JP3045795B2 - High-strength spring and oil-tempered wire for spring used in its manufacture - Google Patents
High-strength spring and oil-tempered wire for spring used in its manufactureInfo
- Publication number
- JP3045795B2 JP3045795B2 JP3046416A JP4641691A JP3045795B2 JP 3045795 B2 JP3045795 B2 JP 3045795B2 JP 3046416 A JP3046416 A JP 3046416A JP 4641691 A JP4641691 A JP 4641691A JP 3045795 B2 JP3045795 B2 JP 3045795B2
- Authority
- JP
- Japan
- Prior art keywords
- spring
- oil
- strength
- tempered wire
- surface hardness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Description
【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION
【0001】[0001]
【産業上の利用分野】本発明は自動車や自動2輪車のエ
ンジンの弁ばねあるいは懸架ばね等に適した疲労強度の
優れた高強度ばね、およびこの高強度ばねの製造に適し
たばね用オイルテンパー線に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-strength spring having excellent fatigue strength suitable for a valve spring or a suspension spring of an engine of an automobile or a motorcycle, and an oil temper for a spring suitable for manufacturing the high-strength spring. About the line.
【0002】[0002]
【従来の技術】現在、自動車や自動2輪車のエンジンの
弁ばねあるいは懸架ばねの一部はオイルテンパー線を冷
間でばねに成形したものが用いられている。2. Description of the Related Art At present, a part of a valve spring or a suspension spring of an engine of an automobile or a motorcycle is formed by cold-forming an oil-tempered wire into a spring.
【0003】最近、エンジンの高出力化および車体の軽
量化のため、高強度で高疲労強度の弁ばねや懸架ばねが
強く求められている。ばねの疲労強度を向上させるに
は、ばね材料の強度を上げることが一つの有効な手段で
ある。従ってばね材料には合金元素量を増したばね用材
料が提案されている。しかしばね材料を高強度化すると
延性や靭性が低下し、また切欠き感受性が高くなるため
に、冷間成形でばね加工することが難しくなってしま
う。In recent years, valve springs and suspension springs having high strength and high fatigue strength have been strongly demanded in order to increase the output of an engine and reduce the weight of a vehicle body. Increasing the strength of the spring material is one effective means for improving the fatigue strength of the spring. Therefore, a spring material with an increased amount of alloying elements has been proposed as a spring material. However, when the strength of the spring material is increased, ductility and toughness are reduced, and the notch sensitivity is increased, so that it is difficult to perform spring working by cold forming.
【0004】[0004]
【発明が解決しようとする課題】本発明は冷間成形によ
るばね加工性が優れ且つ高強度のばね用オイルテンパー
線と、これを用いた高強度ばねの提供を課題としてい
る。SUMMARY OF THE INVENTION An object of the present invention is to provide an oil-tempered wire for a spring having excellent spring workability by cold forming and high strength, and a high-strength spring using the same.
【0005】[0005]
【課題を解決するための手段および作用】本発明者等は
この課題を解決するため、種々実験を重ねた結果、オイ
ルテンパーに際して鋼線の最表層を意図的に脱炭させる
ことにより、鋼線の冷間成形によるばね加工性が顕著に
向上することを知得した。また、鋼線の最表層を脱炭さ
せると、鋼線の表層の硬さが低下して疲労強度が低下す
るが、本発明者は、この疲労強度の低下は、ばね加工後
に窒化または浸炭窒化処理とショットピーニング処理を
行う事によって改善されて、高疲労強度を有する高強度
のばねが得られることを知得して本発明をなすに至っ
た。The present inventors have conducted various experiments to solve this problem, and as a result, intentionally decarburized the outermost layer of the steel wire at the time of oil tempering. It has been found that the spring workability by cold forming is remarkably improved. In addition, when the outermost layer of the steel wire is decarburized, the hardness of the surface layer of the steel wire is reduced and the fatigue strength is reduced. The present invention was found to be improved by performing the treatment and the shot peening treatment, and it was found that a high-strength spring having high fatigue strength was obtained.
【0006】本願は(1) 重量%で、C :0.50〜0.80、 Si:1.00〜2.50 Mn:0.40〜1.00、 Cr:0.40〜2.00 V :0.05〜0.60、 Mo:0.10〜1.00 を含有し、残部は実質的にFeからなる低合金鋼線を用
いて、オイルテンパーに際して脱炭により表層の硬度を
Hvで400以下とし、ばねに冷間成形し、その後窒化
または浸炭窒化とショットピーニングにより表層の硬度
をHvで900以上にした事を特徴とする高強度ばねで
ある。また(2) 重量%で、C :0.50〜0.80、 Si:1.00〜2.50 Mn:0.40〜1.00、 Cr:0.40〜2.00 V :0.05〜0.60、 Mo:0.10〜1.00 を含有し、残部は実質的にFeからなる低合金鋼線で、
オイルテンパーに際して脱炭により表層の硬度をHvで
400以下とした、前記(1)に記載の高強度ばねの製
造に用いるばね用オイルテンパー線である。In the present application, (1) by weight%, C: 0.50 to 0.80, Si: 1.00 to 2.50 Mn: 0.40 to 1.00, Cr: 0.40 to 2.00 V: 0.05 to 0.60, Mo: 0.10 to 1.00, and the balance being Hv using a low alloy steel wire substantially composed of Fe and decarburizing during oil tempering. Is a high-strength spring characterized in that the hardness of the surface layer is increased to 900 or more in Hv by cold forming into a spring and thereafter nitriding or carbonitriding and shot peening. (2) In weight%, C: 0.50 to 0.80, Si: 1.00 to 2.50 Mn: 0.40 to 1.00, Cr: 0.40 to 2.00 V: 0. 0.5 to 0.60, Mo: 0.10 to 1.00, and the balance is a low alloy steel wire substantially composed of Fe.
A spring oil-tempered wire used for manufacturing a high-strength spring according to (1), wherein the hardness of the surface layer is reduced to 400 or less in Hv by decarburization during oil tempering.
【0007】C:Cは鋼の強度を高めるのに有効な元素
であり、0.50%未満では必要な強度を得ることがで
きず、0.80%を越えて含有させてもそれ以上の強度
上の利点がないので0.50〜0.80%の範囲とする。C: C is an element effective for increasing the strength of steel. If the content is less than 0.50%, the required strength cannot be obtained. Since there is no advantage in strength, the range is 0.50 to 0.80%.
【0008】Si:Siはフェライト中に固溶することに
より鋼の強度を高め、耐へたり性を向上させるのに有効
な元素であり、1.00%未満では十分な耐へたり性を
確保することができず、2.50%を越えてもそれ以上
の効果が得られないため、1.00〜2.50%の範囲と
した。Si: Si is an element effective for increasing the strength of steel and improving sag resistance by forming a solid solution in ferrite. When the Si content is less than 1.00%, sufficient sag resistance is secured. Therefore, if the content exceeds 2.50%, no further effect can be obtained, so that the content is set in the range of 1.0 to 2.50%.
【0009】Mn:Mnは鋼の脱酸および鋼の焼入性を向
上させるのに有効な元素であり、0.40%未満ではそ
の効果は不十分であり、1.00%を越えてもそれ以上
の効果が得られないため、0.40〜1.00%の範囲と
した。Mn: Mn is an element effective for improving the deoxidation of steel and the hardenability of steel. If its content is less than 0.40%, its effect is insufficient. Since no further effect can be obtained, the range is set to 0.40 to 1.00%.
【0010】Cr:CrはMnと共に鋼の焼入れ性を向上
させるのに有効な元素であり、0.40%未満ではその
効果は不十分であり、2.00%を越えると炭化物の固
溶を抑制し強度の劣化をまねくため、0.40〜2.00
%の範囲とした。[0010] Cr: Cr is an element effective for improving the hardenability of steel together with Mn. If its content is less than 0.40%, its effect is insufficient. 0.40 to 2.00 in order to suppress and lead to deterioration of strength.
%.
【0011】Mo:Moは焼もどし軟化抵抗を高め、また
微細な炭化物を析出することにより、ばねに強度と靭性
を付与するために必要な元素であり、0.10%未満で
はその効果が認められず、1.00%を越えると効果が
飽和してしまうため、0.10〜1.00%の範囲とし
た。Mo: Mo is an element necessary for imparting strength and toughness to a spring by increasing temper softening resistance and precipitating fine carbides. Mo is effective at less than 0.10%. However, if the content exceeds 1.00%, the effect is saturated. Therefore, the content is set in the range of 0.10 to 1.00%.
【0012】V:Vは鋼の結晶粒の微細化、また析出硬
化による強度の向上、および耐へたり性の改善に有効な
元素であり、0.05%未満ではその効果は認められ
ず、0.60%を越えて添加しても効果は飽和してしま
うため、0.05〜0.60%の範囲とした。V: V is an element effective for refining steel crystal grains, improving strength by precipitation hardening, and improving sag resistance. If V is less than 0.05%, the effect is not recognized. The effect is saturated even if it exceeds 0.60%, so the range is 0.05 to 0.60%.
【0013】本発明では、オイルテンパー線をばね加工
する際の折損を防止するために、オイルテンパーに際し
て表面を脱炭させて、表面硬度をHvで400以下にす
る。オイルテンパー線を格別に工夫しないで高強度化す
ると、鋼線のきず感受性が高くなり、従来は無害とされ
ていた極めて微細な表面欠陥が起点となって、ばね加工
時に折損し易い。後で図2で述べるが、オイルテンパー
に際して表面を脱炭させて、表面硬度をHvで400以
下にすると、ばね加工時の折損を有効に防止することが
できる。この脱炭と表面硬度の調整は、オイルテンパー
に際しての加熱炉の雰囲気を調整する事によって達成す
ることができる。尚、オイルテンパーの前の工程におい
て、あらかじめ脱炭処理を施しておいてもよい。In the present invention, the surface is decarburized at the time of oil tempering so as to prevent the oil tempered wire from being broken at the time of spring working, and the surface hardness is set to 400 or less in Hv. If the strength of the oil-tempered wire is increased without specially devising it, the sensitivity of the steel wire to flaws is increased, and extremely fine surface defects, which have been regarded as harmless in the past, serve as starting points, and are easily broken during spring processing. As will be described later with reference to FIG. 2, when the surface is decarburized at the time of oil tempering and the surface hardness is set to 400 or less in Hv, breakage during spring working can be effectively prevented. The decarburization and the adjustment of the surface hardness can be achieved by adjusting the atmosphere of the heating furnace during oil tempering. In the process before the oil tempering, a decarburization treatment may be performed in advance.
【0014】本発明の請求項2は、このオイルテンパー
線を用いた高強度ばねである。表面の硬さの低下はばね
の疲労強度を低下させる原因となる。このため本発明で
は、ばね加工後に窒化または浸炭窒化処理とショットピ
ーニングを施して、ばねの表面硬度をHvで900以上
に調整する。本発明のオイルテンパー線は、ばね加工前
の表面硬度は低いが、ばね加工を行い浸炭窒化とショッ
トピーニングを施すことによって、後で図3で述べる如
く、ばねの表面硬度は十分に上昇してHvで900以上
とすることができる。A second aspect of the present invention is a high-strength spring using the oil-tempered wire. A decrease in surface hardness causes a decrease in the fatigue strength of the spring. Therefore, in the present invention, nitriding or carbonitriding and shot peening are performed after the spring processing to adjust the surface hardness of the spring to 900 or more in Hv. The oil-tempered wire of the present invention has a low surface hardness before spring processing, but by performing spring processing and performing carbonitriding and shot peening, the surface hardness of the spring is sufficiently increased as described later with reference to FIG. Hv can be 900 or more.
【0015】[0015]
【実施例】表1に示す化学成分を有する鋼線を用い、直
径3.2mmで引張強さ2160N/mm2の強度を有す
るオイルテンパー線を製作した。尚このオイルテンパー
処理に際して、加熱炉は電気炉で雰囲気酸素量を下記の
如くに調整して、表面を脱炭させた。A:2〜3容量
%、B:5〜7容量%、C:10〜15容量%、D:2
0以上容量%、A〜Dの雰囲気で製造したオイルテンパ
ー線の表層の硬さ分布を図1のA〜Dで示した。図中比
較材は本発明品と同一化学成分の材料で従来法により表
面脱炭のないオイルテンパー線の例である。EXAMPLES Using a steel wire having the chemical composition shown in Table 1, an oil-tempered wire having a diameter of 3.2 mm and a tensile strength of 2160 N / mm 2 was produced. At the time of the oil tempering treatment, the surface of the heating furnace was decarburized by adjusting the amount of atmospheric oxygen in an electric furnace as described below. A: 2-3% by volume, B: 5-7% by volume, C: 10-15% by volume, D: 2
The hardness distribution of the surface layer of the oil-tempered wire manufactured in the atmosphere of A to D with 0% or more by volume is shown by A to D in FIG. The comparative material in the figure is an example of an oil-tempered wire having the same chemical composition as the product of the present invention and having no surface decarburization by the conventional method.
【0016】比較材およびA〜Dの各オイルテンパー線
を、表2に示すばね仕様に成形加工を行い、ばね加工時
における折損率を調べて、図2に示した。図2の比較材
およびA,Bにみられる如く、表面硬度が高いオイルテ
ンパー線はばね加工で折損が発生したが、図2のC,D
にみられる如く、表面硬度がHvで400以下の場合に
はばね加工で折損することがなかった。そこで本発明は
表面硬度をHvで400以下とすることにした。The comparative material and each of the oil-tempered wires A to D were formed into the spring specifications shown in Table 2, and the breakage rate during the spring processing was examined. The results are shown in FIG. As shown in the comparative material of FIG. 2 and the oil-tempered wires having high surface hardness as shown in A and B, breakage occurred by spring processing, but C and D in FIG.
As can be seen, when the surface hardness was 400 or less in Hv, there was no breakage by spring processing. Therefore, in the present invention, the surface hardness is set to 400 or less in Hv.
【0017】[0017]
【表1】 [Table 1]
【0018】本発明のD材と比較材を用いて製造したば
ねに、浸炭窒化とショットピーニングを施し、ばねの表
面硬度を調査した結果を図3に示した。尚D材と比較材
に施した浸炭窒化とショットピーニングの条件は同一で
ある。オイルテンパー線ではD材は比較材に比べて表面
硬度が低いが、ばね加工を行い更に浸炭窒化とショット
ピーニングを施すと、ばねの表面硬度はHvで900以
上となって、比較材と同等の表面硬度となる。FIG. 3 shows the results obtained by subjecting a spring manufactured using the D material of the present invention and the comparative material to carbonitriding and shot peening and examining the surface hardness of the spring. The conditions of carbonitriding and shot peening applied to the D material and the comparative material are the same. In the oil-tempered wire, the D material has a lower surface hardness than the comparative material, but when subjected to spring processing and further carbonitriding and shot peening, the surface hardness of the spring becomes 900 or more in Hv, which is equivalent to the comparative material. It becomes the surface hardness.
【0019】[0019]
【表2】 [Table 2]
【0020】図4は、ばね加工を行い更に浸炭窒化とシ
ョットピーニングを施した本発明のD材と比較材のばね
疲労試験の結果である。ばね疲労試験は星型コイルばね
疲労試験機(東海試験機株製)を用いて行った。図4に
みられる如く、本発明のD材のばね疲労強度は、比較材
と同等であった。FIG. 4 shows the results of a spring fatigue test of the D material of the present invention, which was subjected to spring working, and further subjected to carbonitriding and shot peening, and a comparative material. The spring fatigue test was performed using a star coil spring fatigue tester (manufactured by Tokai Testing Machine Co., Ltd.). As shown in FIG. 4, the spring fatigue strength of the D material of the present invention was equivalent to that of the comparative material.
【0021】[0021]
【実施例2】表3に示す化学成分の鋼線を用いて直径
3.2mmで引張強さ2210N/mm2の、表面を脱炭
させて表面硬度がHvで400以下のオイルテンパー線
を製作した。その表面硬度の例を図5に示した。このオ
イルテンパー線を表2に示すばね仕様にばね加工した
が、ばね加工時の折損は発生しなかった。このばねに更
に浸炭窒化処理とショットピーニングを施し、ばね疲労
試験を行った。浸炭窒化とショットピーニングを行った
後のばねの表面は、図6にみられる如く十分に硬質で、
その結果5×107回で590±530N/mm2とい
う、高い疲労強度が得られた。Example 2 An oil-tempered wire having a diameter of 3.2 mm and a tensile strength of 2210 N / mm 2 and a surface hardness of 400 or less in Hv was produced using a steel wire having a chemical composition shown in Table 3 and a tensile strength of 2210 N / mm 2. did. FIG. 5 shows an example of the surface hardness. The oil-tempered wire was spring-processed according to the spring specifications shown in Table 2, but no breakage occurred during the spring processing. The spring was further subjected to carbonitriding and shot peening to conduct a spring fatigue test. The surface of the spring after carbonitriding and shot peening is sufficiently hard as seen in FIG.
As a result, a high fatigue strength of 590 ± 530 N / mm 2 was obtained in 5 × 10 7 times.
【0022】[0022]
【表3】 [Table 3]
【0023】[0023]
【発明の効果】本発明のオイルテンパー線を用いると、
ばね加工時の折損を有効に防止することができる。した
がって従来よりも高強度のオイルテンパー線を用いて
も、ばね加工時の折損を防止することができる。この結
果、従来よりも高強度で高疲労強度のばねの製造が可能
となる。When the oil-tempered wire of the present invention is used,
Breakage during spring processing can be effectively prevented. Therefore, even if an oil-tempered wire having higher strength than the conventional one is used, breakage during spring processing can be prevented. As a result, it becomes possible to manufacture a spring having higher strength and higher fatigue strength than before.
【図1】は実施例1におけるオイルテンパー線の表面硬
度を示す図、FIG. 1 is a diagram showing the surface hardness of an oil-tempered wire in Example 1.
【図2】はオイルテンパー線の表面硬度とばね加工にお
ける折損の関係の例を示す図、FIG. 2 is a diagram showing an example of the relationship between the surface hardness of an oil-tempered wire and breakage in spring processing.
【図3】は浸炭窒化とショットピーニング後のばねの表
面硬度の例を示す図、FIG. 3 is a diagram showing an example of the surface hardness of a spring after carbonitriding and shot peening;
【図4】はばね疲労試験の結果の例を示す図、FIG. 4 is a view showing an example of a result of a spring fatigue test;
【図5】はオイルテンパー線の表面硬度の他の例を示す
図、FIG. 5 is a diagram showing another example of the surface hardness of an oil-tempered wire;
【図6】は浸炭窒化とショットピーニング後のばねの表
面硬度の他の例の図、である。FIG. 6 is a diagram of another example of the surface hardness of a spring after carbonitriding and shot peening.
フロントページの続き (72)発明者 小野田 光芳 千葉県習志野市東習志野7−5−1 鈴 木金属工業株式会社内 (72)発明者 林 博昭 千葉県習志野市東習志野7−5−1 鈴 木金属工業株式会社内 (72)発明者 中野 修 愛知県豊田市トヨタ町1番地 トヨタ自 動車株式会社内 (72)発明者 石川 裕二 愛知県愛知郡東郷町大字春木字蛭池1番 地 株式会社東郷製作所内 (72)発明者 内田 尚志 東京都千代田区大手町二丁目6番3号 新日本製鐵株式会社内 (56)参考文献 特開 平2−301541(JP,A) 特開 昭63−176430(JP,A) 特開 昭62−177152(JP,A) 特開 昭63−303036(JP,A) 特開 平3−162550(JP,A) (58)調査した分野(Int.Cl.7,DB名) C22C 38/00 301 C21D 7/06 C22C 38/24 C22C 8/32 Continued on the front page (72) Inventor Mitsuyoshi Onoda 7-5-1 Higashi Narashino, Narashino City, Chiba Prefecture Inside Suzuki Metal Industry Co., Ltd. (72) Inventor Hiroaki Hayashi 7-5-1 Higashi Narashino City, Narashino City, Chiba Prefecture Suzuki Metal Industry Co., Ltd. In-house (72) Inventor Osamu Nakano 1 Toyota Town, Toyota City, Aichi Prefecture Inside Toyota Motor Co., Ltd. Inventor Naoshi Uchida 2-6-3 Otemachi, Chiyoda-ku, Tokyo Nippon Steel Corporation (56) References JP-A-2-301541 (JP, A) JP-A-63-176430 (JP, A JP-A-62-177152 (JP, A) JP-A-63-303036 (JP, A) JP-A-3-162550 (JP, A) (58) Fields investigated (Int. Cl. 7 , DB name) C22C 38/00 301 C21D 7/06 C22C 38/24 C22C 8/32
Claims (2)
いて、オイルテンパーに際して脱炭により表層の硬度を
Hvで400以下とし、ばねに冷間成形し、その後窒化
または浸炭窒化とショットピーニングにより表層の硬度
をHvで900以上にした事を特徴とする高強度ばね。C: 0.50 to 0.80, Si: 1.00 to 2.50 Mn: 0.40 to 1.00, Cr: 0.40 to 2.00 V: 0% by weight 0.05 to 0.60, Mo: 0.10 to 1.00, the balance being a low alloy steel wire substantially composed of Fe, and the hardness of the surface layer is 400 or less in Hv by decarburization during oil tempering. A high-strength spring characterized by having a surface hardness of 900 or more in Hv by cold forming into a spring and thereafter nitriding or carbonitriding and shot peening.
オイルテンパーに際して脱炭により表層の硬度をHvで
400以下とした、請求項1に記載の高強度ばねの製造
に用いるばね用オイルテンパー線。2. In% by weight, C: 0.50 to 0.80, Si: 1.00 to 2.50 Mn: 0.40 to 1.00, Cr: 0.40 to 2.00 V: 0 0.05 to 0.60, Mo: 0.10 to 1.00, and the balance is a low alloy steel wire substantially composed of Fe.
The oil tempered wire for a spring used for manufacturing a high-strength spring according to claim 1, wherein the hardness of the surface layer is reduced to 400 or less in Hv by decarburization during oil tempering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3046416A JP3045795B2 (en) | 1991-03-12 | 1991-03-12 | High-strength spring and oil-tempered wire for spring used in its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3046416A JP3045795B2 (en) | 1991-03-12 | 1991-03-12 | High-strength spring and oil-tempered wire for spring used in its manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04285142A JPH04285142A (en) | 1992-10-09 |
| JP3045795B2 true JP3045795B2 (en) | 2000-05-29 |
Family
ID=12746548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3046416A Expired - Lifetime JP3045795B2 (en) | 1991-03-12 | 1991-03-12 | High-strength spring and oil-tempered wire for spring used in its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3045795B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3173756B2 (en) * | 1994-07-28 | 2001-06-04 | 株式会社東郷製作所 | Manufacturing method of coil spring |
| JP3403913B2 (en) * | 1997-03-12 | 2003-05-06 | 新日本製鐵株式会社 | High strength spring steel |
| JP3754788B2 (en) * | 1997-03-12 | 2006-03-15 | 中央発條株式会社 | Coil spring with excellent delayed fracture resistance and manufacturing method thereof |
| EP2546380B1 (en) * | 2010-03-11 | 2016-06-08 | Nippon Steel & Sumitomo Metal Corporation | High-strength steel wire rod and high-strength bolt with excellent resistance to delayed fracture, and manufacturing method therefor |
| EP3081661B1 (en) * | 2013-12-12 | 2019-07-17 | Aichi Steel Corporation | Ring member for cvt and method for producing same |
-
1991
- 1991-03-12 JP JP3046416A patent/JP3045795B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04285142A (en) | 1992-10-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3173756B2 (en) | Manufacturing method of coil spring | |
| US7763123B2 (en) | Spring produced by a process comprising coiling a hard drawn steel wire excellent in fatigue strength and resistance to setting | |
| JP2839900B2 (en) | Spring steel with excellent durability and sag resistance | |
| JP4116762B2 (en) | High strength spring steel excellent in hydrogen fatigue resistance and method for producing the same | |
| JP4097151B2 (en) | High strength spring steel wire and high strength spring with excellent workability | |
| US7615186B2 (en) | Spring steel excellent in sag resistance and fatigue property | |
| EP0614994B1 (en) | Spring steel wires and process for producing the same | |
| JP3045795B2 (en) | High-strength spring and oil-tempered wire for spring used in its manufacture | |
| JP2783145B2 (en) | Steel for nitrided spring and nitrided spring with excellent fatigue strength | |
| JP2708279B2 (en) | Manufacturing method of high strength spring | |
| JP3859331B2 (en) | High fatigue strength steel wires and springs and methods for producing them | |
| CN115485409B (en) | Spring steel wire | |
| JP4464511B2 (en) | Method for producing high-strength ultrafine steel wire with excellent ductility and fatigue properties | |
| JP4133515B2 (en) | Spring steel wire with excellent sag and crack resistance | |
| JP2003003241A (en) | High strength spring steel wire | |
| JPH05331597A (en) | High fatigue strength coil spring | |
| WO2004055226A1 (en) | Steel wire for spring | |
| JPH10251760A (en) | High-strength oil-tempered wire excellent in spring formability and method for producing the same | |
| JP3872364B2 (en) | Manufacturing method of oil tempered wire for cold forming coil spring | |
| JPH05179348A (en) | Method for manufacturing coil spring by hot coiling | |
| JP3142689B2 (en) | Spring with excellent fatigue strength | |
| JP5400536B2 (en) | Hard drawing line | |
| JP2003193197A (en) | High strength coil spring and production method therefor | |
| JP2790303B2 (en) | Method of manufacturing high fatigue strength spring and steel wire used for the method | |
| JP2860789B2 (en) | Spring steel with excellent hardenability and durability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20000229 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090317 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090317 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100317 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100317 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110317 Year of fee payment: 11 |
|
| EXPY | Cancellation because of completion of term |