JP3390461B2 - Hair rinse for acid hair coloring - Google Patents
Hair rinse for acid hair coloringInfo
- Publication number
- JP3390461B2 JP3390461B2 JP03703492A JP3703492A JP3390461B2 JP 3390461 B2 JP3390461 B2 JP 3390461B2 JP 03703492 A JP03703492 A JP 03703492A JP 3703492 A JP3703492 A JP 3703492A JP 3390461 B2 JP3390461 B2 JP 3390461B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- carbon atoms
- group
- rinse
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Description
【発明の詳細な説明】
【０００１】
【産業上の利用分野】本発明は、酸性染毛料を使用した
後の毛髪に対して有効に使用され、酸性染毛料の色もち
を良くしかつ毛髪をしっとりする効果に優れたヘアーリ
ンスに関する。
【０００２】
【従来の技術及び発明が解決しようとする課題】毛髪が
老化等の為に白髪化したり、パーマ等の化学処理によ
り、生来の毛髪色が変化する場合がある。このようにな
った人たちが毛髪の色を元の外観に戻す処理をしたいと
望んだ時、染毛剤を使用するのが最も効果的な方法であ
る。この染毛方法の１つに、酸性染料を使用する方法が
ある。この方法は、酸化染料を使用する方法よりも安全
性が高く、毛髪損傷の懸念はないが、染毛力が弱い為に
数回の洗髪で落ちてしまう。その為、安全性が高く、な
おかつ染毛力の強い染毛剤を得る為に、酸性染料の色も
ちを良くすることが望まれてきた。この事を達成する手
段として、特開昭５９−４２３１０号公報が提案されて
いるが、これは染毛料の固着性を改善する為に、染毛剤
を毛髪に塗布・乾燥した後さらに毛髪組成物を塗布・乾
燥させる方法である。しかし、この方法では染毛に手間
がかかり、また、毛髪がごわついてしまう。また、その
他に、特開昭６０−１５８１０５号公報と特開昭６１−
６３６１１号公報が提案されているが、これはパーマ等
の化学的処理をした後に毛髪を中和する為のものであ
り、酸性染毛料の色持ちを良くすることは期待できず、
またリンスとしての官能的効果はなく、リンス後の仕上
がりに不満が残る。
【０００３】そこで、本発明者等は、上記従来技術の難
点を改良せんとして鋭意研究を重ねその結果、第４級ア
ンモニウム塩、高級アルコール、酸及び油性成分を特定
のｐＨ領域のもとに、特定の割合で配合したものを、ヘ
アーリンス剤として洗髪後に使用すると、酸性染料の色
もちが良くなり、かつしっとり感を得られることを見出
し、本発明を完成するに至った。本発明の目的は、酸性
染毛料の色もちを良くし、かつしっとり感のあるヘアー
リンスを提供することにある。
【０００４】
【課題を解決するための手段】上記の目的を達成する本
発明は、次の四成分（Ａ），（Ｂ），（Ｃ）および
（Ｄ）を含有し、ｐＨ１．５〜４であることを特徴とす
る、酸性染毛料処理毛髪に対する洗い流し用ヘアーリン
スである。
（Ａ）下記の一般式（１）
【化３】
［式中、Ｒ１〜Ｒ４のうちのいずれか一つ又は二つは炭
素数１０〜２４のアルキル基、炭素数１０〜２４のヒド
ロキシアルキル基、又は一般式Ｒ（ＣＨ2ＣＨ2Ｏ）n
（但し、Ｒは炭素数１０〜２４のアルキル基、又は炭素
数１０〜２４のヒドロキシアルキル基、ｎは１〜１０の
整数である。）で表される基であり、残りは炭素数１〜
３のアルキル基、一般式Ｈ（ＣＨ2ＣＨ2Ｏ）ｎ又は、Ｈ
（ＣＨ（ＣＨ3）ＣＨ2Ｏ）ｎ（但し、ｎは１〜５の整
数）で表される基、ベンジル基、又はシンナミル基であ
り、Ｘはハロゲン原子又は炭素数１若しくは２のアルキ
ル硫酸基である。］
で表される第４級アンモニウム塩の一種又は二種以上を
０．５〜１０重量％。
（Ｂ）炭素数１２〜２６の直鎖もしくは分岐鎖のアルキ
ル基又はアルケニル基を有する高級アルコールの一種又
は二種以上を０．５〜１０重量％。
（Ｃ）酢酸、酒石酸、ホウ酸、コハク酸、クエン酸、サ
リチル酸、リン酸、塩酸のうちの一種又は二種以上。
（Ｄ）下記の一般式（２）
【化４】［式中、Ｒ１〜Ｒ３は炭素数３〜２１のアルキル基、炭
素数３〜３５のヒドロキシアルキル基、炭素数３〜２１
のアルケニル基又は炭素数３〜３５のヒドロキシアルケ
ニルである。］
で表される油性成分の一種又は二種以上を０．１〜５重
量％。
【０００５】本発明の第１の必須成分である第４級アン
モニウム塩の具体例としては、塩化アルキルトリメチル
アンモニウム、塩化ステアリルトリメチルアンモニウ
ム、臭化ジステアリルジメチルアンモニウム、塩化セト
ステアリルトリメチルアンモニウム、塩化ジステアリル
ジメチルアンモニウム、塩化ステアリルジメチルベンジ
ルアンモニウム、臭化ベヘニルトリメチルアンモニウム
等を挙げることが出来、これらの一種又は二種以上を用
いることが出来る。第４級アンモニウム塩の配合量は、
酸性染毛料用ヘアーリンス全体に対して、０．５〜１０
重量％である。０．５重量％未満であると、本発明の効
果が発揮されず、１０重量％を超えると毛髪にベタつき
が生じ、重い仕上がり感となる。
【０００６】本発明の第２の必須成分である高級アルコ
ールの具体例としては、ラウリルアルコール、セチルア
ルコール、ステアリルアルコール、アラキルアルコー
ル、ベヘニルアルコール、セリルアルコール、ヘキサデ
シルアルコール、イソステアリルアルコール、オクチル
ドデカノール等を挙げることが出来、これらの一種又は
二種以上を用いることが出来る。高級アルコールの配合
量は、酸性染毛料用ヘアーリンス全体に対し、０．５〜
１０重量％である。０．５重量％未満であると、本発明
の効果が発揮されず、１０重量％を越えると毛髪にベタ
つきが生じ、重い仕上がり感となる。
【０００７】本発明の第３の必須成分である酸として
は、酢酸、酒石酸、ホウ酸、コハク酸クエン酸、サリチ
ル酸、リン酸、塩酸等を挙げることが出来、これらの一
種又は二種以上を用いることが出来る。酸は、酸性染毛
料用ヘアーリンスのｐＨが１．５〜４に調整されるよう
に配合される。ｐＨが１．５未満であると、毛髪をしっ
とりする効果が発揮されず、ｐＨが４を越えると、酸性
染毛料の色持ちを良くする効果が発揮されない。本発明
の第４の必須成分である油性成分としては、オリーブ
油、ヤシ油、なたね油、パーム油、ヒマシ油、硬化ヒマ
シ油、落花生油、牛脂、トリパルミチン酸グリセリド、
トリミリスチン酸グリセリド等を挙げることが出来、こ
れらの一種又は二種以上を用いることが出来る。油性成
分の配合量は、酸性染毛料用ヘアーリンス全体に対し、
０．１〜５重量％である。０．１重量％未満であると、
本発明の効果が発揮されず、５重量％を超えると毛髪に
ベタつきが生じ重い仕上がり感となる。また、本発明の
ヘアーリンスは系の安定性や前記の必須成分の他に、流
動パラフィン等の油性物質、多価アルコール等の保湿
剤、香料、防腐剤、酸化防止剤、紫外線吸収剤、色素な
どの慣用任意成分を配合することもできる。
【０００８】
【実施例】次に、本発明を実施例をもって詳細に説明す
るが、本発明はこれにより限定されるものではない。
尚、実施例および比較例中の数値は重量％である。ここ
で、実施例の説明に先立ち、各例において採用した評価
方法について説明する。
（１）脱色防止効果試験
（イ）サンプル試験毛
毛束（白色毛髪の束）２ｇを酸性染毛料５ｇで染毛し、
２０分間放置した後、水洗いし、風乾した。これを洗髪
試験前の毛髪とした。
（ロ）試験法
３０℃に保った試料ヘアーリンス１０％水溶液の中に、
上記試料毛を浸漬し、１０回の手もみを行った後、水洗
いし、風乾する。これを１回として、５回繰り返した
後、下記の式より洗髪試験後の退色率を求めた。
退色率（％）＝（１−Ａ／Ｂ）×１００
Ａ：洗髪試験後の毛髪と白髪の色差
Ｂ：洗髪試験前の毛髪と白髪の色差
この数値が小さい程、脱色防止効果が大きく、染毛料の
色もちが良いことを示す。退色率２０％までを「○」、
２１〜４９％を「△」、５０％以上を「×」として表し
た。尚、色差は、高速色差計（村上色材社製ＣＭＳ−１
０００型）を用いて測色したＸ，Ｙ，Ｚ値をＨｕｎｔｅ
ｒのＬ，ａ，ｂ表色系へ変換し、下記の式により求め
た。 色差（△Ｅ）＝｛（△Ｌ） 2 ＋（△ａ） 2 ＋（△ｂ） 2 ｝ 1/2 △Ｌ：Ｌ値の差 △ａ：ａ値の差 △ｂ：ｂ値の差
【０００９】（２）ヘアーリンス後の仕上がり（しなや
かさ、櫛通り、しっとり感）効果
各例におけるヘアーリンス後の仕上がりについて「しな
やかさ」、「櫛通り」「しっとり感」を２０名のパネラ
−により官能的に比較し、下記基準で評価を行った。
◎；良いと答えた人が１８人以上の場合
○；良いと答えた人が１４〜１７人の場合
△；良いと答えた人が８〜１３人の場合
×；良いと答えた人が７人以下の場合
【００１０】実施例１〜４、比較例１〜５
表１に示す配合組成のヘアーリンスを通常の方法で調製
し、前記諸試験を行い表２にその結果を示した。
【００１１】
【表１】
【００１２】
【表２】【００１３】
【発明の効果】以上記載のごとく、本発明のヘアーリン
スは、酸性染毛料の色もちを良くし、かつ仕上がり効果
の優れたものであり、その効果は著しく、商品価値は極
めて高い。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is effectively used for hair after the use of an acid hair dye, thereby improving the color of the acid hair dye and improving the hair. It relates to a hair rinse excellent in moisturizing effect. 2. Description of the Related Art In some cases, hair becomes gray due to aging or the like, or the natural hair color changes due to chemical treatment such as perm. When these people want to restore the hair color to its original appearance, it is most effective to use a hair dye. One of the hair dyeing methods is a method using an acid dye. This method is safer than the method using an oxidation dye, and there is no concern about damage to the hair. Therefore, in order to obtain a hair dye having high safety and strong hair dyeing power, it has been desired to improve the color of the acid dye. As means for achieving this, Japanese Patent Application Laid-Open No. 59-42310 has been proposed. In order to improve the fixability of the hair dye, a hair dye is applied to the hair and dried, and then the hair composition is further improved. This is a method of applying and drying an object. However, this method requires a lot of time for dyeing the hair, and the hair becomes stiff. In addition, JP-A-60-158105 and JP-A-61-105105
No. 63611 has been proposed, but this is for neutralizing hair after a chemical treatment such as perm, and it cannot be expected to improve the color durability of an acidic hair dye.
In addition, there is no sensual effect as a rinse, and dissatisfaction remains in the finish after rinsing. Accordingly, the present inventors have conducted intensive studies in an attempt to improve the above-mentioned disadvantages of the prior art, and as a result, have found that quaternary ammonium salts, higher alcohols, acids and oily components can be obtained under a specific pH range. It has been found that the use of a compound formulated at a specific ratio after hair washing as a hair rinsing agent improves the color of the acid dye and gives a moist feeling, thereby completing the present invention. An object of the present invention is to provide a hair rinse which improves the color of an acidic hair dye and has a moist feeling. The present invention for achieving the above object contains the following four components (A), (B), (C) and (D), and has a pH of 1.5 to 4. A hair rinse for rinsing hair treated with an acidic hair dye, characterized in that: (A) The following general formula (1) [In the formula, any one or two of R1 to R4 are an alkyl group having 10 to 24 carbon atoms, a hydroxyalkyl group having 10 to 24 carbon atoms, or a general formula R (CH 2 CH 2 O) n
Wherein R is an alkyl group having 10 to 24 carbon atoms or a hydroxyalkyl group having 10 to 24 carbon atoms, and n is an integer of 1 to 10.
An alkyl group of the general formula H (CH 2 CH 2 O) n or H
(CH (CH 3 ) CH 2 O) n (where n is an integer of 1 to 5), a benzyl group or a cinnamyl group, and X is a halogen atom or an alkyl sulfate having 1 or 2 carbon atoms. Group. 0.5 to 10% by weight of one or more of the quaternary ammonium salts represented by the formula: (B) 0.5 to 10% by weight of one or more of higher alcohols having a linear or branched alkyl or alkenyl group having 12 to 26 carbon atoms. (C) One or more of acetic acid, tartaric acid, boric acid, succinic acid, citric acid, salicylic acid, phosphoric acid, and hydrochloric acid. (D) The following general formula (2) [Wherein, R1 to R3 are an alkyl group having 3 to 21 carbon atoms, a hydroxyalkyl group having 3 to 35 carbon atoms, and a C3 to C21
Or an alkenyl group having 3 to 35 carbon atoms. 0.1 to 5% by weight of one or more of the oily components represented by [0005] Specific examples of the quaternary ammonium salt which is the first essential component of the present invention include alkyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium bromide, cetostearyltrimethylammonium chloride, distearyl chloride. Examples thereof include dimethylammonium, stearyldimethylbenzylammonium chloride, and behenyltrimethylammonium bromide, and one or more of these can be used. The amount of the quaternary ammonium salt is
0.5 to 10 with respect to the entire hair rinse for acidic hair dye
% By weight. If the amount is less than 0.5% by weight, the effect of the present invention is not exerted. If the amount exceeds 10% by weight, the hair becomes sticky, giving a heavy finished feeling. Specific examples of the higher alcohol which is the second essential component of the present invention include lauryl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, seryl alcohol, hexadecyl alcohol, isostearyl alcohol, octyldodecanol. And the like, and one or more of these can be used. The amount of the higher alcohol is 0.5 to 0.5% based on the entire hair rinse for acidic hair dye.
10% by weight. If the amount is less than 0.5% by weight, the effect of the present invention is not exhibited. If the amount is more than 10% by weight, the hair becomes sticky, giving a heavy finished feeling. [0007] Examples of the acid which is the third essential component of the present invention include acetic acid, tartaric acid, boric acid, citric acid succinate, salicylic acid, phosphoric acid, hydrochloric acid, and the like. Can be used. The acid is blended so that the pH of the acid rinse hair rinse is adjusted to 1.5 to 4. If the pH is less than 1.5, the effect of moisturizing the hair is not exhibited, and if the pH exceeds 4, the effect of improving the color durability of the acidic hair dye is not exhibited. The oil component the a fourth essential component of the present invention, olive oil, coconut oil, rapeseed oil, palm oil, castor oil, hardened castor oil, peanut oil, beef tallow, preparative Riparumichin acid glycerides,
Can be mentioned trimyristate glycerin de like, can be used alone or in combination. The amount of the oily component is based on the entire hair rinse for acidic hair dyes.
0.1 to 5% by weight. If it is less than 0.1% by weight,
If the effect of the present invention is not exhibited, and if it exceeds 5% by weight, the hair becomes sticky, giving a heavy finish feeling. In addition, the hair rinse of the present invention is, in addition to the stability of the system and the essential components, an oily substance such as liquid paraffin, a humectant such as a polyhydric alcohol, a fragrance, a preservative, an antioxidant, an ultraviolet absorber, and a dye. Conventional optional components such as the above can also be blended. [0008] Next, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.
The numerical values in Examples and Comparative Examples are% by weight. Here, prior to the description of the embodiments, the evaluation method adopted in each example will be described. (1) bleaching prevention effect test (a) sample testing hair tresses (bundle of white hair) 2 g was dyed with an acidic hair dye 5g,
After standing for 20 minutes, it was washed with water and air-dried. Wash this
The hair before the test was used. (B) Test method In a 10% aqueous solution of sample hair rinse kept at 30 ° C,
The sample hair is immersed, hand-fed 10 times, washed with water and air-dried. This was repeated once and repeated five times. Then, the fading rate after the hair washing test was determined by the following formula. Fading rate (%) = (1-A / B) × 100 A: Color difference between hair and gray hair after hair washing test B: Color difference between hair and gray hair before hair washing test Indicates that the hair color is good. "O" for up to 20% fading,
21 to 49% are represented by “△”, and 50% or more are represented by “x”. The color difference was measured using a high-speed color difference meter (CMS-1 manufactured by Murakami Color Materials Co., Ltd.).
Hunte the X, Y, and Z values measured using
r is converted to the L, a, b color system and calculated by the following equation.
Was. Color difference (△ E) = ｛(△ L) 2 + (△ a) 2 + (△ b) 2 ｝ 1/2 ΔL: Difference of L value Δa: Difference of a value Δb: Difference of b value [ (2) Effect of finish after hair rinsing (flexibility, combing, moist feeling) Regarding the finish after hair rinsing in each example, "Smoothness", "comb passing" and "moist feeling" are evaluated by 20 panelists. They were compared organoleptically and evaluated according to the following criteria. ◎; 18 or more answered good ○; 14 to 17 answered good △; 8 to 13 answered good ×; 7 answered good Examples 1 to 4 and Comparative Examples 1 to 5 Hair rinses having the composition shown in Table 1 were prepared by a conventional method, subjected to the above-mentioned tests, and the results are shown in Table 2. [Table 1] [Table 2] As described above, the hair rinse of the present invention improves the color of an acidic hair dye and has an excellent finishing effect. The effect is remarkable and the commercial value is extremely high. .
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7，ＤＢ名) A61K 7/08 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int.Cl. 7 , DB name) A61K 7/08
Claims (1)
び（Ｄ）を含有し、ｐＨ１．５〜４であることを特徴と
する、酸性染毛料処理毛髪に対する洗い流し用ヘアーリ
ンス。 （Ａ）下記の一般式（１） 【化１】 ［式中、Ｒ１〜Ｒ４のうちのいずれか一つ又は二つは炭
素数１０〜２４のアルキル基、炭素数１０〜２４のヒド
ロキシアルキル基、又は一般式Ｒ（ＣＨ2ＣＨ2Ｏ）n
（但し、Ｒは炭素数１０〜２４のアルキル基、又は炭素
数１０〜２４のヒドロキシアルキル基、ｎは１〜１０の
整数である。）で表される基であり、残りは炭素数１〜
３のアルキル基、一般式Ｈ（ＣＨ2ＣＨ2Ｏ）ｎ又は、Ｈ
（ＣＨ（ＣＨ3）ＣＨ2Ｏ）ｎ（但し、ｎは１〜５の整
数）で表される基、ベンジル基、又はシンナミル基であ
り、Ｘはハロゲン原子又は炭素数１若しくは２のアルキ
ル硫酸基である。］ で表される第４級アンモニウム塩の一種又は二種以上を
０．５〜１０重量％。 （Ｂ）炭素数１２〜２６の直鎖もしくは分岐鎖のアルキ
ル基又はアルケニル基を有する高級アルコールの一種又
は二種以上を０．５〜１０重量％。 （Ｃ）酢酸、酒石酸、ホウ酸、コハク酸、クエン酸、サ
リチル酸、リン酸、塩酸のうちの一種又は二種以上。 （Ｄ）下記の一般式（２） 【化２】 ［式中、Ｒ１〜Ｒ３は炭素数３〜２１のアルキル基、炭
素数３〜３５のヒドロキシアルキル基、炭素数３〜２１
のアルケニル基又は炭素数３〜３５のヒドロキシアルケ
ニルである。］ で表される油性成分の一種又は二種以上を０．１〜５重
量％。(57) [Claim 1] It contains the following four components (A), (B), (C) and (D), and has a pH of 1.5 to 4, Rinse hair rinse for acid hair treated hair . (A) The following general formula (1) [In the formula, any one or two of R1 to R4 are an alkyl group having 10 to 24 carbon atoms, a hydroxyalkyl group having 10 to 24 carbon atoms, or a general formula R (CH 2 CH 2 O) n
Wherein R is an alkyl group having 10 to 24 carbon atoms or a hydroxyalkyl group having 10 to 24 carbon atoms, and n is an integer of 1 to 10.
An alkyl group of the general formula H (CH 2 CH 2 O) n or H
(CH (CH 3 ) CH 2 O) n (where n is an integer of 1 to 5), a benzyl group or a cinnamyl group, and X is a halogen atom or an alkyl sulfate having 1 or 2 carbon atoms. Group. 0.5 to 10% by weight of one or more of the quaternary ammonium salts represented by the formula: (B) 0.5 to 10% by weight of one or more of higher alcohols having a linear or branched alkyl or alkenyl group having 12 to 26 carbon atoms. (C) One or more of acetic acid, tartaric acid, boric acid, succinic acid, citric acid, salicylic acid, phosphoric acid, and hydrochloric acid. (D) The following general formula (2) [Wherein, R1 to R3 are an alkyl group having 3 to 21 carbon atoms, a hydroxyalkyl group having 3 to 35 carbon atoms, and a C3 to C21
Or an alkenyl group having 3 to 35 carbon atoms. 0.1 to 5% by weight of one or more of the oily components represented by
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03703492A JP3390461B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse for acid hair coloring |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03703492A JP3390461B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse for acid hair coloring |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05201835A JPH05201835A (en) | 1993-08-10 |
| JP3390461B2 true JP3390461B2 (en) | 2003-03-24 |
Family
ID=12486346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP03703492A Expired - Lifetime JP3390461B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse for acid hair coloring |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3390461B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5759527A (en) * | 1996-10-02 | 1998-06-02 | Colgate-Palmolive Company | Hair conditioning composition |
| GB2328954B (en) * | 1997-09-04 | 2002-01-09 | Henkel Kommandigesellschaft Au | The use of esterquats as emulsifiers for the production of formulations for coloring keratin fibers |
| US7538236B2 (en) | 2006-01-04 | 2009-05-26 | Suresh Narine | Bioplastics, monomers thereof, and processes for the preparation thereof from agricultural feedstocks |
| JP2016102099A (en) * | 2014-11-29 | 2016-06-02 | 有限会社オーセンエンジニアリング | Hair rinse agent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6130540U (en) * | 1984-07-30 | 1986-02-24 | ダイハツ車体株式会社 | Makeup box in the car |
| SE464401B (en) * | 1986-12-02 | 1991-04-22 | Autopart Sweden Ab | SUN PROTECTION FOR MOTOR VEHICLE |
| SE9002133L (en) * | 1990-06-15 | 1991-12-16 | Autopart Sweden Ab | MIRROR AND LIGHTING UNIT FOR MOTOR VEHICLE |
-
1992
- 1992-01-27 JP JP03703492A patent/JP3390461B2/en not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| 田村健夫 外１名著「香粧品化学−理論と実際」、フレグランスジャーナル社、平成２年９月２５日発行、第 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05201835A (en) | 1993-08-10 |
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