JP3619981B2 - Eye makeup cosmetics - Google Patents
Eye makeup cosmetics Download PDFInfo
- Publication number
- JP3619981B2 JP3619981B2 JP29593098A JP29593098A JP3619981B2 JP 3619981 B2 JP3619981 B2 JP 3619981B2 JP 29593098 A JP29593098 A JP 29593098A JP 29593098 A JP29593098 A JP 29593098A JP 3619981 B2 JP3619981 B2 JP 3619981B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- makeup
- acrylate
- examples
- usability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002537 cosmetic Substances 0.000 title claims description 24
- 229920001296 polysiloxane Polymers 0.000 claims description 27
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 22
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- 150000001875 compounds Chemical class 0.000 claims description 9
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- 229920005989 resin Polymers 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- -1 2-ethylhexyl Chemical group 0.000 description 54
- 230000000694 effects Effects 0.000 description 20
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
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- 239000003205 fragrance Substances 0.000 description 3
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- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
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- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
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Description
【０００１】
【発明の属する技術分野】
本発明は、アイメイクアップ化粧料において、アイメイクアップ化粧料に必要な目元をはっきりさせるという化粧効果に加えて、塗膜のツヤとその持続性に優れるという新しい化粧効果を併せ持ち、また化粧持ちと使用性に優れ、安全性、安定性も良好なアイメイクアップ化粧料に関する。
【０００２】
【従来の技術】
従来、アイメイクアップ化粧料は、睫、アイライン、眉などに使用し、目元をはっきりさせるといった化粧効果をもつものであるが、最近は加えて、塗膜にエナメルの様なツヤを与えて、より特徴的な新しい化粧効果を演出するものが求められている。
一般的に従来のアイメイクアップ化粧料は、固形状油分、例えばワックスやロウ類、及び粉体、皮膜形成剤を中心として構成されており、化粧品としての快適な使用性、使用感、及び機能性を持たせるために、種々の性状、性質をもつワックス類、粉体、皮膜形成剤の配合検討が行われてきた。
【０００３】
【発明が解決しようとする課題】
しかしながら、ワックスやロウ類、粉体、皮膜形成剤といった一般的に従来から使用されている成分の配合検討のみでは、目元をはっきり見せるといった機能は演出できるが、目元にツヤを与えるという新しい化粧効果を演出するには十分な効果が得られなかった。例えば、マスカラの場合、ワックスやロウ類などの固形状油分を増量すると、睫を上にカールしボリュームを与え目元をきわだたせることができるものの、塗膜のツヤはなくなってしまうといった欠点があった。逆に、固形状油分を減量すると塗膜のツヤは出るものの、カール力、ボリューム感が不足し、汗や皮脂で化粧膜が崩れやすくなり、まぶたの下へにじんだり、化粧膜が欠落してしまい、化粧効果の持続に欠けるといった欠点があった。
【０００４】
【課題を解決するための手段】
そこで本発明者らは、上記課題を解決するため鋭意研究した結果、アクリル−シリコーン系グラフト共重合体とロジン酸系樹脂を用いることにより、ツヤがあって、且つ目元をきわだたせるといった化粧効果に優れ、化粧持ちが良く、良好な使用性、使用感及び均一な化粧膜を付与できる事を見出し、本発明を開発するに至った。すなわち本発明は、次の成分（ａ）、（ｂ）；
（ａ）分子鎖の片末端にラジカル重合性基を有するオルガノポリシロキサン化合物と、アクリレート及び／又はメタクリレートを主体とし且つ炭素数１２〜３０のアルキル（メタ）アクリレートを含有するラジカル重合性モノマーとを共重合して得られるアクリル−シリコーン系グラフト共重合体０．１〜２０重量％
（ｂ）ロジン酸系樹脂１〜２５重量％
を含有することを特徴とするアイメイクアップ化粧料に関するものである。
【０００５】
【発明の実施の形態】
以下、本発明を詳細に説明する。
本発明に使用される成分（ａ）のアクリル−シリコーン系グラフト共重合体は、分子鎖の片末端にラジカル重合性基を有するオルガノポリシロキサン化合物とアクリレート及び／又はメタクリレートを主体とするラジカル重合性モノマーをラジカル重合することにより得られ、特開平２−２５４１１号公報、特開平２−１３２１４１号公報等に記載されているものが例示される。例えば、分子鎖の片末端にラジカル重合性を有するオルガノポリシロキサン化合物は、下記一般式（１）
【０００６】
【化１】
Ｒ１：メチル基又は水素原子
Ｒ２：場合によりエーテル結合１個又は２個で遮断されている直鎖状又は分岐状の炭素鎖を有する炭素原子１〜１０個の２価の飽和炭化水素基
Ｒ３：メチル基又はブチル基
ｌ：３〜３００
で表されるものが挙げられる。
【０００８】
一方、アクリレート及び／又はメタクリレートを主体とするラジカル重合性モノマーはラジカル重合性不飽和結合を分子中に１個有する化合物を意味し、使用されるアクリレート及び／又はメタクリレートとしては、メチル（メタ）アクリレート、エチル（メタ）アクリレート、ｎ−ブチル（メタ）アクリレート、ステアリル（メタ）アクリレート、ベヘニル（メタ）アクリレート、２−エチルヘキシル（メタ）アクリレート等のアルキル（メタ）アクリレート、２−ヒドロキシエチル（メタ）アクリレート、２−ヒドロキシプロピル（メタ）アクリレート等のヒドロキシアルキル（メタ）アクリレート、フルオロ炭素鎖１〜１０のパーフルオロアルキル（メタ）アクリレート、コレステリル（メタ）アクリレート、アルキルコレステリル（メタ）アクリレート、（メタ）アクリル酸アミドを例示することができる。また、本発明におけるアクリレート及び／又はメタクリレートを主体とするラジカル重合性モノマーにおいて、上記したアクリレート及び／又はメタクリレート以外に必要に応じて種々の重合性モノマー化合物を使用することができる。これらの化合物としては、スチレン、置換スチレン、酢酸ビニル、（メタ）アクリル酸、無水マレイン酸、マレイン酸エステル、フマル酸エステル、塩化ビニル、塩化ビニリデン、エチレン、プロピレン、ブタジエン、アクリロニトリル、フッ化オレフィン、Ｎ−ビニルピロリドン等を例示することができる。また、本発明のアイメイクアップ化粧料において、炭素数１２〜３０のアルキル（メタ）アクリレートを使用することを必須とする。炭素数１２〜３０のアルキル（メタ）アクリレートを使用すると、ツヤ感が一段と向上する。分子鎖の片末端にラジカル重合性基を有するジメチルポリシロキサン化合物（Ａ）とアクリレート及び／又はメタクリレートを主体とするラジカル共重合性モノマー（Ｂ）との共重合は、重合比率（（Ａ）／（Ｂ））：１／１９〜２／１の範囲内で、ベンゾイルパーオキサイド、ラウロイルパーオキサイド、アゾビスイソブチロニトリル等の通常のラジカル重合開始剤の存在下で行われ、溶液重合法、乳化重合法、懸濁重合法、バルク重合法のいずれの方法の適用も可能である。市販品としては、ＫＰ５６１（信越化学工業社製）等が挙げられる。
【０００９】
アクリル−シリコーン系グラフト共重合体は、本発明のアイメイクアップ化粧料中により好ましくは０．１〜２０重量％（以下、単に「％」で示す。）、更に好ましくは１〜１０％の範囲で配合される。配合量がこの範囲であればツヤ、化粧持ち、化粧効果において特に良好なものが得られる。また、これらのアクリル−シリコーン系グラフト共重合体は必要に応じて１種又は２種以上を用いることができる。
【００１０】
本発明に用いられる成分（ｂ）のロジン酸系樹脂は、ロジンの多価アルコールエステルで、ロジン、水添ロジン、重合ロジンの主成分である樹脂酸を多価アルコール類でエステル化したものである。このロジンの多価アルコールエステルを構成する多価アルコール類は、例えば、ペンタエリスリット、ジペンタエリスリット、グリセリン、エチレングリコール、プロピレングリコール、ジエチレングリコール、ネオペンチルグリコール、トリメチロールプロパン、ヘキサントリオール等が挙げられる。これらのロジン酸系樹脂は必要に応じ、１種又は２種以上を用いることができる。
本発明に用いられるロジン酸系樹脂の配合量は、全組成物中１〜２５％が好ましく、特に５〜２０％が好ましい。配合量がこの範囲であればツヤ、化粧持ち、化粧効果、使用性、使用感の面で良好なものが得られる。
【００１１】
本発明のアイメイクアップ化粧料には、上記した必須成分の他に、通常化粧料に使用される成分、例えば炭化水素、高級脂肪酸エステル、動植物油脂、シリコーン油、フッ素系油等の油性成分や、有機顔料、無機顔料等の粉体、水溶性高分子、アルコール類、水等の水性成分、界面活性剤、紫外線吸収剤、保湿剤、酸化防止剤、美容成分、防腐剤、香料などを本発明の効果を損なわない範囲で適宜配合することができる。
【００１２】
油性成分としては、必須成分の他に、動物油、植物油、合成油等の起源、及び、固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類、油性ゲル化剤類等が挙げられる。具体的には、流動パラフィン、スクワラン、ワセリン、ポリイソブチレン、ポリブテン、パラフィンワックス、セレシンワックス、マイクロクリスタリンワックス、エチレンプロピレンコポリマー、モクロウ、モンタンワックス、フィッシュトロプスワックス等の炭化水素類、オリーブ油、ヒマシ油、ホホバ油、ミンク油、マカデミアンナッツ油等の油脂類、ミツロウ、カルナウバワックス、キャンデリラワックス、ゲイロウ等のロウ類、セチルイソオクタネート、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、トリオクタン酸グリセリル、ジイソステアリン酸ポリグリセリル、トリイソステアリン酸ジグリセリル、トリベヘン酸グリセリル、ジオクタン酸ネオペンチルグリコール、コレスレロール脂肪酸エステル、Ｎ−ラウロイル−Ｌ−グルタミン酸ジ（コレステリル・ベヘニル・オクチルドデシル）等のエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、イソステアリン酸、オレイン酸、１２−ヒドロキシステアリン酸等の脂肪酸類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、低重合度ジメチルポリシロキサン、高重合度ジメチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、ポリエーテル変性ポリシロキサン、ポリオキシアルキレン・アルキルメチルポリシロキサン・メチルポリシロキサン共重合体、アルコキシ変性ポリシロキサン、架橋型オルガノポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体、デキストリン脂肪酸エステル、蔗糖脂肪酸エステル、デンプン脂肪酸エステル、１２−ヒドロキシステアリン酸アルミニウム、ステアリン酸カルシウム等の油性ゲル化剤類等が挙げられる。
【００１３】
粉体としては、形状も球状、板状、針状等特に限定することなく配合できる。例えば無機粉体としては、タルク、カオリン、マイカ、合成マイカ、セリサイト、炭酸マグネシウム、炭酸カルシウム、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムマグネシウム、無水ケイ酸、炭化珪素、硫酸バリウム、ベントナイト、スメクタイト、酸化チタン、酸化亜鉛、酸化マグネシウム、酸化アルミニウム、ベンガラ、黄酸化鉄、黒酸化鉄、一酸化チタン、チッ化硼素、酸化クロム、コンジョウ、群青、酸化鉄雲母、酸化鉄雲母チタン、雲母チタン、オキシ塩化ビスマス等が挙げられ、有機粉体としては、ナイロン粉末、ポリエチレン粉末、ポリスチレン粉末、シリコーン粉末、メチルメタアクリレート粉末、ポリテトラフルオロエチレンパウダー、ウールパウダー、シルクパウダー、結晶セルロース、タール系色素及びそのレーキ色素等、又、これらの粉体を複合化したものが挙げられる。更にフッ素化合物、シリコーン系油剤、金属石鹸、ロウ、油脂、炭化水素等の１種又は２種以上を用いて表面処理を施したものを用いることもできる。
【００１４】
水性成分としては、水に可溶な成分であれば何れでもよく、例えば、エチルアルコール、イソプロピルアルコール等のアルコール類、プロピレングリコール、１，３−ブチレングリコール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、ソルビトール、マルチトール、ショ糖、でんぷん糖、ラクチトール等の糖類、グアーガム、コンドロイチン硫酸ナトリウム、ヒアルロン酸ナトリウム、アラビアガム、アルギン酸ナトリウム、カラギーナン、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸ナトリウム等の水溶性高分子、塩化ナトリウム、塩化マグネシウム、乳酸ナトリウム等の塩類、アロエベラ、ウィッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液等及び水が挙げられる。
【００１５】
界面活性剤としては、非イオン界面活性剤、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤等が挙げられる。
非イオン界面活性剤としては、例えば、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、プロピレングリコール脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビトールの脂肪酸エステル及びそのアルキレングリコール付加物、ポリアルキレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、ポリオキシアルキレンアルキルエーテル、グリセリンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン硬化ヒマシ油、ラノリンのアルキレングリコール付加物、ポリオキシアルキレン変性シリコーン、ポリエーテル変性シリコーン等が挙げられる。
アニオン界面活性剤としては、例えば、ステアリン酸、ラウリン酸等の脂肪酸の無機及び有機塩、アルキルベンゼン硫酸塩、アルキルスルホン酸塩、α−オレフィンスルホン酸塩、ジアルキルスルホコハク酸塩、α−スルホン化脂肪酸塩、アシルメチルタウリン塩、Ｎ−メチル−Ｎ−アルキルタウリン塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、アルキル燐酸塩、ポリオキシエチレンアルキルエーテル燐酸塩、ポリオキシエチレンアルキルフェニルエーテル燐酸塩、Ｎ−アシルアミノ酸塩、Ｎ−アシル−Ｎ−アルキルアミノ酸塩、ο−アルキル置換リンゴ酸塩、アルキルスルホコハク酸塩等が挙げられる。
カチオン界面活性剤としては、例えば、アルキルアミン塩、ポリアミン及びアルカノールアミン脂肪酸誘導体、アルキル四級アンモニウム塩、環式四級アンモニウム塩等が挙げられる。
両性界面活性剤としては、レシチンやリゾレシチン及びこれらの水素添加物等のリン脂質含有成分、アミノ酸タイプやベタインタイプのカルボン酸型、硫酸エステル型、スルホン酸型、リン酸エステル型のものがあり、人体に対して安全とされるものが使用できる。例えば、Ｎ，Ｎ−ジメチル−Ｎ−アルキル−Ｎ−カルボキシルメチルアンモニウムベタイン、Ｎ，Ｎ−ジアルキルアミノアルキレンカルボン酸、Ｎ，Ｎ，Ｎ−トリアルキル−Ｎ−スルフォアルキレンアンモニウムベタイン、Ｎ，Ｎ−ジアルキル−Ｎ，Ｎ−ビス（ポリオキシエチレン硫酸）アンモニウムベタイン、２−アルキル−１−ヒドロキシエチル−１−カルボキシメチルイミダゾリニウムベタイン等を挙げられる。
【００１６】
紫外線吸収剤としては、例えば、ベンゾフェノン系としては、２−ヒドロキシ−４−メトキシベンゾフェノン、２−ヒドロキシ−４−メトキシベンゾフェノン−５−スルホン酸、２−ヒドロキシ−４−メトキシベンゾフェノン−５−スルホン酸ナトリウム、２，２’−ジヒドロキシ−４，４’−ジメトキシベンゾフェノン、２，２’−ジヒドロキシ−４，４’−ジメトキシベンゾフェノン−５−スルホン酸ナトリウム、２，４−ジヒドロキシベンゾフェノン、２，２’，４，４’−テトラヒドロキシベンゾフェノン等が挙げられ、ＰＡＢＡ系としては、パラアミノ安息香酸、パラアミノ安息香酸エチル、パラアミノ安息香酸グリセリル、パラジメチルアミノ安息香酸アミル、パラジメチルアミノ安息香酸−２−エチルヘキシル、パラジヒドロキシプロピル安息香酸エチル等が挙げられ、ケイ皮酸系としては、ｐ−メトキシケイ皮酸−２−エチルヘキシル、４−メトキシケイ皮酸−２−エトキシエチル等が挙げられ、サリチル酸系としては、サリチル酸−２−エチルヘキシル、サリチル酸フェニル、サリチル酸ホモメンチル等が挙げられ、その他、２−（２−ヒドロキシ−５−メチルフェニル）ベンゾトリアゾール、４−ｔｅｒｔ−ブチル−４’−メトキシジベンゾイルメタン、オキシベンゾン等が挙げられる。
【００１７】
保湿剤としては、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等が挙げられる。酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等が挙げられる。美容成分としては、例えばビタミン類、消炎剤、生薬等が挙げられる。防腐剤としては、例えばパラオキシ安息香酸アルキル、フェノキシエタノール等が挙げられる。
【００１８】
本発明のアイメイクアップ化粧料の形態としては、非水系、Ｗ／Ｏ型、Ｏ／Ｗ型等，それぞれ固形状、半固形状、液状等が挙げられ、マスカラ、アイライナー、アイブロー、アイカラー等として使用することができる。
【００１９】
【実施例】
以下に実施例をあげて本発明を更に説明する。尚、これらは本発明を何ら限定するものではない。
【００２０】
製造例１ アクリル−シリコーン系グラフト共重合体１
下記組成式（２）
【００２１】
【化２】
で示される片末端メタクリレート置換ジメチルポリシロキサン５０ｇ、メチルメタクリレート１０ｇ、ステアリルメタクリレート４０ｇ、トルエン１００ｇを混合し、続いてアゾビスイソブチロニトリル１．５ｇを添加、溶解させた後、攪拌下に８０〜９０℃の温度範囲内で５時間反応させ粘ちょうな溶液を得た。この溶液をメタノール中に注ぎ込み、グラフトポリマーを沈殿析出せしめた。沈殿物を濾別し、乾燥させて重合体を得た。
【００２３】
製造例２ アクリル−シリコーン系グラフト共重合体２
下記組成式（３）
【００２４】
【化３】
で示される片末端メタクリレート置換ジメチルポリシロキサン６０ｇ、ｎ−ブチルメタクリレート５ｇ、ステアリルメタクリレート２５ｇ、ベヘニルメタクリレート１０ｇ、トルエン１００ｇを混合し、続いてアゾビスイソブチロニトリル１．５ｇを添加、溶解させた後、攪拌下に８０〜９０℃の温度範囲内で５時間反応させ粘ちょうな溶液を得た。この溶液をメタノール中に注ぎ込み、グラフトポリマーを沈殿析出せしめた。沈殿物を濾別し、乾燥させて重合体を得た。
【００２６】
実施例１〜１０及び比較例１〜２：マスカラ
表１に示す処方のマスカラを調製し、ツヤ、化粧持ち（にじみにくさ）、カール力、ボリューム感等の化粧効果、塗布時の化粧のしやすさ（使用性及び使用感）について下記の方法により官能評価を行った。その結果も併せて表１に示す。
【００２７】
【表１】
（製造方法）
実施例１〜１０及び比較例１〜２
Ａ．成分（１）〜（５）、（７）を加熱溶解し、成分（６）、（８）〜（１０）を加え、均一に混合する。
Ｂ．Ａを容器に充填して製品とする。
【００２９】
（評価方法）
１０名の官能パネルにより、各試料を下記ａ〜ｄについて、（１）絶対評価基準を用いて７段階に評価し、各試料ごとの評点の平均値を（２）４段階評価基準を用いて評価した。
ａ．塗布膜のツヤ
ｂ．化粧持ち（にじみにくさ）
ｃ．化粧効果（カール力、ボリューム感）
ｄ．化粧のしやすさ（使用性、及び使用感）
（１）絶対評価基準
（評点）：（評価）
６：非常に良い
５：良い
４：やや良い
３：普通
２：やや悪い
１：悪い
０：非常に悪い
（２）４段階評価基準
５点を超える：非常に良好：◎
３点を超えて５点以下：良好 ：○
１点を超えて３点以下：やや不良 ：△
１点以下：不良 ：×
【００３０】
表１の結果から明らかなように、本発明品である実施例１〜１０のマスカラは塗布膜のツヤ、化粧持ち（にじみにくさ）、化粧効果（カール力、ボリューム感）に優れ、使用性、使用感も良いものであった。これに対し、比較例１〜２のマスカラにおいては塗布膜のツヤ、化粧持ち（にじみにくさ）、化粧効果（カール力、ボリューム感）、使用性、使用感のすべてに優れるものは得られなかった。
【００３１】
実施例１１ 非水系アイライナー
（成分） （％）
（１）アクリル−シリコーン系グラフト共重合体 ５
（２）ロジン酸ペンタエリスリット ５
（３）ポリイソブチレン １５
（４）パルミチン酸デキストリン ３
（５）カルナウバワックス ２
（６）有機変性ベントナイト ４
（７）軽質流動イソパラフィン ４６
（８）黒酸化鉄 ６
（９）タルク １４
（製造方法）
Ａ．（１）〜（５）、（７）を均一に加熱溶解し、（６）、（８）、（９）を加え均一に混合する。
Ｂ．Ａを容器に充填し、製品とする。
以上のようにして得られた非水系アイライナーは塗布膜のツヤ、化粧持ち、使用感、使用性の点で優れた特性を有するものが得られた。
【００３２】
実施例１２ Ｏ／Ｗ型マスカラ
（成分） （％）
（１）アクリル−シリコーン系
グラフト共重合体 １０
（２）ロジン酸ネオペンチルグリコール １０
（３）カルナウバワックス ２
（４）ステアリン酸 ２
（５）セタノール ２
（６）モノステアリン酸グリセリン １
（７）モノオレイン酸
ポリオキシエチレンソルビタン １
（８）酸化チタン １
（９）グンジョウ ５
（１０）タルク ３
（１１）マイカ ３
（１２）トリエタノールアミン １
（１３）１，３−ブチレングリコール ５
（１４）ポリアクリル酸ポリマーエマルション
（固形分５０％） ３０
（１５）香料 ０．１
（１６）防腐剤 ０．５
（１７）精製水 残量
（製造方法）
Ａ．（１）〜（７）を均一に加熱し、（８）〜（１１）を加え混合する。
Ｂ．（１２）〜（１７）を均一に混合する。
Ｃ．ＡにＢを加え乳化する。
Ｄ．Ｃを容器に充填して製品とする。
以上のようにして得られたＯ／Ｗ型マスカラは、塗布膜のツヤ、化粧持ち、化粧効果（カール力、ボリューム感）、使用感、使用性の点で優れた特性を有するものが得られた。
【００３３】
実施例１３ Ｗ／Ｏアイカラー
（成分） （％）
（１）アクリル−シリコーン系
グラフト共重合体 １５
（２）ロジン酸ペンタエリスリット ３
（３）ロジン酸トリメチロールプロパン ２
（４）ポリオキシアルキレン・
アルキルメチルポリシロキサン・
メチルポリシロキサン共重合体 ４
（５）デカメチルシクロペンタシロキサン ２０
（６）酸化チタン １
（７）グンジョウ １
（８）赤色２０２号 ０．５
（９）タルク ３
（１０）マイカ ３
（１１）雲母チタン １０
（１２）ナイロンパウダー ５
（１３）１，３−ブチレングリコール ５
（１４）香料 ０．１
（１５）防腐剤 ０．５
（１６）精製水 残量
（製造方法）
Ａ．（１）〜（１２）を混合する。
Ｂ．（１３）〜（１６）を混合溶解する。
Ｃ．ＡにＢを加えて乳化する。
Ｄ．Ｃを容器に充填して製品とする。
以上のようにして得られたＷ／Ｏ型アイカラーは、塗布膜のツヤ、化粧持ち、使用感、使用性の点で優れた特性を有するものが得られた。
【００３４】
実施例１４ 粉末固形状アイブロー
（成分） （％）
（１）アクリル−シリコーン系
グラフト共重合体 ５
（２）ロジン酸ペンタエリスリット ２
（３）イソオクタン酸セチル １０
（４）シリコンＫＦ９６（６ＣＳ） ３
（５）マイカ ４０
（６）タルク ２６．４
（７）ナイロンパウダー ３
（８）雲母チタン ３
（９）黒酸化鉄 ６．５
（１０）紺青 ０．５
（１１）防腐剤 ０．５
（１２）香料 ０．１
（製造方法）
Ａ．（１）〜（４）を均一に加熱溶解する。
Ｂ．（５）〜（１１）を混合する。
Ｃ．ＢにＡ及び（１２）を加え、混合する。
Ｄ．Ｃをプレス成型して製品とする。
以上のようにして得られた粉末固形状アイブローは、塗布膜のツヤ、化粧持ち、化粧効果（ボリューム感）、使用感、使用性の点で優れた特性を有するものが得られた。
【００３５】
【発明の効果】
本発明のアイメイクアップ化粧料は、アクリル−シリコーン系グラフト共重合体、ロジン酸系樹脂を用いることにより、目元をはっきりさせるという化粧効果に加えて、塗布膜のツヤ、化粧持ち（にじみにくさ）、化粧効果（カール力、ボリューム感）に優れ、使用性、使用感も良いアイメイクアップ化粧料である。[0001]
BACKGROUND OF THE INVENTION
In addition to the cosmetic effect of clarifying the eye area necessary for eye makeup cosmetics, the present invention has a new cosmetic effect of excellent gloss and durability of the coating film. The present invention relates to eye makeup cosmetics that have excellent usability, safety, and stability.
[0002]
[Prior art]
Conventionally, eye makeup cosmetics have a cosmetic effect that is used for eyelids, eyelines, eyebrows, etc., and makes the eyes clear. Recently, however, the paint has been given a gloss like enamel. There is a need for a new and more characteristic makeup effect.
In general, conventional eye makeup cosmetics are mainly composed of solid oils such as waxes and waxes, powders, and film-forming agents, and are comfortable to use, feel and function as cosmetics. In order to impart the properties, studies have been made on the blending of waxes, powders, and film forming agents having various properties and properties.
[0003]
[Problems to be solved by the invention]
However, a new cosmetic effect that gives a gloss to the eyes can be achieved with the ability to clearly show the eyes only by studying the combination of ingredients that have been conventionally used such as waxes, waxes, powders, and film forming agents. The effect was not enough to produce. For example, in the case of mascara, increasing the amount of solid oil such as wax or wax can curl up the straw and give a volume to make the eye noticeable, but the gloss of the paint film will be lost. It was. On the contrary, if the solid oil content is reduced, the gloss of the coating film will appear, but the curling power and volume feeling will be insufficient, and the makeup film will easily collapse due to sweat and sebum, oozing under the eyelids, and the makeup film will be missing As a result, there was a drawback that the makeup effect was not sustained.
[0004]
[Means for Solving the Problems]
Therefore, as a result of intensive studies to solve the above-mentioned problems, the present inventors have found that the use of an acrylic-silicone graft copolymer and a rosin acid-based resin has a glossy effect that makes the eyes noticeable. The present invention has been developed by finding that it has excellent makeup, good makeup, good usability, usability and uniform makeup film. That is, the present invention includes the following components (a) and (b):
(A) an organopolysiloxane compound having a radical polymerizable group at one end of a molecular chain, and a radical polymerizable monomer mainly composed of acrylate and / or methacrylate and containing an alkyl (meth) acrylate having 12 to 30 carbon atoms 0.1-20% by weight of an acrylic-silicone graft copolymer obtained by copolymerizing
(B) 1 to 25% by weight of rosin acid resin
In particular, the present invention relates to an eye makeup cosmetic.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described in detail.
The acrylic-silicone graft copolymer of component (a) used in the present invention is a radically polymerizable compound mainly composed of an organopolysiloxane compound having a radically polymerizable group at one end of a molecular chain and acrylate and / or methacrylate. Examples are those obtained by radical polymerization of monomers and described in JP-A-2-25411, JP-A-2-132141 and the like. For example, an organopolysiloxane compound having radical polymerizability at one end of a molecular chain is represented by the following general formula (1)
[0006]
[Chemical 1]
R 1 : a methyl group or a hydrogen atom R 2 : a divalent saturated hydrocarbon group having 1 to 10 carbon atoms having a linear or branched carbon chain optionally blocked by one or two ether bonds R 3 : methyl group or butyl group l: 3 to 300
The thing represented by is mentioned.
[0008]
On the other hand, the radical polymerizable monomer mainly composed of acrylate and / or methacrylate means a compound having one radical polymerizable unsaturated bond in the molecule, and the acrylate and / or methacrylate used is methyl (meth) acrylate. , Ethyl (meth) acrylate, n-butyl (meth) acrylate, stearyl (meth) acrylate, behenyl (meth) acrylate, 2-ethylhexyl (meth) acrylate and other alkyl (meth) acrylates, 2-hydroxyethyl (meth) acrylate , Hydroxyalkyl (meth) acrylates such as 2-hydroxypropyl (meth) acrylate, perfluoroalkyl (meth) acrylates having 1 to 10 fluorocarbon chains, cholesteryl (meth) acrylate, alkyl cholesteryl ( Data) acrylate can be exemplified (meth) acrylic acid amide. Moreover, in the radically polymerizable monomer mainly composed of acrylate and / or methacrylate in the present invention, various polymerizable monomer compounds can be used as required in addition to the above-mentioned acrylate and / or methacrylate. These compounds include styrene, substituted styrene, vinyl acetate, (meth) acrylic acid, maleic anhydride, maleic acid ester, fumaric acid ester, vinyl chloride, vinylidene chloride, ethylene, propylene, butadiene, acrylonitrile, fluorinated olefins, Examples thereof include N-vinyl pyrrolidone. In the eye makeup cosmetic of the present invention, it is essential to use an alkyl (meth) acrylate having 12 to 30 carbon atoms . With alkyl (meth) acrylate of 12 to 30 carbon atoms, gloss is further improved. Copolymerization of the dimethylpolysiloxane compound (A) having a radical polymerizable group at one end of the molecular chain with the radical copolymerizable monomer (B) mainly composed of acrylate and / or methacrylate is carried out by polymerization ratio ((A) / (B)): In the range of 1/19 to 2/1, it is carried out in the presence of a normal radical polymerization initiator such as benzoyl peroxide, lauroyl peroxide, azobisisobutyronitrile, solution polymerization method, Any of an emulsion polymerization method, a suspension polymerization method, and a bulk polymerization method can be applied. As a commercial item , KP561 (made by Shin-Etsu Chemical Co., Ltd.) etc. are mentioned.
[0009]
The acrylic-silicone graft copolymer is more preferably 0.1 to 20% by weight (hereinafter simply indicated as “%”) in the eye makeup cosmetic of the present invention, and more preferably in the range of 1 to 10%. It is blended with. If the blending amount is within this range, a particularly good gloss, makeup lasting and cosmetic effect can be obtained. These acrylic-silicone graft copolymers may be used alone or in combination of two or more as required.
[0010]
The rosin acid resin of component (b) used in the present invention is a polyhydric alcohol ester of rosin, which is obtained by esterifying resin acid, which is the main component of rosin, hydrogenated rosin, and polymerized rosin, with polyhydric alcohols. is there. Examples of the polyhydric alcohols constituting the polyhydric alcohol ester of rosin include pentaerythritol, dipentaerythritol, glycerin, ethylene glycol, propylene glycol, diethylene glycol, neopentyl glycol, trimethylolpropane, and hexanetriol. It is done. These rosin acid-based resins may be used alone or in combination of two or more.
The blending amount of the rosin acid-based resin used in the present invention is preferably 1 to 25%, particularly preferably 5 to 20%, based on the total composition. If the blending amount is within this range, a product having good gloss, makeup lasting, makeup effect, usability and usability can be obtained.
[0011]
In addition to the essential components described above, the eye makeup cosmetics of the present invention include components commonly used in cosmetics such as hydrocarbons, higher fatty acid esters, animal and vegetable oils, silicone oils, fluorine oils, , Organic pigments, inorganic pigments, water-soluble polymers, alcohols, water and other aqueous components, surfactants, UV absorbers, moisturizers, antioxidants, beauty ingredients, preservatives, perfumes, etc. It can mix | blend suitably in the range which does not impair the effect of invention.
[0012]
As oily components, in addition to essential components, regardless of the origin of animal oils, vegetable oils, synthetic oils, and properties such as solid oils, semi-solid oils, liquid oils, volatile oils, hydrocarbons, fats and oils, Examples thereof include waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorinated oils, lanolin derivatives, and oily gelling agents. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, owl, montan wax, fish trops wax, olive oil, castor oil Oils such as jojoba oil, mink oil, macadamian nut oil, waxes such as beeswax, carnauba wax, candelilla wax, gay wax, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, Glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, neopentyl glycol dioctanoate, choleslero Fatty acid esters, esters such as N-lauroyl-L-glutamic acid di (cholesteryl, behenyl, octyldodecyl), stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, and fatty acids such as 12-hydroxystearic acid , Stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, Octamethylcyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, alcohol Si-modified polysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane and other silicones, perfluorodecane, perfluorooctane, perfluoropolyether and other fluorine oils, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol Lanolin derivatives such as dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxyaluminum stearate, calcium stearate and other oily gelling agents.
[0013]
The powder can be blended without any particular limitation such as spherical shape, plate shape, needle shape and the like. For example, inorganic powders include talc, kaolin, mica, synthetic mica, sericite, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, magnesium aluminum silicate, anhydrous silicic acid, silicon carbide, barium sulfate, bentonite, Smectite, Titanium oxide, Zinc oxide, Magnesium oxide, Aluminum oxide, Bengala, Yellow iron oxide, Black iron oxide, Titanium monoxide, Boron nitride, Chromium oxide, Conger, Ultramarine, Mica oxide, Titanium oxide mica, Mica titanium Organic powders include nylon powder, polyethylene powder, polystyrene powder, silicone powder, methyl methacrylate powder, polytetrafluoroethylene powder, wool powder, silk powder, crystalline cellulose, tar series And boron lake dyes, also include those powders that complexed. Furthermore, what performed the surface treatment using 1 type (s) or 2 or more types, such as a fluorine compound, a silicone type oil agent, metal soap, wax, fats and oils, and a hydrocarbon, can also be used.
[0014]
The aqueous component may be any component that is soluble in water, for example, alcohols such as ethyl alcohol and isopropyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol. Glycerols such as glycerin, diglycerin, polyglycerin, saccharides such as sorbitol, maltitol, sucrose, starch sugar, lactitol, guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, methylcellulose, hydroxy Water-soluble polymers such as ethyl cellulose, carboxymethyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate, sodium chloride, magnesium chloride Um, salts such as sodium lactate, aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, plant extracts, etc. and water rose and the like.
[0015]
Examples of the surfactant include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants.
Examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol addition. Of sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin Examples include alkylene glycol adducts, polyoxyalkylene-modified silicones, polyether-modified silicones, etc. It is.
Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfates, alkylsulfonates, α-olefinsulfonates, dialkylsulfosuccinates, α-sulfonated fatty acid salts. , Acylmethyl taurate, N-methyl-N-alkyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl phenyl Examples thereof include ether phosphates, N-acyl amino acid salts, N-acyl-N-alkyl amino acid salts, o-alkyl substituted malate salts, and alkyl sulfosuccinate salts.
Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.
Amphoteric surfactants include phospholipid-containing components such as lecithin and lysolecithin and their hydrogenated products, amino acid type and betaine type carboxylic acid type, sulfate ester type, sulfonic acid type, phosphate ester type, Anything that is safe for the human body can be used. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine and 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine.
[0016]
Examples of the UV absorber include 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, and 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid sodium as benzophenone series. 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone-5-sulfonic acid sodium salt, 2,4-dihydroxybenzophenone, 2,2 ′, 4 , 4′-tetrahydroxybenzophenone, etc., and examples of the PABA system include paraaminobenzoic acid, ethyl paraaminobenzoate, glyceryl paraaminobenzoate, amyl paradimethylaminobenzoate, 2-dimethylhexyl paradimethylaminobenzoate, paradihydroxy Professional Ethyl benzoate and the like, and cinnamic acid type include p-methoxycinnamic acid-2-ethylhexyl, 4-methoxycinnamic acid-2-ethoxyethyl and the like, and salicylic acid type includes salicylic acid- Examples thereof include 2-ethylhexyl, phenyl salicylate, homomenthyl salicylate, and the like, and other examples include 2- (2-hydroxy-5-methylphenyl) benzotriazole, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like. .
[0017]
Examples of the humectant include protein, mucopolysaccharide, collagen, elastin, keratin and the like. Examples of the antioxidant include α-tocopherol and ascorbic acid. Examples of the beauty component include vitamins, anti-inflammatory agents, herbal medicines and the like. Examples of the preservative include alkyl paraoxybenzoate and phenoxyethanol.
[0018]
Examples of the form of the eye makeup cosmetic of the present invention include non-aqueous, W / O type, O / W type, etc., solid, semi-solid, liquid, etc., respectively, mascara, eyeliner, eyebrow, eye color Can be used as etc.
[0019]
【Example】
The following examples further illustrate the present invention. Note that these do not limit the present invention.
[0020]
Production Example 1 Acrylic-silicone graft copolymer 1
The following composition formula (2)
[0021]
[Chemical formula 2]
After mixing 50 g of one-end methacrylate-substituted dimethylpolysiloxane, 10 g of methyl methacrylate, 40 g of stearyl methacrylate, and 100 g of toluene, 1.5 g of azobisisobutyronitrile was added and dissolved, and then the mixture was stirred at 80 to 80 with stirring. The mixture was reacted for 5 hours within a temperature range of 90 ° C. to obtain a viscous solution. This solution was poured into methanol to precipitate the graft polymer. The precipitate was filtered off and dried to obtain a polymer.
[0023]
Production Example 2 Acrylic-silicone graft copolymer 2
The following composition formula (3)
[0024]
[Chemical 3]
After mixing 60 g of one-end methacrylate-substituted dimethylpolysiloxane, 5 g of n-butyl methacrylate, 25 g of stearyl methacrylate, 10 g of behenyl methacrylate, and 100 g of toluene, and then adding and dissolving 1.5 g of azobisisobutyronitrile. The mixture was reacted for 5 hours in the temperature range of 80 to 90 ° C. with stirring to obtain a viscous solution. This solution was poured into methanol to precipitate the graft polymer. The precipitate was filtered off and dried to obtain a polymer.
[0026]
Examples 1 to 10 and Comparative Examples 1 and 2: Mascara Mascara having the formulation shown in Table 1 was prepared, and makeup effects such as gloss, makeup retention (bleeding resistance), curling power, and volume feeling, and makeup when applied. Sensory evaluation was performed by the following method about ease (usability and usability). The results are also shown in Table 1.
[0027]
[Table 1]
(Production method)
Examples 1-10 and Comparative Examples 1-2
A. Components (1) to (5) and (7) are dissolved by heating, and components (6) and (8) to (10) are added and mixed uniformly.
B. A is filled into a container to obtain a product.
[0029]
(Evaluation methods)
With 10 sensory panels, each sample was evaluated in 7 levels using the absolute evaluation criteria for the following a to d, and the average score for each sample was (2) using the 4-step evaluation criteria. evaluated.
a. Gloss of coating film b. Long-lasting makeup
c. Makeup effect (curl strength, volume)
d. Ease of makeup (usability and feel)
(1) Absolute evaluation criteria (score): (Evaluation)
6: Very good 5: Good 4: Slightly good 3: Normal 2: Slightly bad 1: Poor 0: Very bad (2) Exceeding 4-point evaluation criteria of 5 points: Very good: A
3 points to 5 points or less: Good: ○
More than 1 point and 3 points or less: Somewhat bad: △
1 point or less: Defect: ×
[0030]
As is apparent from the results in Table 1, the mascara of Examples 1 to 10, which are the products of the present invention, are excellent in gloss of the coating film, long-lasting (bleeding resistance), and cosmetic effect (curling power, volume feeling), and usability. The usability was also good. On the other hand, in the mascara of Comparative Examples 1 and 2, it is not possible to obtain a coating film that is excellent in gloss, makeup lasting (bleeding difficulty), makeup effect (curling power, volume feeling), usability and usability. It was.
[0031]
Example 11 Non-aqueous eyeliner (component) (%)
(1) Acrylic-silicone graft copolymer 5
(2) Pentaerislits for rosin acid 5
(3) Polyisobutylene 15
(4) Dextrin palmitate 3
(5) Carnauba wax 2
(6) Organically modified bentonite 4
(7) Light liquid isoparaffin 46
(8) Black iron oxide 6
(9) Talc 14
(Production method)
A. (1) to (5) and (7) are uniformly heated and dissolved, and (6), (8) and (9) are added and mixed uniformly.
B. Fill A into a container to make a product.
The non-aqueous eyeliner obtained as described above was obtained having excellent properties in terms of gloss of the coating film, makeup durability, usability, and usability.
[0032]
Example 12 O / W type mascara (component) (%)
(1) Acrylic-silicone graft copolymer 10
(2) Neopentyl glycol rosinate 10
(3) Carnauba wax 2
(4) Stearic acid 2
(5) Cetanol 2
(6) Glycerol monostearate 1
(7) Polyoxyethylene sorbitan monooleate 1
(8) Titanium oxide 1
(9) Gunjo 5
(10) Talc 3
(11) Mica 3
(12) Triethanolamine 1
(13) 1,3-butylene glycol 5
(14) Polyacrylic acid polymer emulsion (solid content 50%) 30
(15) Fragrance 0.1
(16) Preservative 0.5
(17) Remaining amount of purified water (production method)
A. (1) to (7) are heated uniformly, and (8) to (11) are added and mixed.
B. (12) to (17) are mixed uniformly.
C. Add B to A and emulsify.
D. Fill the container with C to make a product.
The O / W type mascara obtained as described above has excellent properties in terms of gloss of the coating film, makeup durability, makeup effect (curling power, volume feeling), feeling of use and usability. It was.
[0033]
Example 13 W / O eye color (component) (%)
(1) Acrylic-silicone graft copolymer 15
(2) Rosin acid pentaerythrit 3
(3) Trimethylolpropane rosinate 2
(4) Polyoxyalkylene
Alkylmethylpolysiloxane
Methyl polysiloxane copolymer 4
(5) Decamethylcyclopentasiloxane 20
(6) Titanium oxide 1
(7) Gunjo 1
(8) Red No. 202 0.5
(9) Talc 3
(10) Mica 3
(11) Mica titanium 10
(12) Nylon powder 5
(13) 1,3-butylene glycol 5
(14) Fragrance 0.1
(15) Preservative 0.5
(16) Purified water remaining (manufacturing method)
A. (1) to (12) are mixed.
B. (13) to (16) are mixed and dissolved.
C. B is added to A and emulsified.
D. Fill the container with C to make a product.
The W / O type eye color obtained as described above was obtained with excellent properties in terms of gloss of the coating film, long-lasting makeup, feeling of use, and usability.
[0034]
Example 14 Powdered solid eyebrow (component) (%)
(1) Acrylic-silicone graft copolymer 5
(2) Pentaeri slit 2 rosin acid
(3) Cetyl isooctanoate 10
(4) Silicon KF96 (6CS) 3
(5) Mica 40
(6) Talc 26.4
(7) Nylon powder 3
(8) Mica titanium 3
(9) Black iron oxide 6.5
(10) Bitumen 0.5
(11) Preservative 0.5
(12) Fragrance 0.1
(Production method)
A. (1) to (4) are uniformly dissolved by heating.
B. (5) to (11) are mixed.
C. Add A and (12) to B and mix.
D. C is press molded into a product.
The powdered solid eyebrow obtained as described above was obtained with excellent properties in terms of gloss of the coated film, makeup durability, makeup effect (volume feeling), usability and usability.
[0035]
【The invention's effect】
The eye makeup cosmetic of the present invention uses an acrylic-silicone-based graft copolymer and a rosin acid-based resin, in addition to the cosmetic effect of clarifying the eye area, gloss of the coating film, and long-lasting makeup ), Eye makeup cosmetics with excellent cosmetic effects (curling power, volume feeling), good usability and usability.
Claims (1)
（ａ）分子鎖の片末端にラジカル重合性基を有するオルガノポリシロキサン化合物と、アクリレート及び／又はメタクリレートを主体とし且つ炭素数１２〜３０のアルキル（メタ）アクリレートを含有するラジカル重合性モノマーとを共重合して得られるアクリル−シリコーン系グラフト共重合体０．１〜２０重量％
（ｂ）ロジン酸系樹脂１〜２５重量％
を含有することを特徴とするアイメイクアップ化粧料。The following components (a), (b);
(A) an organopolysiloxane compound having a radical polymerizable group at one end of the molecular chain, and a radical polymerizable monomer mainly composed of acrylate and / or methacrylate and containing an alkyl (meth) acrylate having 12 to 30 carbon atoms ; 0.1-20% by weight of an acrylic-silicone graft copolymer obtained by copolymerizing
(B) 1 to 25% by weight of rosin acid resin
Eye makeup cosmetics characterized by containing a cosmetic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29593098A JP3619981B2 (en) | 1998-10-16 | 1998-10-16 | Eye makeup cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29593098A JP3619981B2 (en) | 1998-10-16 | 1998-10-16 | Eye makeup cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000119139A JP2000119139A (en) | 2000-04-25 |
| JP3619981B2 true JP3619981B2 (en) | 2005-02-16 |
Family
ID=17826969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29593098A Expired - Fee Related JP3619981B2 (en) | 1998-10-16 | 1998-10-16 | Eye makeup cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3619981B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10034829B2 (en) | 2010-10-27 | 2018-07-31 | Noxell Corporation | Semi-permanent mascara compositions |
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|---|---|---|---|---|
| JP4919543B2 (en) * | 2001-05-31 | 2012-04-18 | 株式会社コーセー | Water-in-oil emulsified cosmetic |
| JP5064623B2 (en) * | 2001-09-25 | 2012-10-31 | 株式会社コーセー | Cosmetic for salmon |
| JP2005306845A (en) * | 2004-03-24 | 2005-11-04 | Kose Corp | Cake powder cosmetic |
| JP4801918B2 (en) * | 2005-03-25 | 2011-10-26 | 株式会社コーセー | Oily salmon cosmetic |
| JP4805595B2 (en) * | 2005-03-30 | 2011-11-02 | 株式会社コーセー | Oily salmon cosmetic |
| JP2009522268A (en) * | 2005-12-30 | 2009-06-11 | エイボン プロダクツ インコーポレーテッド | How to curl eyelashes |
| JP5214863B2 (en) * | 2006-08-30 | 2013-06-19 | 株式会社コーセー | Eye makeup cosmetics |
| JP5558669B2 (en) * | 2008-02-06 | 2014-07-23 | 株式会社コーセー | Water-in-oil emulsified makeup cosmetics |
| EP2262467B1 (en) * | 2008-03-04 | 2017-09-20 | Avon Products, Inc. | Cosmetic compositions for imparting superhydrophobic films |
| KR101014498B1 (en) * | 2008-09-01 | 2011-02-14 | (주)아모레퍼시픽 | Eye makeup cosmetic composition |
| KR101830292B1 (en) | 2009-12-24 | 2018-03-29 | 다우 코닝 도레이 캄파니 리미티드 | Surface-treatment agent for powder for use in cosmetic and cosmetic containing powder treated with the same |
| US10047199B2 (en) | 2009-12-24 | 2018-08-14 | Dow Corning Toray Co., Ltd. | Copolymer having carbosiloxane dendrimer structure, and composition and cosmetic containing the same |
| JP6092545B2 (en) | 2012-08-22 | 2017-03-08 | 東レ・ダウコーニング株式会社 | Copolymer having carbosiloxane dendrimer structure and hydrophilic group and use thereof |
| JP5797618B2 (en) | 2012-08-22 | 2015-10-21 | 東レ・ダウコーニング株式会社 | Copolymer having carbosiloxane dendrimer structure, and composition and cosmetic containing the same |
| US10633539B2 (en) * | 2016-03-10 | 2020-04-28 | Momentive Performance Materials Inc. | Composition comprising organosiloxane nano latex and preparation of organosiloxane nano latex |
-
1998
- 1998-10-16 JP JP29593098A patent/JP3619981B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10034829B2 (en) | 2010-10-27 | 2018-07-31 | Noxell Corporation | Semi-permanent mascara compositions |
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| Publication number | Publication date |
|---|---|
| JP2000119139A (en) | 2000-04-25 |
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