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JP4070661B2 - Absorber manufacturing method - Google Patents

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Publication number
JP4070661B2
JP4070661B2 JP2003121074A JP2003121074A JP4070661B2 JP 4070661 B2 JP4070661 B2 JP 4070661B2 JP 2003121074 A JP2003121074 A JP 2003121074A JP 2003121074 A JP2003121074 A JP 2003121074A JP 4070661 B2 JP4070661 B2 JP 4070661B2
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suction
region
absorber
basis weight
opening area
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JP2003121074A
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JP2004065930A (en
Inventor
大介 保村
真人 大島
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Kao Corp
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Kao Corp
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Priority to JP2003121074A priority Critical patent/JP4070661B2/en
Priority to DE60325672T priority patent/DE60325672D1/en
Priority to EP03012919A priority patent/EP1371348B2/en
Priority to TW092115530A priority patent/TWI270371B/en
Priority to US10/456,833 priority patent/US7297307B2/en
Priority to CNB031413307A priority patent/CN100508928C/en
Publication of JP2004065930A publication Critical patent/JP2004065930A/en
Priority to US11/764,054 priority patent/US20070244453A1/en
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Description

【0001】
【発明の属する技術分野】
本発明は、吸収容量を部分的に高く設計した部位を有し、該部位の吸収性能を十分に発現させることのできる吸収性能に優れた吸収体を、効率的且つ経済的に製造することのできる吸収体の製造方法に関する。
【0002】
【従来の技術及び発明が解決しようとする課題】
一般に、吸収性物品の吸収容量は、その用途に応じて設計される。例えば、使い捨ておむつの場合、新生児用から介護が必要な大人まで、幅広いユーザーが対象であり、その各々について吸収容量を設計する必要がある。
【0003】
例えば、新生児用は、その排泄物の殆どが軟便であることから、軟便に対応するために、おむつ長手方向中央部から後方部(背側)にかけての便吸収性能を高めるように設計することがあり、幼児用や大人用は、大量の排尿に対応するために、長手方向中央部から前方部(腹側)にかけての尿吸収性能を高めるように設計することがある。前者の場合には、新生児用であるため、全体の吸収容量をあまり高く設計しなくても漏れが生じることはあまりない。一方、後者の場合には、排尿が中心でしかもその量が多いことから、おむつ長手方向中央部から前方部の吸収容量を高める必要があり、その目的から、高吸水性ポリマーが前方に多くなるようにポリマーをパターン散布したり、前方のみを2層に重ねた吸収体構造とする方法が知られている。
【0004】
しかし、高吸水性ポリマーをパターン散布した場合には、パターン散布用の設備が必要である上に、散布パターンと散布されるシート基材とを正確に位置合わせする装置等が必要であり、更に散布パターンの位置を製造ライン上で検出しにくいという問題がある。また、場合によっては、ポリマーリッチな部位からのポリマー漏れが生じたり、ゲルブロッキングが生じる怖れがあり、期待した程の吸収容量が発現しないことがある。
前方のみを2層に重ねた吸収体としては、下層吸収体の一部に、別に製造した上層吸収体を積層した吸収体や、単一の層からなる吸収体の一部を折り返して2層の部分を形成した吸収体が知られているが、前者は、2種類の吸収体を製造するために、例えば積繊装置が複数必要になり、後者は、折り返し装置等が必要となるなど、何れの吸収体も製造設備が複雑となり、安価で高性能の吸収体を提供することができない。更には、上層の吸収体のポリマーが吸液膨潤してゲルブロッキングが生じると、下層の吸収体に液がスムーズに移行しなくなることがあるため、結果として前方に、ポリマーやパルプ繊維等の吸収性材料の量に見合った吸収性能が得られず、場合によっては漏れの原因となる。また、前方のみを2層に重ねた吸収体の場合には、後方の一層構造の部分との境界に剛性の差が生じる等により、着用時に違和感を感じることがある。
【0005】
所定の部位を高坪量とする製造方法として、特開昭62−206071号公報(特許文献1)には繊維素材を堆積させる平面プレートの一部に特定形状の凹部を設け、該凹部には高い圧力が加わるように凹部下を工夫した技術が開示されている。しかし、当該公報には、繊維素材の堆積についてしか記載がなく、高吸水性ポリマーとパルプの混合系については考慮されていない。しかも、当該方法では、高坪量とする部位に、開孔を有しない傾斜部を有する凹部を設けているため、当該個所には直接吸引力が発生せず、プレートの平坦部分と凹部とでは、物理的に不連続な堆積物構造になる可能性が高い。しかも、傾斜部では気流の乱れが生じたりするため、高吸水性ポリマーとパルプの混合系では混合比率が乱れて所望の吸収性能が得られない。
【0006】
また、特開2000−234255号公報(特許文献2)には、集積用凹部の底面部に、開口率の異なる複数の吸引領域を設け、これらの吸引領域に原料を吸引堆積させて高さや密度の異なる領域を有する繊維成形体を製造する方法が記載されている。しかし、当該公報には、具体的に高吸水性ポリマーとパルプ繊維の混合系で製造した場合についての記載がなく、また、凹部内に段差を設けて高さと密度を制御するもので、坪量の制御については記載がない。しかも、当該段差部分によって吸収体搬送時に吸収体が壊れてしまったりする可能性がある。
【0007】
【特許文献1】
特開昭62−206071号公報
【特許文献2】
特開2000−234255号公報
【0008】
従って、本発明の目的は、吸収容量を部分的に高く設計した部位を有し、該部位の吸収性能を十分に発現させることのできる吸収性能に優れた吸収体を、簡易な設備で効率的且つ経済的に製造することのできる吸収体の製造方法を提供することにある。
【0009】
【課題を解決するための手段】
本発明は、高吸水性ポリマー及びパルプ繊維を飛散状態で供給し、底面部に多数の吸引孔を設けた集積用凹部に吸引堆積させ、前記高吸水性ポリマー及び前記パルプ繊維の堆積物を、前記集積用凹部内から離型して吸収体を製造する吸収体の製造方法であって、前記集積用凹部の底面部に、開口面積率の高い第1吸引領域と第1吸引領域よりも開口面積率の低い第2吸引領域を設け、第1吸引領域の開口面積率R1を40〜80%、第2吸引領域の開口面積率R2を2〜20%、両開口面積率の比(Rl/R2)を70/30〜99/1の範囲とし、これら両吸引領域に前記高吸水性ポリマー及び前記パルプ繊維を堆積させることを特徴とする吸収体の製造方法を提供することにより、上記の目的を達成したものである。
【0010】
【発明の実施の形態】
以下、本発明をその好ましい実施形態に基いて説明する。
先ず、本発明の吸収体の製造方法により製造される吸収体の好ましい例について説明する。図1及び図2に示される吸収体4は、使い捨ておむつ1用の吸収体である。使い捨ておむつ1は、液透過性の表面シート2、液不透過性の裏面シート3、及び両シート2,3間に介在された液保持性の吸収体4を具備し、実質的に縦長に形成されており、長手方向の一端から他端に向かって、着用時に着用者の背側に配される背側部A、股下に配される股下部B及び腹側に配される腹側部Cを順に有している。使い捨ておむつ1は、いわゆる展開型の使い捨ておむつであり、背側部Aの左右両側縁部におむつ止着用のファスニングテープ11を有しており、対応するランディングテープ12を、腹側部Cの外表面に有している。
【0011】
吸収体4は、高吸水性ポリマー及びパルプ繊維からなり、該高吸水性ポリマー及び該パルプ繊維それぞれの坪量が、他の部位である低坪量領域42よりも高い高坪量領域41を有している。尚、高吸水性ポリマー及びパルプ繊維を含有するという表現には、高吸水性ポリマー及びパルプ繊維以外の成分を含む場合と、高吸水性ポリマー及びパルプ繊維以外の成分を含まない場合の両者が含まれる。
高坪量領域41は、吸収体4の長手方向の両端の内、おむつ1の着用時に着用者の腹側に配される側の一端4a側に偏倚した位置に形成されており、より具体的には、おむつ1における、着用者の排尿部に対向配置される部位(股下部Bから腹側部Cに亘る部位)に形成されている。
【0012】
高坪量領域41及び低坪量領域42は、物理的に連続した一体構造で形成されている。即ち、両領域は、単一の構造体を形成しており、両領域間には別個の吸収体を連結した様な界面が存在していない。尚、高坪量領域41における吸収体4の厚みは、低坪量領域42における吸収体4の厚みよりも若干厚い。
【0013】
両領域41、42に亘る吸収体4の断面構造(厚み方向の断面構造)は、従来の2層構造の吸収体、即ち下層吸収体の上に、別に製造した上層吸収体を積層した吸収体や、単一の層からなる吸収体の一部を折り返して2層の部分を形成した吸収体における断面構造とは異なるものである。具体的には、図2(b)のように高坪量領域と低坪量領域との間に不連続さがなく単一の構造となっている。
吸収体4は、図2(b)に示すように、高坪量領域41及び低坪量領域42の両領域が、各々厚み方向に複数の層からなっている。具体的には、両領域41,42は、それぞれ、厚み方向にパルプ繊維を主体とする上層41a、高吸水性ポリマーを主体とする中間層41b、及びパルプ繊維を主体とする下層41cを有している。そして、その複数の層41a〜41cのいずれもが両領域に亘って物理的に連続した一体構造をなしている。
従来技術では、高坪量の部分と低坪量の部分の間に物理的不連続さが生じてしまうのである。本発明においては高坪量領域と低坪量領域との間に物理的に不連続な領域ができないことが大きな差異である。
【0014】
吸収体4は、高坪量領域41と低坪量領域42との間に坪量差を有している。より具体的には、高坪量領域41及び低坪量領域42は、平面視した場合に両領域の境界面において坪量が急激に変化し、両領域間に坪量差を生じている。これは、両領域においては、密度がほぼ一定に保たれつつ、かつパルプ繊維と高吸水性ポリマーの積繊量が高坪量領域で低坪量領域よりも多いことに起因する。このような構造とするには、後述するような製造技術上の工夫が重要となる。
【0015】
両領域41、42の坪量差は20〜600g/m2、特に30〜200g/m2であることが、着用者に違和感を与えない程度の剛性差が得られ易く、しかも当該剛性差によって着用者所定部位に適度なフィット性を与え、着用し易いという効果が得られるので好ましい。
なお、各領域の坪量は以下のようにして測定される。
<坪量の測定方法>
各領域から平面視における寸法が3cm×3cm以上(好ましくは5cm×5cm以上)の同面積である測定片を採取し、各測定片の面積と重量を測定して、坪量(重量/面積)を算出した。測定片は、両領域から5つ、好ましくは各領域から5つずつ採取する。
【0016】
両領域の坪量差は、高坪量領域の測定片の坪量の平均値と低坪量領域の測定片の坪量の平均値とから算出する。
両領域の坪量は吸収体の用途等に応じて適宜決定でき、特に制限されるものではないが、例を示せば、高坪量領域の坪量は200〜400g/m2であり、低坪量領域の坪量は100〜300g/m2である。
【0017】
吸収体4は、高吸水ポリマーとパルプ繊維との混合比が、高坪量領域と低坪量領域とで実質的に同じである。というのは、そのような構成によって、高坪量領域と低坪量領域の吸収速度差がつき難くなるし、また一方側にゲルブロッキングが発生する等の問題が生じ難くなるからである。
具体的には、高坪量領域41における、前記高吸水性ポリマー及び前記パルプ繊維それぞれの配合比率(%)と、前記低坪量領域における、該高吸水性ポリマー及び該パルプ繊維それぞれの配合比率(%)との差が、それぞれ±5%の範囲内である。前記配合比率(%)は、高吸水性ポリマー及びパルプ繊維の合計量に対する該高吸水性ポリマー又は該パルプ繊維の配合割合を百分率(%)で示した値である。例えば高坪量領域41における、高吸水性ポリマーとパルプ繊維との混合比(前者:後者)が54:46の場合、該領域41における、該高吸水性ポリマーの配合比率は54%で、パルプ繊維の配合比率は46%である。そして、このとき、低坪量領域42における、高吸水性ポリマーの配合比率が55%であるとすれば、高坪量領域41におけるポリマー配合比率(%)と、低坪量領域42におけるポリマーの配合比率(%)との差は、−1%(54%−55%)である。
【0018】
また、吸収体4は、高坪量領域と低坪量領域の密度が実質的に同じである。具体的には、両領域41、42の密度の比(高坪量領域/低坪量領域)が0.9〜1.1である。当該範囲内とすることで両領域での吸収性能の設計が容易となり、しかも剛性差が両領域間で違和感を与えない程度と設計し易い。なお、各領域の密度は以下のようにして測定される。
<密度の測定方法>
高坪量領域と低坪量領域が十分な大きさを有している場合には、各々の領域を採取して体積と重量を測定し、密度を算出する。
両領域の一方が十分な大きさを有していない場合(例えば、平面積1cm2未満の複数の高坪量領域が低坪量領域に散りばめられているような場合)には、吸収体上の任意の部位5個所(但し、高坪量領域と低坪量領域は少なくとも該部位のうち1ケ所ずつに含まれるようにする)を、3cm×3cm以上(好ましくは5cm×5cm以上)の寸法で同面積となるように採取し、体積と重量を測定する。各々の測定片について密度(重量/体積)を算出する。この場合、各測定片の密度の差が±5%以内であれば、高坪量領域と低坪量領域の密度が実質的に同じである。
【0019】
吸収体4は、高坪量領域と低坪量領域でほぼ同じ密度とするために、後述するような製造方法を施すことによって、高吸水ポリマーとパルプ繊維との混合比が、両領域41、42において実質的に同じとなるようにし、且つ、両領域41,42に実質的に異なった圧力が加わらないような圧縮処理を施す(高坪量領域と低坪量領域の厚み差に合わせた段を備えたプレートで押さえる等)か、若しくは圧縮処理が施されていない。尚、図示した吸収体4は、全域で密度が略均一である。
【0020】
各領域41,42における高吸水性ポリマーの混合比は、以下のようにして測定される。
<ポリマー及びパルプ繊維の混合比の測定方法>
吸収体の高坪量領域及び低坪量領域を必ず1点は含むように5点切り出し(即ち、5点切り出したうち高坪量領域と低坪量領域とが1点ずつは含まれるように切り出し)、各々についてポリマーとパルプ繊維をふるい等によって分離し、ポリマーとパルプ繊維の各重量を測定する。混合比は、両領域毎に平均をとる。分離の手段は両者がほぼ完全に分離できればよく、種々の手段を用いることができる。例えば、粒径の差を利用し、目の細かいメッシュでふるい分けしたり、重量の差を利用してパルプのみが飛散するような風量下に置いて、飛散前後の重量を測定しても良い。
【0021】
吸水性ポリマーとしてポリアクリル酸系のものを使用した場合に特に好ましい方法は、パルプ繊維及び吸水性ポリマーを含むサンプル中の該ポリマーに低分子化を起こさせ、その低分子化により生じた低分子成分を分離除去し、該低分子成分を除去した後の残存物の重量を定量し、その定量した重量を用いて、前記サンプル中の繊維及び吸水性ポリマーの含有量を算出する方法である。
【0022】
具体的には、各領域41,42からサンプルを採取し、90℃で8時間以上乾燥処理を行った後、室温にて平衡化した後に正確に秤量する。
そして、各サンプルを、予め正確に秤量してある、メッシュ袋に充填し、該メッシュ袋ごと、4重量%のアスコルビン酸及び0.02重量%のリボフラビンを含有する水溶液中に浸漬させ、該水溶液をサンプルに充分に含ませる。次いで、メッシュ袋を水溶液中から取り出し、サンプルを日光(紫外線)による低分子化処理を8時間×3日間施し、低分子化により低分子化して可溶化した成分を、メッシュ袋から水洗により分離除去する。リボフラビンにより着色されたポリマーの色が消失していない場合又は水洗時のぬるぬる感が消失していない場合には、メッシュ袋を再度前記水溶液中に浸漬させ、日光による低分子化処理を繰り返す。すべてのサンプルについて前記ポリマーの色が完全に消失し且つ水洗時のぬるぬる感が消失した時点で処理を終了する。
【0023】
メッシュ袋を充分に水洗した後、遠心分離器を用いて800回転/分の速度で10分遠心して脱水する。次いで、90℃で18時間以上の乾燥を行い、室温にて平衡化した後、残存物を収容した状態のメッシュ袋の重量を秤量する(以下、この重量を処理後重量ともいう)。
そして、処理後重量からメッシュ袋単体の重量を差し引いた値をサンプル中のパルプ繊維の含有量とし、予め測定しておいたサンプル重量からパルプ繊維の重量を差し引いた値を吸水性ポリマーの含有量とする。
【0024】
上記構成の吸収体4は、高い吸収容量が要求される部位に高坪量領域41を設けると共に、要求される吸収容量が相対的に低い部位に低坪量領域42を設けることにより、高吸水性ポリマー、パルプ繊維等の吸収性材料、及びそれらにより実現される吸収容量を最も効果的な方法で有効に活用することができる。しかも、高吸収容量を目指した高坪量領域41が、吸収体同士を積層していない単一構造体から形成されている(即ち、低坪量領域の吸収体構造と基本構造は同じで、別の吸収体を積載していない)ため、該領域における吸収性能を効率的に発現させることができる。即ち、従来の、低吸収容量部分の吸収体構造に別の吸収体構造体を積載した2層構造の吸収体においては、上層の吸収体において、高吸水性ポリマーが排泄物と接して大きく膨潤すると、排泄物が下層の吸収体にスムーズに移行することが妨げられることがあるが(ゲルブロッキング)、上記構成の吸収体4のように、高坪量領域41が単一構造体から形成されていると、排泄物が厚さ方向の全体に導入され易く、下方に存在するポリマーまで有効に利用される。
また、高坪量領域41と低坪量領域(他の部位)が、物理的に連続した一体構造で形成されているため、従来の2層構造の吸収体とは異なり、高坪量領域41と低坪量領域42との間に大きな剛性の差が生じにくいため、おむつ等の吸収性物品に組み入れて用いる場合に、着用者が違和感を感じにくい。
【0025】
また、高吸水ポリマーとパルプ繊維との混合比率を両領域において実質的に同じにしてあるため、密度を均一にできるだけでなく、吸収体上での吸収性能の設計が非常に容易になる。というのは、密度が同じであっても、高吸水性ポリマーとパルプ繊維の混合比率が異なっていては、吸収体の吸収速度や吸収容量が局所的に望ましくない性能となることがありえ、その結果尿漏れやポリマー漏れなどの諸問題を誘発する恐れがあるからである。
【0026】
次に、本発明の吸収体の製造方法の好ましい一実施形態について説明する。図3に示す吸収体の製造装置は、本発明の実施に好ましく用いられる吸収体の製造装置である。本実施形態においては、図3に示す装置を用いて、上記構成の吸収体4を製造する。
図3に示す吸収体の製造装置は、外周面に、底面部に多数の吸引孔を有する複数の集積用凹部50を備えた回転ドラム(積繊ドラム)5と、該回転ドラム5の外周面に、吸収体原料を飛散させて供給する原料供給手段6とを備え、上記原料を上記各集積用凹部50内に吸引堆積させ、該原料の堆積物を該各集積用凹部50から順次離型して吸収体4を連続的に製造する装置である。
【0027】
回転ドラム5は、その外周面に、集積用凹部50を所定の間隔に複数有しており、集積用凹部50を有するリング状の部分が、図3中の矢印A方向に回転するようになっている。回転ドラム5の内部は、異なる圧力に調整可能な複数の部屋に区画されており、集積用凹部50に原料を堆積させる部位54,55,56の裏側に位置する各部屋は負圧に維持される。また、他の一部の部屋は陽圧とされ、その陽圧とされた部位において、集積用凹部50内の原料の堆積物が集積用凹部50内から排出される。部位54〜56の裏側の負圧を同一にする場合、部位54〜56の裏側に共通する一つの部屋を設けることもできる。
【0028】
原料供給手段6は、吸収体4を製造するための原料として、高吸水性ポリマー及びパルプ繊維を、回転ドラム50の外周面に飛散状態として供給するように構成されている。具体的には、第1及び第2パルプ繊維供給装置61,62が、それぞれパルプ繊維を供給し、ポリマー供給装置63が高吸水性ポリマーを供給する。両パルプ繊維供給装置61,62は、それぞれ公知の機構によりシート状の原料パルプを粉砕し、生じたパルプ繊維を、ダクト64内に生じた空気流に随伴させて回転ドラム5の外周面上に供給する。ポリマー供給装置63は、公知の機構により高吸水性ポリマーを、上記空気流中に導入し、回転ドラム5の外周面上に供給する
【0029】
原料供給手段6から供給された高吸水性ポリマー及びパルプ繊維は、回転ドラム5の負圧の作用により、各集積用凹部50内に吸引堆積され、所定部位まで搬送された後、各集積用凹部50から順次、搬送ベルト7上に離型される。
【0030】
各集積用凹部50の底面部には、図4に示すように、開口面積率の高い第1吸引領域51と第1吸引領域51よりも開口面積率の低い第2吸引領域52が設けられている。第1吸引領域51及び第2吸引領域52は、それぞれ上述した吸収体4の高坪量領域41及び低坪量領域42に対応する。
本発明では、吸引領域51と第2吸引領域52との境界部に、厚み調整手段としての段差を設ける必要がない。厚み調整手段としての段差とは、吸収体に厚みの厚い部分と厚みの薄い部分とを形成するための段差である。吸収体の厚みに影響しないような段差は、厚み調整手段としての段差ではない。
【0031】
本発明においては、第1吸引領域51の開口面積率R1と第2吸引領域52の開口面積率R2との比(R1/R2)を70/30〜99/1の範囲に設定する。
両領域51,52の開口面積率の比(R1/R2)が70/30未満であると、開口面積率の差が小さすぎ、高坪量領域と低坪量領域とが形成されない(即ち、坪量の差が殆ど生じない)ばかりでなく、ある一定の範囲では、パルプ/ポリマー混合比率が均一とならないことが生じたりする(ある一定の範囲とは、前記比(R1/R2)が70/30以下で、50/50近傍を除く比率の領域である)。
他方、前記開口面積率の比(R1/R2)が99/1超であると、第2吸収領域52の開口面積率R2が低くなり過ぎて、第2吸引領域にはパルプ/ポリマー混合物が積層しにくくなり、特に重量の重いポリマーは第1吸引領域に集中し易くなるため、パルプ/ポリマー比が極端に偏在してしまう。
【0032】
パルプ/ポリマー混合比率を高い確率で均一に保つことができるという観点から、第1及び第2吸引領域の開口面積率比(R1/R2)は75/25〜95/5であることがより好ましい。
【0033】
また、本発明においては、第1吸引領域51の開口面積率R1を40〜80%とし、第2吸引領域52の開口面積率R2を2〜20%とする。
第1吸引領域の開口面積率R1が40%未満であると、所望の風量が発生せず、ポリマーが失速し、パルプに対し充分にポリマーが混合されない。また、80%超であると、風量が過剰となり、集積用凹部にパルプ/ポリマーによる閉塞が生じやすい。
第2吸引領域の開口面積率R2が2%未満であると、吸収体の安定的な積繊が損なわれ、形状の欠陥、折れ、めくれが生じやすい。30%超であると、低坪量領域が形成されない。
【0034】
また、パルプ/ポリマー混合比の均一化及び保形性に優れた吸収体を得る目的から、第1吸引領域の開口面積率R1は45〜58%が好ましく、パルプ/ポリマー混合比の均一化とポリマー配合量を増やしても均一化が容易である点から、第2吸引領域の開口面積率R2は3〜18%が好ましい。
【0035】
ここで、各吸引領域の開口面積率Rは、各吸引領域の面積(吸引孔の面積を含む)をS1とし、該各吸引領域内に存する吸引孔の合計開口面積をS2としたときに、次式(1)により与えられる値である。
開口面積率R=(S2/S1)×100 (1)
【0036】
第1吸引領域51と第2吸引領域52とで開口面積率を異ならせる方法としては、▲1▼両領域で吸引孔の大きさ(直径等)は同じとするが、吸引孔のピッチを異ならせる方法、▲2▼両領域で吸引孔のピッチは同じとするが、吸引孔の大きさ(直径等)を異ならせる方法、▲3▼両領域で吸引孔のピッチと大きさの両者を異ならせる方法が挙げられる。後述する実施例においては、▲1▼の方法を用いている。
吸引孔の平均直径は、両領域51,52の何れにおいても0.05〜0.5mmの範囲内であることが好ましく、実質的に総ての吸引孔の直径が前記範囲内であることが好ましい。吸引孔は真円状が好ましいが、楕円状の場合の直径は、開口面積から真円と仮定した場合の直径を算出する。
尚、図示の装置においては、集積用凹部の底面部は、パンチング加工により多数の円形の吸引孔を設けたパンチングメタルからなり、隣接する吸引孔の中心点を結ぶ形状が3角形状である。
【0037】
上述した製造装置を用いて吸収体を製造するには、回転ドラム5を矢印A方向に一定速度で回転させると共に、集積用凹部50に原料を堆積させる部位54,55,56の裏側に位置する回転ドラム5内の各部屋を負圧にして、各吸引孔に吸引力を付与し、また、それにより、原料供給手段6のダクト64内に、原料を飛散状態にて搬送可能な空気流を生じさせる。
原料供給手段6により原料をダクト64内に導入すると、それらは飛散状態となって回転ドラム5に向かって供給される。そして、それらは各集積用凹部50内に吸引されて堆積する。尚、高吸水性ポリマーとパルプ繊維は混合状態で飛散させるとは、少なくとも一部が飛散状態にて混合されるようにすることを意味し、本実施形態においては、それぞれの供給口から供給されたパルプ及びポリマーがそれぞれ飛散状態となると共に少なくとも一部が混合した状態となって集積用凹部に向かって移動し集積される。
【0038】
集積用凹部50に、高吸水性ポリマー及びパルプ繊維を吸引堆積させる際には、第1及び第2吸引領域51,52に対して、集積用凹部50の底面部の裏側から、大気圧に対して1〜20kPa減圧した真空圧、特に5〜15kpa減圧した真空圧を作用させることが、パルプ/ポリマー混合比率をほぼ一定に保ちつつ、両領域の坪量を異ならせ(パルプ/ポリマーを偏在させ)ることができ、しかも両領域間に物理的に不連続な境界を形成しにくくなるので好ましい。
上記範囲の真空圧を作用させる方法としては、第1パルプ繊維供給装置61からのパルプ繊維を堆積させる部位54の裏側の部屋の真空圧を上記範囲とする方法、高吸水性ポリマーを堆積させる部位55の裏側の部屋の真空圧を上記範囲とする方法、第2パルプ繊維供給装置62からのパルプ繊維を堆積させる部位56の裏側の部屋の真空圧を上記範囲とする方法が挙げられるが、高吸水性ポリマー及び/又はパルプ繊維を吸引堆積させる部位の総ての部位54〜56の裏側の部屋の真空圧を上記範囲とすることが好ましい。尚、第1パルプ繊維供給装置61からのパルプ繊維を堆積させる部位54の裏側の部屋の圧力を上記範囲とする方法は、集積用凹部50に吸収体構成物が堆積していないので印加圧力を正確に測定できるので好ましい。
【0039】
本実施形態においては、各集積用凹部50に、パルプ繊維、高吸水性ポリマー、パルプ繊維が概ねこの順に堆積し、その堆積物に一定の形状が付与される。そして、集積用凹部50内の堆積物が回転ドラム5の下方において、順次離型される。回転ドラム5の回転を継続させ、原料の吸引堆積と堆積物の離型とが繰り返されることによって、吸収体4が効率的に連続生産される。
【0040】
本実施形態の吸収体の製造方法によれば、上述したような吸収体、即ち、吸収容量を部分的に高く設計した部位を有し、該部位の吸収性能を十分に発現させることのできる吸収性能に優れた吸収体を、このようにして、簡易な設備で効率的且つ経済的に製造することができる。
【0041】
尚、高吸水性ポリマーとしては、各種公知のものを特に制限なく用いることができ、例えば、ポリアクリル酸ナトリウム、(アクリル酸−ビニルアルコール)共重合体、ポリアクリル酸ナトリウム架橋体、(でんぷん−アクリル酸)グラフト共重合体、(イソブチレン−無水マレイン酸)共重合体及びそのケン化物、ポリアスパラギン酸等が挙げられる。また、吸収体の原料として、高吸水性ポリマー及びパルプ繊維に加え、レーヨン繊維やコットン、酢酸セルロース等の親水性繊維、ポリエチレン、ポリプロピレン等のポリオレフィン系繊維、ポリエステル、ポリアミド等の縮合系繊維、塩化ビニル、酢酸ビニル等のビニルモノマー重合体の繊維等を用いても良い。尚、吸収体は、台紙や液透過性の不織布からなる被覆シートで被覆されていても良い。
【0042】
吸収体の原料として、パルプ繊維に加えて他の繊維を用いる場合、吸水性ポリマー及び全繊維の合計重量に対するポリマーの比率(重量%)並びに前記合計重量に対する全繊維合計の重量の比率(重量%)は、それぞれ、高坪量領域と低坪量領域とで差が±5%の範囲内であることが好ましい。吸水性ポリマー及びパルプ繊維の吸収体中の合計含有量は70〜100%、特に80〜100%が好ましい。
【0043】
尚、上述した実施形態においては、展開型の使い捨ておむつ用の吸収体を例に説明したが、本発明で製造する吸収体は、パンツ型の使い捨ておむつ、生理用ナプキン、失禁パッド、パンティライナー等の吸収性物品に用いられる吸収体、更には、ドリップシート、キッチン用吸収シート、家庭用清掃シート、ペット用シート等における吸収体として用いるものであっても良い。
また、吸収体の製造装置は、二つのパルプ繊維供給装置を具備するものに代えて、単一のパルプ繊維供給装置によりパルプ繊維を一カ所からダクト内に供給するものを用いることもできる。
【0044】
〔実施例1〕
(1)吸収体の製造
高吸水性ポリマー及びパルプ繊維を原料とし、図3に示すような構成の吸収体の製造装置を用いて、図2に示す形態の吸収体を製造した。
集積用凹部の形状並びに第1及び第2吸引領域の配置等は、図4(a)に示す形状及び配置等とし、第1吸引領域51の開口面積率は56%、第2吸引領域52の開口面積率は5%とした。吸引孔の直径は、両領域51,52の何れにおいても0.1〜0.3mmの範囲内に分布しており、吸引孔の平均直径は、両領域51,52の何れにおいても0.2mmであった。尚、図3中の部位54〜56の裏側に位置する各部屋の圧力は、大気圧に対して8〜11kPa減圧した真空圧とし、この圧力を第1及び第2吸引領域に作用させた。
各吸引領域の面積等を表1に示す通りとした。表1中「腹側」及び「背側」は、各々第1吸引領域及び第2吸引領域に対応する。吸収体1枚当たりのパルプ繊維量及び高吸水性ポリマー量は、順に14g及び12gとした。高吸水性ポリマーは、ポリアクリル酸系のものを用いた。
【0045】
〔実施例2,3〕
第2吸引領域52の開口面積率を10%又は18%に代えた以外は、実施例1と同様にして吸収体を製造した。
【0046】
〔比較例1〕
第1吸引領域51の開口面積率を50%、第2吸引領域52の開口面積率を25%に代えた以外は、実施例1と同様にして吸収体を製造した。但し、吸収体1枚当たりの吸水性ポリマー量を14gとした。
【0047】
〔比較例2〕
集積用凹部の底面部の開口面積率を底面部全域に亘って40%とした以外は、実施例1と同様にして吸収体を製造した。
【0048】
〔実施例4〕
第1及び第2吸引領域の配置を、図5に示す配置に代えた以外は、実施例2と同様にして吸収体を製造した。表1中「T領域」及び「Y領域」は、各々第1吸引領域及び第2吸引領域に対応する。
【0049】
(2)吸収体
実施例及び比較例で得られた吸収体について、第1吸引領域に対応する部位(高坪量領域41,表1中「腹側」又は「T領域」)及び第2吸引領域に対応する部位(低坪量領域42,表1中「腹側」又は「Y領域」)のパルプ繊維やポリマーの坪量等を測定又は算出して表1に示した。
【0050】
(3)吸収体の評価
実施例及び比較例で得られた吸収体を用いて使い捨ておむつを製造した。使い捨ておむつの構成は、実施例及び比較例で得られた吸収体を使う以外は、花王株式会社製の市販の使い捨ておむつ(商品名「メリーズパンツ もれないスマート」)と同一とした。吸収体は、おむつの腹側に高坪量領域が位置するように配置した。
得られた使い捨ておむつについて、漏れ難さを評価するため、以下のようにして前もれ値を測定した。結果を表1に示した。
【0051】
〔前もれ値の測定方法〕
前側にモデル排尿部を有する人体モデルに各吸収体を用いて製造したパンツ型おむつをはかせ、前側を床につけた状態(うつぶせ寝)で、生理食塩水を10g/秒の速度で、モデル排尿部からおむつ内に注入する。50g流す毎に10秒間間をおき、再度流すという操作を繰り返し、前側(ウエスト開口)から漏れ出すまでの重量を測定し、これを前もれ値とした。
【0052】
【表1】

Figure 0004070661
【0053】
表1に示す結果から、実施例においては、得られた吸収体に、吸収容量を他の部位よりも高めた部位が十分に形成されており、該部位の吸収性能が十分に発揮されることが判る。これに対して、比較例の吸収体は、前側が高坪量にならなかったり(比較例1)、パルプ/ポリマー重量比が前後で大きく異なったりして、所望の前漏れ防止性能が発揮されなかった。
また、実施例で得られた吸収体を用いることにより、高吸水性ポリマーの使用量を抑えつつ、使い捨ておむつの漏れ防止性を向上させることができることが判る。
【0054】
【発明の効果】
本発明の吸収体の製造方法によれば、吸収容量を部分的に高く設計した部位を有し、該部位の吸収性能を十分に発現させることのできる吸収性能に優れた吸収体を、効率的且つ経済的に製造することができる。
【図面の簡単な説明】
【図1】図1は、本発明で製造される吸収体の例を、使い捨ておむつの一部として用いた状態を示す平面図であり、使い捨ておむつを表面シート側から見た状態を示す一部破断図である。
【図2】図2は、図1の吸収体を単独で示す図で、図2(a)は平面図、図2(b)は図2(a)のX−X線断面を模式的に示す断面図である。
【図3】図3は、本発明の実施に好ましく用いられる吸収体の製造装置を示す概略図である。
【図4】図4は、集積用凹部並びに第1及び第2吸引領域の配置の一例を示す図で、図4(a)は集積用凹部の俯瞰図、図4(b)は図4(a)のY−Y線断面を模式的に示す断面図である。
【図5】図5は、第1及び第2吸引領域の他の配置を示す図である。
【符号の説明】
1 使い捨ておむつ
2 表面シート
3 裏面シート
4 吸収体
5 回転(積繊)ドラム
50 集積用凹部
51 第1吸引領域
52 第2吸引領域
53 第1吸引領域と第2吸引領域の境界部[0001]
BACKGROUND OF THE INVENTION
The present invention has an area where the absorption capacity is designed to be partially high, and an absorber excellent in absorption performance capable of sufficiently expressing the absorption performance of the area is manufactured efficiently and economically. The present invention relates to a method for producing an absorbent body.
[0002]
[Prior art and problems to be solved by the invention]
Generally, the absorbent capacity of an absorbent article is designed according to its application. For example, disposable diapers are intended for a wide range of users, from newborns to adults who need nursing care, and it is necessary to design an absorption capacity for each of them.
[0003]
For example, since most of the excrement is soft stool, it can be designed to enhance the fecal absorption performance from the central part of the diaper longitudinal direction to the rear part (back side) in order to deal with soft stool. In addition, for infants and adults, in order to cope with a large amount of urination, the urine absorption performance from the central part in the longitudinal direction to the front part (abdominal side) may be designed. In the former case, since it is for a newborn, there is not much leakage even if the overall absorption capacity is not designed to be too high. On the other hand, in the latter case, since the amount of urination is the center and the amount is large, it is necessary to increase the absorption capacity from the central part in the longitudinal direction of the diaper to the front part. As described above, there are known methods in which a polymer is pattern-dispersed or an absorber structure in which only the front is stacked in two layers.
[0004]
However, when a pattern of highly water-absorbing polymer is sprayed, equipment for pattern spraying is required, and an apparatus for accurately aligning the spray pattern with the sheet base material to be sprayed is necessary. There is a problem that the position of the spray pattern is difficult to detect on the production line. In some cases, polymer leakage from a polymer-rich site or gel blocking may occur, and the expected absorption capacity may not be exhibited.
As an absorber in which only the front is stacked in two layers, an absorber in which a separately manufactured upper-layer absorber is laminated on a part of a lower-layer absorber or a part of an absorber composed of a single layer is folded back into two layers. The former is known, but the former requires, for example, a plurality of fiber stacking devices in order to produce two types of absorbers, and the latter requires a folding device, etc. In any of the absorbers, manufacturing facilities are complicated, and it is impossible to provide an inexpensive and high-performance absorber. Furthermore, if the polymer in the upper absorber absorbs and swells and gel blocking occurs, the liquid may not smoothly move to the lower absorber, resulting in absorption of polymers, pulp fibers, etc. in the forward direction. Absorption performance commensurate with the amount of the functional material cannot be obtained, which may cause leakage in some cases. In addition, in the case of an absorbent body in which only the front is stacked in two layers, there may be a feeling of strangeness when worn due to a difference in rigidity at the boundary with the rear single layer structure.
[0005]
As a manufacturing method in which a predetermined portion has a high basis weight, Japanese Patent Application Laid-Open No. 62-206071 (Patent Document 1) provides a concave portion having a specific shape in a part of a flat plate on which a fiber material is deposited. A technique in which the lower part of the recess is devised so that a high pressure is applied is disclosed. However, this publication only describes the deposition of the fiber material, and does not consider a mixed system of superabsorbent polymer and pulp. In addition, in this method, since a concave portion having an inclined portion that does not have an opening is provided in a portion having a high basis weight, no direct suction force is generated at the portion, and the flat portion and the concave portion of the plate It is likely to be a physically discontinuous sediment structure. In addition, since the airflow is disturbed in the inclined portion, the mixing ratio is disturbed in the mixed system of the superabsorbent polymer and the pulp, and the desired absorption performance cannot be obtained.
[0006]
Japanese Patent Laid-Open No. 2000-234255 (Patent Document 2) provides a plurality of suction regions having different aperture ratios on the bottom surface of the concave portion for accumulation, and sucks and deposits raw materials in these suction regions to obtain height and density. A method for producing a fiber molded body having different regions is described. However, this publication does not specifically describe the case where it is produced with a mixed system of a superabsorbent polymer and pulp fiber, and also provides a step in the recess to control the height and density. There is no description of the control. In addition, the absorber may be broken by the stepped portion when the absorber is transported.
[0007]
[Patent Document 1]
Japanese Patent Laid-Open No. 62-206071 [Patent Document 2]
Japanese Patent Laid-Open No. 2000-234255
Therefore, an object of the present invention is to provide an absorbent body having a portion designed to have a partly high absorption capacity, and capable of fully expressing the absorption performance of the portion, with simple equipment and efficiently. Another object of the present invention is to provide a method for producing an absorbent body that can be produced economically.
[0009]
[Means for Solving the Problems]
The present invention supplies the superabsorbent polymer and the pulp fiber in a scattered state, and sucks and deposits it in the concave portion for accumulation having a large number of suction holes on the bottom surface, and deposits of the superabsorbent polymer and the pulp fiber. A method of manufacturing an absorbent body, wherein the absorbent body is manufactured by releasing from the concave portion for accumulation, wherein a first suction region having a higher opening area ratio and an opening than the first suction region are formed in a bottom surface portion of the concave portion for accumulation. A second suction area having a low area ratio is provided, the opening area ratio R1 of the first suction area is 40 to 80%, the opening area ratio R2 of the second suction area is 2 to 20%, and the ratio of both opening area ratios (Rl / By providing a method for producing an absorbent body, wherein R2) is in the range of 70/30 to 99/1, and the superabsorbent polymer and the pulp fiber are deposited in both suction regions. Is achieved.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described based on preferred embodiments thereof.
First, the preferable example of the absorber manufactured by the manufacturing method of the absorber of this invention is demonstrated. The absorbent body 4 shown in FIGS. 1 and 2 is an absorbent body for the disposable diaper 1. The disposable diaper 1 includes a liquid-permeable top sheet 2, a liquid-impermeable back sheet 3, and a liquid-retaining absorbent 4 interposed between both sheets 2 and 3, and is formed substantially vertically long. From one end in the longitudinal direction toward the other end, a back side portion A disposed on the wearer's back side when worn, a crotch portion B disposed on the crotch, and a ventral side portion C disposed on the abdomen side In order. The disposable diaper 1 is a so-called unfolded disposable diaper, and has fastening tapes 11 for fastening diapers on the left and right side edges of the back side A, and the corresponding landing tape 12 is attached to the outside of the abdominal side C. Has on the surface.
[0011]
The absorbent body 4 is composed of a superabsorbent polymer and pulp fibers, and each of the superabsorbent polymer and the pulp fibers has a high basis weight region 41 in which the basis weight is higher than the low basis weight region 42 which is another part. is doing. In addition, the expression containing a superabsorbent polymer and pulp fiber includes both the case where a component other than the superabsorbent polymer and pulp fiber is included and the case where a component other than the superabsorbent polymer and pulp fiber is not included. It is.
The high basis weight region 41 is formed at a position biased toward the one end 4a side of the side disposed on the abdomen side of the wearer when the diaper 1 is worn among the longitudinal ends of the absorbent body 4, and more specifically. In the diaper 1, it forms in the site | part (site ranging from the crotch part B to the abdominal side part C) facing the wearer's urination part.
[0012]
The high basis weight region 41 and the low basis weight region 42 are formed in a physically continuous integral structure. That is, both regions form a single structure, and there is no interface that connects separate absorbers between the two regions. The thickness of the absorber 4 in the high basis weight region 41 is slightly thicker than the thickness of the absorber 4 in the low basis weight region 42.
[0013]
The cross-sectional structure (cross-sectional structure in the thickness direction) of the absorber 4 across both regions 41 and 42 is a conventional two-layer absorber, that is, an absorber in which a separately manufactured upper-layer absorber is laminated on a lower-layer absorber. Or, it is different from the cross-sectional structure of the absorber in which a part of the absorber composed of a single layer is folded to form a two-layer part. Specifically, there is no discontinuity between the high basis weight region and the low basis weight region as shown in FIG.
As shown in FIG. 2B, the absorbent body 4 includes a plurality of layers each having a high basis weight region 41 and a low basis weight region 42 in the thickness direction. Specifically, each of the regions 41 and 42 includes an upper layer 41a mainly composed of pulp fibers in the thickness direction, an intermediate layer 41b mainly composed of a superabsorbent polymer, and a lower layer 41c mainly composed of pulp fibers. ing. Each of the plurality of layers 41a to 41c has an integral structure that is physically continuous over both regions.
In the prior art, there is a physical discontinuity between the high basis weight portion and the low basis weight portion. In the present invention, a major difference is that there is no physically discontinuous region between the high basis weight region and the low basis weight region.
[0014]
The absorbent body 4 has a basis weight difference between the high basis weight region 41 and the low basis weight region 42. More specifically, in the high basis weight region 41 and the low basis weight region 42, when viewed in plan, the basis weight changes abruptly at the boundary surface between the two regions, and a difference in basis weight occurs between the two regions. This is due to the fact that in both regions, the density is kept almost constant and the amount of pulp fibers and superabsorbent polymer is higher in the high basis weight region than in the low basis weight region. In order to obtain such a structure, a device on the manufacturing technique as described later is important.
[0015]
The difference in basis weight between the two regions 41 and 42 is 20 to 600 g / m 2 , especially 30 to 200 g / m 2 , and it is easy to obtain a rigidity difference that does not give the wearer a sense of incongruity. It is preferable because an appropriate fit property is given to a predetermined part of the wearer and an effect that it is easy to wear is obtained.
In addition, the basic weight of each area | region is measured as follows.
<Measurement method of basis weight>
Measurement pieces having the same area of 3 cm × 3 cm or more (preferably 5 cm × 5 cm or more) in plan view from each region are collected, the area and weight of each measurement piece are measured, and the basis weight (weight / area) Was calculated. Five measurement pieces are collected from both regions, preferably five from each region.
[0016]
The basis weight difference between the two areas is calculated from the average value of the basis weight of the measurement piece in the high basis weight area and the average value of the basis weight of the measurement piece in the low basis weight area.
The basis weight of both regions can be determined as appropriate according to the application of the absorbent body and is not particularly limited. However, for example, the basis weight of the high basis weight region is 200 to 400 g / m 2 , and is low. The basis weight of the basis weight region is 100 to 300 g / m 2 .
[0017]
In the absorbent body 4, the mixing ratio of the superabsorbent polymer and the pulp fiber is substantially the same in the high basis weight region and the low basis weight region. This is because such a configuration makes it difficult for a difference in absorption rate between the high basis weight region and the low basis weight region to occur, and also causes problems such as gel blocking on one side.
Specifically, the blending ratio (%) of each of the superabsorbent polymer and the pulp fiber in the high basis weight region 41, and the blending ratio of the superabsorbent polymer and the pulp fiber in the low basis weight region. The difference from (%) is within a range of ± 5%. The blending ratio (%) is a value indicating the blending ratio of the superabsorbent polymer or the pulp fiber as a percentage (%) with respect to the total amount of the superabsorbent polymer and the pulp fiber. For example, when the mixing ratio (the former: the latter) of the superabsorbent polymer and pulp fiber in the high basis weight region 41 is 54:46, the blending ratio of the superabsorbent polymer in the region 41 is 54%. The blending ratio of the fiber is 46%. At this time, if the blending ratio of the superabsorbent polymer in the low basis weight region 42 is 55%, the polymer blending ratio (%) in the high basis weight region 41 and the polymer blending ratio in the low basis weight region 42 The difference from the blending ratio (%) is -1% (54% -55%).
[0018]
Moreover, as for the absorber 4, the density of a high basic weight area | region and a low basic weight area | region is substantially the same. Specifically, the density ratio (high basis weight region / low basis weight region) of both regions 41 and 42 is 0.9 to 1.1. By making it within this range, it is easy to design the absorption performance in both regions, and the design is so easy that the difference in rigidity does not give a sense of incongruity between the two regions. The density of each region is measured as follows.
<Density measurement method>
When the high basis weight region and the low basis weight region have a sufficient size, each region is sampled, the volume and weight are measured, and the density is calculated.
When one of the two regions does not have a sufficient size (for example, when a plurality of high basis weight regions having a plane area of less than 1 cm 2 are scattered in the low basis weight region), Dimension of 3 cm × 3 cm or more (preferably 5 cm × 5 cm or more) of any 5 parts of the above (however, the high basis weight region and the low basis weight region should be included in at least one of the parts) Collect the same area and measure the volume and weight. The density (weight / volume) is calculated for each measurement piece. In this case, if the difference in density between the measurement pieces is within ± 5%, the density of the high basis weight region and the low basis weight region is substantially the same.
[0019]
In order to make the absorbent body 4 have substantially the same density in the high basis weight region and the low basis weight region, the mixing ratio of the superabsorbent polymer and the pulp fiber is changed to both regions 41, by applying a manufacturing method as described later. 42, and a compression treatment is performed so that substantially different pressure is not applied to both regions 41 and 42 (according to the thickness difference between the high basis weight region and the low basis weight region). It is pressed with a plate having a step or the like) or is not compressed. The illustrated absorber 4 has a substantially uniform density throughout the entire area.
[0020]
The mixing ratio of the superabsorbent polymer in each of the regions 41 and 42 is measured as follows.
<Measurement method of mixing ratio of polymer and pulp fiber>
Cut out 5 points so that the high basis weight region and the low basis weight region of the absorbent body always include one point (that is, the high basis weight region and the low basis weight region are included one by one in the cut out 5 points). Cut out), the polymer and the pulp fiber are separated from each other by sieving or the like, and the respective weights of the polymer and the pulp fiber are measured. The mixing ratio is averaged for both regions. Any separation means may be used as long as the two can be almost completely separated, and various means can be used. For example, the weight before and after scattering may be measured by using a difference in particle size and sieving with a fine mesh, or by placing under an air volume such that only pulp is scattered using the difference in weight.
[0021]
When a polyacrylic acid-based polymer is used as the water-absorbing polymer, a particularly preferable method is to cause the polymer in the sample containing pulp fiber and the water-absorbing polymer to have a low molecular weight, and the low molecular weight generated by the low molecular weight. In this method, the components are separated and removed, the weight of the residue after removing the low molecular components is quantified, and the content of the fibers and the water-absorbing polymer in the sample is calculated using the quantified weight.
[0022]
Specifically, samples are taken from each of the regions 41 and 42, dried at 90 ° C. for 8 hours or more, equilibrated at room temperature, and accurately weighed.
Each sample is filled in a mesh bag, which is accurately weighed in advance, and the mesh bag is immersed in an aqueous solution containing 4% by weight ascorbic acid and 0.02% by weight riboflavin. Fully in the sample. Next, the mesh bag is taken out from the aqueous solution, and the sample is subjected to a low molecular weight treatment with sunlight (ultraviolet rays) for 8 hours × 3 days. To do. When the color of the polymer colored by riboflavin has not disappeared or when the slimy feeling at the time of washing with water has not disappeared, the mesh bag is again immersed in the aqueous solution, and the low molecular weight treatment by sunlight is repeated. The processing is terminated when the color of the polymer has completely disappeared for all the samples and the slimy feeling during washing has disappeared.
[0023]
After the mesh bag is sufficiently washed with water, it is dehydrated by centrifugation for 10 minutes at a speed of 800 rpm with a centrifuge. Next, after drying at 90 ° C. for 18 hours or more and equilibrating at room temperature, the weight of the mesh bag containing the residue is weighed (hereinafter, this weight is also referred to as post-treatment weight).
And the value obtained by subtracting the weight of the mesh bag from the weight after the treatment is the pulp fiber content in the sample, and the value obtained by subtracting the weight of the pulp fiber from the sample weight measured in advance is the content of the water-absorbing polymer. And
[0024]
The absorbent body 4 having the above configuration has a high water absorption capacity by providing a high basis weight region 41 in a portion where a high absorption capacity is required and providing a low basis weight region 42 in a portion where the required absorption capacity is relatively low. Absorbent materials such as water-soluble polymers and pulp fibers, and the absorption capacity realized by them can be effectively utilized in the most effective manner. And the high basic weight area | region 41 aiming at the high absorption capacity | capacitance is formed from the single structure which has not laminated | stacked absorbers (namely, the basic structure is the same as the absorber structure of a low basic weight area | region, Therefore, the absorption performance in the region can be efficiently expressed. That is, in the conventional two-layer structure in which another absorber structure is loaded on the absorber structure of the low-absorption capacity portion, the superabsorbent polymer swells greatly in contact with excrement in the upper-layer absorber. Then, although the excrement may be prevented from smoothly transferring to the lower-layer absorber (gel blocking), the high basis weight region 41 is formed from a single structure like the absorber 4 having the above configuration. In this case, excreta is easily introduced in the entire thickness direction, and even the polymer existing below is effectively used.
Moreover, since the high basic weight area | region 41 and the low basic weight area | region (other parts) are formed in the physically continuous integral structure, unlike the absorber of the conventional 2 layer structure, the high basic weight area | region 41 Since a large difference in rigidity is unlikely to occur between the low basis weight region 42 and the low basis weight region 42, the wearer is less likely to feel uncomfortable when used in an absorbent article such as a diaper.
[0025]
Further, since the mixing ratio of the superabsorbent polymer and the pulp fiber is substantially the same in both regions, not only can the density be made uniform, but also the design of the absorption performance on the absorbent body becomes very easy. This is because even if the density is the same, if the mixing ratio of the superabsorbent polymer and the pulp fiber is different, the absorption rate and absorption capacity of the absorbent body may be locally undesirable, As a result, various problems such as urine leakage and polymer leakage may be induced.
[0026]
Next, one preferable embodiment of the manufacturing method of the absorber of the present invention will be described. The absorbent body manufacturing apparatus shown in FIG. 3 is an absorbent body manufacturing apparatus preferably used for carrying out the present invention. In the present embodiment, the absorber 4 having the above configuration is manufactured using the apparatus shown in FIG.
The absorbent body manufacturing apparatus shown in FIG. 3 includes a rotating drum (stacking drum) 5 having a plurality of concave portions for accumulation 50 having a plurality of suction holes on the bottom surface on the outer peripheral surface, and the outer peripheral surface of the rotating drum 5. And a raw material supply means 6 for scattering and supplying the absorber raw material, the raw material is sucked and deposited in the respective accumulation recesses 50, and the deposits of the raw materials are sequentially released from the respective accumulation recesses 50. Thus, the absorber 4 is continuously manufactured.
[0027]
The rotating drum 5 has a plurality of accumulation recesses 50 at predetermined intervals on the outer peripheral surface thereof, and the ring-shaped portion having the accumulation recesses 50 rotates in the direction of arrow A in FIG. ing. The interior of the rotary drum 5 is partitioned into a plurality of chambers that can be adjusted to different pressures, and each chamber located behind the portions 54, 55, and 56 where the raw material is deposited in the accumulation recess 50 is maintained at a negative pressure. The Further, the other part of the chamber is set to a positive pressure, and the deposit of the raw material in the accumulation concave portion 50 is discharged from the accumulation concave portion 50 at the positive pressure portion. When the negative pressures on the back sides of the parts 54 to 56 are the same, a common room can be provided on the back sides of the parts 54 to 56.
[0028]
The raw material supply means 6 is configured to supply a superabsorbent polymer and pulp fibers as a raw material for manufacturing the absorber 4 in a scattered state to the outer peripheral surface of the rotary drum 50. Specifically, the first and second pulp fiber supply devices 61 and 62 supply pulp fibers, respectively, and the polymer supply device 63 supplies a superabsorbent polymer. Both pulp fiber supply devices 61 and 62 respectively pulverize the sheet-like raw material pulp by a known mechanism, and cause the generated pulp fibers to follow the air flow generated in the duct 64 on the outer peripheral surface of the rotary drum 5. Supply. The polymer supply device 63 introduces a superabsorbent polymer into the air flow by a known mechanism and supplies it to the outer peripheral surface of the rotary drum 5.
The superabsorbent polymer and pulp fiber supplied from the raw material supply means 6 are sucked and deposited in the respective accumulation recesses 50 by the action of the negative pressure of the rotary drum 5 and conveyed to a predetermined portion, and then each accumulation recess. From 50, the mold is released on the conveyor belt 7 sequentially.
[0030]
As shown in FIG. 4, a first suction region 51 having a high opening area ratio and a second suction region 52 having a lower opening area ratio than the first suction area 51 are provided on the bottom surface of each accumulation recess 50. Yes. The first suction region 51 and the second suction region 52 correspond to the high basis weight region 41 and the low basis weight region 42 of the absorbent body 4 described above, respectively.
In the present invention, it is not necessary to provide a step as thickness adjusting means at the boundary between the suction region 51 and the second suction region 52. The step as the thickness adjusting means is a step for forming a thick part and a thin part in the absorber. A step that does not affect the thickness of the absorber is not a step as thickness adjusting means.
[0031]
In the present invention, the ratio (R1 / R2) between the opening area ratio R1 of the first suction region 51 and the opening area ratio R2 of the second suction region 52 is set in the range of 70/30 to 99/1.
If the ratio (R1 / R2) of the opening area ratio of both the regions 51 and 52 is less than 70/30, the difference in the opening area ratio is too small, and a high basis weight region and a low basis weight region are not formed (that is, Not only does the difference in basis weight hardly occur), but also in a certain range, the pulp / polymer mixing ratio may not be uniform (the certain ratio is that the ratio (R1 / R2) is 70). / 30 or less and a ratio area excluding the vicinity of 50/50).
On the other hand, if the ratio (R1 / R2) of the opening area ratio is more than 99/1, the opening area ratio R2 of the second absorption region 52 becomes too low, and the pulp / polymer mixture is laminated in the second suction region. In particular, a heavy polymer tends to concentrate on the first suction region, and the pulp / polymer ratio is extremely unevenly distributed.
[0032]
From the viewpoint that the pulp / polymer mixing ratio can be kept uniform with high probability, the ratio of the opening area ratio (R1 / R2) of the first and second suction regions is more preferably 75/25 to 95/5. .
[0033]
In the present invention, the opening area ratio R1 of the first suction region 51 is set to 40 to 80%, and the opening area ratio R2 of the second suction region 52 is set to 2 to 20%.
When the opening area ratio R1 of the first suction region is less than 40%, a desired air volume is not generated, the polymer is stalled, and the polymer is not sufficiently mixed with the pulp. On the other hand, if it exceeds 80%, the air volume becomes excessive, and the accumulation recesses are likely to be clogged with pulp / polymer.
When the opening area ratio R2 of the second suction region is less than 2%, stable fiber stacking of the absorber is impaired, and shape defects, breakage, and turning are likely to occur. If it exceeds 30%, a low basis weight region is not formed.
[0034]
Further, for the purpose of obtaining an absorbent body having a uniform pulp / polymer mixing ratio and an excellent shape retention, the opening area ratio R1 of the first suction region is preferably 45 to 58%, and the pulp / polymer mixing ratio is uniform. The opening area ratio R2 of the second suction region is preferably 3 to 18% from the viewpoint that it is easy to make uniform even if the amount of the polymer is increased.
[0035]
Here, the opening area ratio R of each suction region is defined by assuming that the area of each suction region (including the area of the suction holes) is S1, and the total opening area of the suction holes existing in each suction region is S2. It is a value given by the following equation (1).
Opening area ratio R = (S2 / S1) × 100 (1)
[0036]
As a method of making the opening area ratios different between the first suction area 51 and the second suction area 52, (1) the suction holes have the same size (diameter, etc.), but the suction holes have different pitches. (2) The suction hole pitch is the same in both areas, but the suction hole size (diameter, etc.) is different. (3) The suction hole pitch and size are different in both areas. The method to make is mentioned. In the embodiment described later, the method (1) is used.
The average diameter of the suction holes is preferably in the range of 0.05 to 0.5 mm in both the regions 51 and 52, and the diameters of all the suction holes are substantially in the above range. preferable. The suction hole is preferably a perfect circle, but the diameter in the case of an ellipse is calculated from the opening area assuming a perfect circle.
In the illustrated apparatus, the bottom surface of the accumulation recess is made of punching metal provided with a number of circular suction holes by punching, and the shape connecting the center points of adjacent suction holes is a triangular shape.
[0037]
In order to manufacture the absorber using the above-described manufacturing apparatus, the rotary drum 5 is rotated at a constant speed in the direction of arrow A, and is positioned behind the portions 54, 55, and 56 where the raw material is deposited in the accumulation recess 50. Each chamber in the rotary drum 5 is set to a negative pressure, and a suction force is applied to each suction hole. Thereby, an air flow capable of conveying the raw material in a scattered state is provided in the duct 64 of the raw material supply means 6. Cause it to occur.
When the raw materials are introduced into the duct 64 by the raw material supply means 6, they are scattered and supplied toward the rotating drum 5. Then, they are sucked and deposited in each accumulation recess 50. Incidentally, the dispersion of the superabsorbent polymer and the pulp fiber in a mixed state means that at least a part is mixed in the scattered state, and in this embodiment, the super absorbent polymer and the pulp fiber are supplied from the respective supply ports. The pulp and polymer are each scattered and at least partially mixed to move toward the accumulation recess and accumulate.
[0038]
When sucking and depositing the superabsorbent polymer and the pulp fiber in the collecting recess 50, the first and second suction regions 51 and 52 are exposed to the atmospheric pressure from the back side of the bottom surface of the collecting recess 50. Applying a vacuum pressure reduced by 1 to 20 kPa, particularly a vacuum pressure reduced by 5 to 15 kPa, makes the basis weight of both regions different while keeping the pulp / polymer mixing ratio substantially constant (the pulp / polymer is unevenly distributed). And it is difficult to form a physically discontinuous boundary between the two regions.
As a method of applying the vacuum pressure in the above range, a method in which the vacuum pressure in the chamber on the back side of the portion 54 where the pulp fiber from the first pulp fiber supply device 61 is deposited is within the above range, a portion where the superabsorbent polymer is deposited. 55, the method of setting the vacuum pressure of the room on the back side of the above-mentioned range, and the method of setting the vacuum pressure of the room on the back side of the portion 56 where the pulp fibers from the second pulp fiber supply device 62 are deposited are in the above range. It is preferable that the vacuum pressure in the chamber on the back side of all the portions 54 to 56 where the water-absorbing polymer and / or the pulp fibers are sucked and deposited is within the above range. In the method of setting the pressure in the chamber on the back side of the portion 54 on which the pulp fiber from the first pulp fiber supply device 61 is deposited in the above range, the applied pressure is set because the absorbent component is not deposited in the accumulation recess 50. It is preferable because it can be measured accurately.
[0039]
In the present embodiment, the pulp fibers, the superabsorbent polymer, and the pulp fibers are generally deposited in this order in each accumulation recess 50, and a certain shape is given to the deposit. Then, the deposit in the accumulation recess 50 is sequentially released under the rotary drum 5. By continuously rotating the rotating drum 5 and repeating the suction deposition of the raw material and the release of the deposit, the absorber 4 is efficiently and continuously produced.
[0040]
According to the manufacturing method of the absorbent body of the present embodiment, the absorbent body as described above, that is, an absorption having a part designed to have a partially high absorption capacity and capable of sufficiently expressing the absorbent performance of the part. Thus, the absorber excellent in performance can be manufactured efficiently and economically with simple equipment.
[0041]
As the superabsorbent polymer, various known polymers can be used without particular limitation. For example, sodium polyacrylate, (acrylic acid-vinyl alcohol) copolymer, sodium polyacrylate cross-linked product, (starch- Acrylic acid) graft copolymers, (isobutylene-maleic anhydride) copolymers and saponified products thereof, polyaspartic acid, and the like. In addition to the superabsorbent polymer and pulp fiber, the absorbent material is made of rayon fiber, hydrophilic fiber such as cotton and cellulose acetate, polyolefin fiber such as polyethylene and polypropylene, condensed fiber such as polyester and polyamide, chloride Fibers of vinyl monomer polymers such as vinyl and vinyl acetate may be used. In addition, the absorber may be covered with a cover sheet made of a mount or a liquid-permeable nonwoven fabric.
[0042]
When using other fibers in addition to pulp fibers as the raw material of the absorbent, the ratio of the water-absorbing polymer and the polymer to the total weight of the total fibers (% by weight) and the ratio of the total weight of the total fibers to the total weight (% by weight ) Is preferably within a range of ± 5% between the high basis weight region and the low basis weight region. The total content of the water-absorbing polymer and pulp fiber in the absorbent body is preferably 70 to 100%, particularly preferably 80 to 100%.
[0043]
In the above-described embodiment, the absorbent body for the deployable disposable diaper has been described as an example. However, the absorbent body manufactured in the present invention is a pants-type disposable diaper, a sanitary napkin, an incontinence pad, a panty liner, and the like. The absorbent body used in the absorbent article may be used as an absorbent body in drip sheets, kitchen absorbent sheets, household cleaning sheets, pet sheets and the like.
Moreover, the manufacturing apparatus of an absorber can replace with what comprises two pulp fiber supply apparatuses, and can also use what supplies a pulp fiber in a duct from one place with a single pulp fiber supply apparatus.
[0044]
[Example 1]
(1) Production of Absorber An absorbent body having the form shown in FIG. 2 was produced using a superabsorbent polymer and pulp fibers as raw materials and using an absorbent production apparatus having the structure shown in FIG.
The shape of the concave portion for accumulation and the arrangement of the first and second suction areas are the same as those shown in FIG. 4A. The opening area ratio of the first suction area 51 is 56%, and the second suction area 52 The opening area ratio was 5%. The diameter of the suction holes is distributed within a range of 0.1 to 0.3 mm in both the regions 51 and 52, and the average diameter of the suction holes is 0.2 mm in both the regions 51 and 52. Met. In addition, the pressure of each room located in the back side of the site | parts 54-56 in FIG. 3 was made into the vacuum pressure which pressure-reduced 8-11 kPa with respect to atmospheric pressure, and this pressure was made to act on a 1st and 2nd suction area | region.
The area of each suction region was as shown in Table 1. In Table 1, “abdominal side” and “back side” correspond to the first suction region and the second suction region, respectively. The pulp fiber amount and superabsorbent polymer amount per absorber were 14 g and 12 g in this order. As the superabsorbent polymer, a polyacrylic acid-based polymer was used.
[0045]
[Examples 2 and 3]
An absorbent body was manufactured in the same manner as in Example 1 except that the opening area ratio of the second suction region 52 was changed to 10% or 18%.
[0046]
[Comparative Example 1]
An absorbent body was manufactured in the same manner as in Example 1 except that the opening area ratio of the first suction region 51 was changed to 50% and the opening area ratio of the second suction region 52 was changed to 25%. However, the amount of water-absorbing polymer per absorber was 14 g.
[0047]
[Comparative Example 2]
An absorbent body was manufactured in the same manner as in Example 1 except that the opening area ratio of the bottom surface portion of the accumulation recess was 40% over the entire bottom surface portion.
[0048]
Example 4
An absorbent body was manufactured in the same manner as in Example 2 except that the arrangement of the first and second suction regions was changed to the arrangement shown in FIG. In Table 1, “T region” and “Y region” correspond to the first suction region and the second suction region, respectively.
[0049]
(2) About the absorber obtained by the absorber Example and the comparative example, the site | part (high basic weight area | region 41, "abdominal side" in Table 1, or "T area | region") corresponding to the 1st suction area | region, and 2nd suction | inhalation Table 1 shows the measured or calculated basis weights of pulp fibers and polymers in the region corresponding to the region (low basis weight region 42, “abdominal side” or “Y region” in Table 1).
[0050]
(3) Evaluation of absorbent body Disposable diapers were manufactured using the absorbent bodies obtained in the examples and comparative examples. The configuration of the disposable diaper was the same as that of a commercially available disposable diaper manufactured by Kao Corporation (trade name “Merry's Pants Lean Smart”) except that the absorbent bodies obtained in Examples and Comparative Examples were used. The absorber was arrange | positioned so that a high basic weight area | region may be located in the belly side of a diaper.
About the obtained disposable diaper, in order to evaluate the difficulty of leaking, the forward value was measured as follows. The results are shown in Table 1.
[0051]
[Measurement method of the previous value]
Put a pants-type diaper manufactured using each absorber on a human body model that has a model urination part on the front side, and put the physiological saline at a rate of 10 g / sec from the model urination part with the front side on the floor (collapsed). Inject into diapers. Every time 50 g was flown, the operation of passing again for 10 seconds and reflowing was repeated, and the weight until leakage from the front side (waist opening) was measured.
[0052]
[Table 1]
Figure 0004070661
[0053]
From the results shown in Table 1, in the examples, in the obtained absorbent body, a portion having a higher absorption capacity than other portions is sufficiently formed, and the absorption performance of the portion is sufficiently exhibited. I understand. On the other hand, the absorbent body of the comparative example does not have a high basis weight on the front side (Comparative Example 1), and the pulp / polymer weight ratio is greatly different between before and after, and the desired pre-leakage prevention performance is exhibited. There wasn't.
Moreover, it turns out that the leakage prevention property of a disposable diaper can be improved by suppressing the usage-amount of a superabsorbent polymer by using the absorber obtained in the Example.
[0054]
【The invention's effect】
According to the method for producing an absorbent body of the present invention, an absorbent body having a portion designed to have a partly high absorption capacity and capable of sufficiently expressing the absorbent performance of the portion is efficiently produced. And it can be manufactured economically.
[Brief description of the drawings]
FIG. 1 is a plan view showing a state in which an example of an absorbent body manufactured according to the present invention is used as a part of a disposable diaper, and a part showing a state when the disposable diaper is viewed from a top sheet side. FIG.
2 is a diagram showing the absorber of FIG. 1 alone, FIG. 2 (a) is a plan view, and FIG. 2 (b) is a schematic cross-sectional view taken along line XX of FIG. 2 (a). It is sectional drawing shown.
FIG. 3 is a schematic view showing an absorbent body production apparatus preferably used in the practice of the present invention.
4 is a diagram showing an example of the arrangement of the stacking recesses and the first and second suction regions, FIG. 4A is an overhead view of the stacking recesses, and FIG. It is sectional drawing which shows the YY line cross section of a) typically.
FIG. 5 is a diagram showing another arrangement of the first and second suction regions.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Disposable diaper 2 Top sheet 3 Back sheet 4 Absorber 5 Rotation (stacking) drum 50 Concave part 51 1st suction area 52 2nd suction area 53 Boundary part of 1st suction area and 2nd suction area

Claims (5)

高吸水性ポリマー及びパルプ繊維を飛散状態で供給し、底面部に多数の吸引孔を設けた集積用凹部に吸引堆積させ、前記高吸水性ポリマー及び前記パルプ繊維の堆積物を、前記集積用凹部内から離型して吸収体を製造する吸収体の製造方法であって、
前記集積用凹部の底面部に、開口面積率の高い第1吸引領域と第1吸引領域よりも開口面積率の低い第2吸引領域を設け、第1吸引領域の開口面積率R1を40〜80%、第2吸引領域の開口面積率R2を2〜20%、両開口面積率の比(Rl/R2)を70/30〜99/1の範囲とし、これら両吸引領域に対し、前記集積用凹部の底面部の裏側から大気圧に対して1〜20kPa減圧した同一圧力の真空圧を作用させ、これら両吸引領域に前記高吸水性ポリマー及び前記パルプ繊維を堆積させることを特徴とする吸収体の製造方法。
Supplying the superabsorbent polymer and pulp fiber in a scattered state, sucking and depositing the superabsorbent polymer and the pulp fiber in the stacking recess having a large number of suction holes on the bottom surface, It is a manufacturing method of an absorber which molds from the inside and manufactures an absorber,
A first suction region having a high opening area ratio and a second suction region having a lower opening area ratio than the first suction area are provided on the bottom surface of the accumulation recess, and an opening area ratio R1 of the first suction region is set to 40 to 80. %, The opening area ratio R2 of the second suction area is 2 to 20%, and the ratio (Rl / R2) of both opening area ratios is in the range of 70/30 to 99/1 . An absorber having the same pressure reduced by 1 to 20 kPa with respect to atmospheric pressure from the back side of the bottom surface of the recess, and depositing the superabsorbent polymer and the pulp fiber in both suction regions Manufacturing method.
第1吸引領域と第2吸引領域との境界部に、厚み調整手段としての段差を設けない請求項1記載の吸収体の製造方法。  The manufacturing method of the absorber of Claim 1 which does not provide the level | step difference as a thickness adjustment means in the boundary part of a 1st suction area | region and a 2nd suction area | region. 前記高吸水性ポリマーと前記パルプ繊維を混合状態で飛散させる請求項1又は2記載の吸収体の製造方法。The method for producing an absorbent body according to claim 1 or 2 , wherein the superabsorbent polymer and the pulp fiber are scattered in a mixed state. 第1吸引領域及び第2吸引領域は、前記吸引孔の大きさを同じとするが該吸引孔のピッチを異ならせることにより、前記開口面積率を相互に異ならせてある請求項1〜3の何れか記載の吸収体の製造方法。The first suction area and the second suction area have the same size of the suction holes, but the opening area ratios are made different from each other by changing the pitch of the suction holes. The manufacturing method of the absorber in any one. 第1吸引領域及び第2吸引領域は、前記吸引孔のピッチを同じとするが該吸引孔の大きさを異ならせることにより、前記開口面積率を相互に異ならせてある請求項1〜3の何れか記載の吸収体の製造方法。The first suction region and the second suction region have the same pitch of the suction holes, but have different opening area ratios by making the sizes of the suction holes different from each other. The manufacturing method of the absorber in any one.
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DE60325672T DE60325672D1 (en) 2002-06-10 2003-06-06 An absorbent core and method of making the same
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TW092115530A TWI270371B (en) 2002-06-10 2003-06-09 An absorbent member and a method of producing an absorbent member
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