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JP3655765B2 - Welded steel pipe with excellent weather resistance - Google Patents

Welded steel pipe with excellent weather resistance Download PDF

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Publication number
JP3655765B2
JP3655765B2 JP564199A JP564199A JP3655765B2 JP 3655765 B2 JP3655765 B2 JP 3655765B2 JP 564199 A JP564199 A JP 564199A JP 564199 A JP564199 A JP 564199A JP 3655765 B2 JP3655765 B2 JP 3655765B2
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less
steel
amount
weather resistance
weld metal
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JP564199A
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JP2000204436A (en
Inventor
好男 寺田
照久 高本
邦夫 小山
明 宇佐見
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Nippon Steel Corp
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Nippon Steel Corp
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Description

【0001】
【発明の属する技術分野】
本発明は、海浜地区や融雪塩を散布する地区など、高飛来海塩粒子環境で塩害が懸念される大気環境における橋梁、鉄塔などの鋼構造物に使用される優れた耐候性を有する溶接鋼管に関するものである。
【0002】
【従来の技術】
従来、海岸地帯などの塩害が発生する場所で使用する鋼構造部材の防食として、普通鋼材の塗装使用、めっき鋼板、溶射やモルタルライニングなどの表面被覆、ステンレスやチタンなどの高合金高耐食材料が使用されている。さらに、鋼構造物の維持管理費を低減する技術として、耐候性鋼材(JISG3141溶接構造用耐候性鋼)の無塗装使用がある。
塗装の場合、塗り替えが必要となるので、維持管理費が高くなる。また、めっきの場合、構造体の溶融めっきでは熱応力による変形やめっきの剥離がある。溶射やモルタルライニングの場合も、防食皮膜の剥離や劣化などの問題がある。さらに、高合金の耐食材料の場合、材料コストが高く、主要構造部材として、広く使えないという問題がある。
【0003】
耐候性鋼材は、無塗装使用の場合、使用後数年から10年で鋼材表面に防食性に優れた緻密な安定さびが形成し、この安定さびがその後の鋼材の腐食の進行を防ぐ鋼材である。鋼構造物には、溶接性を考慮した耐候性溶接構造用鋼が、橋梁や建築物を中心にこれまで多く使用されてきた。しかしながら、「無塗装耐候性橋梁の設計・施工要領(改訂案):建設省土木研究所、鋼材倶楽部、日本橋梁建設協会、平成5年3月」に示されるように、海浜地区や融雪塩を散布する地区など飛来海塩粒子が多い地域では、鋼材表面に付着した塩分によって保護性に優れた安定さびの形成が阻害されるために、無塗装使用に適さないといった問題点があった。
【0004】
耐候性鋼の海浜地区での鋼材の耐候性向上について、例えば特公昭56−9356号公報では、Pを0.03〜0.20%含有し、溶接性に優れ、かつ海水が関与した腐食環境や一般大気環境で優れた耐候性を有する鋼材が開示されている。また、特開平2−125839号公報には低Si−P−Cu−Niの複合添加にCaとAlの複合酸化物の添加が有効であることが記載されている。また、特開平5−51668号公報では、酸化物を鋼材中に微細分散させて、鋼材表面のpHの低下を抑制することが有効であることが開示されている。このように、従来の耐候性鋼の欠点である海浜地区での耐候性に優れた鋼材が開発されている。
【0005】
近年、橋梁の建設コストに大きな比重を占める部材の溶接を省略するために、鋼管を橋梁桁に使用することが提案されている。橋梁桁として使用される鋼管は、主としてUOEやBR(ベンディングロール)にて製造される大径の溶接鋼管である。これらの鋼管はサブマージドアーク溶接(SAW)により製造されるが、溶接入熱量が大きくなるため、Niを多く含む場合、溶接時に高温割れ(凝固割れ)が発生する。このため、海浜地区での耐候性に優れた溶接鋼管が強く望まれている。
【0006】
【発明が解決しようとする課題】
本発明は海浜地区での耐候性に優れた溶接鋼管を提供するものである。
【0007】
【課題を解決するための手段】
本発明の要旨は、重量%で、 C :0.03〜0.15%、 Si:0.6%以下、
Mn:0.3〜2.0%、 P :0.03%以下、
S :0.005%以下、 Cu:0.3〜1.0%、
Ni:1.0〜5.5%、 Cr:0.1%以下、
Ti:0.005〜0.03%、 Al:0.09%以下、
N :0.001〜0.006%、 O :0.006%以下
に、さらにMo:0.1〜1.0%、Nb:0.005〜0.1%、V:0.01〜0.1%、B:0.0003〜0.002%、Ca:0.001〜0.005%のうち一種または二種以上を含有し、残部が鉄および不可避的不純物からなる母材と、
C :0.03〜0.09%、 Si:0.6%以下、
Mn:0.3〜2.0%、 P :0.03%以下、
S :0.005%以下、 Cu:0.1〜1.0%、 Ni:1.0〜3.5%、 Cr:0.1%以下、
Ti:0.005〜0.03%、 Al:0.09%以下、
N :0.001〜0.006%、 O :0.02〜0.06%
に、さらにMo:0.1〜1.0%、Nb:0.005〜0.1%、V:0.01〜0.1%、B:0.0003〜0.002%、Ca:0.001〜0.005%のうち一種または二種以上を含有し、残部が鉄および不可避的不純物からなり、さらにNi量が前記母材の2.0%少ない領域から0.16%少ない領域の範囲にある溶接金属部を有することである。
【0008】
以下に、本発明の海浜地区での耐候性に優れた溶接鋼管について詳細に説明する。
従来、飛来海塩粒子の少ない内陸部において、耐候性の向上にはCrが有効であることが知られている。しかしながら、海浜地区や融雪塩を散布する地区などの高飛来塩粒子環境では、Crは耐候性に対して悪影響をおよぼすことが判明した。また、種々の合金元素について耐候性を向上させるための検討を行った結果、Cu−1%以上のNiの複合添加が海浜地区での安定さび生成に有効であることが明らかとなった。さらに、Cu−Ni系の適用限界(安定さびが十分に形成する上限の年平均飛来海塩粒子量)はNi添加量でほぼ整理できることが判明した。
【0009】
一方、溶接鋼管において、海浜地区において優れた耐候性を有し、かつ溶接品質に優れた溶接金属成分について鋭意検討した結果、溶接金属のNi量が母材の少なくとも2.0%少ない領域以上であれば、良好な耐候性が得られることを見出した。さらに、溶接金属のNi量が母材の0.2%以下で、かつ3.5%以下であること、および溶接金属中のC、P、S量を限定することにより、多量のNiを含有する場合でも高温割れが発生しないことを見出し、本発明に至った。
すなわち、本発明の特徴は、鋼管母材として、Ni−Cu系成分を適用し、溶接金属として、海浜地区での耐候性および高温割れ防止の観点からC量、P量、S量およびNi量を適正な範囲に限定することにより、海浜地区での耐候性に優れた溶接鋼管を提供するものである。
【0010】
まず、鋼管母材の成分限定理由について説明する。
Cは母材および溶接部の強度を確保するために必要な元素であり、その下限は0.03%である。しかしながら、C量が多すぎると低温靱性、溶接性が劣化するので、その上限の値を0.15%とした。
Siは脱酸や強度向上のため添加する元素であるが、多く添加すると溶接熱影響部(HAZ)靱性を劣化させるので、上限を0.6%とした。鋼の脱酸はAlやTiのみでも十分であり、Siは必ずしも添加する必要はない。
【0011】
Mnは強度、低温靱性を確保する上で不可欠な元素であり、その下限は0.3%である。しかしMnが多過ぎると鋼の焼入性が増加して溶接性を劣化させるだけでなく、連続鋳造鋼片の中心偏析を助長し、低温靱性も劣化させるので上限を2.0%とした。
Pは耐候性を向上させる元素であるが、0.03%を超えると低温靱性、溶接性が劣化するので、その上限の値を0.03%とした。とくに溶接部の高温割れを防止するためには、0.015%以下が好ましい。
【0012】
Sは鋼管の靱性や耐候性を劣化させる不可避的不純物であるので、少ないほど好ましい。とくに、0.01%を超えると、低温靱性が劣化するので、0.005%以下が好ましい。
Cuはさび層の形成時にさび粒子の結晶・粗大化を抑制し、さびの緻密さを保持するため、飛来海塩粒子の多い環境での耐候性を向上させる元素であり、この効果を発揮させるためには0.3%以上の添加が必要である。しかし、1.0%を超えると析出硬化により母材、HAZの靱性劣化や熱間圧延時にCu−クラックが発生するために、その上限の値を1.0%とした。
【0013】
Niはさび層表面に飛来海塩粒子として付着したClイオンのさび層/地鉄界面への浸透を抑制し、さび層内部を低Cl環境として、さび粒子の結晶化・粗大成長を抑制することにより、さび層の緻密さを保持する効果を有する。この効果を発揮させるためには、1.0%以上の添加が必要である。しかし5.5%以上の添加は鋼板表面にひび割れが発生するためにその上限の値を5.5%とした。Crは鉄よりも卑な金属であるため、数%の添加では海塩粒子の多い環境中での耐候性や溶接性を阻害するため、少なければ少ないほど好ましい。とくに、0.1%を超えると、耐候性が劣化するので、その上限の値を0.1%とした。
【0014】
Tiは微細なTiNを形成し、スラブ再加熱時およびHAZのγ粒の粗大化を抑制して、ミクロ組織を微細化して、母材およびHAZの低温靱性を改善し、本発明において必須の元素である。この効果を発揮させるためには0.005%以上の添加が必要である。また多すぎるとTiNの粗大化やTiCによる析出硬化が生じ、低温靱性を劣化させるので、その上限の値を0.03%に限定した。
Alは通常脱酸元素として効果を有する。しかし、Al量が0.09%を超えるとAl系非金属介在物が増加して、鋼の清浄度を劣化させるので、上限を0.09%とした。鋼の脱酸はTiのみでも十分であり、Alは必ずしも添加する必要はない。
【0015】
NはTiNを形成し、スラブ再加熱時およびHAZのγ粒の粗大化を抑制して母材、HAZの低温靱性を向上させる。このために必要な最小量は0.001%である。しかし、N量が多すぎるとスラブ表面きずや固溶NによるHAZ靱性の劣化の原因となるので、その上限の値は0.006%に抑える必要がある。
Oは鋼管の靱性を劣化させる不可避的不純物であるので、少ないほど好ましい。とくに0.006%を超えると鋼中に粗大な酸化物が多量に生成するため、靱性が劣化するので、その上限の値を0.006%とした。
【0016】
つぎに、Mo、Nb、V、Ca、Bを添加する理由について説明する。基本成分にさらにこれらの元素を添加する主たる目的は本発明鋼の特徴を損なうことなく、強度・低温靱性などの特性の向上を図るためである。したがってその添加量は自ら制限されるべき性質のものである。
Moは母材および溶接部の強度を上昇させる元素であるが、1.0%を超えると母材、HAZの靱性および溶接性を劣化させる。また0.1%以下の添加ではその効果が薄い。
【0017】
Nbは制御圧延時にγの再結晶を抑制して結晶粒を微細化するだけでなく、析出硬化や焼入れ性の増大にも寄与し、鋼を強靱化する作用を有する。この効果を得るためには0.005%のNbが必要である。しかしながら、Nb量が多すぎるとHAZ靱性が劣化するので、その上限の値を0.1%に限定した。
VはほぼNbと同様の効果を有するが、その効果はNbに比較して格段に弱い。その効果を発揮させるためには0.01%以上の添加が必要である。また上限は現地溶接性、HAZ靱性の点から0.1%まで許容できる。
【0018】
Bは極微量で鋼の焼入れ性を飛躍的に高め、良好な強度と靱性が得られる。この効果を発揮させるためには0.0003%以上の添加が必要である。また多すぎるとHAZ靱性を劣化させるので、その上限の値を0.002%に限定した。Caは硫化物(MnS)の形態を制御し、低温靱性を向上(シャルピー試験における吸収エネルギーの増加など)させる。0.001%以下ではその効果が少なく、また0.005%を超えて添加するとCaO−CaSが大量に生成してクラスター、大型介在物となり鋼の清浄度を害するだけでなく、現地溶接性にも悪影響をおよぼす。このためCa添加量を0.001〜0.005%に制限した。
【0019】
次に、溶接金属の成分限定理由について説明する。
良好な耐候性を有する、Niを多量に含有する鋼を大入熱で溶接する場合、高温割れが発生する。そこで、溶接金属の高温割れ防止および良好な耐候性確保のためには、C:0.03〜0.09%、P:0.01%以下、S:0.005%以下、Ni:1.0〜3.5%、かつNi量が母材の2.0%少ない領域から0.2%多い領域の範囲に限定する必要がある。C、P、SおよびNi量を限定することにより、高温割れを防止することができる。このため、C、P、S量の上限をそれぞれ0.09%、0.01%および0.005%に限定した。
【0020】
さらに、溶接金属のNi量が母材の0.16%少ない領域以下で、かつ3.5%以下であれば、高温割れを防止できる。なお、溶接金属のNi量が母材の少なくとも2.0%少ない領域以上であれば、良好な耐候性が得られるので、下限の値を1.0%かつ母材の少なくとも2.0%少ない量とした。また、Cは溶接部の強度を確保するために必要な元素であり、その効果を発揮させるために、下限の値を0.03%に限定した。
【0021】
Siは脱酸や強度向上のため添加する元素であるが、多く添加すると低温靱性を劣化させるので、上限を0.6%とした。
Mnは強度、低温靱性を確保する上で不可欠な元素であり、その下限は0.3%である。しかし、Mnが多すぎると鋼の焼入れ性が増加して低温靱性を劣化させるので、上限を2.0%とした。
Cuはさび層の形成時にさび粒子の結晶・粗大化を抑制し、さびの緻密さを保持するため、飛来海塩粒子の多い環境での耐候性を向上させる元素であり、溶接金属において、この効果を発揮させるためには0.1%以上の添加が必要である。しかし、1.0%を超えると析出硬化により、靱性が劣化するため、その上限の値を1.0%とした。
【0022】
Crは鉄よりも卑な金属であるため、数%の添加では海塩粒子の多い環境中での耐候性を阻害するため、少なければ少ないほど好ましい。とくに、0.1%を超えると、耐候性が劣化するので、その上限の値を0.1%とした。
Tiは微細なTiNやTiOを形成し、ミクロ組織を微細化して、溶接金属の低温靱性を改善する。この効果を発揮させるためには0.005%以上の添加が必要である。また多すぎるとTiCによる析出硬化が生じ、低温靱性を劣化させるので、その上限の値を0.03%に限定した。
【0023】
Alは通常脱酸元素として効果を有する。しかし、Al量が0.09%を超えるとAl系非金属介在物が増加して、鋼の清浄度を劣化させるので、上限を0.09%とした。鋼の脱酸はTiのみでも十分であり、Alは必ずしも添加する必要はない。
NはTiNを形成し、ミクロ組織を微細化して、低温靱性を向上させる。このために必要な最小量は0.001%である。しかし、N量が多すぎると固溶Nによる靱性の原因となるので、その上限の値は0.006%に抑える必要がある。Oは溶接金属中において酸化物を形成し、粒内変態フェライトの核として作用し、組織の微細化に効果がある。しかし、多すぎると溶接金属の低温靱性が劣化するとともに、スラグ巻き込みなどの溶接欠陥を起こす。このためO量の下限を0.02%、上限を0.06%とした。
【0024】
次に、Mo、Nb、V、B、Caを添加する理由について説明する。
基本となる成分にさらに、必要に応じてこれらの元素を添加する主たる目的は本発明鋼の優れた特徴を損なうことなく、溶接金属の強度・低温靱性などの特性の向上をはかるためである。したがって、その添加量は自ら制限されるべき性質のものである。
Moは溶接部の強度を上昇させる元素であるが、1.0%を超えると低温靱性を劣化させる。また0.1%以下の添加ではその効果が薄い。
【0025】
Nbは結晶粒を微細化するだけでなく、析出硬化や焼入れ性の増大にも寄与し、鋼を強靱化する作用を有する。この効果を得るためには最低0.005%のNbが必要である。しかしながら、Nb量が多すぎるとHAZ靱性が劣化するので、その上限の値を0.1%に限定した。
VはほぼNbと同様の効果を有するが、その効果はNbに比較して格段に弱い。その効果を発揮させるためには0.01%以上の添加が必要である。また上限は低温靱性の点から0.1%まで許容できる。
【0026】
Bは極微量で鋼の焼入れ性を飛躍的に高め、良好な強度と靱性が得られる。この効果を発揮させるためには0.0003%以上の添加が必要である。また多すぎると低温靱性を劣化させるので、その上限の値を0.002%に限定した。
Caは硫化物(MnS)の形態を制御し、低温靱性を向上(シャルピー試験における吸収エネルギーの増加など)させる。0.001%以下ではその効果が少なく、また0.005%を超えて添加するとCaO−CaSが大量に生成してクラスター、大型介在物となり、鋼の清浄度を害する。このためCa添加量を0.001〜0.005%に制限した。
【0027】
【実施例】
本発明の実施例について述べる。種々の鋼成分の鋼板を用いて、鋼管を製造し、諸性質を調査した。鋼管溶接部の品質(溶接欠陥の有無)は内外面1層のSAW(サブマージドアーク溶接)を実施した後、超音波探傷装置を用いて評価した。試作鋼管は離岸距離(平均飛来海塩粒子量)がそれぞれ、5m(1.3mdd)、50m(0.8mdd)、200m(0.5mdd)、800m(0.2mdd)の地点で暴露試験に供した。高海塩粒子環境での耐候性は、さびのイオン透過抵抗および腐食量から求めた平均板厚減少量から評価した。さびのイオン透過抵抗測定では、交流インピーダンス法によるさびのイオン透過抵抗値を測定し、3kΩ以上のものを緻密な安定さび形成と判断した。平均板厚減少量は4カ所での腐食−時間曲線から50年後の推定板厚減少量を求め、無塗装橋梁使用の基準である腐食量0.4mm/50年を無塗装使用可否の目安とした。
【0028】
【表1】

Figure 0003655765
【0029】
【表2】
Figure 0003655765
【0030】
【表3】
Figure 0003655765
【0031】
【表4】
Figure 0003655765
【0032】
実施例を表1〜表4に示す。本発明の溶接鋼管は母材および溶接部において優れた耐候性を有する。これに対して比較鋼は化学成分が適切でなく、いずれかの特性が劣る。
10は母材のC量が多すぎるため、母材の低温靱性が劣る。鋼11は母材のP量が多すぎるため、母材の低温靱性が劣る。鋼12は母材のS量が多すぎるため、母材の低温靱性が劣る。鋼13は母材のCu量が少ないため、母材の耐候性が劣る。鋼14は母材のNi量が少ないため、母材の耐候性が劣る。鋼15は母材のNi量が多すぎるため、母材にひび割れが発生する。鋼16は母材のCr量が多すぎるため、母材の耐候性が劣る。鋼17は溶接金属のC量が多すぎるため、溶接金属において高温割れが発生する。鋼18は溶接金属のP量が多すぎるため、溶接金属において高温割れが発生する。
【0033】
19は溶接金属のS量が多すぎるため、溶接金属において高温割れが発生する。鋼20は溶接金属のNi量が少ないため、溶接金属の耐候性が劣る。鋼21は溶接金属のNi量が多すぎるため、溶接金属において高温割れが発生する。鋼22は溶接金属のCr量が多すぎるため、溶接金属の耐候性が劣る。鋼23は溶接金属のNi量が母材のNi量よりも2.0%を超えて少なすぎるため、溶接金属の耐候性が劣る。鋼24は溶接金属のNi量が母材のNi量よりも0.2%を超えて多すぎるため、溶接金属において高温割れが発生する。
【0034】
【発明の効果】
本発明による海浜地区での優れた耐候性を有する溶接鋼管を橋梁などの鋼構造物の部材として採用することにより、鋼構造物の製造コストが低減されるとともに、保守管理の簡略化、管理費用の大幅な低減が可能となった。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a welded steel pipe having excellent weather resistance used for steel structures such as bridges and steel towers in an air environment where salt damage is a concern in a high-flying sea salt particle environment such as a beach area or a district where snow melting salt is dispersed. It is about.
[0002]
[Prior art]
Conventionally, as corrosion protection for steel structural members used in places where salt damage occurs such as coastal areas, use of ordinary steel coatings, plated steel sheets, surface coating such as spraying and mortar lining, high alloy high corrosion resistance materials such as stainless steel and titanium, etc. in use. Furthermore, as a technique for reducing the maintenance cost of the steel structure, there is a non-painting use of weathering steel (JISG 3141 weathering steel for welded structure).
In the case of painting, since it is necessary to repaint, the maintenance cost becomes high. In the case of plating, there is deformation due to thermal stress or peeling of the plating in the hot dipping of the structure. In the case of thermal spraying and mortar lining, there are problems such as peeling and deterioration of the anticorrosive film. Further, in the case of a high alloy corrosion resistant material, there is a problem that the material cost is high and it cannot be widely used as a main structural member.
[0003]
Weather-resistant steel is a steel material that, when used unpainted, forms a dense stable rust with excellent anticorrosion properties on the steel surface within a few years to 10 years after use, and this stable rust prevents the subsequent corrosion of the steel material. is there. For steel structures, weather-resistant welded structural steels that take weldability into account have been used so far, mainly in bridges and buildings. However, as shown in “Design and construction guidelines for unpainted weather-resistant bridges (draft): Ministry of Construction, Civil Engineering Research Institute, Steel Club, Japan Bridge Construction Association, March 1993” In areas where there are a lot of flying sea salt particles, such as the area where it is sprayed, the formation of stable rust with excellent protective properties is hindered by the salt attached to the steel surface, which makes it unsuitable for unpainted use.
[0004]
For improving the weather resistance of steel materials in the beach area of weathering steel, for example, Japanese Patent Publication No. 56-9356 discloses a corrosive environment containing 0.03 to 0.20% P, excellent weldability and sea water. Steel materials having excellent weather resistance in general atmospheric environments are disclosed. JP-A-2-125839 describes that the addition of a complex oxide of Ca and Al is effective for the complex addition of low Si—P—Cu—Ni. Japanese Patent Application Laid-Open No. 5-51668 discloses that it is effective to finely disperse oxides in a steel material to suppress a decrease in pH of the steel material surface. As described above, steel materials having excellent weather resistance in the beach area, which is a drawback of conventional weather resistant steel, have been developed.
[0005]
In recent years, it has been proposed to use steel pipes for bridge girders in order to omit welding of members that occupy a large specific gravity in bridge construction costs. A steel pipe used as a bridge girder is a large-diameter welded steel pipe manufactured mainly by UOE or BR (bending roll). Although these steel pipes are manufactured by submerged arc welding (SAW), the amount of welding heat input becomes large. Therefore, when a large amount of Ni is contained, hot cracking (solidification cracking) occurs during welding. For this reason, a welded steel pipe excellent in weather resistance in the beach area is strongly desired.
[0006]
[Problems to be solved by the invention]
The present invention provides a welded steel pipe having excellent weather resistance in a beach area.
[0007]
[Means for Solving the Problems]
The gist of the present invention is, by weight%, C: 0.03 to 0.15%, Si: 0.6% or less,
Mn: 0.3 to 2.0%, P: 0.03% or less,
S: 0.005% or less, Cu: 0.3-1.0%,
Ni: 1.0 to 5.5%, Cr: 0.1% or less,
Ti: 0.005 to 0.03%, Al: 0.09% or less,
N: 0.001 to 0.006%, O: 0.006% or less, Mo: 0.1 to 1.0%, Nb: 0.005 to 0.1%, V: 0.01 to 0 0.1%, B: 0.0003 to 0.002%, Ca: 0.001 to 0.005%, or one or two or more kinds, and the balance is made of iron and inevitable impurities,
C: 0.03 to 0.09%, Si: 0.6% or less,
Mn: 0.3 to 2.0%, P: 0.03% or less,
S: 0.005% or less, Cu: 0.1-1.0%, Ni: 1.0-3.5%, Cr: 0.1% or less,
Ti: 0.005 to 0.03%, Al: 0.09% or less,
N: 0.001-0.006%, O: 0.02-0.06%
Furthermore, Mo: 0.1 to 1.0%, Nb: 0.005 to 0.1%, V: 0.01 to 0.1%, B: 0.0003 to 0.002%, Ca: 0 .001-0.005% of one or two or more types, the balance is made of iron and inevitable impurities, and the amount of Ni is less than 2.0% of the base material to 0.16% less Having a weld metal part in range.
[0008]
Below, the welded steel pipe excellent in the weather resistance in the beach area of this invention is demonstrated in detail.
Conventionally, it is known that Cr is effective for improving weather resistance in an inland area where there are few flying sea salt particles. However, it has been found that Cr has an adverse effect on the weather resistance in a high-flying salt particle environment such as a beach area or a snow spray salt application area. Further, as a result of studies for improving the weather resistance of various alloy elements, it has been clarified that the combined addition of Ni of Cu-1% or more is effective for generating stable rust in the beach area. Furthermore, it has been found that the application limit of Cu—Ni system (the upper limit of the annual average amount of sea salt particles that can be sufficiently formed by stable rust) can be roughly arranged by adding Ni.
[0009]
On the other hand, in a welded steel pipe, as a result of intensive studies on a weld metal component having excellent weather resistance in the beach area and excellent weld quality, the Ni content of the weld metal is at least 2.0% less than that of the base metal. If it exists, it discovered that favorable weather resistance was acquired. Furthermore, a large amount of Ni is contained by limiting the amount of Ni in the weld metal to 0.2% or less and 3.5% or less of the base metal, and limiting the amount of C, P, and S in the weld metal. In this case, it was found that hot cracking does not occur, and the present invention has been achieved.
That is, the feature of the present invention is that a Ni-Cu-based component is applied as a steel pipe base material, and a C amount, a P amount, an S amount and a Ni amount are used as a weld metal from the viewpoint of weather resistance and prevention of hot cracking in a beach area. By limiting the range to an appropriate range, a welded steel pipe having excellent weather resistance in the beach area is provided.
[0010]
First, the reasons for limiting the components of the steel pipe base material will be described.
C is an element necessary for ensuring the strength of the base metal and the welded portion, and its lower limit is 0.03%. However, if the amount of C is too large, the low temperature toughness and weldability deteriorate, so the upper limit value was made 0.15%.
Si is an element added for deoxidation and strength improvement, but if added in a large amount, the weld heat-affected zone (HAZ) toughness deteriorates, so the upper limit was made 0.6%. For the deoxidation of steel, only Al or Ti is sufficient, and Si does not necessarily have to be added.
[0011]
Mn is an indispensable element for securing strength and low temperature toughness, and its lower limit is 0.3%. However, too much Mn not only increases the hardenability of the steel and deteriorates the weldability, but also promotes center segregation of the continuously cast steel slab and deteriorates the low temperature toughness, so the upper limit was made 2.0%.
P is an element that improves weather resistance, but if it exceeds 0.03%, the low temperature toughness and weldability deteriorate, so the upper limit value was made 0.03%. In particular, 0.015% or less is preferable in order to prevent hot cracking of the weld.
[0012]
Since S is an unavoidable impurity that deteriorates the toughness and weather resistance of the steel pipe, the smaller the amount, the better. In particular, if it exceeds 0.01%, the low temperature toughness deteriorates, so 0.005% or less is preferable.
Cu is an element that improves the weather resistance in an environment with a lot of incoming sea salt particles to suppress crystallization and coarsening of the rust particles during the formation of the rust layer and maintain the fineness of the rust. Therefore, addition of 0.3% or more is necessary. However, if it exceeds 1.0%, precipitation hardening causes toughness deterioration of the base material and HAZ and Cu-cracks are generated during hot rolling, so the upper limit value was made 1.0%.
[0013]
Ni suppresses the penetration of Cl ions adhering to the surface of the rust layer as flying sea salt particles into the rust layer / ground metal interface, and suppresses crystallization and coarse growth of the rust particles with a low Cl environment inside the rust layer. This has the effect of maintaining the denseness of the rust layer. In order to exert this effect, addition of 1.0% or more is necessary. However, addition of 5.5% or more causes cracks on the steel sheet surface, so the upper limit value was set to 5.5%. Since Cr is a base metal rather than iron, the addition of a few percent inhibits the weather resistance and weldability in an environment with many sea salt particles. In particular, if it exceeds 0.1%, the weather resistance deteriorates, so the upper limit value was made 0.1%.
[0014]
Ti forms fine TiN, suppresses coarsening of γ grains of HAZ during reheating of the slab, refines the microstructure, improves the low temperature toughness of the base material and HAZ, and is an essential element in the present invention It is. In order to exert this effect, 0.005% or more must be added. On the other hand, if the amount is too large, TiN coarsening and precipitation hardening due to TiC occur and the low-temperature toughness is deteriorated. Therefore, the upper limit value is limited to 0.03%.
Al usually has an effect as a deoxidizing element. However, if the Al content exceeds 0.09%, Al-based non-metallic inclusions increase and the cleanliness of the steel is deteriorated, so the upper limit was made 0.09%. For the deoxidation of steel, only Ti is sufficient, and Al is not necessarily added.
[0015]
N forms TiN and suppresses coarsening of γ grains of HAZ during reheating of the slab and improves the low temperature toughness of the base material and HAZ. The minimum amount required for this is 0.001%. However, if the amount of N is too large, it will cause deterioration of the HAZ toughness due to slab surface flaws and solid solution N, so the upper limit value must be limited to 0.006%.
Since O is an unavoidable impurity that deteriorates the toughness of the steel pipe, the smaller the amount, the better. In particular, if it exceeds 0.006%, a large amount of coarse oxides are produced in the steel and the toughness deteriorates, so the upper limit value was made 0.006%.
[0016]
Next, the reason for adding Mo, Nb, V, Ca, and B will be described. The main purpose of adding these elements to the basic components is to improve the properties such as strength and low temperature toughness without impairing the characteristics of the steel of the present invention. Therefore, the amount added is of a nature that should be restricted by itself.
Mo is an element that increases the strength of the base metal and the welded portion. However, if it exceeds 1.0%, the toughness and weldability of the base material and HAZ are deteriorated. In addition, the effect is small when 0.1% or less is added.
[0017]
Nb not only suppresses the recrystallization of γ during controlled rolling and refines the crystal grains, but also contributes to precipitation hardening and an increase in hardenability, and has the effect of strengthening the steel. To obtain this effect, 0.005% Nb is required. However, if the amount of Nb is too large, the HAZ toughness deteriorates, so the upper limit value was limited to 0.1%.
V has almost the same effect as Nb, but the effect is much weaker than Nb. In order to exhibit the effect, addition of 0.01% or more is necessary. Further, the upper limit is acceptable up to 0.1% from the viewpoint of on-site weldability and HAZ toughness.
[0018]
B is a very small amount and dramatically improves the hardenability of the steel, and good strength and toughness can be obtained. In order to exert this effect, 0.0003% or more must be added. Moreover, since HAZ toughness will deteriorate when there is too much, the upper limit was limited to 0.002%. Ca controls the form of sulfide (MnS) and improves low-temperature toughness (such as an increase in absorbed energy in the Charpy test). Less than 0.001%, the effect is small, and if added over 0.005%, CaO-CaS is produced in large quantities, resulting in clusters and large inclusions, not only detracting from the cleanliness of the steel, but also in the field weldability. Also adversely affects. For this reason, the amount of Ca added is limited to 0.001 to 0.005%.
[0019]
Next, the reason for limiting the components of the weld metal will be described.
When a steel having a good weather resistance and containing a large amount of Ni is welded with a large heat input, hot cracking occurs. Therefore, in order to prevent hot cracking of the weld metal and ensure good weather resistance, C: 0.03 to 0.09%, P: 0.01% or less, S: 0.005% or less, Ni: 1. It is necessary to limit the range of 0 to 3.5% and the range where Ni amount is 2.0% less than the base material to 0.2% more. By limiting the amounts of C, P, S and Ni, hot cracking can be prevented. For this reason, the upper limit of the amount of C, P, and S was limited to 0.09%, 0.01%, and 0.005%, respectively.
[0020]
Furthermore, hot cracking can be prevented if the amount of Ni in the weld metal is not more than 0.16% less than the base metal and not more than 3.5%. In addition, if the amount of Ni in the weld metal is at least 2.0% less than the base material, good weather resistance can be obtained, so the lower limit value is 1.0% and at least 2.0% less than the base material. The amount. Further, C is an element necessary for ensuring the strength of the welded portion, and the lower limit value is limited to 0.03% in order to exert the effect.
[0021]
Si is an element added for deoxidation and strength improvement, but if added in a large amount, the low temperature toughness deteriorates, so the upper limit was made 0.6%.
Mn is an indispensable element for securing strength and low temperature toughness, and its lower limit is 0.3%. However, if there is too much Mn, the hardenability of the steel increases and the low temperature toughness deteriorates, so the upper limit was made 2.0%.
Cu is an element that improves the weather resistance in an environment with a lot of incoming sea salt particles in order to suppress the rust particles from being crystallized and coarsened during the formation of the rust layer and maintain the fineness of the rust. In order to exhibit the effect, addition of 0.1% or more is necessary. However, if it exceeds 1.0%, the toughness deteriorates due to precipitation hardening, so the upper limit value was made 1.0%.
[0022]
Since Cr is a base metal rather than iron, addition of a few percent inhibits the weather resistance in an environment with a large amount of sea salt particles. In particular, if it exceeds 0.1%, the weather resistance deteriorates, so the upper limit value was made 0.1%.
Ti forms fine TiN and TiO, refines the microstructure, and improves the low temperature toughness of the weld metal. In order to exert this effect, 0.005% or more must be added. Moreover, since precipitation hardening by TiC will arise if there is too much and low temperature toughness will deteriorate, the upper limit value was limited to 0.03%.
[0023]
Al usually has an effect as a deoxidizing element. However, if the Al content exceeds 0.09%, Al-based non-metallic inclusions increase and the cleanliness of the steel is deteriorated, so the upper limit was made 0.09%. For the deoxidation of steel, only Ti is sufficient, and Al is not necessarily added.
N forms TiN, refines the microstructure, and improves low temperature toughness. The minimum amount required for this is 0.001%. However, if the amount of N is too large, it causes toughness due to solute N, so the upper limit value must be suppressed to 0.006%. O forms an oxide in the weld metal, acts as a nucleus of intragranular transformed ferrite, and is effective in refining the structure. However, if the amount is too large, the low temperature toughness of the weld metal deteriorates and welding defects such as slag entrainment occur. For this reason, the lower limit of the amount of O is set to 0.02%, and the upper limit is set to 0.06%.
[0024]
Next, the reason for adding Mo, Nb, V, B, and Ca will be described.
In addition to the basic components, the main purpose of adding these elements as necessary is to improve properties such as strength and low temperature toughness of the weld metal without impairing the excellent characteristics of the steel of the present invention. Therefore, the amount of addition is a property that should be restricted by itself.
Mo is an element that increases the strength of the welded portion, but if it exceeds 1.0%, the low temperature toughness is deteriorated. In addition, the effect is small when 0.1% or less is added.
[0025]
Nb not only refines crystal grains, but also contributes to precipitation hardening and hardenability, and has the effect of strengthening steel. To obtain this effect, a minimum of 0.005% Nb is required. However, if the amount of Nb is too large, the HAZ toughness deteriorates, so the upper limit value was limited to 0.1%.
V has almost the same effect as Nb, but the effect is much weaker than Nb. In order to exhibit the effect, addition of 0.01% or more is necessary. The upper limit is acceptable up to 0.1% from the viewpoint of low temperature toughness.
[0026]
B is a very small amount and dramatically improves the hardenability of the steel, and good strength and toughness can be obtained. In order to exert this effect, 0.0003% or more must be added. Moreover, since the low temperature toughness deteriorates if it is too much, the upper limit value is limited to 0.002%.
Ca controls the form of sulfide (MnS) and improves low-temperature toughness (such as an increase in absorbed energy in the Charpy test). If the amount is less than 0.001%, the effect is small, and if added over 0.005%, a large amount of CaO-CaS is formed to form clusters and large inclusions, which impairs the cleanliness of the steel. For this reason, the amount of Ca added is limited to 0.001 to 0.005%.
[0027]
【Example】
Examples of the present invention will be described. Steel pipes of various steel components were used to manufacture steel pipes and various properties were investigated. The quality (presence or absence of welding defects) of the welded portion of the steel pipe was evaluated using an ultrasonic flaw detector after performing SAW (submerged arc welding) of one layer on the inner and outer surfaces. The test steel pipes were subjected to exposure tests at points where the separation distance (average amount of sea salt particles) was 5 m (1.3 mdd), 50 m (0.8 mdd), 200 m (0.5 mdd), and 800 m (0.2 mdd), respectively. Provided. The weather resistance in the high sea salt particle environment was evaluated from the average reduction in plate thickness obtained from the ion permeation resistance and corrosion amount of rust. In the rust ion permeation resistance measurement, the rust ion permeation resistance value was measured by the AC impedance method, and a value of 3 kΩ or more was judged as the formation of dense stable rust. The average reduction in thickness is obtained from the corrosion-time curve at four locations, and the estimated reduction in thickness after 50 years is calculated. The standard for the use of unpainted bridges is 0.4mm / 50 years. It was.
[0028]
[Table 1]
Figure 0003655765
[0029]
[Table 2]
Figure 0003655765
[0030]
[Table 3]
Figure 0003655765
[0031]
[Table 4]
Figure 0003655765
[0032]
Examples are shown in Tables 1 to 4. The welded steel pipe of the present invention has excellent weather resistance in the base material and the welded portion. On the other hand, the chemical composition of the comparative steel is not appropriate, and any of the characteristics is inferior.
Steel 10 because the C content of the base material is too large, the low temperature toughness of the base material is poor. Since the steel 11 has too much P content of the base material, the low temperature toughness of the base material is inferior. Since steel 12 has too much S content in the base material, the low temperature toughness of the base material is inferior. Since steel 13 has a small amount of Cu in the base material, the weather resistance of the base material is inferior. Since the steel 14 has a small amount of Ni in the base material, the weather resistance of the base material is inferior. Since the amount of Ni in the base material of the steel 15 is too large, the base material is cracked. Since steel 16 has too much Cr in the base material, the weather resistance of the base material is inferior. Since the steel 17 has too much C in the weld metal, hot cracking occurs in the weld metal. Since the steel 18 has too much P amount of the weld metal, hot cracking occurs in the weld metal.
[0033]
Since the steel 19 has too much S in the weld metal, hot cracking occurs in the weld metal. Since the steel 20 has a small amount of Ni in the weld metal, the weather resistance of the weld metal is inferior. Since the steel 21 has too much Ni in the weld metal, hot cracking occurs in the weld metal. Since the steel 22 has too much Cr in the weld metal, the weather resistance of the weld metal is inferior. Steel 23 is inferior in the weather resistance of the weld metal because the Ni content of the weld metal exceeds 2.0% and is less than the Ni content of the base metal. Since the amount of Ni in the weld metal of the steel 24 is more than 0.2% than the amount of Ni in the base metal, hot cracking occurs in the weld metal.
[0034]
【The invention's effect】
By adopting a welded steel pipe having excellent weather resistance in the beach area according to the present invention as a member of a steel structure such as a bridge, the manufacturing cost of the steel structure is reduced and the maintenance management is simplified and the management cost is increased. Can be significantly reduced.

Claims (4)

重量%で、
C :0.03〜0.15%、 、 Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.03%以下、
S :0.005%以下、 Cu:0.3〜1.0%、
Ni:1.0〜5.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.006%以下
に残部が鉄および不可避的不純物からなる母材と、
C :0.03〜0.09%、
Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.01%以下、
S :0.005%以下、
Cu:0.1〜1.0%、
Ni:1.0〜3.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.02〜0.06%
に、残部が鉄および不可避的不純物からなり、さらにNi量が前記母材の2.0%少ない領域から0.16%少ない領域の範囲にある溶接金属部を有することを特徴とする耐候性に優れた溶接鋼管。
% By weight
C: 0.03 to 0.15%, Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.03% or less,
S: 0.005% or less, Cu: 0.3-1.0%,
Ni: 1.0 to 5.5%,
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: a base material consisting of iron and inevitable impurities with 0.006% or less remaining,
C: 0.03-0.09%,
Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.01% or less,
S: 0.005% or less,
Cu: 0.1 to 1.0%
Ni: 1.0 to 3.5%
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: 0.02 to 0.06%
In addition, the weather resistance is characterized in that the balance is made of iron and unavoidable impurities, and further has a weld metal part in which the amount of Ni is in the range of 2.0% less than the base metal to 0.16% less. Excellent welded steel pipe.
重量%で、
C :0.03〜0.15%、
Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.03%以下、
S :0.005%以下、
Cu:0.3〜1.0%、
Ni:1.0〜5.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.006%以下
に、さらにMo:0.1〜1.0%、Nb:0.005〜0.1%、V:0.01〜0.1%、B:0.0003〜0.002%、Ca:0.001〜0.005%のうち一種または二種以上を含有し、残部が鉄および不可避的不純物からなる母材と、
C :0.03〜0.09%、
Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.01%以下、
S :0.005%以下、
Cu:0.1〜1.0%、
Ni:1.0〜3.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.02〜0.06%
に残部が鉄および不可避的不純物からなり、さらにNi量が前記母材の2.0%少ない領域から0.16%少ない領域の範囲にある溶接金属部を有することを特徴とする耐候性に優れた溶接鋼管。
% By weight
C: 0.03-0.15%,
Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.03% or less,
S: 0.005% or less,
Cu: 0.3 to 1.0%,
Ni: 1.0 to 5.5%,
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: 0.006% or less, Mo: 0.1-1.0%, Nb: 0.005-0.1%, V: 0.01-0.1%, B: 0.0003-0 0.002%, Ca: one or two or more of 0.001 to 0.005%, with the balance being composed of iron and inevitable impurities,
C: 0.03-0.09%,
Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.01% or less,
S: 0.005% or less,
Cu: 0.1 to 1.0%
Ni: 1.0 to 3.5%
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: 0.02 to 0.06%
And the balance is made of iron and inevitable impurities, and further has a weld metal part in which the Ni amount is in the range of 2.0% less than the base metal to 0.16% less. Welded steel pipe.
重量%で、
C :0.03〜0.15%、
Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.03%以下、
S :0.005%以下、
Cu:0.3〜1.0%、
Ni:1.0〜5.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.006%以下
に残部が鉄および不可避的不純物からなる母材と、
C :0.03〜0.09%、
Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.01%以下、
S :0.005%以下、
Cu:0.1〜1.0%、
Ni:1.0〜3.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.02〜0.06%
に、さらにMo:0.1〜1.0%、Nb:0.005〜0.1%、V:0.01〜0.1%、B:0.0003〜0.002%、Ca:0.001〜0.005%のうち一種または二種以上を含有し、残部が鉄および不可避的不純物からなり、さらにNi量が前記母材の2.0%少ない領域から0.16%少ない領域の範囲にある溶接金属部を有することを特徴とする耐候性に優れた溶接鋼管。
% By weight
C: 0.03-0.15%,
Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.03% or less,
S: 0.005% or less,
Cu: 0.3 to 1.0%,
Ni: 1.0 to 5.5%,
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: a base material consisting of iron and inevitable impurities with 0.006% or less remaining,
C: 0.03-0.09%,
Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.01% or less,
S: 0.005% or less,
Cu: 0.1 to 1.0%
Ni: 1.0 to 3.5%
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: 0.02 to 0.06%
Furthermore, Mo: 0.1 to 1.0%, Nb: 0.005 to 0.1%, V: 0.01 to 0.1%, B: 0.0003 to 0.002%, Ca: 0 .001-0.005% of one or two or more types, the balance is made of iron and inevitable impurities, and the amount of Ni is less than 2.0% of the base material to 0.16% less A welded steel pipe excellent in weather resistance, characterized by having a weld metal part in a range.
重量%で、
C :0.03〜0.15%、
Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.03%以下、
S :0.005%以下、
Cu:0.3〜1.0%、
Ni:1.0〜5.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.006%以下
に、さらにMo:0.1〜1.0%、Nb:0.005〜0.1%、V:0.01〜0.1%、B:0.0003〜0.002%、Ca:0.001〜0.005%のうち一種または二種以上を含有し、残部が鉄および不可避的不純物からなる母材と、
C :0.03〜0.09%、
Si:0.6%以下、
Mn:0.3〜2.0%、
P :0.01%以下、
S :0.005%以下、
Cu:0.1〜1.0%、
Ni:1.0〜3.5%、
Cr:0.1%以下、
Ti:0.005〜0.03%、
Al:0.09%以下、
N :0.001〜0.006%、
O :0.02〜0.06%、
に、さらにMo:0.1〜1.0%、Nb:0.005〜0.1%、V:0.01〜0.1%、B:0.0003〜0.002%、Ca:0.001〜0.005%のうち一種または二種以上を含有し、残部が鉄および不可避的不純物からなり、さらにNi量が前記母材の2.0%少ない領域から0.16%少ない領域の範囲にある溶接金属部を有することを特徴とする耐候性に優れた溶接鋼管。
% By weight
C: 0.03-0.15%,
Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.03% or less,
S: 0.005% or less,
Cu: 0.3 to 1.0%,
Ni: 1.0 to 5.5%,
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: 0.006% or less, Mo: 0.1-1.0%, Nb: 0.005-0.1%, V: 0.01-0.1%, B: 0.0003-0 0.002%, Ca: one or two or more of 0.001 to 0.005%, with the balance being composed of iron and inevitable impurities,
C: 0.03-0.09%,
Si: 0.6% or less,
Mn: 0.3 to 2.0%,
P: 0.01% or less,
S: 0.005% or less,
Cu: 0.1 to 1.0%
Ni: 1.0 to 3.5%
Cr: 0.1% or less,
Ti: 0.005 to 0.03%,
Al: 0.09% or less,
N: 0.001 to 0.006%,
O: 0.02 to 0.06%,
Furthermore, Mo: 0.1 to 1.0%, Nb: 0.005 to 0.1%, V: 0.01 to 0.1%, B: 0.0003 to 0.002%, Ca: 0 .001-0.005% of one or two or more types, the balance is made of iron and inevitable impurities, and the amount of Ni is less than 2.0% of the base material to 0.16% less A welded steel pipe excellent in weather resistance, characterized by having a weld metal part in a range.
JP564199A 1999-01-12 1999-01-12 Welded steel pipe with excellent weather resistance Expired - Fee Related JP3655765B2 (en)

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