JP5709167B2 - Gel cleansing cosmetic - Google Patents

Description

  The present invention relates to a gel cleansing cosmetic.

  Cleansing cosmetics are high cleansing bases mainly containing oily ingredients and surfactants, and lotions, oils, creams, emulsions, etc. are marketed. ing.

  However, conventional oil-type and cream-type cleansing cosmetics are highly blended with oily ingredients, so they have a markedly superior effect on makeup removal, while the oil-specific use feeling increases. There's a problem. There is also a problem that the skin after cleansing becomes too dry due to excessive degreasing.

  On the other hand, lotion type and emulsion type cleansing cosmetics are highly formulated with water, so the skin after cleansing will not dry, but in order to fully demonstrate the makeup removal effect, Surfactant must be highly blended and may cause undesired irritation to the skin and ocular mucosa during use. Moreover, since it is a liquid medicine type | mold, there also exists a problem of dripping from skin at the time of application | coating and being inferior to a usability | use_condition.

  In order to solve such problems, gel-type cleansing cosmetics have been studied as a form in which makeup can be removed with a light feeling of use without dripping at the time of application. Specifically, a gel cleansing cosmetic containing a gelling agent, a polyoxyethylene fatty acid glyceryl and a polyhydric alcohol (see, for example, Patent Document 1); a specific ester oil or hydrocarbon oil A gel-type cleansing material containing a polyoxyethylene hydrogenated castor oil-type nonionic surfactant, glycerin, and a specific polymer (see, for example, Patent Document 2); a specific alkyl glucoside, and a liquid oil Gel cleansing cosmetic containing water, a nonionic surfactant and a gelling agent (see, for example, Patent Document 3); a polyglycerol fatty acid ester of a specific HLB, glycerol, and silicone oil , Oil-containing gel cleansing composition (see, for example, Patent Document 4); trimethoxysilylated powder and liquid oil component , A hydrophilic gelling agent, cosmetic for cleansing containing a polyoxyethylene fatty acid glyceryl (e.g., Patent Document 5 references) have been proposed.

  However, based on these attempts, a gel-type cleansing cosmetic can be obtained, but in a system using a gelling agent that has been studied in various ways, an oily component in an amount that sufficiently exhibits the cleansing function. When a surfactant is added, there is a problem that it cannot be gelled. Moreover, even if it can be gelled, a sufficient thickening effect cannot be obtained, so that there is a problem that the preparation stability and the feeling of use are inferior. On the other hand, even in gelation using the association properties of surfactants, in order to sufficiently thicken the surfactant, it is necessary to add a high amount of surfactant, which only has an adverse effect on makeup familiarity and lowers the cleansing function. In addition, there is a problem that the feeling of use becomes heavy and the washing is inferior.

  As described above, the conventional gel preparation-type cleansing cosmetics have the disadvantage that, from the viewpoint of formulation, it is impossible to add an oily component or a surfactant in an amount sufficient to exert the cleansing function. The cleansing effect cannot be fully exhibited.

Japanese Patent Laid-Open No. 2001-19619 JP 2003-95918 A JP 2003-267836 A JP 2004-175736 A JP 2011-32228 A

  The present invention has been made in view of the above prior art, and even if an oily component and a surfactant in an amount that sufficiently exhibits the cleansing function are blended, the viscosity is sufficiently increased to form a gel. It is an object of the present invention to provide a gel-type cleansing cosmetic that can be used and has excellent formulation stability, usability, and makeup removal effect.

That is, the present invention
[1] (A) nonionic surfactant, (B) oil agent, (C) synthetic silicate and / or derivative thereof, (D) (meth) alkyl acrylate copolymer, and (E) (meth) Acrylic acid / (meth) acrylic acid alkyl / (meth) acrylic acid polyoxyethylene alkyl ether copolymer and / or (meth) acrylic acid / (meth) acrylic acid alkyl / itaconic acid polyoxyethylene alkyl ether copolymer Gel cleansing cosmetic ,
Gel cleansing cosmetics wherein the content of the component (A) is 10 to 50% by mass and the content of the component (B) is 10 to 50% by mass ,
[2] The gel cleansing makeup according to [1], wherein the component (A) is at least one selected from the group consisting of polyoxyethylene fatty acid, polyoxyethylene glycerin fatty acid ester, and polyoxyethylene sorbitan fatty acid ester. Fee,
[3] The gel cleansing cosmetic according to [1] or [2], wherein the component (B) is at least one selected from the group consisting of hydrocarbon oils, fatty acid esters and cyclic silicones ,
[ 4] The gel cleansing cosmetic according to any one of [1] to [3], wherein the component (C) is fluorosilicic acid (sodium / magnesium) .
[5] The gel cleansing cosmetic according to any one of [1] to [4], further comprising 5 to 50% by mass of water, and
[6] The above-mentioned [1] to [5], which do not contain an anionic surfactant or contain an anionic surfactant and the content of the anionic surfactant is 5% by mass or less. The gel cleansing cosmetic according to any one of the above .
In the present specification, “(meth) acryl” means both “acryl” and “methacryl”.

  The gel cleansing cosmetic composition of the present invention can be sufficiently thickened to form a gel, even if an oily component or surfactant in an amount that sufficiently exhibits the cleansing function is blended. It has an excellent effect on the formulation stability of suppressing the liquid and maintaining the gel-like form. In addition, the gel cleansing cosmetic of the present invention has no dripping at the time of application, is smooth and well-familiar with makeup, and can be easily washed off, so that it has an excellent effect on feeling of use, An excellent cleansing function that can easily remove makeup stains can be exhibited.

  The gel cleansing cosmetic of the present invention comprises (A) a nonionic surfactant, (B) an oil agent, (C) a synthetic silicate and / or a derivative thereof, (D) an alkyl (meth) acrylate copolymer, And (E) a specific copolymer and / or a specific cross polymer.

  Examples of the nonionic surfactant (A) include polyoxyethylene fatty acid, glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and sucrose fatty acid. Examples include esters, polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene (cured) castor oil, and fatty acid alkylolamides. These components (A) may be used alone or in appropriate combination of two or more.

  Suitable component (A) includes polyoxyethylene fatty acid, polyoxyethylene glycerin fatty acid ester, and polyoxyethylene sorbitan fatty acid ester from the viewpoints of formulation stability, a sufficient cleansing function, and a washing-off viewpoint. It is preferable to use at least one selected from the group consisting of

  (A) As a fatty-acid part which comprises a component, a C8-C22 fatty acid is mentioned. Specific examples include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, linolenic acid, behenic acid, and the like. Moreover, in this invention, a fatty-acid part may be a mixture of an above-described fatty acid, for example, coconut oil fatty acid, palm oil fatty acid, palm kernel oil fatty acid.

  Specific polyoxyethylene fatty acids include polyethylene glycol monolaurate, polyethylene glycol dilaurate, polyethylene glycol monomyristate, polyethylene glycol monopalmitate, polyethylene glycol dipalmitate, polyethylene glycol monostearate, polyethylene glycol distearate, mono Examples thereof include polyethylene glycol isostearate, polyethylene glycol diisostearate, polyethylene glycol monooleate, polyethylene glycol dioleate, and the like. The number of added moles of ethylene oxide is not particularly limited as long as a desired effect is imparted, but is preferably 2 to 100, and more preferably 5 to 90, from the viewpoint of formulation stability.

  In addition, a commercial item can also be used for polyoxyethylene fatty acid. Commercially available products of polyethylene glycol monolaurate include, for example, trade name: Emanon 1112 (ethylene oxide addition moles: 12, manufactured by Kao Corporation), trade name: NIKKOL MYL-10 (ethylene oxide addition moles: 10, Nippon Surfactant Industries, Ltd.) Etc.). As a commercial item of polyethylene glycol monolaurate, a brand name: NIKKOL MYO-10 (Ethylene oxide addition mole number: 10, Nippon Surfactant Kogyo Co., Ltd. product) etc. can be illustrated, for example. As a commercial item of polyethylene stearate monostearate, brand name: NIKKOL MYS-4V (ethylene oxide addition mole number: 4, Nippon Surfactant Kogyo Co., Ltd. product) etc. can be illustrated, for example.

  Specific polyoxyethylene glycerin fatty acid esters include polyoxyethylene (capryl / capric acid) glyceryl, polyoxyethylene coconut oil fatty acid glycerin, monooleic acid polyoxyethylene glyceryl, monomyristic acid polyoxyethylene glyceryl, monostearic acid Examples thereof include polyoxyethylene glyceryl, polyisoethylene glyceryl monoisostearate, and polyoxyethylene glyceryl triisostearate. The number of added moles of ethylene oxide is not particularly limited as long as a desired effect is imparted, but is preferably 2 to 100, more preferably 4 to 90 from the viewpoint of formulation stability.

  In addition, a commercial item can also be used for polyoxyethylene glycerol fatty acid ester. As a commercial item of polyoxyethylene (capryl / capric acid) glyceryl, for example, trade name: Hiber Oil CC-6 (number of moles of ethylene oxide added: 6, manufactured by Koyo Fine Chemical Co., Ltd.), trade name: CETIOL HE810 (ethylene oxide) Addition mole number: 7, manufactured by Cognis Japan), trade name: Softigogen 767 (ethylene oxide addition mole number: 6, manufactured by Sasol Corporation) and the like can be exemplified. Examples of commercial products of polyoxyethylene glyceryl monoisostearate include, for example, trade names: BROWNON RGL-5MISE (number of moles of ethylene oxide added: 5), RGL-8MISE (number of moles of ethylene oxide added: 8), RGL-10 MISE (oxidized) Examples include ethylene addition moles: 10), RGL-20MISE (ethylene oxide addition moles: 20) (both manufactured by Aoki Yushi Kogyo Co., Ltd.). As a commercial item of polyoxyethylene glyceryl triisostearate, a brand name: BROWNON RGL-20TISE (ethylene oxide addition mole number: 20, Aoki Yushi Kogyo Co., Ltd.) etc. can be illustrated, for example.

  Specific polyoxyethylene sorbitan fatty acid esters include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan monoisostearate , Polyisoethylene stearate polyoxyethylene sorbitan, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan trioleate, mono coconut oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan sesquioleate, polyoxyethylene sorbitan sesquistearate It can be illustrated. The number of added moles of ethylene oxide is not particularly limited as long as a desired effect is imparted, but is preferably 10 to 100, more preferably 20 to 90, from the viewpoint of formulation stability.

  In addition, a commercial item can also be used for polyoxyethylene sorbitan fatty acid ester. Examples of commercially available products of polyoxyethylene sorbitan monooleate include, for example, trade name: RHEODOL TWO-120V (ethylene oxide addition moles: 20, manufactured by Kao Corporation), trade name: NIKKOL TO-10V (ethylene oxide addition moles: 20, Nikko Chemicals). As a commercial item of polyisoethylene sorbitan monoisostearate, a brand name: NIKKOL TI-10V (ethylene oxide addition mole number: 20, Nippon Surfactant Kogyo Co., Ltd.) etc. can be illustrated, for example. As a commercial item of mono coconut oil fatty acid polyoxyethylene sorbitan, a brand name: NIKKOL TL-10 (Ethylene oxide addition mole number: 20, Nippon Surfactant Kogyo Co., Ltd. product) etc. can be illustrated, for example.

  The content of the component (A) is not particularly limited as long as a desired effect is imparted. Usually, from the viewpoint of formulation stability, a viewpoint of sufficiently exerting a cleansing function, and a viewpoint of washing off, makeup is performed. 5 mass% or more is preferable in a raw material, More preferably, it is 10 mass% or more. Moreover, from a viewpoint of usability, 50 mass% or less is preferable, More preferably, it is 30 mass% or less. From these viewpoints, the content of the component (A) is preferably 5 to 50% by mass, more preferably 10 to 30% by mass.

  Examples of the component (B) oil include fats and oils, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, fatty acid esters, silicone (straight silicone, modified silicone cyclic silicone), and the like. These components (B) may be used singly or in appropriate combination of two or more.

  Specific examples of the fats and oils include sunflower oil, cottonseed oil, soybean oil, olive oil, coconut oil, castor oil, jojoba oil, camellia oil, mink oil, and the like.

  Specific examples of waxes include carnauba wax, candelilla wax, beeswax, rice bran wax, shellac wax, whale wax, and lanolin.

  Specific hydrocarbon oils include light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, squalane, ceresin, paraffin, liquid paraffin, liquid isoparaffin, microcrystalline wax, polyethylene powder, polyethylene wax, petrolatum, etc. be able to.

  Specific examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, undecylenic acid, lanolinic acid, and isostearic acid.

  Specific examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, lanolin alcohol, behenyl alcohol, cetostearyl alcohol, octyldecanol, and decyltetradecanol.

  Specific fatty acid esters include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, oleyl oleate, octyldodecyl myristate, octyldodecyl oleate, ethyl isostearate, isopropyl isostearate, Cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, isocetyl octoate, isostearyl octoate, isopropyl isostearate, isocetyl isostearate, octyldodecyl isostearate, octyldodecyl dimethyloctanoate, ethylene glycol dioleate, dicaprylic acid Propylene glycol, propylene glycol dicaprate, di (capryl / capric) propylene glycol, Sosutearin propylene glycol, can be exemplified neopentylglycol dicaprate, glyceryl tri-2-ethylhexanoate, triisopalmitate, glyceryl tetra-2-ethylhexanoate, pentaerythritol and the like.

  Specific silicones include straight silicones such as octamethyltrisiloxane, tetradecamethylhexasiloxane, methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane; alcohol-modified silicone, alkyl-modified silicone And modified silicones such as amino-modified silicone, polyether-modified silicone, and epoxy-modified silicone; and cyclic silicones such as methylcyclopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane. it can.

  As a suitable component (B), it is preferable to use at least one selected from the group of hydrocarbon oils, fatty acid esters, and cyclic silicones from the viewpoint of enhancing makeup familiarity and exhibiting an excellent cleansing function.

  The content of the component (B) is not particularly limited as long as a desired effect is imparted, but usually 1% by mass or more is preferable in the cosmetic from the viewpoint of sufficiently exerting the cleansing function, and more preferably. It is 5 mass% or more. Moreover, from a viewpoint of usability, 60 mass% or less is preferable, More preferably, it is 50 mass% or less. From these viewpoints, the content of the component (B) is preferably 1 to 60% by mass, more preferably 5 to 50% by mass.

  Synthetic silicate and / or derivative thereof as component (C) is not a silicate mineral mainly composed of magnesium silicate or sodium silicate (sodium / magnesium) derived from nature, which contains impurities. It refers to silicates and silicate derivatives obtained by synthesis.

  Specific examples of the component (C) include, for example, an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 2, CTFA, 2010, p. 2868): a synthetic silicic acid represented by SODIUM MAGNESIUM SILICATE. (Sodium / magnesium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 2, CTFA, 2010, p. 1668): Magnesium fluorosilicate represented by MAGNESIUM FLUOROSILICATE, International CI name (International Ingredient D (ctionary and Handbook, 13th edition, volume 2, CTFA, 2010, p. 2868): SODIUM MAGNESIUM FLUOROSILICATE, fluorosilicic acid (sodium / magnesium), INCI name (International Cosmetic Ingredient Dict. 13) Edition, Vol. 2, CTFA, 2010, p.1674): MAGNESIUM POTASSIUM FLUOROSILIC fluorosilicate (magnesium / potassium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, Vol. 13, 2nd edition) CTF , 2010, p. 1675): MAGNESIUM SODIUM FLUOROSILICATE, fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 1, CTFA, 2010. 145): synthetic aluminum silicate represented by ALUMINUM SILICATE, and the like.

  These components (C) may be used alone or in appropriate combination of two or more. As a suitable component (C), it is preferable to use synthetic silicic acid (sodium / magnesium) and fluorosilicic acid (sodium / magnesium) from the viewpoint of formulation stability and feeling of use, suppressing dripping during application, From the viewpoint of extending smoothly, it is most preferable to use fluorosilicic acid (sodium / magnesium).

  In addition, a commercial item can also be used for the said (C) component. As a commercial item of synthetic silicic acid (sodium / magnesium), for example, trade name: LAPONITE XLG (manufactured by Rockwood) can be exemplified. As a commercial item of fluorosilicic acid (sodium / magnesium), brand name: Laponite XL21 (made by Rockwood) etc. can be illustrated, for example.

  The content of the component (C) is not particularly limited as long as the desired effect is imparted, but usually 0.05% by mass or more in the cosmetic from the viewpoint of formulation stability and familiarity with makeup. Is more preferable, and 0.1% by mass or more is more preferable. Moreover, from a viewpoint of a usability | use_condition, 10 mass% or less is preferable, More preferably, it is 5 mass% or less. From these viewpoints, the content of the component (C) is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass.

  The (D) component (meth) acrylic acid alkyl copolymer is represented by the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 1, CTFA, 2010, p. 53): ACRYLATES COPOLYMER. It is a copolymer comprising two or more components among alkyl acrylate (C1-4, C8) and alkyl methacrylate (C1-4, C8), acrylic acid and methacrylic acid. The component (D) used in the present invention is commercially available under trade names such as Pemulen TR-1, TR-2, Carbopol ETD2020, etc., and is generally referred to as an acrylic acid / alkyl methacrylate copolymer. The structure is different.

  In addition, as a commercial item of the said (D) component, brand name: Aculin 33A (made by Rohm and Haas Japan) can be illustrated.

  The component (D) is usually used after neutralizing with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine, inorganic bases such as ammonia, sodium hydroxide and potassium hydroxide, and basic amino acids such as arginine. The addition amount of the basic substance is an amount sufficient to neutralize the copolymer which is the above component (D), and may be appropriately blended depending on the type and amount of use of these components.

  The content of the component (D) is not particularly limited as long as a desired effect is imparted, but usually, the viewpoint of increasing the stability of the preparation by suppressing the liquid separation, and the familiarity with the makeup by extending smoothly. From the viewpoint of enhancing the content, 0.1% by mass or more is preferable in the cosmetic, and more preferably 0.2% by mass or more. Moreover, from a viewpoint of a usability | use_condition, 8 mass% or less is preferable, More preferably, it is 5 mass% or less. From these viewpoints, the content of the component (D) is preferably 0.1 to 8% by mass, more preferably 0.2 to 5% by mass.

The copolymer and / or cross polymer of component (E) is at least one selected from the group consisting of copolymers and cross polymers consisting of the following (a) and (b).
(A) (meth) acrylic acid and / or alkyl (meth) acrylate (b) itaconic acid polyoxyethylene alkyl ether, (meth) acrylic acid polyoxyethylene alkyl ether or vinyl neodecanoate

  Examples of the copolymer of component (E) include (meth) acrylic acid / alkyl (meth) acrylate / (meth) acrylic acid polyoxyethylene alkyl ether copolymer, (meth) acrylic acid / alkyl (meth) acrylate / itacon And acid polyoxyethylene alkyl ether copolymers. Moreover, as a cross polymer, (meth) acrylic acid / (meth) acrylic acid alkyl / (meth) acrylic acid polyoxyethylene alkyl ether crosspolymer, (meth) acrylic acid / (meth) acrylic acid alkyl / neodecanoic acid, for example A vinyl cloth polymer etc. are mentioned. These components (E) may be used alone or in appropriate combination of two or more. The number of moles of ethylene oxide to be polymerized is not particularly limited, but is preferably 10 to 40 from the viewpoint of suppressing liquid separation and improving formulation stability.

  Specific examples of (meth) acrylic acid / (meth) acrylic acid alkyl / (meth) acrylic acid polyoxyethylene alkyl ether copolymers include INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 1, CTFA, 2010, p. 53): ACRYLATES / CETETH-20 METHACRYLATE COPOLYMER acrylates / polyoxyethylene (20) cetyl ether copolymer, INCI name (International Cosmetic Indigenous Dictionary, Volume 13) CTFA, 2010, p. 59): ACRYLA ES / STEARETH-20 METRACRYLATE COPOLYMER acrylates / polyoxyethylene methacrylate (20) stearyl ether copolymer, INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 1, CTFA, 2010. 51): ACRYLATES / BEHENETH-25 METRACRYLATE COPOLYMER acrylates / polyoxyethylene methacrylate (25) behenyl ether copolymer and the like. In addition, the numerical value in a parenthesis represents the addition mole number of ethylene oxide.

  Specific examples of (meth) acrylic acid / (meth) acrylic acid alkyl / itaconic acid polyoxyethylene alkyl ether copolymers include INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 1, CTFA, 2010, p. 53): ACRYLATES / CETETH-20 ITECONATE COPOLYMER, acrylates / itaconic acid polyoxyethylene (20) cetyl ether copolymer, INCI name (International Cosmetic Ingredient Dictionary and Handbook, Vol. 13, 1st edition) 2010, p. 59): ACRYLATES / STEA Such as ETH-20 ITACONATE acrylates / itaconic acid polyoxyethylene (20) which is denoted by COPOLYMER stearyl ether copolymers can be exemplified. In addition, the numerical value in a parenthesis represents the addition mole number of ethylene oxide.

  Specific (meth) acrylic acid / (meth) acrylic acid / (meth) acrylic acid polyoxyethylene alkyl ether cross-polymer includes INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 1, CTFA) 2010, p. 59): ACRYLATES / STEARETH-20 METHACRYLATE CROSSPOLYMER acrylates / polyoxyethylene methacrylate (20) stearyl ether crosspolymer, and the like. In addition, the numerical value in a parenthesis represents the addition mole number of ethylene oxide.

  Specific examples of the (meth) acrylic acid / alkyl (meth) acrylate / neodecanoic acid vinyl crosspolymer include the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 1, CTFA, 2010, p. 61). ): ACRYLATES / VINYL NEODECanoNOTE CROSSPOLYMER An alkyl acrylate / neodecanoic acid vinyl crosspolymer and the like can be exemplified.

  Suitable components (E) include (meth) acrylic acid / (meth) acrylic acid alkyl / (meth) acrylic acid polyoxyethylene alkyl ether copolymer, (meth) acrylic acid / It is preferable to use a (meth) acrylic acid alkyl / itaconic acid polyoxyethylene alkyl ether copolymer.

  The component (E) is usually used after neutralizing with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine, inorganic bases such as ammonia, sodium hydroxide and potassium hydroxide, and basic amino acids such as arginine. Moreover, the addition amount of the basic substance is an amount sufficient to neutralize the above-described component (E) copolymer or cross polymer, and may be appropriately blended depending on the type and amount of use of these components.

  In addition, a commercial item can also be used for the said (E) component. As a commercial item of an acrylates / polyoxyethylene methacrylate (20) stearyl ether copolymer, for example, trade name: Aculin 22 (manufactured by Rohm and Haas Japan) can be exemplified. As a commercial item of acrylates / polyoxyethylene methacrylate (25) behenyl ether copolymer, for example, trade name: Aculin 28 (manufactured by Rohm and Haas Japan) can be exemplified. As a commercial item of the acrylates / polyoxyethylene itaconate (20) cetyl ether copolymer, for example, trade name: STRUCTURE 3001 (manufactured by Akzo Nobel) can be exemplified. Examples of commercially available products of acrylates / polyoxyethylene itaconate (20) stearyl ether copolymer include trade name: STRUCTURE 2001 (manufactured by Akzo Nobel).

  The content of the component (E) is not particularly limited as long as a desired effect is imparted, but usually from the viewpoint of suppressing liquid separation and improving formulation stability, and from the viewpoint of suppressing dripping during application. In cosmetics, 0.1 mass% or more is preferable, More preferably, it is 0.2 mass% or more. Moreover, from a viewpoint of a usability | use_condition, 8 mass% or less is preferable, More preferably, it is 5 mass% or less. From these viewpoints, the content of the component (E) is preferably 0.1 to 8% by mass, more preferably 0.2 to 5% by mass.

  In addition, water is used for the remainder of the gel cleansing cosmetic of the present invention. The water used is not particularly limited as long as it can be used as a cosmetic raw material, but purified water is usually used. The content of water in the present invention is preferably 5 to 80% by mass, and more preferably 20 to 50% by mass in the cosmetic from the viewpoint of gel. The reason is that when the amount is less than 5% by mass, a sufficient thickening effect cannot be obtained and the formulation stability is poor, and when the amount exceeds 80% by mass, a sufficient cleansing effect cannot be obtained.

  In addition, the gel cleansing cosmetic composition according to the present invention may contain an anionic surfactant from the viewpoint of further enhancing wash-off and the viewpoint of further enhancing the cleansing function. Specific examples of the anionic surfactant include sodium lauryl sulfate, triethanolamine lauryl sulfate, sodium myristyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate and sodium cetyl sulfate; polyoxyethylene lauryl ether sulfate Sodium, polyoxyethylene alkyl ether sulfate such as sodium polyoxyethylene myristyl sulfate; α-olefin sulfonate such as sodium tetradecenesulfonate; sodium myristoyl methyl taurate, sodium palmitoyl methyl taurine, sodium stearoyl methyl taurine, oleoyl N-acylmethyl taurine salts such as methyl taurine sodium and palm oil fatty acid methyl taurine sodium; Sulfosuccinic acid alkyl salts such as dioctyl sodium and lauryl disodium sulfosuccinates; Polyoxyethylene alkyl sulfosuccinates such as polyoxyethylene lauryl disodium sulfosuccinate; Monoalkyls such as sodium lauryl phosphate, sodium cetyl phosphate, diethanolamine cetyl phosphate Phosphoric acid ester salt; sodium polyoxyethylene lauryl ether phosphate, sodium polyoxyethylene cetyl ether phosphate, sodium polyoxyethylene oleyl ether phosphate, sodium polyoxyethylene alkylphenyl ether phosphate, polyoxyethylene alkylphenyl ether phosphate Polyoxyethylene alkyl ether phosphates such as triethanolamine; Lauroyl sarcosine N-acyl sarcosine salts such as potassium, lauroyl sarcosine triethanolamine, myristoyl sarcosine sodium, coconut oil fatty acid sarcosine sodium; lauroyl methylalanine sodium, lauroyl methylalanine triethanolamine, myristoyl methylalanine sodium, coconut oil fatty acid sodium methylalanine, etc. N-acyl-N-methyl-β-alanine salt; sodium lauroyl glutamate, triethanolamine lauroyl glutamate, sodium myristoyl glutamate, potassium stearoyl glutamate, disodium stearoyl glutamate, sodium coconut oil fatty acid acyl glutamate, coconut oil fatty acid acyl glutamic acid triethanol N-acyl glutamates such as amines; palm N-acylglycine salts such as potassium fatty acid acylglycine, sodium coconut oil fatty acid acylglycine; sodium lauryl glycol acetate (sodium dodecane-1,2-diol acetate), potassium lauryl glycol acetate, sodium myristyl glycol acetate, potassium myristyl glycol acetate, Examples include alkyl ether glycol acetates such as sodium palmityl glycol acetate, potassium palmityl glycol acetate, sodium stearyl glycol acetate, potassium stearyl glycol acetate, sodium behenyl glycol acetate, and potassium behenyl glycol acetate. These components may be used alone or in appropriate combination of two or more.

  The content of the anionic surfactant is not particularly limited as long as a desired effect is imparted, but usually 0.01% by mass or more is preferable in the cosmetic from the viewpoint of washing off, more preferably. It is 0.05 mass% or more. Moreover, from a viewpoint of formulation stability, 10 mass% or less is preferable, More preferably, it is 5 mass% or less. From these viewpoints, the content of the anionic surfactant is preferably 0.01 to 10% by mass, more preferably 0.05 to 5% by mass.

  In addition, the gel cleansing cosmetic composition according to the present invention includes ethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, polyethylene, in addition to the components described above, as long as the effects of the present invention are not impaired. Glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, mannitol, sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2 -Polyhydric alcohols such as octanediol; Refreshing agents such as menthol, menthyl glyceryl ether, camphor; Preservatives such as phenoxyethanol and glycerin mono-2-ethylhexyl ether; Antioxidants, sequestering agents, vitamins, animals and plants Out extract, pearlescent agents, coloring agents, may also be appropriately blended various perfumes depending on the purpose.

  The gel cleansing cosmetic composition of the present invention can be produced by mixing the above-described components and stirring them using a known method such as a propeller mixer.

  The viscosity (mPa · s) of the gel cleansing cosmetic is not particularly limited as long as it does not cause dripping at the time of application, but it is 30,000 to 300,000 mPa from the viewpoint of smooth extension and quick integration with makeup. It is preferable to be within the range of s, and more preferably 50,000 to 200,000 mPa · s. The viscosity (mPa · s) was measured using a B type viscometer (manufactured by VISCOMETER Toki Sangyo Co., Ltd.) under the measurement condition: rotor NO. Although it is a value measured at 4, 3 rpm for 1 minute, it is not limited only to these measurement conditions.

  The gel cleansing cosmetic of the present invention can be used as a face massage agent or makeup remover. Among these, it is most preferably used as a makeup remover from the viewpoint of excellent familiarity with makeup. Further, the method of use is not particularly limited as long as it can remove makeup stains, even if it is a method of use in the form of washing away or a method of use in a form of wiping by impregnating a base such as cotton. From the viewpoint of irritation to the skin and feeling of use, it is preferably used in a method of washing away with lukewarm water after the treatment.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by mass” unless otherwise specified. Moreover, (D) component and (E) component were converted into the pure part.

(Sample preparation)
According to the composition described in Table 1 and Table 2, the cosmetics for cleansing of Examples 1-7 and Comparative Examples 1-7 were prepared and used for the following evaluation test. The results are shown in Table 1 and Table 2, respectively. In addition, the numerical value in a parenthesis represents the addition mole number of ethylene oxide.

(Test Example 1: Confirmation of properties)
The properties of each sample obtained in the examples and comparative examples were observed visually.

(Test Example 2: Evaluation of formulation stability)
Each sample obtained in Examples and Comparative Examples is filled in a 50 mL transparent glass container, visually observed for 1 month in each thermostatic bath at 5 ° C. and 40 ° C., and in accordance with the following evaluation criteria. Visual evaluation was made.
In Test Example 1, formulation stability was not evaluated for those in which the properties immediately after production were liquid.

<Evaluation criteria for formulation stability (5 ° C.)>
◎: Maintains a gel-like form as compared with the properties immediately after manufacture ○: Maintains a gel-like form as compared with the properties immediately after manufacture, but slight liquid separation is observed on the surface △: Compared with the properties immediately after production, the gel-like form is not maintained, and clear liquid separation is observed on the surface. X: In contrast with the properties immediately after production, liquid separation (separation) occurs. Have

<Evaluation criteria for formulation stability (40 ° C.)>
◎: Maintains a gel-like form as compared with the properties immediately after manufacture ○: Maintains a gel-like form as compared with the properties immediately after manufacture, but slight liquid separation is observed on the surface △: Compared with properties immediately after production, gel-like form is not maintained, and clear liquid separation is observed on the surface. ×: Compared with properties immediately after production, liquefied.

(Test Example 3: Evaluation of use feeling and cleansing function)
Each sample obtained in the examples and comparative examples was actually used in the form of a makeup remover by 20 female sensory evaluation panels applying makeup. Specifically, after 2 g of sample was applied, it was thoroughly acclimated to the makeup stains, cleansed for 2 minutes to draw a small circle with the fingertips, then rinsed thoroughly with warm water and wiped away with towel dry. .

In the usage test, “dripping” during application, “nodding” and “familiarity with makeup” during cleansing, “ease of rinsing (washing off)” during washing, and “make-up dirt removal effect” after towel drying The sensory evaluation was performed according to the following evaluation criteria.
In addition, as for the makeup familiarity, those having an excellent effect of raising makeup stains were evaluated as “excellent in makeup familiarity”.

<Evaluation criteria for dripping>
◎: 16 or more out of 20 responded that there was no dripping ○: 11-15 out of 20 responded that there was no dripping △: 6-10 out of 20 responded that there was no dripping ×: 20 Less than 5 of the names responded that there was no dripping

<Evaluation criteria for Nobi>
◎: More than 16 out of 20 responded that there was no “smooth” at the time of extension, and that it extended smoothly ○: 11 to 15 out of 20 responded that there was no “smooth” at the time of extension, and that it extended smoothly △: 20 6-10 of the names responded that there was no “smoothness” at the time of extension, and that it extended smoothly ×: 5 out of 20 respondents said that there was no “smoothness” at the time of extension, and that it extended smoothly

<Evaluation criteria for familiarity with makeup>
A: Reply if 16 or more out of 20 people are excellent in make-up. ○: Reply if 11-15 out of 20 people are good in make-up. Δ: Reply if 6-10 out of 20 people are good in make-up. ×: 20 5 or less of the respondents say they are familiar with makeup

<Evaluation criteria for ease of rinsing (washing off)>
◎: More than 16 out of 20 people feel that there is no slimy feeling and easy to rinse ○: 11 to 15 out of 20 people feel that there is no slimy feeling and easy to rinse Δ: 6 to 10 out of 20 people get wet No sensation and easy to rinse ×: 5 out of 20 respondents said that there was no sliminess and easy to rinse

<Evaluation criteria for makeup stain removal effect>
◎: 16 or more out of 20 respondents with no makeup residue and excellent removal effect ○: 11 to 15 out of 20 respondents with no makeup residual and excellent removal effect Δ: 6 to 10 out of 20 Responded that there was no makeup residue and excellent removal effect ×: 5 or less of 20 people answered that there was no makeup residue and excellent removal effect

  From the results of Tables 1 and 2, the cleansing cosmetics of each example can be sufficiently thickened and gelled as compared to those of each comparative example, and also suppressed liquid separation. Thus, it can be seen that it has an excellent effect on the stability of the formulation that maintains the gel-like form. In addition, it can be seen that there is no dripping at the time of application, it extends smoothly, is familiar with makeup, can be easily washed off, and exhibits an excellent cleansing function.

  On the other hand, in Comparative Example 1 and Comparative Example 3 that do not satisfy the configuration of the present invention, it is understood that a sufficient thickening effect cannot be obtained and a gel-like form is not obtained. Moreover, in Comparative Example 2 and Comparative Examples 4 to 5 that do not satisfy the configuration of the present invention, although a gel-like form can be obtained, liquid separation is recognized and the gel-like form cannot be maintained, resulting in poor formulation stability. Or it turns out that it is inferior to a usability | use_condition and the cleansing function is not fully exhibited. In addition, in Comparative Examples 6 to 7 in which the component (D) or the component (E), which is an essential component of the present invention, is replaced with another component having a thickening effect, a sufficient thickening effect cannot be obtained. It turns out that it does not become a shape form.

  Hereinafter, formulation examples of the gel cleansing cosmetic according to the present invention will be shown. In addition, content is mass%. POE is an abbreviation for polyoxyethylene, and the numerical value in parentheses represents the number of added moles of ethylene oxide.

(Prescription Example 1)
Isostearic acid POE (8) glyceryl 20.0
Polyethylene glycol monolaurate (12) 1.0
Fluorosilicic acid (sodium / magnesium) 2.0
Alkyl acrylate copolymer 1.5
Acrylates / methacrylic acid POE (20) stearyl ether copolymer
2.5
Light isoparaffin 5.0
Cetyl 2-ethylhexanoate 10.0
Isopropyl myristate 10.0
Propylene glycol monoisostearate 15.0
Dipropylene glycol 5.0
Glycerin 2.0
1,3-butylene glycol 5.0
Dipropylene glycol 5.0
Glycerin mono-2-ethylhexyl ether 0.1
1,2-hexanediol 0.5
Potassium hydroxide appropriate amount Preservative appropriate amount Metal chelating agent appropriate amount
Purified water balance part Total 100.0

(Prescription example 2)
Isostearic acid POE (8) glyceryl 20.0
Polyethylene glycol monolaurate (12) 1.0
N-stearoyl-sodium L-glutamate 0.5
Fluorosilicic acid (sodium / magnesium) 1.0
Alkyl acrylate copolymer 1.5
Acrylates / methacrylic acid POE (20) stearyl ether copolymer
2.5
Light isoparaffin 5.0
Cetyl 2-ethylhexanoate 10.0
Isopropyl palmitate 10.0
Liquid paraffin 15.0
Dipropylene glycol 5.0
Glycerin 2.0
1,3-butylene glycol 5.0
Dipropylene glycol 5.0
Glycerin mono-2-ethylhexyl ether 0.1
1,2-octanediol 0.5
Potassium hydroxide appropriate amount Preservative appropriate amount Metal chelating agent appropriate amount
Purified water balance part Total 100.0

(Prescription Example 3)
Isostearic acid POE (8) glyceryl 20.0
Polyethylene glycol monolaurate (12) 1.0
Polyoxyethylene (carryl / capric acid) glyceryl (6) 0.5
Fluorosilicic acid (sodium / magnesium) 1.0
Synthetic silicic acid (sodium / magnesium) 0.5
Alkyl acrylate copolymer 1.5
Acrylates / methacrylic acid POE (20) stearyl ether copolymer
2.5
Light isoparaffin 5.0
Cetyl 2-ethylhexanoate 10.0
Isopropyl myristate 10.0
Propylene glycol monoisostearate 15.0
Dipropylene glycol 5.0
Glycerin 2.0
1,3-butylene glycol 5.0
Dipropylene glycol 5.0
Glycerin mono-2-ethylhexyl ether 0.1
1,2-hexanediol 0.4
1,2-octanediol 0.4
Potassium hydroxide appropriate amount Preservative appropriate amount Metal chelating agent appropriate amount
Purified water balance part Total 100.0

Claims (6)

(A) nonionic surfactant, (B) oil agent, (C) synthetic silicate and / or derivative thereof, (D) (meth) acrylic acid alkyl copolymer, and (E) (meth) acrylic acid / Gel-like cleansing comprising (meth) acrylic acid alkyl / (meth) acrylic acid polyoxyethylene alkyl ether copolymer and / or (meth) acrylic acid / (meth) acrylic acid alkyl / itaconic acid polyoxyethylene alkyl ether copolymer is the use cosmetics,
Gel cleansing cosmetic in which the content of the component (A) is 10 to 50% by mass and the content of the component (B) is 10 to 50% by mass .   The gel cleansing cosmetic according to claim 1, wherein the component (A) is at least one selected from the group consisting of polyoxyethylene fatty acid, polyoxyethylene glycerin fatty acid ester and polyoxyethylene sorbitan fatty acid ester.   The gel cleansing cosmetic according to claim 1 or 2, wherein the component (B) is at least one selected from the group consisting of hydrocarbon oils, fatty acid esters and cyclic silicones.   The gel cleansing cosmetic according to any one of claims 1 to 3, wherein the component (C) is fluorosilicic acid (sodium / magnesium). Furthermore, the gel-type cleansing cosmetics in any one of Claims 1-4 formed by containing 5-50 mass% water. The gel according to any one of claims 1 to 5, which does not contain an anionic surfactant or contains an anionic surfactant, and the content of the anionic surfactant is 5% by mass or less. Cleansing cosmetic.