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JP5691677B2 - Method for correcting phase defect of reflective photomask - Google Patents

Method for correcting phase defect of reflective photomask Download PDF

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JP5691677B2
JP5691677B2 JP2011052595A JP2011052595A JP5691677B2 JP 5691677 B2 JP5691677 B2 JP 5691677B2 JP 2011052595 A JP2011052595 A JP 2011052595A JP 2011052595 A JP2011052595 A JP 2011052595A JP 5691677 B2 JP5691677 B2 JP 5691677B2
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film
defect
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multilayer film
phase defect
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JP2012190964A (en
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松尾 正
正 松尾
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Toppan Inc
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Description

本発明は、半導体集積回路等の作製に際して使用される極端紫外線等を用いた反射型フォトマスクのマスクパターンの位相欠陥修正方法に関する。   The present invention relates to a method for correcting a phase defect in a mask pattern of a reflective photomask using extreme ultraviolet light or the like used in the manufacture of a semiconductor integrated circuit or the like.

半導体デバイスの微細化は年々進んでおり、それに伴いフォトリソグラフィ技術に使用される光も短波長化が進行している。すなわち、従来光源として使用されてきたKrFエキシマレーザ(波長248nm)からArFエキシマレーザ(波長193nm)に移行するとともに、近年は、ArFエキシマレーザを使用する液浸露光法や2重露光法の研究が活発に行われている。一方で、エキシマレーザよりも波長が一桁以上短い(10nm〜15nm)極端紫外線(Extreme UV、以下EUVと略記)を用いた反射型光学系によるEUVリソグラフィの研究開発が進められている。   The miniaturization of semiconductor devices is progressing year by year, and accordingly, light used in photolithography technology is also being shortened. That is, the KrF excimer laser (wavelength 248 nm), which has been used as a conventional light source, is shifted to an ArF excimer laser (wavelength 193 nm). In recent years, immersion exposure methods and double exposure methods using an ArF excimer laser have been studied. It is active. On the other hand, research and development of EUV lithography using a reflection-type optical system using extreme ultraviolet rays (Extreme UV, hereinafter abbreviated as EUV) whose wavelength is one digit or more shorter than that of an excimer laser is in progress.

光源の短波長化とともに、半導体ウェハーにパターンを転写する際に使用されるフォトマスクにも微細化、高精度化の要求がますます強くなってきている。フォトマスクは、従来からArF露光までは光透過型が用いられているが、EUV光に対しては材料の屈折率差が小さく屈折型光学系が使えず、反射型光学系となるため、EUV露光用フォトマスクも反射型が用いられる。   Along with the shortening of the wavelength of the light source, there is an increasing demand for miniaturization and high precision in photomasks used for transferring patterns to semiconductor wafers. Conventionally, the photomask is a light transmission type until ArF exposure, but the EUV light has a small difference in refractive index of the material and the refraction type optical system cannot be used. A reflection type is also used for the exposure photomask.

これまで開発されてきた一般的なEUVマスクは、Siウェハーやガラス基板上に、2層膜を40〜50対ほど積層した多層膜部分を高反射領域とし、その上に低反射領域(吸収領域)として金属性膜のパターンを形成した構造であった。高反射領域は、屈折率差が大きく、吸収がなるべく小さな2種類の膜(例えばMoとSi)を交互に積層して、多層膜としたものである。この結果、各層対からの僅かな反射成分が干渉して強め合い、直入射に近いEUV光に対して比較的高い反射率を得ることが可能になる。また通常、多層膜を保護する意味で、多層膜の最上層(吸収膜に近い層)に、EUV光に対する透明性が高いSiなどからなる膜をキャッピング膜として形成する。   In general EUV masks that have been developed so far, a multilayer film portion in which about 40 to 50 pairs of two-layer films are laminated on a Si wafer or glass substrate is used as a high reflection region, and a low reflection region (absorption region) is formed thereon. ) As a metal film pattern. The high reflection region is a multilayer film in which two kinds of films (for example, Mo and Si) having a large difference in refractive index and absorption as small as possible are alternately laminated. As a result, a slight reflection component from each layer pair interferes and strengthens, and it is possible to obtain a relatively high reflectivity with respect to EUV light close to normal incidence. Usually, in order to protect the multilayer film, a film made of Si or the like having high transparency to EUV light is formed as a capping film on the uppermost layer of the multilayer film (a layer close to the absorption film).

フォトマスクは、半導体ウェハー上に回路パターンを焼付け転写する前に検査されるが、該回路パターン間に微小異物、欠陥が存在する場合、該異物、欠陥により前記回路パターンが正常に転写されず、半導体デバイスが不良になる。この問題は、最近の半導体デバイスの高集積化に伴い一層顕在化し、より微小な異物や欠陥の存在も許容されなくなってきている。   A photomask is inspected before a circuit pattern is baked and transferred onto a semiconductor wafer, but if there are minute foreign objects or defects between the circuit patterns, the circuit pattern is not normally transferred due to the foreign objects or defects, A semiconductor device becomes defective. This problem has become more apparent with the recent high integration of semiconductor devices, and the presence of finer foreign matters and defects has become unacceptable.

通常フォトマスクではパターン欠陥がまったくないことが要求され、この段階でのマスク検査、修正技術が重要である。一般に、フォトマスクの欠陥には遮光膜(EUVマスクでは吸収膜)があるべきところに遮光膜(EUVマスクでは吸収膜)がない白欠陥と、透過領域(EUVマスクでは高反射領域)に余分な遮光膜(吸収膜)が残存してしまう黒欠陥がある。
前記のような一般的なフォトマスクの欠陥の他に、EUVマスクに特有の欠陥として、位相欠陥がある。EUVマスクは前述のように、基板上に積層した多層膜の干渉光によって高反射領域を形成するが、基板上、あるいは多層膜中に突起(パーティクル)やピットがあった場合、その部分からの反射光は、正常な高反射領域からの反射光に対して位相差を持つとともに、反射率の低下を伴う。このような欠陥部は位相欠陥と呼ばれる。
Usually, a photomask is required to have no pattern defects, and mask inspection and correction techniques at this stage are important. In general, a defect in a photomask should have a light-shielding film (an absorption film in an EUV mask) where there should be a light-shielding film (an absorption film in an EUV mask), and an excess in a transmission region (a high-reflection region in an EUV mask). There is a black defect in which the light shielding film (absorbing film) remains.
In addition to the general photomask defects as described above, there is a phase defect as a defect peculiar to the EUV mask. As described above, the EUV mask forms a highly reflective region by the interference light of the multilayer film laminated on the substrate. If there are protrusions (particles) or pits on the substrate or in the multilayer film, The reflected light has a phase difference with respect to the reflected light from the normal high reflection region, and is accompanied by a decrease in reflectance. Such a defective portion is called a phase defect.

EUVマスクの典型的な位相欠陥の例を、図3によって説明する。図3はEUVマスク
の位相欠陥部を部分的に切り取ったものである。ここでは、基板1’上にSiからなる突起欠陥(パーティクル)3が存在し、その上にMoとSiからなる多層膜2が積層されている。多層膜2の最上層は、多層膜を保護するためのキャッピング膜(図3では省略)となっている。突起欠陥3によって盛り上がった多層膜の部分4の高さは、通常、突起欠陥3の高さよりも低くなる。これは、突起欠陥部の上に成膜される多層膜の各層(Mo、Si)の厚さが、正常な部分に成膜される膜厚よりも数%程度薄くなるからである。
An example of a typical phase defect of an EUV mask will be described with reference to FIG. FIG. 3 is a partial cutout of the phase defect portion of the EUV mask. Here, a protrusion defect (particle) 3 made of Si exists on the substrate 1 ′, and a multilayer film 2 made of Mo and Si is laminated thereon. The uppermost layer of the multilayer film 2 is a capping film (not shown in FIG. 3) for protecting the multilayer film. The height of the portion 4 of the multilayer film raised by the protrusion defect 3 is usually lower than the height of the protrusion defect 3. This is because the thickness of each layer (Mo, Si) of the multilayer film formed on the protrusion defect part is about several percent thinner than the film thickness formed on the normal part.

図3のような位相欠陥をもつEUVマスクを、模式的に描いたものが図4(a)である。図4(a)では、多層膜の一部として、Siなどからなるキャッピング膜2aも図示している。図4(a)のようなEUVマスクにおいて、典型的なEUV露光の波長である13.52nmにおける、正常な高反射領域からの反射光5と欠陥部からの反射光6の反射率、及び反射光5と反射光6の位相差を、Si突起の高さを横軸として計算すると、図4(b)、(c)のようになる。ここで、突起欠陥部の上に成膜される多層膜の各層(Mo、Si)の厚さは、正常な部分に成膜される膜厚よりも各々2%薄いとして計算している。   FIG. 4A schematically shows an EUV mask having a phase defect as shown in FIG. 4A also shows a capping film 2a made of Si or the like as a part of the multilayer film. In the EUV mask as shown in FIG. 4A, the reflectance and reflection of the reflected light 5 from the normal high reflection region and the reflected light 6 from the defect portion at 13.52 nm, which is a typical EUV exposure wavelength. When the phase difference between the light 5 and the reflected light 6 is calculated with the height of the Si protrusion as the horizontal axis, the results are as shown in FIGS. Here, the thickness of each layer (Mo, Si) of the multilayer film formed on the protrusion defect part is calculated as 2% thinner than the film thickness formed on the normal part.

図4(b)から分かるように、欠陥部においては、その上に成膜される多層膜の各層(Mo、Si)の膜厚が、正常な膜厚よりも各々2%薄いために、反射光6による反射率Rdは、反射光5による反射率Rmよりも10%程度低くなる。このことは、基板直上に欠陥があることと、微小な(数nm程度)欠陥である限り、欠陥高さ(横軸)に依らない。一方、図4(c)から分かるように、微小な突起欠陥においても、RmとRdの位相差は、欠陥の高さとともに急激に大きくなることが分かる。   As can be seen from FIG. 4B, in the defect portion, the thickness of each layer (Mo, Si) of the multilayer film formed thereon is 2% thinner than the normal film thickness. The reflectance Rd by the light 6 is about 10% lower than the reflectance Rm by the reflected light 5. This does not depend on the defect height (horizontal axis) as long as there is a defect directly above the substrate and a minute defect (about several nm). On the other hand, as can be seen from FIG. 4C, it can be seen that the phase difference between Rm and Rd increases rapidly with the height of the defect even in a minute protrusion defect.

図5は、突起欠陥が多層膜の途中にあるEUVマスクを模式的に描いている。ここでは突起欠陥3’が多層膜2’の途中に存在している。従って欠陥上部の、正常な部分の多層膜よりも薄い多層膜の層数は、欠陥が基板直上にある場合よりも少なくなるので、欠陥3’によって盛り上がった多層膜の部分4’の高さは、欠陥が基板直上にある場合よりも低くなる。しかしながら、反射光6’の反射率が反射光5の反射率よりも低くなること、及び反射光5と反射光6’の間に位相差が生じ位相欠陥となることは、欠陥が基板直上にある場合と同様である。   FIG. 5 schematically illustrates an EUV mask having a protrusion defect in the middle of the multilayer film. Here, the protrusion defect 3 ′ is present in the middle of the multilayer film 2 ′. Accordingly, since the number of layers of the multilayer film that is thinner than the multilayer film of the normal part above the defect is smaller than when the defect is directly above the substrate, the height of the part 4 ′ of the multilayer film raised by the defect 3 ′ is This is lower than when the defect is directly above the substrate. However, the fact that the reflectance of the reflected light 6 ′ is lower than the reflectance of the reflected light 5 and that a phase difference occurs between the reflected light 5 and the reflected light 6 ′ causes a phase defect. It is the same as in some cases.

以上のように、反射型マスクの位相欠陥は、欠陥部と非欠陥(正常)部の位相差のみならず反射率の差を伴うが、その原因となる突起(パーティクル)やピットの位置、大きさ、材質により、さまざまなバリエーションがあり、それらを広汎に修正し、解決する方法は具体的に提案されていなかった。   As described above, the phase defect of the reflective mask involves not only the phase difference between the defective part and the non-defect (normal) part, but also the reflectance difference. Now, there are various variations depending on the material, and no method has been specifically proposed to fix and solve them extensively.

特開2006−60059号公報JP 2006-60059 A 特開2007−27035号公報JP 2007-27035 A 国際公開第2007/102333号パンフレットInternational Publication No. 2007/102333 Pamphlet

豊田浩一、岡崎信次監修:EUV光源の開発と応用、シーエムシー出版、ISBN:4882316668、2007Supervised by Koichi Toyoda and Shinji Okazaki: Development and application of EUV light source, CM Publishing, ISBN: 4882316668, 2007

本発明は、以上のような事情の下になされ、反射型マスクがダメージを受けることなく、精度よく、位相欠陥が修正されることを可能とする、反射型マスクの位相欠陥修正方法を提供することを目的とする。   The present invention provides a method for correcting a phase defect in a reflective mask, which is made under the circumstances as described above, and enables the phase defect to be corrected with high accuracy without damage to the reflective mask. For the purpose.

請求項1に記載の本発明は、
MoとSiを交互に積層して多層膜とした反射型フォトマスクの高反射部に発生した位相欠陥を修正する方法であって、
位相欠陥部上に、一方がSi(シリコン)である2種類の材料からなる多層膜を積層することにより、該位相欠陥部と高反射部の位相差を実用上0(ゼロ)とし、該位相欠陥部の反射率と高反射部の反射率を実用上等しくするにあたり、
前記位相欠陥部上に積層されるSi(シリコン)の1層あたりの膜厚は、高反射部に使用されるSiの1層あたりの膜厚と異なることを特徴とする。
The present invention described in claim 1
A method of correcting a phase defect generated in a highly reflective portion of a reflective photomask in which Mo and Si are alternately laminated to form a multilayer film,
By laminating a multilayer film made of two kinds of materials, one of which is Si (silicon), on the phase defect portion, the phase difference between the phase defect portion and the high reflection portion is practically 0 (zero), In practically equalizing the reflectance of the defective part and the reflectance of the highly reflective part,
The film thickness per layer of Si (silicon) laminated on the phase defect portion is different from the film thickness per layer of Si used for the high reflection portion.

請求項2に記載の本発明は、
前記位相欠陥部上に積層される2種類の材料の他方はMo(モリブデン)であることを特徴とする。
The present invention described in claim 2
The other of the two types of materials laminated on the phase defect portion is Mo (molybdenum).

請求項3に記載の本発明は、
前記位相欠陥部上に積層される2種類の材料の他方はRu(ルテニウム)であることを特徴とする。
The present invention according to claim 3 provides:
The other of the two types of materials laminated on the phase defect portion is Ru (ruthenium).

請求項4に記載の本発明は、
前記位相欠陥部上に積層される多層膜は、前記位相欠陥部のキャッピング膜を剥離した上に積層されることを特徴とする。
The present invention according to claim 4 provides:
The multilayer film laminated on the phase defect portion is laminated after the capping film of the phase defect portion is peeled off.

請求項5に記載の本発明は、前記位相欠陥部上に積層される多層膜は、前記位相欠陥部のキャッピング膜、および該キャッピング膜の下の多層膜の一部を剥離した上に積層されることを特徴とする。   According to the fifth aspect of the present invention, the multilayer film laminated on the phase defect portion is laminated after peeling off the capping film of the phase defect portion and a part of the multilayer film under the capping film. It is characterized by that.

請求項6に記載の本発明は、前記位相欠陥部上に積層される多層膜は、前記位相欠陥部のキャッピング膜、および該キャッピング膜の下の多層膜、さらにその下の欠陥を剥離した上に積層されることを特徴とする。   The multilayer film laminated on the phase defect portion may be formed by peeling a capping film of the phase defect portion, a multilayer film under the capping film, and a defect below the multilayer film. It is characterized by being laminated on.

本発明の反射型マスクの位相欠陥修正方法によると、位相欠陥部に2種類の好適な材料からなる多層膜を、欠陥部の反射率の低下と位相差に応じて、最適な膜厚と層数で形成するので、精度よく、反射率及び位相差の修正を行うことができる。   According to the phase defect correcting method for a reflective mask of the present invention, a multilayer film made of two kinds of suitable materials is applied to the phase defect portion according to the decrease in the reflectance of the defect portion and the phase difference. Since they are formed by numbers, the reflectance and the phase difference can be corrected with high accuracy.

本発明の実施の形態に関わる位相欠陥修正方法により修正された反射型マスクの修正部を示す断面模式図である。It is a cross-sectional schematic diagram which shows the correction | amendment part of the reflective mask corrected by the phase defect correction method in connection with embodiment of this invention. 本発明の実施の形態に関わる位相欠陥修正方法により修正された別の反射型マスクの修正部を示す断面模式図である。It is a cross-sectional schematic diagram which shows the correction part of another reflection type mask corrected by the phase defect correction method in connection with embodiment of this invention. 位相欠陥を持つ反射型マスクの一部を示す断面模式図である。It is a cross-sectional schematic diagram which shows a part of reflective mask with a phase defect. 位相欠陥を持つ反射型マスクを示す断面模式図(a)、及びこのときの反射率(b)と位相差(c)を計算した結果を示す特性図である。It is a cross-sectional schematic diagram (a) which shows the reflection type mask with a phase defect, and a characteristic view which shows the result of having calculated the reflectance (b) and phase difference (c) at this time. 位相欠陥を持つ別の反射型マスクを示す断面模式図である。It is a cross-sectional schematic diagram which shows another reflection type mask with a phase defect. 反射率と位相差を計算するために用いた材料の波長13.52nmにおける光学定数(屈折率、消衰係数)を示す表である。It is a table | surface which shows the optical constant (refractive index, extinction coefficient) in wavelength 13.53nm of the material used in order to calculate a reflectance and a phase difference. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention. 本発明の位相欠陥修正方法に係る修正用多層膜の膜厚を求めるための、位相差と反射率を計算した結果を示す特性図である。It is a characteristic view which shows the result of having calculated the phase difference and the reflectance for calculating | requiring the film thickness of the multilayer film for correction which concerns on the phase defect correction method of this invention.

以下、本発明を実施する形態を、図面を参照しつつ説明する。実施の形態において、同一構成要素には同一符号を付け、実施の形態において重複する説明は省略する。
(実施の形態)
図1はEUVマスクの位相欠陥部を本発明の方法により修正した後の断面を模式的に示す図である。ここで、突起欠陥3は基板1’の直上にあり、多層膜2は、その上に積層されている。多層膜2の最上層は、Siなどからなるキャッピング層となっている(図では省略)。さらに、7は位相欠陥を修正するために積層した多層膜である。修正用多層膜7は、多層膜2のキャッピング膜の上に積層されているか、あるいは、反射率、位相差の状況によっては位相欠陥部のキャッピング膜まで、若しくは多層膜2の上部数対までを剥離した上に積層されている。
DESCRIPTION OF EMBODIMENTS Hereinafter, embodiments for carrying out the present invention will be described with reference to the drawings. In the embodiments, the same components are denoted by the same reference numerals, and redundant description in the embodiments is omitted.
(Embodiment)
FIG. 1 is a view schematically showing a cross section after correcting a phase defect portion of an EUV mask by the method of the present invention. Here, the protrusion defect 3 is located immediately above the substrate 1 ′, and the multilayer film 2 is laminated thereon. The uppermost layer of the multilayer film 2 is a capping layer made of Si or the like (not shown in the figure). Further, reference numeral 7 denotes a multilayer film laminated for correcting phase defects. The correction multilayer film 7 is laminated on the capping film of the multilayer film 2, or depending on the reflectivity and phase difference, the capping film of the phase defect portion or the upper pair of the multilayer film 2 is covered. It is laminated on the peeled.

図2はEUVマスクの別の位相欠陥部を本発明の方法により修正した後の断面を模式的に示す図である。ここで、突起欠陥3’は多層膜2’の途中に存在している。多層膜2’の最上層は、Siなどからなるキャッピング層となっている(図では省略)。さらに、7’は位相欠陥を修正するために積層した多層膜である。修正用多層膜7’は、多層膜2’のキャッピング膜の上に積層されているか、あるいは、反射率、位相差の状況によっては位相欠陥部のキャッピング膜まで、若しくは多層膜2’の上部数対まで、若しくは欠陥3’までを剥離した上に積層されている。   FIG. 2 is a view schematically showing a cross section after another phase defect portion of the EUV mask is corrected by the method of the present invention. Here, the protrusion defect 3 'exists in the middle of the multilayer film 2'. The uppermost layer of the multilayer film 2 'is a capping layer made of Si or the like (not shown in the figure). Further, 7 'is a multilayer film laminated to correct the phase defect. The correcting multilayer film 7 ′ is laminated on the capping film of the multilayer film 2 ′, or depending on the reflectivity and phase difference, up to the capping film of the phase defect portion, or the upper number of the multilayer film 2 ′. It is laminated after peeling up to the pair or up to the defect 3 ′.

以下、本発明の位相欠陥修正方法が有効であることを、光学薄膜理論による反射率、位相差の計算によって確認した結果を示す。尚、計算において、波長はEUV露光に典型的
な13.52nm、このときの薄膜材料の光学定数は図6に示した値を用いた。また、高反射用のMo/Si多層膜は50対(各層における膜厚は、S:4.16nm、Mo:2.80nm)、キャッピング膜は一般的なSi:11nm厚、突起欠陥の材質はSi、突起欠陥部の上に成膜される多層膜の各層の厚さは、正常な高反射部に成膜される膜厚よりも各々2%薄いとして計算したが、これらの材質や数字が多少変わっても、本発明の方法の有効性には影響しない。
Hereinafter, the results of confirming that the phase defect correcting method of the present invention is effective by calculating the reflectance and the phase difference according to the optical thin film theory will be shown. In the calculation, the wavelength is 13.52 nm, which is typical for EUV exposure, and the values shown in FIG. 6 are used as the optical constants of the thin film material. Moreover, 50 pairs of Mo / Si multilayer films for high reflection (the film thickness in each layer is S: 4.16 nm, Mo: 2.80 nm), the capping film is a general Si: 11 nm thickness, and the material of the protrusion defect is The thickness of each layer of the multilayer film formed on Si and the protrusion defect part was calculated as 2% thinner than the film thickness formed on the normal high reflection part. Some variation does not affect the effectiveness of the method of the present invention.

上記の反射率、位相差の計算は、本発明の方法により、位相欠陥部に修正用多層膜を成膜した後の反射率、位相差を計算することで行った。この際、突起欠陥が基板真上にある場合(図4(a))、通常の高反射用多層膜の中央にある場合(図5)によって分け、突起欠陥の高さは3nmと5nmの2通りとし、計算図の横軸は、修正用多層膜の片方の材料の1層あたりの膜厚とした。このとき修正用多層膜の1対あたりの合計膜厚は通常のMo/Si多層膜と同じとした。これは、干渉によって反射率が向上する合計膜厚は、材料に依らずほぼ半波長であることが理論上分かっているからである。   The above-described reflectance and phase difference were calculated by calculating the reflectance and phase difference after forming the correction multilayer film in the phase defect portion by the method of the present invention. At this time, when the protrusion defect is directly above the substrate (FIG. 4A), the protrusion defect is divided into the case where it is in the center of the normal high reflection multilayer film (FIG. 5). The horizontal axis of the calculation diagram is the film thickness per layer of one material of the correction multilayer film. At this time, the total film thickness per pair of the correction multilayer film was the same as that of the normal Mo / Si multilayer film. This is because it is theoretically known that the total film thickness at which the reflectance is improved by the interference is almost a half wavelength regardless of the material.

図7は、基板真上に高さ3nmのSi突起(パーティクル)からなる位相欠陥があるときに、位相欠陥部にSiとMoからなる修正用多層膜を19対積層したときの、正常な高反射領域からの反射光5と修正部からの反射光8(図1参照)の位相差、及び反射光5による反射率Rmと反射光8による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。尚、位相差の図で、0°と360°の間には「飛び」が生じているが、これは計算に使用したソフトの表示上の都合によるもので、実際は連続している。図7から分かるように、修正用Si膜の1層あたりの膜厚がほぼ4nmのときに反射光5と反射光8の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   FIG. 7 shows a normal height when 19 pairs of correction multilayer films made of Si and Mo are stacked in the phase defect portion when there is a phase defect made of Si protrusions (particles) having a height of 3 nm directly above the substrate. The phase difference between the reflected light 5 from the reflection region and the reflected light 8 from the correction unit (see FIG. 1), and the reflectance Rm by the reflected light 5 and the reflectance Rd by the reflected light 8 per layer of the Si film for correction It shows the result of calculation with the film thickness of as a horizontal axis. In the phase difference diagram, a “jump” occurs between 0 ° and 360 °, but this is due to the display on the software used for the calculation and is actually continuous. As can be seen from FIG. 7, the phase difference between the reflected light 5 and the reflected light 8 becomes substantially zero when the thickness of the Si film for correction is approximately 4 nm, and the reflectance Rd of the defect portion is a normal portion. It can be seen that the correction is made almost equal to the reflectance Rm.

図8は、基板真上に高さ5nmのSi突起からなる位相欠陥があるときに、位相欠陥部のSi:11nm厚からなるキャッピング膜を剥離した後、SiとMoからなる修正用多層膜を27対積層したときの、反射光5と反射光8(図1参照)の位相差、及び反射光5による反射率Rmと反射光8による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図8から分かるように、修正用Si膜の1層あたりの膜厚がほぼ3.5nmのときに反射光5と反射光8の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   FIG. 8 shows that when there is a phase defect consisting of a Si protrusion having a height of 5 nm directly above the substrate, a capping film having a thickness of Si: 11 nm in the phase defect portion is peeled off, and then a correction multilayer film made of Si and Mo is formed. When 27 pairs are stacked, the phase difference between the reflected light 5 and the reflected light 8 (see FIG. 1), and the reflectance Rm by the reflected light 5 and the reflectance Rd by the reflected light 8 are obtained for each layer of the Si film for correction. The results of calculation with the film thickness as the horizontal axis are shown. As can be seen from FIG. 8, the phase difference between the reflected light 5 and the reflected light 8 is substantially zero when the thickness of the Si film for correction is approximately 3.5 nm, and the reflectance Rd of the defect portion is It can be seen that the correction is made almost equal to the reflectance Rm of the normal part.

図9は、基板真上に高さ3nmのSi突起からなる位相欠陥があるときに、位相欠陥部にSiとRu(ルテニウム)からなる修正用多層膜を19対積層したときの、反射光5と反射光8(図1参照)の位相差、及び反射光5による反射率Rmと反射光8による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図9から分かるように、修正用Si膜の1層あたりの膜厚がほぼ4.4nmのときに反射光5と反射光8の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   FIG. 9 shows reflected light 5 when 19 pairs of correction multilayer films made of Si and Ru (ruthenium) are laminated on the phase defect portion when there is a phase defect made of a Si protrusion having a height of 3 nm directly above the substrate. And the phase difference between the reflected light 8 (see FIG. 1), and the reflectance Rm by the reflected light 5 and the reflectance Rd by the reflected light 8 are calculated with the film thickness per layer of the correction Si film as the horizontal axis. It is shown. As can be seen from FIG. 9, when the thickness of the Si film for correction is approximately 4.4 nm, the phase difference between the reflected light 5 and the reflected light 8 is substantially 0, and the reflectance Rd of the defect portion is It can be seen that the correction is made almost equal to the reflectance Rm of the normal part.

図10は、基板真上に高さ5nmのSi突起からなる位相欠陥があるときに、位相欠陥部のSi:11nm厚からなるキャッピング膜を剥離後、SiとRuからなる修正用多層膜を28対積層したときの、反射光5と反射光8(図1参照)の位相差、及び反射光5による反射率Rmと反射光8による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図10から分かるように、修正用Si膜の1層あたりの膜厚がほぼ4.2nmのときに反射光5と反射光8の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   FIG. 10 shows that when there is a phase defect composed of a Si protrusion having a height of 5 nm directly above the substrate, a correction multilayer film composed of Si and Ru is removed after removing the capping film composed of Si: 11 nm thick in the phase defect portion. The phase difference between the reflected light 5 and the reflected light 8 (see FIG. 1) and the reflectance Rm due to the reflected light 5 and the reflectance Rd due to the reflected light 8 when the layers are laminated are determined as a film per layer of the Si film for correction. The results of calculation with the thickness as the horizontal axis are shown. As can be seen from FIG. 10, the phase difference between the reflected light 5 and the reflected light 8 becomes substantially zero when the thickness of the Si film for correction is approximately 4.2 nm, and the reflectance Rd of the defect portion is It can be seen that the correction is made almost equal to the reflectance Rm of the normal part.

図11は、通常多層膜の中央に高さ3nmのSi突起からなる位相欠陥があるときに、位相欠陥部のSi:11nm厚からなるキャッピング膜を剥離後、位相欠陥部にSiとMoからなる修正用多層膜を21対積層したときの、正常な高反射領域からの反射光5と修正部からの反射光8’(図2参照)の位相差、及び反射光5による反射率Rmと反射光8’による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図11から分かるように、修正用Si膜の1層あたりの膜厚がほぼ3.7nmのときに反射光5と反射光8’の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   FIG. 11 shows that when there is a phase defect consisting of a Si protrusion having a height of 3 nm at the center of the multilayer film, the phase defect part is made of Si and Mo after peeling the capping film made of Si: 11 nm thick. When 21 pairs of correction multilayer films are laminated, the phase difference between the reflected light 5 from the normal high reflection region and the reflected light 8 ′ from the correction portion (see FIG. 2), and the reflectance Rm and reflection by the reflected light 5 The reflectance Rd by light 8 'shows the result of having calculated the film thickness per layer of Si film for correction | amendment with a horizontal axis. As can be seen from FIG. 11, when the thickness of the Si film for correction is approximately 3.7 nm, the phase difference between the reflected light 5 and the reflected light 8 ′ becomes substantially zero, and the reflectance Rd of the defect portion. Is substantially equal to the reflectance Rm of the normal part, and it can be seen that correction is made.

図12は、通常多層膜の中央に高さ5nmのSi突起からなる位相欠陥があるときに、SiとMoからなる修正用多層膜を25対積層したときの、反射光5と反射光8’(図2参照)の位相差、及び反射光5による反射率Rmと反射光8’による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図12から分かるように、修正用Si膜の1層あたりの膜厚がほぼ3.9nmのときに反射光5と反射光8’の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   FIG. 12 shows reflected light 5 and reflected light 8 ′ when 25 pairs of correction multilayer films made of Si and Mo are laminated when there is a phase defect made of a Si protrusion having a height of 5 nm at the center of the multilayer film. The phase difference of (refer FIG. 2) and the result of having calculated the reflectance Rm by the reflected light 5 and the reflectance Rd by the reflected light 8 'by setting the film thickness per one layer of the Si film for correction to the horizontal axis. is there. As can be seen from FIG. 12, when the thickness of the Si film for correction is approximately 3.9 nm, the phase difference between the reflected light 5 and the reflected light 8 ′ becomes substantially zero, and the reflectance Rd of the defect portion. Is substantially equal to the reflectance Rm of the normal part, and it can be seen that correction is made.

図13は、通常多層膜の中央に高さ5nmのSi突起からなる位相欠陥があるときに、SiとRuからなる修正用多層膜を25対積層したときの、反射光5と反射光8’(図2参照)の位相差、及び反射光5による反射率Rmと反射光8’による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図13から分かるように、修正用Si膜の1層あたりの膜厚がほぼ4.3nmのときに反射光5と反射光8’の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   FIG. 13 shows reflected light 5 and reflected light 8 ′ when 25 pairs of correction multilayer films made of Si and Ru are laminated when there is a phase defect consisting of a Si protrusion having a height of 5 nm in the center of the multilayer film. The phase difference of (refer FIG. 2) and the result of having calculated the reflectance Rm by the reflected light 5 and the reflectance Rd by the reflected light 8 'by setting the film thickness per one layer of the Si film for correction to the horizontal axis. is there. As can be seen from FIG. 13, the phase difference between the reflected light 5 and the reflected light 8 ′ becomes substantially zero when the thickness of the Si film for correction is about 4.3 nm, and the reflectance Rd of the defect portion. Is substantially equal to the reflectance Rm of the normal part, and it can be seen that correction is made.

位相欠陥部の位相差、反射率の状況は、原因となる突起(パーティクル)欠陥の位置、大きさ、材料によって異なる。従って状況によっては、位相欠陥部のキャッピング膜のみならずその下の多層膜の上部数対を剥離した上に、修正用多層膜を積層する方がよい場合もある。図14は、基板真上に高さ5nmのSi突起からなる位相欠陥があるときに、位相欠陥部のSi:11nm厚からなるキャッピング膜を剥離し、さらにその下の2%薄い多層膜を5対剥離後、位相欠陥部にSiとRuからなる修正用多層膜を30対積層したときの、反射光5と反射光8(図1参照)の位相差、及び反射光5による反射率Rmと反射光8による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図14から分かるように、修正用Si膜の1層あたりの膜厚がほぼ4.8nmのときに反射光5と反射光8の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   The phase difference and reflectivity of the phase defect portion vary depending on the position, size, and material of the causal protrusion (particle) defect. Therefore, depending on the situation, it may be better to laminate not only the capping film of the phase defect portion but also the upper several pairs of the multilayer film below it, and then laminating the correction multilayer film. FIG. 14 shows that when there is a phase defect consisting of a Si protrusion having a height of 5 nm directly above the substrate, the capping film made of Si: 11 nm thick in the phase defect portion is peeled off, and a 2% thin multilayer film thereunder is further removed. After the peeling, the phase difference between the reflected light 5 and the reflected light 8 (see FIG. 1) and the reflectance Rm by the reflected light 5 when 30 pairs of correction multilayer films made of Si and Ru are laminated on the phase defect portion The result of calculating the reflectance Rd by the reflected light 8 with the film thickness per layer of the Si film for correction as the horizontal axis is shown. As can be seen from FIG. 14, when the thickness of the Si film for correction is approximately 4.8 nm, the phase difference between the reflected light 5 and the reflected light 8 is substantially 0, and the reflectance Rd of the defect portion is It can be seen that the correction is made almost equal to the reflectance Rm of the normal part.

位相欠陥の原因となる突起(パーティクル)欠陥は、その欠陥の位置が通常多層膜の表面に近いほど、及び材料的にEUV光の吸収性が大きいほど、通常の黒欠陥(または振幅欠陥)に近いものとなってくる。この場合は反射率の低下が大きいとともに、高反射部との位相差も残った欠陥となる。このような場合は、欠陥部のキャッピング膜、薄い多層膜だけでなく、欠陥自身も剥離した後に、修正用多層膜を積層する方が効果的である。図15は、2%薄い多層膜の上から10層目にSi突起があるときに、位相欠陥部のSi:11nm厚からなるキャッピング膜を剥離し、続けてその下の薄い多層膜を10対剥離し、さらに突起欠陥自身を剥離した後、SiとRuからなる修正用多層膜を28対積層したときの、反射光5と反射光8’(図2参照)の位相差、及び反射光5による反射率Rmと反射光8’による反射率Rdを、修正用Si膜の1層あたりの膜厚を横軸として計算した結果を示すものである。図15から分かるように、修正用Si膜の1層あたりの膜厚がほぼ4.3nmのときに反射光5と反射光8’の位相差はほぼ0になるとともに、欠陥部の反射率Rdは正常部の反射率Rmにほぼ等しくなり、修正がなされることが分かる。   Protrusion (particle) defects that cause phase defects usually become black defects (or amplitude defects) as the position of the defects is closer to the surface of the multilayer film and as the material absorbs more EUV light. It will be close. In this case, the reflectivity is greatly lowered, and the phase difference from the highly reflective portion remains. In such a case, it is more effective to stack the multilayer film for correction after the defect itself is peeled off as well as the capping film of the defective portion and the thin multilayer film. FIG. 15 shows that when there is a Si protrusion on the 10th layer from the top of the 2% thin multilayer film, the capping film having a Si: 11 nm thickness at the phase defect portion is peeled off, and then 10 pairs of the thin multilayer films thereunder are separated. The phase difference between the reflected light 5 and the reflected light 8 ′ (see FIG. 2) and the reflected light 5 when the pair of correction multilayer films made of Si and Ru are laminated after peeling and further removing the projection defect itself. 2 shows the result of calculation of the reflectance Rm by the reflected light and the reflectance Rd by the reflected light 8 ′ with the film thickness per layer of the correction Si film as the horizontal axis. As can be seen from FIG. 15, the phase difference between the reflected light 5 and the reflected light 8 ′ becomes almost zero when the thickness of the Si film for correction is about 4.3 nm, and the reflectance Rd of the defect portion. Is substantially equal to the reflectance Rm of the normal part, and it can be seen that correction is made.

本発明での修正用多層膜の形成方法は、従来の透過型フォトマスクにおける白欠陥修正方法を応用することができる。まず、あらかじめ転写露光、または光学的測定、またはサブミクロンオーダーに絞ったFIB(集束イオンビーム)でパターン表面を走査し、表面から放出される2次電子を検出してディスプレイ上に走査イオン像としてとらえること等により、位相欠陥部を特定する。次に照射処理室内に修正のために形成する材料を含むガスを導入し、FIBを位相欠陥部に照射することでガスを分解しつつ修正用多層膜を形成していく。ガスとしては、Si系膜のためのSiH(CH)、Ru(ルテニウム)膜を形成するためのルテニウムカルボニル(Ru(CO)12)(特許文献2)や、ルテニウムのペンタジエニル化合物(特許文献3)、C(カーボン膜)を形成するためのスチレンやピレン等の炭素系のガスなど、金属または半導体元素を含む有機系のガスを用いることができる。 As a method for forming a correction multilayer film in the present invention, a white defect correction method in a conventional transmission type photomask can be applied. First, the pattern surface is scanned by FIB (focused ion beam) focused in advance by transfer exposure, optical measurement, or sub-micron order, and secondary electrons emitted from the surface are detected to form a scanned ion image on the display. The phase defect portion is specified by grasping. Next, a gas including a material to be formed for correction is introduced into the irradiation processing chamber, and the phase defect portion is irradiated with FIB to form a correction multilayer film while decomposing the gas. Examples of gases include SiH (CH 3 ) 3 for Si-based films, ruthenium carbonyl (Ru 3 (CO) 12 ) for forming Ru (ruthenium) films (Patent Document 2), and pentadienyl compounds of ruthenium (patents). Reference 3), organic gases containing metals or semiconductor elements such as carbon-based gases such as styrene and pyrene for forming C (carbon film) can be used.

本発明のうち、修正用多層膜を形成する前にあらかじめ、キャッピング膜、さらに位相差、反射率の状況によっては薄い多層膜、突起欠陥まで剥離するときにも従来の透過型フォトマスクにおける黒欠陥修正方法を応用することができる。すなわち、剥離する膜よりも硬い探針を有する原子力間顕微鏡の探針を用いて削り取る方法や、FIBをパターン表面に照射し、表面上の原子や分子を真空中にはじき出す(スパッタリング現象)方法、またはFIBにより塩素(Cl)ガスなどのエッチングガスを分解させて反応させる方法により被剥離膜を除去することができる。 In the present invention, before forming a correction multilayer film, a black defect in a conventional transmissive photomask is also obtained when a capping film, a thin multilayer film depending on the phase difference and reflectivity, and a protrusion defect are peeled off in advance. A correction method can be applied. That is, a method of scraping using a probe of an atomic force microscope having a probe harder than a film to be peeled off, a method of irradiating a pattern surface with FIB and ejecting atoms and molecules on the surface into a vacuum (sputtering phenomenon), Alternatively, the film to be peeled can be removed by a method in which an etching gas such as chlorine (Cl 2 ) gas is decomposed and reacted with FIB.

本発明は、半導体集積回路等の製造に際して使用される、EUV露光用等の反射型フォトマスクの高反射部に存在する位相欠陥の修正に広範に適用することができる。   The present invention can be widely applied to the correction of phase defects existing in the high reflection portion of a reflective photomask for EUV exposure, etc. used in the manufacture of semiconductor integrated circuits and the like.

1……反射型マスク基板
1’……反射型マスク基板の一部
2……基板直上に突起欠陥を持つ多層膜
2’……多層膜中央に突起欠陥を持つ多層膜
2a……キャッピング膜
3……基板真上の突起欠陥
3’……多層膜中央の突起欠陥
4……基板真上の突起欠陥により盛り上がった多層膜の部分
4’……多層膜中央の突起欠陥により盛り上がった多層膜の部分
5……高反射部の反射光
6……基板真上の突起欠陥により盛り上がった部分の反射光
6’……多層膜中央の突起欠陥により盛り上がった部分の反射光
7……基板真上の突起による位相欠陥を修正した部分
7’……多層膜中央の突起による位相欠陥を修正した部分
8……基板真上の突起による位相欠陥を修正した部分の反射光
8’……多層膜中央の突起による位相欠陥を修正した部分の反射光
DESCRIPTION OF SYMBOLS 1 ... Reflective type mask substrate 1 '...... Part of the reflective type mask substrate 2 ... Multilayer film 2' having a projection defect immediately above the substrate ... Multilayer film 2a having a projection defect at the center of the multilayer film ... Capping film 3 ... Protrusion defect 3 'directly above the substrate .... Protrusion defect 4 in the center of the multilayer film .... Multilayer film portion 4' raised due to the protrusion defect directly above the substrate .... Multilayer film raised due to the protrusion defect in the center of the multilayer film. Part 5 …… Reflected light 6 of the highly reflective part …… Reflected light 6 ′ raised due to the protrusion defect right above the substrate 6 …… Reflected light 7 swelled due to the protrusion defect at the center of the multilayer film 7 Portion 7 'corrected phase defect due to protrusion 8 ... Portion corrected phase defect due to protrusion at the center of the multilayer film 8 Reflected light 8' corrected phase defect due to protrusion directly above the substrate 8 '... Reflected light at the part where phase defects due to protrusions are corrected

Claims (6)

MoとSiを交互に積層して多層膜とした反射型フォトマスクの高反射部に発生した位相欠陥を修正する方法であって、
位相欠陥部上に、一方がSi(シリコン)である2種類の材料からなる多層膜を積層することにより、該位相欠陥部と高反射部の位相差を実用上0(ゼロ)とし、該位相欠陥部の反射率と高反射部の反射率を実用上等しくするにあたり、
前記位相欠陥部上に積層されるSi(シリコン)の1層あたりの膜厚は、高反射部に使用されるSiの1層あたりの膜厚と異なることを特徴とする反射型フォトマスクの位相欠陥修正方法。
A method of correcting a phase defect generated in a highly reflective portion of a reflective photomask in which Mo and Si are alternately laminated to form a multilayer film ,
By laminating a multilayer film made of two kinds of materials , one of which is Si (silicon) , on the phase defect portion, the phase difference between the phase defect portion and the high reflection portion is practically 0 (zero), and the phase In practically equalizing the reflectance of the defective part and the reflectance of the highly reflective part ,
The phase of a reflective photomask characterized in that the film thickness per layer of Si (silicon) laminated on the phase defect portion is different from the film thickness per Si layer used in the high reflection portion. Defect correction method.
前記位相欠陥部上に積層される2種類の材料の他方はMo(モリブデン)であることを特徴とする請求項に記載の反射型フォトマスクの位相欠陥修正方法。 2. The method of correcting a phase defect in a reflective photomask according to claim 1 , wherein the other of the two kinds of materials laminated on the phase defect portion is Mo (molybdenum). 前記位相欠陥部上に積層される2種類の材料の他方はRu(ルテニウム)であることを特徴とする請求項に記載の反射型フォトマスクの位相欠陥修正方法。 2. The method of correcting a phase defect in a reflective photomask according to claim 1 , wherein the other of the two kinds of materials laminated on the phase defect portion is Ru (ruthenium). 前記位相欠陥部上に積層される多層膜は、前記位相欠陥部のキャッピング膜を剥離した上に積層されることを特徴とする請求項1乃至のいずれかに記載の反射型フォトマスクの位相欠陥修正方法。 The multilayer film is laminated on the phase defect, said reflection type photomask as claimed in any one of claims 1 to 3, characterized in that it is laminated on peeling off the capping layer of the phase defect phase Defect correction method. 前記位相欠陥部上に積層される多層膜は、前記位相欠陥部のキャッピング膜、および該キャッピング膜の下の多層膜の一部を剥離した上に積層されることを特徴とする請求項1乃至のいずれかに記載の反射型フォトマスクの位相欠陥修正方法。 The multilayer film laminated on the phase defect portion is laminated after peeling off a capping film of the phase defect portion and a part of the multilayer film under the capping film. 4. The phase defect correcting method for a reflective photomask according to any one of 3 above. 前記位相欠陥部上に積層される多層膜は、前記位相欠陥部のキャッピング膜、および該キャッピング膜の下の多層膜、さらにその下の欠陥を剥離した上に積層されることを特徴とする請求項1乃至のいずれかに記載の反射型フォトマスクの位相欠陥修正方法。 The multilayer film stacked on the phase defect portion is formed by peeling a capping film of the phase defect portion, a multilayer film below the capping film, and further removing a defect below the multilayer film. Item 4. A method for correcting a phase defect in a reflective photomask according to any one of Items 1 to 3 .
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