JP3653061B2 - Transparent cosmetic composition - Google Patents
Transparent cosmetic composition Download PDFInfo
- Publication number
- JP3653061B2 JP3653061B2 JP2002137634A JP2002137634A JP3653061B2 JP 3653061 B2 JP3653061 B2 JP 3653061B2 JP 2002137634 A JP2002137634 A JP 2002137634A JP 2002137634 A JP2002137634 A JP 2002137634A JP 3653061 B2 JP3653061 B2 JP 3653061B2
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- water
- oil
- cosmetic composition
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002537 cosmetic Substances 0.000 title abstract description 32
- 239000000203 mixture Substances 0.000 title abstract description 30
- -1 fatty acid ester Chemical class 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 24
- 239000000194 fatty acid Substances 0.000 claims abstract description 24
- 229930195729 fatty acid Natural products 0.000 claims abstract description 24
- 239000000839 emulsion Substances 0.000 claims abstract description 14
- 229920000223 polyglycerol Polymers 0.000 claims abstract description 10
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 9
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 4
- 150000004671 saturated fatty acids Chemical class 0.000 claims abstract description 4
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 4
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims abstract description 3
- 150000003839 salts Chemical class 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000013040 bath agent Substances 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 abstract description 7
- 239000002736 nonionic surfactant Substances 0.000 abstract description 5
- 210000004761 scalp Anatomy 0.000 abstract description 5
- 238000003287 bathing Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000003599 detergent Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 28
- 235000019198 oils Nutrition 0.000 description 28
- 238000011156 evaluation Methods 0.000 description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 235000002639 sodium chloride Nutrition 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 230000001804 emulsifying effect Effects 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- LDDUCKDUDZVHLN-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C LDDUCKDUDZVHLN-UHFFFAOYSA-N 0.000 description 1
- BKZCZANSHGDPSH-KTKRTIGZSA-N [3-(2,3-dihydroxypropoxy)-2-hydroxypropyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)COCC(O)CO BKZCZANSHGDPSH-KTKRTIGZSA-N 0.000 description 1
- SJLAFUFWXUJDDR-KTKRTIGZSA-N [3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]-2-hydroxypropyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)COCC(O)COCC(O)CO SJLAFUFWXUJDDR-KTKRTIGZSA-N 0.000 description 1
- NPTLAYTZMHJJDP-KTKRTIGZSA-N [3-[3-[3-[3-[3-[3-[3-[3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)CO NPTLAYTZMHJJDP-KTKRTIGZSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940031578 diisopropyl adipate Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229940100554 isononyl isononanoate Drugs 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 235000019265 sodium DL-malate Nutrition 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
【０００１】
【産業上の利用分野】
本発明は、非イオン界面活性剤であるポリオキシアルキレン誘導体を含有せず、ポリグリセリン脂肪酸エステルのみを用いた、水や温水と接した場合に瞬時にＯ／Ｗエマルションを形成する乳化性能が極めて良好で、且つ外観が透明で、低温域および高温域の両方において温度安定性が良好である透明化粧料組成物に関するものである。更に詳しくは、浴槽の湯に添加して入浴効果を高めるバスオイル等の入浴剤や、メークとの馴染みが特に良好でハードメークにも適したクレンジングオイル等の化粧品、シャンプー前の頭皮の洗浄料等のトイレタリー製品等に良好な性能を示す透明化粧料組成物に関するものである。
【０００２】
【従来の技術】
医薬品、化粧品、及び食料品の界面活性剤として有用であるポリグリセリン脂肪酸エステルは、脂肪酸とポリグリセリンとをエステル化することによって得られる。母核のポリグリセリンは一般的にはグリセリンの縮合による場合が多く、このように、ポリグリセリン脂肪酸エステルはグリセリンを出発物質としているため、皮膚刺激が少なく、安全性において殆ど問題のない界面活性剤である。このことから、最近はより安全性を高める目的で、皮膚刺激が懸念される従来の石油系ポリオキシアルキレン誘導体を使用せず、天然由来の安全性に優れたポリグリセリン脂肪酸エステルを用いた処方系が望まれるケースが増えてきている。
【０００３】
しかし、ポリグリセリン脂肪酸エステルは化粧品分野、特に油性成分を基剤とした系に少量の界面活性剤を配合し、水や温水と接した場合に瞬時にＯ／Ｗエマルションを形成することが求められる製品、例えばバスオイル等の入浴剤や、クレンジングオイル等に配合する界面活性剤として使用される場合が非常に少なく、一般にはポリオキシアルキレン誘導体、具体的にはポリオキシエチレン鎖を有する非イオン界面活性剤を使用する場合が殆どであった。その理由としては、バスオイルやクレンジングオイルに必要な機能、即ち、水と接した場合に瞬時にＯ／Ｗエマルションを形成する機能が不十分であったり、外観の透明性や経時的安定性が悪かったりする等の問題があった。本発明者は先に、上記課題を解決することを見出し提案している（特願２００２−０６３５２１）。しかし、このものは、水と接した場合に瞬時にＯ／Ｗエマルションを形成するが、乳化性能が不十分であり、改良の余地が残されていた。例えば、バスオイルとして、浴槽の湯に投入して利用した場合、瞬時に白く濁りＯ／Ｗエマルションを形成するが、経時的に湯上に油滴が発生する問題があった。また、クレンジングオイル等の化粧品やシャンプー前の頭皮の洗浄料等のトイレタリー製品等に利用した場合も配合している油性原料の全てが乳化仕切れずに、それらが皮膚や頭皮、毛髪に付着し残るため、油性感が発現し、官能上不快となる問題点があった。
【０００４】
【発明が解決しようとする課題】
そこで本発明者は、上記の事情に鑑み、非イオン界面活性剤であるポリオキシアルキレン誘導体を含有せず、ポリグリセリン脂肪酸エステルを用いた処方系において、バスオイル、クレンジングオイルに必要な機能、すなわち水と接した場合に瞬時にＯ／Ｗエマルションを形成する乳化性能が極めて良好で、且つ外観の透明性が良好で、低温域および高温域の両方の経時的温度安定性に優れた透明化粧料組成物を得ることを目的とした。
【０００５】
【問題を解決するための手段】
本発明者は、上記課題を達成するために鋭意研究した結果、特定のポリグリセリン脂肪酸エステル、２価以上の多価アルコール、水を含有する透明化粧料組成物が、上記課題を解決し得ることを見出し、本発明を完成するに至った。
【０００６】
即ち、本発明は次の成分（Ａ）〜（Ｃ）：
（Ａ）平均重合度が２〜１０のポリグリセリンと、炭素数１２〜２２の飽和脂肪酸及び不飽和脂肪酸より選ばれた１種又は２種以上の脂肪酸とをエステル化して得られる、ポリグリセリン脂肪酸エステル５．０〜２０．０重量％
（Ｂ）２価以上の多価アルコール１５．０〜４０．０重量％
（Ｃ）水０．０１〜５．０重量％
及び油分から成る、水や温水と接した場合に瞬時にＯ／Ｗエマルションを形成する乳化性能が極めて良好で且つ、外観の透明性が良好で、低温域および高温域の両方の経時的温度安定性が良好な透明化粧料組成物に関するものである。
【０００７】
前記、非イオン界面活性剤であるポリオキシアルキレン誘導体とは、一般にポリオキシエチレンが付加した界面活性剤を指す。例えば、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンオクチルドデシルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレン硬化ヒマシ油等のエーテル系のものや、ポリオキシエチレンモノステアレート、ポリオキシエチレンオレート、ポリオキシエチレンイソステアレート等のエステル系、ポリオキシエチレン・ポリオキシプロピレン共重合体等が挙げられる。本発明ではこのようなポリオキシアルキレン誘導体を使用せず透明化粧料組成物を得る。以下、本発明を詳細に説明する。
【０００８】
本発明で使用するポリグリセリン脂肪酸エステルとは平均重合度２〜１０のポリグリセリンと、炭素数１２〜２２の飽和又は不飽和の脂肪酸より選ばれた１種又は２種以上の脂肪酸とをエステル化して得られるポリグリセリン脂肪酸エステルである。ポリグリセリン脂肪酸エステルを構成する脂肪酸は、直鎖及び分岐の脂肪酸のいずれであっても良い。このようなポリグリセリン脂肪酸エステルとしては、モノイソステアリン酸ジグリセリル、ジイソステアリン酸ジグリセリル、テトライソステアリン酸ジグリセリル、モノイソステアリン酸テトラグリセリル、モノイソステアリン酸ヘキサグリセリル、セスキイソステアリン酸ヘキサグリセリル、モノイソステアリン酸デカグリセリル、ジイソステアリン酸デカグリセリル、モノラウリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノラウリン酸デカグリセリル、モノミリスチン酸デカグリセリル、モノオレイン酸ジグリセリル、モノオレイン酸テトラグリセリル、モノオレイン酸ヘキサグリセリル、モノオレイン酸デカグリセリル、モノステアリン酸デカグリセリル、ジステアリン酸デカグリセリル、ペンタステアリン酸デカグリセリル等が挙げられ、これらの１種又は２種以上を使用する。
【０００９】
本発明の透明化粧料組成物には、上記のポリグリセリン脂肪酸エステルを５．０〜２０．０重量％、好ましくは１０．０〜１５．０重量％使用する。５．０重量％未満では、透明化粧料組成物は得られず、また、２０．０重量％を超えて調製した透明化粧料組成物は、低温域及び高温域での安定性が悪くなる。
【００１０】
本発明で使用する２価以上の多価アルコールとしては、１，３−ブチレングリコール、プロピレングリコール、ポリエチレングリコール等の２価の多価アルコールやグリセリン、ジグリセリン、ポリグリセリン、グルコース、フラクトース、ソルビトール、マルチトール、マンニトール等の３価以上の多価アルコールが挙げられ、これらの１種又は２種以上を使用する。これらの内、グリセリンが特に好ましい。
【００１１】
本発明の透明化粧料組成物には、上記２価以上の多価アルコールを１５．０〜４０．０重量％、好ましくは２０．０〜３０．０重量％使用する。１５．０重量％未満では、水と接した場合に瞬時にＯ／Ｗエマルションを形成することが困難となり乳化性能が不十分となる。また、４０．０重量％を超えて調製した透明化粧料組成物は、低温域及び高温域での安定性が極めて悪くなる。
【００１２】
また本発明の透明化粧料組成物には、水を０．０１〜５．０重量％、好ましくは０．１〜３．０重量％使用する。０．１重量％未満で調製した透明化粧料組成物は、低温域及び高温域での安定性が極めて悪くなる。また、５．０重量％を超えて調製した場合も、低温域及び高温域での安定性が極めて悪くなる。
【００１３】
本発明で使用する無機塩類としては、塩化ナトリウム、塩化カリウム、硫酸ナトリウム、硫酸マグネシウム、炭酸ナトリウム、炭酸水素ナトリウム、リン酸ナトリウム等が挙げられる。また有機塩類としては、クエン酸ナトリウム、リンゴ酸ナトリウム、グルコン酸ナトリウム、乳酸ナトリウム、コハク酸ナトリウム、酒石酸ナトリウム等が挙げられ、これらの一種又は二種以上を使用する。
【００１４】
本発明の透明化粧料組成物に、無機塩類及び／又は有機塩類を０．００１〜２．０重量％、好ましくは０．０１〜１．０重量％を使用することにより、透明化粧料組成物と、水と接した場合に形成されるＯ／Ｗエマルション形成のスピードをより一層早くすることが可能となる。０．００１重量％未満で調製した透明化粧料組成物は、無機塩類及び／又は有機塩類を配合しないものとの差がない。また、２．０重量％を超えて調製した透明化粧料組成物は、低温域及び高温域での安定性が悪くなる。
【００１５】
本発明の透明化粧料組成物に配合する油分としては、特に限定はなく、例えば流動パラフィン、スクワラン等の炭化水素類、アジピン酸ジイソプロピル、ミリスチン酸オクチルドデシル、イソノナン酸イソノニル、ミリスチン酸イソプロピル、２−エチルヘキサン酸セチル等のエステル類、トリ２−エチルヘキサン酸グリセリル、トリ（カプリル・カプリン酸）グリセリル等のトリグリセライド類、オリブ油、ホホバ油、月見草油、ヤシ油等の植物油類、ジメチルポリシロキサン、メチルフェニルポリシロキサン、環状メチルポリシロキサン等のシリコーン類、オクチルドデカノール、オレイルアルコール等の高級アルコール等が挙げられ、これらの一種又は二種以上を使用する。
【００１６】
更に、本発明の透明化粧料組成物は、発明の効果を損なわない範囲で通常の化粧料に使用される成分、例えば、各種ビタミン、アミノ酸、生薬、消炎剤、細胞賦活剤、色素、防腐剤、香料等を適宜配合することができる。
【００１７】
本発明の透明化粧料組成物は、常法に従って製造することができ、例えば、ポリグリセリン脂肪酸エステルと多価アルコールとを混合溶解した界面活性剤相の撹拌下に、各油性成分を均一溶解した油相を徐々に添加し、その後無機塩類及び／又は有機塩類を溶解した水溶液を添加溶解していくことにより得ることができる。
【００１８】
【実施例】
以下に実施例を挙げて本発明を具体的に説明するが、本発明はこれらに限定されるものではない。
【００１９】
実施例１〜８、比較例１〜６
表１、２記載の組成物を調製し、以下の評価方法により評価した。その結果を表１、２に示す。
【００２０】
（評価方法）
１）透明性
実施例、比較例で調製した組成物の状態を目視にて観察し、以下の評価基準を基に評価した。
◎：極めて良好な透明性を呈する
○：良好な透明性を呈する
△：少し濁る
×：白濁を呈する
２）乳化性能▲１▼
実施例、比較例で調製した組成物１．０ｇを、水１リットルに添加したときのＯ／Ｗエマルション形成のしやすさ、及び水への分散性能を目視にて観察し、以下の評価基準を基に評価した。
（評価基準）
◎：添加後、直ちに白濁し、極めて容易に分散する
○：添加後、直ちに白濁し、容易に分散する
△：添加後、白濁もしくは分散に撹拌が必要
×：添加後、白濁しない（油滴となって表面に浮く）
３）乳化性能▲２▼
上記評価で作成した、Ｏ／Ｗエマルションの経時安定性（１２時間後及び２４時間後の水面での油滴の有無）を以下の評価基準を基に評価した。
（評価基準）
◎：２４時間以上放置後も油滴がない
○：１２時間を超え、２４時間以内に油滴が発生する
△：６時間を超え、１２時間以内に油滴が発生する
×：６時間以内に油滴が発生する
４）安定性
実施例、比較例で調製した組成物を０℃、５０℃の恒温槽に一ヵ月放置後の状態を目視にて観察し、以下の評価基準を基に評価した。
（評価基準）
○：状態変化なし
×：白濁、分離等の状態変化がある
【００２１】
【表１】
【表２】
実施例１〜８に示した透明化粧料組成物は、全評価項目について十分なものであった。一方、比較例１〜６に示したものについては、評価項目のいずれかの項目で不十分な評価結果であった。
【００２４】
【００２５】
【００２６】
【発明の効果】
本発明の透明化粧料組成物は、非イオン界面活性剤であるポリオキシアルキレン誘導体を含有せず、ポリグリセリン脂肪酸エステルをのみを用いた処方系のものであり、水と接した場合に瞬時にＯ／Ｗエマルションを形成する乳化性能が極めて良好で、且つ外観の透明性が良好で、低温域および高温域の両方において温度安定性が良好なものである。本発明の透明化粧料組成物は、バスオイル（入浴剤）、クレンジングオイル、シャンプー前の頭皮の洗浄料等に利用できるものである。[0001]
[Industrial application fields]
The present invention does not contain a polyoxyalkylene derivative that is a nonionic surfactant, and uses only a polyglycerin fatty acid ester, and has an extremely high emulsifying performance that instantly forms an O / W emulsion when in contact with water or warm water. The present invention relates to a transparent cosmetic composition having good appearance and transparent appearance, and having good temperature stability in both a low temperature range and a high temperature range. More specifically, bath oils such as bath oils that are added to the bath water to enhance the bathing effect, cosmetics such as cleansing oils that are particularly familiar with make-up and suitable for hard make-up, and scalp cleansing agents before shampooing It is related with the transparent cosmetics composition which shows favorable performance, such as toiletry products.
[0002]
[Prior art]
Polyglycerin fatty acid esters that are useful as surfactants for pharmaceuticals, cosmetics, and foods are obtained by esterifying fatty acids and polyglycerin. In general, polyglycerin in the mother nucleus is often obtained by condensation of glycerin. Thus, since the polyglycerin fatty acid ester uses glycerin as a starting material, there is little skin irritation and there is almost no problem in safety. It is. Because of this, for the purpose of improving safety more recently, the prescription system using polyglycerol fatty acid ester with excellent natural safety without using conventional petroleum-based polyoxyalkylene derivatives that are concerned about skin irritation Increasing cases are desired.
[0003]
However, polyglycerin fatty acid esters are required to form an O / W emulsion instantly when in contact with water or warm water by blending a small amount of a surfactant into the cosmetics field, particularly a system based on an oil component. Very rarely used as a surfactant in products such as bath oils such as bath oils, cleansing oils, etc., and generally polyoxyalkylene derivatives, specifically nonionic interfaces having polyoxyethylene chains In most cases, an activator was used. The reason is that the functions necessary for bath oil and cleansing oil, that is, the function of forming an O / W emulsion instantaneously when in contact with water, are insufficient, or the transparency of the appearance and the stability over time are insufficient. There were problems such as being bad. The inventor has previously found and proposed to solve the above problems (Japanese Patent Application No. 2002-063521). However, this instantly forms an O / W emulsion when in contact with water, but the emulsifying performance is insufficient, leaving room for improvement. For example, when bath oil is used by being poured into hot water in a bathtub, it becomes cloudy instantly and forms an O / W emulsion, but there is a problem that oil droplets are generated on the hot water over time. Also, when used in cosmetics such as cleansing oil and toiletry products such as scalp before shampooing, all of the oily ingredients that are blended are not emulsified and remain attached to the skin, scalp and hair. For this reason, there is a problem that an oily feeling is expressed and sensory discomfort occurs.
[0004]
[Problems to be solved by the invention]
Therefore, in view of the above circumstances, the present inventor does not contain a polyoxyalkylene derivative that is a nonionic surfactant, and in a prescription system using a polyglycerin fatty acid ester, functions necessary for bath oil and cleansing oil, that is, Transparent cosmetics with extremely good emulsifying performance that instantly forms an O / W emulsion when in contact with water, excellent appearance transparency, and excellent temperature stability over time in both low and high temperature ranges The object was to obtain a composition.
[0005]
[Means for solving problems]
As a result of intensive research to achieve the above-mentioned problems, the present inventors have found that a transparent cosmetic composition containing a specific polyglycerin fatty acid ester, a dihydric or higher polyhydric alcohol, and water can solve the above problems. As a result, the present invention has been completed.
[0006]
That is, the present invention includes the following components (A) to (C):
(A) Polyglycerol fatty acid obtained by esterifying polyglycerol having an average degree of polymerization of 2 to 10 and one or more fatty acids selected from saturated fatty acids having 12 to 22 carbon atoms and unsaturated fatty acids Esters 5.0-20.0% by weight
(B) Dihydric or higher polyhydric alcohol 15.0 to 40.0% by weight
(C) Water 0.01-5.0% by weight
And oil, it forms an O / W emulsion instantly when it comes into contact with water or warm water. It has very good emulsifying performance, has a good appearance transparency, and is stable over time in both low and high temperatures. The present invention relates to a transparent cosmetic composition having good properties.
[0007]
The polyoxyalkylene derivative which is a nonionic surfactant generally refers to a surfactant added with polyoxyethylene. For example, ethers such as polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene octyldodecyl ether, polyoxyethylene oleyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene monostearate, polyoxyethylene Examples include esters such as ethylene oleate and polyoxyethylene isostearate, and polyoxyethylene / polyoxypropylene copolymers. In the present invention, a transparent cosmetic composition is obtained without using such a polyoxyalkylene derivative. Hereinafter, the present invention will be described in detail.
[0008]
The polyglycerin fatty acid ester used in the present invention is an esterification of polyglycerin having an average degree of polymerization of 2 to 10 and one or more fatty acids selected from saturated or unsaturated fatty acids having 12 to 22 carbon atoms. It is a polyglycerol fatty acid ester obtained. The fatty acid constituting the polyglycerin fatty acid ester may be either a linear or branched fatty acid. Examples of such polyglycerol fatty acid esters include diglyceryl monoisostearate, diglyceryl diisostearate, diglyceryl tetraisostearate, tetraglyceryl monoisostearate, hexaglyceryl monoisostearate, hexaglyceryl sesquiisostearate, decaglyceryl monoisostearate , Deisoglyceryl diisostearate, tetraglyceryl monolaurate, hexaglyceryl monolaurate, decaglyceryl monolaurate, decaglyceryl monomyristate, diglyceryl monooleate, tetraglyceryl monooleate, hexaglyceryl monooleate, decaglyceryl monooleate , Decaglyceryl monostearate, decaglyceryl distearate, pentastearic acid de Glyceryl and the like, to use one or more of these.
[0009]
In the transparent cosmetic composition of the present invention, the above-mentioned polyglycerin fatty acid ester is used in an amount of 5.0 to 20.0% by weight, preferably 10.0 to 15.0% by weight. If it is less than 5.0% by weight, a transparent cosmetic composition cannot be obtained, and a transparent cosmetic composition prepared in excess of 20.0% by weight has poor stability at low and high temperatures.
[0010]
Examples of the dihydric or higher polyhydric alcohol used in the present invention include divalent polyhydric alcohols such as 1,3-butylene glycol, propylene glycol, and polyethylene glycol, glycerin, diglycerin, polyglycerin, glucose, fructose, sorbitol, Examples include trihydric or higher polyhydric alcohols such as maltitol and mannitol, and one or more of these are used. Of these, glycerin is particularly preferred.
[0011]
In the transparent cosmetic composition of the present invention, the dihydric or higher polyhydric alcohol is used in an amount of 15.0 to 40.0% by weight, preferably 20.0 to 30.0% by weight. If it is less than 15.0% by weight, it is difficult to instantaneously form an O / W emulsion when in contact with water, and the emulsification performance becomes insufficient. Moreover, the transparent cosmetic composition prepared in excess of 40.0% by weight has extremely poor stability in the low temperature range and the high temperature range.
[0012]
In the transparent cosmetic composition of the present invention, water is used in an amount of 0.01 to 5.0% by weight, preferably 0.1 to 3.0% by weight. The transparent cosmetic composition prepared at less than 0.1% by weight has extremely poor stability at low and high temperatures. In addition, even when the content exceeds 5.0% by weight, the stability in the low temperature range and the high temperature range is extremely deteriorated.
[0013]
Examples of the inorganic salts used in the present invention include sodium chloride, potassium chloride, sodium sulfate, magnesium sulfate, sodium carbonate, sodium hydrogen carbonate, sodium phosphate and the like. Examples of organic salts include sodium citrate, sodium malate, sodium gluconate, sodium lactate, sodium succinate, sodium tartrate and the like, and one or more of these are used.
[0014]
By using 0.001 to 2.0% by weight, preferably 0.01 to 1.0% by weight, of an inorganic salt and / or an organic salt in the transparent cosmetic composition of the present invention, the transparent cosmetic composition And the speed of O / W emulsion formation formed when it contacts with water can be made still faster. The transparent cosmetic composition prepared at less than 0.001% by weight is not different from one not containing inorganic salts and / or organic salts. Moreover, the transparent cosmetic composition prepared in excess of 2.0% by weight has poor stability at low temperatures and high temperatures.
[0015]
The oil to be blended in the transparent cosmetic composition of the present invention is not particularly limited. For example, hydrocarbons such as liquid paraffin and squalane, diisopropyl adipate, octyldodecyl myristate, isononyl isononanoate, isopropyl myristate, 2- Esters such as cetyl ethylhexanoate, glyceryl tri-2-ethylhexanoate, triglycerides such as glyceryl tri (capryl / capric acid), vegetable oils such as olive oil, jojoba oil, evening primrose oil, coconut oil, dimethylpolysiloxane, Examples include silicones such as methylphenylpolysiloxane and cyclic methylpolysiloxane, higher alcohols such as octyldodecanol and oleyl alcohol, and one or more of these are used.
[0016]
Furthermore, the transparent cosmetic composition of the present invention is a component used in ordinary cosmetics within a range not impairing the effects of the invention, such as various vitamins, amino acids, herbal medicines, anti-inflammatory agents, cell activators, pigments, preservatives. A fragrance or the like can be appropriately blended.
[0017]
The transparent cosmetic composition of the present invention can be produced according to a conventional method. For example, each oil component is uniformly dissolved under stirring of a surfactant phase in which polyglycerin fatty acid ester and polyhydric alcohol are mixed and dissolved. It can be obtained by gradually adding an oil phase and then adding and dissolving an aqueous solution in which inorganic salts and / or organic salts are dissolved.
[0018]
【Example】
EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples.
[0019]
Examples 1-8, Comparative Examples 1-6
The compositions described in Tables 1 and 2 were prepared and evaluated by the following evaluation methods. The results are shown in Tables 1 and 2.
[0020]
(Evaluation methods)
1) Transparency The states of the compositions prepared in Examples and Comparative Examples were visually observed and evaluated based on the following evaluation criteria.
A: Exhibits extremely good transparency O: Exhibits good transparency Δ: Slightly turbid ×: Exhibits white turbidity 2) Emulsification performance (1)
The following evaluation criteria were observed by visually observing the ease of forming an O / W emulsion and the ability to disperse in water when 1.0 g of the composition prepared in Examples and Comparative Examples was added to 1 liter of water. Based on the evaluation.
(Evaluation criteria)
◎: Immediately after addition, it becomes very cloudy and disperses very easily ○: Immediately after addition, it becomes cloudy immediately and disperses easily Δ: After addition, it becomes cloudy or requires stirring to disperse x: After addition, it does not become cloudy (with oil droplets) Float on the surface)
3) Emulsification performance (2)
The stability over time of the O / W emulsion prepared in the above evaluation (presence of oil droplets on the water surface after 12 hours and 24 hours) was evaluated based on the following evaluation criteria.
(Evaluation criteria)
◎: No oil droplets after standing for 24 hours or more ○: Over 12 hours, oil droplets are generated within 24 hours Δ: Over 6 hours, oil droplets are generated within 12 hours ×: Within 6 hours 4) Stability of oil droplets 4) Stability The composition prepared in Examples and Comparative Examples was visually observed for one month in a thermostatic bath at 0 ° C. and 50 ° C., and evaluated based on the following evaluation criteria. did.
(Evaluation criteria)
○: No change in state ×: Change in state such as cloudiness, separation, etc. [0021]
[Table 1]
[Table 2]
The transparent cosmetic compositions shown in Examples 1 to 8 were sufficient for all evaluation items. On the other hand, about what was shown to Comparative Examples 1-6, it was an inadequate evaluation result in any item of an evaluation item.
[0024]
[0025]
[0026]
【The invention's effect】
The transparent cosmetic composition of the present invention does not contain a polyoxyalkylene derivative that is a nonionic surfactant, is a prescription system using only a polyglycerin fatty acid ester, and instantly when in contact with water The emulsification performance for forming the O / W emulsion is very good, the appearance is transparent, and the temperature stability is good in both the low temperature range and the high temperature range. The transparent cosmetic composition of the present invention can be used for bath oil (bathing agent), cleansing oil, scalp before washing and the like.
Claims (1)
（Ａ）平均重合度が２〜１０のポリグリセリンと、炭素数１２〜２２の飽和脂肪酸及び不飽和脂肪酸とをエステル化して得られる、ポリグリセリン脂肪酸エステル１０．０〜１５．０重量％
（Ｂ）２価以上の多価アルコール２０．０〜３０．０重量％
（Ｃ）水０．１〜３．０重量％
及び油分から成り、
無機塩類及び／又は有機塩類０．００１〜２．０重量％を含有する
水や温水と接した場合にＯ／Ｗエマルションを形成するバスオイル（入浴剤）。The following components (A) to (C):
(A) 10.0-15.0% by weight of a polyglycerol fatty acid ester obtained by esterifying a polyglycerol having an average degree of polymerization of 2 to 10, a saturated fatty acid having 12 to 22 carbon atoms, and an unsaturated fatty acid.
(B) 20.0 to 30.0% by weight of a dihydric or higher polyhydric alcohol
(C) Water 0.1 to 3.0% by weight
And Ri consists of oil,
A bath oil (bath agent) that forms an O / W emulsion when in contact with water or warm water containing 0.001 to 2.0% by weight of inorganic salts and / or organic salts .
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| JP2002137634A JP3653061B2 (en) | 2002-05-13 | 2002-05-13 | Transparent cosmetic composition |
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| JP2002137634A JP3653061B2 (en) | 2002-05-13 | 2002-05-13 | Transparent cosmetic composition |
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| JP3653061B2 true JP3653061B2 (en) | 2005-05-25 |
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Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5382974B2 (en) * | 2005-03-11 | 2014-01-08 | 太陽化学株式会社 | Cosmetic composition and cosmetics |
| JP5410650B2 (en) * | 2005-06-13 | 2014-02-05 | 太陽化学株式会社 | Cosmetic composition and cosmetics |
| JP4809052B2 (en) * | 2005-12-22 | 2011-11-02 | 阪本薬品工業株式会社 | Cleansing cosmetics |
| WO2009078245A1 (en) * | 2007-12-19 | 2009-06-25 | Foodtech Trading Co., Ltd. | Transparent emulsified composition and cosmetic and food containing the same |
| JP5468314B2 (en) * | 2009-06-08 | 2014-04-09 | クラシエホームプロダクツ株式会社 | Skin cleanser composition |
| WO2012167905A2 (en) * | 2011-06-07 | 2012-12-13 | Beiersdorf Ag | Polyethylene glycol-free cosmetic or dermatological preparations |
| DE102011077028A1 (en) * | 2011-06-07 | 2012-12-13 | Beiersdorf Ag | Cosmetic or dermatological preparations with improved rheological properties |
| JP6291031B2 (en) | 2013-04-05 | 2018-03-14 | ザ プロクター アンド ギャンブル カンパニー | Personal care composition containing pre-emulsified formulation |
| US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
| US9993404B2 (en) | 2015-01-15 | 2018-06-12 | The Procter & Gamble Company | Translucent hair conditioning composition |
| JP6970094B2 (en) | 2016-01-20 | 2021-11-24 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | Hair conditioning composition containing monoalkyl glyceryl ether |
| JP6694726B2 (en) * | 2016-02-15 | 2020-05-20 | 日清オイリオグループ株式会社 | O / D type emulsion composition, oil-in-water type emulsion composition, food and drink and food material |
| JP7051383B2 (en) * | 2017-11-17 | 2022-04-11 | 花王株式会社 | Double layer cosmetics |
| FR3084259B1 (en) * | 2018-06-25 | 2021-01-22 | Oreal | COMPOSITION CONSISTING OF A FATTY ACID AND POLYGLYCEROL MONOESTER, AN OIL AND A POLYOL, PROCESS AND USE |
| JP2021046373A (en) * | 2019-09-19 | 2021-03-25 | 阪本薬品工業株式会社 | Cleansing cosmetic |
| JP7634857B2 (en) * | 2020-07-14 | 2025-02-25 | 阪本薬品工業株式会社 | Water-based cleansing cosmetics |
| JP7678678B2 (en) * | 2021-02-12 | 2025-05-16 | 花王株式会社 | Self-emulsifying bath composition |
| US12329847B2 (en) | 2022-06-13 | 2025-06-17 | Taiyo Kagaku Co., Ltd. | Cosmetic composition |
| JP2024044620A (en) * | 2022-09-21 | 2024-04-02 | 株式会社マンダム | oil-based cosmetics |
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