。   On the other hand, on the control circuit 26 side, for example, a converter 31 for control power source that outputs 30 W at 24 VDC is provided, and on the output side, the pump 11, the water supply electromagnetic valve 22, and other devices and switches are used as input signals. A control device 32 provided with a program for controlling accordingly is provided.

上記装置に示す構成は最小限のものを示すもので、装置の運転上、例えば後述する給水作動を開始させるための光センサー,スイッチ類その他の機器類や回路は示されておらず、上記以外の運転上求められる各種電装品等は必要に応じて設置されるものである。   The configuration shown in the above device shows a minimum, and for the operation of the device, for example, optical sensors, switches and other devices and circuits for starting the water supply operation described later are not shown. Various electrical components and the like required for the operation are installed as necessary.

また図1に示す装置の電解槽1の構造と機能及び使用方法を含めて基本的には特許文献1に示すものと共通しているが、後述するようにこれを手指洗浄・消毒用として介護施設,病院,食堂その他各種の施設の出入口や洗面所,便所等のように公衆も出入りする場所で簡単に使用するために、小型化するに当り出力や電解処理能力は適宜変更される。   Further, the structure, function and usage of the electrolytic cell 1 of the apparatus shown in FIG. 1 are basically the same as those shown in Patent Document 1, but this is used for hand washing and disinfection as described later. In order to use it easily in places where the public enters and exits, such as entrances, toilets, toilets, etc. of facilities, hospitals, cafeterias and other various facilities, the output and electrolytic treatment capacity are appropriately changed as the size is reduced.

次に上記装置を用いて電解水を生成する本発明の方法につき説明すると、本発明の方法において、イオン透過性の隔膜3をそれぞれ備えた陰電極8bと陽電極8a間に設けられた電解槽1の中間室4と、電解液としての食塩水を収容する塩水タンク2との間で電解液を循環させて中間室に電解液を供給し、上記中間室4の両側に設けた前記電解槽1の陰極室7と陽極室6にそれぞれ水を供給排出することにより高還元水及び高酸化水を生成する点は前記従来従来の方法と共通している。   Next, the method of the present invention for generating electrolyzed water using the above apparatus will be described. In the method of the present invention, an electrolytic cell provided between the negative electrode 8b and the positive electrode 8a each provided with an ion-permeable diaphragm 3. The electrolytic bath provided on both sides of the intermediate chamber 4 by circulating the electrolytic solution between the intermediate chamber 4 of 1 and a salt water tank 2 containing a saline solution as an electrolytic solution. The point that high reduced water and high oxidized water are generated by supplying and discharging water to and from the cathode chamber 7 and the anode chamber 6 is the same as the conventional method.

しかし既述のように3室型電解水生成装置による方法では、食塩水の電気分解に伴って生じる塩酸が陰極側の電解水として取出されるだけでなく、中間室から塩水タンク2内に戻され、さらに電解の継続と共に塩水タンク2内に貯留されて高濃度になる。このため既述のような各種の不都合が生じる。   However, as described above, in the method using the three-chamber electrolyzed water generating apparatus, hydrochloric acid generated by the electrolysis of the salt water is not only taken out as electrolyzed water on the cathode side, but also returned to the salt water tank 2 from the intermediate chamber. Furthermore, it is stored in the salt water tank 2 along with the continuation of electrolysis, resulting in a high concentration. For this reason, various disadvantages as described above occur.

これに対し本発明では塩水タンク2に投入する食塩水に塩酸ガス(塩化水素)の発生を抑制する塩酸ガス抑制剤を添加するものである。後述する実施例では塩酸ガス抑制剤として炭酸水素ナトリウム(NaHCO)が使用されているが、例えば炭酸カルシウム(CaCO)又は炭酸カリウム(KCO)のように炭酸イオン(CO (2−))を含む物質であれば、これらのケースでは塩酸と反応して、それぞれ食塩(NaCl),塩化カルシウム(CaCl)又は塩化カリウム(KCl)のいずれかと水及び二酸化炭素が生成され、塩酸の残留や蓄積が防止又は抑制できる。 In contrast in this onset bright it is to add inhibit hydrochloric acid gas inhibitor generation of hydrochloric acid gas (hydrogen chloride) in saline to be introduced into the brine tank 2. In the examples described later, sodium hydrogen carbonate (NaHCO 3 ) is used as a hydrochloric acid gas inhibitor, but for example, carbonate ions (CO 3 (2 ) such as calcium carbonate (CaCO 3 ) or potassium carbonate (K 2 CO 3 ). -) ), In these cases, it reacts with hydrochloric acid to produce either sodium chloride (NaCl), calcium chloride (CaCl 2 ) or potassium chloride (KCl), water and carbon dioxide, respectively. Can be prevented or suppressed.

以下本発明装置の実施例につき図1〜図5に基き説明する。図2〜図4は本発明の装置の正面断面図,平面図,右側面図を示し、装置は各種使用施設内のテーブル上や洗面所,便所等に配置又は設置するために全体として小型化が図られ、例えば横幅165,高さ355,奥行400(mm),重量8kg程度に納められている。ちなみにこの実施例の装置は後述する表1の手指洗浄用(小型)電解槽の欄に示すものが対象となっている。   Embodiments of the present invention will be described below with reference to FIGS. 2 to 4 show a front sectional view, a plan view, and a right side view of the apparatus of the present invention, and the apparatus is reduced in size as a whole to be placed or installed on a table, a washroom, a toilet, etc. in various use facilities. For example, the width is 165, the height is 355, the depth is 400 (mm), and the weight is about 8 kg. By the way, the apparatus of this embodiment is the one shown in the column of the hand washing (small) electrolytic cell in Table 1 described later.

装置は中空ボックス状のケース41内に収納されており、周壁は左右壁42,43と中底(板)44,下部底46及び天板47とが一体的な剛体として組立形成されており、天板47と中底44の間には各種の機器類や電装品を配置し内部スペースの大半を占める本体室48が形成され、中底44と下部底46との間には主として外部の給水管17を導入する配管室49が形成されており、中底(板)44には同配管及び塩水タンク2からのドレン管14を通すための配管孔51が形成されている。   The device is housed in a hollow box-shaped case 41, and the peripheral wall is formed by assembling a rigid body integrally with left and right walls 42, 43, an insole (plate) 44, a lower bottom 46 and a top plate 47, A main body chamber 48 that occupies most of the internal space is formed between the top plate 47 and the midsole 44, and a main body water 48 is mainly disposed between the midsole 44 and the lower bottom 46. A pipe chamber 49 for introducing the pipe 17 is formed, and a pipe hole 51 for allowing the drain pipe 14 from the pipe and the salt water tank 2 to pass through is formed in the middle bottom (plate) 44.

この例ではケース41の左側壁42は平板で構成されているが、右側壁43は山型に半円形の円弧状断面に湾曲形成されており、その上端側には周壁が当該円弧と同心円に形成された塩水タンク2が一体的に形成されている。そして上記右側壁43の前後の端部と左側壁42との間には正面側と背面側の長方形の開口部を密閉状に塞ぐ前後のカバー52,53が着脱可能に取付けられており、この前後の開口部を通じて本体室48内に各種機器類を取付け及び取外し又はこれらの操作や設定及びメンテナンス等を行う機構となっている。   In this example, the left side wall 42 of the case 41 is formed of a flat plate, but the right side wall 43 is formed in a mountain shape and curved in a semicircular arc-shaped cross section, and the peripheral wall is concentric with the arc at the upper end side. The formed salt water tank 2 is integrally formed. Between the front and rear ends of the right side wall 43 and the left side wall 42, front and rear covers 52 and 53 for sealing the front and rear rectangular openings in a sealed manner are detachably attached. Various mechanisms are attached to and detached from the main body chamber 48 through the front and rear openings, or a mechanism for performing these operations, settings, maintenance, and the like.

本体室48内の片側(左側)中心位置には3室型で直方体形状の電解槽1が中底44上に固定して取付けられており、右側の塩水タンク2の底面側には開閉蓋付の塩水ポンプ11が取付固定されている。この塩水ポンプ11は塩水タンク2の底面にジョイント管55を介して取付け固定されているほか、必要に応じ下部側をブラケット(図示しない)等を介して中底44側に補強的に支持する機構としてもよい。   A three-chamber type rectangular parallelepiped electrolytic cell 1 is fixedly mounted on the midsole 44 at a central position on one side (left side) in the main body chamber 48, and an open / close lid is provided on the bottom side of the salt water tank 2 on the right side. The salt water pump 11 is attached and fixed. The salt water pump 11 is attached and fixed to the bottom surface of the salt water tank 2 via a joint pipe 55, and a mechanism for supporting the lower side on the side of the insole 44 via a bracket (not shown) or the like as needed. It is good.

前記右側壁43の内側で塩水タンク2の下方には、後述する表示装置54が右外向きに右側壁43に取付けられており、表示装置54の外側には右側壁43の外側にディスプレイ56が設けられ、このディプレイ56は図示するように右側壁43の半円形の右外側に形成された平面的な凹部57に表示装置54を嵌合して取付けることによって外表面に露出している。   A display device 54 to be described later is attached to the right wall 43 outwardly to the right inside the right side wall 43 and below the salt water tank 2. A display 56 is provided outside the right side wall 43 outside the display device 54. The display 56 is exposed to the outer surface by fitting and attaching the display device 54 to a flat recess 57 formed on the right side of the right side wall 43 as shown in the figure.

本体室48内の略中央位置で電解槽1の背面側には、全体の制御用の電源となるコンバーター31が中底44上に取付けられて設置され、さらに電解槽1の上部には取付棚58が左右方向に設置され、その上部の天板47との間には電解作動用の電源となるコンバーター28が取付棚58に取付けて設置されている。また塩水ポンプ11の下方で前方寄りの中底44上には電極切換スイッチ29が取付け配置されている。   A converter 31 serving as an overall control power source is mounted and installed on the inner bottom 44 on the back side of the electrolytic cell 1 at a substantially central position in the main body chamber 48. 58 is installed in the left-right direction, and a converter 28 serving as a power source for electrolytic operation is installed on the mounting shelf 58 between the top plate 47 on the upper side. An electrode changeover switch 29 is mounted on the inner bottom 44 near the front under the salt water pump 11.

右側壁43のディスプレイ取付用の凹部57の下方中心位置には、外部に露出するように内部から差込状態で取付けられるセンサー59が設けられ、利用者が外側よりこのセンサー59に手をかざすことにより、取出管18bと18aより洗浄水と除菌水が順次定量ずつ排出される。   A sensor 59 that is attached in an inserted state from the inside so as to be exposed to the outside is provided at the lower center position of the display mounting recess 57 on the right side wall 43, and the user holds the hand over the sensor 59 from the outside. Thus, the washing water and the sterilizing water are sequentially discharged from the extraction pipes 18b and 18a one after another.

天板47上には前後に振分けて除菌水と洗浄水の取出管18a,18bがそれぞれ取付けられ、各種取出管18a,18bはいずれも塑性変形可能な金属製のらせん管であり、さらに天板47の前後中心位置で右寄り位置にはブラケット61が突設され、このブラケット61と左側壁42の上部突出端との間には、左右方向の棒状の把手62が横設され、装置の持ち運び時に把手として使用される。   Distributing pipes 18a and 18b for sterilizing water and washing water are attached to the top plate 47 in the front-rear direction, and the various taking-out pipes 18a and 18b are metal spiral pipes that can be plastically deformed. A bracket 61 projects from the front and rear center position of the plate 47 to the right, and a left and right bar-shaped handle 62 is laterally disposed between the bracket 61 and the upper projecting end of the left side wall 42 to carry the device. Sometimes used as a handle.

電解槽1の前後両壁の下部位置には、陰極室7と陽極室6に電解水生成用の水を供給する配管(ホース)17a又は同17bの接続口63aが、同上部位置には取出管18a又は同18bと接続される生成水取出用の接続口63bがそれぞれ設けられ、さらに前後方向中央の中間室4の左側の上部位置には塩水タンク2からの食塩水の供給(循環)配管9aを接続する接続口64aが、同右側の下部位置には使用済の電解液(塩水)を塩水タンク2に返送する(循環)配管9bを接続する接続口64bがそれぞれ設けられている。   A pipe (hose) 17a for supplying water for generating electrolyzed water to the cathode chamber 7 and the anode chamber 6 or a connection port 63a of the same 17b is taken out at the lower position of both the front and rear walls of the electrolytic cell 1 and taken out at the upper position. A connecting port 63b for removing the generated water connected to the pipe 18a or 18b is provided, and a salt water supply (circulation) pipe from the salt water tank 2 is provided at the upper left position of the middle chamber 4 at the center in the front-rear direction. A connection port 64a for connecting 9a is provided at a lower position on the right side, and a connection port 64b for connecting a piping 9b for returning (circulating) the used electrolyte (salt water) to the salt water tank 2 is provided.

そして給水管17から分岐する分岐管17a,17b,循環配管9a,9b及び各種電装機器類の配線(ハーネス)配置はケース41内の本体室48内の空間を利用して行われ、この本体室48は少なくとも周面及び上面は(できる限り底面側も)密閉状態で外部と遮蔽されており、内部のガスが外部に洩れない構造となっている。   The branch pipes 17a and 17b branching from the water supply pipe 17 and the circulation pipes 9a and 9b and wiring (harness) of various electrical equipments are arranged using the space in the main body chamber 48 in the case 41. 48 has a structure in which at least the peripheral surface and the top surface (as much as possible on the bottom surface side) are shielded from the outside in a sealed state, and the internal gas does not leak outside.

なお、図1〜図4は、電解生成水用の水を水道管と接続し、水道圧を利用して洗浄水、除菌水を取出す例につき述べたが、図2,図4のケース41下部の仮想線で示すように、配管室49を設けないでこれより大容積の給水タンク66をケース41の下部に一体的に設け、給水口67より給水して貯留し、給水タンク66内又は本体室48内に設けた給水ポンプ(図示しない)により、電解槽1の陽極室6及び陰極室7に給水することができる。このタイプの装置は水道管と接続する必要がないため、水道管のない場所でも使用でき、任意の場所に携帯移動できる利点がある。   1 to 4 describe an example in which water for electrolytically generated water is connected to a water pipe, and washing water and sterilized water are taken out using water pressure, but the case 41 in FIGS. As indicated by the lower phantom line, the water supply tank 66 having a larger volume than that of the pipe chamber 49 is integrally provided at the lower portion of the case 41 without being provided with the piping chamber 49, and is supplied and stored through the water supply port 67. Water can be supplied to the anode chamber 6 and the cathode chamber 7 of the electrolytic cell 1 by a water supply pump (not shown) provided in the main body chamber 48. Since this type of device does not need to be connected to a water pipe, it can be used even in places where there is no water pipe, and has the advantage that it can be carried around anywhere.

図5は表示装置54のディスプレイ56に表示される指示内容と流れの1例で、利用者はこの指示に従って洗浄、除菌を行うことができ、電解液が繰り返し使用によって電解機能が一定以下に低下した時は、交換の手順を表示して電解液の交換をさせる内容となっている。   FIG. 5 is an example of the instruction content and flow displayed on the display 56 of the display device 54. The user can perform cleaning and sterilization according to this instruction, and the electrolytic function is kept below a certain level by repeatedly using the electrolyte. When the voltage drops, the replacement procedure is displayed and the electrolyte is replaced.

ちなみに図1に示す装置を用いて生成した電解水で、大腸菌,カンジダ菌,サルモネラ菌,セレウス菌,緑膿菌,レジオネラ菌,黄色ブドウ球菌について洗浄と除菌の実験を行った結果では、洗浄水(100%)を用いたケースで、添加1分後,5分後,10分後の菌数は緑膿菌ではすべてで陰性、セレウス菌では急減しながら10分後のみ陰性、その他は経時に伴い若干減少を示すものの大きな殺菌効果は認められていない。   1 (100%), 1 minute, 5 minutes, and 10 minutes after addition, the number of bacteria was negative for Pseudomonas aeruginosa, negative for Bacillus cereus, negative only after 10 minutes, others over time Although it shows a slight decrease, a large bactericidal effect is not recognized.

これに対し、除菌水(100%)と除菌水(50%)と水道水(50%)のものは、各経過時間ともにすべて陰性であった(島根県環境保険公社実験)。
そして前記本実施例の方法による電解水もこれらと略同様の結果が得られた。
In contrast, the sterilized water (100%), the sterilized water (50%), and the tap water (50%) were all negative for each elapsed time (Shimane Environmental Insurance Corporation experiment).
The electrolyzed water produced by the method of this example also gave substantially the same results.

介護者や看護師は1日20〜30回と頻繁に手洗を行うが、アルコールやイソジン消毒による場合が多いが、これらのケースでは肌荒れを免れない。これに対し、島根大学医学部皮膚科・産学共同研究センターにおける実験によれば、4週間後の比較で本発明方法による洗浄水、除菌水では肌荒れを確実に防ぐことができた。   Caregivers and nurses frequently wash their hands 20 to 30 times a day, but often use alcohol or isodine disinfection, but in these cases, rough skin is unavoidable. On the other hand, according to the experiment at the Department of Dermatology and Industry-Academia Research, Shimane University School of Medicine, it was possible to reliably prevent rough skin with the washing water and the sterilizing water according to the method of the present invention in comparison after 4 weeks.

次に先に述べた本発明の方法を、例えば病院、介護施設等の衣類その他の洗濯用又は洗浄用として用いられる図1に示す在来の大型の業務用電解水生成装置(「業務用装置」)と、図1〜図4に示す本発明の小型の手指洗浄用電解水生成装置(「手指用装置」)を用いた実施例につき説明する。表1は上記2種類の装置の仕様を示している。   Next, the above-described method of the present invention is applied to the conventional large commercial electrolyzed water generating device (“business device” shown in FIG. 1 used for washing or washing clothes such as hospitals and nursing care facilities. )) And an example using the small-sized hand-washing electrolyzed water generating device (“hand device”) of the present invention shown in FIGS. 1 to 4. Table 1 shows the specifications of the two types of devices.

Figure 0006499990
Figure 0006499990

図6は上記2種類の装置を用いて、それぞれ飽和食塩水と、食塩と重曹(炭酸水素ナトリウム)を3:7の割合で添加した溶液とで電解水を生成した場合の電解液(食塩水),除菌水,洗浄水の水素イオン濃度(pH),酸化還元電位(ORP),塩素濃度(ppm)の計測値の経時変化を示した表である。   FIG. 6 shows an electrolyte solution (saline solution) in the case where electrolyzed water is produced using a saturated saline solution and a solution to which sodium chloride and sodium bicarbonate (sodium bicarbonate) are added at a ratio of 3: 7, respectively, using the above two types of devices. ), Sterilized water, washing water hydrogen ion concentration (pH), redox potential (ORP), chlorine concentration (ppm) is a table showing the change over time.

表1によればいずれの装置の場合も、塩水タンク内の電解質のpH値を除いてはいずれの対象水の測定値にも有意な差が認められないのに対し、業務用装置,手指用装置共に食塩水に重曹を添加したものでは食塩水と比較してpH値が高く中性化又は弱アルカリ化していることが明らかである。   According to Table 1, there is no significant difference in the measured value of any target water except for the pH value of the electrolyte in the salt water tank in any of the devices. It is clear that both the devices were obtained by adding sodium bicarbonate to saline and having a high pH value compared to saline and neutralizing or weakly alkalizing.

即ち、業務用装置の場合の塩水タンク内の電解質では、後者のpH値が0.88〜1.41の強い酸性を示す(塩酸濃度が高い)のに対し、前者のpH値は7.25〜8.50の中性乃至は弱酸性に留まる(塩酸がない)ことが明らかである。
また手指用装置の場合も同様に飽和食塩水ではpH値が0.22〜1.15の強酸を示すのに対し、重曹を添加したものでは7.82〜10.35の中性乃至弱アルカリ性であること、即ち塩酸を含まないことが明らかである。なお、食塩と重曹の配合比は塩化水素の発生量,電解質の総量,電解液の使用量等を考慮して適宜決定される。
That is, in the electrolyte in the salt water tank in the case of a commercial apparatus, the latter pH value shows strong acidity of 0.88 to 1.41 (high hydrochloric acid concentration), whereas the former pH value is 7.25. It is clear that it remains neutral or weakly acidic (no hydrochloric acid) at ~ 8.50.
Similarly, in the case of a device for fingers, saturated saline shows a strong acid having a pH value of 0.22 to 1.15, whereas a sodium salt added is 7.82 to 10.35 neutral to weakly alkaline. It is clear that it does not contain hydrochloric acid. The mixing ratio of sodium chloride and sodium bicarbonate is appropriately determined in consideration of the amount of hydrogen chloride generated, the total amount of electrolyte, the amount of electrolyte used, and the like.

図7は本発明の方法に使用され、特に手指洗浄・消毒用と使用する際に、洗浄水(還元水)と除菌水(酸化水)とを異なるタイミングで各別に取出すのに適した構成の装置として提供するものである。即ち図1に示す装置では1台の3室型電解槽1で洗浄水と除菌水を提供しているために、いずれか一方の電解水を生成して取出すと必ず他方の電解水も生成される結果、一方のみを使用した時は他方の水を無駄に廃棄することになるほか、酸とアルカリの濃度(pH)も一方が決まれば他方もこれに対応して自動的に決められる等、他方に対し一方を調整することができないという問題があった。   FIG. 7 is used in the method of the present invention, and particularly suitable for taking out washing water (reduced water) and disinfecting water (oxidized water) separately at different timings when used for hand washing / disinfection. It is provided as a device. That is, in the apparatus shown in FIG. 1, since the washing water and the sterilizing water are provided by a single three-chamber electrolysis tank 1, when one of the electrolyzed water is generated and taken out, the other electrolyzed water is always generated. As a result, when only one of them is used, the other water is wasted, and when one of the acid and alkali concentrations (pH) is determined, the other is automatically determined accordingly. However, there is a problem that one cannot be adjusted with respect to the other.

この実施例は上記課題に対応するもので、図7に示すように電解槽1を除菌水生成用の電解槽(酸性電解槽)1Aと洗浄水生成用の電解槽(還元電解層)1Bとに分けて形成している。各電解槽1A,1Bがイオン透過性の隔膜8a又は8bに近接して配置される陽電極8aと陰電極8bを挿入し、その両側に電解水となる水を導入排出して電解水生成室(陽極室6又は陰極室7)を形成している点と、各電解液室4a,4bが塩水タンク2と接続されて食塩水が循環しながら供給される点は共通している。   This embodiment corresponds to the above-described problem. As shown in FIG. 7, the electrolytic cell 1 is divided into an electrolytic cell (acidic electrolytic cell) 1A for generating sterilized water and an electrolytic cell (reducing electrolytic layer) 1B for generating cleaning water. It is divided and formed. Each electrolytic cell 1A, 1B is inserted with a positive electrode 8a and a negative electrode 8b, which are arranged close to the ion-permeable diaphragm 8a or 8b, and water to be electrolyzed water is introduced into and discharged from both sides to generate an electrolyzed water generation chamber. The point which forms (the anode chamber 6 or the cathode chamber 7) and the point which each electrolyte solution chamber 4a, 4b is connected with the salt water tank 2, and is supplied while circulating a salt solution are common.

他方で両電解槽1A,1Bは、酸性電解槽1A側の隔膜3aが陰イオン交換膜であって陽電極8a側に陽極室6が形成され、陰電極8b側に電解液室4aが形成されているのに対し、還元電解槽1B側は隔膜3bが陽イオン交換膜であり、陰電極8b側に陰極室7が形成され、陽電極8b側に電解液室4bが形成されている点が異なる。換言すれば、この例で示す装置は図1に示す3室型の装置の電解液室(中間室)4を左右に2分割して4a,4bとし、両電解液室4a,4bそれぞれに塩水を循環供給する機構であり、電解水生成機能は3室型の装置と略同一である。   On the other hand, in both electrolytic cells 1A and 1B, the diaphragm 3a on the acidic electrolytic cell 1A side is an anion exchange membrane, the anode chamber 6 is formed on the positive electrode 8a side, and the electrolyte chamber 4a is formed on the negative electrode 8b side. In contrast, the diaphragm 3b is a cation exchange membrane on the reducing electrolytic cell 1B side, the cathode chamber 7 is formed on the negative electrode 8b side, and the electrolyte chamber 4b is formed on the positive electrode 8b side. Different. In other words, in the apparatus shown in this example, the electrolyte chamber (intermediate chamber) 4 of the three-chamber type apparatus shown in FIG. 1 is divided into left and right parts 4a and 4b, and each of the electrolyte chambers 4a and 4b has salt water. The electrolyzed water generation function is substantially the same as that of the three-chamber type device.

また上記構成に対応して各電極室6,7に接続される給水分岐管17a,17bの上流側にはそれぞれ電磁バルブ22a,22bが各別に設けられている点,2つの電解液室4a,4bには循環路9a,9bが分岐して接続されるとともに給液側の循環路9aの各分岐管には各別に流量調節用のバルブ12a,12bがそれぞれ設けられている点,各電解槽1A,1Bに対して電解回路24a,24bが分岐されて接続されるとともに、電解回路24a,24bに分岐されたことに伴い電極切換用の切換スイッチが同29a,29bに示すように2段階に分けて設置され、両電解槽1A,1Bの電極が各別に選択操作できるようになっている点とが、図1の電解水生成装置と異なる点である。上記相違点以外で図1の装置と共通する符号は同図のものと共通の機能を持つ部分又は部品を表している。   Corresponding to the above configuration, electromagnetic valves 22a and 22b are provided on the upstream side of the water supply branch pipes 17a and 17b connected to the electrode chambers 6 and 7, respectively, the two electrolyte chambers 4a, 4b is connected to the circulation passages 9a and 9b in a branched manner, and each branch pipe of the circulation passage 9a on the liquid supply side is provided with valves 12a and 12b for adjusting the flow rate, respectively. Electrolytic circuits 24a and 24b are branched and connected to 1A and 1B, and the switch for switching electrodes is divided into two stages as shown in 29a and 29b along with branching to electrolytic circuits 24a and 24b. 1 is different from the electrolyzed water generating device of FIG. 1 in that the electrodes of both electrolytic cells 1A and 1B can be selected and operated separately. Except for the above differences, reference numerals common to the apparatus of FIG. 1 represent parts or parts having the same functions as those of the apparatus of FIG.

図7に示す装置は上記のように構成される結果、酸性電解槽1Aと還元電解槽1Bとでは、酸性水(除菌水)と還元水(洗浄水)が互いに独立して他方に影響されることなく各別に生成され、いずれか単独でも生成取出しできる利点があり、また両生成水のpH濃度や流量等を使用目的に応じて独自に調節することもでき、手指洗浄・消毒用の装置としても適している。   The apparatus shown in FIG. 7 is configured as described above. As a result, in the acidic electrolyzer 1A and the reducing electrolyzer 1B, acidic water (sanitized water) and reduced water (washing water) are influenced by the other independently. There is an advantage that it can be generated separately and can be generated and taken out independently, and the pH concentration and flow rate of both product water can be adjusted independently according to the purpose of use, and it is a device for hand washing and disinfection Also suitable.

なお、この実施例においても電解質である食塩水は塩水タンク2に貯留され且つ電解槽1A,1Bとの間で循環しているので、塩水タンク2に塩酸ガスの発生を抑制する抑制剤を供給することにより塩酸ガスの発生を抑制することが可能であることは勿論である。   In this embodiment as well, since the salt water as the electrolyte is stored in the salt water tank 2 and circulates between the electrolytic cells 1A and 1B, an inhibitor that suppresses the generation of hydrochloric acid gas is supplied to the salt water tank 2. Of course, the generation of hydrochloric acid gas can be suppressed.

この発明の装置は洗浄と除菌を行う各種作業に利用ができ、且つ装置の製造はそれ自体が工業的な生産に適するものである。 Equipment of the present invention can utilize the various operations of cleaning and disinfection, and manufacture of the device is one which itself suitable for industrial production.

1 電解槽
1A 酸性電解槽
1B 還元電解槽
2 塩水タンク
3 隔膜(イオン交換膜)
3a 陰イオン交換膜
3b 陽イオン交換膜
4 中間室(電解液室)
4a,4b 電解液室
6 陽極室
7 陰極室
8a 陽電極
8b 陰電極
11 ポンプ
18a,18b 取出管
41 ケース
66 給水タンク
DESCRIPTION OF SYMBOLS 1 Electrolysis tank 1A Acidic electrolysis tank 1B Reduction electrolysis tank 2 Salt water tank 3 Diaphragm (ion exchange membrane)
3a anion exchange membrane 3b cation exchange membrane 4 intermediate chamber (electrolyte chamber)
4a, 4b Electrolyte chamber 6 Anode chamber 7 Cathode chamber 8a Positive electrode 8b Negative electrode 11 Pump 18a, 18b Extraction pipe 41 Case 66 Water supply tank

Claims (4)

電解槽(1)を酸性水を生成する酸性電解槽(1A)と還元水を生成する還元電解槽(1B)とに分離して形成し、各電解槽(1A),(1B)に陰イオン透過性の隔膜(3a)と陽イオン透過性の隔膜(3b)とをそれぞれ介して一対の陽電極(8a)と陰電極(8b)を対応させて配置し、両電極(8a),(8b)の一方の側に電解液を導入排出する電解液室(4a),(4b)を形成し、他方の側に水を導入排出して酸性水又は還元水を生成させる陽極室(6)又は陰極室(7)のいずれかを形成し、電解液である食塩水を貯留し且つ各電解液室(4a),(4b)に接続して循環供給する塩水タンクを設けてなる電解水生成装置において、左右方向に横長で天板及び周壁により外部より遮蔽されたボックス状のケースの(41)内に密閉状態で閉蓋できる蓋付きの前記塩水タンク(2)を設け、上記ケース(41)内の塩水タンク(2)の底部に電解液循環駆動用のポンプ(11)を取付け固定し、前記ケース(41)内の他方の端部にはプレート状に組合された電解槽(1)を左右方向に設置し、上記電解槽(1)と塩水タンク(2)間の電解液循環用の配管と同電解槽(1)の陰極室(7)と陽極室(6)の給排水用の配管を前記ケース(41)内に密閉状態で収納させてなる電解水生成装置。 The electrolytic cell (1) is formed separately into an acidic electrolytic cell (1A) that generates acidic water and a reducing electrolytic cell (1B) that generates reduced water, and each electrolytic cell (1A) and (1B) has an anion. A pair of positive electrode (8a) and negative electrode (8b) are arranged in correspondence with each other through a permeable membrane (3a) and a cation permeable membrane (3b), respectively, and both electrodes (8a), (8b) ) Forming an electrolytic chamber (4a), (4b) for introducing and discharging an electrolytic solution on one side of the anode chamber (6) or generating an acidic water or reduced water by introducing and discharging water on the other side forming one of the cathode chamber (7), the electrolyte storing the brine is and each electrolyte chamber (4a), (4b) Ru electrodeposition name provided water tank circulation supplies connected to Kaisui in the production apparatus, the left-right direction in a horizontally long in the top plate and the box-like case which is shielded from the outside by a peripheral wall (41) The salt water tank (2) with a lid that can be closed in a sealed state is provided, and a pump (11) for driving electrolyte circulation is attached and fixed to the bottom of the salt water tank (2) in the case (41). (41) An electrolytic cell (1) combined in a plate shape is installed at the other end in the left-right direction, and a pipe for circulating the electrolyte between the electrolytic cell (1) and the salt water tank (2) An electrolyzed water generating apparatus in which the water supply / drain piping of the cathode chamber (7) and the anode chamber (6) of the electrolytic cell (1) is stored in a sealed state in the case (41) . 陰極室(7)と陽極室(6)に接続される各排出配管に、ケース(41)の外部に取付けられる還元水と酸化水の各取出管(18a),(18b)に接続し、還元水と酸化水手指洗浄及び手指消毒用である請求項に記載の手指洗浄・消毒用の電解水生成装置。 Each discharge pipe connected to the cathode chamber (7) and the anode chamber (6) is connected to each extraction pipe (18a), (18b) of reducing water and oxidized water attached to the outside of the case (41). water and oxidation water electrolytic water generation apparatus for hand washing and disinfection of claim 1 which is used for hand wash and hand disinfection. 電解槽(1)の陰極室(7)及び陽極室(6)への給水配管をケース(41)の外部からの水道配管に接続し、両室に水道水を供給する請求項に記載の手指洗浄・消毒用の電解水生成装置。 Connect the electrolytic cell cathode chamber (1) (7) and the anode chamber the water supply piping to (6) Case (41) to a water pipe from the outside of the outside, according to claim 2 for supplying tap water to the chambers Electrolyzed water generator for washing and disinfecting fingers. 電解槽(1)の陰極室(7)及び陽極室(6)への給水配管と接続され、両室への供給水を貯留して必要に応じて給水する給水タンク(66)をケース(41)に設置し、携帯移動可能に構成した請求項に記載の手指洗浄・消毒用の電解水生成装置。 A water supply tank (66) connected to the water supply piping to the cathode chamber (7) and the anode chamber (6) of the electrolytic cell (1) and storing the supply water to both chambers and supplying water as required is provided with a case (41 The electrolyzed water generating device for washing and disinfecting hands according to claim 2 , wherein the electrolyzed water generating device is configured to be portable and movable.
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